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  • Articles  (111)
  • Blackwell Publishing Ltd
  • National Academy of Sciences
  • 1995-1999  (44)
  • 1990-1994
  • 1980-1984  (67)
  • 1925-1929
  • 1997  (44)
  • 1981  (67)
  • Physics  (111)
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  • Articles  (111)
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  • 1995-1999  (44)
  • 1990-1994
  • 1980-1984  (67)
  • 1925-1929
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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: X-ray diffraction (XRD) patterns from nominally β-SiC specimens often differ from those expected for the cubic crystal structure. These differences include the presence of additional peaks, enhanced background intensities, peak broadening, changes in relative peak heights, and shifts in peak positions. It has long been recognized that they are due to the presence of stacking faults, and models relating the experimental observations to stacking fault population have continued to evolve. The presence and relative magnitude of these features vary among different β-SiC specimens. In this work, computer simulations were used to show that the variations are closely related to differences in the type and spatial distribution of stacking faults in each specimen. In these simulations, stacking sequences were generated using a selectively activated 1-D Ising model with a Boltzmann-type probability function for specifying errors, which allows a wide variety of fault configurations to be generated. Direct correlations between different features in the XRD data to the underlying fault population are demonstrated, which are discussed in this paper. It is also shown that this computer model is general, in the sense that many of the models presented in prior work can be interpreted as limiting cases of it.
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  • 2
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    Oxford, UK : Blackwell Publishing Ltd
    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: Dipole-dipole induced polarization (IP) data are displayed typically as multi-level profiles, or as contours on vertical sectional plots referred to as pseudo-sections. The dipole-dipole array tends to yield IP anomalies in which the most anomalous values are displaced laterally from the source body. The data patterns are fairly interpretable on pseudo-sections or on multi-level profiles but are sufficiently complex to discourage the contouring of the data in plan.A method was developed for the presentation of dipole-dipole IP data on a contour map. The method consists of a simple averaging of data which can be performed manually if desired. It yields a single output value per station which reflects all levels of the pseudo-section, and is suitable for contouring in plan. The advantage of the technique is that it provides a quantitative picture of IP anomalies in their background or regional setting.
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  • 3
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    Oxford, UK : Blackwell Publishing Ltd
    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: Constant offset sections can be mapped to a fixed offset and compared in order to provide a method of velocity analysis. The direct mapping to zero offset prior to stack might provide an alternative processing procedure to NMO and stack. The main advantage of such a procedure would lie in the correct treatment of cross-dips, but interpretational advantages might also follow from the performance of partial stacks biased to either high or low offset information.
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  • 4
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    Oxford, UK : Blackwell Publishing Ltd
    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: Induced polarization and resistivity model studies over thin dykes for varying resistivity contrasts, depth of burial, and dip angles show striking parallelism of the surface apparent resistivity contours with the boundary of the body. This effect may be utilized for the estimation of strike length of the body. Results show that intermediate values of the electrode spacing is satisfactory for detection under widely varying conditions of resistivity contrast and depth. The percentage frequency effect (P.F.E.) and the metal factor (M.F.) responses are found to be more sensitive to the variation in the depth of burial than the resistivity responses. Pseudosections for P.F.E. and M.F. are concentrated much closer to the body than the resistivity pseudo-sections.
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  • 5
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    Oxford, UK : Blackwell Publishing Ltd
    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: A direct interpretation scheme is developed which is capable of determining most of the geological features of a ground which can be assumed to be two dimensional in structure. This scheme extends the earlier work of Pekeris (1940) and Koefoed (1968) to the case where the basal layer of a ground is undulating. It also has a limited use for finding the parameters of a dipping dyke in the lower medium. Though the top and dip of the dyke can be determined, this is not true for the thickness.
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  • 6
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    Oxford, UK : Blackwell Publishing Ltd
    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: Laboratory studies of absorption-frequency behavior in rocks often use spectral ratios of digitally recorded ultrasonic signals which have been transmitted through a rock sample and a reference sample of very low absorption, respectively. It is proposed to treat the digitally recorded signals as an autoregressive-moving average (ARMA) process which, using recursive filter concepts, can be represented as a ratio of two polynomials in the z-transform variable z. The numerator polynomial contains only that part of the signal that is modified by anelastic effects, whereas the denominator contains the elastic effects of the physical apparatus such as reverberations. Examples are given which show that this separation of the recorded signal greatly facilitates the laboratory investigation of loss mechanisms and absorption-frequency behavior based on spectral ratios.
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  • 7
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    Oxford, UK : Blackwell Publishing Ltd
    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
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  • 8
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    Oxford, UK : Blackwell Publishing Ltd
    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: The generalized integral equation for the electric potential governed by a quasi-harmonic equation can be derived via a variational formulation. For surface current distributions it is not always a Fredholm integral equation of the second kind. Numerical solutions of the general heterogeneous problem can be obtained with the “reciprocal averaging technique”, where the solution is obtained a second time after exchange of source and field points.
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  • 9
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    Oxford, UK : Blackwell Publishing Ltd
    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: A method to calculate the resistivity transform of Schlumberger VES curves has been developed. It consists in approximating the field apparent resistivity data by utilizing a linear combination of simple functions, which must satisfy the following requirements: (i) they must be suitable for fitting the resistivity data; (ii) once the fitting function has been obtained they allow the kernel to be determined in an analytic way.The fitting operation is carried out by the least mean squares method, which also accomplishes a useful smoothing of the field curve (and therefore a partial noise filtering). It gives the possibility of assigning different weights to the apparent resistivity values to be approximated according to their different reliability.For several examples (theoretical resistivity curves in order to estimate the precision of the method and with field data to verify the practicality) yield good results with short execution time independent of shape the apparent resistivity curve.
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  • 10
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    Oxford, UK : Blackwell Publishing Ltd
    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: A method is given for solving the dc electric field problem of a point current source in an anisotropic 2 1/2-dimensional structural model. The surface integral equation of the field strength is given. Parallel to the strike the field strength is represented by a Fourier series. On the plane perpendicular to the strike each term of the field strength series is solved by means of the method of sub-sections, where linear behaviour of field strength over the sub-sections is assumed. Some numerical examples for different galvanic effects are given.
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  • 11
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    Oxford, UK : Blackwell Publishing Ltd
    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
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  • 12
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    Oxford, UK : Blackwell Publishing Ltd
    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
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  • 13
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    Oxford, UK : Blackwell Publishing Ltd
    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: It is proposed that the vertical resolving power of a seismic signal is controlled by three aspects: the width of the central lobe, the side lobe ratio, and the side-tail oscillations. A comparative study of zero-phase signals covering the same frequency range shows that improvement of any one of these aspects inevitably leads to deterioration of one of the other aspects.An analytical simulation model is proposed of zero-phase signals free from side-tail oscillations, in which both the width of the central lobe and the side lobe ratio are adjustable. Analysis of the spectra of this model shows that, while the high frequency content of the spectrum is essential for obtaining a small width of the central lobe, the low frequency content of the spectrum plays an essential part in causing a low value of the side lobe ratio.
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  • 14
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    Oxford, UK : Blackwell Publishing Ltd
    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: The objective of this study is to generate the separation-distance-domain (r-domain) transformation of the theoretically calculated wave number domain (m-domain) electromagnetic induction field component Bz(m, ω) of a stratified medium and to search for interpretive information which has been absent in the previously achieved numerical solutions of the problem.The r-domain kernel R̃(r, ω) function defining the induction field appears to adequately reflect the layering and electrical properties of the medium if it is expressed as a function of the frequency if the source-receiver separation r is small with respect to the thickness of the first layer. However, exact values of the conductivity cannot be distinguished from those of the neighboring values unless a resistive basement layer is present. This feature is the result of the truncation in series representation of the kernel function R̃(m, ω). However, this truncation is regarded as significant in the case of a conductive first layer. In m-domain static-zone studies, a conductive first layer slightly influences its r-domain correspondent.Although the computational cost of obtaining the kernel B(r, ω) by evaluation of the convolution in a cylindrical coordinate system is high, this semi-analytic solution is still superior to those based on the asymptotic assumptions.
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  • 15
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    Oxford, UK : Blackwell Publishing Ltd
    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: Les différentes sources d'erreurs de la mesure gravimétrique sont examinées. Leur connaissance a une importance particulière dans les prospections de surface, dites “microgravimétriques”.Les auteurs démontrent, expériences à l'appui, que toutes précautions prises, la source la plus fréquente d'erreurs de mesure en microgravimétrie est une mauvaise estimation de la dérive.Les auteurs exposent alors un processus de mesure et d'interprétation dont le but est une meilleure estimation de la dérive. La justification théorique et expérimentale du processus est donnée. La méthode implique une prise de mesure suivant une répartition spatiale aléatoire ou semi-aléatoire. Un cas réel est décrit.
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  • 16
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    Oxford, UK : Blackwell Publishing Ltd
    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
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  • 17
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    Oxford, UK : Blackwell Publishing Ltd
    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: A number of time-domain IP traverses were carried out across two parallel mineralized sheets in the Lower Pillow Lavas, near Mitsero, Cyprus with Huntec Mark III equipment using the pole-dipole array. In one sheet the mineralization was disseminated (2%S), and in the other it was massive (30%S). The transients were recorded at separation n= 2 at a number of points to give the complete shape of the curves. The normalized time integrals were anomalous over the two sheets, but were not significantly different; the highest values being observed over the disseminated sheet. Both sheets were also associated with high electromagnetic components of the decay curve. The chargeability and resistivity values obtained over the disseminated body were considerably higher. The metal factor was also of value in discriminating between massive ore, disseminated mineralization, and barren rock. The values of P2 and P3 for the two bodies were also compared (P2 and P3 are defined by〈displayedItem type="mathematics" xml:id="mu1" numbered="no"〉〈mediaResource alt="image" href="urn:x-wiley:00168025:GPR906:GPR_906_mu1"/〉where M1 to M4 are the amplitudes of the decay curve at 55, 130, 280 and 580 ms respectively). For the massive ore, P was inversely related to M, but for the disseminated ore P was independent of M. Four simple parameters from the decay curves show that indices of curve shape offer the best prospect of grade discrimination.
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  • 18
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    Oxford, UK : Blackwell Publishing Ltd
    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
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  • 19
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    Oxford, UK : Blackwell Publishing Ltd
    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: Large gravity platforms are often used as alternatives to the more conventional pilesupported structures in hydrocarbon exploitation. A gravity structure, as opposed to the piled structure, is sitting on the sea floor by virtue of its weight and base width; as such it poses considerable problems for the site investigation engineer. One such problem is the calculation of the settlement of the structure and its time history; these depend upon the permeability and compressibility of the soil and its drainage conditions. The required data are usually obtained by sampling for subsequent laboratory testing. The collection of an undisturbed sample is beset by problems so that the consolidation behavior of the foundation material can only be inadequately assessed by laboratory testing. However, a series of laboratory consolidation experiments during which seismic velocities have been measured on the sample as consolidation proceeds shows that it is possible to reconstruct the stress-strain and time-dependent curves from the seismic data, once the initial void ratio and permeability of the soil are known. This leads the way to an in situ technique for predicting settlement using a combination of geophysical techniques (electrical resistivity and seismic velocities) to obtain the required engineering properties.
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  • 20
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    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: An underground gravity study was carried out under extreme conditions of the Alpine regions. The lead–zinc mine Bleiberg, Carinthia, was selected as an example to show the possibilities and limitations of the subsurface gravity method. For in situ density determinations, gravity measurements were made in two vertical mine shafts passing through Triassic sedimentary rocks of the Bleiberg Unit. The main prblem in gravity data reduction in extremely rugged topography is the accurate calculation of the terrain effect on underground stations. A general discussion of the various corrections required for the gravity measurements in the mine is presented. The mean interval densities in the two shafts, in limestone, dolomite, and schists formations, were determined as 2.76 and 2.77 g/cm3, respectively, with an accuracy of better than 0.01 g/cm3 for a depth interval of 50 m. The interval densities provide valuable information about the lithological and structural changes in the shaft surroundings and also agree well with the representative hand sample densities.In the second part, the applications of subsurface horizontal gravity surveys in exploration are discussed. Since the influence of topography is less underground because of the greater distance to the surface, subsurface surveys have definite advantages over surface surveys and can be very helpful in locating anomalous density zones in the mines. An example of gravity survey with a station spacing of 10 m at a depth of about 540 m is presented.
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  • 21
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    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
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  • 22
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    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: Lateral inhomogeneities generate fluctuations in the traveltime of seismic waves. By evaluation of these traveltime fluctuations from different source and receiver positions, lateral inhomogeneities can be located using a pseudo inverse matrix method (Aki, Christoffersson and Husebye 1977). The formulation of the problem is possible for transmitted waves as well as for reflected and refracted waves. In reflection seismics this method is of importance, if no reflections from the inhomogeneities themselves, but only reflections from lower boundaries can be observed.The basic assumptions for the mathematical formulation are (1) the average velocities and depths of the reflecting horizons are known already from standard processing methods, and (2) the traveltime residuals are due to lateral velocity changes between different reflectors or between reflectors and the surface. The area of the earth to be considered is divided into layers and the layers into rectangular blocks. The parallel displacement of a ray after passing a disturbed block is neglected, only the traveltime residual is taken into account.In this paper the method and its application to data obtained with two-dimensional models are described.
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  • 23
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    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: The electric and magnetic fields generated by horizontal electric and vertical magnetic dipoles lying on the surface of a conducting medium with horizontal anisotropy are investigated. Full expressions of their Fourier transforms are given, and the fields for a vertical magnetic dipole are calculated numerically. The radial and vertical magnetic components are found to be independent of the receiver-transmitter direction, whereas the other magnetic and electric components strongly vary with this direction. These results give useful criteria for defining the direction and amplitude of anisotropy from ground data; a ground experiment on fissured limestone was found to confirm the expected variations of the various field components. It is believed that this electromagnetic method can be used in order to provide information about the direction and amplitude of electric anisotropy.
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  • 24
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    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: On the basis of known relationships between various elastic moduli and porosity in a porous medium and of various parameters from well-logs, the reflection coefficient for normal incidence of P-waves is compared to that of S-waves. If pores contain gas, the reflection coefficient in S is much smaller than that of P but shows large differences for different gas concentration in one of the two layers while the reflection coefficient in P is insensitive to the gas concentration. It is found that the ratio of the two reflection coefficients provides a powerful tool for discriminating between layers of different degrees of gas concentration and for the extension of the sensitivity of the bright-spot technique to greater depths.
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  • 25
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    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: The laterites in Burundi, which are formed by weathering of ultrabasic rocks, show a complete profile with the following horizons: canga, the ferruginous crust capping, ferralite, consisting essentially of iron hydroxides, and saprolite, which contains a large quantity of hydrosilicate minerals. Nickel bearing minerals occur in the saprolite and the lower portion of ferralite.Resistivity well-logging and resistivity sounding indicated that the electrical properties of rocks depend upon their composition: Canga and ferralite showed high resistivities of 6,500 Ωm and 800 Ωm, respectively. The resistivity of saprolite was found to be much lower, between 10 Ωm and 20 Ωm. The laterite is underlain by resistive peridotite. The chargeability of saprolite was found to be lower than that of the upper horizons and the bedrock.Electrolytic conductivity of laterite, which depends on the geometry of the deposit, was found to be low, because the laterite contains moisture and ground water, which are highly resistive. The relatively high conductivity of saprolite is caused by nickeliferous hydrosilicates, which exhibit the electrical properties of clay minerals, with an apparent maximum conductivity of 0.25 S/m. The conductivity of saprolite corresponds to a concentration between 30% and 50% of conductive silicate minerals distributed in the pore space of deposit. A nickel enrichment of up to 6% was estimated from the resistivity of the saprolite.Prospecting for laterites by electrical sounding showed that the development of laterite horizons in a nickel deposit correlates with the surface morphology of weathered ultrabasic massif. Thus the method can be used in preliminary exploration of such deposits.
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    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
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    Topics: Geosciences , Physics
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  • 27
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    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: Thirty-eight gravity method estimates of the depth to the pre-Cenozoic surface under Yucca Flat are used to determine the statistical accuracy associated with the gravity method. Results indicate that the gravity method tends to overestimate the depth to the pre-Cenozoic surface, on the average, by 3.5 m with a standard deviation of 75.2 m. No significant change of this statistical estimate was observed with (1) depth, (2) location, or (3) date when the gravity-method estimate was made.
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    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
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    Topics: Geosciences , Physics
    Notes: Since its development some thirty years ago, the airborne electromagnetic (AEM) method has been primarily used as a tool for mineral prospecting. However, advanced AEM systems are capable of other tasks, such as geological mapping and groundwater exploration. Excellent correlation between maps of apparent conductivity and geological maps was observed in several regions of Brazil where AEM surveys were performed. The degree of correlation seems to depend on the local climate. In humid and subhumid tropical regions, a weathered layer develops whose thickness and conductivity depend upon bedrock lithology. Therefore certain lithological types can be recognized from their conductivity signature; e.g., granites and Precambrian coarse clastic rocks are resistive, metavolcanic (particularly mafic) and volcanic rocks are conductive, Phanerozoic sediments are generally highly conductive.Two geophysical surveys are analyzed in the paper. The first was conducted with the time-domain, towed-bird AEM system in the Itapicuru greenstone belt in the state of Bahia. The apparent conductivity map correlated better with the local lithology than the magnetic map. Results of the AEM survey were successfully used to improve the regional geological map. A helicopter EM system was used in the second survey, which covered a portion of the Precambrian shield of Rio Grande do Sul. Also in this region ground checks confirmed the usefulness of conductivity surveys in geological mapping.The technique outlined in the paper holds great promise for countries of humid tropical climate, where few outcrops exist and access is often difficult. The tests performed in Brazil indicate that by executing AEM/aeromagnetic surveys during initial stages of mapping and exploration programs, time and expenditure required for geological field work can be considerably reduced. The resulting geological maps are more accurate and the inventory of mineral occurrences becomes more complete.
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  • 29
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    Geophysical prospecting 29 (1981), S. 0 
    ISSN: 1365-2478
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: The examination of apparent resistivity space sections over two-dimensional targets requires the accumulation of large amounts of data, if the resistivity field is to be adequately described.Whilst such data may be obtained from an intensive sounding traverse in the field, it is desirable for interpretation purposes to be able to generate such space sections for a range of model variations.Within their limitations, tank analogs can be used to provide such interpretation material, but the collection of data can itself be time-consuming. In this paper, an account is given of the development of an automated tank analog, where an entire space section can be scanned and the output obtained in paper tape format for later processing on a digital computer. The resistance measurement accuracy attained is comparable with normal field measurement accuracy.A practical example of the use of this analog in investigating the problem of resolving and discriminating between two horizontal cylindrical tunnels is given. This problem is basic to an understanding of the minimum size and disposition of targets which can be observed on a space section. The square array has been used in this example because of its good resolution properties in general prospecting rather than its particular suitability for the targets investigated. The directional response of the array is also illustrated and discussed.
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    Notes: The “Autorité des amenegements des valées des Voltas (AVV)” is establishing new rural settlements in the Volta valleys. First, a survey of available water supplies is performed. Economic aquifers in Precambrian terrains are deep (15–50 m) and usually occur in fractured zones accompanying faults. Such zones can be identified on aerial photographs, but their precise location on the ground is virtually impossible by visual means. Because of the small size of the aquifers, a location error of 5 m can make the difference between a productive well and a dry hole.Traditionally, resistivity profiling has been used as the means of locating the fractured zones in the field. Our studies suggest that the task can be performed faster, cheaper and more accurately by VLF and EM methods. Because of the limited choice of transmitting stations reccivable in Upper Volta, the VLF method is not sufficiently sensitive to detect conductors with a strike between 45° and 105°. The results obtained with a multifrequency, horizontal-loop EM (HLEM) system were satisfactory in all investigated areas. During the 1980 field season, 35 target areas were surveyed. Of the 24 holes drilled so far, 23 are productive.The weathered layer is a source of distinctive HLEM anomalies, which are characteristic of the underlying rocks. Therefore, different interpretational procedures had to be developed for granitic and volcano-sedimentary areas. Despite the high background level of in-phase and quadrature components, which varied with thickness and conductivity of the weathered layer, aquifers could be detected at a depth greater than 30 m. Attempts were made to interpret the HLEM results quantitatively using two models: a three-layer medium and a valley discontinuity. The latter model is more realistic, but more scale modelling will have to be performed to permit development of viable interpretational procedures. Meanwhile, phasor diagrams based on drilling and resistivity sounding data can be used to estimate the aquifer depth.
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    Notes: A type of iterative deconvolution that extracts the source waveform and reflectivity from a seismogram through the use of zero memory, non-linear estimators of reflection coefficient amplitnde is developed. Here, we present a theory for iterative deconvolution that is based upon the specification of a stochastic model describing reflectivity. The resulting parametric algorithm deconvolves the seismogram by forcing a filtered version of the seismogram to resemble an estimated reflection coefficient sequence. This latter time series is itself obtained from the filtered seismogram, and so a degree of iteration is required. Algorithms utilizing zero memory non-linearities (ZNLs) converge to a family of processes, which we call Bussgang, of which any colored Gaussian process and any independent process are members. The direction of convergence is controlled by the choice of ZNL used in the algorithm. Synthetic and real data show that, generally, five to ten iterations are required for acceptable deconvolutions.
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    Notes: The magnetic anomaly due to a uniformly magnetized vertical rectangular prism and that due to an arbitrary structure which can be divided into a number of such prisms are expressed in forms suitable for rapid computation. Both two-dimensional and three-dimensional cases are considered. The simplified expressions will find use in interpretation techniques where repeated computations have to be made of the anomaly due to prisms as in automated fitting of prism anomalies to observed magnetic anomalies using non-linear optimization techniques or related methods.
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    Notes: The determination of the nature of reservoirs containing hydrocarbons is approached via a pattern-recognition method with prior learning. This method consists of comparing the nature of a reservoir that has been drilled into with an unknown reservoir. The known reservoir plays the part of a monitor for the learning process. To this end an algorithm is compiled using the Burg method of the features represented by different portions of traces contained in the reservoirs. An analysis of the dots representing these different features serves as a criterion for deciding whether the two reservoirs have identical or different natures.
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    Notes: In this paper we design a non-linear filter to suppress surface multiples in a non-normal incidence plane wave seismogram of a horizontally-layered elastic (or acoustic) earth model. Our filter is optimal in a least-squares sense and is very efficient in suppressing surface multiples, especially for small incidence angles. The design is based on an extension of earlier work by Mendel on normal incidence Bremmer series decomposition to the case of non-normal incidence, and relies heavily on work by Aminzadeh on a non-normal incidence state space model.
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    Notes: The radiation distribution of a single vibrator can be described using the formulas given by Miller and Pursey. From these the displacement characteristic for the radial component and also for horizontal component can be derived. This horizontal component is strengthened by adding another vibrator with opposite polarity near the first one. When this horizontal component is oriented perpendicular to the X-Z plane (plane spanned by the direction of the spread and the vertical axes), an SH-wave can be generated. Survey results indicate that this method works efficiently.
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    Notes: High-frequency electromagnetic probing is used to monitor the rate and direction of flow of fluids injected into the ground. This method shows the potential for providing more detailed information than procedures presently used. The experimental technique and the test-of-concept experimental results are discussed. This technique has applications in oil-reservoir engineering and in hydrology studies concerning storage of chemical wastes.
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    Notes: Vertical velocity gradients can be readily accommodated in seismic refraction interpretations by using simple mathematical idealizations of curved raypaths entailed by certain analytic representations of these gradients. Computation procedures are formulated for velocity gradients in the overburden or an intermediate layer of a multilayer section. The former is demonstrated for an overburden velocity gradient manifest in published time-distance data.
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    Notes: A laboratory instrument was developed to investigate the electrical properties of rock samples with respect to changes of frequency, temperature and pressure. The instrument can be used to obtain general trends and typical values for geological media. It should be of particular interest in geothermal studies and research in the geophysical properties of rocks.The design intervals for quantities under investigation were 20–300°C, 105-4 × 107 Pa and 5 × 10−4-103 Hz. Certain limitations exist on the simultaneous use of the highest values of temperature and pressure.The main features of the instrument are: analog electrical outputs recorded by an x-y recorder or observed on a scope with an attached camera (according to the frequency range); pressures produced by an oil hydraulic system in order to ensure electrical insulation of the sample; temperatures obtained by placing the pressure vessel into a thermostatically controlled room. Thus the monitoring instrumentation is directly accessible during the experiment. Information is also given about calibration procedures and examples of rock sample data are given.
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    Notes: Optimum multichannel filters can be designed to process seismic events falling on hyperbolic moveout curves using the conventional least-squares method. Contrary to the linear moveout filters, autocorrelation and crosscorrelation functions inherent in the normal equations have to be computed numerically. However, computation times of filter coefficients are comparable to linear moveout operators.For a given source-receiver geometry and assuming straight ray-path, relative moveout of a seismic reflection event is dependent on the two way arrival time and rms velocity. Consequently, to avoid overlapping of pass and reject moveout windows, hyperbolic moveout filters have to be designed over time gates rather than for the whole record lengths. Hyperbolic and hyperbolic-linear moveout filters applied to synthetic and field seismic reflection traces show good signal-to-noise (S/N) ratio improvements. Results of some combined synthetic and field data examples are presented.
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    Notes: A simple theory is presented to derive explicit recursive migration schemes in three dimensions which are suitable for situations with lateral velocity variations. The proposed schemes can be realized by one-dimensional convolutions along the x-axis and y-axis. An investigation is made on the errors of each scheme. For each frequency component the amplitude error and the phase error are computed as a function of the immergence angle (dip). Based on the error analysis a critical discussion is given on the stability of explicit schemes.
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    Notes: Due to non-linear effects, the swept frequency signals (sweeps) transmitted into the subsurface by vibrators are contaminated by harmonics. Upon correlation of the recorded seismograms, these harmonics lead to noise trains which are particularly disturbing in the case of down-sweeps. The method described in this paper—which can be regarded as a generalization of Sorkin's approach to the suppression of even order harmonics—allows elimination, from the final vibratory source seismogram, of harmonics of the sweep up to any desired order. It requires that not one single signal but rather a series of M signals is employed where each signal has an initial phase differing from that of the previous one of the series by the phase angle 2πM. Prior to stacking, the seismograms generated with the different signals have to be brought into the form they would have if they had been generated with the same signal.The method seems also to be capable of reducing the correlation noise if sign-bit recording techniques are used.
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    Notes: Six thousand three hundred IP measurements made in central and southern Germany have been statistically evaluated. Shapes of IP decay curves obtained in the course of routine prospecting for sulfides were characterized in the following way: three chargeabilities were recorded during the 2 s current-off time. By dividing the last by the first chargeability an “IP decay coefficient’ was calculated and statistically evaluated by means of histograms. When the histograms were compared with the statistics of apparent resistivity and chargeability, no relationship could be detected. Therefore, the histograms of M3/M1 values represent a characteristic property of distinct areas with certain geological features, mineral assemblage and tectonics. Weathering does not alter this geophysical “fingerprint”, which depends solely on geology.
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    Notes: An iterative stacking algorithm (superstack) has been applied in velocity analysis as a velocity filter prior to the coherency measurements. The effect of this filtering is demonstrated on both synthetic and real data using the following three methods of velocity analysis: Constant velocity stack, constant velocity gather, and velocity spectrum. The experimental results indicate that the velocity analysis can be improved by this approach.
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    Notes: A nomogram has been devised for situations, in which the source of a self-potential anomaly can be approximated by an obliquely polarized sphere or horizontal cylinder embedded in a homogeneous half space. The nomogram can be used for rapid determination of three parameters of the target: (1) depth to the centre, (2) angle between the axis of polarization and the horizontal, (3) shift of the point vertically above the centre of the body from zero potential value.The nomogram has been tested and the parameters determined for SP results obtained over ore bodies Weiss and Süleymanköy in the Ergani Copper district, Turkey. The curves computed for the estimated parameters match the field curves well.
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    Notes: The amplitude and phase response of a simple model is compared with the performance of a real vibrator working in the field. The field results show a characteristic phase response which confirms that the real drive force applied to the baseplate and its load impedance is faithfully represented by the acceleration of the reaction mass. It follows that all the parameters necessary to calculate the load impedance and the true power dissipated in the earth can be measured at the output of the vibrator. It also follows that the current method of baseplate phase compensation should be reconsidered.
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    Notes: The induction problem for an inhomogeneous two-dimensional conductor presenting a vertical contact between two media of diverse conductivities is considered. The general solution of the Helmholtz equation in the atmosphere is constructed for a simple induction mechanism. It is found that in the E-polarization case the anomalous field behavior in the boundary region and beyond differs from the generally assumed one. The conclusion of this paper is that the boundary conditions widely utilized in numerical computations have to be modified.
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    Notes: The “Laterolog 7′’and the “Microlaterolog’ have been studied theoretically for the case of a conducting halfspace containing a single overburden, using a technique based on the method of images. The results have shown these focussed arrays to be more sensitive to the lower medium (i.e., having greater depth of investigation) than unfocussed ones of the same dimensions, when the “correct’ geometric factor is used. The geometric factor of a focussed electrode array is somewhat involved, and is explained with reference to an ideal focussed array; such an array would pass a measuring current of constant intensity into a fixed geometrical shape of conducting material, irrespective of any layering or any other heterogenities that may be present, using auxiliary current sources of variable magnitude. This concept of a constant amount of current flowing in a beam of fixed geometry and current density, is the basis of focussed arrays, and it is shown that the geometric factor, used to calculate the apparent resistivity, is the one derived when considering the homogeneous case. The value of the constant measuring current, alone, is used to convert the measured potential difference into a resistance, the ratio between this value and the combined intensities of the auxiliary current sources, for the homogeneous case, being incorporated into the geometric factor.Surprisingly good agreement was found between the theoretical models and practical experiments using a focussing seabed resistivity probe which is a substantial modification of the “Microlaterolog”. Both show similar deviations from the ideal case which are explained in terms of refraction at the overburden interface. All experiments indicated that focussed arrays have a greater depth of investigation than similar unfocussed ones for a single overburden, whether it be resistive or conductive.
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    Notes: A forward solution for the reflection response of a parallel stratified lossless medium characterized by discrete reflection coefficients and unequal layer delays, for a normally incident pressure source signal, is presented. The notation, which details the reflection history of each wavelet in a response record, facilitates systematic enumeration of all terms in the reflection impulse response model, the determination of compact closed form expressions for amplitudes and delays of multiply reflected wavelets, and the aggregation of dynamic analog groups. An equal delay time constraint on layer thicknesses leads then to the reflection sequence or synthetic seismogram structure as an infinite sum of wavelets by their order of reflection.
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    Notes: It is advantageous to postulate the phenomenological equivalence of chargeability with a slight increase in resistivities rather than a similar reduction in the conductivities. Substitution of these increments in the expression for the total differential of apparent resistivity leads directly to Seigel's formula. Included also are (i) an equally simple demonstration that, for a homogeneously chargeable ground with arbitrary resistivity distribution, the apparent chargeability ma, equals the true homogeneous value m, and (ii) a direct derivation of the completely general resistivity relation〈displayedItem type="mathematics" xml:id="mu1" numbered="no"〉〈mediaResource alt="image" href="urn:x-wiley:00168025:GPR432:GPR_432_mu1"/〉where the symbols have the usual meanings.
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    Notes: One of the most troublesome problems in resistivity sounding is caused by the spurious effects of near-surface lateral resistivity variations. It has been found that the effects can be strongly reduced by measuring earth resistances at two electrode array positions such that in one position the lateral effect is a positive contribution to the total measured signal and in the other the contribution is negative. The subsequent combination of the two measurements virtually eliminates the lateral effect.The same technique can also result in a significant reduction in the total number of necessary electrode positions. Consequently the method can be used with a multicore cable system. In this way, in addition to improving the accuracy of the measured results, time and manpower are considerably reduced.Details of the method, examples and comparisons with traditional sounding techniques are given.
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    Notes: An analysis of amplitudes of refraction records of some shallow refraction profiles shot primarily for detailing the near-surface structure in a granitic terrain has yielded information on refractor properties: reduced amplitudes are plotted on amplitude-distance graphs. The negative power n to which distance should be raised to represent (elastic) amplitude decay with respect to distance due to spreading of the critically refracted wave involved is examined. Computed values of this “spreading index”n are close to n = 2 as predicted by the theory.With this value of n, amplitude data are processed to determine residual attenuation attributable to elastic absorption in the bedrock. A graphical approach for this purpose from comparison of amplitude-distance graphs with the plots of amplitude decay due to spreading which is applicable to flat and horizontal refractor situations is suggested. Assuming residual attenuation to represent absorption in the granite bedrock, the computed coefficients of absorption, which vary from 0.5 to 3.90 km−1 for a frequency of 50 Hz, are obtained.From amplitude graphs of reversed profiles it is shown that the amplitude differences plot bears a relation to lateral velocity changes in the refractor. From comparison of practical amplitude decay graphs with those computed for different subsurface models, it appears possible to detect fractured rock occurrences in the refractor.
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    Notes: The design of a standard hydrophone with a maximally flat (Butterworth) response in the frequency range 8.0 Hz-1.0 kHz is described. The standard hydrophone has been developed primarily for calibrating line hydrophone arrays (seismic streamers) and marine seismic sources.The standard hydrophone has been used successfully during the past eight years for monitoring the output of a single air gun. It can be used for the calibration of a marine seismic streamer.
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    Notes: A method has been developed for computation of the electrical DC potential of an arbitrary three-dimensional resistivity structure using a finite difference method. The threedimensionality is necessary for interpretation of geoelectrical soundings with controlled point sources over a laterally inhomogeneous medium. Lateral inhomogeneities should be considered in resistivity soundings with large layouts. The results obtained with the described method permit a more realistic representation of geological features.The resolution of the method is determined by the number of elements in the resistivity network. The problem of core memory space has been resolved by using random access disc files. The results computed using a Fortran program are in good agreement with analytically obtained solutions.
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    Notes: In discussion of the one-dimensional wave equation the Kunetz “energy relations’ are often invoked. Since the treatment often involves lengthy algebraic calculations which yield a simple result, it may be of interest to present an elementary derivation from first principles. A generalization to higher-dimensional wave equations follows readily.
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    Notes: Motivated by several papers by Indian colleagues suggesting that a single-pole array is the most favorable one for locating electrically conductive targets in the underground, detailed measurements were carried out with different electrode arrays over a well-known graphite deposit near Pfaffenreuth, Germany. The following arrays were used: (1) Wenner array; (2) single-pole array; (3) half-Wenner array; (4) half-Schlumberger array. Each of the arrays established the location of the main graphite deposit. The half-Schlumberger array turned out to be the most reliable one since it showed details which were only very poorly indicated by the other arrays or not at all.Mathematical modeling of three-dimensional bodies simulating the geological situation for this deposit were carried out. These results show an unexpectedly good correlation with the measured effects.
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    Notes: Waves propagating through a sequence of layers that are thin compared with the wavelength show effects of anisotropy: velocity and displacement direction depend on the angle between the plane of layering and the wave normal, and shear waves split up into two distinct types of different velocity. The layered medium can thus be replaced by a transversely isotrophic medium the parameters of which depend on the parameters of the individual constituent layers.A survey of the anisotropy effects possible in such a medium is generally done by varying the layer parameters in order to obtain different replacement media. This approach guarantees that the replacement medium is realistic, but it does not guarantee adequate sampling of the set of replacement media. To this end one has to begin by selecting the replacement media and then check whether the chosen media possess stable (and eventually realistic) representations by layer sequences. In general, there is an infinite number of layer representations for any transversely isotropic medium that can at all be represented. However, if one restricts the solutions to those requiring the minimal number of layers and the minimum number of different layer parameters, the set of solutions has only one free parameter (i.e., it is a one-dimensional manifold), and an important subset even has a unique solution. A simple algorithm exists for the determination of these “simplest representations”.Aside from sampling the set of representable transversely isotropic media for survey purposes, the method can be applied to the problem of determining the cause of observed anisotropy effects (or lateral changes in such effects). If this method can be applied to real data, it would for instance allow to determine changes in relative thickness or lithology on a scale smaller than the limit of resolution of the seismic method.
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    Notes: A three-dimensional marine seismic survey was conducted in the Gulf of Thailand to aid in the development of a gas field indicated by three wildcat wells. The results and interpretation reported previously demonstrated improved fault resolution and better structural definition.Five successful appraisal wells have now been drilled, and these show that most of the sands have limited extent. Widespread character changes in the seismic data also support stratigraphic variations in many of the sands.Several new methods of 3D stratigraphic interpretation have been developed while investigating the depositional history of this area. Anomalous seismic amplitudes, tied to sands penetrated by wells and mapped from SeiscropTM horizontal sections in time and depth, have indicated the distribution of bars and channels. Horizon Seiscrop sections, each sliced through a single bed, have been used to delineate these depositional features directly. G-LOGTM sections, displaying seismic logs derived by rigorous wave equation inversion, confirm the existence of these features. Sands greater than 10 m thick have proved mappable.
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    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences , Physics
    Notes: The gravity anomaly caused by a deviation of a density interface that is of constant profile but finite extension (a so-called 2 1/2-dimensional structure) can be expressed in polynomial form that can be inverted. Numerical experiments with synthetic structures show the viability of this inversion method.
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    Topics: Geosciences , Physics
    Notes: The electromagnetic response of anticline fold models in a uniform field has been studied using scale-modeling. With the increasing conductance the in-phase anomaly increases initially but then starts to decrease and finally attains a negative saturations, whilst the quadrature anomaly reaches a positive saturation. E.M. response of folds is similar to that of an interaction between two weakly coupled circuits in a dipolar field. The base of the fold is one of the characteristic parameters to determine the measured response.
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    Geophysical prospecting 29 (1981), S. 0 
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    Topics: Geosciences , Physics
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    Geophysical prospecting 29 (1981), S. 0 
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    Topics: Geosciences , Physics
    Notes: Two dimensional inverse modeling, a process to be applied after standard processing and interpretation, uses interfaces picked by the user. These interfaces are transformed into an approximate subsurface model.The subsurface model is represented by curved interfaces and interval velocities. The interfaces have to be unique functions of the line coordinate. Otherwise they may be arbitrarily curved and may begin or terminate anywhere along the section, e.g., at faults, pinchouts, salt domes and the like. Interval velocities may vary laterally along the section. The inverse modeling algorithm then modifies the model until traveltimes calculated from this model match the traveltimes observed as closely as possible in a least squares sense.The traveltimes corresponding to the model are obtained through ray tracing taking exact account of refraction. The traveltimes observed are the arrival times of single impulses before stacking contributing to the interfaces. These traveltimes are provided by ANAKON, a continuous interface analysis system.The comparison of INMOD results with those of well measurements and those of classical interval velocity computation from seismic data shows the accuracy of the method. Deviations of INMOD derived interface depths are within 2% of well data.
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    Geophysical prospecting 29 (1981), S. 0 
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    Topics: Geosciences , Physics
    Notes: For years, reflection coefficients have been the main aim of traditional deconvolution methods for their significant informational content.A method to estimate seismic reflection coefficients has been derived by searching for their amplitude and their time positions without any other limitating assumption. The input data have to satisfy certain quality constraints like amplitude and almost zero phase noise—ghosts, reverberations, long period multiples, and diffracted waves should be rejected by traditional processing. The proposed algorithm minimizes a functional of the difference between the spectra of trace and reflectivity in the frequency domain. The estimation of reflection coefficients together with the consistent “wavelet’ is reached iteratively with a multidimensional Newton-Raphson technique. The residual error trace shows the behavior of the process. Several advantages are then obtainable from these reflection coefficients, like conversion to interval velocities with an optimum calibration either to the well logs or to the velocity analysis curves. The procedure can be applied for detailed stratigraphic interpretations or to improve the resolution of a conventional velocity analysis.
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    Geophysical prospecting 29 (1981), S. 0 
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    Topics: Geosciences , Physics
    Notes: This tutorial paper presents a time-domain derivation of the Normal equations which are associated with the normal-incidence inverse problem. Connections are made between our time-domain derivation and the more familiar z-transform transfer function derivation.
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  • 69
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    Journal of the American Ceramic Society 80 (1997), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: We have studied the atomistic structure of a σ3 (111) grain boundary in strontium titanate by high-resolution transmission electron microscopy (HRTEM). Quantitative evaluation of HRTEM images reveals that shear stresses, which may originate from processing or external loading, have an important effect on the translation state of the two adjacent grains and on the ion positions at the grain boundary. While under low shear stress the boundary exhibits mirror symmetry with respect to the boundary plane and a comparatively large free volume, high shear stress transforms the structure to a “lock-in” configuration, which has no mirror symmetry and a smaller excess volume. These results suggest that internal or external stresses may significantly alter the charge transport properties of SrTiO3.
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    Journal of the American Ceramic Society 80 (1997), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The hardness of opposite basal faces of 4H-SiC single crystals has been measured in the temperature range 25°-1200°3C. A strong hardness anisotropy between the silicon-terminated (0001) and carbon-terminated (0001) faces of this polar crystal has been found. Transmission electron microscopy investigation of the dislocations in the plastic zone of the 1200°3C indentations shows that they lie predominantly on the basal planes parallel to the indented face, and the extra-half planes of the nonscrew dislocations originate from the indented face. It is also found that, when the (0001) Si-terminated face is indented, the dislocations are either widely dissociated, with the width of the stacking fault ribbon much larger than the equilibrium value, or else they are single leading partials, with the corresponding trailing partials absent. In this case, all the leading partials are found to have a silicon core. On the other hand, the dislocations in the plastic zone of the carbon-terminated face are in the form of dissociated dislocations, with the width of the associated stacking fault ribbons appreciably less than the equilibrium value. Moreover, the leading partials of éhese dissociated dislocations have a carbon core. The results indicate that the hardness of the polar basal faces of 4H-SiC at elevated temperatures is partly determined by the nature of the dislocation cores nucleated by the indentation process. It is argued that this is due to the influence of the core on the generation and glide of the leading partial dislocations.
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  • 71
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    Journal of the American Ceramic Society 80 (1997), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Using the technique of fluorescence piezospectroscopy, we determine the distribution of thermal residual stresses across the edges of three laminated alumina/zirconia composites. We develop a methodology for separating the measured stress state into microstresses that result from grain-to-grain thermal mismatch and macrostresses that result from lamination-induced thermal mismatch between individual plies. Comparison between the measured edge-stress distributions and those calculated based on a simple force-superposition model shows good agreement, indicating that the laminate system is well approximated as linear elastic. Given the experimental confirmation of significant edge stresses in multi-ply laminates, the possibility of failure initiating at composite edges must be considered in the design of surface-compressed laminate structures with the aim of mediating the detrimental effect of surface flaws.
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  • 72
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    Journal of the American Ceramic Society 80 (1997), S. 0 
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    Notes: Local laser-induced oxidation of thin titanium films on glass is shown to be self-limiting due to a decrease in the absorptivity during the reaction. Taking advantage of this confinement, stable writing of transparent oxide line structures narrower than the diffraction-limited focused spot of a continuous wave Ar ion laser (500 nm) has been accomplished. The greatest optical contrast (1:10) with the highest resolution down to 165 nm was observed if the film thickness is of the order of the light absorption length in the metal.
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  • 73
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    Journal of the American Ceramic Society 80 (1997), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Multilayered composites consisting of LaPO4 (La-monazite) layers alternating with various ZrO2-based materials were fabricated to investigate whether LaPO4 provides a weakly bonded interface suitable for promoting toughening, as previously observed in the system LaPO4/Al2O3. The following ZrO2-based materials were assessed: Y-ZrO2, Y-ZrO2/Al2O3, Ce-ZrO2, and Ce-ZrO2/Al2O3. Debonding was observed in all cases. The composites containing Y-ZrO2 and Y-ZrO2/Al2O3 were stable, with no reactions, at temperatures up to at least 1600°3C. However, in the composites containing Ce-ZrO2, interdiffusion of Ce and La occurred, resulting in formation of a pyrochlore-like phase and, in the case of the Ce-ZrO2/Al2O3 composite, a (Ce,La)Al11O18 magnetoplumbite phase.
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  • 74
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    Journal of the American Ceramic Society 80 (1997), S. 0 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Copper/niobium multilayers prepared by sputtering onto Si substrates with layer thicknesses ranging from 11 to 5000 Å have been characterized by transmission electron microscopy and nanoindentation. The films are strongly textured with {110} close-packed planes of the bcc Nb parallel to the {111} close-packed planes of the fcc Cu and close-packed directions tending to be parallel as well. For the 11 Å layers, the Cu is found to grow pseudomorphically on Nb in the bcc structure. It is thought that, for thicker layers, the bcc Cu loses coherency and transforms martensitically to the fcc phase, thus resulting in the observed Kurdjumov—Sachs orientation relationship. As the layer thickness, d, decreases from 5000 to 500 Å, the hardness increases as d-1/2; i.e., it follows a Hall—Petch relationship so that hardening is due to grain boundaries and interfaces. The slope is the same as in pure Cu, but there is a large intercept which is ascribed to internal stresses and a large dislocation density. As the layer thickness decreases from 100 to 11 Å, the hardness increases as (1/d) ln (0.69d), which is a line tension formulation such as would be expected for Orowan dislocation bowing between the layers. Again there is a large intercept which is ascribed to cutting through the Cu/Nb interfaces. The interfacial energy is calculated to be 0.46 J/m2.
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  • 75
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    Journal of the American Ceramic Society 80 (1997), S. 0 
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    Notes: Aqueous Zr-nitrate solutions containing appropriate amounts of Fe(NO3)3·6H2O and Al(NO3)3·6H2O were used to synthesize ZrO2-Fe2O3 compositions (up to 40 mol% Fe2O3) and one ZrO2-Al2O3-Fe2O3 composition. An amorphous phase was produced after pyrolysis, which subsequently crystallized to a single-phase Zr(Fe)O2 solid solution (or Zr(Fe,Al)O2 ss) that appeared cubic by X-ray diffraction, but tetragonal (c/a→ 1) by electron diffraction. The crystallization temperature increased with Fe2O3 content. At higher temperatures, the single phase partitioned to two phases, tetragonal-ZrO2+γ-Fe2O3. The γ- to α-Fe2O3 transformation occurred at still higher temperatures to produce a two-phase microstructure composed of two interpenetrating phases (ZrO2+α-Fe2O3), each with equiaxed grains. This microstructure was relatively stable to grain coarsening, even to temperatures just below the apparent eutectic temperature. With the exception of the lower transition temperatures and the equiaxed grains observed for both phases, these observations are similar to that previously reported for the ZrO2-Al2O3 system. The microstructure development reported here is another example for the synthesis via solution processing that involves diffusion-limited crystallization. Namely, a two-phase material can be produced where the grain size of each can be very small, and can be prevented from growing rapidly at high temperatures due to the constraint of each phase on one another.
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  • 76
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    Notes: High-temperature creep behavior of yttria fully stabilized zirconia single crystals with various yttria contents in the interval 9.4 ≤x≤ 21 mol% has been studied. The mechanical data have been collected as a function of both the temperature and the yttria concentration. The creep behavior has been explained in terms of a transition between a dislocation viscous glide and a dislocation climb controlled mechanism, making use of a generalized version of a classical model for alloys proposed by Burton. The yttria concentration dependence of the creep rate has been connected with results on cationic diffusivity, with a possible influence of impurities.
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    Notes: The examination of natural materials at the microscopic and microchemical level from a materials science perspective can occasionally suggest advances in modern materials engineering. The present paper reports on such a case: an analytical study of the detailed structure and composition of sea urchin teeth.
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    Notes: Compression tests of single crystals are analyzed with respect to shear due to the friction at the loaded ends. This simple approach permits an explanation of the features associated with prism plane slip in sapphire (α-Al2O3), i.e., the shape changes of the specimens and the curvature of the glide planes.
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    Notes: The microstructure of polydomain tetragonal zirconia (t-ZrO2), i.e., a ZrO2 modification exhibiting ferroelastic behavior, is studied by high-voltage electron microscopy. This material consists of three domain variants of the tetragonal phase with their c-axes nearly orthogonal to each other. Always two variants of these platelike domains are alternately arranged, forming elongated regular colonies. Hence, in both variants the common habit plane of the domains is a {110} twin plane. The colonies are of columnar shape with a longitudinal axis. They are bound by {110} planes, too, which are twin planes for the domains in the contiguous colonies. Owing to their particular structure and the helical arrangement of the adjoining colonies, the material remains coherent and pseudocubic over large macroscopic regions, although it is formed by different tetragonal domains.
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    Notes: The ferroelastic deformation of t-ZrO2, the microstructure of which was described in detail in Part I, was investigated by in situ deformation experiments in the high-voltage electron microscope at 1150°3C. During the experiments those two domain variants with their c-axes perpendicular to the [010] tensile direction were transformed into the third one with its c-axis parallel to the tensile direction. The subsequent ‘switching’ of the domains inside the colonies proceeds much faster than the penetration of the transformation front into a neighboring colony. Therefore, the transformed region, exhibiting a unique tetragonal structure and containing residual defects, preferentially expands into the longitudinal directions of the colonies. The transformation of single domains proceeds instantaneously within the time resolution of the video tape recording.
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    Notes: The effect of particle solubility and the dissolution rate on agglomeration was studied by drying silica and titania particles from aqueous slurries with pH values in the range of 2–12. The agglomerate strength and strength distribution were measured by a calibrated ultrasonic force, and the strength increased as the solubility and dissolution rate increased. Two silica powders of different particle size (60 nm and 500 nm) were studied, and smaller-sized particles formed stronger agglomerates. The drying rate of the powders was varied by using spray drying and tray drying, and slower drying was shown to lead to higher agglomerate strength. The agglomerate strength of titania powder (insoluble in water) was independent of pH, whereas the agglomerate strength of silica was dependent on pH. It was concluded that the solubility and dissolution rate are important parameters that govern the strength of agglomerates.
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    Notes: The formation kinetics of products formed by the reaction between dense molybdenum and vapor-supplied silicon at an activity approximating that of solid silicon under open flowing gas conditions was studied at 1200°3C. An outer MoSi2 layer overlaid the much thinner Mo5Si3 that formed on the molybdenum. Both phases obeyed parabolic growth laws over a 22 h period, having parabolic rate constants of 6.8 times 10-10 cm2/s for the MoSi2 and 1.3 times 10-13 cm2/s for the Mo5Si3 phases. These results were ∼2 orders of magnitude less than prior results, mostly obtained by another processing route. Possible explanations include enhanced growth rates from chemical contamination. Gross distortion and abnormal layer thicknesses at specimen edges and the 159% volume increase during siliciding suggest that the kinetics also are strain dependent.
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    Notes: An anomalous positive temperature coefficient of resistivity (PTCR) was investigated in the ZnO-NiO system. It was found that the ZnOSS (Zn0.97Ni0.03O) and NiOSS (Ni0.6Zn0.4O) constituent phases of that system exhibit negative temperature coefficient of resistivity (NTCR) character, while their combination shows a PTCR effect with a maximum at 400°3C, which coincides with a large difference in the coefficient of linear thermal expansion between the ZnOSS and NiOSS phases at that temperature. On the basis of the brick wall model microstructure, the PTCR anomaly of this system can be explained. The magnitude of the PTCR effect is governed by the difference in resistivity of the two constituent phases at the temperature where the maximum of the PTCR anomaly occurs. The predicted temperature dependence of the resistance, R(T), of a model microstructure consisting of constituent phases with different grain sizes agrees well with the experimental R(T) of the prepared composite ceramics.
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    Notes: Small substitutions of BaZrO3 into Ba[(Zn,Ni)1/3Ta2/3]O3 are utilized in the commercial preparation of low-loss perovskite microwave dielectrics. The structures of a series of these phases with substitution levels ranging from 1% to 5% BaZrO3 were examined using high-resolution TEM. For ≤ 2.15% BaZrO3 the solid solutions retain the ordered “1:2” structure of the Ba[(Zn,Ni)1/3Ta2/3]O3 end-member but are comprised of small ordered domains whose size decreases as the Zr content is raised. The decrease in the size of the domains parallels a decrease in the processing time required to access a low-loss state. Although for pure Ba[(Zn,Ni)1/3Ta2/3]O3 reductions in the degree of cation order produce a large increase in the dielectric loss, the Zr-substituted ceramics retain a very low loss. We believe the low losses of the 1:2 ceramics are derived from the stabilization of the ordering-induced domain boundaries via the partial segregation of the Zr cations. For substitutions between 3% and 5% BaZrO3 the size of the ordered domains continues to decrease but the system undergoes an abrupt transformation to a cubic “1:1” ordered structure with a doubled perovskite repeat. The structures of these phases have been interpreted using a “random layer” model in which one site is occupied by Ta and the other by a random distribution of Zn, Zr, and the remaining Ta cations, i.e., Ba{[Zn(2-y)/3Ta(1–2y)/3Zry]1/2[Ta1/2]}O3. Although the ordering is confined to nano-sized domains, these ceramics also exhibit low losses, again reflecting the relative stability of the domain boundaries. In this case we believe the low losses reflect the effectiveness of the random layer in stabilizing the anti-phase boundaries.
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    Notes: The isothermal oxidation of HfC single crystals with (100) orientation was carried out using an electromicrobalance at temperatures of 600° to 900°3C at an oxygen pressure of 2 to 8 kPa. Nonisothermal oxidation was performed by a simultaneous thermogravimetry—differential thermal analysis—mass spectrometry analysis. A polished cross section of the oxidized crystal was observed by backscattered electron imaging in a scanning electron microscope. Quantitative chemical analysis for Hf, O, and C and their elemental profiles in the HfC and oxide scale was carried out by wavelength dispersive X-ray microanalysis. It was found that the oxide scale consists of two regions, zones 1 and 2, both of which showed the existence of carbon. The carbon content at the middle point of zone 1 was about twice that in zone 2, which contained 7 to 14 at.% carbon. Zone 1 showed an almost compact and pore-free phase; its thickness remained constant (1 to 2 μm) after a prolonged time. The thickness of zone 2 increased linearly with time. The oxidation mechanism including interfacial reaction responsible for the deposition of carbon is discussed.
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    Notes: Basic principles of fabricating tile glazes based on cordieritic glass-ceramics are explained. Glass compositions from the MgO-Al2O3-SiO2 three-component phase diagram have been melted with and without the nucleating agent TiO2. Additionally, a sodium borosilicate glass that is commonly used in the tile glaze industry has been wet milled, together with the previous compositions, to produce a coating slip. Studies are focused on the role of the nucleating agent and glassy formulation in the crystallization of the glass-ceramic system using differential thermal analysis, X-ray diffractometry, and scanning electron microscopy. When added to a borosilicate glass, only one composition is capable of crystallizing cordierite under a fast-firing cycle used for “monoporosa” production. The porosity of the glaze layer is sufficiently low and the crystal size is small to ensure good mechanical and chemical properties. The presence of cordierite crystals in the glaze should enhance abrasion and acid resistance, in comparison to a traditional matte glaze that contains mostly enstatite or diopside crystals.
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    Notes: Transparent and highly oriented Ba2NaNb5O15 (BNN) thin films have been prepared by using metal alkoxides. A homogeneous precursor solution was prepared by the controlled reaction of NaOC2H5, Nb(OC2H5)5, and barium metal. The BNN precursor included a molecular-level mixture of NaNb(OC2H5)6 and Ba[Nb(OC2H5)6]2 in ethanol. The alkoxy-derived powder crystallized to a low-temperature phase, and then transformed to orthorhombic BNN (tungsten bronze) at 600°3C. BNN precursor films on substrates crystallized to orthorhombic BNN at 800°3C via the low-temperature phase. Highly (002) oriented BNN films of tungsten bronze structure were successfully prepared on MgO (100) substrates at 700°3C by using BNN underlayer.
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    Notes: An aqueous-based system (Si-Al2O3-Y2O3-Fe2O3) for processing sintered reaction-bonded silicon nitride (SRBSN) was investigated with an emphasis on chemical control of suspension component interactions. Chemical stability and dispersion properties of a commercial silicon powder were characterized using electroacoustic, adsorption isotherm, and rheological measurements. The interactions of silicon with nitriding agent, sintering aids, dispersants, and binder were considered. The effects of pH, electrolyte, aging, particle size, and solids loading were examined. The suspension properties of the silicon powder were influenced by the native oxide film and powder treatment history. The silicon—oxide composite particles exhibit dispersion behavior similar to silica, characterized by a negative surface potential above pH 2. A method to improve the dispersion and homogeneity of suspension components based on the use of quaternary amine dispersants is proposed.
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    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The kinetics of grain growth and Ostwald ripening in Al2O3-ZrO2 two-phase composites was systematically investigated using two-dimensional (2-D) computer simulations, based on a diffuse-interface field model. Using average values for the experimentally measured ratios of the grain boundary energies to the interphase boundary energy as the input, the predicted 2-D microstructural features and their evolution are in excellent qualitative agreement with experimental observations on 2-D cross sections of 3-D Al2O3-ZrO2 two-phase composite microstructures. It was found that the coupled grain growth in Al2O3-ZrO2 composites is controlled by long-range diffusion and the average size (Rt) as a function of time (t) follows the power-growth law, Rmt - Rm0=kt with m= 3, which is independent of the initial microstructures and volume fractions of the two phases. The predicted variation of the kinetic coefficient (k) on the volume fraction follows a trend similar to that experimentally measured through the entire range of volume fractions. The scaling of grain size distributions is observed at a given volume fraction, i.e., they are time-invariant in the steady state. However, the characteristics of size distributions vary with the initial microstructures and the volume fractions. The relationship between matrix grain size and second-phase grain size is discussed.
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  • 90
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    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: It was observed that slurries of oxide powders in oxidized polybutene fluids can be caused to change reversibly between fluid, nearly Newtonian behavior and plastic behavior by modest changes in temperature. This phenomenon was believed to result from changes in the dispersion vs association among the particles. The rheological effects of temperature, polymer oxidation, and particle size were observed for 30 vol% slurries of TiO2, Al2O3, and ZrO2 powders in polybutene fluids. Elasticity (in oscillation) and low-shear-rate viscosity (in steady shear) were observed to increase with increasing temperature for TiO2 and Al2O3 particles in oxidized polybutene fluids. This behavior was attributed to the creation of interparticle structures. The attainment of this structure on heating was observed to be inhibited by increased oxidation of the polymer and increased particle size. It was concluded that the adsorption of oxidized molecules from the polymer liquid, along with the high viscosity of the bulk polymer, resulted in suspensions that were metastable against coagulation. Increased temperature resulted in lower viscosities of the liquid, allowing coagulation on a short time scale. The presence of the adsorbed polymer, however, prevented intimate contact among the particles so that the coagulated structure was easily destroyed upon subsequent cooling and shearing.
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  • 91
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Minimum infiltration times during isothermal chemical vapor infiltration were calculated for the formation of a silicon carbide matrix composite from methyltrichlorosilane (MTS). Several different reaction models were used to describe the SiC deposition kinetics. The results show that the nature of the reaction model has a significant effect on process optimization considerations. It is clear that a simple first-order deposition reaction does not accurately describe the infiltration process, while rate expressions that treat the effect of chlorine-containing byproduct gases provide much more accurate predictions. In theory, much shorter infiltration times can be obtained with precursor chemistries that do not produce Cl-containing gases. The results also provide guidelines for minimizing infiltration times with MTS.
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  • 92
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Cracking parallel to the fibers in off-axis plies is usually the initial form of damage in composite laminates. This cracking process has been associated with the (transverse) fracture toughness, defined by the critical strain energy release rate, GIc. The measurement of GIc provides basic information about the transverse crack resistance. In this study, the utility of the double torsion (DT) test technique to determine GIc in a glass-ceramic matrix composite (Nicalon/CAS-II) at temperatures up to 1000°3C has been demonstrated. GIc did decrease moderately with increasing temperature (as does the bulk matrix); however, no evidence of an interphase oxidizing effect on crack growth (parallel to the fibers) could be found. The inevitable misalignment of fibers in the material was not very efficient at bridging the crack in the DT specimens, in contrast to the significant matrix crack interactions with the fibers reported for other geometries such as double cantilever beam and flexure specimens.
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  • 93
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: NiAl2O4 spinel—mullite composites were prepared by simultaneous replacement of Al by Ti and/or Ni in 3:2 stoichiometric mullite. Specimens having nominal compositions 3(Al2-2xNixTixO3) · 2SiO2 (x= 0, 0.025, 0.05, 0.2) and 3(Al2-xMxO3) · 2SiO2 (M = Ni2+ or Ti4+ and x= 0.05) were synthesized by sol—gel techniques, which provide homogeneous gels in the SiO2-Al2O3 system. Gel structures investigated by infrared (IR) spectroscopy revealed the formation of Al-O-Si bonds in dried gels. The reaction sequence of gel-derived glasses, previously obtained by preheating gels at 750°3C for 3 h, was evaluated by X-ray powder diffraction (XRD) and ultraviolet—visible (UV—vis) spectroscopy. All samples crystallized at around 1000°3C from an amorphous state, but unexpectedly the first crystalline phase was Al-Si spinel in all aluminum-substituted specimens; i.e., a change in the sequence of reaction with respect to the 3:2 stoichiometric mullite was produced. NiAl2O4 spinel was almost simultaneously detected. Two processes of mullite crystallization were observed. The temperature of formation of mullite was the lowest for the higher substituted sample. The microstructure of the final NiAl2O4 spinel—mullite composites found in all Ni-containing samples after annealing for 96 h was examined by scanning electron microscopy with energy dispersive X-ray analysis (SEM/EDX), which revealed the presence of small particles of NiAl2O4 spinel dispersed in a mullite matrix. For annealed compositions with the larger Al replacement, i.e., when x= 0.2, a small amount of very small Al2TiO5 particles was also detected by XRD and transmission electron microscopy (TEM).
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  • 94
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The reactions of stoichiometric Y2O3, CuO, and different barium salts (BaCO3, Ba(NO3)2, BaO2, BaCuO2) for forming various compounds in the yttrium—barium—copper—oxygen system (i.e., YBa2Cu3O7–8, BaCuO2, Y2BaCuO5, and Y2Cu2O5) were systematically investigated by thermal analysis and X-ray diffractometry. In a few cases, the relevant activation energies were calculated. The reaction pathway and kinetics were significantly dependent on the physicochemical and thermal stability of the barium precursors, as well as on the crystalline size of the reagent. Binary BaO-CuO phases formed at low temperature (650°-700°3C) when in the presence of easy-to-decompose barium precursors, and then slowly transformed to ternary compounds; in contrast, when barium ions were released at temperatures of 〉900°3C, ternary phases formed directly from the components.
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  • 95
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A ceramic matrix for carbon-fiber-reinforced ceramic-matrix composites (CMCs) has been developed from poly-siloxane/boron mixtures. Complex geometries can be realized by using standard technologies of fiber-reinforced polymer composites. On pyrolysis, the polymer—filler mixture is converted to a ceramic matrix, consisting of silicon carbide, boron carbide, boron nitride, and a silicon oxycarbide (SiOC) glass, without reacting with the carbon fiber. Because of the large volume increase of the boron filler on nitridation (142 vol%), no multiple reinfiltration of the structure is necessary to achieve a dense matrix. Tensile strength and interlaminar shear strength exhibit maxima at a pyrolysis temperature of 1300°3C, where extensive fiber pullout is observed. Thermodynamic calculations have been used to evaluate the theoretical qualitative and quantitative phase compositions at equilibrium. Thermoanalytical (thermogravimetry—mass spectroscopy) and structural analysis (X-ray diffractometry) have shown a satisfying coherence with respect to the condensed phases, whereas deviations have been noted with respect to the composition of the gas phase.
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  • 96
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Carbohydrates are often key components in the formulation of extrusion pastes, yet the reasons for selection are presently empirical. The influence on paste extrusion of various types of carbohydrates, such as starch, dextrin, lactose, and glucose, have been studied and related to their water retention capacities. The bulk yield stress and the surface shear stress both decrease as the moisture content increases; however, the way in which the water that is present interacts with the carbohydrate has an important influence. The behavior of some carbohydrates can be substantially accounted for by a consideration of packing effects; however, dextrin behaves differently. The carbohydrates function not only as a binder but also as a means of retaining the liquid phase.
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  • 97
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Spherical indentation of thick and thin glass plates was investigated numerically and experimentally. The energy release rate at the tip of a cone crack was calculated by using finite element techniques and used to investigate the applicability in thick plates of Roesler's law relating the cone crack radius to the indentation load. Indentations of thin glass specimens resting on different substrates were also studied numerically and experimentally. The stresses in the thin specimens were calculated and correlated with the observed failures. On the basis of these results, a crack initiation mechanism map was developed for glass specimens on different substrates.
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  • 98
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Stereological measurements were performed to characterize the indentation crack path in a cubic zirconia—10 vol% alumina (c-ZrO2-10 vol% Al2O3) composite. Cracks were generated using Vickers indentation, and the crack propagation behavior was characterized as a function of the indentation loading/unloading rates. Cracks that were produced by Vickers indentation formed at higher crack velocities as the loading/unloading rates increased. The amount of contact between the crack and the Al2O3 particles increased as the indentation rate decreased. The total number of crack—particle interactions per unit crack length also increased as the indentation rate decreased, because of an increase in the number of particles that were fractured per unit crack length, whereas the number of particles that were debonded remained relatively constant as the indentation rate changed. These results suggest that residual thermal mismatch stresses have predominant control of the crack path at lower crack velocities (low indentation loading/unloading rate), whereas elastic mismatch stresses predominate at higher crack velocities (high indentation loading/unloading rate).
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  • 99
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The purpose of this study was to determine the chemical composition changes of hydroxyapatite (HA) coated titanium using surface analysis (X-ray photoemission) and bulk analysis (energy dispersive spectroscopy). The specimens examined were controls and specimens aged 30 min and 3 h at room temperature in distilled water and 0.2M sodium phosphate buffer (pH 7.2). Each X-ray photoemission cycle consisted of three scans followed by argon sputtering for 10 min for usually 20 cycles, corresponding to a sampling depth of ∼1500 Å. The energy dispersive spectroscopy analysis was on a 110 by 90 μm area for 500 s. The X-ray photoemission results indicated the oxidation effect of water on the titanium (as TiO2) and the effect of the buffer to increase the surface concentration of phosphorus. No differences in the chemical composition were observed by energy dispersive spectroscopy analysis.
    Type of Medium: Electronic Resource
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  • 100
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of the American Ceramic Society 80 (1997), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A novel in situ reaction between a ceria-doped zirconia interphase coating on Saphikon fibers and an outer alumina coating has resulted in the formation of oriented hexaaluminate platelets which can act as a low fracture energy interface barrier for crack deflection in oxide—oxide ceramic-matrix composites (CMCs). The reaction proceeds only in reducing environments where the reduction of the cerium and zirconium ions to their 3+ valent state causes a destabilization phenomenon consistent with previously reported findings. The diffusion of the cerium from the zirconia into solid solution with the alumina can stabilize the layered hexaaluminate structure. Preferred orientational growth of the hexaaluminate parallel to the coating interface was observed which is the required orientation for enhanced debonding at the fiber/matrix interface in long-fiber-reinforced CMCs.
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