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  • Chemistry  (13,189)
  • Analytical Chemistry and Spectroscopy  (1,712)
  • Cell & Developmental Biology  (997)
  • METEOROLOGY AND CLIMATOLOGY
  • 2015-2019  (17)
  • 2010-2014
  • 1980-1984  (14,940)
  • 2016  (17)
  • 1984  (7,883)
  • 1980  (7,057)
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  • 2015-2019  (17)
  • 2010-2014
  • 1980-1984  (14,940)
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  • 1
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    [Perspective] Molecular sieves for gas separation (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-07-08
    Description: Separation and purification are critical industrial processes for separating components of chemical mixtures, and these processes account for about half of industrial energy usage (1). Gas mixtures of compounds with very similar physical properties are particularly difficult to separate. On pages 137 and 141 of this issue, Cadiau et al. (2) and Cui et al. (3), respectively, show that microporous materials can be designed to have high adsorption capacity and selectivity for particular hydrocarbons, enabling energy-efficient separation. Author: Jerry Y. S. Lin
    Keywords: Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 2
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    [Perspective] How to break down crystalline cellulose (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-05-27
    Description: Biomass-degrading microorganisms use lytic polysaccharide monooxygenase (LPMO) enzymes to help digest cellulose, chitin, and starch. By cleaving otherwise inaccessible crystalline cellulose chains, these enzymes provide access to hydrolytic enzymes. LPMOs are of interest to biotechnology because efficient depolymerization of cellulose is a major bottleneck for the production of biologically based chemicals and fuels. On page 1098 of this issue, Kracher et al. (1) compare LPMO-reducing substrates in fungi from different taxonomic groups and lifestyles, based on both biochemical and genomic evidence. The results provide insights into reductive activation of LPMO that are important for developing more efficient industrial enzymes for lignocellulose biorefineries. Author: Angel T. Martínez
    Keywords: Chemistry
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  • 3
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    [Editors' Choice] Engineering open structures using DNA (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-03-25
    Description: Author: Marc S. Lavine
    Keywords: Chemistry
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 4
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    Quantum interference and diradicals [Chemistry] (2016)
    National Academy of Sciences
    Details
    Publication Date: 2016-01-27
    Description: An empirical observation of a relationship between a striking feature of electronic transmission through a π-system, destructive quantum interference (QI), on one hand, and the stability of diradicals on the other, leads to the proof of a general theorem that relates the two. Subject to a number of simplifying assumptions,...
    Keywords: Chemistry
    Print ISSN: 0027-8424
    Electronic ISSN: 1091-6490
    Topics: Biology , Medicine , Natural Sciences in General
    Published by National Academy of Sciences
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  • 5
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    [This Week in Science] Synthetic twists among lipids (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-04-29
    Description: Author: Jake Yeston
    Keywords: Chemistry
    Print ISSN: 0036-8075
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 6
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    [This Week in Science] Temporarily caught in a bind (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-03-18
    Description: Author: Marc S. Lavine
    Keywords: Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 7
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    [Perspective] Quantum dynamics in the smallest water droplet (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-03-18
    Description: Water plays a central role in scientific disciplines ranging from geology to astronomy to biology. Yet it is an extraordinarily dif cult liquid to understand because of its complex, ever-changing patterns of hydrogen bonds. Studies of small water clusters have provided important insights into the concerted hydrogen-bond motions that can occur in water. These studies are also crucial for developing an accurate potential function for simulating the properties of liquid water and ice (1). On page 1310 of this issue, Richardson et al. (2) provide evidence for a concerted type of motion in which two hydrogen bonds in a water cluster are broken simultaneously (see the figure). The results have implications for many areas of scientific study, including the chemistry of polar solvents, the conformations of proteins, and the dissolution of ions in minerals. Author: David C. Clary
    Keywords: Chemistry
    Print ISSN: 0036-8075
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 8
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    [Editors' Choice] Beyond blank slates in the lab notebook (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-03-18
    Description: Author: Jake Yeston
    Keywords: Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 9
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    [Perspective] Surprised by selectivity (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-03-04
    Description: Lower olefins, particularly ethylene (C2H4), propylene (C3H6), and butylene (C4H8), are important intermediates in the manufacture of products such as plastics, solvents, paints, and medicines. They are produced worldwide in amounts exceeding 200 million tons per year (see the photo) (1), mostly from crude oil. More recent approaches use methanol or synthesis gas (syngas; a mixture of carbon monoxide and hydrogen) as feedstocks, but capital investments are high and/or selectivities to lower olefins limited. A bifunctional catalyst reported by Jiao et al. on page 1065 of this issue (2) enables the direct conversion of synthesis gas to lower olefins with a surprisingly high selectivity. Author: Krijn P. de Jong
    Keywords: Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 10
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    Ligand-accelerated enantioselective methylene C(sp3)-H bond activation (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-09-02
    Description: Effective differentiation of prochiral carbon–hydrogen (C–H) bonds on a single methylene carbon via asymmetric metal insertion remains a challenge. Here, we report the discovery of chiral acetyl-protected aminoethyl quinoline ligands that enable asymmetric palladium insertion into prochiral C–H bonds on a single methylene carbon center. We apply these palladium complexes to catalytic enantioselective functionalization of β-methylene C–H bonds in aliphatic amides. Using bidentate ligands to accelerate C–H activation of otherwise unreactive monodentate substrates is crucial for outcompeting the background reaction driven by substrate-directed cyclopalladation, thereby avoiding erosion of enantioselectivity. The potential of ligand acceleration in C–H activation is also demonstrated by enantioselective β-C–H arylation of simple carboxylic acids without installing directing groups.
    Keywords: Chemistry
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  • 11
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    [Editors' Choice] Sourcing hydrogen directly from wax (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-11-04
    Description: Author: Jake Yeston
    Keywords: Chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 12
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    Cytochrome a3 structure in carbon monoxide-bound cytochrome oxidase (1984)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1984-07-20
    Description: The iron-carbon monoxide stretching mode and the iron-carbon-oxygen bending mode in carbon monoxide-bound cytochrome oxidase have been assigned at 520 and 578 cm-1, respectively. The frequencies, widths, and intensities of these modes show that the Fe-C-O grouping in carbon monoxide-cytochrome a3 is linear but tilted from the normal to the heme plane; that the iron-histidine bond in both five- and six-coordinate cytochrome a3 is strained; and that the carbon monoxide and the proximal histidine each have characteristic, well-defined orientations in all molecules. These data can account for the binding affinities of carbon monoxide and dioxygen under physiological conditions.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Argade, P V -- Ching, Y C -- Rousseau, D L -- New York, N.Y. -- Science. 1984 Jul 20;225(4659):329-31.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6330890" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Carbon Monoxide/metabolism ; Cattle ; Chemical Phenomena ; Chemistry ; Electron Transport Complex IV/*metabolism ; Myoglobin/metabolism ; Oxidation-Reduction ; Oxygen/metabolism ; Spectrum Analysis, Raman
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  • 13
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    Amphiphilic secondary structure: design of peptide hormones (1984)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1984-01-20
    Description: Peptide synthesis can be used for elucidating the roles of secondary structures in the specificity of hormones, antigens, and toxins. Intermediate sized peptides with these activities assume amphiphilic secondary structures in the presence of membranes. When models are designed to optimize the amphiphilicity of the secondary structure, stronger interactions can be observed with the synthetic peptides than with the naturally occurring analogs.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Kaiser, E T -- Kezdy, F J -- HL-18577/HL/NHLBI NIH HHS/ -- New York, N.Y. -- Science. 1984 Jan 20;223(4633):249-55.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6322295" target="_blank"〉PubMed〈/a〉
    Keywords: Amino Acid Sequence ; Apolipoprotein A-I ; Apolipoproteins ; Binding Sites ; Calcitonin ; Chemical Phenomena ; Chemistry ; Corticotropin-Releasing Hormone ; Endorphins ; Glucagon ; Growth Hormone-Releasing Hormone ; *Hormones/pharmacology ; Lipoproteins, HDL ; Melitten ; Models, Structural ; *Peptides/chemical synthesis/metabolism/pharmacology ; Protein Conformation ; Structure-Activity Relationship ; beta-Endorphin
    Print ISSN: 0036-8075
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  • 14
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    Fourier transform mass spectrometry (1984)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1984-10-19
    Description: Fourier transform mass spectrometry will play an important role in the future because of its unique combination of high mass resolution, high upper mass limit, and multichannel advantage. These features have already found application in gas chromatography-mass spectrometry, multiphoton ionization, laser desorption, and secondary ion mass spectrometry. However, its most notable feature is the ability to store ions. This characteristic, when combined with the others, will allow expeditious study of the interaction of gas-phase ions with both photons (photodissociation) and neutral molecules, and the convenient application of this fundamental information for chemical analysis.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Gross, M L -- Rempel, D L -- 2-8423576/PHS HHS/ -- New York, N.Y. -- Science. 1984 Oct 19;226(4672):261-8.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6385250" target="_blank"〉PubMed〈/a〉
    Keywords: Chemical Phenomena ; Chemistry ; *Fourier Analysis ; Ions ; Lasers ; *Mass Spectrometry/instrumentation/methods
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  • 15
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    Studying enzyme mechanism by 13C nuclear magnetic resonance (1984)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1984-08-31
    Description: High-resolution carbon-13 nuclear magnetic resonance (NMR) spectra of enzyme-inhibitor and enzyme-substrate complexes provide detailed structural and stereochemical information on the mechanism of enzyme action. The proteases trypsin and papain are shown to form tetrahedrally coordinated complexes and acyl derivatives with a variety of compounds artificially enriched at the site or sites of interest. These results are compared with the structural information derived from x-ray diffraction. Detailed NMR studies have provided a clearer picture of the ionization state of the residues participating in enzyme-catalyzed processes than other more classical techniques. The dynamics of enzymic catalysis can be observed at sub-zero temperatures by a combination of cryoenzymology and carbon-13 NMR spectroscopy. With these powerful techniques, transient, covalently bound intermediates in enzyme-catalyzed reactions can be detected and their structures rigorously assigned.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Mackenzie, N E -- Malthouse, J P -- Scott, A I -- New York, N.Y. -- Science. 1984 Aug 31;225(4665):883-9.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6433481" target="_blank"〉PubMed〈/a〉
    Keywords: Binding Sites ; Carbon Isotopes ; Carboxypeptidases/metabolism ; Carboxypeptidases A ; Catalysis ; Chemical Phenomena ; Chemistry ; Coenzymes/*metabolism ; Endopeptidases/metabolism ; Enzymes/*metabolism ; Freezing ; Fructose-Bisphosphate Aldolase/metabolism ; Magnetic Resonance Spectroscopy ; Papain/metabolism ; Pepsin A/metabolism ; Peptide Hydrolases/*metabolism ; Protease Inhibitors ; Pterins/metabolism ; Pyridoxal Phosphate/metabolism ; Serine Endopeptidases
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  • 16
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    What is the risk from chlorofluorocarbons? (1984)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1984-03-09
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Maugh, T H 2nd -- New York, N.Y. -- Science. 1984 Mar 9;223(4640):1051-2.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6695193" target="_blank"〉PubMed〈/a〉
    Keywords: *Air Pollutants ; *Atmosphere ; Carbon Tetrachloride ; Chemical Phenomena ; Chemistry ; *Chlorofluorocarbons, Methane ; Free Radicals ; Nitrogen Dioxide ; Nitrous Oxide ; Oxygen ; *Ozone ; Photochemistry ; Risk ; Singlet Oxygen ; Trichloroethanes ; Ultraviolet Rays
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  • 17
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    Pyrolysis mass spectrometry of complex organic materials (1984)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1984-10-19
    Description: Pyrolysis mass spectrometry in combination with computerized multivariate statistical analysis enables qualitative and quantitative analysis of nonvolatile organic materials containing molecular assemblies of a complexity and size far beyond the capabilities of direct mass spectrometry. The state of the art in pyrolysis mass spectrometry techniques is illustrated through specific applications, including structural determination and quality control of synthetic polymers, quantitative analysis of polymer mixtures, classification and structural characterization of fossil organic matter, and nonsupervised numerical extraction of component patterns from complex biological samples.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Meuzelaar, H L -- Windig, W -- Harper, A M -- Huff, S M -- McClennen, W H -- Richards, J M -- New York, N.Y. -- Science. 1984 Oct 19;226(4672):268-74.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6484572" target="_blank"〉PubMed〈/a〉
    Keywords: Biochemical Phenomena ; Biochemistry ; Chemical Phenomena ; Chemistry ; Coal ; Enterobacteriaceae/analysis/isolation & purification ; Hot Temperature ; Mass Spectrometry/*methods ; Polymers
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    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 18
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    Lariat RNA's as intermediates and products in the splicing of messenger RNA precursors (1984)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1984-08-31
    Description: The splicing of messenger RNA precursors in vitro proceeds through an intermediate that has the 5' end of the intervening sequence joined to a site near the 3' splice site. This lariat structure, which has been characterized for an adenovirus 2 major late transcript, has a branch point, with 2'-5' and 3'-5' phosphodiester bonds emanating from a single adenosine residue. The excised intervening sequence retains the branch site and terminates in a guanosine residue with a 3' hydroxyl group. The phosphate group at the splice junction between the two exons originates from the 3' splice site at the precursor.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Padgett, R A -- Konarska, M M -- Grabowski, P J -- Hardy, S F -- Sharp, P A -- P01-CA14051/CA/NCI NIH HHS/ -- P01-CA26717/CA/NCI NIH HHS/ -- R01-GM32467/GM/NIGMS NIH HHS/ -- New York, N.Y. -- Science. 1984 Aug 31;225(4665):898-903.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6206566" target="_blank"〉PubMed〈/a〉
    Keywords: Adenoviruses, Human/metabolism ; Base Sequence ; Chemical Phenomena ; Chemistry ; Nucleic Acid Conformation ; Nucleic Acid Precursors/analysis/*metabolism ; Oligoribonucleotides/metabolism ; Phosphates/metabolism ; RNA/analysis/*metabolism ; RNA Precursors ; *RNA Splicing ; RNA, Messenger/analysis/*metabolism ; RNA, Viral/analysis/*metabolism
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  • 19
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    beta-Carotene: an unusual type of lipid antioxidant (1984)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1984-05-11
    Description: The mechanism of lipid peroxidation and the manner in which antioxidants function is reviewed. beta-Carotene is a purported anticancer agent, which is believed by some to have antioxidant action of a radical-trapping type. However, definitive experimental support for such action has been lacking. New experiments in vitro show that beta-carotene belongs to a previously unknown class of biological antioxidants. Specifically, it exhibits good radical-trapping antioxidant behavior only at partial pressures of oxygen significantly less than 150 torr, the pressure of oxygen in normal air. Such low oxygen partial pressures are found in most tissues under physiological conditions. At higher oxygen pressures, beta-carotene loses its antioxidant activity and shows an autocatalytic, prooxidant effect, particularly at relatively high concentrations. Similar oxygen-pressure-dependent behavior may be shown by other compounds containing many conjugated double bonds.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Burton, G W -- Ingold, K U -- New York, N.Y. -- Science. 1984 May 11;224(4649):569-73.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6710156" target="_blank"〉PubMed〈/a〉
    Keywords: Antioxidants/*metabolism ; Carotenoids/*metabolism ; Chemical Phenomena ; Chemistry ; Free Radicals ; Humans ; Linoleic Acids/metabolism ; *Lipid Metabolism ; Oxidation-Reduction ; Oxygen/metabolism ; Partial Pressure ; Peroxides/metabolism ; Tetrahydronaphthalenes/metabolism ; beta Carotene
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  • 20
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    Phenylalanine transfer RNA: molecular dynamics simulation (1984)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1984-03-16
    Description: Yeast phenylalanine transfer RNA was subjected to a 12-picosecond molecular dynamics simulation. The principal features of the x-ray crystallographic analysis are reproduced, and the amplitudes of atomic displacements appear to be determined by the degree of exposure of the atoms. An analysis of the hydrogen bonds shows a correlation between the average length of a bond and the fluctuation in that length and reveals a rocking motion of bases in Watson-Crick guanine X cytosine base pairs. The in-plane motions of the bases are generally of larger amplitude than the out-of-plane motions, and there are correlations in the motions of adjacent bases.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Harvey, S C -- Prabhakaran, M -- Mao, B -- McCammon, J A -- New York, N.Y. -- Science. 1984 Mar 16;223(4641):1189-91.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6560785" target="_blank"〉PubMed〈/a〉
    Keywords: Chemical Phenomena ; Chemistry ; Computers ; Cytosine ; Guanine ; Hydrogen Bonding ; Nucleic Acid Conformation ; *RNA, Fungal ; *RNA, Transfer, Amino Acyl ; Yeasts/analysis
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    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 21
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    Reaction of the antitumor antibiotic CC-1065 with DNA: structure of a DNA adduct with DNA sequence specificity (1984)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1984-11-16
    Description: Sequence-dependent variations in DNA revealed by x-ray crystallographic studies have suggested that certain DNA-reactive drugs may react preferentially with defined sequences in DNA. Drugs that wind around the helix and reside within one of the grooves of DNA have perhaps the greatest chance of recognizing sequence-dependent features of DNA. The antitumor antibiotic CC-1065 covalently binds through N-3 of adenine and resides within the minor groove of DNA. This drug overlaps with five base pairs for which a high sequence specificity exists.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Hurley, L H -- Reynolds, V L -- Swenson, D H -- Petzold, G L -- Scahill, T A -- New York, N.Y. -- Science. 1984 Nov 16;226(4676):843-4.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6494915" target="_blank"〉PubMed〈/a〉
    Keywords: Antibiotics, Antineoplastic/*metabolism ; *Base Sequence ; Binding Sites ; Chemical Phenomena ; Chemistry ; DNA/*metabolism ; *Indoles ; Leucomycins/*metabolism ; Molecular Conformation ; X-Ray Diffraction
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  • 22
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    Allylamine derivatives: new class of synthetic antifungal agents inhibiting fungal squalene epoxidase (1984)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1984-06-15
    Description: A new class of synthetic antifungal agents, the allylamines , has been developed by modification of naftifine , a topical antimycotic. SF 86-327, the most effective of these compounds so far, is highly active in vitro against a wide range of fungi and exceeds clinical standards in the oral and topical treatment of guinea pig dermatophytoses. SF 86-327 is a powerful specific inhibitor of fungal squalene epoxidase, a key enzyme in sterol biosynthesis.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Petranyi, G -- Ryder, N S -- Stutz, A -- New York, N.Y. -- Science. 1984 Jun 15;224(4654):1239-41.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6547247" target="_blank"〉PubMed〈/a〉
    Keywords: Allylamine/analogs & derivatives/*chemical synthesis/pharmacology ; Amines/*chemical synthesis ; Animals ; Antifungal Agents/*chemical synthesis/pharmacology ; Chemical Phenomena ; Chemistry ; Dermatomycoses/drug therapy ; Fungi/*drug effects/enzymology ; Guinea Pigs ; Naphthalenes/chemical synthesis/pharmacology ; Oxygenases/*antagonists & inhibitors ; Squalene Monooxygenase
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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    Disulfide bond engineered into T4 lysozyme: stabilization of the protein toward thermal inactivation (1984)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1984-11-02
    Description: By recombinant DNA techniques, a disulfide bond was introduced at a specific site in T4 lysozyme, a disulfide-free enzyme. This derivative retained full enzymatic activity and was more stable toward thermal inactivation than the wild-type protein. The derivative, T4 lysozyme (Ile3----Cys), was prepared by substituting a Cys codon for an Ile codon at position 3 in the cloned lysozyme gene by means of oligonucleotide-dependent, site-directed mutagenesis. The new gene was expressed in Escherichia coli under control of the (trp-lac) hybrid tac promoter, and the protein was purified. Mild oxidation generated a disulfide bond between the new Cys3 and Cys97, one of the two unpaired cysteines of the native molecule. Oxidized T4 lysozyme (Ile3----Cys) exhibited specific activity identical to that of the wild-type enzyme when measured at 20 degrees C in a cell-clearing assay. The cross-linked protein was more stable than the wild type during incubation at elevated temperatures as determined by recovered enzymatic activity at 20 degrees C.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Perry, L J -- Wetzel, R -- New York, N.Y. -- Science. 1984 Nov 2;226(4674):555-7.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6387910" target="_blank"〉PubMed〈/a〉
    Keywords: Chemical Phenomena ; Chemistry ; DNA, Recombinant/metabolism ; Escherichia coli/enzymology ; *Genetic Engineering ; Kinetics ; Muramidase/*genetics/metabolism ; Protein Denaturation
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    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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    A nitrogen pressure of 50 atmospheres does not prevent evolution of hydrogen by nitrogenase (1984)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1984-06-08
    Description: The effect of a partial pressure of nitrogen of 50 atmospheres (5065 kilopascals ) on the hydrogen evolution reaction of nitrogenase has been investigated. Evolution of hydrogen was not blocked completely by 50 atmospheres of nitrogen in any of four experiments; rather, 27.3 +/- 2.4 percent of the total electron flux through nitrogenase was directed toward production of hydrogen. The ratio of hydrogen evolved to nitrogen fixed was close to 1:1, which implies that hydrogen evolution is obligatory in the fixation of molecular nitrogen by nitrogenase.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Simpson, F B -- Burris, R H -- AI-00848/AI/NIAID NIH HHS/ -- New York, N.Y. -- Science. 1984 Jun 8;224(4653):1095-7.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6585956" target="_blank"〉PubMed〈/a〉
    Keywords: Chemical Phenomena ; Chemistry ; *Hydrogen ; *Nitrogen ; Nitrogen Fixation ; *Nitrogenase ; Partial Pressure
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    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 25
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    Nonvolatile mutagens in drinking water: production by chlorination and destruction by sulfite (1980)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1980-01-04
    Description: In concentrates of water produced in a laboratory simulation of a drinking water treatment process, direct-acting, nonvolatile mutagens were readily detected by means of the Ames Salmonella test. The mutagens were shown to be produced by the chlorination process. Treatment of the water with chloramine resulted in less mutagenic activity than treatment with free chlorine. Dechlorination of drinking water with sulfite sharply reduced the mutagenic activity. Treatment with sulfur dioxide is proposed as an effective, inexpensive method of reducing the direct-acting mutagenic activity of drinking water and of aqueous industrial effluents.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Cheh, A M -- Skochdopole, J -- Koski, P -- Cole, L -- New York, N.Y. -- Science. 1980 Jan 4;207(4426):90-2.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6985746" target="_blank"〉PubMed〈/a〉
    Keywords: Chemical Phenomena ; Chemistry ; Chloramines ; Chlorine ; Mutagens/*analysis ; Salmonella typhimurium/genetics ; Sulfites ; Water Pollutants/*analysis ; Water Pollutants, Chemical/*analysis ; Water Supply/*analysis
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    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 26
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    Trace chemistries of fire: a source of chlorinated dioxins (1980)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1980-10-01
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Bumb, R R -- Crummett, W B -- Cutie, S S -- Gledhill, J R -- Hummel, R H -- Kagel, R O -- Lamparski, L L -- Luoma, E V -- Miller, D L -- Nestrick, T J -- Shadoff, L A -- Stehl, R H -- Woods, J S -- New York, N.Y. -- Science. 1980 Oct;210(4468):385-90.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6159682" target="_blank"〉PubMed〈/a〉
    Keywords: Air Pollutants/analysis ; Chemical Phenomena ; Chemistry ; Chromatography, High Pressure Liquid ; *Dioxins/analysis ; *Fires ; Power Plants ; Smoke/analysis ; Soil Pollutants/analysis ; Tetrachlorodibenzodioxin/analysis ; Vehicle Emissions/analysis ; Water Pollutants, Chemical/analysis
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    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 27
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    Synthetic competitive antagonists of corticotropin-releasing factor: effect on ACTH secretion in the rat (1984)
    American Association for the Advancement of Science (AAAS)
    Details
    Publication Date: 1984-05-25
    Description: Polypeptide analogs of the known members of the corticotropin-releasing factor (CRF) family were synthesized and tested in vitro and in vivo for enhanced potency or competitive antagonism. Predictive methods and physicochemical measurements had suggested an internal secondary alpha-helical conformation spanning about 25 residues for at least three members of the CRF family. Maximization of alpha-helix-forming potential by amino acid substitutions from the native known sequences (rat/human and ovine CRF, sauvagine, and carp and sucker urotensin 1) led to the synthesis of an analog that was found to be more than twice as potent as either of the parent peptides in vitro. In contrast, certain amino-terminally shortened fragments, such as alpha-helical CRF or ovine CRF residues 8 to 41, 9 to 41, and 10 to 41, were found to be competitive inhibitors in vitro. Selected antagonists were examined and also found to be active in vivo.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Rivier, J -- Rivier, C -- Vale, W -- AA03504/AA/NIAAA NIH HHS/ -- AM20917/AM/NIADDK NIH HHS/ -- AM26741/AM/NIADDK NIH HHS/ -- etc. -- New York, N.Y. -- Science. 1984 May 25;224(4651):889-91.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/6326264" target="_blank"〉PubMed〈/a〉
    Keywords: Adrenocorticotropic Hormone/secretion ; Animals ; Binding, Competitive ; Chemical Phenomena ; Chemistry ; Corticotropin-Releasing Hormone/*antagonists & inhibitors ; Rats
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    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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    [Editors' Choice] A clean combination of CO and amines (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-11-25
    Description: Author: Jake Yeston
    Keywords: Chemistry
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 29
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    [Perspective] Ammonia activation at a metal (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-11-11
    Description: Although ammonia (NH3) is made on a vast scale for use in fertilizers, its use as a chemical feedstock or as an energy carrier is much more limited. Many reactions that occur easily with its substitution products (amines) are sluggish for NH3, in part because of the difficulty of activating the N-H bond. For fuel cells, NH3 is attractive because it does not generate greenhouse gases, as do methanol and methane (1), and is more easily stored than hydrogen (H2). Amine-containing organic molecules are used in pharmaceutical and materials applications, and accessing these structures directly from ammonia could limit the generation of by-products during their synthesis (2). Bringing NH3 up to speed for these applications will require both the development of catalysts that can activate the strong N–H bond of ammonia and a fundamental understanding of the N–H bond cleavage step. On page 730 of this issue, Bezdek et al. (3) report a molybdenum complex capable of weakening the N–H bond of NH3 and releasing a H atom to generate H2 under mild conditions. Author: Jessica Hoover
    Keywords: Chemistry
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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    Enantioselective cyanation of benzylic C-H bonds via copper-catalyzed radical relay (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-09-02
    Description: Direct methods for stereoselective functionalization of sp 3 -hybridized carbon–hydrogen [C(sp 3 )–H] bonds in complex organic molecules could facilitate much more efficient preparation of therapeutics and agrochemicals. Here, we report a copper-catalyzed radical relay pathway for enantioselective conversion of benzylic C–H bonds into benzylic nitriles. Hydrogen-atom abstraction affords an achiral benzylic radical that undergoes asymmetric C(sp 3 )–CN bond formation upon reaction with a chiral copper catalyst. The reactions proceed efficiently at room temperature with the benzylic substrate as limiting reagent, exhibit broad substrate scope with high enantioselectivity (typically 90 to 99% enantiomeric excess), and afford products that are key precursors to important bioactive molecules. Mechanistic studies provide evidence for diffusible organic radicals and highlight the difference between these reactions and C–H oxidations mediated by enzymes and other catalysts that operate via radical rebound pathways.
    Keywords: Chemistry
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    A highly active and stable IrOx/SrIrO3 catalyst for the oxygen evolution reaction (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-09-02
    Description: Oxygen electrochemistry plays a key role in renewable energy technologies such as fuel cells and electrolyzers, but the slow kinetics of the oxygen evolution reaction (OER) limit the performance and commercialization of such devices. Here we report an iridium oxide/strontium iridium oxide (IrO x /SrIrO 3 ) catalyst formed during electrochemical testing by strontium leaching from surface layers of thin films of SrIrO 3 . This catalyst has demonstrated specific activity at 10 milliamps per square centimeter of oxide catalyst (OER current normalized to catalyst surface area), with only 270 to 290 millivolts of overpotential for 30 hours of continuous testing in acidic electrolyte. Density functional theory calculations suggest the formation of highly active surface layers during strontium leaching with IrO 3 or anatase IrO 2 motifs. The IrO x /SrIrO 3 catalyst outperforms known IrO x and ruthenium oxide (RuO x ) systems, the only other OER catalysts that have reasonable activity in acidic electrolyte.
    Keywords: Chemistry
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    [This Week in Science] Cooperation between frustrated partners (2016)
    American Association for the Advancement of Science (AAAS)
    In: Science
    Details
    Publication Date: 2016-12-09
    Description: Author: Jake Yeston
    Keywords: Chemistry
    Print ISSN: 0036-8075
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    Topics: Biology , Chemistry and Pharmacology , Geosciences , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 33
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    Application of a snowmelt-runoff model using LANDSAT data (1980)
    In:  CASI
    Details
    Publication Date: 2006-04-26
    Description: The snowmelt-runoff model developed for two small central European watersheds simulate daily streamflow on the 228 sq km Dinwoody Creek basin in Wyoming, using snowcover extent for LANDSAT and conventionally measured temperature and precipitation. For the six-month snowmelt seasons of 1976 and 1974, the simulated seasonal runoff volumes were within 5 and 1%, respectively, of the measured runoff. Also the daily fluctuations of discharge were simulated to a high degree by the model. Thus far the limiting basin size for applying the model has not been reached, and improvements can be expected if the hydrometeorological data can be obtained from a station inside the basin. LANDSAT provides an efficient way to obtain the critical snowcover input parameter required by the model.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Goddard Lab. for Atmospheric Sci., Collected Reprints 1978 - 1979, Vol. 2; p 745-760
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    The utilization of spaceborne microwave radiometers for monitoring snowpack properties (1980)
    In:  CASI
    Details
    Publication Date: 2006-04-26
    Description: Snow accumulation and depletion at specific locations can be monitored from space by observing related variations in microwave brightness temperatures. Using vertically and horizontally polarized brightness temperatures from the Nimbus 6 electrically scanning microwave radiometer, a discriminant function can be used to separate snow from no snow areas and map snowcovered area on a continental basis. For dry snow conditions on the Canadian high plains, significant relationships between snow depth or water equivalent and microwave brightness temperature were developed which could permit remote determination of these snow properties after acquisition of a wider range of data. The presence of melt water in the snowpack causes a marked increase in brightness temperature which can be used to predict snowpack priming and timing of runoff. As the resolutions of satellite microwave sensors improve the application of these results to snow hydrology problems should increase.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Goddard Lab. for Atmospheric Sci., Collected Reprints 1978 - 1979, Vol. 2; p 745-760
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  • 35
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    Seasonal and daily snowmelt runoff estimates utilizing satellite data (1980)
    In:  CASI
    Details
    Publication Date: 2006-04-26
    Description: Methods using snowcovered area to update seasonal forecasts as snowmelt progresses are also being used in quasi-operational situations. The input of snowcovered area to snowmelt models for short term perdictions was attempted in two ways; namely, the modification of existing hydrologic models and/or the use of models that were specifically designed to use snowcovered area. A daily snowmelt runoff model was used with LANDSAT data to simulate discharge on remote basins in the Wind River Mountains of Wyoming. Daily predicted and actual flows compare closely, and, summarized over the entire snowmelt season (April 1 - September 30), the average difference is only three percent. The model and snowcovered area data are currently being tested on additional watersheds to determine the method's transferability.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Goddard Lab. for Atmospheric Sci. Collected Reprints 1978 - 1979, Vol. 2; p 742
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  • 36
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    Lightning research: A user's lament (1984)
    In:  CASI
    Details
    Publication Date: 2006-02-14
    Description: As a user of devices and procedures for lightning protection, the author is asking the lightning research community for cookbook recipes to help him solve his problems. He is lamenting that realistic devices are scarce and that his mission does not allow him the time nor the wherewithal to bridge the gap between research and applications. A few case histories are presented. In return for their help he is offering researchers a key to lightning technology--the use of the Eastern Test Range and its extensive resources as a proving ground for their experiment in the lightning capital of the United States. A current example is given--a joint lightning characterization project to take place there. Typical resources are listed.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: NASA. Langley Research Center Intern. Aerospace and Ground Conf. on Lightning and Static Elec.; 6 p
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  • 37
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    The program of the Techniques Development Laboratory in aviation weather forecasting (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: Some operational and experimental products developed for aviation weather forecasting are briefly described. Experimental products include surface dew point, obstructions to vision, boundary layer model, computer-worded terminal forecasts, terminal alerting procedure, generalized equivalent Markov, and radar forecasts (0-2 hours).
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: NASA. Marshall Space Flight Center Proc.: Fourth Ann. Workshop on Meteorol. and Environ. Inputs to Aviation Systems; p 209-212
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  • 38
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    Doctor Fujita's microburst analysis at Chicago (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: Doppler radar measurements of an intense wind shear occurance are discussed. The data suggest the presence of an incredibly strong low level jet outflow component of the microburst event, reaching 60 knots only 50 meters above the surface. Evidence also suggests that microbursts more typically occur in very weak thunderstorms that have hardly reached thunderstorm stage.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: NASA. Marshall Space Flight Center Proc.: Fourth Ann. Workshop on Meteorol. and Environ. Inputs to Aviation Systems; p 201-202
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  • 39
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    The microburst: Common factor in recent aircraft accidents (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: The phenomenology of one class of strong thunderstorm downdrafts, microbursts, is described. Several aircraft accidents are analyzed in which a microburst was involved and a concept for an early warning wind shear sensor is presented.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: NASA. Marshall Space Flight Center Proc.: Fourth Ann. Workshop on Meteorol. and Environ. Inputs to Aviation Systems; p 186-200
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  • 40
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    Clear air turbulence forecasting techniques (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: A method to improve clear air turbulence (CAT) forecasting by more effectively using the currently operational rawinsonde (RW) system is discussed. The method is called the Diagnostic Richardson Number Tendency (DRT) technique. The technique does not attempt to use the RW as a direct detector of the turbulent motion or even of the CAT mechanism structure but rather senses the synoptic scale centers of action which provide the energy to the CAT mechanism at the mesoscale level. The DRT algorithm is deterministic rather than statistical in nature, using the hydrodynamic equations (equations of motion) relevant to the synoptic scale. However, interpretation, by necessity, is probabilistic. What is most important with respect to its operational implementation is that this method uses the same input data as currently used by the operational National Meteorological Center prognostic models.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: NASA. Marshall Space Flight Center Proc.: Fourth Ann. Workshop on Meteorol. and Environ. Inputs to Aviation Systems; p 203-208
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  • 41
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    The 1979 clear air turbulence flight test program (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: A clear air turbulence (CAT) flight test to evaluate and test four different sensors in the detection and measuring of CAT and other meteorological targets that relate to turbulence is discussed. The primary types of CAT investigated were mountain wave CAT, jetstream CAT, CAT in cirrus clouds, and CAT in frontal wind shears, troughs, and ridges. The sensors included the CO2 pulsed Doppler lidar and three radiometers. One of the radiometers, at a frequency of 55.5 GHz, looked at atmospheric temperature structure. Another, at a frequency of 180.1 GHz, looked at atmospheric water vapor and investigated the feasibility of measuring at the microwave frequency the turbulence features seen in the infrared (IR) frequencies. An IR radiometer at 27 to 33 microns was the fourth sensor. This last device and the temperature structure radiometer worked well at all flight levels.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Proc.: Fourth Ann. Workshop on Meteorol. and Environ. Inputs to Aviation Systems; p 171-179
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  • 42
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    Very short range forecasts of visibility and ceiling (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: The development of methods for the short range forecasting of visibility and ceiling conditions is discussed. Short range forecasts of one hour or less (5 or 30 minutes), immediately after a series of local observations can be expected to be more accurate and reliable than any forecast of more than one hour. These forecasts can be accomplished by the operational implementation of fully automated aviation observation systems and the utilization of statistical techniques such as the Generalized Equivalent Markov model.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: NASA. Marshall Space Flight Center Proc.: Fourth Ann. Workshop on Meteorol. and Environ. Inputs to Aviation Systems; p 180-185
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  • 43
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    Measuring weather for aviation safety in the 1980's (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: Requirements for an improved aviation weather system are defined and specifically include the need for (1) weather observations at all airports with instrument approaches, (2) more accurate and timely radar detection of weather elements hazardous to aviation, and (3) better methods of timely distribution of both pilot reports and ground weather data. The development of the discrete address beacon system data link, Doppler weather radar network, and various information processing techniques are described.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: NASA. Marshall Space Flight Center Proc.: Fourth Ann. Workshop on Meteorol. and Environ. Inputs to Aviation Systems; p 162-167
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  • 44
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    Observing lightning from ground-based and airborne stations (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: The operational designs and performance capabilities of ground-based and airborne lightning detection systems are reviewed. The airborne Stormscope system is described and compared with onboard radar and the lightning detection and ranging system (LDAR). Two examples of difference-in-time-of-arrival systems for detecting spherics from discharges in electrified clouds are described: (1) The LDAR system and (2) Taylor's lightning mapping system. Next, an interferometric system adapted to lightning location is discussed. Finally, systems that are based upon crossed-loop magnetic direction finding principles but which have been refined and improved to accurately locate lightning discharges to ground are reviewed.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: NASA. Marshall Space Flight Center Proc.: Fourth Ann. Workshop on Meteorol. and Environ. Inputs to Aviation Systems; p 130-139
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    Aeronautical concerns and National Aeronautics and Space Administration atmospheric electricity projects (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: The phenomenology of lightning and lightning measurement techniques are briefly examined with a particular reference to aeronautics. Developments made in airborne and satellite detection methods are reported. NASA research efforts are outlined which cover topics including in-situ measurements, design factors and protection, remote optical and radio frequency measurements, and space vehicle design.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Proc.: Fourth Ann. Workshop on Meteorol. and Environ. Inputs to Aviation Systems; p 140-160
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  • 46
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    Remote probing of wind and wind shears (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: The ability of various types of remote probes to measure wind is discussed. Two important advantages over in-situ sensors are reported: (1) their ability to measure atmospheric parameters without disturbing the air flow; (2) their ability to scan through large volumes of the atmosphere with relative ease. Direct measurement sensors such as anemometers and wind vanes are categorized into two groups; active and passive. Acoustic radar, microwave radar, and lidar are included in the first group and the latter group is typified by the infrared radiometers.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: NASA. Marshall Space Flight Center Proc: Fourth Ann. Workshop on Meteorol. and Environ. Inputs to Aviation Systems; p 109-124
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  • 47
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    Winds and wind shear in-situ sensors (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: The problem of development of instrumentation for providing wind speed and direction information directly or indirectly to a pilot in the cockpit is considered. The pilots need for horizontal wind information at various stages of flight (i.e., at liftoff, in approach and departure corridors, and even in flight outside the terminal area) are emphasized.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: NASA. Marshall Space Flight Center Proc: Fourth Ann. Workshop on Meteorol. and Environ. Inputs to Aviation Systems; p 82-108
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  • 48
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    Clear air turbulence: Historical comments (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: The basic reference material for gust design criteria are cited. The status of clear air turbulence meteorology (forecasting and detection) is discussed. The directions of further research technology is indicated.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: NASA. Marshall Space Flight Center Proc: Fourth Ann. Workshop on Meterol. and Environ. Inputs to Aviation Systems; p 71-81
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  • 49
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    Aircraft icing instrumentation: Unfilled needs (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: A list of icing instrumentation requirements are presented. Because of the Army's helicopter orientation, many of the suggestions are specific to rotary wing aircraft; however, some of the instrumentation are also suitable for general aviation aircraft.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: NASA. Marshall Space Flight Center Proc: Fourth Ann. Workshop on Meteorol. and Environ. Inputs to Aviation Systems; p 61-65
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  • 50
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    Icing instrumentation (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: The types and usage categories of icing instrumentation are discussed. The state-of-the-art for the technology governing the use of icing instrumentation is reported with particular emphasis on ground based facilities for icing tests.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: NASA. Marshall Space Flight Center Proc: Fourth Ann. Workshop on Meteorol. and Environ. Inputs to Aviation Systems; p 49-60
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  • 51
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    Turbulence: From a pilot's viewpoint (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: The measurement of atmospheric turbulence is discussed in terms of a pilots viewpoint. Two areas of measurement are considered: frequency and severity of turbulence. Suggestions are given for helping the pilot solve the turbulence problem.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: NASA. Marshall Space Flight Center Proc: Fourth Ann. Workshop on Meteorol. and Environ. Inputs to Aviation Systems; p 66-70
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  • 52
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    Federal Aviation Administration and National Weather Service Aviation Research and Development (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: An overview is given of the developmental status of aviation weather services. Particular attention is given to justifying the need for better, more reliable service. The accomplishments of several automatic weather stations are discussed.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Proc: Fourth Ann. Workshop on Meteorol. and Environ. Inputs to Aviation Systems; p 45-48
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  • 53
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    Aviation meteorology research and development: A status report (1980)
    In:  CASI
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    Publication Date: 2006-01-16
    Description: The dynamic and rapid growth of technology in the area of aviation meteorology research and development are described with emphasis on the measurement of hazardous weather phenomena. Aspects of both onboard instrumentation and ground based facilities are evaluated in terms of their effectiveness of in avoiding hazards due to atmospheric electricity and lightning. Methods of alleviating terminal are hazards such as fog, low visibility and ceilings are also described.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Proc: Fourth Ann. Workshop on Meteorol. and Environ. Inputs to Aviation Systems; p 40-44
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  • 54
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    Survey of Workshops on Meteorological and Environmental Inputs to Aviation Systems (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: Various aspects of aviation meteorology are discussed with respect to their relative effects on aircraft terminal operations. Existing data on turbulence and wind shear from aircraft and towers are summarized. The significance of obtaining more real time wind and temperature information is emphasized. The application and testing of various radiometer devices are also described. Airborne methods to indicate wind differences at flight altitude and at touchdown are reported.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Proc: Fourth Ann. Workshop on Meteorol. and Environ. Inputs to Aviation Systems; p 23-39
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  • 55
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    First Scientific Working Group Meeting of Airborne Doppler Lidar Wind Velocity Measurement Program, appendix J (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: Three projects are suggested which could be done using the Doppler lidar. The first is a cooperative effort at BAO, the purpose of which is to check out instrumentation and contribute to boundary layer investigations at BAO. The second concerns unintended weather modification. Its purpose is to detect mechanisms by which regions of industry and urbanization modify weather. The cirrus cloud study proposes to characterize cirrus clouds by their lidar signal and to compare lidar and visually observed characteristics.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: NASA. Marshall Space Flight Center First Sci. Working Group Meeting of Airborne Doppler Lidar Wind Velocity Meas. Program; 5 p
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  • 56
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    Report of secondary flows, boundary layers, turbulence and wave team, report 1 (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: General criteria for a flight test option are that: (1) there be a good opportunity for comparison with other measurement techniques; (2) the flow to be measured is of considerable scientific or practical interest; and (3) the airborne laser Doppler system is well suited to measure the required quantities. The requirement for comparison, i.e., ground truth, is particularly important because this is the first year of operation for the system. It is necessary to demonstrate that the system does actually measure the winds and compare the results with other methods to provide a check on the system error analysis. The uniqueness of the laser Doppler system precludes any direct comparison, but point measurements from tower mounted wind sensors and two dimensional fields obtained from radars with substantially different sampling volumes are quite useful.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: First Sci. Working Group Meeting of Airborne Doppler Lidar Wind Velocity Meas. Program; 8 p
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  • 57
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    Cooperative convective precipitation experiment (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: The experiment strives to improve understanding of the physics of convective precipitation. Major emphasis is placed on obtaining a good description of the whole convective precipitation system. A framework is presented within which single, significant, tractable problems are investigated.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: NASA. Marshall Space Flight Center First Sci. Working Group Meeting of Airborne Doppler Lidar Wind Velocity Meas. Program; 25 p
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  • 58
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    Severe storms measurement system real time data processing and displays (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: The objectives of the system are to provide the system operator with real time system performance check and to provide data recording of all SSMS data. Meteorologists are provided with real time indication of meteorological data measurements including aid for directing flight profiles in real time and aid for directing SSMS operations. A day-to-day feedback is provided to meteorologists, system operators, and flight crews for flight planning on subsequent flight tests days.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: NASA. Marshall Space Flight Center First Sci. Working Group Meeting of Airborne Doppler Lidar Wind Velocity Meas. Program; 15 p
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  • 59
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    First Scientific Working Group Meeting of Airborne Doppler Lidar Wind Velocity Measurement Program, appendix C (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: The problem is to operate on two scalar fields to produce a vector field, to produce user products from the vector field, and to establish reliability of results. Data problems encountered include sparse measurements, irregular distribution, varying quality, imperfect orthogonality, aliasing due to sampling volume, and measurements not simultaneous. Desired algorithm characteristics, solution elements, and characteristics of the model are listed. The seven simulation elements, eight algorithm steps and the required user inputs are given.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: NASA. Marshall Space Flight Center First Sci. Working Group Meeting of Airborne Doppler Lidar Wind Velocity Meas. Program; 8 p
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  • 60
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    Report of convective phenomena team (1980)
    In:  CASI
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    Publication Date: 2006-01-16
    Description: A group meeting was assembled to focus on the planning of specific experiments, to establish some priorities, identify interested scientists who would like to participate, establish any special requirements, make recommendations on data processing, and to prepare flight plan outlines. Since the number of convective storms in the CCOPE (Cooperative Convective Precipitation Experiment) field experiment area are limited to only a few days during the operational time period the flight plans must be designed with a hierarchy of abort experiments so that the easily identified and lowest probability events should take priority until their quota is filled.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: First Sci. Working Group Meeting of Airborne Doppler Lidar Wind Velocity Meas. Program; 10 p
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  • 61
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    The MSFC Doppler lidar system, appendix B (1980)
    In:  CASI
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    Publication Date: 2006-01-16
    Description: The development of pulsed and continuous wave Doppler lidars for atmospheric measurement is discussed. A description of how the lidar systems operate is presented. The scanning mode is also described.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Exploratory Meeting on Airborne Doppler Lidar Wind Velocity Meas.; p 40-42
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  • 62
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    Possible applications of MSFC Doppler lidar system, appendix C (1980)
    In:  CASI
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    Publication Date: 2006-01-16
    Description: An interpretation of the Doppler lidar return is presented. Possible applications of the system to severe storm research are discussed. The present project schedule of the Doppler lidar system is outlined.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Exploratory Meeting on Airborne Doppler Lidar Wind Velocity Meas.; p 43-46
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  • 63
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    Wind field measurement in the nonprecipitous regions surrounding storms by an airborne pulsed Doppler lidar system, appendix A (1980)
    In:  CASI
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    Publication Date: 2006-01-16
    Description: Coherent Doppler lidar appears to hold great promise in contributing to the basic store of knowledge concerning flow field characteristics in the nonprecipitous regions surrounding severe storms. The Doppler lidar, through its ability to measure clear air returns, augments the conventional Doppler radar system, which is most useful in the precipitous regions of the storm. A brief description of the Doppler lidar severe storm measurement system is provided along with the technique to be used in performing the flow field measurements. The application of the lidar is addressed, and the planned measurement program is outlined.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Exploratory Meeting on Airborne Doppler Lidar Wind Velocity Meas.; p 31-39
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  • 64
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    Application of the Doppler lidar system to agricultural burning and air-sea interactions (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: The Doppler lidar system is potentially a very powerful measurement system. Three areas concerning the system are discussed: (1) error analysis of the system to verify the results; (2) application of the system to agricultural burning in California central valley; and (3) oceanographic possibilities of the system.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: NASA. Marshall Space Flight Center Exploratory Meeting on Airborne Doppler Lidar Wind Velocity Meas.; p 25
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  • 65
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    Measurement of phenomena associated with water clouds using Doppler lidar (1980)
    In:  CASI
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    Publication Date: 2006-01-16
    Description: Doppler lidar measurements of phenomena associated with water clouds (such as aerosols) are discussed. The purpose of the measurements and details of executing the experiment are described.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Exploratory Meeting on Airborne Doppler Lidar Wind Velocity Meas.; p 20-24
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  • 66
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    Potential uses of the airborne Doppler lidar wind velocity measurement system (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: Four aspects of the Doppler lidar are discussed: (1) error analysis of the system; (2) design of the first field program; (3) potential areas of application; and (4) verification of Doppler lidar data by independent measurements.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: NASA. Marshall Space Flight Center Exploratory Meeting on Airborne Doppler Lidar Wind Velocity Meas.; p 16-17
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  • 67
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    Potential scientific research which will benefit from an airborne Doppler lidar measurement system (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: Areas of research which can be significantly aided by the Doppler lidar airborne system are described. The need for systematic development of the airborne Doppler lidar is discussed. The technology development associated with the systematic development of the system will have direct application to satellite systems for which the lidar also promises to be an effective instrument for atmospheric research.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: NASA. Marshall Space Flight Center Exploratory Meeting on Airborne Doppler Lidar Wind Velocity Meas.; p 13-15
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  • 68
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    Potential applications of the Doppler lidar measurements (1980)
    In:  CASI
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    Publication Date: 2006-01-16
    Description: The potential application of the Doppler lidar measurements to the determination of material (e.g., water vapor) and energy budgets, momentum transports, etc., in the environment at all stages and in the development of convective clouds are discussed.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: NASA. Marshall Space Flight Center Exploratory Meeting on Airborne Doppler Lidar Wind Velocity Meas.; p 18-19
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  • 69
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    Airborne Doppler lidar wind measuring system: Application to atmospheric problems (1980)
    In:  CASI
    Details
    Publication Date: 2006-01-16
    Description: The ability to map velocities over a large area on one side of the aircraft flight path offers a number of opportunities to elucidate scientific questions related to atmospheric dynamics. Several types of experiments which are possible are described.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: NASA. Marshall Space Flight Center Exploratory Meeting on Airborne Doppler Lidar Wind Velocity Meas.; p 11-12
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  • 70
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    Statistical Analysis of daily mean temperatures (1980)
    In:  CASI
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    Publication Date: 2006-02-14
    Description: Data of daily mean temperatures recorded at the Kennedy Center during the period of 1957-1977 were analyzed to forecast daily mean temperatures and their thirty-day moving averages for a period of ten to fifteen days in a given month. Since it is found that the standard deviation is linear in the mean, a logarithmic transformation of the data is used for finding an integrated moving average process IMA by the Box-Jenkins aproach. The first differences of the transformed data seem to fit a moving average model with parameter value 2, MA(2). The consideration of seasonality factor makes the fit worse.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: The 1981 NASA(ASEE Summer Fac. Fellowship Program; 13 p
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  • 71
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    Some aspects of understanding changes in the global carbon cycle (1984)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: The collective character of carbon exchanges between the atmosphere and other pools is partially revealed by comparing the record of CO2 concentration beginning in 1958 with estimates of the releases from fossil fuels during this period. In analyzing the secular increase in CO2 concentration induced by fossil fuel use, the atmosphere is generally treated as a single well-mixed reservoir; however, to study finer structure in the CO2 records, the influence of atmospheric circulation must be more carefully considered. The rate of carbon uptake by the oceans, the primary sink for fossil fuel CO2, is assessed more reliably than influences on the atmosphere due to interactions with other pools. Models of the global carbon cycle are being substantially refined while data that reflect the response of the cycle to fossil fuel use and other perturbations are being extended.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: JPL The interaction of Global Biochemical Cycles; p 55-84
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  • 72
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    A statistical correlation method for the retrieval of atmospheric moisture profiles by microwave radiometry (1984)
    In:  Other Sources
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    Publication Date: 2011-08-18
    Description: A statistical correlation technique is applied to the retrieval of vertical moisture profiles under clear-sky conditions from down-looking radiometric measurements of atmospheric radiation at microwave wavelengths. For a given set of channels, the method selects the optimum radiometric channels for estimating water vapor at specific pressure levels between the surface and 300 mb. The water vapor mixing ratio at these pressure levels is then calculated from a linear combination of the selected channel brightness temperatures. To test its validity the algorithm was applied, in a numerical experiment, to fifty independent tropical radiosondes. The rms absolute deviation of the estimated moisture profiles from the actual profiles was comparable to that obtained using an iterative retrieval method reported earlier. The statistical method, however, requires several orders of magnitude less computer time than the iterative method; it is suitable for high speed processing of large amounts of data.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Journal of Climate and Applied Meteorology (ISSN 0733-3021); 23; 1110-111
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  • 73
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    Problems in simulating the stratocumulus-topped boundary layer with a third-order closure model (1984)
    In:  Other Sources
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    Publication Date: 2011-08-18
    Description: The Andre et al. (1976, 1978) third-order closure model, in which the time rate of change terms, the relaxation and rapid effects for pressure-related terms, and the clipping approximation are used along with the quasi-normal closure, is invoked in the study of turbulence in a cloudy layer that is radiatively cooled from above. A spurious oscillation whose greatest amplitude lies near the inversion is shown by analysis to arise from the mean gradient and buoyancy terms of the triple-moment equations. An attempt is made to damp the oscillation through the introduction of diffusion terms into the triple-moment equations. The results obtained are noted to be sensitive to the ad hoc eddy coefficient applied in the third-moment equations.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Journal of the Atmospheric Sciences (ISSN 0022-4928); 41; 1588-160
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  • 74
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    Lightning activity and severe storm structure (1984)
    In:  Other Sources
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    Publication Date: 2011-08-18
    Description: Space-time mapping of VHF sources from four severe storms on June 19, 1980 reveals that lightning processes for cloud-to-ground (CG) and large intracloud (IC) flashes are confined to an altitude below about 10 km and closely associated with the central regions of high reflectivity. Another class of IC flashes produces a splattering of sources within the storms' main electrically active volumes and also within the large divergent wind canopy aloft. There is no apparent temporal association between the small high altitude IC flashes that occur almost continuously and the large IC and CG flashes that occur sporadically in the lower portions of storms.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Geophysical Research Letters (ISSN 0094-8276); 11; 545-548
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  • 75
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    A variational formulation for time-dependent climate models (1984)
    In:  Other Sources
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    Publication Date: 2011-08-18
    Description: A variational principle for time dependent diffusion problems is presented and is demonstrated by applying it to simple seasonal climate models. Two cases are treated. The first, a North-Coakley-type model with constant properties, is used as a tutorial example for the application of the technique. For the second case, heat capacity and thermal conductivity are considered to be latitude dependent in order to treat the effects of land/ocean distribution on the seasonal temperature distribution over the earth. The variational equations are derived and approximate analytical solutions are developed which delineate the influences of the physical asymmetries of the hemispheres in producing an asymmetric annual cycle.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Journal of Geophysical Research (ISSN 0148-0227); 89; 2601-260
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  • 76
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    Analogs in the wintertime 500 mb height field (1984)
    In:  Other Sources
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    Publication Date: 2011-08-18
    Description: Lorenz (1969) has considered the possibility that an atmospheric circulation pattern might recur, taking into account the definition of a pair of analogous flows or 'analogs'. The present investigation is concerned with a search of time series of Northern Hemisphere wintertime geopotential heights for possible analogs. Attention is given to data and analysis procedure, analog quality, and error growth rates. The obtained results imply that the found analogs are not a useful tool for forecasting the evolution of the midlatitude flow on time scales of several days. It is pointed out, however, that the negative results should not be extended to other applications of analog forecasting.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Journal of the Atmospheric Sciences (ISSN 0022-4928); 41; 177-189
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  • 77
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    Highlights of the Symposium on the Multiple-Parameter Radar Measurements of Precipitation - Personal reflections. (1984)
    In:  Other Sources
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    Publication Date: 2011-08-18
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Radio Science (ISSN 0048-6604); 19; 238-242
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  • 78
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    The small ice cap instability in diffusive climate models (1984)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: Simple climate models which invoke diffusive heat transport and ice cap albedo feedback have equilibrium solutions with no stable ice cap smaller than a radius of about 20 deg on a great circle. Attention is presently given to a solution of this phenomenon which is physically appealing. The ice-free solution has a thermal minimum, and if the minimum temperature is just above the critical value for ice formation, then the artificial addition of a patch of ice leads to a widespread depression of the temperature below the critical freezing temperature. A second stable solution will then exist whose spatial extent is determined by the range of the influence function of a point sink of heat, due to the albedo shift in the patch.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Journal of the Atmospheric Sciences (ISSN 0022-4928); 41; 3390-339
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    Comments on 'Comparative diagnostic case study of east coast secondary cyclogenesis under weak versus strong synoptic-scale forcing' (1984)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: A comment is presented on a recent paper by Pagnotti and Bosart (1984) which contrasted different forcing mechanisms for weak and strong cyclones along the east coast of the U.S., and Bosart replies. The comment argues that the paper did not give a clear definition of 'weak' upper-level forcing and did not provide sufficient evidence to support its claim that the return branch of transverse circulations may be coupled to the middle as opposed to the lower troposphere.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Monthly Weather Review (ISSN 0027-0644); 112; 2540
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  • 80
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    A numerical simulation of barotropic instability. II Wave-wave interaction (1984)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: A fully nonlinear numerical model of the point jet barotropic instability is used to test and confirm the hypothesis that the magnitude of the wave vorticity does not exceed the magnitude of the initial shear. This result arises directly from the local conservation of vorticity following a parcel and the fact that unstable waves are principally confined to the region where the zonal mean vorticity can be smoothed by the wave so as to eliminate the instability. Comparisons are made between fully nonlinear and quasi-linear models of the point jet instability and their tracer transport properties. Differences become particularly evident after wave saturation. The most important effect neglected by the wave-mean flow model appears to be the advection of wave vorticity by the most unstable mode. However, as equilibration of the instability proceeds, the globally averaged properties of both models are found to be similar.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Journal of the Atmospheric Sciences (ISSN 0022-4928); 41; 2869-288
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  • 81
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    Some aspects of the interannual variation of mean monthly sea level pressure on the Southern Hemisphere (1984)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: We calculate the seasonal changes that are largely associated with the half-yearly wave, autocorrelation functions, and the mean planetary waves in the monthly mean sea level pressure from two data sources. One covers the period from 1951 to 1958 (from the South African Weather Bureau) and the other the period from 1972 to 1980 (from the Australian Bureau of Meteorology). Thirty years of data from stations over the southern hemisphere are used to assess the reliability of the differences between the two periods that the grid-point data show. These differences are especially large over the Atlantic Ocean and the Pacific Ocean. The station data confirm the changes between the two periods and thus the observed differences in the mean waves, which are especially large for wave number 3.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Journal of Geophysical Research (ISSN 0148-0227); 89; 9541-954
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  • 82
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    GASP cloud encounter statistics - Implications for laminar flow control flight (1984)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: The cloud observation archive from the NASA Global Atmospheric Sampling Program (GASP) is analyzed in order to derive the probability of cloud encounter at altitudes normally flown by commercial airliners, for application to a determination of the feasability of Laminar Flow Control (LFC) on long-range routes. The probability of cloud encounter is found to vary significantly with season. Several meteorological circulation features are apparent in the latitudinal distribution of cloud cover. The cloud encounter data are shown to be consistent with the classical midlatitude cyclone model with more clouds encountered in highs than in lows. Aircraft measurements of route-averaged time-in-clouds fit a gamma probability distribution model which is applied to estimate the probability of extended cloud encounter, and the associated loss of LFC effectiveness along seven high-density routes. The probability is demonstrated to be low.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Journal of Aircraft (ISSN 0021-8669); 21; 851-857
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  • 83
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    Vertical temperature sounding of the atmosphere (1984)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: Attention is given to physical principles that affect the determination of atmospheric temperature profiles from observations of outgoing IR and microwave radiation. Simultaneous analysis of IR and microwave observations enhances observations in each spectral region. While IR soundings have higher sensitivity to lower tropospheric temperatures, ground temperatures, and sea surface temperatures, microwave observations are not only more suited to stratospheric sounding but are sensitive to snow and ice cover. They significantly aid correction of IR observations for cloud effects. Because effective cloud parameters and snow and ice cover can be inferred from the observations, 'temperature sounders' also yield data for a number of important climatic parameters.
    Keywords: METEOROLOGY AND CLIMATOLOGY
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  • 84
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    Role of soil moisture in maintaining droughts (1984)
    In:  Other Sources
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    Publication Date: 2011-08-18
    Description: The influence of soil moisture on the persistence of an ongoing drought was investigated. The case study of drought of the summer of 1980 was selected. The difference in the simulation of two identical twin runs: one with the climatological normal soil moisture and the other with anomalous soil moisture for drought conditions, were examined on the mean monthly circulation. It is found that a reduction in soil moisture did produce a corresponding reduction in precipitation. The pattern of the rainfall anomaly however, was not identical to the soil moisture (evapotranspiration) anomaly but had a good resemblance with observations.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Res. Rev., 1983; p 335-340
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  • 85
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    The sensitivity of a general circulation model to Saharan dust heating (1984)
    In:  Other Sources
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    Publication Date: 2011-08-18
    Description: During the Northern summer, sporadic outbreaks of wind borne Saharan dust are carried out over the Atlantic by the tropical easterlies. Optical depths due to the dust can reach 3 near the African coast, and the dust cloud can be detected as far west as the Caribbean Sea (Carlson, 1979). In order to obtain insight into the possible effects of Saharan dust on the weather and climate of North Africa and the tropical Atlantic Ocean, simulation experiments have been performed with the Climate Model of the Goddard Laboratory for Atmospheric Sciences. The most recent version of the model is described by Randall (1982). The model produces realistic simulations of many aspects of the observed climate and its seasonal variation.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Res. Rev., 1983; p 3323-328
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  • 86
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    Climate sensitivity with a seasonal cycle energy balance model (1984)
    In:  Other Sources
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    Publication Date: 2011-08-18
    Description: The sensitivity of climate which may have a local maximum as the ice cap passes through a midlatitude region where the atmosphere's transport efficiency varies strongly with latitude is examined. This behavior, found in a two level primitive equations climate model forced with annual mean insolation, was reproduced in an energy balance model (EBM) by making the diffusion coefficient a function of latitude. The two level seasonally varying EBM was applied and the global mean surface temperature vs. solar constant for this model are shown and two regions of enhanced sensitivity appear. The snowcover distributions around the year for three cases are shown.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Res. Rev., 1983; p 227-230
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  • 87
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    On the role of the transient eddies in maintaining the seasonal mean circulation (1984)
    In:  Other Sources
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    Publication Date: 2011-08-18
    Description: The role of transient eddies in maintaining the observed local seasonal mean atmospheric circulation was investigated by examining the time-averaged momentum balances and omega equation, using seasonal statistics calculated from daily operational analyses by the European Centre for Medium Range Weather Forecasts. While both the Northern and Southern Hemispheres and several seasons were studied, emphasis was placed upon the Northern Hemisphere during December 1981-February 1982. The results showed that transient eddies played a secondary role in the seasonal mean zonal momentum budget and in the forcing of seasonal mean vertical and a geostrophic motion.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Res. Rev., 1983; p 205-208
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  • 88
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    Teleconnection patterns in the Southern Hemisphere (1984)
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    Publication Date: 2011-08-18
    Description: Contemporaneous correlations between geopotential heights on a given pressure surface at widely separated points on Earth, commonly referred to as teleconnections, are calculated from monthly mean sea level pressure and 500 mb geopotential height analyses for the Southern Hemisphere for five-month winter and summer seasons. During summer (November-March), anomalies over the three continents occur out of phase with anomalies over the subtropical oceans and in a wavenumber 3 pattern over the Southern Ocean near 55 deg S. The subtropical part of the pattern appears largely associated with the interannual variation of the seasonal cycle and annual mean. In winter (May-September) 500 mb geopotential heights over Africa exhibit positive correlations with heights over South America and the central South Pacific near New Zealand and negative correlations with height over the Southern Ocean. A striking wavenumber three pattern is apparent which shows the correlation of 500 mb geopotential height anomalies with 500 mb anomalies at 50 deg S, 95 deg E during winter. The strong positive correlations between 50 deg S, 95 E and 58 deg S, 150 deg W and 38 deg S, 15 deg W contrast with negative correlations over Antarctica and in low latitudes. Time variations in a similar pattern in sea level pressure are in phase with variations in the 500 mb pattern, suggesting an equivalent barotropic structure.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Res. Rev., 1983; p 193-195
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  • 89
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    Localized blocking accounted for by slow variations of the zonal driving (1984)
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    Publication Date: 2011-08-18
    Description: The incorporation of observed zonal topography in a barotropic nonlinear channel model is discussed. The model is then extended to explain the regional features of blocking by employing a two scale method to allow small slow variations of the momentum (zonal) driving.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Res. Rev., 1983; p 190-192
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  • 90
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    Stratocumulus simulations with a general circulation model (1984)
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    Publication Date: 2011-08-18
    Description: Stratus and stratocumulus cloud sheets which are among the most common cloud types over the world are discussed. They are characteristic of the undisturbed subtropical marine boundary layer over the eastern oceans, where cool water and large scale sinking motion suppress penetrative cumulus convection. They also occur over the Arctic Ocean, particularly in summer, and behind cold outbreaks over the western oceans in winter. Observational studies were conducted and further observations are planned.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Res. Rev., 1983; p 222-226
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  • 91
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    Influence of surface roughness of a desert (1984)
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    Publication Date: 2011-08-18
    Description: A numerical simulation study, using the current GLAS climate GCM, was carried out to examine the influence of low bulk aerodynamic drag parameter in the deserts. The results illustrate the importance of yet another feedback effect of a desert on itself, that is produced by the reduction in surface roughness height of land once the vegetation dies and desert forms. Apart from affecting the moisture convergence, low bulk transport coefficients of a desert lead to enhanced longwave cooling and sinking which together reduce precipitation by Charney's (1975) mechanism. Thus, this effect, together with albedo and soil moisture influence, perpetuate a desert condition through its geophysical feedback effect. The study further suggests that man made deserts is a viable hypothesis.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Res. Rev., 1983; p 329-334
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  • 92
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    Two contrasting Northern Hemisphere winters: 1980 - 1981 and 1981 - 1982 (1984)
    In:  Other Sources
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    Publication Date: 2011-08-18
    Description: Seasonal statistics calculated from daily operational analyses by the European Centre for Medium Range Weather Forecasts for December 1980 - February 1981 (season 1) and December 1981 - February 1982 (season 2) were used to contrast the two seasonal mean circulation patterns present in the Northern Hemisphere and to investigate possible causes for the differences. The vertically averaged seasonal mean zonal wind and E-vector, a measure of the anisotropy of the transient eddies over the Pacific is shown for season 1 and season 2. The pattern in season 2, but not season 1, resembles that found in a modeling study of barotropic instability. One possible explanation for the differences between season 1 and 2 is a weak change in tropical heating associated with the southern oscillation, the effect of which in midlatitude was amplified by the occurrence of barotropic instability over the Pacific in season 2, but not season 1.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Res. Rev., 1983; p 209-214
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  • 93
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    An ensemble formulation of PBL fluxes in a GCM (1984)
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    Publication Date: 2011-08-18
    Description: An ensemble approach is applied to Planetary Boundary Layer (PBL) calculations with the bulk Richardson number identified as the key parameter. An ensemble averaging calculation was carried out to rederive the bulk friction and heat transport coefficients for the mean condition. Two simulations are carried out and compared. Significant differences in PBL fluxes low level cloudiness, land surface roughness heights, and surface evaporation are noted between the modified and unmodified simulations. Modifications to the model were: (1) the relationship between actual and potential Effective Temperature (ET) to accord with Sud and Fennessy (1982); (2) maximum permissible instantaneous ET at any time is 1.5 mm per hr; (3) moisture distribution in low level cumulus convection to be consistent with no precipitation; (4) appearance of supersaturation clouds to be consistent with supersaturation condition at that level; (5) invoking a simple function for stomatal diffusion effect in the ET calculation.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Res. Rev., 1983; p 270-274
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  • 94
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    Theoretical studies: Radiation, clouds, transport (1980)
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    Publication Date: 2011-08-19
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: NASA, Washington Upper Atmosphere Res. Program; p 161-162
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  • 95
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    Comments on 'Inference of cloud temperature and thickness by microwave radiometry from space' (1984)
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    Publication Date: 2011-08-19
    Description: The method proposed by Pandey et al. (1983) for estimating the temperature differential and thickness of clouds from microwave data obtained with the scanning multichannel microwave radiometers of the Seasat and Nimbus-7 satellites is examined critically. It is pointed out that both the thicknesses and the temperature differentials derived from them may not be meaningful unless accurate measurements of cloud-top height (from IR radiometry) and reliable data on liquid-water content are available. It is suggested that the good fits obtained in generating regression coefficients for the proposed method may be artifacts of the fixed or limited-range liquid-water densities of the cloud models used. With respect to cloud-top height, the need to quantify and account for differences in the fields of view and spatial resolutions of the IR and microwave radiometers, as undertaken for the case of precipitating clouds by Yeh and Liou (1983), is stressed.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Journal of Climate and Applied Meteorology (ISSN 0733-3021); 23; 1579
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  • 96
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    The diurnal variation of Atlantic Ocean tropical cyclone cloud distribution inferred from geostationary satellite infrared measurements (1984)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Monthly Weather Review (ISSN 0027-0644); 112; 2338-234
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  • 97
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    Delineating mid- and low-level water vapor patterns in pre-convective environments using VAS moisture channels (1984)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: Infrared and visible imagery from VAS are used to delineate mid- and lower-tropospheric moisture fields for a variety of severe storm cases in the southern and central United States. The ability of sequences of images to isolate areas of large negative vertical moisture gradients and apparent convective instability prior to the onset of convective storms is assessed. A variety of image combination procedures are used to deduce the stability fields which are then compared with the available radiosonde data. The results for several severe storm cases indicate that VAS can detect mid- and low-level mesoscale water vapor fields as distinct radiometric signals. The VAS imagery shows a strong tendency for thunderstorms to develop along the edges of bands of midlevel dryness as they overtake either preexisting or developing low-level moisture maxima. Image sequences depict the speed with which deep moist and dry layers can develop and move.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Monthly Weather Review (ISSN 0027-0644); 112; 2178-219
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  • 98
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    Stratocumulus cloud field reflected fluxes - The effect of cloud shape (1984)
    In:  Other Sources
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    Publication Date: 2011-08-19
    Description: The reflected fluxes of stratocumulus cloud fields are calculated as a function of sky cover aspect ratio and cloud shape. In order to obtain a better fit with general circulation models (GCMs), cloud liquid water volume values were kept invariant relative to cloud shape. On the basis of the required accuracy of the Earth Radiation Budget Experiment (ERBE), an order of magnitude value of 10 W per sq m was used to estimate the difference between plane-parallel and broken cloudiness reflected fluxes. An empirical relationship for effective cloud cover at a solar zenith angle of 60 deg is derived. The relationship allows for the accurate computation of broken cloud field reflected fluxes using plane-parallel calculations. It is predicted that more accurate estimates of broken cloud field radiative properties may be possible in the future.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Journal of the Atmospheric Sciences (ISSN 0022-4928); 41; 3085-310
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  • 99
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    On the dynamics of stratocumulus formation and dissipation (1984)
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    Publication Date: 2011-08-19
    Description: Results obtained with a mixed layer model are used to study the dynamics of stratocumulus formation and dissipation in subtropical marine stratocumulus cloud regimes. The model used allows entrainment to be driven by shear as well as buoyancy, and includes a very crude parameterization of the partial blackness of thin cloud layers. Model results show that for some values of the large-scale divergence there are three equilibrium mixed layer structures, two of which are stable. One of the stable equilibria is cloudy, deep, and buoyancy-driven, while the other is clear, shallow, and shear-driven. It is found that as a result of hysteresis effects a transient increase in the large-scale divergence can produce a long-lasting break in the clouds.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Journal of the Atmospheric Sciences (ISSN 0022-4928); 41; 3052-305
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  • 100
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    Modeling the middle atmosphere circulation (1984)
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    Publication Date: 2011-08-19
    Description: Some of the motivations for constructing models of the middle atmosphere circulation are given. These are as follows: (1) to provide a better understanding of middle atmosphere dynamics; (2) to study the coupling of middle atmosphere dynamics with radiation and chemistry; (3) to study the sensitivity of tropospheric climate modeling and/or weather forecasting to changes in the middle atmosphere; (4) to better understand the limitations of more simplified models; (5) to supply a proxy for atmospheric data for diagnostic analysis; and finally, (6) for forecast-analysis of data. Different types of models are discussed in relation to their anticipated use. Various model simplifications, such as using the quasi-geostrophic set of equations and simplified radiative transfer, are discussed as are some of the consequences of these simplifications. Some of the accomplishments of middle atmosphere circulation modeling are presented as are some of the difficulties in existing models. Finally, some of the problems in constructing and verifying middle atmosphere circulation models are discussed.
    Keywords: METEOROLOGY AND CLIMATOLOGY
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