ALBERT

Description: Using the fault plane mechanisms of the shallow earthquakes occurring along the Hellenic arc and the extent of the intermediate seismic belt, we make a quantitative estimate of the relative motion occurring between the Hellenic arc and the adjacent sea floor. This estimate is then used to evaluate the deformation in the Aegean area and to reconstruct the pattern of motion over the Eastern Mediterranean region for the last 13 m.y. It is shown that this pattern is compatible with the neotectonic and seismicity studies in Aegea. We then discuss the dynamics of the area and propose that, since Serravallian-Tortonian time, Aegea has been spreading gravitationally in front of the southwestward advancing Turkey. The reasons for this gravitational spreading are discussed.

Description: Data gathered by recent “Islas Orcadas” cruises reveal the seafloor spreading pattern for a region south of the Agulhas/Falkland fracture zone system. The presence of a magnetic anomaly bight about the Agulhas Plateau indicates that the Agulhas Plateau may have developed at the site of a tectonic plate triple junction during the Late Cretaceous. A westward jump in the seafloor spreading center during the Late Maestrichtian (anomaly 34−31) reduced the offset across the Falkland/Agulhas fracture zone system and resulted in the formation of two conjugate aseismic ridges here described as the Meteor and Islas Orcadas Rises. The magnetic lineation pattern in the Agulhas Basin suggests that a tectonic plate (Malvinas Plate) existed during Campanian to Maestrichtian times. Relative rates of motion are calculated for Antarctica, South America, and Africa for the Late Cretaceous.

Description: This chapter discusses the carbon turnover, calcification, and growth in coral reefs. Carbon turnover within a total reef community is a function of two distinct, biochemically interacting cycles. The first is the metabolic cycle consisting of the photosynthetic fixation of CO2 and the release of CO2 by respiration and decomposition processes. Superimposed on this are the direct incorporation of organic compounds (dissolved or particulate; living or non-living) originating outside the reef systems (in the adjacent ocean waters), and the loss of organic compounds from the reef system into the out-flowing water. The second is the inorganic carbonate cycle involving the biological and non-biological precipitation and dissolution of carbonates. Superimposed on this is the loss of particulate carbonates in suspension in the out-flowing water. The main chemical component of a coral-reef system is calcium carbonate, which occurs either as high-Mg calcite, aragonite, or low-Mg calcite. The mean calcification values in various environments at One Tree Reef are presented in the chapter. These data may be converted to an implied vertical growth rate potential assuming that accrual is dominantly aragonite (density = 2.89 g cm–3) and that there is 50% porosity after normal compaction.

Description: Squids (teuthoids) fall into two distinct groups according to their density in sea water. Squids of one group are considerably denser than sea water and must swim to stop sinking; squids in the other group are nearly neutrally buoyant. Analyses show that in almost all the neutrally buoyant squids large amounts of ammonium are present. This ammonium is not uniformly distributed throughout the body but is mostly confined to special tissues where its concentration can approach half molar. The locations of such tissues differ according to the species and developmental stage of the squid. It is clear that the ammonium-rich solution are almost isosmotic with sea water but of lower density and they are present in sufficient volume to provide the main buoyancy mechanism of these squids. A variety of evidence is given which suggests that squids in no less than 12 of the 26 families achieve near-neutral buoyancy in this way and that 14 families contain squids appreciably denser than sea water [at least one family contains both types of squid]. Some of the ammonium-rich squids are extremely abundant in the oceans.

Description: Microbial decomposition of organic matter in recent sediments of the Landsort Deep—an anoxic basin of the central Baltic Sea—resulted in the formation of a characteristic assemblage of authigenic mineral precipitates of carbonates, sulfides. phosphates and amorphous silica, The dominant crystalline phases are a mixed Mn-carbonate [(Mn0.85Ca0.10Mg0.05)CO3]. Mn-sulfide [MnS] and Fecarbonate [FeCO3]. Amorphous Fe-sulfide [FeS]. Mn-phosphate [Mn3(PO4)2] and a mixed Fe-Ca-phosphate [(Fe0.86Ca0.14)3(PO4)2] were identified by their chemical compositions only. The variability in composition of these solid phases and their mode of occurrence as a co-existing assemblage constrains the conditions and solution composition from which they precipitated. Estimates of activities for dissolved Fe. Mn. PO4, CO3 and S in equilibrium with such an assemblage are close to those found in recent anoxic interstitial water-sediment systems. It is important to have detailed knowledge of the composition and stability conditions of these solid precipitates in order to refine stoichiometric models of interstitial nutrient regeneration in anoxic sediments.

Description: Goban Spur lies on the continental margin of northwest Europe, southwest of Ireland. It is a marginal plateau underlain by Hercynian granites and Palaeozoic sediments, which form large horsts, grabens and tilted fault blocks with a trend that is approximately parallel to the main Celtic/Armorican Shelf edge. The spur is thought to be a westward continuation of the buoyant Cornubian Ridge, and is bounded to the north and south by large fault lines which probably represent reactivation of Hercynian structural trends. The continental basement is further divided longitudinally into a low-lying outer zone (Intermediate Zone) and a high inner region (Goban Spur proper). The ocean/continent boundary is thought to lie at the outer edge of the Intermediate Zone, Sea-floor spreading anomalies immediately west of the Intermediate Zone suggest that the adjacent ocean crust was created prior to anomaly 33 (say at ca. 90 m.y. B.P.). The sedimentary sequence on Goban Spur can be subdivided into four layers which can be tentatively correlated with the stratigraphic succession on the Meriadzek Terrace (IPOD sites). Such a correlation suggests that the lowermost sediment layer (?Jurassic-Albian) represents a tectono-sedimentary rift infill, and that Layers 2–4 (Upper Cretaceous to Quaternary) were deposited during slow epeirogenic downwarping of the plateau and that the sedimentary processes involved both draping and strong current moulding. The relatively buoyant nature of Inner Goban Spur has inhibited the accumulation of a thick post-rifting sedimentary sequence (700–1000 m), and has shielded the Intermediate Zone from downslope mass movements of material. This has resulted in the accumulation of an anomalously thin post-rift stage outer margin sediment prism (ca. 1000 m) compared to most continent rises (up to 10 km).

Description: A bathymetric map of the deep-sea floor off southeastern Africa shows the Agulhas Plateau to be separated from the continental margin of southeastern Africa by a narrow (50 km) elongate depression, the Agulhas Passage, which acts as a deep-water connection between the Agulhas and Transkei basins. Three regionally developed sediment layers occur in the deep (〉 4500 m) Transkei Basin/Agulhas Passage area. With the aid of a simple ocean crust sinking/carbonate compensation level (CCL) model these layers are related to the sedimentation history of the area. The model suggests that acoustic basement (Horizon X) represents Lower Cretaceous limestones draped over oceanic basement, and that this is overlain by an acoustically transparent sequence of pelagic/terrigenous material (Horizon A) that was deposited during a lengthy period (95 m.y.) beneath the carbonate compensation level. Post-Late Miocene sedimentation (Horizons B and C) has probably taken place above the CCL. Local sedimentation has always been influenced by strong sea-floor currents, but since middle Palaeogene times these currents have operated on a regional scale and have generated numerous large ridge and billow-like bed forms.

Description: Deep sea sediments contain more Cu, Ni, Ba, B etc., than transport of detrital terrigenous matter (TM) can explain. Longdistance transport in dissolved from is of no importance for many of these elements. Marine biological matter (BM) is enriched in Cu, Ni, Ba, B etc. Conservative mixing models, using BM and TM as inputs show that the compositional variations in pelagic sediments can be explained by these sources. Such mixing models have been used to estimate how the influx of BM and TM have varied with time, and to what extent different elements ares upplied by BM and TM. The results show that in Cenozoic Equatorial Pacific sediments CaCO₃, opaline silica, B, Ba, and Cu are predominantly biogenous. It is probable that also P and Ni belong to this group of elements, whereas almost all Al, Ti, Zr, V and Mn are delivered by TM or some volcanic processes. The accumulation rates (AR) for the biological constituents reached maxima during the L. Oligocene and the Miocene, and minima during the U. Oligocene and the Pleistocene; some AR from the Oligocene and the Miocene being 3-6 times higher than at present. The accumulation rate patterns for opaline silica, Ba and B co-vary, whereas the AR for CaCO₃ show another time dependance pattern. These AR-patterns are probably partly due to climatic variations. Plankton in Pacific Equatorial waters incorporate much more Cu, Ni, etc., than is required for the particulate transport of these elements to the ocean floor. This suggests that transport in particulate form of BM is an important source of Cu, Ba, B, etc. for the deep sea floor.

Description: Several tissues (e.g. kidney, blood, digestive gland) in oceanic cephalopods which do not exhibit in vivo bioluminescence, luminesce when homogenized in the presence of air or when simply exposed to air in a vial (blood). The source of the luminescence appears to be a luciferin: treatment of kidney homogenates and blood with a photophore extract presumably containing luciferase resulted in a 20-fold increase in light production. Luminescence was also found in the renal fluid, which may be the source of luminescent clouds produced by squids. The variability in luminescence found in some tissues of cephalopods appeared to be related to feeding. Luminescence was also detected in the digestive glands of midwater octopods.

Description: The means of detecting downwelling light for counterillumination in several midwater animals has been examined. Eyes and extraocular photoreceptors (drosal photosensitive vesicles in the enoploteuthid squid Abraliopsis sp. B and pineal organs in the myctophid fish Myctophum spinosum) were alternately exposed to overhead light or covered by a small opaque shield above the animal and the bioluminescent response of the animal was monitored. Covering either the eyes or the extraocular photoreceptors resulted in a reduction in the intensity of counterillumination. Preliminary experiments examining the bioluminescent feedback mechanism for monitoring intensity of bioluminescence during counterillumination in the midwater squid Abralia trigonura indicated that the ventral photosensitive vesicles are responsible for bioluminescent feedback.

Description: Infrared and Mössbauer spectroscopy show that the extent of the reduction of nontronite is dependent on the chemical composition of the nontronite and on the nature of the reducing agent. Hydrazine reversibly reduces about 10% of the iron in all of the nontronites studied irrespective of composition and it is suggested that the resulting ferrous iron occurs only in distorted octahedral sites. Similar conclusions are reached for the dithionite reduction of the nontronites containing little tetrahedral iron, but for those with more than one in eight silicons replaced by iron, changes brought about by dithionite treatment are irreversible due to dissolution of appreciable quantities of iron. Results from both spectroscopic techniques suggest that iron in tetrahedral sites is preferentially dissolved and that up to 80% of the structural iron can be reduced. Evidence is presented for the formation in these extensively reduced nontronites of a small amount of a mica-like phase resembling celadonite or glauconite, and, as dithionite is used for the pretreatment of soils, the implication of this observation is briefly discussed. The use of deuterated hydrazine as a reducing agent has enabled the nontronite absorption band near 850 cm-1 to be assigned to a Si-O (apical) stretching vibration, which is inactive in the infrared for perfect hexagonal symmetry, but which is activated by distortions in the tetrahedral layer

Description: An estimate of average river particulate matter (RPM) composition was bàsed on analyses of more than 40 elements in the Amazon, Congo, Ganges, Magdalena, Mekong, Parana and Orinoco rivers, to which were added literature data for 13 other major world rivers, covering the whole spectrum of morphoclimatic features. Geographic variations of major elements in RPM are mostly linked to weathering types and to the balance between weathering rate and river transport. As a result of chemical erosion, Al, Fe and Ti are enriched in RPM with respect to the average parent rock, while Na, Ca, Mg and Sr are strongly depleted. These figures are directly related to the relative importance of dissolved and particulate transport in rivers; this has been computed for each of 40 elements. In order to study weathering on a global scale, the total observed elemental fluxes (dissolved + particulate) have been computed and compared to theoretical ones. The latter were derived from the elemental content in the average parent rock and the total quantity of weathered material, computed from the Al ratio in RPM and in parent rock. Observed and theoretical fluxes are balanced for the less mobilized elements (rare earths, Co, Cr, Cs, Fe, Mn, Rb, Si, Th, Ti, U and V) for which no enrichment relative to Al is noted in RPM, and for B, Ba, Ca, K, Mg, Na, Sr which are relatively depleted in RPM due to their high dissolved transport. Additional fluxes have been found for Br, Sb, Pb, Cu, Mo, Zn and are possible also for Ni and P. This is reflected by marked enrichments in RPM relative to Al for the poorly or moderately dissolved transports (Pb, Cu, Zn). Several hypotheses involving either the natural origin (volcanic dust, marine aerosols, geochemical fractionation) or the artificial origin (worldwide pollution) are discussed to explain these discrepancies, assuming river transport and weathering either to be in a steady state on a global scale or not. However, none of them can fully account for these additional fluxes. It is most likely that these excesses have multiple origins, anthropogenic or natural or both. The comparison between RPM and deep-sea clay compositions emphasizes the prime influence of river input on oceanic sedimentation of Si, Al, Fe, Ti, lanthanides, Sc, Rb, V, etc. A few elements such as Zn, Sb, occur in excess in RPM as compared to deep-sea clays; in order to balance this excess, a remobilization of these elements out of the sediment can be considered. Finally, the enrichment of Co, Cu, Mn and Ni in deep-sea clays compared to RPM is discussed and attributed to several sources and processes.