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  • Articles  (57,134)
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  • 2010-2014
  • 2005-2009  (25,346)
  • 1985-1989  (16,154)
  • 1975-1979  (15,634)
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  • 1
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    Circuits, systems and signal processing 6 (1987), S. 363-387 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract For a broad class of interconnected nonlinear systems, this paper develops a complete design methodology for decentralized variable structure control. Specifically, the paper sets forth design schemes for local switching surfaces and the related local switched feedback gains which together force the original nonlinear interconnected system to behave as a reduced order interconnected equivalent system having a desired response such as stability, tracking, or prespecified eigenvalues. Also developed is a numerical algorithm for constructing the switched local feedback gains. A simple nonlinear example illustrates the control strategy.
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  • 2
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    Circuits, systems and signal processing 6 (1987), S. 391-419 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract A new stabilization method of a large-scale dynamic system, consisting of a set of interconnected subsystems, is presented in this paper. The topology of the interconnected subsystems is given as a network containing nodes with only one ingoing link, and none, one, or more outgoing links. Here, when the notion “node” is used a subsystem is assumed, and the links stand for the subsystem interconnections. The stabilization method is made only by the use of local linear state feedback around each subsystem, in order to satisfy constraints given in the problem. The interconnections among the subsystems are assumed to be nonlinear, time-varying. According to the topology of the large-scale system, the method of stabilization is hierarchic, one proceeds from node to node, and is applicable from a computer standpoint. A design algorithm follows directly, and can be made using the Generate and Test method for each subsystem independently, thus enabling designers to use a computer which has a video terminal as a peripheral unit and providing a possibility for interactive applications.
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  • 3
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    Circuits, systems and signal processing 6 (1987), S. 421-447 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The estimation of covariance matrices which are structured, for example, of Toeplitz type, from measurement data is considered. The problem is considered in the context of array beamforming, and various methods of estimation are derived and compared, such comparison including consideration of the behavior of the estimate in beamforming applications.
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  • 4
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    Circuits, systems and signal processing 6 (1987), S. 449-456 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The planar least-squares inverse (PLSI) polynomials are used for stabilization of two-dimensional unstable recursive filters. In order to obtain the PLSI polynomials, the main work involved consists in forming a set of linear equations and then solving them. In this paper we present an efficient and simple method to form the necessary set of linear equations (i.e., the required coefficient matrix) for a chosen pattern and order of the desired PLSI polynomial, starting from the denominator polynomial of a two-dimensional unstable recursive filter.
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  • 5
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    Circuits, systems and signal processing 6 (1987), S. 347-362 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract This paper shows how to use orthogonal functions to invert singular (i.e., generalized state-space) systems. The approach is to express the inverse system itself as a singular system, and then to apply the theory of orthogonal functions to convert that differential-algebraic system to a purely algebraicgeneralized Lyapunov equation whose solution yields the input of the original system given its output. Both left and right inversion are treated. Necessary and sufficient conditions for the existence and uniqueness of the generalized Lyapunov equation are derived, and a generalizedQZ algorithm is given for its efficient solution. It is also shown that the coefficients in the Walsh function expansion may be approximately found using an FFT-type butterfly network. These results provide both an extension in theory, by investigating the properties of a new Lyapunov equation, and an extension in the implementation of system inversion, by providing a scheme which applies to generalized state-space systems and uses an unconventional approach which may prove to be a useful contribution.
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  • 6
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    Circuits, systems and signal processing 6 (1987), S. I 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
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  • 7
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    Circuits, systems and signal processing 6 (1987), S. 457-470 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract In digital communication networks, a special class of complex biquad recursive digital filters called orthogonal filters is increasingly being used. The separate effects of the overflow and quantization nonlinearities on these orthogonal filters' responses have been investigated [5], [6]. In this paper we examine the zero-input stability properties of the actual orthogonal filter having both overflow and quantization nonlinearities. The overflow nonlinearities considered include saturation, bit-by-bit inversion, zeroing, and modulo 2 arithmetic. The quantization techniques used may be roundoff, magnitude, or value truncation. An example demonstrates the adverse coupling effect between the overflow and quantization nonlinearities. Two criteria are therefore derived to ensure asymptotic overflowstability of the filter in the presence of quantization. These criteria have been translated to the coefficient plane; various regions corresponding to different minimum wordlengths required to ensure decoupling of the overflow and quantization phenomena have been derived.
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  • 8
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    Circuits, systems and signal processing 6 (1987), S. 471-505 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The identification problem for electromagnetic objects excited by transients is discussed. Several classes of models are reviewed, and an output error model is selected. An algorithm for solving the transient identification problem using this model is presented, and some of the issues connected with its use are considered. Examples of the application of this algorithm to electromagnetic data are given.
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  • 9
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    Circuits, systems and signal processing 6 (1987), S. 3-30 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Conditions are obtained for the cepstrum of anl 1 sequence having arbitrary support on theM-dimensional lattice to exist also as anl 1 sequence with arbitrary support. These conditions are used to show that the cepstrum of a sequence with support on a half-space will, when it exists, also have support on the same half-space. This result is used, in turn, to describe the support of the cepstrum of a sequence with bounded support on a half-space. The relationship between the existence of the cepstrum and bounded-input, bounded-output (BIBO) stability for all three of these cases is considered. Finally, the derivatives of the inversion operator, the homomorphic transform operator, and its inverse are calculated. These results are also useful in the one-dimensional case.
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  • 10
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    Circuits, systems and signal processing 6 (1987), S. 31-43 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract A signal-processing software system is described which allows the simulation of systems described by block diagrams or signal-flow graphs. A high-level data-flow language describes the interconnection of the components. All configurations of interconnections are allowed, including those containing feedback. Component systems (blocks) are allowed to be multi-input, multi-output, and to be programmed in any language. Blocks are implemented as separate processes running under a UNIX2 operating system. Input and output signals are transferred between blocks via the UNIXpipe facility. Thedata type of a signal is arbitrary in the context of the compiler; within a component or system, signals and internal variables can be either floating point or fixed point. The compiler enforces strong or weak type checking of signals according to the characteristics of the blocks generating and receiving the signals. The invariance of the program to implementation data type is accomplished by the use of abstract data types. Fixed-point simulations having differing number of bits per signal and per internal variable in a block are supported. Special display software is used to allow any signal in the system to be displayed on any graphics device.
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  • 11
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    Circuits, systems and signal processing 6 (1987), S. 61-75 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Necessary and sufficient conditions are given for the solvability of fully implicit index-one and semiexplicit index-two linear time-varying semistate systems of the formA(t)x′+B(t)x=f(t). Using these solvability criteria, we establish the convergence and stability of backward difference formulas (BDF) for solvable semiexplicit index-two systems. In the algebraic variables, these methods exhibit a boundary layer of instability of length 2k, wherek is the order of the method. Finally, we show that the systems considered in this paper belong to a class of problems, solvable by BDF, which strictly contains the systems safely transformable to standard canonical form.
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  • 12
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    Circuits, systems and signal processing 6 (1987), S. 45-60 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The design of two-dimensional IIR digital filters is approached using linear-programming techniques. The problem is formulated as an approximation problem and filter frequency response characteristics are represented via the square of the magnitude of the filter transfer function. An appropriate approximation error is minimized leading to a linear problem formulation. The latter problem does not require differential correction methods for its solution, thus resulting in a computationally efficient algorithm. Stability conditions and symmetry considerations are easily accounted for. The linear programming approach assures convergence of the solution to a global minimum, among other advantages over nonlinear methods. Several examples illustrate the strength and effectiveness of the methodology.
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  • 13
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    Circuits, systems and signal processing 6 (1987), S. 77-93 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Necessary and sufficient conditions for output and state feedback stabilization are given for single-input/single-output systems. Extensions are also provided for single-input/multi-output and multi-input/single-output systems. A technique for constructing explicitly a stabilizing controller is presented, and the main differences with respect to the one-dimensional case are clarified. Finally, the existence of “intrinsically unstable” transfer functions, i.e., not allowing stabilizable realizations, is discussed.
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  • 14
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    Circuits, systems and signal processing 6 (1987), S. 95-106 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract A single-parameter controlled-variable amplitude change function has been constructed for digital filtering using multiple units of a prototype filter. The limits of variation are discussed. The technique is shown to be useful not only for the reduction of errors in either the pass band or the stop band of the overall filter, but also for varying the cutoff frequency of the overall filter over a wide range. Hardware implementation problems resulting from a wide variation are shown to be overcome by a modular approach.
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  • 15
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    Circuits, systems and signal processing 6 (1987), S. 125-126 
    ISSN: 1531-5878
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    Topics: Electrical Engineering, Measurement and Control Technology
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  • 16
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    Circuits, systems and signal processing 6 (1987), S. 123-123 
    ISSN: 1531-5878
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    Topics: Electrical Engineering, Measurement and Control Technology
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  • 17
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    Circuits, systems and signal processing 6 (1987), S. 107-119 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract This paper considers the problem of estimating the parameters of continuous-time stationary Gaussian processes with rational spectra, from uniformly sampled measurements. The sampled process is shown to be an autoregressive moving-average process, and explicit relationships between the parameters of the continuous-time and the sampled processes are derived. These relationships are then used to derive a lower bound on the variances of biased estimates of the continuous-time parameters, and on the generalized variance of such estimates. It is shown by some examples that the bound on the generalized variance depends on the sampling interval in a nonmonotonic manner. In particular, for each specific set of parameters there exists a sampling interval for which the lower bound is minimized.
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  • 18
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    Circuits, systems and signal processing 6 (1987), S. 127-137 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The identification of concurrency is a critical factor in the high-speed calculation of algorithms. This study considers maps onX, a discrete resolution space. We establish a resolution on the space of linear maps onX which exhibit compatibility with array processing. Our results are extended to the partially ordered resolution space setting. While on-line array processing motivates our study, the results also suggest efficient processing procedures for off-line applications.
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  • 19
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    Circuits, systems and signal processing 6 (1987), S. 139-151 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract This paper describes a method for designing systolic structures with bit-level pipelining. The proposed technique starts with the signal flow graph representation of a given algorithm. A new signal flow graph rule, called the gain transfer rule is introduced to achieve bit-level pipelining. Using this approach, systolic arrays with bit-level pipelining are derived for a general recursive digital filter and a convolver. The proposed technique is quite general and has also been applied to obtain systolic structures for other problems such as vector transformation. In comparison with some previously reported designs, the new architectures are characterized by simpler basic processing cells and faster data throughput rate or smaller chip area requirements.
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    Circuits, systems and signal processing 6 (1987), S. 191-215 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract NON-VON is a highly parallel non-von Neumann supercomputer presently under construction at Columbia University. The basis for NON-VON's significant cost/performance advantage lies in a highly unusual application of VLSI technology to the realization of massive computational parallelism. This paper outlines the manner in which the emerging technology of VLSI circuits is employed in NON-VON to achieve this advantage. Particular emphasis is given to novel aspects of the design, layout, and operation of the NON-VON processing element, eight of which are to be embedded within each integrated circuit chip.
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    Circuits, systems and signal processing 6 (1987), S. 153-174 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Parallel sorting algorithms have been proposed for VLSI implementation. Random defects in the silicon wafer and fabrication errors render processors in the wafer faulty, and may cause these algorithms to fail despite a significant number of nonfaulty processors. This paper presents twofault-tolerant pipelined sorting algorithms that would work on a wafer comprised of faulty and nonfaulty processors. Both the algorithms useO(n) processors and requireO(n) time to sortn elements.
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    Circuits, systems and signal processing 6 (1987), S. 175-189 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract With the advent of wafer-scale integration (WSI), the placement of several “processors” on a single VLSI wafer is becoming a realistic possibility. To avoid the problems of a very low yield inherent in any silicon component of (very) large area, redundant components will be used. In this article we examine three different solutions for reconnecting the nonfaulty processors so that the resulting network is a square grid. We then present results of simulations for various percentages of faulty processors, which show that a small amount of redundancy is the interprocessors paths and a simple back-track based algorithm can produce a resulting grid that, while not necessarily optimal, includes most of the nonfaulty processors.
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    Circuits, systems and signal processing 6 (1987), S. 239-259 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Conventional random access memories are capable only of writing data into and reading data from the storage location corresponding to a given address. The availability of VLSI circuits containing hundreds of thousands of switching devices, however, has recently made practical the implementation of “active” memory chips capable of performing a range of complex operations on their stored data. Such designs are characterized by the extensive intermingling of processing and memory resources within a single chip to achieve the rapid and cost-effective parallel execution of operations relevant to such tasks as image processing, computer graphics, artificial intelligence, and database management. This paper presents a brief survey of a number of active memory chips that have been implemented or proposed, along with a more detailed examination of a particular active memory circuit, the NON-VON 3 primary processing subsystem chip.
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  • 24
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    Circuits, systems and signal processing 6 (1987), S. 217-238 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Serialization of memory access can be a critical bottleneck in shared memory parallel computers. The NYU Ultracomputer, a large-scale MIMD (multiple instruction stream, multiple data stream) shared memory architecture, may be viewed as a column of processors and a column of memory modules connected by a rectangular network of enhanced 2×2 buffered crossbars. These VLSI nodes enable the network to combine multiple requests directed at the same memory location. Such requests include a new coordination primitive, fetch- and-add, which permits task coordination to be achieved in a highly parallel manner. Processing within the network is used to reduce serialization at the memory modules. To avoid large network latency, the VLSI network nodes must be high-performance components. Design tradeoffs between architectural features, asymptotic performance requirements, cycle time, and packaging limitations are complex. This report sketches the Ultracomputer architecture and discusses the issues involved in the design of the VLSI enhanced buffered crossbars which are the key element in reducing serialization.
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    Circuits, systems and signal processing 6 (1987), S. 263-286 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Conventional frequency-domain window-leakage analysis accurately describes the leakage in the short-time Fourier transform only for stationary signals. Leakage in the time-frequency plane from concentrated transient or nonstationary signals can be effectively analyzed by use of a time-frequency window-leakage envelope with rectangular contours. This envelope is obtained from the Wigner distribution of the analysis window, with appropriate corrections for the sidelobe leakage. The time-frequency window-leakage envelope gives insight into the tradeoffs in time-frequency leakage between various windows and allows quick and accurate estimates of the leakage in the short-time Fourier transform. A simple technique for constructing signals with Wigner distributions that are linear transformations of the Wigner distribution of a known signal is developed. With this technique, windows with a variety of time-frequency orientations and leakage behavior can be developed.
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    Circuits, systems and signal processing 6 (1987), S. 287-298 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Fitting a high-order autoregressive model to data is often used to estimate the frequencies of sinusoids from their noisy measurements. This paper analyzes the asymptotic bias of the frequency estimates obtained by this method. It is shown that the bias decreases significantly with increasing model order.
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    Circuits, systems and signal processing 6 (1987), S. 299-314 
    ISSN: 1531-5878
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract We consider the general nonstationary passive systems modeled by linearRCG (G = gyrator) networks. Such networks in general contain conventional topological degeneracies (i.e., capacitor-only loops and/or inductor-only cutsets) as well as the topological degeneracies due to gyrator positioning in the network. Our central result is the explict demonstration that the existence of topological degeneracies does not impose any obstruction to the existence of the explicit state model, which we derive under no restriction on the topology of the network. We also discuss the conditions for the existence of the state model, its unique solutions, and the continuity of the state vector. The nature of the degeneracies inherent in the formulation is highlighted and it is shown that a gyrator-only subnetwork is accountable for algebraic degeneracies. Since the nature and the existence of topological degeneracies does not have anything to do with whether the element characteristics are linear or nonlinear, passive or active, our results are easy to extend to a large class of nonlinear and/or activeRCG networks.
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    Circuits, systems and signal processing 6 (1987), S. 315-334 
    ISSN: 1531-5878
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    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract This paper studies the behavior of motions of large-scale (LS) semistate systems (SSS) governed byP i (t)x i =M i (t,x i )x i +f i (t)+h i (t, x), i=1,2,...,s, =(x 1 T x 2 T ⋯x s T )T, where matricesP i (t) are singular. Using Lyapunov's approach and the tools for LS system analysis, a variant of attractivity and ultimate boundedness of appropriate time-variable sets are investigated. The results are based on a specific choice of the aggregate functions. It is assumed that the reduction of equations to a normal form of lower order is inconvenient. The aggregation-decomposition approach used in this paper reduces the dimensionality of an aggregate matrix of the system to the number of its systems. Motion properties of LS systems are deduced from the properties of its isolated subsystems, the character of interconnections, and the conditions imposed on the system aggregate matrix. Sufficient algebraic conditions for the above-mentioned motion properties are developed.
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    Circuits, systems and signal processing 6 (1987), S. 335-345 
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    Topics: Electrical Engineering, Measurement and Control Technology
    Notes: Abstract In this paper various conditions guaranteeing the ordinary, uniform, and asymptoticA-stability of semistate equations are given. These results are based on and given in terms of the semi-explicit form of a semistate equation.
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    Stochastic environmental research and risk assessment 1 (1987), S. 1-2 
    ISSN: 1436-3259
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering , Geography , Geosciences
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    Stochastic environmental research and risk assessment 1 (1987), S. 3-16 
    ISSN: 1436-3259
    Keywords: Annual maximum ; partial duration series ; T-year estimate ; marshall-Olkin bivariate distribution ; Morgenstern bivariate distribution
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering , Geography , Geosciences
    Notes: Abstract As a basis for development of the annual maximum distribution the so-called partial duration series with Poissonian occurrence times and exponentially distributed peak exceedance values has been selected. The model is generalized by allowing for a Markov dependence between succeeding peak values. Correlation values from p=0 to p=1 can be accounted for by introducing the Marshall-Olkin bivariate exponential distribution, which is presented in detail. The developed distribution function for the annual maximum is throughly analysed and a variety of distribution forms depending on the value of the correlation coefficient and the intensity in the Poisson process is hereby recognized. To a certain extent this might be considered as parallel to the scattering of hydrological regions with different generating mechanisms for the annual maxima.
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    Stochastic environmental research and risk assessment 1 (1987), S. 37-52 
    ISSN: 1436-3259
    Keywords: Cyclonic precipitation ; mathematical modeling ; simulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering , Geography , Geosciences
    Notes: Abstract A stochastic description is developed for extratropical cyclonic precipitation fields at synoptic and meso scales as they are typically observed by radars over the Earth. This description attempts to account I) for the synoptic scale behavior of a cyclonic storm (its birth, its synoptic scale motion trajectory, and its dissipation) II) for the synoptic-scale organizational structure of subsynoptic precipitation areas (rainbands, precipitation cores and raincells) within a cyclonic storm; and III) for the behavior of subsynoptic precipitation areas, in terms of their births, their spatial configuration evolutions, their motions, and their deaths (dissipation). The precipitation cores and the raincells are taken as the building blocks of the subsynoptic precipitation, areas within a cyclonic rainfield.
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    Stochastic environmental research and risk assessment 1 (1987), S. 81-100 
    ISSN: 1436-3259
    Keywords: Stochastic differential equations ; Itô calculus ; Stratovovich integrals ; Jump integrals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering , Geography , Geosciences
    Notes: Abstract Fundamentals of the theory of stochastic calculus and stochastic differential equations (SDE's) which are finding increasing application in water resources engineering are reviewed. The basics of probability theory, mean square calculus and the Wiener, white Gaussian and compound Poisson processes are given in preparation for a discussion of the general Itô SDE with drift, diffusion and jump discontinuity terms driven by Gaussian white noise and compound Poissionian impulses. Also discussed are stochastic integration and the derivation of moment equations via the Itô differential rule. The lierature of SDE's is reviewed with an emphasis on the more accessible sources.
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    Stochastic environmental research and risk assessment 1 (1987), S. 53-66 
    ISSN: 1436-3259
    Keywords: Hurst range ; conditioned exchangeable, variables
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    Notes: Abstract A new theoretical interpretation is proposed for Hurst's empirical law which is applicable to discrete-valued inflows and is consistent with the existing interpretation for continuous-valued inflows. This is applied to independent net inflows {X r} having values +1 and −1 with unequal probabilities. With the aid of a new result on the exchangeability of symmetrically conditioned exchangeable variables, values of the resulting range are obtained and tabulated. It is found that the effect of skewness is very slight for skewness values between (about) 3 and −3, and that Hurst's own approximation, the “conditioned range”, is remarkably accurate.
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    Stochastic environmental research and risk assessment 1 (1987), S. 67-80 
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    Keywords: pattern analysis ; mixed-mode data ; event-covering ; discretization ; hydrometric data
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    Notes: Abstract This paper presents a pattern analysis technique that has been successfully applied to a set of hydrometric network data collected in British Columbia, Canada. This technique can extract information from a set of observed heterogeneous multivariate data. The data are represented as n-tuples of mixed discrete and continuous values. The technique is capable of screening out statistically irrelevant information. It is also able to detect inherent subgroups in the data through adopting an event-covering approach. The subgroup characteristics represent important empirical understanding even though there may be considerable probabilistic variation within each individual subgroup.
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    Stochastic environmental research and risk assessment 1 (1987), S. 17-36 
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    Keywords: Stochastic hydrology ; multivariate analysis ; information extraction ; information transfer ; structure of time series ; time series analysis ; spatial characteristics ; simulation of processes
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    Notes: Abstract A stochastic approach to the analysis of hydrologic processes is defined along with a discussion of causes of tendency, periodicity and stochasticity in hydrologic series. Sources of temporal non-stationarity are described along with objectives and methods of analysis of processes and, in general, of information extraction from data. Transferred information as measured by correlation coefficients is compared with the transferable information as measured by entropy coefficients. Various multivariate approaches to hydrologic stochastic modeling are classified in light of complexities of spatial/temporal hydrologic processes. Alternatives of time series structural decomposition and modeling are compared. A special approach to modeling of space properties further contributes to approximate simulations of spatial/temporal processes over large areas. Several aspects of stochastic models in hydrology are concisely reviewed.
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    Stochastic environmental research and risk assessment 1 (1987), S. 101-116 
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    Keywords: Soil moisture ; stochastic processes ; stochastic differential equations
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    Notes: Abstract The dynamics of water within the unsaturated root zone of the soil are represented by a pair of stochastic differential equations (SDE's), one representing the so-called “surplus” state of the moisture and the other the “deficit” condition. The inputs to the model are the climatically controlled random infiltration events and evapotranspiration which are modeled as a compound Poisson process and a Wiener (Brownian motion) process, respectively. The solutions to these SDE's are not in “close-form” but sample functions are obtained by numerical integration. The moment properties of the soil moisture evolution process have also been derived analytically including the mean, variance, covariance and autocorrelation functions. To illustrate the model, climatic parameters representing the “surplus” and “deficit” cases and properties of clay loam soil have been used to numerically derived the corresponding sample functions. With proper selection of all the parameters, physically realistic sample trajectories can be obtained for the model.
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    Stochastic environmental research and risk assessment 1 (1987), S. 127-134 
    ISSN: 1436-3259
    Keywords: Upland erosion ; annual erosion losses
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    Notes: Abstract Point rainfall triggers the complex processes of overland flow and surface erosion. The probability density functions of rainfall duration and intensity are coupled with a physically based dynamic formulation of rainfall-runoff-sediment transport relationships for upland areas. When considering a single storm, rainfall depth alone is a poor predictor of sediment transport because of the dispersion introduced by the effect of rainfall intensity. On a long terms basis, however, the total amount of rainfall can be used to predict total erosion losses.
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    Stochastic environmental research and risk assessment 1 (1987), S. 117-126 
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    Keywords: equi-risk line ; detention pond ; urban runoff ; frequency analysis ; flood risk
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    Notes: Abstract The expression of equi-risk line derived by the authors represents the relationship between discharge capacityy 0 u and storage capacityz 0 u to keep flood frequency under a certain risk level represented by the return periodT, i.e.,z 0/z 0 u ={(y 0 u −y 0 u )/y 0 u } S , wherey 0 u andz 0 u areT-year probability peak discharge and total volume of a hydrograph. The shape parametersS is evaluated in this paper for various release rules of the storage facilities and correlations of durations and peaks of hydrographs. The expression forS is: $$S = S_\infty + (S_0 - S_\infty )\exp ( - \sqrt p )$$ , whereS 0 andS ∞ are the values ofS forp=0 and ∞, andp is the exponent of a general storage-release relation,q=az' p, wherea is the storage constant, andz' andq are the volume of stored water and the corresponding release. The values ofS 0 andS ∞ are expressed in terms of the correlation coefficient ρ of durations and peaks of inflow hydrographs.
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    Stochastic environmental research and risk assessment 1 (1987), S. 135-140 
    ISSN: 1436-3259
    Keywords: Upland erosion ; annual soil losses
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    Notes: Abstract Annual erosion losses from 135 experimental plots under a variety of soil types, vegetation cover densities and conservation practices in Iraq have been measured over a period of four years. The first three years of this data set demonstrate that annual erosion losses can be predicted from annual rainfall depths. The results obtained from regression analysis were then validated with the fourth year of soil erosion data. These results corroborate the theoretical findings of the companion paper in that long term erosion losses can be predicted from the total amount of rainfall.
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    Stochastic environmental research and risk assessment 1 (1987), S. 141-154 
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    Keywords: Contemporaneous ARMA models ; maximum likelihood estimation ; multivariate modelling ; stochastic hydrology ; time series analysis
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    Notes: Abstract In order to allow contemporaneous autoregressive moving average (CARMA) models to be properly applied to hydrological time series, important statistical properties of the CARMA family of models are developed. For calibrating the model parameters, efficient joint estimation procedures are investigated and compared to a set of uivariate estimation procedures. It is shown that joint estimation procedures improve the efficiency of the autoregressive and moving average parameter estimates, but no improvements are expected on the estimation of the mean vector and the variance covariance matrix of the model. The effects of the different estimation procedures on the asymptotic prediction error are also considered. Finally, hydrological applications demonstrate the usefulness of the CARMA models in the field of water resources.
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    Stochastic environmental research and risk assessment 1 (1987), S. 155-160 
    ISSN: 1436-3259
    Keywords: Gamma Markov ; estimation ; maximum likelihood estimates
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    Notes: Abstract The linearly regressive Gamma Markov sequence is being increasingly used as a model for geophysical phenomena, one of the reasons being that it is possible to determine the distribution of (weighted or otherwise) cumulative sums of such a sequence. In this paper we show briefly how to simulate such a sequence and its seasonal extension; we also show how to estimate its parameters. It is shown that the estimates obtained by the method of moments do not have a high efficiency, whereas those obtained by a modified maximum likelihood method have an efficiency close to unity.
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    Stochastic environmental research and risk assessment 1 (1987), S. 161-168 
    ISSN: 1436-3259
    Keywords: Inverse problem ; groundwater management ; groundwater response function ; stochastic control ; consistent parameter estimation
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    Notes: Abstract The response of groundwater basins to natural and anthropogenic inputs depends on many interrelated factors such as the values of groundwater flow and mass transport parameters. This work presents a theoretical analysis of the impact of parameter uncertainty on groundwater management decisions. It is shown that under classical, Bayesian, and deterministic assumptions about the parameter structure, the resulting management decisions could be very different. This underscores the importance of adopting the proper parameter structure and the need for using consistent methods to solve the inverse problem.
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    Stochastic environmental research and risk assessment 1 (1987), S. 185-198 
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    Keywords: Pattern matching ; tracking ; rainfall ; mesoscale ; radar
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    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering , Geography , Geosciences
    Notes: Abstract This paper presents a new feature-based matching algorithm for tracking mesoscale precipitation phenomena in radar image sequences. Distinct rainfall areas are identified in each image and characterized by a feature vector of shape descriptors, which provide a mathematical representation of the spatial characteristics of each identified area. Rainfall areas observed in consecutive images are matched by comparing the relative values of the features. Two match scoring algorithms are developed to generate the initial estimates of correct matches, which are then updated by likelihood measures based on relative location. The method is applied to mesoscale rainfall areas observed in sequences of radar-derived images of rainfall activity over Southwestern Ontario during the summers of 1980 and 1981.
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    Stochastic environmental research and risk assessment 1 (1987), S. 199-208 
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    Keywords: Extreme value distribution ; two-component distribution ; maximum entropy principle ; parameter estimation ; regional estimation
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    Notes: Abstract The two component extreme value (TCEV) distribution has recently been shown to account for most of the characteristics of the real flood experience. A new method of parameter estimation for this distribution is derived using the principle of maximum entropy (POME). This method of parameter estimation is suitable for application in both the site-specific and regional cases and appears simpler than the maximum likelihood estimation method. Statistical properties of the regionalized estimation were evaluated using a Monte Carlo approach and compared with those of the maximum likelihood regional estimators.
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    Stochastic environmental research and risk assessment 1 (1987), S. 169-184 
    ISSN: 1436-3259
    Keywords: Stochastic control and programming ; real-time hydrologic forecasting ; reservoir theory
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    Notes: Abstract A new approximate method of solution for stochastic optimal control problems with many state and control variables is introduced. The method is based on the expansion of the optimal control into the deterministic feedback control plus a caution term. The analytic, small-perturbation calculation of the caution term is at the heart of the new method. The developed approximation depends only on the first two statistical moments of the random inputs and up to the third derivatives of the cost functions. Its computational requirements do not exhibit the exponential growth exhibited by discrete stochastic DP and can be used as a suboptimal solution to problems for which application of stochastic DP is not feasible. The method is accurate when the cost-to-go functions are approximately cubic in a neighbourhood around the deterministic trajectory whose size depends on forecasting uncertainty. Furthermore, the method elucidates the stochastic optimization problem yielding insights which cannot be easily obtained from the numerical application of discrete DP.
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    Stochastic environmental research and risk assessment 1 (1987), S. 209-216 
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    Keywords: Transport ; sedimentation ; random walk ; Markov chain in continuous time ; distribution of maximum
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    Notes: Abstract A simple two-dimensional random walk model is developed for the motion of a particle in a fluid flow. Some earlier results for the persistent injection of particles into the flow are extended, and the distribution of the maximum number of particles in suspension over the period (0,t) is derived.
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    Stochastic environmental research and risk assessment 1 (1987), S. 217-240 
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    Keywords: Transport of fluid ; random network ; macro-permeability ; micro-geometry ; statistical mechanics
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    Notes: Abstract This paper presents a detailed statistical analysis of Hagen-Poiseuille flow in plane random isotropic networks of interconnected channels. The emphasis is on statistico-geometrical features of networks that affect macroscopic permeability. It is shown that permeability of a network depends on its average co-ordination number, the first two moments of the channel length distribution and other explicitly identifiable geometrical features. Distributions of flow rates in channels and average flow rates are established by minimization of the rate of energy dissipation. Theoretical developments are interpreted in the context of classical statistical mechanics. Analytical results are illustrated and verified using numerical analysis of flow in a simulated random network.
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    Stochastic environmental research and risk assessment 1 (1987), S. 280-280 
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    Stochastic environmental research and risk assessment 1 (1987), S. 241-262 
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    Keywords: Martingale ; stochastic-convective ; stochastic-relativist ; spectral-integral ; perturbative ; statistical-mechanical
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    Notes: Abstract The use of stochastic models in subsurface hydrology is growing at a logistic pace. To tie together a number of different stochastic methodologies for deriving subsurface transport equations, we have put together a brief review of some of the more common techniques. Our attention is confined to a few select methodologies so that we might delve in detail into assumptions required by the various approaches and their strengths and weaknesses. The methods reviewed include: Martingale, stochastic-convective, stochastic-relativist, spectral-integral, perturbative, statistical-mechanical, and generalized hydrodynamics. Within this list, we also have included a few stochastic methodologies which have been used solely to develop expressions for the dispersion tensor.
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    Stochastic environmental research and risk assessment 1 (1987), S. 297-302 
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    Keywords: Stochastic PDE ; Zakai equation ; nonlinear filtering ; distributed systems
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    Notes: Abstract We shall consider in this article a general class of stochastic PDE which in particular covers the Zakai equation of nonlinear filtering and natural formulations of distributed systems involving control variables. We use only fixed point arguments, hence we get uniqueness results. In the case of the Zakai equation, Galerkin approximations have been considered by Pardoux (1979) to derive the existence of the solution
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    Stochastic environmental research and risk assessment 1 (1987), S. 281-296 
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    Keywords: Stochastic groundwater flow ; semigroups ; random in time Gaussian process ; random physical parameters ; stochastic partial differential equations
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    Notes: Abstract Two methods for the solution of partial differential equations (PDE) for the general case of random in time physical parameters are presented and their application to the solution of unsteady regional groundwater flow equations are illustrated. The first method is the semigroup approach which directly offers a solution without resorting to “closure approximations” (hierarchy techniques), perturbation techniques, or Montecarlo simulation techniques. The semigroup approach can also handle the general stochastic problem when randomness also appears as initial conditions, boundary conditions or forcing terms. The second method is an approximation scheme to obtain the semigroup solution in complex cases and permits the solution of equations with more than one random coefficient.
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    Stochastic environmental research and risk assessment 1 (1987), S. 303-318 
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    Keywords: Rainfall-runoff models ; forecasting ; unit hydrograph
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    Notes: Abstract Here we review the main thrusts of rainfall-runoff modelling with an eye toward the advantageous use of the massive date sets being accumulated and the modern computers capable of dealing effectively with such sets. More than a tutorial, this study is aimed at providing a unifying structure for analyzing available techniques. The closing section draws attention to the existence of an alternative methodology.
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    Stochastic environmental research and risk assessment 1 (1987), S. 263-279 
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    Keywords: Porous media ; heterogeneity ; groundwater ; dispersion ; stochastic theory ; plume evolution
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    Notes: Abstract The migration of contaminants in heterogeneous aquifers involves dispersive processes that act at different scales. The interaction of these processes as a plume evolves can be studied by micro-scale modelling whereby two scales, a local- or micro-scale and an aquifer- or macro-scale, are covered simultaneously. Local-scale dispersive processes are represented through the local dispersion coefficient in the transport equation, while large-scale dispersion due to heterogeneities is represented through the resolution of the flow field and the diffusive exchange between streamtubes. The micro-scale model provides both the high degree of resolution compatible with local-scale processes, and the extent required for the approach to asymptotic conditions, using grids of up to a million nodal points. The model is based on the dual potential-streamfunction formulation for flow, and the transport problem is formulated in a natural coordinate system provided by the flownet. Simulations can be used to verify stochastic theories of dispersion, without the restrictive assumptions inherent in the theory. For the two-dimensional case, results indicate convergence of the effective dispersivity to the theoretical macrodispersivity value. Convergence takes place within a travel distance of about 50 correlation lengths of the hydraulic conductivity field. However, the approach taken to asymptotic conditions, as well as the macrodispersivity value, may differ for different realizations of the same medium. The influence of early-time events such as plume splitting on the asymptotic convergence remains to be investigated.
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    Polymer bulletin 1 (1978), S. 11-15 
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Lifetime of the propagating species and initiation rate constants (ki) were evaluated for the cationic polymerization of p-methoxystyrene initiated by I2, CH3SO3H, BF3O(C2H5)2, and SnCl4. The lifetime was found to be fairly long, ranging from 0.2 to several seconds in 1,2-dichloroethane at 30°C; that for the intermediate generated by iodine (2–6 s) much exceeded the others. The ki value increased in the order: I2 〈 CH3SO3H ≪ BF3O(C2H5)2 ∼ SnCl4.
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    Notes: Abstract The spontaneous aquation reaction of Co(NH3)5Br2+ was enhanced by addition of sodium polyethylenesulfonate, an anionic polyelectrolyte. The volume of activation was negative in the absence of the macroions and positive in their presence. This suggests that the macroions dehydrate the activated complex more strongly than the reactants, if it may be attributed solely to the solute-solvent interaction term.
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    Polymer bulletin 1 (1978), S. 35-39 
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    Notes: Summary The morphological influence of water-soluble polymers on the aqueous bilayer aggregate (vesicle and/or lamella) of didodecyldimethylammonium bromide was investigated by electron microscopy. Positively charged polymers and uncharged polymers either destroyed the aggregate or was ineffective. On the other hand, the negatively-charged copolymer of acrylamide and acrylate separated the bilayer and produced smaller vesicles.
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    Polymer bulletin 1 (1978), S. 47-53 
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    Polymer bulletin 1 (1978), S. 73-77 
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    Notes: Summary Both asparagine and isoasparagine were converted into polyaspartic acids by refluxing the corresponding aqueous solutions at neutral pH in the presence of a salt. The properties of the resulting polyaspartic acids were studied. The dissociation behavior of the carboxyl groups in the polypeptides were studied by the potentiometric titration. The analysis of the titrational data was performed by a modified Speakman's method. The analysis show that both polyaspartic acids prepared from asparagine and isoasparagine have α- and β-aspartyl residues and the ratio of α- and β-aspartyl residues is 75 ∶ 25∼85 ∶ 15. A possible mechanism for the formation of α- and β-aspartyl residues in the polymer was discussed.
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    Polymer bulletin 1 (1978), S. 181-189 
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    Notes: Conclusions The 13C NMR spectra of H-H PS and H-H PVCH show the influence of the long range order on the chemical shift of several carbons. There is some hope to improve the resolution by the choice of appropriate solvents. The attribution of the lines to specific stereosequences would require the preparation and separation of optically pure dimers and trimers. It is, however, already possible to compare the microstructure of H-H polymers prepared by different chemical ways.
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    Polymer bulletin 1 (1978), S. 215-220 
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    Notes: Summary Poly-l-lysines containing nucleic acid bases, that is, adenine, thymine, uracil and theophylline were synthesized. The nucleic acid base substituted l-lysine derivatives were prepared from α,N-Cbz-l-lysine and the p-nitrophenyl esters of the carboxyethyl derivatives of the nucleic acid bases. The polymers were obtained from these l-lysine derivatives by the NCA method.
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    Polymer bulletin 1 (1978), S. 205-210 
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    Notes: Summary Treatment of wood meal with aqueous alkali in the presence of anthraquinone at 80°C leads to a conversion of reducing hexose end groups in the polysaccharides to mannonic and gluconic acid end groups. Xylose end groups are oxidized to xylonic and lyxonic acid groups. This leads to a stabilization of the polysaccharides against endwise alkaline degradation.
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    Polymer bulletin 1 (1978), S. 61-66 
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    Notes: Abstract Polarized Raman spectra of doubly oriented samples of atactic poly(vinyl alcohol) have been measured. The great usefulness of such polarized spectra has been clarified for the vibrational analysis. The normal coordinate treatments of syndiotactic and isotactic poly(vinyl alcohol) chain models gave good agreement between the observed and calculated frequencies.
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    Polymer bulletin 1 (1978), S. 67-72 
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    Notes: Summary Concentrated solutions (〉20 wt%) of poly (γ -benzyl L-glutamate) (PBLG) were investigated using small angle light scattering (SALS). The gels and cholesteric liquid crystals formed in PBLG concentrated solutions, were analyzed in terms of theories previously developed for SALS from crystalline polymers. It was found that there are two types of the fibrillar aggregation of α-helices in gels and furthermore, two types of the orientation correlation of α-helices in cholesteric liquid crystals.
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    Notes: Summary Spontaneous alternating copolymerizations of 2-phenyl-1,3,2-dioxaphospholane (MN) with p- and with o-formylbenzoic acids (ME) were examined. The copolymerizations took place without catalysts affording the copolymer 3 via zwitterion 6. The copolymerizations involve the oxidation of the phosphorus monomer and the reduction of formylbenzoic acid. The scheme of the copolymerizations was presented. The yields of copolymers were quite different between these two copolymerizations. With ortho acid, the copolymer yield was low due to producing phthalide 4.
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    Polymer bulletin 1 (1978), S. 167-170 
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    Notes: Summary A new reversible photochromic copolymer of maleic anhydride with styrene containing azo side groups was prepared. The system reacts to irradiation by a reversible trans-cis photoisomerization of light-sensitive azo groups. Irradiation also causes a change in the refractive index, so that the polymer may be employed in recording optical information in the form of phase hologram. The resolution of the material is higher than 2000 lines/mm. In spite of the large variability of organic compounds, according to available information only two groups of compounds have been utilized in the reversible recording of volume phase holograms. These are dimers of aromatic polycyclic hydrocarbons (Tomlinson et al. 1972) and stilbene derivatives (Anonym 1974). In this paper we describe a new reversible material for recording volume phase holograms (Matějka et al. 1978).
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  • 69
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    Notes: Summary Alternating copolymerization of 2-acryloxypropionic acid (APA) as a new MN with two MN monomers of phosphorus containing ethylene phenyl phosphonite (EPO) and ethylene phenyl phosphite (EPI) have been disclosed. Copolymerizations took place without added catalyst to produce 1∶1 alternating copolymers of APA-EPO and of APA-EPI. The structures of the copolymers were determined by IR and NMR spectroscopy, elemental analyses, as well as the identification of the alkaline hydrolysis products. The copolymerizations were explained in terms of a mechanism of zwitterion intermediates involving a hydrogen transfer process.
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  • 70
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    Polymer bulletin 1 (1978), S. 191-198 
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  • 71
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    Polymer bulletin 1 (1978), S. 199-204 
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    Notes: Synopsis Poly (ester)s are degraded by the attack of classical carbenium ions. In a representative study it is demonstrated that the carbenium ions are by far more reactive to cleave ester linkages than are protons. The change of molecular weight distribution of the poly-(ester) during reaction with carbenium ions is reported In an example on low molecular weight compounds the reaction path has been clarified.
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  • 72
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    Polymer bulletin 1 (1978), S. 221-225 
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    Notes: Summary Various attempts to induce the anionic polymerisation of 2-vinylfuran and some of its homologues were carried out. Negative results were obtained, except with sodium biphenyl in hexamethylphosphotriamide, a system which gave limited yields and not a living polymerisation. The results are interptreted on the basis of side reactions of the furan ring marring the normal vinyl propagation, A critical discussion of previous conflicting reports is also given.
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  • 73
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    Polymer bulletin 1 (1978), S. 233-237 
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    Notes: Summary Investigation of the photochemistry of benzoin derivatives in a polymer medium leads to the suggestion that oxygen play an important part in the first processes which occur under U.V. irradiation. This is of interest for the understanding of the photocrosslinking process.
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  • 74
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    Notes: Summary A brief kinetic study is reported of the polymerisation of ethylene catalysed by four aluminium-titanium chloro-organic complexes, three of which are new. These systems proved efficient both in terms of polymerisation rate and of the linearity of the high polymers obtained. A comparison is made with previous work in this field.
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  • 75
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    Polymer bulletin 17 (1987), S. 31-36 
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    Notes: Summary In the presence of ZnCl2 phenyl glycidyl ether reacts to different products owing to the ring-opening reaction of the oxirane and the cleavage of the ether bond. Using HPLC and offline mass spectrometry most of the reaction products could be identified. A reaction scheme and the supposed reaction mechanism were described involving the formation of chlorine — containing oligomers and low molecular weight by — products resulting from the cleavage of the ether bond of the monomer. Conclusions were drawn for original polyfunctional epoxy resin systems.
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  • 76
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    Polymer bulletin 17 (1987), S. 55-62 
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    Notes: Summary Basing on that the fluctuations of chains and junctions in real vulcanizates with carbon black fillers are suppressed by the presence of three kinds of forces which are network, entanglement and carbon black-polymer interaction forces. A new molecular theory of rubber elasticity for vulcanizates with carbon blacks at large deformation was presented. It succeeds in relating the elastic state to molecular constitution by three important quantities (C100, C020 and C200). In which the severity of constraints by entanglements, crosslink and junctions of carbon blacks are characterized with four molecular parameters. , , and . The relationships of stress to strain for four types of deformation were derived from this theory.
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    Polymer bulletin 17 (1987), S. 63-70 
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    Notes: Summary A satisfactory account of reinforcement has been secured through the application of the theory of elasticity to rubber vulcanizates with carbon black fillers. A statistical theory of reinforcement by carbon blacks and it's characteristics were developed. Three methods for characterizating the reinforcement of carbon blacks by the difference of elastic free energy, retractive forces and modulus were derived from this theory. The influences of carbon blacks on mechanical properties of SBR and NR vulcanizates were studied by uniaxial equi-biaxial and unequi-biaxial extensions. These results show that an excellent agreement between the theory and experiments. A correlation between the structure parameters of cijk and the tensile strength for SBR vulcanizates filled by different grade of carbon blacks exists.
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  • 78
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    Notes: Summary A rubbery (CTBN based) thin layer is added onto the surface of glass beads embeded in a DGEBA — DDA matrix. The chemical and the coating processes are described. The existence of a specific relaxation of the interphase is evidenced using viscoelastic measurements. The presence of an other α1 relaxation is discussed.
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  • 79
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    Polymer bulletin 17 (1987), S. 7-13 
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    Notes: Summary The efficient synthesis of symmetrical telechelic polyisobutylenes carrying ∼ CH2C(CH3)2Cl groups at either end of the molecule, $$\mathop - \limits^t Cl - PIB - Cl\mathop - \limits^t$$ , has been accomplished by rapid living polymerization using aromatic di-tert.-ether/BCl3 initiator system in CH3Cl at −70°. The living nature of the polymerization was demonstrated by linear Mn versus amount of PIB formed (WPIB) plots starting at the origin. The effect of temperature and solvent composition (polar/nonpolar) on the polymer structure has been investigated. Undesirable indanyl end groups which form during polymerizations carried out at −30° and −50°C can be eliminated by decreasing the temperature to −70°C. The apparent activation energy differences have been determined in the −30 to −70°C range at different polar/nonpolar solvent compositions: ΔEa of $$\mathop - \limits^t Cl - PIB - Cl\mathop - \limits^t$$ decreases from 2.6 to 1.0 kcal/mole by decreasing the polarity of the medium from 100% CH3Cl to a 60/40 v/v CH3Cl/hexanes mixture.
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  • 80
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    Notes: Abstract We observed significant piezoelectric activity in cast films of poly(1-bicyclobutanecarbonitrile).
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    Polymer bulletin 17 (1987), S. 137-140 
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    Notes: Summary The process of crystallization and the structure of poly/ oxymethylene/ (POM) films cast from hexafluoroacetone sesquihydrate solutions were studied. The supermolecular structure of thin POM films was studied by the use of polarization microscope. It has been found to consist mainly of spherulites, the size of which are essentially independent of the initial concentration of the solution. Similarly to the findings reported for thin films made of melts, ovoids and spiral ovodis were also found in minor amounts. Two additional formations indicating more complex structure were also detected. Further details of the structures formed could be recognized applying scanning electron microscopy.
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    Polymer bulletin 17 (1987), S. 149-156 
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    Notes: Summary In water swollen nylon grafted acrylamide (NYgAM) membranes, prepared by the electron beam preirradiation technique, water was classified into three categories: bound, free and intermediate states. The partition of water into these states was evaluated by utilising the data of water sorption capacity and permeability coefficients of water and ionic solutes through the membranes. Reevaluation of the partition was done utilizing the data of water proton relaxation times Ti, measured by pulsed NMR technique. The partition was evaluated as follows: the first 2 moles of water per mole of grafted polyacrylamide (PAM) are bound, the next 4/3 moles are intermediate and the rest of the water is free. It was further found that in highly water swollen membranes, the water beyond 2 moles per mole of PAM can be classified as free water.
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  • 83
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    Notes: Summary Acyl chloride group introduced onto carbon black rapidly lost its activity by the moisture in air. However, the decrease of acyl chloride group content in vacuum was negligibly small. By the reaction of the acyl chloride group with several polymers having hydroxyl or amino group, such as polyethylene glycol (PEG), poly(vinyl alcohol)(PVA), and polyethyleneimine (PEI), these polymers were found to be effectively grafted onto carbon black; for instance, the grafting ratio of PEG (Mn=8.2×103), PVA (Mn=2.2×104), and PEI (Mn=2.0×104) was 18.5%, 32.9%, and 45.8%, respectively. The number of polymer grafted onto carbon black decreased with an increase of its molecular weight.
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    Polymer bulletin 17 (1987), S. 94-94 
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  • 85
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    Notes: Summary The title hypervalent iodine compounds are efficient photoinitiators for the polymerization of 2-(dimethylaminoethyl)methacrylate. The polymer is formed in daylight but faster under UV irradiation, with high conversion; its molecular weight 〈Mn〉 is 9×104 daltons. Copolymerization of this monomer with styrene occurs also under similar conditions at a high rate. A free radical mechanism is suggested for these polymerizations.
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    Polymer bulletin 17 (1987), S. 341-345 
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    Notes: Summary In this communication the results of a series of recent studies of the morphology and deformation behavior of toughened poly(butylene terephthalate) (PBT)/BPA polycarbonate (PC) blends are briefly summarized. Several papers containing a more detailed account are currently in press (1–3). Among the unique morphological features of these blends are the consistent isolation of the core/shell impact modifier (IM) in the PC phase and the crystallization and phase separation of the PBT from the partially miscible PBT/PC melt on slow cooling. DSC studies provide corroborating evidence for melt miscibility of the two resins. The blends deform through a combination of cavitation and shear processes. In all cases cavitation occurs exclusively within the IM particles and is suppressed at higher PC concentrations and elevated temperatures.
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  • 87
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    Notes: Summary A butadiene-styrene copolymer was partially modified by Friedel-Crafts reaction of phenyl groups with benzoyl chloride or phenylacetyl chloride. The resulting benzoylphenyl and phenylacetylphenyl groups served as photosensitizers for a subsequent crosslinking by u.v. irradiation. The extent of crosslinking was measured by sol/gel analysis. Crosslinking was carried out without magnetic field and with magnetic field of flux density 1.0 Tesla. The experiments with magnetic field yielded about 5% less soluble polymer, corresponding to a higher crosslink degree. The data were evaluated by statistical methods.
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  • 88
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    Notes: Summary Comb-like poly(oxyethylenes) ( $$\underset{\raise0.3em\hbox{$\smash{\scriptscriptstyle\thicksim}$}}{2} $$ ), prepared by the HI/I2-initiated living cationic polymerization of vinyl ethers carrying a poly(oxyethylene) pendant, were found to transport alkali metal ions (Li+, Na+, K+, and Cs+) through a dichloromethane liquid membrane at 25°C. Polymer $$\underset{\raise0.3em\hbox{$\smash{\scriptscriptstyle\thicksim}$}}{2} $$ with four oxyethylene units per pendant (n = 4) transported all the four cations (best for K+), and more effective as an ion carrier than its non-polymeric counterpart (tetraglyme), whereas $$\underset{\raise0.3em\hbox{$\smash{\scriptscriptstyle\thicksim}$}}{2} $$ with n = 0 [poly(ethyl vinyl ether)] was virtually ineffective. The observed polymeric effect indicates an enhancement of ion transport via a cooperative action of the neighboring poly(oxyethylene) pendants. Related vinyl ether copolymers consisting of poly(oxyethylene) (n = 4) and hydrophobic phenoxyl pendants were inferior to $$\underset{\raise0.3em\hbox{$\smash{\scriptscriptstyle\thicksim}$}}{2} $$ as ion-transport carriers, but introduction of hydrophilic alcoholic pendants into $$\underset{\raise0.3em\hbox{$\smash{\scriptscriptstyle\thicksim}$}}{2} $$ (n = 4) facilitated the transport of the smaller cations (Li+ and Na+).
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    Polymer bulletin 17 (1987), S. 299-306 
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    Notes: Summary Two EPDM graft terpolymers, one with polystyrene branches and one with poly-α-methylstyrene, were prepared from a commercial EPDM polymer using “grafting from” techniques. The new materials were characterized by GPC, osmometry and nmr spectrometry; tensile strength properties were also determined.
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  • 90
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    Notes: Summary The polymerization of acetylene was investigated using catalysts in which the titanium component, Ti(OBu)4, was reduced with organomagnesium and organolithium compounds. In some cases, mainly with RMgBr, homogeneous films possessing good mechanical properties were obtained. The content of the transform of polyacetylene (40–80%) depended only vaguely both on the type of the reducing agent and on the reaction conditions. In all cases the film density was higher than that of films prepared according to Shirakawa.
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    Polymer bulletin 17 (1987), S. 481-488 
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    Notes: Summary Using the theory of branching processes, conditions for gelation and relations for the sol fraction and concentration of elastically active network chains have been derived for polyurethane systems where also urea, biuret and allophanate units are formed. The application of the theory is illustrated by gelation in diol-diisocyanate-water systems in which urea and biuret units are formed.
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    Polymer bulletin 17 (1987), S. 499-506 
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    Notes: Summary The following dihydroxy linear, branched and block polyesterethers: αω,-dihydroxy-poly (di (oxyethylene) oxysuccinyl) (1), -poly(tri(oxy-ethylene)oxysuccinyl) (2), -poly(oxyethylene-oxysuccinyl)-block-poly(oxyethylene) (3), and -poly(oxy-3-(2-methoxyethoxy)propyleneoxysuccinyl) (4) have been synthetized using polytransesterification reactions. Their NMR spectra have been assigned and compared.
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  • 93
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    Notes: Summary In this paper we present a general expression describing the peak broadening effect on molecular weight averages measured during the elution of a polymer in GPC. This expression is valid for nonlinear column calibration and nonuniform Gaussian spreading across the chromatogram. Comparison is made with analytical relationships derived by Yau, Marais, Hamielec and Netopilik. The methodology developed as an extension of the Pierce and Armonas method is applied to a model system and to elution data of dextrans.
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    Polymer bulletin 17 (1987), S. 523-529 
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    Notes: Summary We report here on the apparent compatibility of a series of n-alkane/PDMPO blends. Three alkanes were examined [eicosane (C20), tetracosane (C24), and Polywax 2000 (nominally C142)] as blends of 5, 10, 15, and 20 wt.% alkane with PDMPO. Samples were judged to be compatible or incompatible according to three criteria: (a) visual appearance, i.e., transparent vs. opaque molded specimens, (b) the presence or absence of an alkane crystalline melting peak in a DSC thermogram, and (c) downward shifts in the PDMPO-rich phase glass transition temperatures from the T g range of 195–200°C for PDMPO homopolymer. The T u〉Tm alkane component transition has not been observed in any of the blends prepared to date.
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  • 95
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    Notes: Summary The temperature dependence of the second virial coefficient and intrinsic viscosity of statistical copolymers of methyl methacrylate and methacrylic acid in 2-ethoxyethanol was investigated. It was found that the θ-temperatures of copolymers are outside the temperature range given by the θ-values for poly(methacrylic acid) and poly(methyl methacrylate). Their dependence on the copolymer composition has a discontinuity. Simple theoretical considerations have shown that this behaviour may be expected with copolymers composed of monomer units dissolving, respectively, with absorption and evolution of heat.
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  • 96
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    Notes: Summary The effect of ZnCl2 addition on the reactivity ratios of the system acrylonitirle (AN)-N-2-Chlorophenylmaleimide (2CMI) has been investigated. It has been found that the addition of small amount of ZnCl2 doubles the reactivity of AN while drastically decreasing that of the 2CMI. The viscosity of the copolymers has been measured and was found to decrease with increasing the maleimide and the ZnCl2 concentrations.
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  • 97
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    Notes: Summary New thermosetting resins were prepared by crosslinking of 2,4,6-tris[4-(maleimido) phenoxy]-s-triazine (TM) or 2,4-bis[4-(maleimido) phenoxy]-6-diethoxyphosphinyl-s-triazine (BM) in presence of various aromatic di- or tri-amines. The maleimide-amine adducts initiated thermal polymerization at lower temperature than did the corresponding neat maleimides. The thermal stability of cured resins was evaluated by thermogravimetric analysis. The cured resins derived from the maleimide-amine adducts were less thermally stable than those of the corresponding neat maleimides. The initial decomposition temperature of the polymers obtained from the maleimide-amine adducts was not remarkably influenced by the chemical structure of the aromatic amine utilized.
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    Polymer bulletin 18 (1987), S. 27-32 
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    Notes: Summary The 300 MHz pmr spectrum of poly(p-bromostyrene) is presented and analyzed. The aliphatic proton resonance of this polymer is very similar to that of polystyrene, but the aromatic proton resonance is somewhat more well defined. The resonance of the ring protons ortho to the polymer backbone occurs in a 5 peak pattern that, in view of the previous results obtained for poly 2- and 3-vinyl thiophenes (1,2) and poly(p-acetylstyrene) (3), was interpreted in terms of pentad stereosequences. Based on the assignments made in this paper, poly (p-bromostyrene) synthesized by free-radical initiated polymerization seems to be atactic.
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    Polymer bulletin 18 (1987), S. 137-141 
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    Notes: Summary Polyvinylfluoride (tedlar) films, 12.5–25 μm thick, were grafted with acrylamide monomer (AM) in an aqueous solution, following preirradiation with a 550 kV electron beam accelerator. The graft yield rose with grafting period up to 285% and 475%, for the 25 μm and the 12.5 μm tedlar films, respectively, and then levelled off due to gelation of the solution. Water permeation rates through the tedlar films were increased, upon grafting with AM, by a factor of up to 3. Water permeation rates through the tedlar grafted with acrylamide (TEDgAM) films were relatively low, as compared with those of cellophane films or nylon grafted acrylamide films (NYgAM) of comparable thickness, implicating that only part of the tedlar film cross-section has been penetrated through by the grafted copolymer. The highest rates of water permeability were observed in 12.5 μm films grafted with 475% acrylamide.
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    Notes: Abstract The influence of the conformation of conjugated molecules on their electronic properties has been investigated using the extended Hückel theory. Dimers of acetylene and methylacetylene have been taken as model compounds of poly(acetylene) and poly(methylacetylene). Upon increasing the torsional angle between the two repeat units, both the band gap and the ionization potential increase, but the change is more pronounced with the former variable. This increase is not regular and becomes more important at angles larger than 30°. Non-planar conformations are then expected with poly(methylacetylene) and other n-alkyl monosubstituted poly(acetylenes) and explain their large band gap (i.e. blue shifting) in comparison with that of poly(acetylene). In addition, similar ionization potentials are expected for n-alkyl substituted poly(acetylenes) and, therefore, their different reactivity in presence of oxidizing agents has to be explained by the size of their substituents.
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