ALBERT

Description: Ferromanganese nodules in the deep-sea and in freshwater lakes usually accrete layers rich in manganese oxides alternating with layers rich in iron oxides. The mechanism producing these alternating layers is unknown; indeed, the mechanism producing the nodules themselves is unknown. In Oneida Lake, New York, precipitants from the lake water and the surfaces of nodules at the sediment-water interface are enriched in Mn, whereas nodules buried in lake sediments have surface layers enriched in Fe. It is hypothesized here, using field and laboratory evidence, that reduction and mobilization of Mn from the nodule surface during periods of anoxic sediment cover produce the high Fe layers observed in the nodules.

Description: Deep sea manganese nodules from the Central Pacific Basin are mainly composed of 10Å manganite and d-MnO2 Two zones equivalent to the minerals are evidently distinguishable according to their optical properties. Microscopic and microprobe analyses revealed quite different chemical compositions and textnral characteristics of the two zones. These different feature of the two zones of nodules suggest the different conditions under which they were formed. Concentrations of 11 metal elements in the zones and inter-element relationships show that the 10Å manganite zone is a monomineralic oxide phase containing a large amount of manganese and minor amounts of useful metals, and that the d-MnO2 zone which is apparently homogeneous under the microscope is a mixture of three or more different minerals. The chemical characteristics of the two zones can explain the variation of bulk composition of deep sea manganese nodules and inter-element relationships previously reported, suggesting that the bulk compositions are attributable to the mixing of the 10Å manganite and d-MnO2 zones in various ratios. Characteristic morphology and surface structure of some types of nodules and their relationships to chemistry are also attribut able to the textural and chemical features of the above mentioned two phases. Synthesis of hydrated manganese oxides was carried out in terms of the formation of manganese minerals in the ocean. The primary product which is an equivalent to d-MnO2 was precipitated from Mn 2+ -bearing alkaline solution under oxigenated condition by air bubbling at one atmospheric pressure and room temperature. The primary product was converted to a l0Å manganite equivalent by contact with Ni 2+, Cu 2++ or CO2+ chloride solutions. This reaction caused the decrease of Ni2+, Cu2+ or CO2+ concentrations and the increase of Na+ concentration in the solution. The reaction also proceeded even in diluted solutions of nickel chloride and resulted in a complete removal of Ni2+ from the solution. Reaction products were exclusively 10Å manganite equivalents and their chemical compositions were very similar to those of 10Å manganite in manganese nodules. The maximum value of(Cu+Ni+Co)/Mn ratio of 10Å manganite zones in manganese nodules is 0.16, and the Ni/Mn ratio of synthetic 10Å manganite ranges from 0.15 to 0.18 with the average of 0.167.

Description: Nine nodules collected from throughout the deep North Pacific were analyzed for their mineralogy and major-element composition before and after leaching with Chester-Hughes solution. Data indicate that the mineral phillipsite accounts for the major part (〉 75%) of the aluminosilicate fraction of all nodules. It is suggested that formation of phillipsite takes place on growing nodule surfaces coupled with the oxidation of absorbed manganous ion. All the nodules could be described as ternary mixtures of amorphous iron fraction (Fe-Ti-P), manganese oxide fraction (Mn-Mg Cu-Ni), and phillipsite fraction (Al-Si-K-Na), these fractions accounting for 96% of the variability of the chemical composition.

Description: The plateau is a foundered continental block, and lies at an average depth of 2000-3000 m. On the plateau the dominant fault direction is NW to WNW, an ancient strike direction on the Australian continent. The western margin probably formed as a series of NE-trending rifts and NW-trending transforms during Late Jurassic breakup. Canyons cut the western margin, and some of these appear to be fault-bounded. One such fault forms the northern margin of a major NW-trending feature, the Wilson Spur. This appears to be a transform fault and perhaps extends across the abyssal plain as far as the eastern end of the Java Trench. Seismic profiles suggest that, at the trench, it separates thrust-faulted continental crust to the east from oceanic crust to the west. This could explain the eastern termintion of the deep part of the trench. The bathymetric depression of the Roti Basin, which lies southeast of the Java Trench, links the trench to the Timor Trough. The Argo Abyssal Plain slopes gently southward, with water depths ranging from 5000 m near the Java Trench to 5730 m in the south. Oceanic basement varies from smooth to hummocky and irregular, and is overlain by about 4000 m of acoustically semi-transparent Late Jurassic and Cretaceous sediments, that is in turn unconformably overlain by 200 m of layered Tertiary sediment. Bottom samples from the outer Scott Plateau show that Callovian breakup was preceded by a period of basic volcanism and shallow marine sedimentation, that restricted shallow marine conditions followed in the Late Jurassic, and that bathyal carbonate sedimenation prevailed by the Late Cretaceous (Campanian). Quaternary marls cored on the northern Scott Plateau straddled the Pleistocene-Holocene boundary, and siliceous oozes cored on the southern slope of the Java Trench contain nannofossils which, below a few decimetres, are older than late Pleistocene. The Java Trench cores indicate that the calcite compensation depth was apparently between 5420 and 5700 m in the early or midel Pleistocene, and is above 4950 m now. The Scott Plateau cores indicate that the present calcite compensation depth in the region lies below 3290 m. On the Scott Plateau Holocene sedimentation rates are about 5 cm/1000 years, but in the Java Trench they are much lower. Manganese oxide crusts and nodules were recovered from the Scott Plateau, but their content of valuable metals was low.