ALBERT

Description: Deep sea manganese nodules from the Central Pacific Basin are mainly composed of 10Å manganite and d-MnO2 Two zones equivalent to the minerals are evidently distinguishable according to their optical properties. Microscopic and microprobe analyses revealed quite different chemical compositions and textnral characteristics of the two zones. These different feature of the two zones of nodules suggest the different conditions under which they were formed. Concentrations of 11 metal elements in the zones and inter-element relationships show that the 10Å manganite zone is a monomineralic oxide phase containing a large amount of manganese and minor amounts of useful metals, and that the d-MnO2 zone which is apparently homogeneous under the microscope is a mixture of three or more different minerals. The chemical characteristics of the two zones can explain the variation of bulk composition of deep sea manganese nodules and inter-element relationships previously reported, suggesting that the bulk compositions are attributable to the mixing of the 10Å manganite and d-MnO2 zones in various ratios. Characteristic morphology and surface structure of some types of nodules and their relationships to chemistry are also attribut able to the textural and chemical features of the above mentioned two phases. Synthesis of hydrated manganese oxides was carried out in terms of the formation of manganese minerals in the ocean. The primary product which is an equivalent to d-MnO2 was precipitated from Mn 2+ -bearing alkaline solution under oxigenated condition by air bubbling at one atmospheric pressure and room temperature. The primary product was converted to a l0Å manganite equivalent by contact with Ni 2+, Cu 2++ or CO2+ chloride solutions. This reaction caused the decrease of Ni2+, Cu2+ or CO2+ concentrations and the increase of Na+ concentration in the solution. The reaction also proceeded even in diluted solutions of nickel chloride and resulted in a complete removal of Ni2+ from the solution. Reaction products were exclusively 10Å manganite equivalents and their chemical compositions were very similar to those of 10Å manganite in manganese nodules. The maximum value of(Cu+Ni+Co)/Mn ratio of 10Å manganite zones in manganese nodules is 0.16, and the Ni/Mn ratio of synthetic 10Å manganite ranges from 0.15 to 0.18 with the average of 0.167.

Description: The major and minor element compositions of a suite of abyssal sea-floor ferromanganese nodules and associated sediments from the eastern central Pacific have been used to examine inter-element relationships and the mineralogy of the nodules, the relationship between the composition of nodules, and their associated sediments and regional variations in composition with respect to likely modes for formation of such deposits. Apart from Mn and Fe, significant proportions of the total Ti, Ca, Mg, K, Ba, Sr, Th and Y and almost all the P, As, Ce, Co, Cu, Mo, Ni, Pb, Zn and Zr are present in the oxide fractions of the nodules. The Mg, Ba, Cu, Mo, Ni and Zn contents are significantly correlated with the total Fe content. Nodules from the northeastern tropical Pacific have Mn/Fe ratios highter than those in the oxide fractions of their associated sediments, todorokite as the principal Mn phase and relatively high concns of minor elements associated with Mn. Nodules from the south central Pacific have Mn/Fe ratios similar to those in the oxide fractions of the associated sediments, {delta}-MnO Sub(2) as the only Mn-phase, and relatively high concns of minor elements associated with Fe. There appears to be a smooth gradation in composition in the tropical Pacific between these 2 end members. The retional compositional variation is interpreted as a reflection of different sources of metals for, and different growth mechanisms of, sea-floor nodules. The oxide precipitate from sea water consists of {delta}-MnO Sub(2), has a relatively low Mn/Fe ratio and minor element contents related to the total Fe and Mn({delta}-MnO Sub(2)) content. The oxide precipitate forming in areas of very low sedimentation as a result of diagenetic remobilisation in the surface sediment consists of todorokite, and has a high Mn/Fe ratio and enhanced metal content in the Mn-(todorokite) phase. Available information on the morphology and compositional variation of individual nodules from the tropical Pacific corroborates these contrasting metal sources and suggests that they can be resolved on the scale of an individual oxide concretion.

Description: Bulk composition of ferromanganese nodules from the pelagic environment of the Pacific Ocean is apparently related to nodule-growth rate, sediment-accumulation rate, and biologic productivity in the overlying seawater. Nodules with a high Mn/Fe ratio and high Ni and Cu concns tend to occur in areas where primary productivity in the surface layer of the ocean is high and the sediment accumulation rate low. They may have a Mn/Fe ratio as low as one and accrete at rates as low as 1 mm/10 M yrs. Nodules with a larger Mn/Fe ratio apparently have growth rates that are greater by as much as a factor of 10.

Description: Information on possible resource value of sea floor manganese nodule deposits in the eastern north Pacific has been obtained by a study of records and collections of the 1972 Sea Scope Expedition.

Description: It is the purpose of this chapter to present information available at the time of publication on the internal features of manganese nodules, to offer genetic interpretations of these features, and to suggest new lines of research. To judge from the limited data available on ocean floor crusts rich in manganese and iron (see, for example, Aumento et al., 1968, doi:10.1594/PANGAEA.862565 ), much of what is learnt about nodules may be applied eventually to an understanding of the origin of these more continuous masses. A genetic relationship between these two is likely.

Description: The plateau is a foundered continental block, and lies at an average depth of 2000-3000 m. On the plateau the dominant fault direction is NW to WNW, an ancient strike direction on the Australian continent. The western margin probably formed as a series of NE-trending rifts and NW-trending transforms during Late Jurassic breakup. Canyons cut the western margin, and some of these appear to be fault-bounded. One such fault forms the northern margin of a major NW-trending feature, the Wilson Spur. This appears to be a transform fault and perhaps extends across the abyssal plain as far as the eastern end of the Java Trench. Seismic profiles suggest that, at the trench, it separates thrust-faulted continental crust to the east from oceanic crust to the west. This could explain the eastern termintion of the deep part of the trench. The bathymetric depression of the Roti Basin, which lies southeast of the Java Trench, links the trench to the Timor Trough. The Argo Abyssal Plain slopes gently southward, with water depths ranging from 5000 m near the Java Trench to 5730 m in the south. Oceanic basement varies from smooth to hummocky and irregular, and is overlain by about 4000 m of acoustically semi-transparent Late Jurassic and Cretaceous sediments, that is in turn unconformably overlain by 200 m of layered Tertiary sediment. Bottom samples from the outer Scott Plateau show that Callovian breakup was preceded by a period of basic volcanism and shallow marine sedimentation, that restricted shallow marine conditions followed in the Late Jurassic, and that bathyal carbonate sedimenation prevailed by the Late Cretaceous (Campanian). Quaternary marls cored on the northern Scott Plateau straddled the Pleistocene-Holocene boundary, and siliceous oozes cored on the southern slope of the Java Trench contain nannofossils which, below a few decimetres, are older than late Pleistocene. The Java Trench cores indicate that the calcite compensation depth was apparently between 5420 and 5700 m in the early or midel Pleistocene, and is above 4950 m now. The Scott Plateau cores indicate that the present calcite compensation depth in the region lies below 3290 m. On the Scott Plateau Holocene sedimentation rates are about 5 cm/1000 years, but in the Java Trench they are much lower. Manganese oxide crusts and nodules were recovered from the Scott Plateau, but their content of valuable metals was low.

Description: Times of vein mineral deposition in the ocean crust have been determined both by Rb-Sr isochron ages of vein smectites and by comparison of 87Sr/86Sr ratios of vein calcites with the known variations of seawater 87Sr/86Sr ratio with time. Results from drilling sites 105, 332B and 418A, Atlantic Ocean, which have basement formation ages of 155 m.y., 3.5 m.y., and 110 m.y., respectively, show that vein deposition is essenrially complete within 5-10 m.y. after formation of the basaltic crust. This provids direct evidence that hydrothermal circulation of sea-water through the oceanic crust is an important process for only 5-10 m.y. after crust formation.