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  • Other Sources  (168)
  • Elsevier  (100)
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  • 1976  (10)
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  • 1995-1999  (82)
  • 1990-1994  (76)
  • 1975-1979  (10)
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  • 1
    Publication Date: 2022-08-04
    Description: Im Zuge der geologisch-telmatologischen Untersuchung des geplanten Prüfgeländes der Mercedes-Benz AG in Papenburg sind zahlreiche Bohrungen in sehr dichtem Abstand in den Mooren südöstlich von Papenburg durchgeführt worden. Die dortigen Hochmoore (Wildes Moor, Kortemoor und Klostermoor) erwiesen sich als z. T. wurzelecht, z. T. vom Versumpfungsmoortyp mit Schwarztorf-Auflage auf Mudden, lokal auch auf Niedermoor- und Bruchwaldtorf. Eine enge Bindung der Vermoorung an Ortsteinhorizonte einer frühpostglazialen Podsolierung, welche sowohl über den Talsanden als auch den Älteren Flugsanden ausgebildet ist, ist festzustellen. Die Hochmoortorfbildung setzt üblicherweise erst in der zweiten Hälfte der Pollenzone VII, gleichzeitig mit der Neolithischen Revolution ein. Starke Beteilung von Eriophorum ist für die Schwarztorfe typisch. Die der Leda und Ems tributären Nebenflüsse zeigen eine spätglazial-frühpostglaziale, auf den spätweichselzeitlichen tiefen Meeresspiegel bezogene Einschneidungsphase in die weichselzeitliche Talsandebene. Mit dem postglazialen Meeresspiegelanstieg schritt die Akkumulation - auf die ansteigende Vorflut eingespielt - von den Flußunterläufen aufwärts fort. Junge Dünenzüge begleiten die für die Siedlungsgeschichte wichtigen Talsandterrassenränder, hinter denen das Sphagnentorfwachstum bis in die Weißtorffazies fortschritt.
    Description: research
    Keywords: ddc:551.7
    Language: German
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  • 2
    Publication Date: 2022-08-02
    Description: Funde nicht-alpiner Gerölle südlich des altpleistozänen Donaulaufs in der östlichen Iller-Lech-Platte werden als umgelagerte Reste pliozäner Donauschotter gedeutet und geben so erste Hinweise auf ein Ausgreifen der Donau 35-40 km südlich ihres heutigen Laufs. Die bisher als Tertiärrelikt angesehene Dinkelscherbener Altwasserscheide dieses Bereichs kann somit erst im Pleistozän entstanden sein und dürfte kaum am Staufenberg vorbei weiter nach NNO gereicht haben.
    Description: research
    Keywords: ddc:551.7
    Language: German
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  • 3
    Publication Date: 2022-08-05
    Description: Korngrößen-, Kies- und Schwermineralanalysen würmzeitlicher Grundmoränen-Ablagerungen des Rheingletschers im baden-württembergischen Alpenvorland zeigen einen meist relativ niedrigen Einfluß des aus Molasse bestehenden Substrats auf die Zusammensetzung dieser Sedimente. Auf Grund theoretischer Überlegungen und großmorphologischer Beobachtungen wird geschlossen, daß auch die Aufnahme präexistierender quartärer Ablagerungen untergeordnet war und daß die Petrographie der Moränen-Ablagerungen hauptsächlich bestimmt wird vom während der letzten Vorland-Vergletscherung vom Rheingletscher ins Vorland transportierten Schutt.
    Description: research
    Keywords: ddc:551.7
    Language: English
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  • 4
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    Geozon Science Media
    Publication Date: 2022-08-05
    Description: Mineralische Rohstoffe werden in großen Mengen für die verschiedensten Wirtschaftszweige benötigt. Die Gewinnung oberflächennaher Rohstoffe bedingt i. a. eine Abbaugrube, welche später wieder in die Umgebung eingefügt, d. h. rekultiviert oder renaturiert, werden muß. Im Zuge eines erstarkenden Umwelt- und Ökologiebewußtseins ist der Renaturierung verstärkte Aufmerksamkeit zu schenken.
    Description: research
    Keywords: ddc:551.7
    Language: German
    Type: doc-type:article , publishedVersion
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  • 5
    Publication Date: 2022-08-05
    Description: Verschieden alte, datierte Böden auf den Niederterrassen des Rheins werden mikromorphologisch charakterisiert und ausgewählte Merkmale dem Bodenalter gegenübergestellt. Klare Beziehungen zum Alter zeigen. Entkalkung und Tonwanderung. Bereits in der Gruppe der 1800jährigen Böden wird eine Entwicklung sichtbar. Ab 6000 Jahren kommen Parabraunerden vor. Stark entwickelt sind die Böden auf präholozänen Sedimenten. Die Bodenbildung in situ wird vom Wechselspiel aus Bodenentwicklung und -abtrag im Liefergebiet der Sedimente mitbestimmt. Die im Liefergebiet begonnene Silicatverwitterung läuft in der Aue weiter, während die Horizontdifferenzierung durch Tonverlagerung nach dem Transport in der Aue neu beginnt. Die Böden aus präholozänen Sedimenten können kurzstreckig verlagertes Material von Bt-Horizonten eemzeitlicher Böden enthalten. Die systematische Stellung der Böden wird diskutiert. Die Bedeutung der Tonwanderung zwischen Sandkörnern wird anhand verdichteter Böden des Versuchsgutes Wahn dargestellt.
    Description: research
    Keywords: ddc:551.7
    Language: German
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  • 6
    Publication Date: 2022-08-05
    Description: Die modernen Anforderungen an den Trinkwasserschutz, die zunehmende Zersiedelung und die landwirtschaftliche Nutzung weiter Teile der Niederrheinischen Bucht führen immer häufiger zu Nutzungskonflikten. Da die einmal vorhandenen Nutzungsstrukturen wie Naßabgrabungen und Gewerbegebiete die Flächen für eine schutzfähige Grundwassergewinnung reduzieren, bleibt oft nur die Verlagerung der Trinkwassergewinnung in zuvor nicht beanspruchte Gebiete. Am Beispiel einer Prognose für die Verschiebung einer Entnahmegalerie aus einer Zone mit gewerblicher und lagerstättentechnischer Nutzung im Umfeld des Xantener Stauchmoränenbogens kann gezeigt werden, daß auf der Grundlage quartärgeologischer Grundlagendaten und eines numerischen Grundwasserströmungsmodells eine Optimierung der Ortslage für eine Trinkwassergewinnung durchgeführt werden kann. Die eiszeitliche Überprägung weiter Teile des hydrogeologischen Grundwasserleitersystems im Xantener Bogen bedingte zahlreiche Restriktionen für die Optimierung eines Grundwassergewinnungsbereichs. Mit Hilfe der Geländeaufnahmen und der Modellrechnungen wurden verschiedene neue Brunnenstandorte simuliert und hinsichtlich der ökologischen und hydrogeologischen Restriktionen bewertet. Die Modellrechnungen ermöglichten bereits im Planungsstadium eine Vorausschau auf die Auswirkungen und den Nutzen einer Verlagerung der ursprünglichen Entnahmeschwerpunkte. Die Ergebnisse zeigen aber auch, daß ein Ausweichen der Trinkwassergewinnung zugunsten anderer Flächennutzungen mit neuen Restriktionen am neuen Standort verbunden sein kann und somit in jedem Einzelfall zu überprüfen ist.
    Description: research
    Keywords: ddc:551.7
    Language: German
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  • 7
    Publication Date: 2022-08-05
    Description: Die MATUYAMA/BRUNHES-Grenze konnte am Mittelrhein in der Schichtenfolge von Kärlich relativ stark eingeengt werden. Sie ist dort älter als die 6. Eiszeit vor heute und liegt in einer Wechselfolge von Sedimenten, die dem „Ville-Interglazial-Komplex" zugeordnet wird. Möglicherweise muß diese Grenze sogar noch etwas tiefer gelegt werden in einen Horizont mit ersten Zeugnissen eiszeitlichen Dauerfrostbodens. In allen anderen untersuchten Lokalitäten ist die Lückenhafbigkeit der Überlieferung zu groß für detailliertere Aussagen. Die MATUYAMA-Epoche ist vorerst sowohl am Rhein wie an der Donau wegen der vorwiegend gröberklastischen Gesteinsfazies nur bedingt mit der Feingliederung des ältesten Pleistozäns korrelierbar. So sind in der Ville (Tgb. Frechen) mehrere altquartäre warmklimatische Tonhorizonte revers magnetisiert (Tonhorizont B2 und C). Darüber folgt ein normal magnetisierter Horizont (Tonhorizont D), der sich ebenfalls noch im Liegenden der Hauptterrassenfolge befindet. Schließlich wurde neuerdings im Liegenden dieser Abfolge ein weiterer, bereits quartärer Horizont (Bl) gefunden, in welchem sich eine Umpolung von normal nach revers vollzieht. Die Schwierigkeit besteht vorerst noch darin, diese Abfolge geobotanisch genauer zu definieren. Die GAUSS-Epoche läßt sich hingegen in einen guten Zusammenhang mit dem mittleren bis höheren Pliozän bringen (Brunssumium bis mittleres Reuverium). Die Tertiär/Quartär-Grenze auf geobotanischer Grundlage kann nach diesen Befunden etwa mit 2 Mio. Jahre vor heute relativ gut festgelegt werden; denn im höchsten Reuverium (C), das zumeist der Erosion zum Opfer gefallen ist, wurde bereits die Umpolung zur reversen Matuyama-Epodie (Beginn rd. 2,4 Mio. Jahre vor heute) gefunden.
    Description: research
    Keywords: ddc:551.7
    Language: German
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  • 8
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    Elsevier
    In:  Amsterdam, 357+IX pp., Elsevier, vol. 121, no. Publ. No. 12, pp. 127, (ISBN 0-521-66034-3, ISBN 0-521-66948-0 paper)
    Publication Date: 1976
    Keywords: Earthquake precursor: prediction research ; Textbook of geophysics
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  • 9
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    Springer
    In:  Bull., Polar Proj. OP-O3A4, Handbuch zur Erkundung des Untergrundes von Deponien und Altlasten hrsg. von der Bundesanstalt für Geowissenschaften und Rohstoffe, Heidelberg, Springer, vol. 3, no. 1, pp. 81-92, (ISBN: 3-540-23712-7)
    Publication Date: 1997
    Keywords: Applied geophysics ; environment ; waste ; disposal ; Seismics (controlled source seismology) ; Geoelectrics ; Gravimetry, Gravitation ; RADAR ; Borehole geophys. ; Physical properties of rocks ; Handbook of geophysics ; Knodel
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  • 10
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    Elsevier
    In:  Int. J. Rock Mech. & Min Sci., Taipei, Elsevier, vol. 34, no. 3-4, pp. 155-162, pp. B09401, (ISBN: 0-12-018847-3)
    Publication Date: 1997
    Keywords: Borehole geophys. ; Stress ; Borehole breakouts ; Hydraulic fracturing ; stability ; Anisotropy ; shear ; tensile ; Strength ; Rock mechanics
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  • 11
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    Elsevier
    In:  Amsterdam, Elsevier, vol. 1, no. 22, pp. 65-70, (ISBN 3-7643-0253-4)
    Publication Date: 1976
    Keywords: Textbook of geophysics ; Filter- ; Recursive filters
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  • 12
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    Elsevier
    In:  Amsterdam, Elsevier, vol. 65, no. ALEX(01)-FR-77-01, AFTAC Contract F08606-76-C-0025, pp. 95-104, (ISBN: 0-08-044051-7)
    Publication Date: 1993
    Keywords: Textbook of geophysics ; GeodesyY ; Geothermics ; Planetology ; ConvolutionE
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  • 13
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    Springer
    In:  Bull., Polar Proj. OP-O3A4, Contributions to the 6th Annual KTB-Colloquium: Geoscientific Results, Berlin, Springer, vol. 66, no. 2, pp. 277-291, (ISBN 0-87590-532-3, AGU Code: GD0305323)
    Publication Date: 1997
    Keywords: Earth tides ; poro-elasticity ; pressure ; permeability ; porosity ; Fluids ; Review article
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  • 14
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    Elsevier
    In:  Int. J. Rock Mech. & Min. Sci., Hannover, Elsevier, vol. 34, no. 3-4, pp. 13021-13032, pp. L15S14, (ISSN: 1340-4202)
    Publication Date: 1997
    Keywords: Stress ; Stress measurements ; Hydraulic fracturing ; Borehole geophys. ; stability ; North ; Sea ; Norway
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  • 15
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    Springer
    In:  New York, Springer, vol. 1, no. 1, pp. 65-66, (ISBN 0 340 76405 8)
    Publication Date: 1976
    Keywords: Stress ; Textbook of geophysics ; Textbook of geology ; Elasticity
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  • 16
    Publication Date: 2020-07-14
    Description: Horizontal starch gel electrophoresis was used to investigate levels of genetic differentiation between four samples of the nominate squid species Martialia hyadesi Rochbrune and Mabille, 1889, obtained from regions of the Patagonian Shelf and Antarctic Polar Fron-tal Zone over 1000 km apart. M. hyadesi is an ecologically important South Atlantic ommastrephid squid and it is probable that, in the future, fishing effort will be increasingly directed towards this species. Details regarding the population structure of the species are therefore required. In comparison with the other three samples of M. hyadesi, one of the samples from the Patagonian Shelf (PAT 89II) exhibited fixed allelic differences at 16 of the 39 enzyme loci which were resolved (genetic identity, I=0.51). This high level of genetic differentiation contradicts the apparent morphological similarity between samples, indicating the presence of a cryptic or sibling congeneric species. Deviations from Hardy-Weinberg equilibrium and significant differences in allele distribution were also detected within and between the other three putative M. hyadesi samples, suggesting that the species fails to maintain effective panmixia across its geographical range. The occurrence of both temporal (1986 cf. 1989) and geographic structuring within the species complex is consequently indicated, caused possibly by an overlap of reproductively isolated stocks (stock mixing) outside their respective breeding areas. Low levels of genetic variability were detected throughout the samples examined, estimates of average heterozygosity per locus within the two species detected being in the order of 0.01 and 0.002. These values are discussed in relation to levels of genetic variability reported for other squid species, and in comparison with values typically expected for marine invertebrates.
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  • 17
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    Springer
    In:  Fortschritte der Chemie Organischer Naturstoffe, 33 (1). pp. 1-72.
    Publication Date: 2017-10-11
    Description: Since organic chemistry began, the chemistry of natural products from terrestrial organisms such as plants and fungi has been studied intensively; in contrast, marine species have received relatively little attention. However, in the last decade research in the field of marine products has increased sbstantially. The heightened interest in this area is attested by the appearance of the monumental treatise of Halstead on Poisonous and Venomous Marine Animals in 1965 (108), Baslow’s review on “Marine Pharmacology” in 1969 (14) and Scheuer’s recent book “Chemistry of Marine Natural Products” (160) in 1973. In addition Premuzic’s review devoted to the Chemistry of Natural Products Derived from Marine Sources, was published in volume 29 of this series in 1971 (152).
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  • 18
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    Springer
    In:  Marine Biology, 115 (1). pp. 143-150.
    Publication Date: 2018-03-21
    Description: Lower and upper survival temperatures of microthalli of 25 species of South American Phaeophyceae isolated from central Peru (14°S) to the Canal Beagle (55°S) were determined using 2-wk exposure for the upper and 4-wk exposure for the lower limit. All species survive 4 wks at -2°C. With respect to the upper limit, species reported only from southernmost South America tolerate 19.9 to 24.5°C (n=8), and species occurring from Cape Horn to central Chile 24.6 to 27.4°C (n=7). Three species that occurred as far north as northern Chile and Peru before the 1982–1983 El Niño event, and whose northern limit was dramatically shifted southwards in 1983, tolerate 20.8 to 25.3°C, whereas five species that have survived in Peru tolerate 25.6 to 28.5°C. Tinocladia falklandica which tolerates 27.8 to 28.1°C but lives only in southernmost South America and Striaria attenuata, which tolerates 31.6 to 31.9°C but occurs at ca. 42°S, are exceptional. Their high temperature tolerance may have no adaptive value in South America. They are restricted to the cold-temperate region due to low temperature requirements for reproduction or for reasons yet unknown. In general, the northern distributional limits of the Phaeophyceae studied along the temperate Pacific coast of South America are reproduction boundaries, except in El Niño years when they are redefined according to the species' upper suvival limits. Temperature tolerance of isolates from northern Chile and Peru agrees well with maximum temperatures reached during the 1983 El Niño.
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  • 19
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    Springer
    In:  Fresenius' Journal of Analytical Chemistry, 345 (12). pp. 773-779.
    Publication Date: 2018-03-23
    Description: During a cruise in the Baltic Sea in March/April 1991, dissolved lipids were concentrated from acidified sea water by adsorption on reversed phase material; the free fatty acids in the lipids were isolated. Titration of the acids with 0.01 mol/l methanolic KOH resulted in a very poor titration curve; assessing total concentration of organic acids in sea water by base titration appears to be impractical. After derivatization with p-phenylphenacyl bromide under crown ether catalysis the fatty acids were analyzed by micro-bore HPLC with UV-detection and comparison with standard reference substances. Some unknown fatty acids were characterized by GC/MS. Total concentrations were in the range from 1 to 4.5 nmol/l. They were the same in parallel samples liquid/liquid extracted with dichloromethane. The HPLC spectra of the fatty acids in both kinds of samples were also quite similar. This confirms earlier observations that adsorptive concentration of dissolved fatty acids and non-polar lipids from sea water is as effective as liquid/liquid extraction. Higher amounts of fatty acids can be concentrated by adsorption from large water volumes, thus lowering detection limits. Palmitic acid had by far the highest concentration in every sample followed by myristic acid, lauric acid, and stearic acid. Palmitoleic acid and oleic acid were the most abundant unsaturated acids. The other saturated and unsaturated acids had medium to low concentrations.
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  • 20
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    Elsevier
    In:  Marine Pollution Bulletin, 26 (3). pp. 152-155.
    Publication Date: 2018-03-22
    Description: Skin and hair samples of harbour seals (Phoca vitulina) found dead along the west coast of northern Germany in 1988 were analysed for total mercury, cadmium and lead. Cadmium and lead concentrations were below the detection limit in most skin samples. The mercury content of the hair (median: 23.1 μg g−1 wet wt) was several magnitudes higher than the mercury content of the skin (0.27 μg g−1 wet wt). Mercury concentrations in hair samples were significantly higher than lead concentrations (0.54 μg g−1 wet wt), which significantly exceeded cadmium levels (0.09 μg g−1 wet wt). Female seals revealed lower cadmium concentrations in the hair than male seals. Accumulations of metals with age were observed for cadmium and lead in hair samples and for mercury in skin samples of male seals. A connection between metal accumulation and pigmentation or rather moult was clearly recognizable.
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  • 21
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 40 (2). pp. 267-291.
    Publication Date: 2018-03-22
    Description: The spreading of Mediterranean Water (MW) released through the Straits of Gibraltar is studied with hydrographic data, oxygen, nutrients and for the first time with chlorofluoromethane (CFM, compounds F11 and F12) distributions along seven sections in the Gulf of Cadiz, and with measurements in the Western Alboran Sea and west of the Gulf. The properties of MW entering the Gulf are deduced from CFM-salinity correlations east and west of the Straits as well as from property-depth profiles in the Western Alboran Sea. At the time of the survey, the outflow originated from depths above the salinity maximum of the Intermediate Water in the Alboran Sea. It turned out that the F11/F12 ratio of the outflow is equal to the ratios found in the Atlantic water in the Gulf of Cadiz; thus the ratio carries no time information in the region. A model is developed to describe mixing of the MW undercurrent with overlying North Atlantic Central Water (NACW) from different depths. The contribution of each layer to the mixing is parameterized by a weighting factor, which has to satisfy the balances of potential temperature (θ), CFMs, oxygen and nutrients in the MW undercurrent. It is shown that entrainment of water from shallower depths into the undercurrent is important near the Iberian Continental Shelf. Farther west and south, the undercurrent mainly mixes with water from near the salinity minimum of the NACW. For regions where the undercurrent has left the bottom, additional mixing with North Atlantic Deep Water (NADW) has to be taken into account. The percentage of MW in the undercurrent decreases from 76% hear the Straits to about 34% at 7°30′W for the lower core (MI) and about 22–24% for the upper core (Mu). Assuming an outflow of undiluted MW through the Straits of 1.0 Sv, the transport of the undercurrent can be calculated by determining an average dilution factor for each section. The undercurrent transports 2.0 Sv just west of the Straits and 3.6 Sv leave the Gulf of Cadiz. At 36°N, 9°54′W, a meddy with unusually high temperatures and salinities below 500 m was found, covering the density range for both cores, Mu and Ml. From the θ−S characteristics and the evaluated mixing scheme of the meddy it appears to have formed near 7°W in the Gulf, a region up to now not proposed in the literature, and moved westward without much further mixing.
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  • 22
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    Elsevier
    In:  International Journal for Parasitology, 23 (6). pp. 749-755.
    Publication Date: 2018-03-23
    Description: In April 1990, 488 marine fish belonging to 30 species from central Phillipine waters were examined for flesh parasitic infections that may affect their consumability. One species of hemirhamphids and 3 species of belonids harboured plerocercoids of Otobothrium penetrans Linton, 1907 (Proceedings of the U.S. National Museum33, 85–126). This is the first record of this parasite from Pacific fish species. The highest intensity of infection found was 8 in Tylosurus crocodilus. Most of the larvae were located between the dorsal spines of the vertebral column, only 32% were found in the fillets. Based on the present material we give a description of the plerocercoid stage of the species using scanning electron microscopy of the armature and morphometrical measurements. Comparison to results from earlier findings of O. penetrons by Linton (1907; 1924, Proceedings of the U.S. National Museum64, 1–114) and to O. kurisi by Shields (1985, International Journal for Parasitology15: 635–643) lead to the conclusion that the latter species is a synonym for O. penetrans.
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  • 23
    Publication Date: 2018-03-21
    Description: Nine large box cores collected in the western Greenland-Iceland-Norwegian (GIN) Sea were analyzed for calcium carbonate content and coarse fraction components. Stratigraphic control is based on oxygen isotope records performed on four of the cores. All cores were correlated using oxygen and carbon isotope data, fluctuations in calcium carbonate content, coarse terrigenous particle content and volcanic ash beds. Glacial and interglacial cycles are documented by a number of terrigenous particle events and differentiated calcium carbonate production which can be correlated to major paleoceanographic and paleoclimatic shifts. In the older core sections, extensive deposition of ice-rafted detritus (IRD) persisted until about oxygen isotope stage 9 and document a relatively stable environment in this area, strongly influenced by cold surface water masses. The following interval was characterized by variations in the general surface water circulation pattern, although high amounts of IRD are still present in Iceland Sea sediments. Pronounced shifts in terrigenous input and pelagic carbonate records were identified close to the oxygen isotope stage Full-size image (〈1 K) and Full-size image (〈1 K) boundaries, indicating massive melting of icebergs in the western GIN Sea. These enormous inputs of debris were followed by an increase in calcium carbonate production caused by maximum intrusion of warm Atlantic surface waters. Relatively high calcium carbonate contents also show that only little dilution by fine-grained material and a minimum of ice melting occurred during these warm phases. During oxygen isotope stage 5, conditions were more uniform indicating a less pronounced westward penetration of Atlantic waters as compared to the Holocene. The last glacial (stages 4-2) is characterized by the occurrence of “Heinrich”-like events, although high IRD contents were present throughout this interval. A distinct contrast between the northernmost cores and the cores in the south is indicative of a rather strong westward penetration of Atlantic water in the north and of an area dominated by cold water east of the Kolbeinsey Ridge during the Holocene. However, conditions west of Jan Mayen seem to have remained constantly dominated by cold surface waters throughout the whole time investigated.
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  • 24
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    Springer
    In:  Cell and Tissue Research, 167 (2). pp. 229-241.
    Publication Date: 2020-07-24
    Description: A single layer of cells secretes the hard cephalopod beaks. The beccublasts are tall columnar cells that separate the beak from the surrounding buccal muscles, and must serve to attach these muscles to the beak. Within the cell layer there are three types of cells. The first, and most frequently found contain cell-long fibrils. These fibrils may have contractile and tensile properties. Complex trabeculae extend from the beccublasts into the matrix of the beak. The fibrils are attached to these trabeculae and at the other end of the cells they are anchored near to the beccublast-muscle cell interface, closely associated with the muscles that move the beak. The second group of cells contain masses of endoplasmic reticulum the cysternae of which are arranged along the long axis of the cell. These cells also contain dense granules and are probably the major source of beak hard tissue. It is probable that each cell secretes its own column of beak hard tissue. The third group of cells contains a mixture of fibrils and secretory tissue. In the beccublast layer there are changes in the proportion of the three types of cells depending upon the region sampled. In the region where growth is most active there are mostly secretory cells, whereas near the biting and wearing tip there are mainly anchoring type cells.
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  • 25
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    Elsevier
    In:  Deep Sea Research Part II: Topical Studies in Oceanography, 40 (3). pp. 783-800.
    Publication Date: 2018-03-05
    Description: Horizontal distribution of myctophid fishes were studied from two transects in the Arabian Sea in 1987. Species numbers exhibited a south-north decline in diversity, with only half of the fish taxa occupying the northeastern region. Diaphus arabicus was the dominant species both in the south and north. All recorded myctophid fish species migrate in a diel pattern, residing during daytime at depths of extremely low oxygen levels (〈0.1 ml O2 1−1) and foraging in the oxygen-rich surface layer at night. Feeding patterns were determined for the six most abundant myctophid species. All species appeared to be opportunistic predators that prey on a comparatively narrow food spectrum consisting principally of small to medium sized copepods. Numerically, non-calanoid copepods (with Oncaea conifera and O. venusta dominating) made up to 70% of the diet of D. arabicus and Bolinichthys longipes. Of the 26 calanoid copepod species identified from the six myctophid taxa, the genera Euchaeta, Pleuromamma and Candacia generally dominated in the stomachs, with P. indica constituting between 21 and 95% (by numbers) of the calanoid copepod prey.
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  • 26
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 40 (6). pp. 1155-1168.
    Publication Date: 2018-03-05
    Description: Particulate fluxes of aluminium, cadmium, cobalt, copper, iron, manganese, nickel, phosphorus, lead, vanadium and zinc in the northeast subtropical Atlantic Ocean have been determined from sediment trap samples collected between 1 December 1986 and 30 April 1987 at 1020 and 4120 m below the ocean surface. The fluxes of most elements (except Cd and P) show small variations between the different layers, and are closely associated with the vertical transport of aluminium. Elemental composition and flux rates suggest that aerosol loadings from northeast trade winds are the major contributor of these elements to depositing material. Extremely low fluxes of copper, lead and zinc also indicate that anthropogenic perturbations are of insignificant importance in this region.
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  • 27
    Publication Date: 2018-03-05
    Description: Within the framework of the JGOFS Pilot Study in 1989 mesozooplankton (0.2–20 mm) was sampled by means of a Hydro-Bios multinet in five depth strata (0–25, 25–50, 50–100, 100–200, 200–500 m) during four Lagrangian drift experiments of 8–14 days' duration at 18, 33, 46 and 58°N, to follow the seasonal progress of the phytoplankton spring bloom development in the northeast Atlantic. Mesozooplankton standing stock, measured as dry weight and ash-free dry weight, increased by a factor of about 6 from 18 to 58°N. Day/night differences amounted to 10–20% of the average and were—with one exception at 18°N—not statistically significant. Using the data on weight-specific respiration rates measured by colleagues on the same cruise, the ingestion rates and potential community grazing of mesozooplankton on phytoplankton within the upper 100 m of the water column were calculated. During all four drift experiments, quasi-steady-state conditions were observed in phyto- and zooplankton standing stock, primary production and daily sedimentation at 100 m depth. The maximum potential grazing rate by mesozooplankton accounted for about half of the daily primary production. Since sedimentation of fresh phytoplankton was negligible, it is concluded that the grazing pressure exercised by mesozooplankton together with micro- and nanozooplankton was responsible for keeping the phytoplankton standing stock at a more or less constant level during the investigated spring bloom in the four areas. Particle flux was thus dominated by zooplankton faecal material.
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  • 28
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    Elsevier
    In:  Journal of Chromatography A, 642 (1-2). pp. 425-434.
    Publication Date: 2019-02-27
    Description: Accurate congener-specific determination of chlorobiphenyl congeners (all 209 congeners) is finally possible with the use of multidimensional gas chromatography-electron-capture detection techniques. The effectiveness of this technique for environmental analyses is enhanced by ultraclean laboratory practices, non-destructive extraction and clean-up steps and the use of low-volume, high-efficiency HPLC separation for various classes of organic contaminants. In the light of these new developments conventional procedures for chlorobiphenyl analysis are evaluated.
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  • 29
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    Elsevier
    In:  Deep Sea Research Part II: Topical Studies in Oceanography, 40 (3). pp. 711-735.
    Publication Date: 2018-03-05
    Description: The productivity regime and size structure of phytoplankton are described for three different epipelagic systems in the Arabian Sea during the inter-monsoon period in spring 1987: (1) the coast of Oman; (2) the central Arabian Sea; and (3) the shelf off Pakistan. These results are related to the functioning of the specific ecosystem. Off the coast of Oman, the transition from a surface maximum of autotrophic biomass and production to a more oligotrophic system, with a chlorophyll subsurface maximum, was observed. Concomitantly, the size spectrum changed towards a higher significance of picoplankton. In the central Arabian Sea, a typical oligotrophic system with a pronounced subsurface maximum of autotrophic biomass and primary production was encountered. Here, the epipelagic system could be divided into two distinct sub-systems: the surface layer “regenerated” production, the predominance of picophytoplankton and minor losses due to sedimentation, thus a “closed” system; and the subsurface maximum layer at the nutricline characterized by higher sedimentation losses and more diatoms. Both sub-systems showed about the same productivity, the turnover in the surface layer having been much greater than in the subsurface maximum. The system on the shelf off Pakistan is seen as a decay stage of the open ocean system when water from offshore is transported onto the shelf during the onset of monsoon winds.
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  • 30
    Publication Date: 2018-03-21
    Description: Crossing studies revealed an intraspecifìc sterility barrier on the level of zygote formation between Japanese Sphaerotrichia divaricata and isolates of the same species from the Northeast Pacific and the North Atlantic. Because no consistent morphological differences exist between sporophytes from Japan and other areas, we propose not to distinguish the intersterile populations as different species. Japanese Sphaerotrichia and isolates from a recently detected population in the Étang de Thau, French Mediterranean coast, are interfertile. The crossing studies support the assumption that this Mediterranean population is a recent introduction from Japan.
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  • 31
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    American Chemical Society
    In:  ACS Division of Fuel Chemistry Preprints, 42 (2). pp. 544-547.
    Publication Date: 2018-04-11
    Description: Test specimens of methane hydrate were grown under static conditions by combining cold, pressurized CH4 gas with H2O ice grains, then warming the system to promote the reaction CH4 (g) + 6H2O (s???l) ??? CH4??6H2O. Hydrate formation evidently occurs at the nascent ice/liquid water interface, and complete reaction was achieved by warming the system above 271.5 K and up to 289 K, at 25-30 MPa, for approximately 8 hours. The resulting material is pure methane hydrate with controlled grain size and random texture. Fabrication conditions placed the H2O ice well above its melting temperature before reaction completed, yet samples and run records showed no evidence for bulk melting of the ice grains. Control experiments using Ne, a non-hydrate-forming gas, verified that under otherwise identical conditions, the pressure reduction and latent heat associated with ice melting is easily detectable in our fabrication apparatus. These results suggest that under hydrate-forming conditions, H2O ice can persist metastably at temperatures well above its melting point. Methane hydrate samples were then tested in constant-strain-rate deformation experiments at T= 140-200 K, Pc= 50-100 MPa, and ????= 10-4-10-6 s-1. Measurements in both the brittle and ductile fields showed that methane hydrate has measurably different strength than H2O ice, and work hardens to a higher degree compared to other ices as well as to most metals and ceramics at high homologous temperatures. This work hardening may be related to a changing stoichiometry under pressure during plastic deformation; x-ray analyses showed that methane hydrate undergoes a process of solid-state disproportionation or exsolution during deformation at conditions well within its conventional stability field.
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  • 32
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    Springer
    In:  Polar Biology, 13 (5). pp. 355-357.
    Publication Date: 2020-06-10
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  • 33
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    Springer
    In:  Polar Biology, 13 (6). pp. 373-376.
    Publication Date: 2020-06-10
    Description: Regurgitations were collected from 41 black-browed albatross adults feeding chicks at Bird Island (54°S 38°W), South Georgia in February 1986. The samples were sorted into recognisable food categories and weighed. Cephalopods were identified by means of the lower beak, or in some cases the gladius, and allometric equations were used to calculate mantle length and wet body weight represented by beaks. The samples contained 35.5%Euphausia superba, 30.9% cephalopods and 27.1% fish, by weight. A total of 21 samples contained recognisable cephalopod remains and 20 contained specimens that could be identified. In all, 50 cephalopod specimens, representing an estimated 6,866 g wet weight, were identified. The diet was dominated in terms of numbers, weight and percent occurrence by the ommastrephid squidMartialia hyadesi, and in most cases the entire squid was present with only partial digestion of the skin and arm armature. The cranchiid squidGaliteuthis glacialis was the only other cephalopod of numerical importance but no soft parts were present suggesting that, although significant in the diet of the adults, this species was not being fed to chicks. One specimen each ofGonatus antarcticus, Chiroteuthis sp.,Histioteuthis sp. B. and the octopodidPareledone polymorpha were also present. The cephalopod composition of the diet corresponded closely with a collection made 10 years earlier. The commonest species in the bird's diet,M. hyadesi, has not been found in net and jig samples at South Georgia although it has been taken from the Antarctic Polar Frontal Zone to the west of the Island. The presence of almost complete, undigested, specimens ofM. hyadesi in the bird's diet indicates that it occurs relatively close to South Georgia.M. hyadesi preys largely on myctophid fishes, which themselves prey on small zooplankters, so a significant component of the black-browed albatross diet depends on a food chain which largely by-passesE. superba.
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  • 34
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    Springer
    In:  Marine Biology, 117 . pp. 495-500.
    Publication Date: 2017-04-28
    Description: The accumulation of parasites in a fish host is modelled as a function of the total amount of prey consumed. The accumulated parasite load is then expressed as a function of fish length so that the asymptotic growth, L∞, of any population of commonly infected fish can be estimated. Estimates of L∞ are obtained for orange roughy (Hoplostethus atlanticus), albacore tuna (Thunnus alalunga) and the New Zealand southern arrow squid (Nototodarus sloanii).
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  • 35
    Publication Date: 2018-01-19
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  • 36
    Publication Date: 2018-03-07
    Description: In February 1988, 60 near surface samples were taken on a track between 2°W in the English Channel, the Pentland Firth and the inner German Bight. Determinations were made on filtered and unfiltered samples. Concentrations of dissolved metals in the North Sea normalized to a salinity of 34.5 were Al 31, Cd 0.13, Co 0.13, Cu 3.4, Mn 6.2 and Ni 3.9 nM. In July 1984 the equivalent concentrations were Al 11, Cd 0.15, Co 0.15, Cu 4.3, Mn 12 and Ni 3.6 nM. Distinct regional differences were detectable which can be related to the origin of the water, differing river inputs, and solution-solid phase exchange reactions. The degree of the influence of exchange reactions was investigated through the concept of Kd, the distribution coefficient. A Kd of 105 ml g−1 for Al is consistent with other observations and explains the relatively high concentrations of dissolved Al detected in the English Channel on this cruise. The data suggest a higher Kd for Mn approaching 106 ml g−1. The high Mn Kd coupled to higher suspended sediment loads in winter may be sufficient to explain the lower concentration of dissolved Mn in winter. Comparison of concentrations across the shelf break suggests that for all the metals studied, the European Shelf is a source of dissolved metals to the deep sea. Calculations based on the limited available data indicate that this export is of similar magnitude to the fresh water input of dissolved metals.
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  • 37
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    Elsevier
    In:  Deep Sea Research Part II: Topical Studies in Oceanography, 40 (1-2). pp. 91-114.
    Publication Date: 2018-03-05
    Description: An overview is given of the multinational investigations carried out at 47°N 20°W for the period 24 April–31 May, with the main emphasis on the succession of plankton communities and the flux of organic carbon through various plankton components. The depth of the upper mixed layer decreased rapidly after 25 April, triggering the start of the spring bloom that developed within a 2-week period. Chlorophyll a stocks integrated to 80 m water depth reached peak concentrations during the first 10 days in May. The observed decline was partly due to the seasonal development, but also may have been influenced by changes in water masses associated with a cyclonic eddy. Primary production ranged from 50 to 150 mmol C m−2 day−1 with highest values in the first half of May. After the first bloom phase, dominated by diatoms, nanophytoplankton gained more importance as primary producers when silicate was depleted. Stocks of bacteria, microzooplankton and mesozooplankton increased in the second half of May. Bacterial production averaged 30% of primary production and probably metabolized a large amount of dissolved organic carbon (DOC) per day, but due to uncertain carbon conversion efficiencies total bacterial carbon consumption is difficult to estimate. Largely daily changes in the DOC standing stock could not be reconciled with the measured primmary production and are probably an expression of spatial rather than temporal variations. Microzooplankton was found to consume around 64% of primary production in the second half of May. Grazing estimates for mesozooplankton varied but seem to be small (〈5% of primary production) for most of the investigation period. The small mesozooplankton size classes (〈1 mm) dominated biomass and grazing. Vertical particulate organnic carbon (POC) flux measured by sediment traps in 150 m depth was around 9.8 mmol C m−2 day−1 representing approximately 11% of primary production. The spring bloom pulse of particle flux reached the deep ocean and benthos 4–6 weeks after the surface water peak.
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  • 38
    Publication Date: 2018-03-22
    Description: Altimetric data from Geosat and some critical hydrographic measurements were used to estimate in real time the mesoscale physical oceanographic environment surrounding the Joint Global Ocean Flux Study (JGOFS) 1989 North Atlantic Bloom Experiment. Three cyclonic eddies, including an exceptionally large one, evolved and interacted over the 10 weeks of observations. Subsequent analysis of all available hydrographic data confirmed the real time estimates and provided further quantitative information concerning the mesoscale and submesoscale structure of the upper ocean. Remotely sensed indicators of near-surface chlorophyll content reveal significant biological variability on these wavelengths. The altimetric and hydrographic data have been assimilated into a dynamical model to produce optimal estimates of physical fields of interest as they evolve in time for use in physical and biological process studies
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  • 39
    Publication Date: 2018-03-22
    Description: The influence of increasing amounts of surfactants on the toxicity of hydrocarbons was determined using the bioluminescence inhibition test (Microtox test). Three biogenic and three synthetic surfactants were tested against the water-soluble fractions (WSF) of crude and weathered Ekofisk oil, phenol, and naphthalene. Surfactant concentrations below 100 mg litre−1 lowered the toxicity of the WSF, indicating an antagonistic interaction reducing the toxicities of surfactants and hydrocarbons. At concentrations greater than 100 mg litre−1 the toxicity rose again and was higher than the untreated WSF. The point of reversal seemed to be the critical micelle concentration, at which the formation of oil/water emulsions is possible.
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  • 40
    Publication Date: 2017-03-30
    Description: Biological and fishery features of the waves of abundance of Illex argentinus in three fishery regions −52°S (shelf with 180–230 m depths in exclusive economic zone of Argentina—EEZA), 46° and 42°S (continental slope with 600–800 m depths off the EEZA) in April–June 1990 were studied. According to age analysis of 629 statoliths made aboard, age-length structure of each wave of abundance were determined. In April–June active spawning migrations of I. argentinus were observed from feeding grounds located in limits 50–52°S along the continental slope northwards through 46° and 42° fishery regions. Only winter-hatched squids (hatched from June to September of the previous year) took part in migrations which were observed as waves of abundance in all three regions. Each migratory wave of abundance consisted of 2–4 successive monthly generations. The start of spawning movement was corresponded with the age and maturity state of the squid. Squid of all monthly generations began migrating from the 52°S region at a mean age of approximately 250 days, passed through 46°S at mean age 280 days and through 42°S at mean age 295 days. Males migrated 2–3 weeks earlier than females of the same generation. Rates of somatic growth were very low during migrations from 52° to 46°S (RDGR - 0.13% mantle length (ML) in mature males and 0.2% ML in maturing females). During movement from 46° to 42°S and, obviously further, mature squids practically ceased somatic growth. Estimated rate of migrations was 23.2–28.9 km day−1 (including current velocity), or 26–30 cm s−1 (0.47 body length s−1). Spawning was considered to occur on the continental slope of Uruguay and Brazil north of 35°S in July–August. Methodical approaches of efficient determination of squid age, growth and stock structure by means of investigation of squid biological features and statolith microstructure in each distinguished wave of abundance were elaborated.
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  • 41
    Publication Date: 2017-05-04
    Description: The effects of feeding a prepared surimi diet (fish-based) and a prepared pelleted diet (shrimpbased) on the survival, growth and feeding rate of the cuttlefish Sepia officinalis L. were evaluated during a 45-day experiment. One hundred and twenty juveniles of laboratory cultured cuttlefish (74.5 ± 12.36 g) were divided into three treatments and were fed thawed shrimp (control), pellets or surimi. Survival rates on these diets were 95.0%, 67.5% and 22.5%, respectively. Preliminary data indicated that the low survival of cuttlefish fed surimi may have been caused by low levels of copper in their blood (131 vs 244 μg/ml) since copper is required for their respiratory blood pigment, hemocyanin. Instantaneous growth rates were 2.71 % body weight BW/day for cuttlefish fed raw shrimp, 0.33% BW/day for cuttlefish fed pellets, and 0.54% BW/day for cuttlefish fed surimi. The feeding rate of cuttlefish fed shrimp was high (6–8% BW/day). The feeding rate on pellets increased with time (from 〈 1 to 3% BW/day) but never reached the level for raw shrimp. The feeding rate on surimi increased to equal the rate for raw shrimp during days 1–30 (8 to 9% BW/day) and thereafter decreased (〈4% BW/day). In conclusion, there was a major distinction between the palatability of a prepared diet and the ability of that diet to support growth. Surimi was highly palatable but resulted in poor survival, suggesting low nutritional quality. In contrast, pellets were less palatable but produced maintenance growth. Development of practical surimi diets will require supplementation of the surimi with soluble micro- and macronutrients.
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  • 42
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    Elsevier
    In:  Acta Oecologica - International Journal of Ecology, 14 (3). pp. 463-470.
    Publication Date: 2020-04-23
    Description: Changes in marine ecosystems can be manifested in many different ways, on different temporal and spatial scales. Seabirds are top consumers in marine foodwebs and offer opportunities to detect and assess the biological effects of changes in physical parameters (sea-surface temperature [SST], salinity, depth of thermocline etc.) of the marine ecosystem. We compare six-eight years' of data on the biology (diet, and breeding success) of four species of seabird (arctic tern Sterna paradisaea and common tern S. hirundo, which feed at the sea surface; and Atlantic puffin Fratercula antica and razorbill Alca torda, which dive 30-60 m for their prey) breeding on Machias Seal Island (MSI) in the Bay of Fundy with both our own meteorological and oceanographic measurements, and with standard measurements from conventional sources. These are compared with fisheries data on changes in the main prey of all the seabirds concerned (juvenile or '0-group' herring Clupea harengus) which are the most direct link between the seabirds and the physical properties of the marine system. We explore relationships between seabird productivity and diet, and other aspects of both herring biology (larval surveys, and fat content) and oceanography (SST data from the island, and remotely sensed data from the entrance to the Bay of Fundy). Timing of laying by puffins followed SST variation at neither the local (MSI) nor regional scales, but at the scale of the North Atlantic, following the trend of populations breeding off northern Norway. The proportion of herring in the diet of terns over 6 years varied inversely with herring larval abundance the previous fall; this relationship was not statistically significant in the puffin and razorbill. A major new finding is the considerable (approximately 50%) inter-annual variation in the energy density (fat content) of juvenile herring that are the main seabird prey; breeding success of both species of tern varied in parallel with the energy density of juvenile herring in the diet until the last two years of the study, when sandlance (Ammodytes sp.) and euphausid shrimp predominated in the diet. Our long-term research approach combines traditional population monitoring (of numbers of breeding birds) with demographic, behavioural and environmental monitoring, to provide new understanding of the marine ecosystem as well as of seabirds.
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  • 43
    Publication Date: 2017-07-06
    Description: A method for attaching acoustic transmitters externally to deep-water fishes in situ is described. Tags, each comprising a transmitter connected to a dart, were fired at fish from a pneumatic gun held by the manipulator arm of a submersible. The method was applied successfully for tagging coelacanths and may have application for use with other species of fishes living at depths to about 1000 m. The usefulness of direct observation for monitoring the effects of tags on fish is evaluated in relation to the effects of the tagging method on coelacanths.
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  • 44
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    Springer
    In:  In: Applied Micropalaeontology. , ed. by Jenkins, D. G. Springer, Dordrecht, pp. 69-91.
    Publication Date: 2017-08-03
    Description: This chapter records the benthonic foraminifera associated with a biogenic gas seep in the North Sea. A sample from an actively seeping site contains a benthonic foraminiferal assemblage statistically distinct from that of a control site. The distinctions are in terms of, firstly, abundance, diversity and dominance, secondly, taxonomic composition, and thirdly, proportions of epifaunal (surface-dwelling) and infaunal (sediment-dwelling) morphotypes.
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  • 45
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    Elsevier
    In:  Deep Sea Research Part II: Topical Studies in Oceanography, 40 (1-2). pp. 495-519.
    Publication Date: 2018-03-05
    Description: Productivity regime and phytoplankton size structure are described for two different epipelagic systems in the tropical/subtropical Northeast Atlantic Ocean investigated during 9–11 day drift studies in spring 1989 in the JGOFS North Atlantic Bloom Experiment, 18°N, 30°W and 33°N, 20°W. At the 18°N study site, an oligotrophic system was encountered. The water column above the main pycnocline at about 50–60 m depth was nutrient-depleted, and both chlorophyll and primary production displayed subsurface maxima at the nutricline. Picoplankton was the dominant size fraction, accounting for 78–90% of chlorophyll and 83–98% of primary production. Synechococcus-type coccoid cyanobacteria were the dominant picoplankters. The hydrographic situation was characterized by high small-scale variability; the most interesting feature was the intrusion of nutrient-depleted Subtropical Salinity Maximum Water into the euphotic zone, whose impacts on the productivity regime are discussed. At 33°N study site, a post-bloom situation was encountered. Although the euphotic zone was nutrient-depleted, higher amounts of larger phytoplankton were present, the contribution of picoplankton being 42–53% of chlorophyll and 42–86% of primary production. Over the course of the drift study, subsurface maxima of chlorophyll and productivity evolved, the contribution of picoplankton having increased. Picocyanobacteria again were the dominant picoplankters. At both study sites the profiles of abundance ratios of picocyanobacteria to picoeucaryotes cell numbers proved to be a useful tool to characterize water masses.
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  • 46
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    Springer
    In:  Boundary-Layer Meteorology, 65 (3). pp. 249-254.
    Publication Date: 2018-03-07
    Description: Turbulence in the Planetary Boundary Layer has been a topic of research for a long time. Its theory, however, is hampered by the fact that we have fewer fundamental equations than unknowns when dealing with turbulent motions. The search for additional “laws” to match the number of equations with the number of unknowns in turbulence theory is commonly labelled the turbulent closure problem. Despite considerable effort, this problem has not been solved. There is a variety of approaches available. However, these have not converged towards a commonly accepted PBL theory, like the Monin-Obukhov similarity for the surface layer. The Working Group on Boundary Layer Dynamics and Air-Sea interaction of ICDM/IAMAP therefore invites the scientific community to discuss these problems and possible solutions. The present paper intends to stimulate such a discussion.
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  • 47
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 40 (11-12). pp. 2167-2177.
    Publication Date: 2018-03-07
    Description: The origin and the spreading of the shallow Mediterranean water core (Ms) in the Iberian basin is discussed with a quasi-synoptic hydrographic data set enhanced by chlorofluoromethane (CFM) measurements. Its characteristic density level is found to be σt = 27.4. Characterized by high temperature and CFM values, Ms enters the Iberian basin in the region of Cape St Vincent between depths of 500–750 dbar. A heat anomaly of 〉11.8 × 109 J m−2 is chosen as the boundary between the presence of Ms and the background field. The core is found in a tongue-like shape as well as in separate isolated eddies of both cyclonic and anticyclonic circulation. Using the optimum multiparameter analysis (Tomczak and Large, 1989, Journal of Geophysical Research, 94, 16141–16149), the North Atlantic Central Water (NACW), which mixes with the Mediterranean outflow to form Ms, turned out to be in the mean 1°C warmer and 0.11 saltier than in regions with minor Mediterranean influence. This points to the Gulf of Cadiz as the origin of Ms, where the Mediterranean oufflows is in contact with NACW of the appropriate characteristics.
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  • 48
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    Elsevier
    In:  Journal of Marine Systems, 4 (2-3). pp. 231-233.
    Publication Date: 2018-03-07
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  • 49
    Publication Date: 2018-03-07
    Description: Gas chromatography-mass spectrometry (GC-MS) analyses of organic concentrates from eastern Mediterranean surface water show that dissolved fossil fuel residues are dominated by unsubstituted aromatic hydrocarbons and heterocyclic aromatics and thus resemble products of incomplete combustion. Deviating from this interpretation, preferential photochemical oxidation of alkyl-substituted aromatics is suggested as the principal causative mechanism, although, especially near land-based sources. the influence of combustion-derived unsubstituted aromatics is not defined. Total concentrations of dissolved aromatics as determined by GC-FID (flame ionization detection) and GC-MS from a limited data subset were in reasonable agreement with UV fluorescence measurements of dissolved/dispersed oil residues. The same preponderance of unsubstituted aromatics over their alkyl derivatives was found in extracts of the particulate phase, but concentrations were small relative to alkanes and/or alkenes of recent marine biosynthetic origin. CPI (carbon preference index) values of higher molecular weight n-alkanes indicated varying contributions of plant waxes to the particulate hydrocarbon pool. CPI values of corresponding dissolved n-alkanes were found to be near unity, indicating fossil fuel origin. Despite differences in higher molecular weight n-alkane CPI values and the predominance of recent biosynthetic aliphatics, the similarity of dissolved and particulate aromatic fractions suggests limited adsorption by particles of fossil fuel derived hydrocarbons and heterocyclics.
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  • 50
    Publication Date: 2018-03-07
    Description: Saudi Arabian coastal waters near sandy beaches, severely contaminated with crude oil released in Kuwait during the 1991 Gulf War, as well as underlying sediments and a few bivalves, were analysed to assess concentrations and composition of petrogenic hydrocarbon mixtures and structurally related oxidation products. Concentrations of dissolved oil residues determined by UV spectrofluorometry (UVF) near oil deposits on beaches did not exceed 3.5 μg l−1; concentrations dropped to approximately 1/10th of this value a few miles offshore. Gravimetric concentrations of unfractionated lipophilic material extracted from large volumes of seawater at the same stations were up to 10 times those determined by UVF. After chromatography on silica gel, individual petroleum hydrocarbons in the low polarity fractions and oxidation products in the polar fractions were characterized by their spectra (GC/MS) and quantitated by Selected Ion Monitoring (SIM) GC/MS. Concentrations of oxidation products (ketones, aldehydes, alcohols) of aromatic hydrocarbons exceeded those of their parent compounds by more than an order of magnitude. Significant concentrations were also found of the presumably pyrogenic triplett sensitizer anthraquinone. Contributions to polar fractions of water extracts by biosynthesized lipids were negligible. UVF determinations appear to underestimate concentrations of dissolved oil residues, because many oxidation products have lower fluorescence quantum yields than the respective parent hydrocarbons. Their ecotoxicological properties are unknown. Concentrations measured in sediments by UVF ranged from 13 to 540 μg g−1 dry wt and 0.5 to 103 μg g−1 as measured by gas chromatography with flame ionization detection (FID GC). Bivalves ranged from 0.8 to 1.5 μg mg−1 extractable organic matter (EOM) by UVF, and 0.1 to 0.3 μg mg−1 EOM by GC analysis. PAHs were identified in sediment and bivalve extracts by GC/MS and quantitated by SIM GC/MS. None of the relatively water soluble alkylbenzene photo-oxidation products found in water samples nor any higher molecular weight quinones could be detected in sediment extracts. However, ion chromatograms strongly suggest the presence of numerous high molecular weight aromatics in that matrix.
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  • 51
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    Springer
    In:  Hydrobiologia, 260/261 . pp. 263-267.
    Publication Date: 2018-03-07
    Description: The objective of the study was to produce a size-based matrix model of a Laminaria digitata (L.) Lamour. population. ‘Hard’ data for insertion in the matrix were collected in a 9 year cohort analysis of size and age specific survival and fertility for a stand in south west Nova Scotia, Canada. The product of the square matrix containing these values and a column vector containing the densities of size classes was used to project the size class structure one year later. The projected estimates were found to fit empirical estimates with some confidence. In contrast, an age-based fertility life table wrongly predicted a population declining in density by 45% per year. The study supports, in theory, the use of size-based matrix models for management of harvested stands. In reality, the amount of work required to obtain ‘hard’ data and the site specific nature of the projections may preclude the use of such an approach to broad scale management.
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  • 52
    Publication Date: 2018-03-07
    Description: As part of the NOAA/ROPME/MSRC sponsored assessment of the coast of Saudi Arabia, heavily impacted by the large oil spills of the 1991 Gulf War, we measured benthic community respiration (R) and primary production (P) rates in shallow subtidal basins near heavily oiled coastlines. Study sites were located in zones predicted to be basins of maximum deposition of any oiled sediments likely to wash off the adjacent coast and in reference bays predicted to be clean and unaffected. We measured oxygen exchange using in situ benthic respirometers and analysed petroleum hydrocarbon (PHC) levels in the near surface sediments at five stations. We concentrated our efforts in mud habitats to complement related studies in seagrass habitats. Measured community R rates ranged from a low of 700 μM m2 h−1 in coarse sand sediments with total organic carbon content (TOC) of only 0.16% of dry wt to the highest rate of 2184 μm m−2 h−1 in finer mud-sand habitats with 0.39% TOC. All measured rates were in the range of literature values for shallow marine sediments at temperatures of 17 to 19°C. Sediment oil content was 13–540 μg g−1 dry wt by ultraviolet fluorescence (UVF) analysis and 0.5–103 μg g−1 by gas chromatography (GC). Benthic P rates, calculated as light minus dark changes in dissolved oxygen, ranged from a low of 1162 μm m−2 h−1 at the most heavily oiled site to a high of 5216 μm m−2 h−1 at less oiled sites. While a weak inverse relationship between benthic P and sediment oil content was not significant statistically due to the small number of samples, a significant inverse relationship was found between the ratio of production to respiration (P/R) and the total petroleum content of the sediments by UVF. The effect appears to be driven more by differences in production than an effect on respiration which showed little relationship with either oil content or productivity. We conclude that within 1 year after the oil grounded on the intertidal sands of Saudi Arabia, the levels of oil in subtidal benthic sediments had decreased in most habitats to levels that did not show community stress by our oxygen measurements. Rather, long term damage to benthic subtidal habitats was limited only to enclosed bays adjacent to the most heavily oiled coastlines. Preliminary estimates of yearly P converted to carbon units indicates that the shallow mud sediments of the Gulf are at least as productive as most oligotrophic water columns. Since benthic habitats covered by seagrass, algae beds or coral reefs are likely to have even higher production rates, we conclude that benthic processes contribute significantly to the overall carbon flux in the Gulf ecosystem.
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  • 53
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 40 (2). pp. 257-266.
    Publication Date: 2018-03-21
    Description: A method for the collection of large-volume samples of oceanic particles is described. Near-surface seawater is pumped from below the ship to a continuous-flow centrifuge at rates of up to 1.2 m3 h−1. The seawater is in contact with polyethylene, polypropylene, Teflon and titanium materials only. The retention efficiency of the centrifuge for marine particles is the same as for standard membrane filters, as shown by comparisons with separate samples from Go-Flo bottles. The pumping system is non-contaminating with respect to both particulate and dissolved species. Several subsampling facilities for additional chemical constituents and other parameters can be supplied simultaneously due to the modular design of the system and the high flow rates
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  • 54
    Publication Date: 2018-03-02
    Description: Sediments of 13 piston cores from opposite continental slopes of the South China Sea, off southern China and Sabah (northern Borneo), were analyzed by sedimentological methods and dated by oxygen isotope stratigraphy. Sediments mostly consist of hemipelagic clay with 20% carbonate off Sabah and 40% off China. We calculated terrigenous and carbonate accumulation rates for up to 11 time-slices from the Holocene to oxygen-isotope stage 6. Terrigenous accumulation rates generally increase with water depth and reach a maximum at the middle slope off Sabah and at the lower continental slope off China. During glacial and interglacial times this distribution pattern did not markedly change, despite an increase of accumulation rates for glacial periods by a factor of 2 to 5 compared to interglacial periods. Rates are negatively correlated with positions of sea level, which controls the partition of fluviatile terrigenous material for deposition on shelf, slope, and abyssal plain. Carbonate accumulation rates are higher off China by a factor of 2 compared to Sabah, probably indicating higher calcareous plankton productivity.
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  • 55
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    Elsevier
    In:  In: Handbook of strata-bound and stratiform ore deposits Pt. 1, Vol. 3: Supergene and surficial ore deposits; textures and fabrics. , ed. by Wolf, K. H. Elsevier, Amsterdam, pp. 245-294. ISBN 0-444-41403-7
    Publication Date: 2016-04-18
    Description: Many occurrences of mineral resources in ocean water, on the ocean floor and in its deeper parts have long been well-known. This is readily understandable, because numerous ancient mineral products which are exploited on land were originally formed in marine milieus as far back as the Precambrian , e.g., marine sedimentary iron ores, rock salt, potassium, phosphate and manganese , as well as petroleum and natural gas. This book deals with ores in sediments, and in sedimentary and volcanic rocks. According to the Concise Oxford Dictionary (Fowler and Fowler , 1964), ore is defined as "solid native mineral aggregate from which valuable constituents not necessarily metal may be usefully extracted". Therefore , in tllis chapter only mineral resources of inorganic origin in ocean water and on the ocean floor are discussed and not those of organic derivation, although the existence of petroleum, natural gas and, to some extent, of coal in the subsurface of the ocean shelves is of greater economic importance. The amount of oil and gas produced in 1969 represented more than 90% by value of all mineral resources obtained from the oceans and ocean floors. Ore deposits in bed-rock formations of the shelf region, such as those which are exploited near Cornwall (England) and Newfoundland for example, are also irrelevant, as these are merely extensions of discoveries on the nearby mainland. The purpose of this chapter is to give a general review of the (inorganic) mineral resources of the oceans and the ocean floors . In this respect, not only are the economically important products which are already in use discussed, but also those materials which, in their oceanic environment, can become of economic value in the near or more remote future. For a better understanding of the existence of such materials, some deposits have also had to be reviewed which will not become of economic value . Since some contributions in this book are specifically dedicated to Recent marine ferromanganese deposits and Recent phosphorite deposits, these mineral resources are only briefly discussed in tllis chapter. (For details on Recent marine and lacustrine manganese deposits see Chapters 7 and 8 by Glasby/Read and by Callender/Bowser, respectively, in Volume 7.) The litarature on the mineral (inorganic) resources of the oceans and ocean floors is extremely extensive, so that a choice had to be made and, therefore, the bibliography added to this chapter consists mainly of recent publications.
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  • 56
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    In:  Umweltwissenschaften und Schadstoff-Forschung, 5 (1). pp. 27-44.
    Publication Date: 2018-03-02
    Description: Die häufigsten vulkanischen Volatilen sind H2O, CO2, SO3 und Halogene. Zusammensetzung, Menge und Injektionsraten von vulkanischen Gasen und Partikeln in die Troposphäre und Stratosphäre hängen ab von der chemischen Zusammensetzung eines Magmas, dem plattentektonischen Milieu sowie Eruptionsmechanismen und Eruptionsraten. Über 90% der eruptierten Magmen sind basaltischer Zusammensetzung mit niedriger Viskosität, relativ geringen Volatilengehalten und meist niedrigen Eruptionsraten sowie wenig explosiven Eruptionen überwiegend entlang der mittelozeanischen Rücken in großen Wassertiefen. Magmen in Inselbögen und Subduktionszonen an Kontinenträndern sind H2O-reich, in anderen plattentektonischen Milieus überwiegt in basaltischen Magmen CO2. In mafischen Magmen ist CO2 schlecht löslich und kann daher schon mehrere Kilometer unter der Erdoberfläche als Gasphase aus einem Magma entweichen. Felsische (hochdifferenzierte) Magmen, H2O-reich und CO2-arm, eruptieren oft hochexplosiv, insbesondere an Subduktionszonen, und mit hohen Eruptionsraten, z.B. El Chichón (Mexiko, 1982) und Pinatubo (Philippinen, 1991). Ihre Eruptionssäulen (Gas-/Partikelgemische) können bis ca. 40 km Höhe erreichen und sind Hauptlieferant der in die Stratosphäre injizierten Gasmengen.
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  • 57
    Publication Date: 2017-06-22
    Description: Benthic foraminifera and surface sediments were analyzed from 23 box-core and core-top samples from 250 to 3600 m depth at the southern Portuguese continental margin between 37 and 38 °N. This area is affected by the MOW which flows northwards along the slope between 600 and 1500 m waterdepth. Sediment structures, grain-size distribution and clay mineral assemblages of surface sediments indicate active winnowing in the upper part of the MOW, and deposition of the fine fraction near its lower boundary. R-mode cluster analyses of foraminiferal census data from the 〉 250 μm fraction revealed four associations. The ‘Shelf Edge Association’ occurs on glauconitic shelf and upper slope sands down to 268 m. The ‘Upper Slope Association’ is recognized between 498 and 1300 m where sand-silt-clays to clayey silts are encountered. The ‘Lower Slope Association’ is found between 1405 and 2985 m and differs markedly from assemblages below 3000 m (‘Deep Water Association’) where the near-surface sediments are soft hemipelagic clays. The ‘Boundary Layer Association’ shows no significant depth limits but abundance maxima both in the density interface above the MOW and in the interval of decreasing turbulence below it. The boundaries of the ‘Shelf Edge’ and ‘Upper Slope Association’ correspond to these hydrographic boundary layers whereas the boundary between ‘Lower Slope’ and ‘Deep Water Assemblage’ is related to threshold values of nutrient flux to the benthic community. Examination of hard-substrates reveals 27 different species of epibenthic foraminifera. Six of these, the ‘Epibenthos Group’, were found attached to elevated substrates only within the MOW. Above the MOW, elevated substrates were inhabited by different species, whilst below the MOW they were not used by any epibenthic foraminifers. Evidently, the hydrodynamic environment of the MOW current provides an ecological niche which is efficiently used by opportunistic suspension feeders. The ‘Epibenthos Group’ is more abundant in the middle part of the study area between 37 °20′ and 37 °40′N where the sand content of surface sediments is also higher. Both indicate an enhanced sediment-water interaction in this area which results from an obstruction of the MOW flow by the ‘Principes d'Avis’ basement spur.
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  • 58
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    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 40 (9). pp. 1925-1933.
    Publication Date: 2018-03-02
    Description: The Vema Channel represents a prominent location for the nortward flow of bottom water in the subtropical western South Atlantic. A recent multibeam echo-sounding survey of the Vema Sill on board F.S. Meteor revealed a narrow and shallow portion of the Vema Channel at 31°12′S, 39°24′W, the Vema Sill. The survey also showed the remarkably asymmetric shape of the sill region, suggesting an interaction between the bottom flow and the shape of the channel.
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  • 59
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    Springer
    In:  Facies, 29 (1). pp. 133-148.
    Publication Date: 2016-04-15
    Description: In the subtropical belt highly productive ecosystems are formed by coral reefs in oligotrophic seas. Towards more eutrophic conditions, coral reefs diminish and are subsequently replaced by highly productive kelp forests. In high latitudes framework constructing carbonate production is enhanced by the growth of branching coralline algae which predominantly generate maerl-type deposits. On a global view, these coralline algal ecosystems show an island-like distribution pattern within the phaeophytic kelp belt. Compared to kelp ecosystems, coralline-algaldominated ecosystems have low rates of productivity. Therefore, it is reasonable to seek the pronounced competitive value of the extremely slow-growing corallines. Due to their low annual growth increment, the coralline algae studied are very endangered by abiotic physical disturbances and by overgrowth of rapidly growing filamentous algae or sessile invertebrates. To overcome fouling pressure and storm-triggered physical disturbances, coralline algae thrive well in wave-sheltered headlands or skerry areas and generate characteristic ‘denuded areas’ by intense herbivory. This general distributional pattern is also true for high-boreal to subarctic coralline algal bioherms in northern Norway. Such a complex biological feedback maintains a high potential of self-regulation or self-organization in the algal reef bioherms. The different proponents involved in feedback processes include bacterial colonization, diatom microfouling and selective induction of larval metamorphosis. The negative impact of diatom microfouling and the important role of herbivores are relevant activities in the feedback system on a microscopic scale. Macroscopically, intense herbivory on coralline algae create denuded conditions, which are a widespread phenomenon in coralline algal ecosystems.
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  • 60
    Publication Date: 2016-11-14
    Description: During the ARCTIC '91 expedition aboard RV Polarstern (ARK VIII/3) to the Central Arctic Ocean, a box corer sample on the Gakkel Ridge at 87 degrees N and 60 degrees E yielded a layer of sand-sized, dark brown volcanic glass shards at the surface of the sediment core. These shards have been investigated by petrographic, mineralogical, geochemical and radiogenic isotope methods. The nearly vesicle-free and aphyric glass shards bear only minute microphenocrysts of magnesiochromite and olivine (Fo(88-89)). Most glasses are fresh, although some show signs of incipient low-temperature alteration. From their shapes and sizes, the glass shards most likely formed by spalling of glassy rinds of a nearby volcanic outcrop. Geochemically, the glasses are relatively unfractionated tholeiites with E-MORB trace element compositions. Thus, they are quite similar to the previously investigated ARK IV/3-11-370-5 basalts from 86 degrees N. The Nd and Sr isotopic ratios of PS 2167-2 glasses are significantly lower than for ARK IV/3-11-370-5 basalts and suggest an isotopically heterogeneous mantle source of Gakkel Ridge MORE between 86 degrees and 87 degrees N. The positive Delta-8/4 Pb value (similar to 16) and high Sr-87/Sr-86 ratio (0.70270), found for PS 2167-2 glasses are similar to that of ARK IV/3-11-370-5 basalts and show the influence of the DUPAL isotopic anomaly in the high Arctic mantle. These results argue against the presence of an 'anti-DUPAL anomaly' in the mantle below the North Pole region and simple models of whole-mantle convection.
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  • 61
    Publication Date: 2017-07-21
    Description: Live observations, cytological characteristics and biometrical measurements on Miliolinella subrotunda (Montagu, 1803) sampled from the northern and southern Atlantic Ocean are presented.M. subrotunda facultatively constructs a long, detritic tube lifting the test several millimeters above the sediment surface. A thickened conical base anchors the construction on the sediment surface and a long, flexible tube protrudes into the velocity profile of the bottom currents. The miliolid test is placed on top, surrounded by the uppermost part of the tube. This construction allows the organisms to feed in the particle stream above the sediment surface. In comparison to species living in and on the surface sediments,M. subrotunda apparently shows higher nutritional values in food ingested and larger amounts of reserve substances. Characteristics of the shape and structure that reduce drag on the tubes include a broadened conical base, a flexible tube, and a rounded top. From biometrical measurements it is concluded, that the tubes are constructed over a short period of their ontogeny.
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  • 62
    Publication Date: 2017-10-05
    Description: Water samples from surface and bottom waters of two bights of the Baltic Sea were analysed for dissolved and/or particulate concentrations of Al, Cd, Co, Cu, Fe, Hg, Mn, Ni, Pb and Zn, in addition to the main oceanographic variables, at 27 stations during six cruises between February 1990 and July 1992. The metal values show distinct regional differences, with maximum concentrations at the near-shore stations, The levels of total Hg exhibit a significant negative relationship with salinity. In surface layers, seasonal differences due to biogenic uptake of elements could not be detected for any of the dissolved metals. In bottom waters, however, summer-time concentrations of a number of metals are in clear excess of winter levels either due to diffusion of metals (Go, Fe, Mn) from the sediments under low-oxygen or anaerobic conditions, or due to mineralization processes (Cd, Zn) of recently sedimented biogenic particulates. With the exception of Fe and Pb, the particulate fractions are of minor importance, with slight variabilities between the seasons only. The K-D values (ratio between metal concentrations in the particulate and dissolved fractions) decrease by more than two orders of magnitude in the order Fe-Pb-Mn-Co-Zn-Cd-Cu-Ni. Finally, the results are discussed with regard to a trace metal monitoring programme in the area.
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  • 63
    Publication Date: 2016-11-14
    Description: The Houtman Abrolhos Islands, situated at the western passive margin of the Australian continent, consist of a series of shelf-edge coral reefs. The central platforms of the reefs are Late Pleistocene in age and are generally some 3–5 m above present sea level. The uppermost part of the Last Interglacial reefs normally has an upward-shallowing sequence, consisting of coral framestone, coralline algal bindstone and skeletal grainstone to rudstone. This sequence represents deposition in water depths of less than 2 m, and provides a good indicator of sea level. High-precision mass-spectrometric dates of corals from the Abrolhos reefs, including dates obtained from drill cores, arological, isotopic and stratigraphic criteria are established for the selection of suitable samples for dating and for assessing the reliability of dates. Using the screened dates and the stratigraphic evidence, the timing and character of the sea level variations of the Last Interglacial in the Abrolhos region are examined. The data show that sea level of the Last Interglacial in the Abrolhos was 4 m below its present height by ca. 134 ka BP and probably reached about 2 m above present height at ca. 133 ka BP. The exact time at which sea level reached its peak (6 m above present sea level) cannot be determined from our data. But it is clear that the sea level high stand of the Last Interglacial lasted until ca. 116 ka BP and that for much of the Last Interglacial sea level at the Abrolhos was at a height of about 4 m above its present level
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  • 64
    Publication Date: 2019-01-22
    Description: The gene coding for the anion-specific porin of the halophilic eubacterium Ectothiorhodospira (Ect.) vacuolata was cloned and sequenced, the first such gene so analyzed from a purple sulfur bacterium. It encodes a precursor protein consisting of 374 amino acid (aa)-residues including a signal peptide of 22-aa residues. Comparison with aa sequences of porins from several other members of the Proteobacteria revealed little homology. Only two regions showed local homology with the previously sequenced porins of Neisseria species, Comamonas acidovorans, Bordetella pertussis, Alcaligenes eutrophus, and Burkholderia cepacia. Genomic Southern blot hybridization studies were carried out with a probe derived from the 5′ end of the gene coding for the porin of Ect. vacuolata. Two related species, Ect. haloalkaliphila and Ect. shaposhnikovii, exhibited a clear signal, while the extremely halophilic bacterium Halorhodospira (Hlr.) halophila (formerly Ect. halophila) did not show any cross-hybridization even at low stringency. This result is in good accordance with a recently proposed reassignment within the family Ectothiorhodospiraceae, which included the separation of the extremely halophilic species into the new genus Halorhodospira.
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  • 65
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    Springer
    In:  Microbial Ecology, 3 (1). pp. 1-9.
    Publication Date: 2015-03-10
    Description: Enrichment cultures were prepared with different media for phototrophic bacteria from four species of marine sponges, collected from oxic coastal waters near Split (Yugoslavia). We obtained pure cultures of six strains of Chromatiaceae and two strains of Rhodospirillaceae by agar shake dilution. The Rhodospirillaceae were identified as Rhodopseudomonas sulfidophila and a marine form of Rhodopseudomonas palustris. TheChromatiaceae were identified as Chromatium vinosum, Chromatium gracile, Chromatium minutissimum. Ectothiorhodospira mobilis, and a Chromatium species, which in some respects resembles Chromatium minus. The occurrence of strictly anaerobic phototrophic bacteria in aerobic sponges is discussed with respect to nutrition and possible syntrophism
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  • 66
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    Springer
    In:  Geologische Rundschau, 87 (2). pp. 518-521.
    Publication Date: 2018-01-25
    Description: Rubrik "Neues aus dem Geologenarchiv (1997)"
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  • 67
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    Elsevier
    In:  Chemical Geology, 103 (1-4). pp. 271-281.
    Publication Date: 2015-11-24
    Description: Accurately weighed aliquots of the ∼ 500-Ma-old interlaboratory standard hornblende MMHb-1 were mixed with known quantities of a ∼ 100 Ma-old Himalayan biotite and subjected to normal Full-size image (〈1 K) incremental heating analysis. The addition of the biotite created monotonically increasing apparent ages, similar to profiles interpreted as showing Ar diffusive loss in the literature. The release of Ar from biotite dominates the low-temperature portion of the spectra and lowers the observed age. Lower Ca/K ratios in the first increments are consistent with contamination, but do not distinguish the composition of the contaminant phase. A large number of published amphibole “diffusive loss” profiles may, in fact, be due to contamination by biotite or other phases which release Ar at low extraction temperatures.
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  • 68
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    Elsevier
    In:  Quaternary Science Reviews, 16 (10). pp. 1115-1124.
    Publication Date: 2016-09-19
    Description: Stable carbon and oxygen isotopes of the polar planktic foraminifera Neogloboquadrina pachyderma sinistral from sediment cores of the Norwegian Sea reveal several anomalous 13C and δ18O depletions in the surface water during the last glacial to interglacial transition and during the later Holocene. The depletions that are observed between the Last Glacial Maximum (LGM) and the end of the main deglacial phase were caused by massive releases of freshwater from thawing icebergs, which consequently resulted in a stratification of the uppermost surface water layer and a non-equilibrium between the water below and the atmosphere. At ~8.5 ka (14C BP) this strong iceberg melting activity ceased as defined by the cessation of the deposition of ice-rafted detritus. After this time, the dominant polar and subpolar planktic foraminiferal species rapidly increased in numbers. However, this post-deglacial evolution towards a modern-type oceanographic environment was interupted by a hitherto undescribed isotopic event (~7–8 ka) which, on a regional scale, is only identified in eastern Norwegian Sea surface water. This event may be associated with the final pulse of glacier meltwater release from Fennoscandia, which affected the onset of intensified coastal surface water circulation off Norway during a time of regional sea-level rise. All these data indicate that surface water changes are an integral part of deglacial processes in general. Yet, the youngest observed change noted around 3 ka gives evidence that such events with similar effects occur even during the later Holocene when from a climatic point of view relativelystable conditions prevailed.
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  • 69
    Publication Date: 2015-09-30
    Description: Paragenetic mineral assemblages have been established based on mineralogical, chemical, and isotope (S, Pb) studies, and the sequence of deposition has been defined in hydrothennal sulfide structures in a typical back-arc basin. The ores in the Manus basin have a prominent Zn specialization (sphalerite, würtzite, and fe-sphalerite). An association of Fe-spbalerite and galena with Ag sulfosalts is noted that is not characteristic of typical midocean ridge hydrothennal systems. The average 34S in the sulfide minerals is 3.5%o, which corresponds to the medium-temperature sphalerite stage in hydrothermal mineral fonnation. It is suggested that the metal source is located in the relatively acid rocks of the island-arc tholeiitic series and possibly in sediments.
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  • 70
    Publication Date: 2017-06-26
    Description: Abundance, biofacies and ATP content of benthic foraminifera (〉63 μm) were studied in the Northeast Water (NEW) Polynya (77–81°N, 5–17°W) over the ice-free summer, 1993, to investigate how a polynya system might influence the underlying benthic community. In the living assemblage, distinguished by Rose Bengal staining, over 60 taxa could be identified. The biofacies identified was similar to that of other Arctic shelf habitats. Foraminifera were counted in 3 size fractions (63–125 μm, 125–250 μm and 〉250 μm), with 65% of the foraminifera occurring in the smallest size fraction (63–125 μm). Total abundances (〉63 μm) in the uppermost 1 cm averaged approximately 200 ind/10 cm3 and declined down-core, as did the number of species. Abundances and species composition correlated positively with sediment chlorophyll and ATP content, with maxima occurring in the shallower northern regions of the polynya, suggesting a general dependence on food. Foraminera biomass was estimated to be 0.1-0.3 g Corg/m2. Abundances, biomass and ATP content were comparable to ice-free, deep-sea regions in the Norwegian Sea. Temporal changes observed over a 2 month period at one location were difficult to distinguish from spatial and analytical variability. Contrary to expectations, growth was unpronounced at the community and at a species level, implying either a delayed response of the benthic foraminiferal community to food inputs from the overlying water column or the presence of biological limitations other than food, such as predation.
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  • 71
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    Elsevier
    In:  Journal of Marine Systems, 11 (3-4). pp. 269-278.
    Publication Date: 2016-01-29
    Description: The present literature on biologically mediated fluxes from the benthic nepheloid layer (BNL) across the sediment-water interface into the sediment and vice versa is reviewed. The processes involved are categorised according to direct bioresuspension and biodeposition, i.e. direct interception of the animal with particles, and those effects, which are indirectly created by benthic organisms, e.g., changes of physical properties in the sediments, constructions like tubes and pits and the corresponding changes in hydrodynamic conditions. It is concluded that benthic organisms significantly increase the flux of particles across the interface and that the physically created fluxes are easily modified by a factor of 2 and more.
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  • 72
    facet.materialart.
    Unknown
    Elsevier
    In:  Palaeogeography, Palaeoclimatology, Palaeoecology, 130 (1-4). pp. 1-23.
    Publication Date: 2017-01-23
    Description: The late Quaternary sedimentary history of the continental margin off Portugal was reconstructed from sediment gravity cores. Hemipelagic sedimentation (lithofacies A) was dominant during glacial times. It was interrupted periodically by deposition of shelf- and upper-slope-derived silty and sandy terrigenous material by dilute turbidity currents (lithofacies B and C), ice-rafted debris during distinct periods of breakdown of North Atlantic ice sheets (Heinrich events, lithofacies D) and large amounts of pteropods (lithofacies F). Settling of biogenic particulate material (lithofacies E) prevailed during the Holocene, when sea level and sea surface temperatures were high and terrigenous shelf-input was low. Downslope transport was dominant on the northern part of the Portuguese margin, culminating in frequent turbidity current transport between 35 and 70 ka. This may be due to a humid climate and a high fluvial input. Pteropod muds are confined to cores south of 41°N. Prominent peaks in pteropod concentration were radiocarbon dated at 17.8 and 24.6 ka. Layers rich in ice-rafted debris (IRD) were found along the entire margin. The base of these layers have been dated at 13.6–15.9 14C ka, 21.0–22.0 14C ka, 33.8 14C ka and ±64.5 ka, which correspond well with the ages of Heinrich events 1, 2, 4 and 6 in the central North Atlantic. Heinrich events 0 (10.5 ka), 3 (27 ka) and 5 (50 ka) rarely influenced sedimentation on the Portuguese slope. A mineralogical study of the IRD within Heinrich layers suggests that most icebergs were derived from the Laurentide Ice Sheet in the Hudson Strait and Hudson Bay area through the Labrador Current and the Canary Current and flowed in a southward direction along the margin. IRD from European ice sheets may have been mixed in during Heinrich event 6. On their way along the margin the icebergs lost much of their sediment load due to melting of the ice in a progressively warmer climate. The southernmost latitude studied (37°N) may be close to the southeastern extension of iceberg transport during Heinrich events.
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  • 73
    Publication Date: 2016-01-28
    Description: The Platanar volcanic center is dominated by a calc-alkaline, basalt-andesite-dacite-rhyolite magma series with unusual LREE enrichment. Adjacent and overlapping the calc-alkaline rocks are the most alkaline basalts found along the volcanic front of Central America. These basalts are mafic, LIL- and LREE-enriched transitional to alkaline basalts. Several are found on the north flank of Platanar in the Aguas Zarcas region, where there are nine cinder cones and a few isolated flows. However, they are also found in isolated lava outcrops at least as far south as Porvenir volcano along the volcanic front. The addition of mafic alkaline magmas with high La/Yb and low Ba/La into the Platanar magma chamber or chambers may contribute to the LREE-enriched character of the Platanar basaltic andesites and andesites. At Platanar the field and geochemical evidence suggest mixing between calc-alkaline and alkaline magmas, a process that has probably occurred throughout the development of the Cordillera Central of Costa Rica. The presence of negative Ce anomalies in several of the calc-alkaline lavas also make the Platanar complex very unusual compared to the rest of the Central American volcanic front. In the center of the Platanar complex is the Chocosuela caldera, an apparent remnant of an avalanche caldera created by the collapse in the Middle Pleistocene of an ancestral stratovolcano toward the NNW in a directed blast-type eruption. Rhyolite is present as pumice lapilli in pyroclastic flow deposits outside the caldera rim. Whole lapilli analyses span the daciterhyolite range. The previous eruption of high silica tephra as pyroclastic flows, the current long dormant period and the repeated occurrence of earthquake swarms on the flanks of the Platanar complex make it a candidate for volcanic hazard mapping, detailed geological mapping and emergency planning.
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  • 74
    Publication Date: 2017-12-08
    Description: Quenched tholeiitic glasses and glassy rims of tholeiitic lava flows and pillow lavas from the neovolcanic rift zone on Iceland (Reykjanes and Hengill fissure swarms) contain olivine phenocrysts (Fo87–91) with abundant primary glass inclusions. These inclusions and host glasses were analyzed by ion microprobe for boron concentrations and isotopic compositions. Inclusions are believed to represent primary or near-primary mantle melts that have not been modified at shallow levels. Boron concentrations and B/K ratios in these melt inclusions are highly variable (0.18–1.35 ppm B, B/K = 2.8 × 10−4−6.1 × 10−3), whereas their δ11B values are nearly constant (−11.3, Full-size image (〈1 K)). This indicates that the Icelandic mantle is likely to have a constant boron isotope composition similar to that previously proposed for the primitive mantle (Full-size image (〈1 K)). The Hengill host glasses are characterized by low concentrations of B (0.26–0.42 ppm) and δ11B values similar to melt inclusions (−11.3, Full-size image (〈1 K)). In contrast, the Reykjanes host glasses have higher δ11B values (∼ −3‰) at the same relatively low concentrations of B (0.43–0.44 ppm), which are likely to be due to interactions of the ascending magmas with the crustal rocks hydrothermally altered at low temperatures by seawater-derived fluids. Boron concentrations and B/K ratios in melt inclusions and matrix glasses correlate with TiO2, K2O and P2O5 contents, and La/Sm)n ratios. Boron contents recalculated on the basis of melt inclusion compositions for the Icelandic mantle are slightly different for the Reykjanes and Hengill areas (0.21, 1σn ± 0.05 and 0.13, 1σn ± 0.03 ppm B, respectively). This is likely to reflect the presence of zones within the Icelandic mantle variously enriched and/or depleted in boron of similar isotopic composition.
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  • 75
    facet.materialart.
    Unknown
    Springer
    In:  Geologische Rundschau, 86 (2). pp. 471-491.
    Publication Date: 2019-01-22
    Description: The climate of the Holocene is not well suited to be the baseline for the climate of the planet. It is an interglacial, a state typical of only 10% of the past few million years. It is a time of relative sea-level stability after a rapid 130-m rise from the lowstand during the last glacial maximum. Physical geologic processes are operating at unusual rates and much of the geochemical system is not in a steady state. During most of the Phanerozoic there have been no continental ice sheets on the earth, and the planet’s meridional temperature gradient has been much less than it is presently. Major factors influencing climate are insolation, greenhouse gases, paleogeography, and vegetation; the first two are discussed in this paper. Changes in the earth’s orbital parameters affect the amount of radiation received from the sun at different latitudes over the course of the year. During the last climate cycle, the waxing and waning of the northern hemisphere continental ice sheets closely followed the changes in summer insolation at the latitude of the northern hemisphere polar circle. The overall intensity of insolation in the northern hemisphere is governed by the precession of the earth’s axis of rotation, and the precession and ellipticity of the earth’s orbit. At the polar circle a meridional minimum of summer insolation becomes alternately more and less pronounced as the obliquity of the earth’s axis of rotation changes. Feedback processes amplify the insolation signal. Greenhouse gases (H2O, CO2, CH4, CFCs) modulate the insolation-driven climate. The atmospheric content of CO2 during the last glacial maximum was approximately 30% less than during the present interglacial. A variety of possible causes for this change have been postulated. The present burning of fossil fuels, deforestation, and cement manufacture since the beginning of the industrial revolution have added CO2 to the atmosphere when its content due to glacial-interglacial variation was already at a maximum. Anthropogenic activity has increased the CO2 content of the atmosphere to 130% of its previous Holocene level, probably higher than at any time during the past few million years. During the Late Cretaceous the atmospheric CO2 content was probably about four times that of the present, the level to which it may rise at the end of the next century. The results of a Campanian (80 Ma) climate simulation suggest that the positive feedback between CO2 and another important greenhouse gas, H2O, raised the earth’s temperature to a level where latent heat transport became much more significant than it is presently, and operated efficiently at all latitudes. Atmospheric high- and low-pressure systems were as much the result of variations in the vapor content of the air as of temperature differences. In our present state of knowledge, future climate change is unpredictable because by adding CO2 to the atmosphere we are forcing the climate toward a “greenhouse” mode when it is accustomed to moving between the glacial–interglacial “icehouse” states that reflect the waxing and waning of ice sheets. At the same time we are replacing freely transpiring C3 plants with water-conserving C4 plants, producing a global vegetation complex that has no past analog. The past climates of the earth cannot be used as a direct guide to what may occur in the future. To understand what may happen in the future we must learn about the first principles of physics and chemistry related to the earth’s system. The fundamental mechanisms of the climate system are best explored in simulations of the earth’s ancient extreme climates.
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  • 76
    Publication Date: 2017-09-26
    Description: Iron speciation was determined in hemiplegic sediments from a high productivity area to investigate systematically the early diagenetic reactivity of Fe. A combination of various leaching agents (1 M HCI, dithionite buffered in citrate/acetic acid, HF/H2SO4, acetic Cr(II)) was applied to sediment and extracted more than 80% of total Fe. Subsequent Fe species determination defined specific mineral fractions that are available for Fe reduction and fractions formed as products of Fe diagenesis. To determine the Fe speciation of (sheet) silicates we explored an extraction procedure (HF/H2SO4) and verified the procedure by application to standard rocks. Variations of Fe speciation of (sheet) silicates reflect the possible formation of Fe-bearing silicates in near surface sediments. The same fraction indicates a change in the primary input at greater depth, which is supported by other parameters. The Fe(II)/ Fe(III) -ratio of total sediment determined by extractions was compared with Mössbauer-spectroscopy ] at room temperature and showed agreement within 10%. M6ssbauer-spectroscopy indicates the occurrence of siderite in the presence of free sulfide and pyrite, supporting the importance of microenvironments during mineral formation. The occurrence of other Fe(II) bearing minerals such as ankerite (Ca-, Fe-, Mg-carbonate) can be presumed but remains speculative.
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  • 77
    Publication Date: 2017-08-09
    Description: Oxygen isotope analyses of marine diatoms were performed in two independent ways. Stepwise fluorination of hydrous opal-A results in plateau δ180 values representing the isotopic composition of the silica frame oxygen. A method of controlled isotope exchange before silica dehydration also produces reliable results, although the exchangeability of the silica was variable. Consequently, a calibration of the isotope exchange method using the results from stepwise fluorination experiments is very useful (and sometimes essential) in order to select a water vapor of an appropriate isotopic composition to be used for equilibration. Sediment diatom samples Ethmodiscus rex and Thalassiothrix longissima from the Antarctic and the North Atlantic Ocean, respectively, show strong 180 enrichments of 46.8 and 44.1‰, which are caused by large isotope fractionation occurring at the low temperature prevailing during silica-water isotope exchange reactions. However, phytoplankton samples from surface waters of the Norwegian-Greenland Sea and the Bellingshausen Sea (Antarctica) have δ180 values between 30.4 and 35.0‰. Thus, the true silica-water isotopic fractionation is approximately 3 to 10‰ lower than the temperature-dependent silica-water equilibrium published in the literature for sedimentary diatoms. Our results indicate that successive isotope exchange reactions of diatomaceous silica with ambient seawater and/or pore water determine the isotope values of diatoms in sediments.
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  • 78
    Publication Date: 2017-08-03
    Description: In situ oxygen fluxes were measured at vent sites in the Aleutian trench at a water depth of almost 5000 m using a TV-guided benthic flux chamber. The flux was 2 orders of magnitude greater than benthic oxygen fluxes in areas unaffected by venting on the continental margin off Alaska. Porewater profiles taken from the surface sediment below a vent site showed high concentrations of sulfide, methane, and ammonia. The reduced carbon and nitrogen compounds are transported to the vent site by fluids expelled from deeper anoxic sediment layers by the forces of plate convergence. The tectonically driven fluid flow was determined from the biochemical turnover in vent communities and was found to be 3.4 ± 0.5 m yr−1. A model was used to quantify the transport of silica, Ca2+, and sulfate via diffusion, advection, and bioirrigation through the surface sediments of a vent site. A nonlocal mixing coefficient of 20–30 yr−1 was determined by fitting the model curves to the measured porewater profiles showing that the transport of solutes within the near-surface sediments and across the sediment-water interface is dominated by the activity of the vent fauna. Sulfate-containing oceanic bottom water and methane-rich vent fluids were mixed below the clam colony to produce sulfide and a CaCO3 precipitate. The vent biota shape their immediate environment and control the sediment-water exchange and the benthic fluxes at vent sites. The oxygen consumption at vent sites is a major sink for oxygen at the study area.
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  • 79
    facet.materialart.
    Unknown
    Elsevier
    In:  Continental Shelf Research, 17 (14). pp. 1765-1784.
    Publication Date: 2019-09-23
    Description: A combined 3-D physical oceanographic model and a field sampling program was performed in July and August 1994 to investigate the potential drift of larval Baltic cod from the center of spawning effort in the Bornholm Basin, Baltic Sea. The goal of this exercise was to predict the drift trajectories of cod larvae in the Bornholm Basin, thereby aiding in the development of future sampling programs as well as the identification of processes influencing larval retention/dispersion in the Bornholm Basin. Distributions of variables (T, S and larval distribution) were obtained utilizing a three-dimensional eddy-resolving baroclinic model of the Baltic Sea based on the Bryan-Cox-Semtner code. Larval drift was simulated by the incorporation of a passive tracer into the model utilized to represent individual cod larvae. Additionally, simulated Lagrangian drift trajectories are presented. For model purposes, initial fields of temperature, salinity and cod larvae concentration for the Bornholm Basin were constructed by objective analysis using observations taken during a research survey in early July, 1994. Outside the Bornholm Basin generalized hydrographic features of the Baltic Sea were utilized with the baroclinic model forced by wind data for the whole Baltic taken from the Europa-Modell (EM) of the German weather service, Offenbach. Verification of simulations was performed by comparison with field measurements of hydrographic variables and ADCP derived current measurements taken during the surveys. In general, most of the hydrographic features observed during the second research cruise are correctly simulated, with variations mainly attributed to the prescribed initial conditions outside the Bornholm Basin. Results from larval sampling during the second cruise could not entirely confirm the modeled larval distributions due to the low numbers of larvae captured. However, the modeled results based on the agreement of the flow fields and hydrographic properties with observed features suggest that predictions of larval distributions can be made with a high degree of confidence if appropriate larval behaviours are included in the simulations.
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  • 80
    facet.materialart.
    Unknown
    Elsevier
    In:  Geochimica et Cosmochimica Acta, 139 (1-4). pp. 287-297.
    Publication Date: 2017-08-25
    Description: The dating of polymetamorphic rocks with the U-Pb zircon method often results in discordant data. Thus a new technique combining cathodoluminescence imaging (CL) and thermal ion mass spectrometry (TIMS) measurements was developed. Cathodoluntinescence-controlled UPb dating (CLC-method) works with bisected zircons and was successfully applied to the multistage S-type granitoids of the Swiss Silvretta nappe. CLC-method enables the resolution of the different anatectic events and later major overprints (Cambrian, Ordovician, Silurian) and gives information about the protolith (Archaean) of the investigated gneisses. This is achieved by conventional UPb dating of selected grains, recovered from the SEM (scanning electron microscope) mounts after cathodoluminescence (CL) imaging. Applying this new combination of two established techniques yields geologically meaningful UPb zircon ages even for complex polymetamorphic rocks.
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  • 81
    facet.materialart.
    Unknown
    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 44 (8). pp. 1377-1403.
    Publication Date: 2016-09-30
    Description: Particle flux data have been collated from the literature representing most areas of the open ocean to determine regional trends in deep water flux and its seasonal variability. Organic carbon flux data normalised to a depth of 2000 m exhibits a range of an order of magnitude in areas outside the polar domains (0.38 to 4.2 g/m2/y). In polar regions the range is wider (0.01–5.9 g/m2/y). Latitudinal trends are not apparent for most components of the flux although calcite flux exhibits a poleward decrease. Limited data from polar regions show fluxes of opaline silica not significantly higher than elsewhere. The variability of flux over annual cycles was calculated and expressed as a Flux Stability Index (FSI) and the relationship between this and vertical flux of material examined. Somewhat surprisingly there is no significant relationship between FSI and fluxes of dry mass, organic carbon, inorganic carbon or opaline silica. At each site, net annual primary production was determined using published satellite derived estimates. There is a negative but weak relationship between FSI and the proportion of primary production exported to 2000 m (e2000 ratio). The most variable of the non-polar environments export to 2000 m about twice as much of the primary production as the most stable ones. Polar environments have very low e2000 ratios with no apparent relationship to FSI. At primary production levels below 200 g C/m2/y there is a positive correlation between production and organic carbon flux at 2000 m but above this level, flux remains constant at about 3.5g C/m2/y. A curve derived to describe this relationship was applied to estimates of annual primary production in each of 34 of the open ocean biogeochemical provinces proposed by Longhurst et al. (1995). Globally, open ocean flux of organic carbon at 2000 m is 0.34 Gt/yr which is 1% of the total net primary production in these regions. This flux is nearly equally divided between the Atlantic, Pacific and Southern Oceans. The Indian and Arctic oceans between them only contribute 5% to the total. The eight planktonic climatological categories proposed by Longhurst (1995) provide a most useful means of examining the data on flux and its variability. A characteristic level of FSI was found in each category with highest levels in the tropics and lowest levels in the Antarctic. There is also a characteristic level of export ratio in each category with the highest in monsoonal environments (1.7%) and the lowest in Antarctica (0.1%)
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  • 82
    Publication Date: 2017-10-05
    Description: Since large, homogeneous dielectric particles have positive asymmetry parameters even when they are densely packed, it has been hypothesized that negative asymmetry parameters retrieved with Hapke's phenomenological model of bidirectional reflectance result from a complicated internal structure of planetary regolith particles. This paper tests that hypothesis by theoretically computing asymmetry parameters for isolated and densely packed composite spherical particles with size typical of regolith grains. It is assumed that the wavelength of the scattered light is much smaller than the particle size, and that particles are filled with large numbers of small inclusions. The computations show that it is essentially impossible to make asymmetry parameters of planetary regolith particles even slightly negative by filling the particles with large numbers of internal inclusions in the form of voids and/or grains with a refractive index substantially different from that of the host medium. Asymmetry parameters are positive even for densely packed composite particles with no internal absorption and extreme values of the internal scattering coefficient. Furthermore, they are sharply increased by even modest absorption inside composite particles, by reducing the refractive index contrast between the inclusions and the host particles, and/or by decreasing the packing density. Thus, the negative asymmetry parameters retrieved with Hapke's model need another explanation rather than assuming that they are real and are the result of a complicated internal structure of regolith particles. Besides the opposition-effect term, Hapke's model is nothing more than an approximate solution of the radiative transfer equation which inherently violates the energy conservation law. Therefore, the negative asymmetry parameters are likely to be numerical artefacts resulting from the approximations made in the model.
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  • 83
    Publication Date: 2016-05-25
    Description: Oceanic and atmospheric circulation patterns varied considerably during the Tertiary and Quaternary and influenced the geochemical cycles of elements in seawater. We report the first resolution lead and neodymium isotopic record of such changes at a high time resolution in two depths profiles from a hydrogenous FeMn crust. The crust, Va13-2, is located in the central Pacific (146°W, 9°25′N, 4830 m) and has previously been dated by 230Th and 10Be. The first profile was drilled with a sample time resolution of ∼3 kyr and allows evaluation of short-term changes to lead and neodymium sources to central Pacific seawater over the last 400 kyr (marine δ18O stages 2 to 11). Longer-term changes were monitored at lower time resolution in a second profile to an age of 10 Ma. Short-term variations in lead and neodymium isotope ratios are resolved in the high resolution profile (0 to 400 kyr). Superimposed on the short-term variations is a secular decrease in Full-size image (〈1 K) ratios beginning at ∼130 kyr in marine δ18O stage 5, implying a change in the lead sources to the central Pacific. Lead and neodymium isotopic compositions indicate an increased influence from Central American eolian sources to Pacific seawater at this time. Lead isotopes are found to be statistically more variable during interglacial than glacial periods. These observations are supported by the greater eolian dust fluxes found in sediment cores from the equatorial Pacific during interglacial stages. The most important paleoceanographic event of the last 10 Ma to affect Pacific seawater was the closure of the Panama gateway. Changes in lead and neodymium isotopes in Val3-2 during the last 10 Ma occurred along with gradual closure of the Panama straits. However, these changes did not occur in tandem: while neodymium isotope ratios increase between 10 and 8 Ma, lead isotope ratios remain constant. In contrast, the period 7 to 1 Ma is marked by a secular increase in lead isotope ratios but nearly constant neodymium. These changes are consistent with a source of radiogenic lead and neodymium conveyed by the Circumpolar Current into the Pacific, rather than by the Panama gateway, and involve 20 to 40% Southern Component Water (SCW) input of lead and neodymium. Modelling of lead and neodymium isotopic mixing between the different water masses involved in generating Pacific deep waters lead us to the following conclusions: (1) Small variations in the strength and composition of North Atlantic Deep Water (NADW) have a relatively minor effect on the amounts of lead and neodymium from SCW contributing to the Pacific and (2) an enhanced SCW flow with an open isthmus of Panama, as suggested by General Circulation Models (GCM), requires a corresponding reduction in NADW Pb and Nd contributions to SCW. The general agreement between the isotopic compositions of surface layers of Mn nodules, integrated over such long time intervals, and those of present-day bottom waters at their respective locations show that the present-day ocean circulation pattern has dominated through the Pleistocene. Our study of Mn crust Va13-2 shows that shorter-term changes in lead and neodymium isotope ratios can be resolved, provided that such crusts are sampled at an appropriate time resolution.
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  • 84
    Publication Date: 2017-09-26
    Description: Precise strontium isotope ratios, combined with chemical analyses and sedimentological information, are used to monitor the water sources and the evolution of the Dead Sea and its late Pleistocene precursor, Lake Lisan (70-18 kyr B.P.). The materials analyzed include bulk aragonite, water-leached soluble salts, and residual aragonite and gypsum from the Lisan Formation in the Perazim Valley (near the SW shore of the Dead Sea). The residual aragonite and the associated soluble salts display systematic fluctuations in 17Sr86Sr ratios between 0.70803 and 0.70806 and from 0.70805 to 0.70807, respectively. In individual soluble salt-residual aragonite pairs, the soluble salt displays a higher 87Sr86Sr ratio. Gypsum samples yield 17Sr86Sr ratios similar to the soluble salts from adjacent layers in the section. This shows that, in individual samples, the source of Sr in aragonite was distinct from that in soluble salts and the gypsum. The sterility of the Lisan sediments, their strictly nonbioturbated fine lamination, and their high content of chloride salts indicate that Lake Lisan was a saline, or even hypersaline water body. In the absence of alternative sources of HCO3− and S042− the abundance of primary aragonite and gypsum in the Lisan column reflects an import of very large volumes of freshwater into the otherwise saline lake, resulting in a density stratification of this water body. The history of the upper water layer and that of the lower brine is reflected in the chemical and strontium isotope composition of the aragonite and in that of the associated soluble salts and in the gypsum samples, respectively. Whereas the bicarbonate and much of the Ca2+ required for aragonite crystallization were supplied by the freshwater, the complementary Ca2+ (and Sr 2+) were added by the lower brine. The upper water layer of Lake Lisan acted as a SO42− capacitor during the lake's rise periods. It was removed therefrom, as prominent gypsum beds, upon climatic-induced (drier period) mixing or even complete overturn of the lake. The evolution of Lake Lisan took place between two distinct modes. The first was characterized by an extensive supply of freshwater and resulted in a rise of the lake's level, a (density) layered structure, and precipitation of aragonite. The second mode was marked by a diminishing freshwater input, resulting in mixing or complete overturn of its water, and precipitation of gypsum. These two modes reflect the climatic evolution of the region in the late Pleistocene which fluctuated between drier and wetter periods. The transition to the Holocene is accompanied by the dry up of Lake Lisan and its contraction to the present Dead Sea.
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  • 85
    facet.materialart.
    Unknown
    Elsevier
    In:  Deep Sea Research Part I: Oceanographic Research Papers, 40 (8). pp. 1547-1557.
    Publication Date: 2016-10-19
    Description: Moored Acoustic Doppler Current Profilers (ADCPs) were used to analyse the daily vertical zooplankton migration and its seasonality. One-year records of vertical velocity and acoustic backscatter were obtained at four stations in the Greenland Sea. Both parameters exhibited a diurnal cycle typical for vertically migrating zooplankton. Upward and downward migration occured in short periods approximately 5 h long, and peak migration velocities were around 1.5 cm s−1. Similar structures were observed at all four mooring sites in the 200–300 m depth range. Farther down, between 1000 and 1400 m, no daily migration was observed. Strong seasonal variations are evident, and both the phase and intensity of the migration pattern change with daylight as the season progresses. In summer and during the polar night the migration became very weak and was only detectable in the displacement of scattering layers. When the day/ night contrast was large, intense upward or downward motion was accompanied by sloping backscatter isopleths. We observed two main scattering layers, a deep layer that varies in depth with season and an almost invariable shallow scattering layer at about 150 m depth. The deep layer was interpreted as the “resting depth” of the migrating plankter, and the latter as their “feeding horizon”. Changes in the “resting depth” from about 400 m in autumn and spring to about 200 m in winter lead to seasonal variations in the migration distance. This behaviour is discussed with respect to environmental conditions.
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  • 86
    Publication Date: 2018-03-21
    Description: Iridium enrichments, at or close to the K/T boundary, are often cited as evidence for impacts of cosmic bodies or volcanic events, or both, that resulted in mass extinctions. A third possible explanation for the high Ir concentrations, that the enrichments were caused by the cosmic micrometeorite flux during times of slow Sediment accumulation, has generally been rejected. In this study we examine the Ir/Au ratios and conclude that they may indicate enrichment of siderophile elements by slow sedimentation. In addition, the concept of slow sedimentation at the K/T boundary is consistent with many aspects of the K/T boundary research such as the gradual decline of the species before the major extinction level and recent reports of faunal transitions from Cretaceous to Tertiary without sudden extinctions, hiatuses or Ir anomalies.
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  • 87
    facet.materialart.
    Unknown
    Elsevier
    In:  Sedimentary Geology, 82 (1-4). pp. 145-155.
    Publication Date: 2016-09-07
    Description: 50 m of Middle Eocene pure radiolarian ooze were drilled at ODP Site 660 in the equatorial East Atlantic, 80 km northeast of the Kane Gap. The oozes comprise a 10 m high and 2 km broad mound of seismic reverberations, covered by manganese-rich sediment, and contain trace amounts of sponge spicules and diatoms, negligible organic carbon (0.15%), clay, and variable amounts of pyrite. The yellow to pale brown silty sediments are relatively coarse-grained (30–45% coarser than 6 μm), little bioturbated, and commonly massive or laminated on a cm-scale. The unlithified radiolarian ooze may indicate an interval of high oceanic productivity, probably linked to a palaeoposition of Site 660 close to the equatorial upwelling belt during Middle Eocene time. The absence of organic matter, however, and both the laminated bedding and the mound-like structure of the deposit on the lower slope of a continental rise indicate deposition by relatively intense contour currents of oxygen-rich deep water, which passed through the Kane Gap, winnowed the fine clay fraction, and prevented the preservation of organic carbon. The ooze may be either a contourite-lag deposit, or a contourite accumulation of displaced radiolarians, originating south of the Kane Gap and being deposited in its northern lee, thus documenting the passage of a strong cross-equatorial bottom-water current formed near Antarctica. These Eocene contourites may be an analogue for ancient radiolarites in the Tethyan Ocean.
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  • 88
    Publication Date: 2017-09-26
    Description: Pelitic schists from the lower garnet to lower staurolite zones from the Rangeley, Perry Mountain, and Smalls Falls formations of western Maine were analyzed for major elements, trace elements, and neodymium isotopes. These formations were derived from highlands created during the Taconian orogeny, deposited into a trough, and metamorphosed during subsequent orogenic events. Most major and trace element abundances relative to Al2O3 were statistically identical between zones of the same formation, as well as between formations. Although the average major element composition of these formations are the same, there are systematic variations in some elements. Notably, plots of SiO2 vs. Al2O3 and K2O vs. Al2O3 suggest that most of the variation could be produced by mixing of a fairly constant ratio of clay minerals and feldspar with varied amounts of quartz due to sorting in the sedimentary system. Different amounts of these minerals should not influence the shape of the REE patterns of the metapelites, but higher amounts of quartz and feldspar may dilute the REEs and most elemental abundances of the clay minerals and lead to lower elemental abundances. The major difference between the samples within the Perry Mountain Formation are different LREE and MREE abundances relative to Al2O3 which are not correlated to differences in major element or other trace element abundances relative to Al2O3. The samples in the Perry Mountain with higher LREE and MREE abundances have, for example, 42.3 ± 8.3 ppm, and those with low abundances have 5.6 ± 3.6 ppm. The samples with the high REE abundances of the Perry Mountain Formation are similar in abundances and REE patterns to those of the Rangeley and Smalls Falls formations typical of mudstones derived from granitoids. Another difference between the low and high REE abundance samples are the calculated Tdm model ages. The high REE abundance samples of the Perry Mountain Formation show Tdm similar to the samples of the Rangeley Formation, with ages of about 1.7–1.8 Ga. The Perry Mountain samples with low REE abundances, however, give unrealistically old Tdms between 2.5 and 5.3 Ga. These unrealistically old Tdms are due to the relatively high Sm/Nd ratios (compared to crustal values) which are characteristic of samples of the Perry Mountain Formation with lower REE abundances. We therefore suggest that these samples may be indicators for open system behavior of the neodymium isotopic system. The timing of this disturbance of the neodymium isotope system is difficult to determine and cannot be tied to weathering or a definite postdepositional event. The complexities of the data suggest more than one resetting event. The most likely event that could have produced much of the movement of the LREEs and MREEs could have been due to small scale migration between anoxic hemipelagites and turbidite mudstones during diagenesis, but some migration may have continued during metamorphism in order to reconcile the neodymium isotopic data.
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  • 89
    Publication Date: 2016-05-26
    Description: A new phototrophic purple bacterium was isolated from a flat, laminated microbial mat in a salt marsh near Woods Hole, Mass., USA. The spiral-shaped bacterium was highly motile and had bipolar tufts of flagella and intracytoplasmic membranes of the vesicular type. The major photosynthetic pigments were identified as the carotenoid tetrahydrospirilloxanthin and bacteriochlorophyll b. The long wavelength in vivo absorption maximum of the bacteriochlorophyll was at 986 nm. The marine bacterium showed optimal growth in the presence of 2% NaCl. It utilized a number of organic substrates as carbon and energy sources and required vitamins and sulfide as a reduced sulfur source for growth. In the presence of sulfide, elemental sulfur globules were formed outside the cells. Elemental sulfur was not further oxidized to sulfate. The new isolate had a unique lipid and fatty acid composition, and according to the 16S rRNA gene sequence, it is most similar to Rhodospirillum rubrum. It is described as a new species and assigned to a new genus with the proposed name Rhodospira trueperi.
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  • 90
    Publication Date: 2016-05-26
    Description: From the microbial mats that develop in Solar Lake, a new purple sulfur bacterium was isolated. This strain (Chromatium strain SL 3201) was morphologically similar to Chromatium gracile and Chromatium minutissimum. Chromatium SL 3201 was found to be a moderate halophile with a growth range between 2 and 20% NaCl (optimum 4-5% NaCl) and was able to grow photo-organotrophically using glycolate and glycerol. It is the first described phototrophic sulfur bacterium able to use glycolate. According to NaCl requirements and utilization of organic compounds, the strain is not related to any known species of the genus Chromatium. On the basis of its 16S rRNA gene sequence, it clusters with other Chromatium species and is most similar to Chromatium salexigens and Chr. gracile, but it is sufficiently separated to be considered as a new species of the genus. It is, therefore, described as Chromatium glycolicum sp. nov.
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  • 91
    facet.materialart.
    Unknown
    Elsevier
    In:  Deep-Sea Research Part II-Topical Studies in Oceanography, 44 (1/2). pp. 69-90.
    Publication Date: 2016-10-10
    Description: High biogenic silica (BSi) concentrations (maximum: 11.7μmoll−1) were recorded during late November at the southern border of the Polar Frontal region (PFr). Position of the BSi maximum at depth suggested the occurrence of a sinking diatom population. By contrast, siliceous biomass was low (BSi 〈0.6 μmol l−1) in the Marginal Ice Zone (MIZ) despite a sea-ice retreat of 200 km during the study period. Diatoms released from the receding ice were not actively growing. The Permanently Open Ocean Zone also showed very low BSi biomass (〈0.5μmol l−1) and appeared as an area where phytoplankton are not dominated by siliceous organisms, especially in its middle part where BSi/POC (particulate organic carbon) molar ratios ranged between 0.04 and 0.06 at 53°S, from surface to 200 m depth. At the southern border of the PFZ, the bloom coincided with an area of high lithogenic silica concentrations probably of aeolian origin. In addition, BSi/POC molar ratios measured in the PFZ were the highest ever recorded in the surface waters of the Southern Ocean (maximum: 1.75). This could be due to the presence of heavily silicified diatoms such as Fragilariopsis kerguelensis or also could reflect the more rapid recycling of POC as compared to BSi. Within the bloom area BSi concentrations were positively correlated to pyrophaeophytin pigments, possibly indicating the occurrence of a senescent diatom population. High concentrations of BSi (〉 1.5 μmol Si 1−1) extended to 200 m between 49°S and 51°S. Numerous empty frustules also were observed, suggesting significant sedimentation of siliceous particles between 49°S and 51°S. Estimates of the BSi production of the Polar Frontal region are derived from 14C primary production and appropriate BSi/POC ratios, and implications for the total annual production of BSi for the Southern Ocean are discussed.
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  • 92
    facet.materialart.
    Unknown
    Elsevier
    In:  Marine Micropaleontology, 20 . pp. 215-234.
    Publication Date: 2017-07-21
    Description: In situ observations of microhabitat preferences of living benthic foraminifera are presented from sediments of the Norwegian-Greenland Sea, the upwelling area off northwestern Africa and the shallow-water Kiel Bight (Baltic Sea). Certain foraminiferal species (e.g.Cibicidoides wuellerstorfi andRupertina stabilis) can be regarded as strictly epibenthic species, colonizing elevated habitats that are strongly affected by bottom water hydrodynamics. Large epibenthic foraminifera (e.g.Rhabdammina abyssorum andHyperammina crassatina) colonize the sediment surface in areas where strong bottom currents occur and might have by virtue of their own size an impact on the small-scale circulation patterns of the bottom water. Motile species changing from epifaunal to infaunal habitats (e.g.Pyrgo rotalaria, Melonis barleeanum, Elphidium excavatum clavatum, Elphidium incertum, Ammotium cassis andSphaeroidina bulloides) are regarded here as highly adaptable to changes in food availability and/or changing environmental conditions. This flexible behaviour is regarded as a dynamic adaptation to optimize food acquisition, rather than a static concept leading to habitat classification of these ubiquitous rhizopods.
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  • 93
    Publication Date: 2017-06-23
    Description: The Houtman Abrolhos reefs, situated on the western continental margin of Australia, occupy a transitional position between cool-water shelf carbonate sediments to the south and more tropical environments to the north. Their existence at the outer limits of the geographical range for coral reef growth is a result of the warm, poleward-flowing Leeuwin Current. Though the modern reefs differ ecologically from tropical reefs, their geological characteristics have been little known until recently. Each of the three island groups in the Abrolhos consists of a central platform of Last Interglacial reefs, about which windward and leeward Holocene reefs have developed asymmetrically. In the Easter Group the subtidal windward reef in the west is ca. 10 m thick and is backed by a leeward-prograding, lagoon sand sheet which is 0–3 m thick. The emergent parts of the leeward reefs in the east consist of an upward-shallowing sequence comprising reef facies, peritidal rudstone facies, and coral rubble storm ridges. This is underlain by over 26 m of Holocene reef facies. Coring and dating of the Holocene reefs (using both TIMS and 14C methods) in the Easter Group has shown significantly different lithofacies in the windward and leeward reefs, and has allowed reconstruction of Holocene reef growth and sea-level history. Coralline algal bindstones and interbedded coral framestone facies characterise the relatively slow-growing windward Holocene reefs, whereas the fast-growing leeward reefs consist of coral framestone facies which are dominated by Acropora. The leeward reefs commenced growth about 10,000 years ago and the Morley reef grew to 0.3 m above present sea level by 6400 years B.P., recording a relative high sea-level event. This generated Holocene constructional topography characterised by “blue-hole” terrain. Windward Holocene reef growth commenced after 8200 years B.P. following erosion of the windward part of the Last Interglacial platform. High wave energy and competition with macroalgae limited coral growth, and the coralline algal-dominated windward reefs grew more slowly to sea level. The Holocene sea-level record provided by dates from the 26 m core of the Morley reef (a “keep-up” reef) is the first such record from the western continental margin of Australia.
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  • 94
    facet.materialart.
    Unknown
    Springer
    In:  Physics and Chemistry of Minerals, 24 . pp. 281-293.
    Publication Date: 2017-01-03
    Description: Mössbauer spectroscopy was applied to characterize the valence states Fe(II) and Fe(III) in sedimentary minerals from a core of the Peru Basin. The procedure in unraveling this information includes temperature-dependent measurements from 275 K to very low temperature (300 mK) in zero–field and also at 4.2 K in an applied field (up to 6.2 T) and by mathematical procedures (least-squares fits and spectral simulations) in order to resolve individual spectral components. The depth distribution of the amount of Fe(II) is about 11% of the total Fe to a depth of 19 cm with a subsequent steep increase (within 3 cm) to about 37%, after which it remains constant to the lower end of the sediment core (at about 40 cm). The steep increase of the amount of Fe(II) defines a redox boundary which coincides with the position where the tan/green color transition of the sediment occurs. The isomer shifts and quadrupole splittings of Fe(II) and Fe(III) in the sediment are consistent with hexacoordination by oxygen or hydroxide ligands as in oxide and silicate minerals. Goethite and traces of hematite are observed only above the redox boundary, with a linear gradient extending from about 20% of the total Fe close to the sediment surface to about zero at the redox boundary. The superparamagnetic relaxation behavior allows to estimate the order of magnitude for the size of the largest goethite and hematite particles within the particle-site distribution, e.g. ∼170 Å and ∼50 Å, respectively. The composition of the sediment spectra recorded at 300 mK in zero-field, apart from the contributions due to goethite and hematite, resembles that of the sheet silicates smectite, illite and chlorite, which have been identified as major constituents of the sediment in the 〈2 μm fraction by X-ray diffraction. The specific “ferromagnetic” type of magnetic ordering in the sediment, as detected at 4.2 K in an applied field, also resembles that observed in sheet silicates and indicates that both Fe(II) and Fe(III) are involved in magnetic ordering. This “ferromagnetic” behavior is probably due to the double-exchange mechanism known from other mixed-valence Fe(II)–Fe(III) systems. A significant part of the clay-mineral iron is redox sensitive. It is proposed that the color change of the sediment at the redox boundary from tan to green is related to the increase of Fe(II)–Fe(III) pairs in the layer silicates, because of the intervalence electron transfer bands which are caused by such pairs.
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  • 95
    facet.materialart.
    Unknown
    Elsevier
    In:  Deep-Sea Research Part II-Topical Studies in Oceanography, 44 (1/2). pp. 23-50.
    Publication Date: 2016-10-10
    Description: Small-scale features of the Antarctic Circumpolar Current (ACC) along a meridional section at 6°W between the Polar Front and the ACC-Weddell Gyre Boundary Front are discussed using data collected during the austral spring cruise ANT X/6 of R. V. Polarstern organized within the framework of the European IGBP-JGOFS (Southern Ocean). The section covered three distinct fronts, namely the Polar Front, the Southern Polar Front (also Southern ACC Front), and the ACC-Weddell Gyre Boundary Front. Physical measurements during repeated transects over a period of 6 weeks in October/November revealed a large variability in the Polar Frontal region, indicating meandering and eddy shedding. The positions of the Southern Polar Front and the ACC-Weddell Gyre Boundary Front were observed to be far more stable than that of the Polar Front. A possible reconstruction of the meandering flow field near the Polar Front, based upon the physical observations, is presented. Details in the flow field coincide with the spatial distribution of a number of biological parameters such as phytoplankton biomass and species, and photosynthetic pigments. Although a causal relationship between them is likely, biomass enhancement cannot be understood simply in terms of macronutrients from deeper layers entering the euphotic zone, as substantiated for other oceanic frontal regions, because macronutrients do not limit phytoplankton blooms. This process, however, can be important for the micronutrient iron. Evidence is presented that the Antarctic Zone of the ACC can be subdivided into a number of spheres of influence related to the fronts. Interleaving of water is apparent between positions within such a region, but not between the regions.
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  • 96
    Publication Date: 2017-06-23
    Description: The Foundation Seamounts form a 1400 km-long chain on the Pacific plate from 32 °S, 127 °W to the Pacific-Antarctic spreading axis at 38 °S, 111 °W. Previously only known from sparse single-beam echosoundings and satellite altimetry, we present here the first multibeam bathymetric survey and geological sampling results. We confirm that the submarine topography correlates with the altimetry, and that the chain is volcanic rather than tectonic or microcontinental in origin. The chain can be divided up morphologically and geochemically into three section: (1) west of 125 °W large flat-topped volcanoes composed of incompatible-element depleted lavas ( ≈ 1) of a near-ridge origin with little or no plume influence, (2) between 125 and 115 °W true intraplate volcanoes with incompatible element enrichment ( 〉 1.9) generated over the Foundation plume, (3) east of 115 °W E-W-trending volcanic ridges with compositions ( 2.0-0.3) suggestive of interaction between the plume and the Pacific-Antarctic spreading axis. On the spreading axis moderate incompatible element enrichments ( ≈0.8, cf. ≈ 0.3 outside the Foundation area) also suggest plume influence. It appears that the activity of the Foundation plume in the last few million years has (1) significantly waned and (2) become wholly channeled towards the spreading axis. The Foundation plume may be in the process of “dying”.
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  • 97
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    Unknown
    Springer
    In:  Applied Physics B, 57 (2). pp. 109-112.
    Publication Date: 2020-04-14
    Description: Here we describe experiments aimed at developing an element-selective ion source for thorium (Th). The technique applied is resonance ionization spectroscopy (RIS) with a thermal atom beam. Ionization schemes for isotopically nonselective ionization of Th as well as for isotopically selective ionization of 230Th are proposed. The RIS-scheme used is two-photon two-colour ionization with excitation in the ultraviolet spectral range between 244 nm and 267 nm or in the visible spectral range between 485 nm and 529 nm. Ionization of the excited atoms is performed either by ultraviolet photons or by visible photons, depending on the energy required for this process.
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  • 98
    facet.materialart.
    Unknown
    Elsevier
    In:  Deep Sea Research Part II: Topical Studies in Oceanography, 40 (1-2). pp. 521-536.
    Publication Date: 2019-01-21
    Description: During a R.V. Meteor JGOFS-NABE cruise to a tropical site in the northeast Atlantic in spring 1989, three different vertical regimes with respect to nitrate distribution and availability within the euphotic zone were observed. Besides dramatic variations in the depth of the nitracline, a previously undescribed nose-like nitrate maximum within the euphotic zone was the most prominent feature during this study. Both the vertical structure of phytoplankton biomass and the degree of absolute and relative new production were related to the depth of the nitracline, which in turn was dependent on the occurrence/non-occurrence of the subsurface subtropical salinity maximum (S(max)). The mesoscale variability of the nitracline depth, as indicated from a pre-survey grid, and published data on the frequent occurrence of the S(max) in tropical waters suggest higher variability of new production and F-ratio than usually expected for oligotrophic oceans. The importance of salt fingering and double diffusion for nitrate transport into the euphotic zone is discussed.
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  • 99
    Publication Date: 2018-03-21
    Description: The spatial distribution and species composition of high-Antarctic ichthyonekton was investigated during the EPOS 3 cruise by RV Polarstern in the eastern Weddell Sea during January–February 1989. A multiple rectangular midwater trawl was used to collect samples from the surface to near the sea floor at 11 stations along a 245 kra transect off Halley Bay. Early larval stages of 18 species, representing about 24% of the known Weddell Sea ichthyofauna, were present in the water column. The Antarctic silver-fish, Pleuragramma antarcticum, over-whelmingly dominated the catches comprising 84.5% of the 5022 specimens caught. The abundance of this species markedly increased towards the offshore end of the transect with the highest numbers occurring near the shelf-break front associated with the westerly current of the southern limb of the Weddell Gyre. The increased abundance of P. antarcticum in continental slope waters was attributed to deflection of the East Weddell Coastal Current beyond the shelf/slope break by fringing ice shelves. Most larval and juvenile fish were found in the seasonally warmed upper 0–70 m layer of the Antarctic Surface Water where conditions occurred that appeared to be favourable to both feeding and growth. Cluster analysis indicated that inner-, central-and outer-shelf assemblages were represented and that the species composition was most effectively described by reference to water mass and depth.
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  • 100
    Publication Date: 2016-05-17
    Description: Al- and Ti-rich smectites associated with alkaline volcanic rocks were dredged during several cruises of the German research vessel “SONNE” as part of an extensive survey of manganese crusts in the Central Pacific seamount region. X-ray diffraction, chemical composition and infrared spectroscopy suggest that the smectites are constituents of the nontronite-beidellite solid solution series. X-ray fluorescence analyses yield considerable amounts of Al2O3 and Fe2O3 averaging 14.5 and 12.4 wt%, respectively. According to ASTM data the smectites are Al-rich nontronites rather than Fe-rich beidellites. A TiO2 content of up to 4.9 wt% is thought to be due to anatase impurities. δ18O-values in the range of +23.8 to +21.0‰ vs. SMOV indicate formation temperatures of 32–48°C. The rare-earth element patterns of the nontronitic smectites and associated alkaline volcanics are almost identical, showing a relative enrichment of light and a depletion of heavy rare-earth elements. It is concluded that the smectites formed as low-temperature alteration products during interaction of seawater with cooling basaltic/alkaline rocks rather than by mixing of hydrothermal fluids with seawater.
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