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  • 1
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    Journal of intelligent manufacturing 10 (1999), S. 323-329 
    ISSN: 1572-8145
    Keywords: Computer-aided design ; rapid prototyping ; modeling ; simulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The direct slicing of CAD models created in CADDS V to generate geometric data for rapid prototyping using fused feposition modeling technique (FDM) is presented in this paper. The report file from an explicit model is accessed for obtaining model data. Algorithms have been developed for determining the volumes of model material as well as support materials. New algorithms have been developed for filling the sheet solid. A simulation module has been developed to verify whether the filling is correctly done. Example of a model is manufactured using this approach is also presented in this paper.
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  • 2
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    Journal of intelligent manufacturing 10 (1999), S. 405-421 
    ISSN: 1572-8145
    Keywords: Flexible manufacturing systems control ; intelligent manufacturing ; neural networks ; simulation ; material handling systems ; automated guided vehicles
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract This paper presents a framework of intelligent manufacturing scheduling and control with specific applications to operations of rail-guided vehicle systems (RGVS). A RGVS control architecture is discussed with a focus on a simulated experiment in operations of the load/unload area of a real industrial flexible manufacturing system (FMS). In the operation stage of a material handling system (MHS), all shop floor data are subject to change as time goes. These data can be collected using a data acquisition device and stored in a dynamic database. The RGVS simulator used in this experimental study is designed to incorporate some possible situations representing existing material handling scenarios in order to evaluate alternative control policies. At the development stage of the controller, all possible combinations of most commonly encountered scenarios such as RGV failures, production schedule changes, machine breakdowns, and rush orders are to be simulated and corresponding results collected. The data are then structured into training data pairs to properly train an artificial neural network. The neural network, trained by using input/output data sets obtained from a number of simulation runs, will then provide control strategy recommendations. At the application stage, whenever an abnormal scenario occurs, a pre-processor will be activated to pre-screen and prepare an input vector for the trained neural network. If such an abnormal scenario falls outside the existing domain of data sets employed to train the neural network, as judged by the MHS supervisory controller, an off-line training module will be activated to eventually update the neural network. The recommended control strategies will be transmitted to the MHS control for real-time execution. If there is no further abnormal event detected, the dynamic data base (DDB) module simply continues to monitor the MHS activities. The proposed MHS control system combines the features of example based neural network technology and simulation modeling for true intelligent, on-line, pseudo real-time control. Not only will the system assure that feasible material handling control actions be taken, but also it will implement better control decisions through continuous learning from experiences captured as the operation time of the MHS accumulates.
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  • 3
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    Journal of intelligent manufacturing 10 (1999), S. 449-462 
    ISSN: 1572-8145
    Keywords: Control chart ; pattern recognition ; neural network ; simulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Abnormal patterns on manufacturing process control charts can reveal potential quality problems due to assignable causes at an early stage, helping to prevent defects and improve quality performance. In recent years, neural networks have been applied to the pattern recognition task for control charts. The emphasis has been on pattern detection and identification rather than more detailed pattern parameter information, such as shift magnitude, trend slope, etc., which is vital for effective assignable cause analysis. Moreover, the identification of concurrent patterns (where two or more patterns exist together) which are commonly encountered in practical manufacturing processes has not been reported. This paper proposes a neural network-based approach to recognize typical abnormal patterns and in addition to accurately identify key parameters of the specific patterns involved. Both single and concurrent patterns can be characterized using this approach. A sequential pattern analysis (SPA) design was adopted to tackle complexity and prevent interference between pattern categories. The performance of the model has been evaluated using a simulation approach, and numerical and graphical results are presented which demonstrate that the approach performs effectively in control chart pattern recognition and accurately identifies the key parameters of the recognized pattern(s) in both single and concurrent pattern circumstances.
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  • 4
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    Journal of polymers and the environment 7 (1999), S. 35-40 
    ISSN: 1572-8900
    Keywords: Starch ; starch blends ; sorption ; diffusion ; biodegradation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The interval sorption and diffusion of water vapor were studied for two systems: methylcellulose (MC)/starch and carboxymethylcellulose (CMC)/starch. The diffusion coefficient of water vapor and the Gibbs free energy of swelling of these blends in water were estimated. The Gibbs free energy of mixing starch with the cellulose derivatives was determined using the thermodynamic cycle. CMC/starch was shown to be more compatible than MC/starch. Biodegradation of these systems in the water–soil environment was measured and found to increase with the concentration of starch in its blends with cellulose derivatives.
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  • 5
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    Journal of cluster science 10 (1999), S. 359-380 
    ISSN: 1572-8862
    Keywords: Silicon ; nanoparticles ; luminescence
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract We have prepared several nanometer-sized silicon colloids in organic liquids in the range from 3.7 to 9.8 nm with a constant weight density of 1 mg/ml by a gas evaporation technique. The blue–green luminescent energy was found to be independent of size, in contrast to its intensity and optical absorption, which showed a clear size effect. Special emphasis is placed on the advantage of using a colloidal system: controllability of mass density in a unit volume, isolation of each particle, selection of wide band-gap substances, capability of absolute quantum efficiency, and easy surface modification. As an example of the above advantages, we have determined the absolute quantum yield as a function of size. From the quantum yield thus derived and the proposed model that combines surface as well as volume effects, experimentally obtained parameters such as the diffusion velocity of an electron–hole pair and the initial flight distance of this pair are found to be consistent with those obtained from other data.
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  • 6
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    International journal of flexible manufacturing systems 11 (1999), S. 271-289 
    ISSN: 1572-9370
    Keywords: random flexible manufacturing systems ; scheduling ; simulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The increased use of flexible manufacturing systems to efficiently provide customers with diversified products has created a significant set of operational challenges for managers. Many issues concerning procedures and policies for the day-to-day operation of these systems still are unresolved. Previous studies in this area have concentrated on various problems by isolating or simplifying the systems under study. The primary objective of this study is to extend previous research by examining the effects of scheduling rules and routing flexibility on the performance of a constrained, random flexible manufacturing system (FMS). Other experimental factors considered are shop load, shop configuration, and system breakdowns. Within the bounds of this experiment, the results indicate that, in the presence of total routing flexibility, the effects of shop load, system breakdowns, and scheduling rules are significantly dampened. In particular, when total routing flexibility exists, the choice of scheduling rules is not critical. We also show that the behavior of scheduling rules in a more constrained FMS environment (i.e., where system breakdowns occur and material handling capability is limited) is consistent with the findings of previous research conducted under less constrained environments. Finally, results indicate that the shop configuration factor has little or no impact on a system's flow-time performance.
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  • 7
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    Computational & mathematical organization theory 5 (1999), S. 167-192 
    ISSN: 1572-9346
    Keywords: rational choice ; friendship ; Markov processes ; random utility models ; simulation ; empirical test
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract We propose a class of actor-oriented statistical models for closed social networks in general, and friendship networks in particular. The models are random utility models developed within a rational choice framework. Based on social psychological and sociological theories about friendship, mathematical functions capturing expected utility of individual actors with respect to friendship are constructed. Expected utility also contains a random (unexplained) component. We assume that, given their restrictions and contact opportunities, individuals evaluate their utility functions and behave such that they maximize the expected amount of utility. The behavior under consideration is the expression of like and dislike (choice of friends). Theoretical mechanisms that are modelled are, e.g., the principle of diminishing returns, the tendency towards reciprocated choices, and the preference for friendship relations with similar others. Constraints imposed on individuals are, e.g., the structure of the existing network, and the distribution of personal characteristics over the respondents. The models are illustrated by means of a data-set collected among university freshmen at 7 points in time during 1994 and 1995.
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  • 8
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    International journal of flexible manufacturing systems 11 (1999), S. 19-35 
    ISSN: 1572-9370
    Keywords: integration ; process planning ; simulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Many studies on integration of process planning and production scheduling have been carried out during the last decade. While various integration approaches and algorithms have been proposed, the implementation of these approaches is still a difficult issue. To achieve successful implementation, it is important to examine and evaluate integration approaches or algorithms beforehand. Based on an object-oriented integration testbed, a simulation study that compares different integration algorithms is presented in this paper. Separated planning method and integrated planning methods are examined. Also, situations of both fixed and variable processing times are simulated, and useful results have been observed. The successful simulation with the object-oriented integration testbed eventually will be extended to include other new planning algorithms for examining their effectiveness and implementation feasibility.
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  • 9
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    Positivity 3 (1999), S. 65-81 
    ISSN: 1572-9281
    Keywords: diffusion ; parabolic ; asymptotic behaviour ; nonlocal
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract The goal of this paper is to study diffusion problems associated with nonlinear diffusions of nonlocal type. We give existence and uniqueness results for these kind of problems and investigate the asymptotic behaviour.
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  • 10
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    Journal of computational analysis and applications 1 (1999), S. 349-385 
    ISSN: 1572-9206
    Keywords: Estimation ; geometric compound ; heavy-tail modeling ; Linnik distribution ; Mittag–Leffler law ; mixture ; multivariate Laplace distribution ; random summation ; simulation ; subordination
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract The paper discusses recent advances in the theory of multivariate geometric stable (GS) distributions. The results presented include characterizations, mixture representations, properties, simulation, and estimation.
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  • 11
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    Computational & mathematical organization theory 5 (1999), S. 361-384 
    ISSN: 1572-9346
    Keywords: bandwagons ; diffusion ; fads ; organizational collectivities ; reputation ; unprofitable innovations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract Bandwagon innovation diffusion is characterized by a positive feedback loop where adoptions by some actors increase the pressure to adopt for other actors. In particular, when gains from an innovation are difficult to quantify, such as implementing quality circles or downsizing practices, diffusion is likely to occur through a bandwagon process. In this paper we extend Abrahamson and Rosenkopf&2018;s (1993) model of bandwagon diffusion to examine both reputational and informational influences on this process. We find that the distribution of reputations among the set of potential adopters affects the extent of bandwagon diffusion under conditions of moderate ambiguity, and we find that bandwagons occur even when potential adopters receive information about others&2018; unprofitable experiences with the innovation.
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  • 12
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    Acta applicandae mathematicae 57 (1999), S. 287-338 
    ISSN: 1572-9036
    Keywords: sub-Riemannian geometry ; optimal control
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract This paper is a continuation of a series of papers, dealing with contact sub-Riemannian metrics on R3. We study the special case of contact metrics that correspond to isoperimetric problems on the plane. The purpose is to understand the nature of the corresponding optimal synthesis, at least locally. It is equivalent to studying the associated sub-Riemannian spheres of small radius. It appears that the case of generic isoperimetric problems falls down in the category of generic sub-Riemannian metrics that we studied in our previous papers (although, there is a certain symmetry). Thanks to the classification of spheres, conjugate-loci and cut-loci, done in those papers, we conclude immediately. On the contrary, for the Dido problem on a 2-d Riemannian manifold (i.e. the problem of minimizing length, for a prescribed area), these results do not apply. Therefore, we study in details this special case, for which we solve the problem generically (again, for generic cases, we compute the conjugate loci, cut loci, and the shape of small sub-Riemannian spheres, with their singularities). In an addendum, we say a few words about: (1) the singularities that can appear in general for the Dido problem, and (2) the motion of particles in a nonvanishing constant magnetic field.
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  • 13
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    Methodology and computing in applied probability 1 (1999), S. 127-190 
    ISSN: 1387-5841
    Keywords: combinatorial optimization ; global optimization ; importance sampling ; markov chain monte carlo ; simulated annealing ; simulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract We present a new and fast method, called the cross-entropy method, for finding the optimal solution of combinatorial and continuous nonconvex optimization problems with convex bounded domains. To find the optimal solution we solve a sequence of simple auxiliary smooth optimization problems based on Kullback-Leibler cross-entropy, importance sampling, Markov chain and Boltzmann distribution. We use importance sampling as an important ingredient for adaptive adjustment of the temperature in the Boltzmann distribution and use Kullback-Leibler cross-entropy to find the optimal solution. In fact, we use the mode of a unimodal importance sampling distribution, like the mode of beta distribution, as an estimate of the optimal solution for continuous optimization and Markov chains approach for combinatorial optimization. In the later case we show almost surely convergence of our algorithm to the optimal solution. Supporting numerical results for both continuous and combinatorial optimization problems are given as well. Our empirical studies suggest that the cross-entropy method has polynomial in the size of the problem running time complexity.
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  • 14
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    Archive of applied mechanics 69 (1999), S. 121-132 
    ISSN: 1432-0681
    Keywords: Key words large deformations ; porous material ; diffusion ; change of porosity ; filtration ; perturbation method
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Summary We present an example of the solution of a boundary value problem for a two-component porous material with large deformation of the skeleton. This example demonstrates the application of a consistent lagrangian description of porous materials which has been proposed earlier. Simultaneously, we demonstrate the important role of the balance equation of porosity which is an essential part of the thermodynamical model of porous materials proposed earlier. We show as well that a modified set of boundary conditions for permeable boundaries yields a solution of field equations which agrees qualitatively with expectations for the problem of axisymmetric stationary filtration. On the basis of a numerical evaluation of solution we indicate the existence of an instability of the model for very large porosities which could not be explained in this work.
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  • 15
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    Journal of intelligent and robotic systems 24 (1999), S. 125-149 
    ISSN: 1573-0409
    Keywords: planning ; control ; multi-fingered robot hand ; optimization ; internal force ; simulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract In this paper, the problem of controlling multi-fingered robot hands with rolling and sliding contacts is addressed. Several issues are explored. These issues involve the kinematic analysis and modeling, the dynamic analysis and control, and the coordination of a multi-fingered robot hand system. Based on a hand-object system in which the contacts are allowed to both roll and slide, a kinematic model is derived and analyzed. Also, the dynamic model of the hand-object system with relative motion contacts is studied. A control law is proposed to guarantee the asymptotic tracking of the object trajectory together with the desired rolling and/or sliding motions along the surface of the object. A planning approach is then introduced to minimize the contact forces so that the desired motion of the object and the relative motions between the fingers and the object can be achieved. Simulation results which support the theoretical development are presented.
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  • 16
    ISSN: 1572-896X
    Keywords: nanoparticles ; thermal plasma ; nanostructural film ; particle deposition ; silicon carbide ; film hardness
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics , Technology
    Notes: Abstract Nanostructured silicon carbide films have been deposited on molybdenum substrates by hypersonic plasma particle deposition. In this process a thermal plasma with injected reactants (SiCl4 and CH4) is expanded through a nozzle leading to the nucleation of ultrafine particles. Particles entrained in the supersonic flow are then inertially deposited in vacuum onto a temperature-controlled substrate, leading to the formation of a consolidated film. In the experiments reported, the deposition substrate temperature Ts has ranged from 250°C to 700°C, and the effect of Ts on film morphology, composition, and mechanical properties has been studied. Examination of the films by scanning electron microscopy has shown that the grain sizes in the films did not vary significantly with Ts. Micro-X-ray diffraction analysis of the deposits has shown that amorphous films are deposited at low Ts, while crystalline films are formed at high Ts. Rutherford backscattering spectrometry has indicated that the films are largely stoichiometric silicon carbide with small amounts of chlorine. The chlorine content decreases from 8% to 1.5% when the deposition temperature is raised from 450°C to 700°C. Nanoindentation and microindentation tests have been performed on as-deposited films to measure hardness, Young's modulus and to evaluate adhesion strength. The tests show that film adhesion, hardness and Young's modulus increase with increasing Ts. These results taken together demonstrate that in HPPD, as in vapor deposition processes, the substrate temperature may be used to control film properties, and that better quality films are obtained at higher substrate temperatures, i.e. Ts≈700°C.
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  • 17
    ISSN: 1572-896X
    Keywords: emulsion ; combustion ; ceramic ; nanoparticles ; synthesis ; barium titanate powder
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics , Technology
    Notes: Abstract The emulsion combustion method (ECM), a novel powder production process, was originally developed to synthesize nano-structured metal-oxide powders. Metal ions in the aqueous droplets were rapidly oxidized by the combustion of the surrounding flammable liquid. The ECM achieved a small reaction field and a short reaction period to fabricate the submicron-sized hollow ceramic particles with extremely thin wall and chemically homogeneous ceramic powder. Alumina, zirconia, zirconia–ceria solid solutions and barium titanate were synthesized by the ECM process. Alumina and zirconia powders were characterized to be metastable in crystalline phase and hollow structure. The wall thickness of alumina was about 10 nm. The zirconia–ceria powders were found to be single-phase solid solutions for a wide composition range. These powders were characterized as equiaxed-shape, submicron-sized chemically homogeneous materials. The powder formation mechanism was investigated through the synthesis of barium titanate powder with different metal sources.
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  • 18
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    Journal of nanoparticle research 1 (1999), S. 267-276 
    ISSN: 1572-896X
    Keywords: nanoparticles ; microemulsions ; reaction engineering ; formation model ; simulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics , Technology
    Notes: Abstract Engineering aspects of the preparation of palladium nanoparticles in non-ionic w/o-microemulsions are examined. In order to achieve reproducible synthesis conditions a semi-batch reactor with a standardized design is used. Influences of the stirring rate and of different ways of concentration control on the product properties are observed. For reproducible synthesis it is important to establish appropriate and defined preparation conditions. Monodisperse palladium particles of around 5 nm size are obtained by adding the microemulsion containing the palladium salt at a constant feed rate to the precharged microemulsion containing the reducing agent. A quantitative kinetic model is proposed to describe particle formation in microemulsions. Unknown parameters of the model have been estimated by independent examinations or can be achieved by fitting to the experimental data.
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  • 19
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    Journal of nanoparticle research 1 (1999), S. 349-352 
    ISSN: 1572-896X
    Keywords: alcohol–aqueous salt solutions ; ZrO2 ; nanoparticles ; aging
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics , Technology
    Notes: Abstract Parameters that influence ZrO2 (3-mol% Y2O3 stabilized) nanoparticles prepared by heating of alcohol–aqueous salt solutions were investigated. It revealed that the kind of alcohol used significantly affected the particle size and morphology of the as synthesized nano-ZrO2 powders. The ratio of alcohol to water (R/H) was also important to conduct the gelation process. The dispersion and sintering behavior of the powder could be optimized via aging. By carefully controlling the process, weakly agglomerated ZrO2 nanoparticles with an average particle size of 13-nm (TEM) were achieved. The classical DLVO theory was employed to clarify the effect of solvent on powder morphology, an aging mechanism was proposed as well.
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  • 20
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    Journal of nanoparticle research 1 (1999), S. 411-418 
    ISSN: 1572-896X
    Keywords: isopycnic centrifugation ; buoyant density ; drug delivery ; nanoparticles ; sucrose linear gradient
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics , Technology
    Notes: Abstract The development of polymer nanoparticles as drug carriers requires numerous steps including several in vitro evaluations in cell cultures and biocompatibility. To perform these experiments, it is crucial to express the particle concentration as the number of particles per volume unit or as the particle surface area. Calculation of these suspension characteristics can be perfomed knowing the size and the density of the nanoparticles as well as the polymer concentration. While particle size and polymer concentration are parameters being determined routinely, this study proposes to measure the density of the nanoparticle drug carriers by isopycnic centrifugation using linear sucrose gradients. The method was found to be very reproducible and it presents the advantage of being applied on a small sample of nanoparticles.
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    Journal of nanoparticle research 1 (1999), S. 115-126 
    ISSN: 1572-896X
    Keywords: nanoparticles ; aerosol charger ; unipolar charging ; Fuchs theory ; experiments
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics , Technology
    Notes: Abstract A novel aerosol charger has been developed, which has high efficiency and high throughput especially for nanometer particles in the size range of 3–50 nm. Unipolar charging with high ion concentration and long charging time is used to obtain the high charging efficiency. High throughput is achieved by reducing particle loss within the charger. This is accomplished by directing ion flow and aerosol flow in the same direction and by the use of sheath air flow. The charger configuration is of a longitudinal design – the direction of aerosol stream and ion stream are flowing parallel along the longitudinal axis of the charger. The charger consists of four sections: the inlet zone, the ion production zone, the unipolar charging zone, and the exit zone. In the inlet and ion production zones, unipolar ions are generated using Po210 radioactive sources with an electric field designed to separate the positive and negative ions, and to focus the selected unipolar ions into the core region of the charger. The ions with the selected polarity is then attracted to the charging zone by an uniform electric field created by a series of ring electrodes applied with a linear ramped voltage. Aerosol entering the charger is sheathed with clean gas flow in order to keep the aerosol in the core region. A novel exit design with a reversed electric field is incorporated in order to minimize the charged particles loss. The performance of the charger is first evaluated using computer simulation and then constructed for experimental validation. Experiment data have demonstrated that the charger achieves 90% and 95% charged-particles penetration efficiency and with 22% and 48% extrinsic charging efficiency at 3 and 5 nm particle sizes, respectively. These performance data represent significant improvement, over a factor of 10, compared with the existing chargers.
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  • 22
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    Journal of nanoparticle research 1 (1999), S. 317-317 
    ISSN: 1572-896X
    Keywords: nanomaterials ; nanotechnology ; nanoparticles ; World Wide Web
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics , Technology
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  • 23
    ISSN: 1572-896X
    Keywords: coflow diffusion flame ; light scattering ; thermophoretic sampling ; flame hydrolysis deposition (FHD) ; fractal aggregate ; nanoparticles
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics , Technology
    Notes: Abstract The evolution of silica aggregate particles in a coflow diffusion flame has been studied experimentally using light scattering and thermophoretic sampling techniques. An attempt has been made to calculate the aggregate number density and volume fraction using the measurements of scattering cross section from 90° light scattering with combination of measuring the particle size and morphology from the localized sampling and a TEM image analysis. Aggregate or particle number densities and volume fractions were calculated using Rayleigh–Debye–Gans and Mie theory for fractal aggregates and spherical particles, respectively. Using this technique, the effects of H2 flow rates on the evolution of silica aggregate particles have been studied in a coflow diffusion flame burner. As the flow rate of H2 increases, the primary particle diameters of silica aggregates have been first decreased, but, further increase of H2 flow rate causes the diameter of primary particles to increase and for sufficiently larger flow rates, the fractal aggregates finally become spherical particles. For the cases of high flame temperatures, the particle sizes become larger and the number densities decrease by coagulation as the particles move up within the flame. For cases of low flame temperatures, the primary particle diameters of aggregates vary a little following the centerline of burner and for the case of the lowest flame temperature in the present experiments, the sizes of primary particles even decrease as particles move upward.
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    Journal of nanoparticle research 1 (1999), S. 163-167 
    ISSN: 1572-896X
    Keywords: Fe2O3 ; nanoparticles ; low-pressure flame ; Fe(CO)5 ; flame synthesis approach
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics , Technology
    Notes: Abstract A burner stabilized premixed low-pressure flame has been used to generate iron-oxide (Fe2O3) nanoparticles with sizes in the range 7–20 nm. The H2/O2/Ar flames were doped with different amounts of iron-pentacarbonyl (Fe(CO)5) with concentrations in the range 524–2096 ppm. The influence of precursor concentration on composition, structure, morphology, and size have been studied utilizing transmission electron microscopy (TEM), X-ray powder diffraction (XRD), measurements of the specific surface area (BET), and infrared spectroscopy (FT-IR). The product particles consist of both, the γ- and the α-phase of Fe2O3. Average particle sizes were measured in the range 7.4–16 nm depending on precursor concentration and flame conditions.
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    Journal of nanoparticle research 1 (1999), S. 215-221 
    ISSN: 1572-896X
    Keywords: nanoparticles ; magnetic materials ; microemulsions ; barium ferrite
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics , Technology
    Notes: Abstract Magnetic nanoparticles of barium ferrite (BaFe12O19) have been synthesized using a microemulsion mediated process. The aqueous cores of water-in-oil microemulsions were used as constrained microreactors for the precipitation of precursor carbonate and hydroxide particles. These precursors were then calcined at 925°C for 12 h, during which time they were transformed to the hexagonal ferrite. The pH of reaction was varied between 5 and 12, and it was found that the fraction of non-magnetic hematite (α-Fe2O3) in the particles varied with the pH of reaction, thus affecting the magnetic properties of the particles. The same precursor particles were also prepared by bulk co-precipitation reaction for comparison. It was found that the microemulsion derived nanoparticles of barium ferrite had both higher intrinsic coercivity (Hc) and saturation magnetization (σs) than the particles derived from bulk co-precipitation. Particles were analyzed by electron microscopy, X-ray diffraction, differential thermal analysis (DTA), thermogravimetric analysis (TGA) and vibrating sample magnetometry (VSM). The best barium ferrite particles produced by the microemulsion synthesis method yielded an intrinsic coercivity of 4310 Oe and a saturation magnetization of 60.48 emu/g.
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    Journal of nanoparticle research 1 (1999), S. 253-265 
    ISSN: 1572-896X
    Keywords: nanoparticles ; surface state ; reactivity ; aerosol catalysis
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    Notes: Abstract Nickel nanoparticles produced by spark discharges were used as aerosol catalyst for the formation of methane. The available surface area of the particles was determined using different methods. It was found that the surface area available for nitrogen adsorption and, therefore, for the methanation reaction remained virtually constant during restructuring of the agglomerates while the surface area based on the mobility was significantly reduced. In general, the reaction parameters such as activation energy and reaction rates agree well with the values for single nickel crystals and foils. At temperatures above 350°C the activation energy and the photoelectric activity of the particles decrease indicating the formation of graphite on the particle surface. Also the change of the work function points to the build up of multiple layers of graphite on the particle surface. The surprisingly low temperature for the surface deactivation may indicate an enhanced formation of carbon atoms at the surface.
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    Journal of nanoparticle research 1 (1999), S. 353-368 
    ISSN: 1572-896X
    Keywords: dendrimers ; nanoparticles ; polymer-inorganic nanocomposites ; templates
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    Topics: Physics , Technology
    Notes: Abstract Structural types of dendrimer nanocomposites have been studied and the respective formation mechanisms have been described, with illustration of nanocomposites formed from poly(amidoamine) PAMAM dendrimers and zerovalent metals, such as gold and silver. Structure of {(Au(0))n−PAMAM} and {(Ag(0))n−PAMAM} gold and silver dendrimer nanocomposites was found to be the function of the dendrimer structure and surface groups as well as the formation mechanism and the chemistry involved. Three different types of single nanocomposite architectures have been identified, such as internal (‘I’), external (‘E’) and mixed (‘M’) type nanocomposites. Both the organic and inorganic phase could form nanosized pseudo-continuous phases while the other components are dispersed at the molecular or atomic level either in the interior or on the surface of the template/container. Single units of these nanocomposites may be used as building blocks in the synthesis of nanostructured materials.
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    Journal of nanoparticle research 1 (1999), S. 329-347 
    ISSN: 1572-896X
    Keywords: nanoparticles ; self assembly ; nanotechnology ; precipitation ; elastic properties
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    Topics: Physics , Technology
    Notes: Abstract The use of strain to direct the assembly of nanoparticle arrays in a semiconductor is investigated experimentally and theoretically. The process uses crystal strain produced by a surface structure and variations in layer composition to guide the formation of arsenic precipitates in a GaAs-based structure grown at low temperature by molecular beam epitaxy. Remarkable patterning effects, including the formation of single and double one-dimensional arrays with completely clear fields are achieved for particles in the 10-nm size regime at a depth of about 50-nm from the semiconductor surface. Experimental results on the time dependence of the strain patterning indicates that strain controls the late stage of the coarsening process, rather than the precipitate nucleation. Comparison of the observed particle distributions with theoretical calculations of the stress and strain distributions reveals that the precipitates form in regions of maximum strain energy, rather than near extremum points of hydrostatic stress or dilatation strain. It is therefore concluded that the patterning results from modulus differences between the particle and matrix materials rather than from other strain related effects. The results presented here should be useful for extending strain directed assembly to other materials systems and to other configurations of particles.
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    ISSN: 1572-896X
    Keywords: STM ; nanoparticles ; colloids ; Met-Cars ; photon emission ; spectroscopy
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    Notes: Abstract Scanning tunneling microscopy can be used to isolate single particles on surfaces for further study. Local optical and electronic properties coupled with topographic information collected by the scanning tunneling microscope (STM) give insight into the intrinsic properties of the species under study. Since each spectroscopic measurement is done on a single particle, each sample is ‘monodisperse’, regardless of the degree of heterogeneity of the original preparation. We illustrate this with three example systems – a metal cluster of known atomic structure, metal nanoparticles dispersed from colloid suspensions, and metallocarbohedrenes (Met-Cars) deposited with other reaction products. Au and Ag nanoparticles were imaged using a photon emission STM. The threshold voltage, the lowest bias voltage at which photons are produced, was determined for Au nanoparticles. Electronic spectra of small clusters of Ni atoms on MoS2 were recorded. Preliminary images of Zr-based Met-Car-containing soot were obtained on Au and MoS2 substrates and partial electronic spectra were recorded of these possible Met-Car particles.
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    Journal of nanoparticle research 1 (1999), S. 495-499 
    ISSN: 1572-896X
    Keywords: optical tweezers ; nanoparticles ; particle-medium interaction ; dynamic mechanical testing ; dynamic moduli ; viscoelasticity
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    Topics: Physics , Technology
    Notes: Abstract We report a new application of the optical tweezers, where a harmonically driven oscillating tweezer is combined with the forward light scattering and lock-in amplification techniques, for probing the mechanics of nanostructures in soft materials in a broad frequency range. Model independent dynamic moduli G′ and G″ of the material at a localized, sub-micron area can be measured directly from the displacement and the phase shift of the particle in the oscillating trap. The probe particles can be as small as 200 nm and the displacement of the particle was in the range of a few nanometers. To illustrate the new methodology, we show the microscopic viscoelastic properties of a transient polymer network in the vicinity of a silica bead.
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    Journal of nanoparticle research 1 (1999), S. 9-15 
    ISSN: 1572-896X
    Keywords: chain aggregates ; aerosol aggregates ; nanoparticles ; titania nanoparticles
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    Topics: Physics , Technology
    Notes: Abstract Studies of the behavior of nanoparticle chain aggregates (NCA) have shown properties similar to those of molecular polymers. Like polymer chains, NCA tend to gather up and become more compact when heated. Under tensile stress, folded chain segments pull out and the NCA elongates. When the tension is relaxed, the chains contract. The stretching of NCA may contribute to the ductility of compacts made from nanoparticles, a subject of current research interest. In a well established technological application, carbon black and pyrogenic silica NCA produce remarkable increases in elastic modulus and tensile strength when added to commercial rubber. This may be due to the mechanical interaction between the polymer chains and NCA. However, basic mechanisms of NCA elasticity differ from those of molecular polymers. The alignment of chain segments when the NCA are subjected to tension probably results from rotation and translation at grain boundaries between neighboring nanocrystals. The elastic properties depend on the van der Waals forces between segments of the chain that fold to minimize surface free energy. Under tension, these segments pull out, but tend to reform when the tension is relaxed. The processes that lead to NCA formation and control the strength of interparticle bonds are briefly reviewed.
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    Journal of nanoparticle research 1 (1999), S. 137-139 
    ISSN: 1572-896X
    Keywords: molecular self-assembly ; nanoelectronics ; nanoparticles ; biostructures
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    Journal of nanoparticle research 1 (1999), S. 185-195 
    ISSN: 1572-896X
    Keywords: charged aerosols ; coagulation ; charge distribution ; population balance ; nanoparticles
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    Topics: Physics , Technology
    Notes: Abstract We consider the coagulation of an aerosol embedded in a stationary atmosphere of bipolar ions. Particles respond to the ionic environment by developing an instantaneous charge the fluctuations of which may produce attraction or repulsion between the particles. The governing parameter is the charge asymmetry factor which quantifies the relative charging efficiency of positive and negative ions. We use a Monte Carlo method to solve the coagulation equation in the free-molecule regime. We perform simulations for conditions ranging from symmetric and nearly symmetric environments (e.g. flames, ionizers), which result in particles that are on the average neutral to highly asymmetric conditions (low-pressure plasmas), which produce a substantial non-zero net charge. In symmetric ionic atmospheres we find that electrostatic interactions are unimportant and particles grow as if in the absence of charging ions. In asymmetric bipolar atmospheres, electrostatic interactions between particles are repulsive, the mean particle size grows logarithmically in time and the resulting size distributions are significantly narrower than the classical self preserving distributions.
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    Journal of nanoparticle research 1 (1999), S. 243-251 
    ISSN: 1572-896X
    Keywords: gold ; nanoparticles ; size selection ; thermal charging ; particle synthesis
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    Notes: Abstract Gold nanoparticles are of great interest for various nanoelectronic applications, e.g., for making single electron transistors or very fine leads to molecular size entities. For this and other applications, it is important that all particles have controllable size and shape. In this paper, we describe the production of size-selected gold aerosol particles in the 20 nm range made by evaporation in a high-temperature tube furnace and subsequent size selection. To obtain spherical particles, it was necessary to reshape the particles at high temperature, which was investigated for temperatures between 25°C and 1200°C. High-resolution transmission electron microscopy showed that the degree of crystallinity became higher for higher reshaping temperature. During reshaping at high temperature, an anomalous charging behavior was discovered, whereby negatively as well as positively charged particles became multiply negatively charged. Possible mechanisms for explaining this thermally activated phenomenon are discussed.
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    Journal of nanoparticle research 1 (1999), S. 277-291 
    ISSN: 1572-896X
    Keywords: nanoparticles ; specific surface area ; surface melting ; coalescence ; surface diffusion ; flame particle synthesis
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    Notes: Abstract Surprisingly, there is still no rational yet practical method to reliably predict absolute ‘primary’ nanospherule sizes and, hence, specific surface areas, in gas phase flame nanoparticle synthesis. The present paper summarizes our approach to this important problem, using a plausible and tractable coagulation–coalescence (two-rate process) model, but with an important modification to the rate of nanoparticle coalescence. The Smoluchowski equation is used to describe the particle Brownian coagulation rate process (free-molecule regime), together with the assumption that the particle population follows a self-preserving size distribution. The decisive coalescence process, driven by the minimization of surface energy of the coalescing nanoparticles, is presumed to occur via the mechanism of surface diffusion. However, a curvature-dependent energy barrier for surface-diffusion is proposed, taking into account the extended ‘surface-melting’ behavior of nanoparticles. This is shown here to have the effect of accelerating the coalescence rate of touching nanoparticles, leading to absolute sizes (at the predicted onset of aggregate formation) in encouraging agreement with available experiments. It was found that the coalescence rate, especially with a curvature-augmented surface diffusivity, is far more sensitive to particle size than is the Brownian coagulation rate. As a result, when cast in terms of characteristic process times, a distinct crossover generally exists, allowing the determination of observed ‘primary’ spherule sizes within larger aggregates. This approach is successfully applied here to several published synthesis examples of vapor-derived nanosized alumina and titania. Its broader implications for nanoparticle synthesis in non-isothermal reactors, including our own counterflow diffusion flame reactor, are also briefly summarized.
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    Journal of nanoparticle research 1 (1999), S. 393-396 
    ISSN: 1572-896X
    Keywords: magnetite ; nanoparticles ; forced mixing ; wet synthesis approach ; superparamagnetism
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    Topics: Physics , Technology
    Notes: Abstract Synthesis of magnetite nanoparticles by precipitation with forced mixing is presented. Using this method it is easy to obtain a high product saturation degree and the constant pH value of the reaction system. The TEM and XRD measurments show that the average size of the product magnetite particles is less than 6.0-nm in the condition of [Fe2+]/[Fe3+]=0.5. The magnetic properties of the samples are discussed.
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    Journal of nanoparticle research 1 (1999), S. 379-392 
    ISSN: 1572-896X
    Keywords: nanoparticles ; aero-sol-gel ; aerosol ; sol-gel ; hydrolysis/condensation ; silica
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    Topics: Physics , Technology
    Notes: Abstract This paper discusses a new approach to the synthesis of nano-structured oxides where sol-gel reactions are carried out in aerosol droplets. This aero-sol-gel (ASG) reactor allows for manipulation of the structure, chemical composition and surface area of silica powders through variation of process parameters. ASG powders differ in nanostructure from other continuous process powders such as pyrolytic and solution-route powders. ASG powders contain mesopores (〉2-nm) and micropores (〈2-nm), the mesopores being responsible for high surface areas measured by nitrogen adsorption using BET theory. Primary particles of close to molecular scale are believed to lead to exceedingly large specific surface areas on the order of 600-m2/g. These primary particles aggregate into nanometer scale mass-fractal aggregates that cluster in micron scale agglomerates. Under controlled reaction conditions the powder structure is reproducible as measured by small-angle X-ray scattering, SAXS, analysis. The ASG reactor displays transport effects similar to those previously seen in laminar flame reactors as evidenced by the effect of reactor geometry and reactant concentration on product structure.
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    Journal of nanoparticle research 1 (1999), S. 439-458 
    ISSN: 1572-896X
    Keywords: nanoparticles ; quantum size ; photocatalysis ; dopants ; sensitization ; nanocrystalline films
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    Topics: Physics , Technology
    Notes: Abstract The aim of this review paper is to give an overview of the development and implications of nanotechnology in photocatalysis. The topics covered include a detailed look at the unique properties of nanoparticles and their relation to photocatalytic properties. Current applications of and research into the use of nanoparticles as photocatalysts has also been reviewed. Also covered is the utilization of nanoparticles in doped, coupled, capped, sensitized and organic–inorganic nanocomposite semiconductor systems, with an effort to enhance photocatalytic and/or optical properties of commonly used semiconductor materials. The use of nanocrystalline thin films in electrochemically assisted photocatalytic processes has been included. Finally, the use of nanoparticles has made a significant contribution in providing definitive mechanistic information regarding the photocatalytic process.
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    Plasma chemistry and plasma processing 19 (1999), S. 487-504 
    ISSN: 1572-8986
    Keywords: Hydrogen plasma ; arcjets ; simulation ; LBI method
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    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract The governing equations describing a flowing stream of a hydrogen plasma encountered in applications, such as diamond deposition, and in devices, such as arcjet thrusters, are solved numerically using the linearized implicit (LBI) Method of Briley and McDonald. The results of simulations under the assumption that the plasma can be described by a single temperature are compared with detailed experimental measurements of flow characteristics and species concentrations in a 1 kW arcjet. These comparisons show that by formulating the problem in terms of known experimental operating conditions, such as mass flow rate, power, and current levels, it is possible to predict many of the characteristics of the flowing plasma. As expected, predictions from this one-temperature model show that some deviations from the experimental results occur near the exit plane of the channel, where unequal electron and heavy particle temperatures are encountered because of lower pressures.
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    Journal of nondestructive evaluation 18 (1999), S. 117-126 
    ISSN: 1573-4862
    Keywords: Nondestructive evaluation ; layered cylindrical structures ; cylindrical waves ; simulation ; inverse problem
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Mathematics
    Notes: Abstract For the characterization of the unknown material properties of a layered cylindrical structure, axially symmetric wave signals transmitted and reflected by the structure have been used. Since only a single wave mode propagates in the structure, the measurement and analysis of the transmitted and reflected signals can be simplified significantly. The evaluation of the material properties of the layers can be achieved with great accuracy. In this paper, we first derive the transmission and reflection coefficients for the layered cylindrical structure sonified axisymmetrically by an incident cylindrical wave. We then relate the spectra of the transmitted and reflected wave signals to the transmission and reflection coefficients as ratio functions. The time-domain signals transmitted and reflected by the structure can then be reconstructed from a routine application of the Fourier integrals. A three-layered aluminum/epoxy/aluminum tube is used to illustrate the application of the expressions for both the forward and inverse problems. The results show that the technique developed in this study can be used very effectively for the characterization of layered cylindrical structures.
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    Oxidation of metals 51 (1999), S. 317-331 
    ISSN: 1573-4889
    Keywords: OXIDATION ; γ-TiAl INTERMETALLIC ; ELECTRODEPOSITEDNi-La2O3 ; COMPOSITE FILM
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A coating of nickel withLa2O3 particles waselectrodeposited on the surface of γ-TiAl toimprove its high-temperature oxidation resistance. Theexperimental results showed that contrary to theoxidation of bare specimens, the electrodepositedNi-La2O3 composite-coated onesexhibited much better resistance to both isothermal andcyclic oxidation in air at 1000 and 900°C. For theoxidation of the Ni-La2O3 composite-coated γ-TiAl EPMA/EDX microanalyses revealed that after the composite film had beenthoroughly oxidized, a La2O3-richNiO layer close to the gas-scale interface and twoalumina-rich layers, with one beneath the NiO layer and the otheradjacent to the γ-TiAl matrix, were produced inthe scale. The results indicated that the preferentiallyformed La2O3-doped NiO layerretarded the growth of rutile and favored the formation of twoalumina-rich layers. The mechanism of the effect of theelectrodeposited Ni-La2O3composite on the oxidation behavior of γ-TiAl isdiscussed in detail.
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    Oxidation of metals 51 (1999), S. 333-351 
    ISSN: 1573-4889
    Keywords: OXIDATION ; Al2O3 SCALE ; GROWTH STRESS ; Fe-Cr-Al ALLOY ; SPECIMEN DEFLECTION
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A new technique has been developed to monitorthe growth stresses in oxide scales by measuringspecimen deflection. Compared to the conventionaldeflection method, the new technique does not require acoating for protecting one side of the specimen fromoxidation. This new method does not have temperaturelimits and has improved precision for stress measurementin alumina scales. Two alumina-forming alloys, Fe-22Cr-5Al-0.3Y and Fe-22.6Cr4.42Al-0.21Ti,were studied with this method. During oxidation at1000°C in air, the average compressive stresses inthe alumina scales were found to decrease from ~1000 to ~100 MPa with increasing scale thickness on thetwo alloys. The growth stress in alumina scales wasdirectly proportional to the oxide growth rates. Thestresses in the substrate alloys were much lower, on the order of 1 MPa. Creep occurred in thesubstrate alloys and was taken into consideration in thestress analysis. It is believed that creep in the alloysubstrates allowed stresses in the oxide scales to relax. Annealing tests showed that thestresses relaxed much easier in thin than in thickscales.
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    Oxidation of metals 51 (1999), S. 291-315 
    ISSN: 1573-4889
    Keywords: OXIDATION ; ELECTRODEPOSITED COMPOSITE FILM ; La2O3 ; NiO ; REACTIVE-ELEMENT EFFECT
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Electrodeposited Ni-La2O3composite films with nanometer-sizeLa2O3 oxide inclusions werefabricated by the codeposition of nickel withLa2O3 particles. The comparativeoxidation behavior in air at 900 and 1000°C of nickel coated with theNi-La2O3 composite and films withand without nickel-plating was studied by TGA, AE,SEM/EDX, EPMA, and TEM/EDX. In general, theNi-La2O3 composite-coated nickelhad the slowest rate and the best resistance tothermal cycling. AE tests revealed that cracking eventsin NiO scales on Ni-La2O3composite-coated nickel was significantly reduced incomparison to that of the scale on nickel-coated nickel during thermalcycling at 900°C. SEM investigation showed that theLa2O3-free NiO scale was composedof outer coarse columnar grains and inner equiaxed ones.By contrast, the scale on the Ni-La2O3composite-coated nickel consisted of only fine equiaxedNiO grains. The scale on theLa2O3-free samples wascharacterized by cracks that originated at thescale-substrate interface and spanned the scale thickness. By contrast,no scale cracks formed at theLa2O3-doped NiO scale-substrateinterface, but small voids were created at the triplepoints of the grain boundaries of NiO. In the La2O3-doped NiOscale, segregation of La ions to the NiO grainboundaries near the scale-surface was observed by EDXmicroanalyses in the TEM. It is believed that the Laions segregated at the grain boundaries of NiO led to an increase in thecohesion between nickel oxides and in a reduction of thescaling rate and the formation of scale with fineequiaxed crystal structure by blocking the outward and lateral growth of scale. The latter was dueto the predominant outward diffusion of nickel along NiOgrain boundaries being inhibited effectively by thesegregated La ions. The mechanism of the effect of the added La2O3particles on the nickel electrodeposits is discussed indetail.
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    Oxidation of metals 51 (1999), S. 421-447 
    ISSN: 1573-4889
    Keywords: COBALT ; YTTRIUM ; TWO-PHASE ALLOYS ; SULFIDATION ; OXIDATION
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The corrosion of Co-15 wt.% Y has been studiedat 600-800°C inH2-H2S-CO2 mixturesproviding a sulfur pressure of 10-8 atm at600-800°C and of 10-7 atm at 800°Cand an oxygen pressure of 10-24 atm at 600°C and of10-20 atm at 700-800°C. The corrosionrates in such sulfidizing-oxidizing atmospheres werecompared with those of pure cobalt and yttrium. Theaddition of yttrium to cobalt is only slightly beneficial, sincefor a yttrium content of 15 wt.% the corrosion rate isreduced quite significantly with respect to pure cobaltat 800°C under 10-7 atm S2,only to a limited extent at 600°C, and even slightlyincreased at 700°C. Moreover, the alloy corrodesconsiderably more rapidly than pure yttrium at800°C, when the latter behaves protectively. At 600 and 700°C, yttrium exhibitedbreakaway behavior, while the alloy corroded morerapidly than yttrium at short times, but more slowly atlong times. Under all conditions, except at 800°Cunder 10-8 atm S2, the alloy formsan external layer of cobalt sulfide overlying anintermediate region of very complex compositioncontaining a mixture of the compounds of the two metalsand an innermost region of internal attack containing compoundsof yttrium with both oxygen and sulfur. Thus, cobalt canstill diffuse through the intermediate region to formthe outer cobalt-sulfide layer at nonnegligible rates. The scaling behavior of the Co-15% Yalloy is discussed by taking into account the limitedsolubility of yttrium in cobalt as well as the presenceof an intermetallic Co-Y compound in thealloy.
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    Oxidation of metals 51 (1999), S. 479-494 
    ISSN: 1573-4889
    Keywords: Fe-Cr-Al ALLOY ; OXIDATION ; LANTHANUM ; BREAKAWAY
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A study has been undertaken of the effects oflanthanum on the oxidation of thin foils of Fe-20Cr-5Alin air at 1150°C. The addition of lanthanum causesthe time to breakaway to increase from about 24 hr for Fe-20Cr-5Al to over 400 hr. Oxidationof the lanthanum-containing alloy occurs in threestages. During the first stage, anα-Al2O3 layer is establishedand thickens with time until the aluminum in the foil is depleted sufficiently for alayer of Cr2O3 to become stableand develop at the scale-alloy interface. This continuesto thicken at a relatively slow rate until breakawayoccurs. The main emphasis in the present paper has been anexamination and analysis of the scale established on thelanthanum-containing alloy in cross section in theanalytical transmission electron microscope (TEM), after an exposure period that coincides with thesecond stage of oxidation, prior to breakaway. The scaleat that time consists of three layers. The outer layeris composed of equiaxed Al2O3grains. The intermediate and inner layers consist of columnarAl2O3 grains and equiaxedCr2O3 grains, respectively.Numerous voids are observed in the oxide grainboundaries and at the intermediate-inner layerinterface. Lanthanum segregates in the oxide grain boundaries andits concentration increases toward the outermost surfaceof the scales. These results are consistent with the“dynamic segregation model” to account for the effects of reactive elements on thegrowth of Al2O3 scales.
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    Oxidation of metals 51 (1999), S. 495-506 
    ISSN: 1573-4889
    Keywords: PURE FE ; Fe-Y ALLOYS ; OXIDATION
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The oxidation of Fe-Y alloys containing 2 and 5at.% Y and pure iron has been studied at 600-800°Cin air. The oxidation of pure iron follows the parabolicrate law at all temperatures. The oxidation of Fe-Y alloys at 600°C approximatelyfollows the parabolic rate law, but not at 700 and800°C, where the oxidation goes through severalstages with quite different rates. The oxide scales on Fe-2Y and Fe-5Y at 700 and 800°C arecomposed of external pure Fe oxides containingFe2O3,Fe3O4, and FeO, with FeO being themain oxide and an inner mixture of FeO andYFeO3. The scales on Fe-2Y and Fe-5Y at 600°C consist ofFe2O3,Fe3O4, andY2O3, with a minor amount of FeO.Significant internal oxidation in both Fe-Y alloysoccurred at all temperatures. The Y-containing oxidesfollow the distribution of the original intermetalliccompound phase in the alloys. The effects of Y on theoxidation of pure Fe are discussed.
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    ISSN: 1573-4889
    Keywords: OXIDATION ; LOW-CARBON STEEL ; INTERFACE ANALYSIS ; AES AUGER ELECTRON SPECTROSCOPY ; CHEMICAL DIFFUSION
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract In order to study the physicochemical evolutionduring oxidation of Fe-C-ΣXi alloyssurfaces (Xi = Cu, Ni, Al, Si, S, withXi% 〈 0.5 wt.%, C% 〈 0.1 wt.%), anoriginal analysis method has been used. After separating the oxide from the metalsubstrate, the first atomic layers of both innersurfaces have been observed by Auger ElectronSpectroscopy (AES). The depth profiles obtained, around0.4 μm thick on both sides of the oxide-metal interface,have been compared for four steels of differentcomposition. Significant differences have been observedand described in this paper. A qualitativeinterpretation of diffusion processes has been proposed. Ametallographic study illustrates some physicalconsequences of alloying elements, especially on thescale thickness.
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    Oxidation of metals 52 (1999), S. 1-29 
    ISSN: 1573-4889
    Keywords: ALUMINA SCALE ; SEGREGATION ; OXIDATION ; SULFUR ; OXIDE-METAL INTERFACE
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Impurity segregation at theAl2O3-metal interface of Fe-Cr-Aland Fe-Cr-Al-Y alloys oxidized at 1100°C was studiedusing Auger electron spectroscopy (AES). A strong sulfursegregation of the order of a monolayer was found at the contactoxide-metal interface on the yttrium-free alloy, whilealmost no sulfur was detected at the interface on theyttrium-containing alloy. These results are in agreement with the AES studies of surface segregation onthe same alloys during heating at 900°C inultra-high vacuum. It is suggested that stresses in thealumina scale and underlying metal during oxidation may provide the driving force for impuritysegregation at the contact oxide-metalinterface.
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    Oxidation of metals 52 (1999), S. 77-94 
    ISSN: 1573-4889
    Keywords: OXIDATION ; HIGH TEMPERATURE ; SODIUM CHLORIDE
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The effect of trace amounts of NaCl vapor on thehigh-temperature oxidation of TiAl was examined bythermogravimetry and analysis of the scale formed onTiAl. The mass gain due to oxidation at 1273 K in O2 with trace amounts of NaCl vaporwas far lower than that in pure O2 withoutNaCl vapor. This low mass gain in the atmosphere withtrace amounts of NaCl vapor resulted from the saturationbehavior of mass gain during the initial period ofoxidation. It was found from X-ray photoemissionspectroscopy (XPS) analyses of the specimen surface thatthe oxide film formed during the initial period in theatmosphere with trace amounts of NaCl vapor consisted ofdense Al2O3, thus, the lowoxidation rate of TiAl was attributed to a protectiveoxide film of denseAl2O3.
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  • 50
    ISSN: 1573-4889
    Keywords: OXIDATION ; WATER VAPOR ; CrO2OH2 ; VOLATILIZATION
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The oxidation of type 304L stainless steel wasinvestigated at 873 K in the presence of O2and O2 + 10% H2O. Oxidation timevaried between 1 and 672 hr. The oxidized samples wereinvestigated by a number of surface-analytical techniques includinggrazing-angle XRD, SEM/EDX, auger spectroscopy, SIMS andXPS. Oxidation in dry oxygen results in the formation acorundum-type oxide (Me2O3) withadditional formation of spinel oxides after prolonged exposure. Theoxide layer contained mainly chromium, with smalleramounts of Fe and Mn. Oxidation in the presence of watervapor results in an oxide that contains more Fe and less Cr, the outer part of the oxide beingdepleted in Cr. In the presence of water vapor, a massloss is detected after prolonged exposure. We show thatthe mass loss is caused by chromium evaporation. The volatile species is suggested to beCrO2(OH)2.
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    Oxidation of metals 52 (1999), S. 113-138 
    ISSN: 1573-4889
    Keywords: CHROMIA ; OXIDATION ; TRANSIENT SCALES
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract High-spatial scanning transmission electronmicroscopy (STEM) has been used to study the developmentof transient scales on a commercially available Ni-20Cralloy. The samples were examined usingelectron-transparent cross sections of the metal and oxide foroxidation times between 0 and 30 min in a furnace at950°C in laboratory air. The samples were polishedto 1 μm diamond before oxidation, producing a recrystallized grain structure within 100 nm ofthe surface. Upon oxidation, the initial scale consistedalmost exclusively of chromia. However, at themetal-oxide interface, thin layers of silica and alumina were detected. At longer oxidation times,(〉5 min), localized thickening of the silica layerwas observed. With increased oxidation time, (〉25min), these regions spread along the metal-oxideinterface until an almost continuous silica layer hadformed. The silica layer was present at much shorteroxidation times than reported by other workers, however,this may be because of the thin layer being undetectable using microprobe techniques. The scale formedwas found to be adherent, although the alloy containedsulfur and did not contain reactive elements. However,sulfur was not found to segregate to the metal-oxide interface possibly because of the presence ofthe amorphous silica layer.
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    Oxidation of metals 52 (1999), S. 139-153 
    ISSN: 1573-4889
    Keywords: SULFUR ; ALUMINUM ; OXIDATION ; INTERFACE
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The deposition of aluminum on S/Fe(111)(1× 1) at 300 K in UHV results in the formation ofa disordered S-modified Al adlayer. Insertion of Albetween the sulfur atoms and the Fe substrate isindicated by an increase of the S Auger signal withincreasing Al deposition. Room-temperature oxidation ofAl/S/Fe(111) in UHV is inhibited compared to theoxidation of aluminum deposited on the sulfur-freeFe(111). The oxygen-uptake curves and variations in theS(LVV), Fe(MVV) intensities with oxygen exposure arealso consistent with the insertion of the aluminum atomsbetween the S overlayer and the Fe substrate.
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  • 53
    ISSN: 1573-4889
    Keywords: PURE IRON ; YTTRIUM ; ION IMPLANTATION ; SOL-GEL COATING ; OXIDATION
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The influence of yttrium introduced by ionimplantation or by sol-gel coatings on the oxidation ofpure iron has been studied at 973 K underp(O2) = 0.04 Pa. The oxide scales wereexamined using a wide range of analytical techniques. The addition ofyttrium by ion implantation or by sol-gel coatingssignificantly improved the oxidation resistance of pureiron. This effect depends upon the introduction mode of yttrium on the surface.
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    Oxidation of metals 9 (1975), S. 473-496 
    ISSN: 1573-4889
    Keywords: nickel ; sulfidation ; multilayer scale ; diffusion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The reaction between pure nickel and sulfur vapor has been studied over the temperature range 380–475° C. A scale consisting of four separate layers is formed and the growth of the three outer layers obeys parabolic kinetics. The innermost layer grows only in the very early stages, after which the thickness remains approximately constant. The layers have been identified as three different sulfides-Ni3S2, which forms the two inner layers, Ni7S6, and NiS. The three outer layers grow with preferred orientations; growth of the Ni3S2 and NiS layers is with the basal planes of their hexagonal structures parallel to the nickel substrate. The formation of the scale can be described in terms of a diffusion-controlled process and the same basic process continues after scale-metal separation occurs. The description of scale growth is combined with experimental data to calculate the diffusion coefficient of nickel ions in each phase.
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    Oxidation of metals 9 (1975), S. 367-378 
    ISSN: 1573-4889
    Keywords: calcia-stabilized zirconia ; oxygen activity ; diffusion ; oxygen pumping
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The oxygen activity of liquid lead was measured using a calcia-stabilized zirconia electrolyte cell inserted into the melt. The oxygen activity was monitored as small additions of Ca or Ba were made to the melt. The oxygen activity dropped rapidly after the addition, and the melt became oxidation-resistant as the oxygen activity increased back to the pre-addition level. The oxidation resistance was attributed to a thin PbO layer, containing a high density of imperfections, on the melt surface.
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    Applied mathematics and mechanics 20 (1999), S. 457-464 
    ISSN: 1573-2754
    Keywords: nonlinear ; competitive system ; diffusion ; equilibrium ; persistence
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Mathematics , Physics
    Notes: Abstract In this paper, the stabilities of boundary equilibrium and positive equilibrium of two-species Ayala competitive systems with two different diffusions are discussed, and dynamic behaviors of species are obtained. At the same time, the dynamic behaviors between systems with diffusion and those without diffusion are compared. This shows the influence of diffusions on the persistence of species.
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    Discrete event dynamic systems 9 (1999), S. 261-284 
    ISSN: 1573-7594
    Keywords: discrete event dynamic systems ; simulation ; communications ; performance analysis ; alignment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract In the design and optimization of discrete event dynamic systems, it is often necessary to order alternative designs based on their relative performance, i.e., to rank them from best to worst. In this paper, alignment of observed performance orders with true orders is considered and properties of the alignment are investigated. Spearman's rank correlation coefficient is a measure of agreement between the observed performance orders and the true ones. It is shown that Spearman's coefficient converges exponentially in the simulation time or observation time, which gives a strong evidence of the efficiency of order comparison for discrete event dynamic systems. In the context of simulation, the effect of simulation dependence on the alignment is also discussed. It is found that neither independent simulation nor the scheme of common random numbers (CRN), a popular scheme for variance reduction, can yield dominant performance. Finally, numerical examples based on a networking optimization problem are provided to illustrate the convergence of Spearman's coefficient. In these examples, the standard clock (SC) simulation technique provides much faster convergence than either independent simulations or CRN simulations. Both the SC and CRN methods use the same random number sequence to drive many events in parallel; however, under SC the events driving the parallel experiments are all identical, whereas under CRN they may be different.
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    Autonomous robots 6 (1999), S. 281-292 
    ISSN: 1573-7527
    Keywords: mobile robotics ; reinforcement learning ; artificial neural networks ; simulation ; real world
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract We present a case study of reinforcement learning on a real robot that learns how to back up a trailer and discuss the lessons learned about the importance of proper experimental procedure and design. We identify areas of particular concern to the experimental robotics community at large. In particular, we address concerns pertinent to robotics simulation research, implementing learning algorithms on real robotic hardware, and the difficulties involved with transferring research between the two.
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    Transport in porous media 37 (1999), S. 93-128 
    ISSN: 1573-1634
    Keywords: diffusion ; partitioning ; homogeneous ; nonhomogeneous ; laminate ; analytical ; algebraic ; eigenfunction ; composite.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract Studies of the transport of contaminants and nutrients in industrial and environmental systems are complicated by the heterogeneous nature of the supporting porous or permeable media, and by the numerical problems associated with high Peclet number advection and sharp interface models. In order to provide independent theoretical checks of numerical transport theories, this set of papers presents analytical solutions to diffusive transport equations in simplified (one-dimensional) laminate systems subject to partitioning interactions. Here, in Part I, a standard separation of variables technique is used to develop analytical eigenfunction expansions of the concentration solution in an N-laminate system subject to steady Cauchy (third-type) nonhomogeneous boundary conditions. Both Cartesian and radial (axisymmetric) coordinate systems are considered. The solutions are developed for two different interface partitioning formulations, allowing the partitioning processes to be described by instantaneous equilibration mechanisms, or in terms of gradual equilibration mediated by mass transfer coefficients. Worked examples are presented and limitations of the approach discussed.
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    Journal of science education and technology 8 (1999), S. 3-19 
    ISSN: 1573-1839
    Keywords: levels ; complexity ; simulation ; modeling ; science education ; mathematics education ; dynamic systems ; systems thinking
    Source: Springer Online Journal Archives 1860-2000
    Topics: Natural Sciences in General , Technology
    Notes: Abstract The concept of emergent "levels" (i.e., levels that arise from interactions of objects at lower levels) is fundamental to scientific theory. In this paper, we argue for an expanded role for this concept of levels in science education. We show confusion of levels (and "slippage" between levels) as the source of many of people's deep misunderstandings about patterns and phenomena in the world. These misunderstandings are evidenced not only in students' difficulties in the formal study of science but also in their misconceptions about experiences in their everyday lives. The StarLogo modeling language is designed as a medium for students to build models of multi-leveled phenomena and through these constructions explore the concept of levels. We describe several case studies of students working in StarLogo. The cases illustrate students' difficulties with the concept of levels, and how they can begin to develop richer understandings.
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    Mathematical geology 7 (1975), S. 117-128 
    ISSN: 1573-8868
    Keywords: data processing ; lognormal theory ; sampling ; simulation ; statistics ; transformations ; economic geology ; mining ; sedimentology
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Mathematics
    Notes: Abstract A logarithmic transformation may be used to improve the efficiency of estimates of the mean when observations follow the lognormal distribution. But if this transformation is applied to observations that follow another distribution, bias may be introduced. We consider some consequences of erroneously applying lognormal estimation theory and demonstrate that biased estimates may be obtained for certain classes of distributions. Illustrations of bias obtained in gold sampling are given.
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    Mathematical geology 7 (1975), S. 47-61 
    ISSN: 1573-8868
    Keywords: Markov processes ; simulation ; cyclothems ; stratigraphy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Mathematics
    Notes: Abstract The Banff Formation (Mississippian) is a sequence of limestone and shale exposed in the southern Canadian Rocky Mountains and underlying the adjacent plains. It was chosen as a vehicle to evaluate Markov-inspired techniques in sedimentary sequences where repetition of rock types is typical but a pattern of cyclicity is not obvious. Distributions of rock-unit thickness in two outcrop sections of the Banff Formation are not all exponential, therefore a one-step Markov model using an equal observational interval is not valid. Memory is indicated by the embedded-chain model. The most likely pattern of recurrence is delineated; shale is the most independent lithologic type and therefore the initial lithology in any ideal pattern. Neither factoring nor powering a probability matrix for the Banff Formation revealed geological cyclicity as defined by W. Schwarzacher. Several problems limit the application of Markov models to sedimentary sequences. Statistical validity requires a minimum number of observations, and in the attainment of a sound statistical basis, geological pertinence may be seriously reduced. Treatment of the probability matrix, by principal components analysis or by powering, yields an exacting criterion for cyclicity.
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    ISSN: 1573-8868
    Keywords: data processing ; discriminant analysis ; graphics ; mapping ; sampling ; simulation ; geochemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Mathematics
    Notes: Abstract The exploration geochemist faces a serious problem in reconciling theoretical statistics with the empirical distribution of elements in materials in the earth's crust. The results of computer-simulation experiments being conducted by the Exploration Geochemistry Group at the University of New Brunswick illustrate some of the problems of the relation between frequency distributions and spatial distributions of elements and raise some interesting questions about sampling patterns and physical size of samples. Most importantly, the simulation experiments and empirical examples support the contention that attempts to make an assumption of normality more efficient by performing log transformations on positively skewed data may defeat the purpose of statistical analysis for exploration work. New developments in computer-data presentation and interpretation, including population sorting and classification, illustrate the increasing use of the computer in exploration geochemistry.
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  • 64
    ISSN: 1573-8868
    Keywords: simulation ; conditional simulation ; fourier methods ; band-limited fractal ; variogram ; fast kriging
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    Topics: Geosciences , Mathematics
    Notes: Abstract We evaluate the performance and statistical accuracy of the fast Fourier transform method for unconditional and conditional simulation. The method is applied under difficult but realistic circumstances of a large field (1001 by 1001 points) with abundant conditioning criteria and a band limited, anisotropic, fractal-based statistical characterization (the von Kármán model). The simple Fourier unconditional simulation is conducted by Fourier transform of the amplitude spectrum model, sampled on a discrete grid, multiplied by a random phase spectrum. Although computationally efficient, this method failed to adequately match the intended statistical model at small scales because of sinc-function convolution. Attempts to alleviate this problem through the “covariance” method (computing the amplitude spectrum by taking the square root of the discrete Fourier transform of the covariance function) created artifacts and spurious high wavenumber content. A modified Fourier method, consisting of pre-aliasing the wavenumber spectrum, satisfactorily remedies sinc smoothing. Conditional simulations using Fourier-based methods require several processing stages, including a smooth interpolation of the differential between conditioning data and an unconditional simulation. Although kriging is the ideal method for this step, it can take prohibitively long where the number of conditions is large. Here we develop a fast, approximate kriging methodology, consisting of coarse kriging followed by faster methods of interpolation. Though less accurate than full kriging, this fast kriging does not produce visually evident artifacts or adversely affect the a posteriori statistics of the Fourier conditional simulation.
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    Journal of electroceramics 4 (1999), S. 41-48 
    ISSN: 1573-8663
    Keywords: diffusion ; oxygen ; zinc oxide ; grain boundary ; dopant ; SIMS ; interstitial diffusion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract 18O diffusion coefficients were measured in zinc oxide ceramics using a secondary ion mass spectrometer. The results are interpreted as indicating extrinsic behavior. The values of the lattice diffusion coefficients with higher valence dopants compared with zinc ions are greater than lower valence dopant such as lithium ions. Using the data at deeper depth, the grain boundary diffusivity of oxide ions was also evaluated. Although the lattice diffusion coefficients varied by two orders of magnitude, the products of grain boundary width and grain boundary diffusion coefficient were less sensitive to the type of dopants.
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    ISSN: 1573-8663
    Keywords: lanthanum chromite ; grain boundary ; TEM ; XPS ; SIMS ; diffusion
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    Topics: Electrical Engineering, Measurement and Control Technology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The morphological characteristics, chromium valence state, and cation transport in the vicinity of grain boundary in La1-xCaxCrO3 were investigated by using TEM/EDS, XPS and SIMS techniques. The width of grain boundary was around 1 nm where anomalous enrichment of calcium was observed. Higher valence state of chromium such as Cr6+(d0) was detected in the grain boundaries whereas Cr3+(d3) and Cr4+(d2) were dominant in the bulk. Very fast interdiffusion of alkaline earths was observed in the Sr2+-La0.75Ca0.25CrO3 system. All observed phenomena were correlated by assuming the A-site vacancy which may be induced by the formation of Cr6 + at grain boundaries.
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    Journal of electroceramics 4 (1999), S. 33-40 
    ISSN: 1573-8663
    Keywords: varistor ; Zn0 ; grain boundary ; DLTS ; diffusion ; interface states
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The operation and performance of electroceramics are commonly dependent on the characteristics of electrically active grain boundaries. To date, our understanding of the role of specified additives and heat treatments on the grain boundary properties remains underdeveloped. We describe efforts directed towards improving our understanding by (a) fabrication and analysis of individual boundaries, (b) improved control and simplification of boundary chemistry (c) systematic investigation of properties (e.g., I-V, DLTS, DO and DM) as a function of boundary structure and chemistry and (d) development of appropriate energy band, defect and diffusion models. Following this approach, preliminary results suggest that lattice defects play critical roles in controlling both the electrical and diffusive properties of the boundaries while the additives appear to act in supportive manner by activating the key lattice defects particularly with respect to the electrical activity of the boundaries.
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    Transport in porous media 37 (1999), S. 183-212 
    ISSN: 1573-1634
    Keywords: diffusion ; partitioning ; harmonic ; laminate ; interface ; lag ; attenuation ; dispersion.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Technology
    Notes: Abstract The migration of organic compounds in stratified media is of fundamental concern in environmental and chemical engineering research. The diffusive transport of volatile organic compounds through laminate systems is characterized by partitioning, i.e., the development of concentration discontinuities at the interfaces between the individual laminae. If the transport is governed by cyclic transients, the relevant equations can be written in terms of coupled systems of diffusion equations subject to sinusoidal boundary conditions. This paper solves these systems of equations to present new algebraic solutions for propagation of the sinusoidal modes through arbitrary (finite) numbers of contiguous one-dimensional laminae. Both Cartesian and radial coordinate systems are considered. Two independent formulations of the lamina interface matching conditions are considered, corresponding to (1) an instantaneous partitioning model and to (2) a mass-limited partitioning model. It is shown that sinusoidal components of the concentration solutions propagate dispersively throughout the laminates. This is manifested, for example, in changes in shape of concentration pulses as measured at different points in the laminate system. Algorithms for generating exact dispersion relations for partitioning laminates are given, and an experimental technique for studying interfacial dynamics via frequency domain measurements is proposed.
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    Journal of optimization theory and applications 17 (1975), S. 361-430 
    ISSN: 1573-2878
    Keywords: Survey papers ; gradient methods ; numerical methods ; computing methods ; calculus of variations ; optimal control ; gradient-restoration algorithms ; boundary-value problems ; bounded control problems ; bounded state problems ; nondifferential constraints
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract This paper summarizes recent advances in the area of gradient algorithms for optimal control problems, with particular emphasis on the work performed by the staff of the Aero-Astronautics Group of Rice University. The following basic problem is considered: minimize a functionalI which depends on the statex(t), the controlu(t), and the parameter π. Here,I is a scalar,x ann-vector,u anm-vector, and π ap-vector. At the initial point, the state is prescribed. At the final point, the statex and the parameter π are required to satisfyq scalar relations. Along the interval of integration, the state, the control, and the parameter are required to satisfyn scalar differential equations. First, the sequential gradient-restoration algorithm and the combined gradient-restoration algorithm are presented. The descent properties of these algorithms are studied, and schemes to determine the optimum stepsize are discussed. Both of the above algorithms require the solution of a linear, two-point boundary-value problem at each iteration. Hence, a discussion of integration techniques is given. Next, a family of gradient-restoration algorithms is introduced. Not only does this family include the previous two algorithms as particular cases, but it allows one to generate several additional algorithms, namely, those with alternate restoration and optional restoration. Then, two modifications of the sequential gradient-restoration algorithm are presented in an effort to accelerate terminal convergence. In the first modification, the quadratic constraint imposed on the variations of the control is modified by the inclusion of a positive-definite weighting matrix (the matrix of the second derivatives of the Hamiltonian with respect to the control). The second modification is a conjugate-gradient extension of the sequential gradient-restoration algorithm. Next, the addition of a nondifferential constraint, to be satisfied everywhere along the interval of integration, is considered. In theory, this seems to be only a minor modification of the basic problem. In practice, the change is considerable in that it enlarges dramatically the number and variety of problems of optimal control which can be treated by gradient-restoration algorithms. Indeed, by suitable transformations, almost every known problem of optimal control theory can be brought into this scheme. This statement applies, for instance, to the following situations: (i) problems with control equality constraints, (ii) problems with state equality constraints, (iii) problems with equality constraints on the time rate of change of the state, (iv) problems with control inequality constraints, (v) problems with state inequality constraints, and (vi) problems with inequality constraints on the time rate of change of the state. Finally, the simultaneous presence of nondifferential constraints and multiple subarcs is considered. The possibility that the analytical form of the functions under consideration might change from one subarc to another is taken into account. The resulting formulation is particularly relevant to those problems of optimal control involving bounds on the control or the state or the time derivative of the state. For these problems, one might be unwilling to accept the simplistic view of a continuous extremal arc. Indeed, one might want to take the more realistic view of an extremal arc composed of several subarcs, some internal to the boundary being considered and some lying on the boundary. The paper ends with a section dealing with transformation techniques. This section illustrates several analytical devices by means of which a great number of problems of optimal control can be reduced to one of the formulations presented here. In particular, the following topics are treated: (i) time normalization, (ii) free initial state, (iii) bounded control, and (iv) bounded state.
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    Journal of optimization theory and applications 16 (1975), S. 277-301 
    ISSN: 1573-2878
    Keywords: Strong variation algorithms ; optimal control algorithms ; optimal control ; optimum trajectories ; bounded control problems
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract This paper presents two demonstrably convergent, first-order, differential dynamic programming algorithms for the solution of optimal control problems with constraints on the control, but without constraints on the trajectory or the terminal state. The second of these algorithms can be used on more difficult problems than the first one, but it is correspondingly more complex.
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  • 71
    ISSN: 1573-2754
    Keywords: dynamic system ; parameters identification ; optimal control ; HJB equation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Mathematics , Physics
    Notes: Abstract Based on the contents of part (I) and stochastic optimal control theory, the concept of optimal control solution to parameters identification of stochastic dynamic system is discussed at first. For the completeness of the theory developed in this paper and part (I), then the procedure of establishing Hamilton-Jacobi-Bellman (HJB) equations of parameters identification problem is presented. And then, parameters identification algorithm of stochastic dynamic system is introduced. At last, an application example-local nonlinear parameters identification of dynamic system is presented.
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    Journal of optimization theory and applications 102 (1999), S. 15-36 
    ISSN: 1573-2878
    Keywords: Domain decomposition ; partial differential equations ; Riccati equation ; optimal control ; feedback law ; synthesis ; wave equation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract We present an iterative domain decomposition method for the optimal control of systems governed by linear partial differential equations. The equations can be of elliptic, parabolic, or hyperbolic type. The space region supporting the partial differential equations is decomposed and the original global optimal control problem is reduced to a sequence of similar local optimal control problems set on the subdomains. The local problems communicate through transmission conditions, which take the form of carefully chosen boundary conditions on the interfaces between the subdomains. This domain decomposition method can be combined with any suitable numerical procedure to solve the local optimal control problems. We remark that it offers a good potential for using feedback laws (synthesis) in the case of time-dependent partial differential equations. A test problem for the wave equation is solved using this combination of synthesis and domain decomposition methods. Numerical results are presented and discussed. Details on discretization and implementation can be found in Ref. 1.
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    Journal of optimization theory and applications 102 (1999), S. 299-313 
    ISSN: 1573-2878
    Keywords: Comparison of methods ; optimal control ; sensitivity ; shooting methods ; stability
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract A new method for solving optimal control problems, here called multiple NOC shooting, is presented. It is developed from NOC shooting. It has some advantages over its parent and over multiple shooting, which are both successful, high-accuracy methods for optimal control. A comparison of the three methods is given, incorporating two examples.
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    Journal of optimization theory and applications 17 (1975), S. 229-238 
    ISSN: 1573-2878
    Keywords: Mathematical programming ; converse duality ; Banach spaces ; convexity ; optimal control
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract Two theorems on converse duality are obtained for mathematical programs in Banach spaces. The proofs are based on a Banach-space generalization of the F. John necessary condition for a constrained minimum. No use is made of Kuhn-Tucker constraint qualifications. In the second theorem, the primal program contains a nonlinear equality constraint, and a converse duality theorem is obtained, using a modified concept of convexity; this result appears new, even for finite-dimensional programs. The results are applied to a problem in optimal control.
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  • 75
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    Journal of optimization theory and applications 100 (1999), S. 599-622 
    ISSN: 1573-2878
    Keywords: Discrete event dynamic systems ; optimal control ; calculus of variations ; polling problems ; transportation systems ; performance optimization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract We explore an approach involving the use of calculus of variations techniques for discrete event dynamic system (DEDS) performance optimization problems. The approach is motivated by the observation that such problems can be described by separable cost functions and recursive dynamics of the same form as that used to describe conventional discrete-time continuous-variable optimal control problems. Three important difficulties are that DEDS are generally stochastic, their dynamics typically involve max and min operations, which are not everywhere differentiable, and the state variables are often discrete. We demonstrate how to overcome these difficulties by applying the approach to a transportation problem, modeled as a polling system, where we are able to derive an explicit and intuitive analytic expression for an optimal control policy.
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    Journal of optimization theory and applications 101 (1999), S. 307-328 
    ISSN: 1573-2878
    Keywords: Approximate controllability ; exact finite-dimensional controllability ; semilinear heat equation ; optimal control
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract This paper deals with the approximate controllability of the semilinear heat equation, when the nonlinear term depends on both the state y and its spatial gradient ∇y and the control acts on any nonempty open subset of the domain. Our proof relies on the fact that the nonlinearity is globally Lipschitz with respect to (y, ∇y). The approximate controllability is viewed as the limit of a sequence of optimal control problems. Another key ingredient is a unique continuation property proved by Fabre (Ref. 1) in the context of linear heat equations. Finally, we prove that approximate controllability can be obtained simultaneously with exact controllability over finite-dimensional subspaces.
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    Journal of optimization theory and applications 101 (1999), S. 329-354 
    ISSN: 1573-2878
    Keywords: Algebraic Riccati equations ; parabolic equations ; optimal control
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract We consider an optimal control problem with indefinite cost for an abstract model, which covers, in particular, parabolic systems in a general bounded domain. Necessary and sufficient conditions are given for the synthesis of the optimal control, which is given in terms of the Riccati operator arising from a nonstandard Riccati equation. The theory extends also a finite-dimensional frequency theorem to the infinite-dimensional setting. Applications include the heat equation with Dirichlet and Neumann controls, as well as the strongly damped Euler–Bernoulli and Kirchhoff equations with the control in various boundary conditions.
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    Journal of optimization theory and applications 101 (1999), S. 375-402 
    ISSN: 1573-2878
    Keywords: Time-optimal problems ; optimal control ; semilinear parabolic equations ; state constraints ; Pontryagin's minimum principle ; unbounded controls
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract We consider time-optimal control problems for semilinear parabolic equations with pointwise state constraints and unbounded controls. A Pontryagin's principle is obtained in nonqualified form without any qualification condition. The terminal time, which is a control variable, satisfies an optimality condition, which seems to be new in the context of control problems for partial differential equations.
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    Journal of optimization theory and applications 102 (1999), S. 1-14 
    ISSN: 1573-2878
    Keywords: Partial differential equations ; optimal control ; population dynamics ; age-structured population models
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract The present paper is concerned with the optimal control problem for a Gurtin–MacCamy type system describing the evolution of an age-structured population. Necessary optimality conditions are established in the form of an Euler–Lagrange system and existence of an optimal control is proved using the Ekeland principle.
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  • 80
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    Journal of optimization theory and applications 101 (1999), S. 557-580 
    ISSN: 1573-2878
    Keywords: Hybrid systems ; switching diffusions ; autonomous jumps ; impulsive jumps ; discounted cost ; optimal control
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract We address the optimal control problem of a very general stochastic hybrid system with both autonomous and impulsive jumps. The planning horizon is infinite and we use the discounted-cost criterion for performance evaluation. Under certain assumptions, we show the existence of an optimal control. We then derive the quasivariational inequalities satisfied by the value function and establish well-posedness. Finally, we prove the usual verification theorem of dynamic programming.
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    Journal of optimization theory and applications 103 (1999), S. 137-159 
    ISSN: 1573-2878
    Keywords: Stochastic optimization ; simulation ; estimation ; time-varying objective functions ; discrete event dynamic systems
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract In this paper, the optimization of time-varying objective functions, known only through estimates, is considered. Recent research defined algorithms for static optimization problems. Based on one of these algorithms, we derive an optimization scheme for the time-varying case. In stochastic optimization problems, convergence of an algorithm to the optimum prevents the algorithm from being efficiently adaptive to changes of the objective function if it is time-varying. So, convergence cannot be required in a time-varying scenario. Rather, we require convergence to the optimum with high probability together with a satisfactory dynamical behavior. Analytical and simulative results illustrate the performance of the proposed algorithm compared with other optimization techniques.
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    Journal of optimization theory and applications 17 (1975), S. 43-92 
    ISSN: 1573-2878
    Keywords: Calculus of variations ; optimal control ; state inequality constraints ; function minimization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract This paper is a sequel to a previous article by the author, concerned with a certain canonical problem in optimal control involving constraints of the typeψ α(t, x)⩽0, α=1,...,m. In that article, a set of second-order conditions necessary for a solution arc was obtained. In this paper, those results are extended to a general control problem involving the above type of constraints.
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    Journal of optimization theory and applications 17 (1975), S. 545-559 
    ISSN: 1573-2878
    Keywords: Calculus of variations ; optimal control ; global sufficient conditions ; Darboux point ; conjugate point
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract A theory of global optimality based upon the Darboux-point concept is developed. A definition is proposed for the Darboux point, and the Darboux point is shown to exist on nonglobally optimal trajectories under relatively general conditions. A mutually exclusive classification of Darboux points is noted, and several properties are proved for one of these classes (the Type-1 Darboux point). Numerous examples are included to illustrate the Darboux-point definition and properties.
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    Multibody system dynamics 3 (1999), S. 1-20 
    ISSN: 1573-272X
    Keywords: muscle models ; visualization ; time-dependent geometry ; optimal control ; human motion ; biomechanics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract In this paper, an interdisciplinary combination of several state-of-the-art techniques from multibody dynamics, biomechanics, muscle modeling, optimal control, and visualization for the investigation of human motions is described. The goal is to use (wherever possible) and modify (wherever necessary) existing techniques and to investigate what has to be observed to make them work together efficiently. A separate investigation and implementation of the topics often is not sufficient for a combined approach, e.g., when some very sophisticated muscle models described in the literature yield infeasible computation times, even on modern supercomputers, if they are combined with optimal control techniques. First, some basic elements of multibody dynamics and muscle models are described. Then, a state space model for the complete system is derived and optimal muscle stimulations are computed using optimal control techniques. Finally, extensions for the visualization of biomechanical effects are presented and the application to human kick and jump motions is shown. However, the main focus of the paper is the presentation of the interdisciplinary approach and its cooperating methods and not the in-depth description of individual topics or the investigation of a specific biomechanical application.
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    Mechanics of time-dependent materials 3 (1999), S. 15-30 
    ISSN: 1573-2738
    Keywords: modelling ; semi-solid materials ; simulation ; suspensions ; thixoforming ; thixotropy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Semi-solid metal alloys, as used in thixoforming, have a special microstructure of globular grains suspended in a liquid metal matrix. The complex rheological properties are strongly influenced by the local solid fraction, particle shape, particle size and state of agglomeration. There is a high demand for models and software tools allowing the simulation of semi-solid casting processes. The material under investigation is a tin-lead alloy (Sn-15%Pb) which exhibits a similar microstructure to aluminium alloys. The experiments were performed with a concentric cylinder rheometer of the Searle type. Initially, the liquid alloy is cooled down to the semi-solid range under constant shearing and then kept under isothermal conditions for further experimentation. Based on the experimental data, a single-phase model has been derived where the semi-solid alloy is regarded as a homogeneous material with thixotropic properties and the microstructure is characterised by a structural parameter. The model consists of two parts: the equation of state, including a finite yield stress, and a rate equation for the structural parameter. The model equations are employed in numerical software and used for the simulation of characteristic filling cases and the comparison with the conventional filling.
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  • 86
    ISSN: 1573-2746
    Keywords: polycrystal ; ionic ; oxide ; molecular-dynamics ; simulation ; growth ; thin film ; structure ; characterization ; grain boundary
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract A simulation methodology for the synthesis of polycrystalline, ionic thin films is developed. The method involves the preparation of a polycrystalline substrate onto which a thin film is subsequently grown by crystallization from the melt. A detailed structural analysis of a textured sixteen-grain FeO film, with a grain size of approximately 4.7 nm, shows that the interiors of the grains are almost perfect single crystals with only a very few vacancies and no interstitials. The grains are delineated by 〈001〉 tilt grain boundaries; as expected, the low-angle grain boundaries in the film consist of arrays of dislocations, while the high-angle grain boundaries are relatively narrow and well ordered.
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    Discrete event dynamic systems 9 (1999), S. 241-260 
    ISSN: 1573-7594
    Keywords: flexible manufacturing ; production scheduling ; optimal control ; necessary optimality conditions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract The problem of detailed scheduling of complex flexible manufacturing systems is addressed by optimal flow control. A model problem of scheduling parallel machines is considered to obtain necessary setup conditions. Studying the conditions results in a new solution approach that takes advantage of a juggling analogy of the production/setup scheduling. This analogy is used in the paper to direct construction of a solution method. The method searches for a globally optimal schedule by means of both a juggling strategy and a method of global optimization. The results obtained for a model problem are then generalized to systems with complex production and setup operations. Computational examples demonstrate the validity of the approach.
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    Experimental mechanics 39 (1999), S. 30-35 
    ISSN: 1741-2765
    Keywords: Three-dimensional deformation ; sheet metal ; grating method ; deformation gradient ; simulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Grating techniques are used to determine the three-dimensional deformation and the tangential strain of sheet metal. A grating is fixed on the surface and taken by stereo CCD cameras in different deformation states. By suitable line-following software, the grating coordinates in the images are determined with subpixel accuracy. Using photogrammetric methods, the three-dimensional coordinates are calculated from the image coordinates. The strain usually is determined by means of a deformation gradient, which is calculated from every deformed triangle. In this paper, the gradient is determined in the center of four neighboring meshes using a polynomial approximation of the displacement function in a reference position. The influence of the nontangential deformation is considered. By simulation, a flat sheet metal is deformed to a rotational symmetric surface. The difference of the known exact strain is compared with the numerically derived strain with respect to different grating pitches. The proposed method yields good results even in the case of large spatial deformation. It is applied to the deformation of a hatlike test specimen.
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