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  • Articles  (2,998)
  • 2000-2004
  • 1980-1984
  • 1970-1974  (2,998)
  • 1973  (2,998)
  • Electrical Engineering, Measurement and Control Technology  (2,998)
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  • Articles  (2,998)
Years
  • 2000-2004
  • 1980-1984
  • 1970-1974  (2,998)
Year
Journal
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Optical and quantum electronics 5 (1973), S. 1-8 
    ISSN: 1572-817X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract An attempt was made to correlate light beam absorption with the longitudinal dispersion of ink in turbulent pipe flow. Ink was injected into water flowing in a 2.22 cm ID pipe and the light beam produced by a laser traversed the pipe through transparent sections. Light beam attenuation by the ink pulse was measured with a photodiode and recorded by various means. Attenuation was measured at two locations downstream of the injection point. Since the attenuation was calibrated for ink density, theoretical prediction of the ink density distribution and the resulting light attenuation at the points of laser traverse was produced. The theoretical density distribution was based on only the first order source of longitudinal dispersion: the velocity gradient. The comparison between theory and experiment shows that, over a wide range of turbulence, dispersion was almost entirely due to velocity gradient and can be conveniently measured by the light beam absorption technique.
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  • 2
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    Optical and quantum electronics 5 (1973), S. 9-25 
    ISSN: 1572-817X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract Turbulent swirling water flow in a pipe has complex velocity distributions with special measurement problems tor experimental work. Some of these problems are described in the introduction to the paper along with comments on the basic characteristics of turbulent swirling flow. The form of laser Doppler anemometer used is briefly noted, with some special optical features developed to suit this class of flow. Experience during some two years of comprehensive experimentation is then outlined, including comment on the data processing system. Results from experiments with tangentially injected water flow in 50 mm bore pipes up to 60 diameters long are reported, with local measurements of mean velocity and turbulence intensity. The variation of mean velocity components and turbulence intensity with radius and distance along the pipe are discussed with a few comparisons of results obtained from other experimental techniques, e.g. pitot-static probe and hot films. For the particular problem examined here it would have been difficult, if not impossible, to obtain the measurements using a technique other than laser anemometry.
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  • 3
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    Optical and quantum electronics 5 (1973), S. 27-39 
    ISSN: 1572-817X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract The NEL laser velocimeter was developed originally as a point velocity meter, for measurement in transparent ducts, and for the calibration of conventional flowmeters by traversing the upstream duct in a number of places. Recently, its scope has been extended to include time-varying as well as mean-velocity measurements, and turbulence investigations in two dimensions. A magnetic-tape data-logger is used to record signals from a counter, and this provides an alternative to the conventional frequency tracker method. The operation of the basic one-dimensional optical and electronic systems is described. A detailed description is then given of the tape-logger which allows up to 500 measurements a second with a time resolution on each reading of 0.25 ms. Alternative approaches to two-dimensional measurements are discussed and details are given of the method finally chosen.
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  • 4
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    Optical and quantum electronics 5 (1973), S. 41-51 
    ISSN: 1572-817X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract Experiments were carried out to measure the optical coherence of an argon laser beam in tap water, distilled water, ocean coastal water and in processed water with 3% sodium chloride added. Measurements were made for water path lengths up to 2.9 m using two different procedures. The first was Young's experiment and the second involved an optical geometry common to the Laser Doppler Velocimeter. Results showed no degradation in the normalized degree of coherence over the measured distances. However, local changes in the index of refraction did cause the interference fringes to have some motion (approximately one-fourth of a fringe width). Tests were also carried out using the Laser Doppler Velocimeter in the back-scatter mode to measure the centre line velocity of a submerged jet. Results agreed very well with independent measurements.
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  • 5
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    Optical and quantum electronics 5 (1973), S. 53-58 
    ISSN: 1572-817X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract This paper deals with the usability of laser velocimeters in supersonic flow field studies. Problems of the optical setup stability are considered as well as possibilities of data acquisition and evaluation. It is demonstrated that dust particles always present in the air are well suited as tracers for the flow velocity. The behaviour of these particles is studied in a rapidly decelerated flow.
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  • 6
    ISSN: 1572-817X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract The sound field radiating from a jet is strongly dependent upon the turbulence in the jet. To describe the sound sources in a hot jet, a method has been developed, based upon the measurement of infra-red radiation of the jet, and a hybrid processing of the measured signal, which enables the computation of characteristic properties of the turbulence at various points inside the jet (convection speed, integral length scale, life time and intensity of turbulence). From these quantities the acoustic far field can be mapped, as a function of the polar distribution of the spectrum, the turbulence intensity and the total sound pressure field.
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  • 7
    ISSN: 1572-817X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract Velocity profiles and turbulence levels have been investigated in a Mach 2 wind-tunnel using a laser anemometer which directly measures the Doppler frequency shift in the scattered laser light. The experiments were performed with the wind-tunnel operating at normal humidity. However, ice particles were always produced in the supersonic throat, making artificial seeding unnecessary. These ice particles proved to be excellent light scattering centres, and were found to respond to the rapid velocity change occurring in an oblique shock wave in a distance 〈0.01 cm, from which the ice particle size was calculated to be 〈0.1μ. Measurements were made across a turbulent boundary layer and compared with Pitot tube data taken under similar conditions. Measurements were also made in a highly turbulent Mach 1 free jet.
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  • 8
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    Optical and quantum electronics 5 (1973), S. 101-106 
    ISSN: 1572-817X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract The spark method uses the fact that gas molecules which have been excited by the passage of a spark form a high conductance path for another high voltage pulse following the previous discharge after 10 to 100μs. A square pulse high voltage spark of duration adjustable down to 01μs is available. To ensure that the first spark of a train is as nearly straight as possible, it is triggered by an alpha particle from a safe radioactive source, the alpha-particle track being finely collimated. Stereoscopic photography of the sparks is used for observation, the pair of photographs being taken on a single 125×100 mm2 film. A Saab microdensitometer scanner is used for automatic recording of the co-ordinates of selected points on the stereo photograph and a data reduction computer program is used to obtain the three-dimensional positions of the spark paths and hence determine the flow velocities working from a known boundary condition.
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  • 9
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    Optical and quantum electronics 5 (1973), S. 71-89 
    ISSN: 1572-817X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract Analogue and digital techniques are proposed for the simulation of signals arising in laser Doppler velocimeters. Their merits are evaluated. Of special interest is the estimation of the instantaneous frequency of the Doppler signal from the zero crossing rate. An analysis is presented whereby the biases introduced in this estimation method are derived for two optical configurations of the velocimeter. This analysis is extended to the case of additive Gaussian noise on the signal, and the cumulative effect of additive noise on the zero crossing rate is determined. The so called “drop-out problem” which pervades the frequency estimation of the instantaneous Doppler signal is next considered, and expressions are derived for mean drop-out rate and the mean interval between drop-outs in terms of an arbitrary signal threshold. These should facilitate choice of threshold detection for given rms Doppler signal levels, and in achieving relative compromises in terms of signal bandwidth. Finally a novel form of frequency tracking system is discussed and its performance critically assessed.
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  • 10
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    Optical and quantum electronics 5 (1973), S. 107-118 
    ISSN: 1572-817X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract The spark tracing method and high speed photography have been used to investigate the flow conditions inside a cross stream air classifier. The photographs obtained clearly demonstrated the increasing mutual interplay between gas flow and particle stream with increasing concentration of the solids. The results show that, in general, in fluid-solids systems the method can be used up to volume concentrations of about 1×10−2.
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  • 11
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    Optical and quantum electronics 5 (1973), S. 129-129 
    ISSN: 1572-817X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
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  • 12
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    Optical and quantum electronics 5 (1973), S. 119-128 
    ISSN: 1572-817X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract The power spectrum of phototube current from a laser Doppler velocimeter operating in the heterodyne mode has been computed. The spectrum is obtained in terms of the space time correlation function, G(†r,τ), of the fluid. The spectral width and shape predicted by the theory is in agreement with experiment. For normal operating parameters the time average spectrum contains information only for times shorter than the Lagrangian integral time scale of the turbulence. To examine the long time behaviour one must use either extremely small scattering angles, much longer wave-length radiation or a different mode of signal analysis, e.g. F.M. detection.
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  • 13
    ISSN: 1572-817X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract Omitting the dispersion of side bands, the self-distortion of an amplitude-modulated e.m. signal due to non-linear polarizability in nonparabolic semiconductors has been investigated. The distortion is basically due to self-focusing of the electromagnetic wave and is different from the resistive (absorption) type demodulation. In n-InSb and at average powers of ∼1 W the index of modulation is found to increase four times at a modulation frequency R~108 s−1.
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  • 14
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    Optical and quantum electronics 5 (1973), S. 137-151 
    ISSN: 1572-817X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract The criteria for the design of optical arrangements for laser anemometry are formulated for reference-beam, two-beam and single-beam modes of operation. The dependence of useful light intensity upon optical path-length difference and number of axial laser modes is calculated. Laser power requirements are evaluated and the dependence upon band-pass filtering is quantitatively assessed. A new two-channel integrated-optical unit, with light-path compensation, and embodying the proposed design criteria, is described.
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  • 15
    ISSN: 1572-817X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract For a generalized scheme of LDV, the expressions describing the light intensity distribution in a photo-receiver plane with regard to the size of the scattering particles have been calculated using Fourier optics. The LDV signal should be considered as a narrow-band stochastic process representing the sum of random phase radio frequency pulses arising from each light scattering particle. Then the expected error of the mean velocity measurement is equal to half the reciprocal of the number of interference fringes squared and the input signal-to-noise ratio is equal to the square root of the product of Doppler frequency, fringe number and averaging time. The device developed by the authors includes d.c. optical signal compensation. The device is described and the results of its use are given.
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  • 16
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    Optical and quantum electronics 5 (1973), S. 163-174 
    ISSN: 1572-817X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract A double slit experiment has been performed in which the condition that only one slit was open at any instant of time was satisfied approximately. The intensity of the light was such that (a) the time between the detection of successive photons contributing to any fringe was much less than the transit time of the photons through the interferometer, and (b) the electro-optic shutters were switched several times between the detection of quanta. The light source used was a He-Ne laser and the modulation was obtained using a single ADP crystal. The theoretical background to the experimental method is given and the experimental results are shown.
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  • 17
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    Optical and quantum electronics 5 (1973), S. 175-187 
    ISSN: 1572-817X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract The signal-to-shot-noise ratio of the photocurrent of a laser Doppler anemometer is calculated as a function of the parameters which describe the system. It is found that the S/N is generally a growing function of receiver area, that few large particles are better than many small ones, and that generally the ‘fringe’ or ‘differential’ mode configuration is equal to, or better than, the ‘reference beam’ mode.
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  • 18
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    Optical and quantum electronics 5 (1973), S. 189-200 
    ISSN: 1572-817X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract A time-dependent theoretical treatment of the intensity distribution within a thermally self-defocused laser beam is presented, based on a ray-geometrical approach. Well-modulated interference fringes are predicted extending over most of the beam. This treatment is applicable to beam propagation in media for which the heat transfer by convection can be neglected when compared with that due to conduction. Numerically determined intensity distributions are given and compared with ones obtained experimentally using a laser beam of 488 nm wavelength and an absorbing medium of glycerol doped with iodine. Good agreement is obtained.
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  • 19
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    Optical and quantum electronics 5 (1973), S. 221-222 
    ISSN: 1572-817X
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  • 20
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    Optical and quantum electronics 5 (1973), S. 217-219 
    ISSN: 1572-817X
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  • 21
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    Optical and quantum electronics 5 (1973), S. 201-215 
    ISSN: 1572-817X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract This contribution attempts to review certain resonance effects which occur in the dynamic behaviour of semiconductor lasers. To study these effects theoretically, a rate equation approach is used for single-mode operation in the region of lasing threshold. The two basic rate equations are given and their transient solutions discussed. The existence of two time constants in these equations, viz. the electron lifetimeτ e and the photon lifetimeτ e; gives rise to a characteristic resonance frequency in the GHz region. This resonance manifests itself in transient ‘spiking’ effects, in quantum noise phenomena, and in high-frequency modulation experiments. In a modified form the resonance frequency may also be studied in lasers with external cavities and in double-diode configurations (or, equivalently, conventional devices with non-uniform excitation along the cavity length). In the latter two examples mentioned above, the resonance is excited by optical feedback of the laser radiation into the active medium via a ‘lossy’ or insufficiently inverted region. In the ‘spiking’ oscillations commonly observed at the commencement of laser operation, the initial ‘population overshoot’ is the cause of the resonance. For the case of quantum noise it is the requirement that the photon and electron populations have integer values which supplies the driving force-a true quantum effect. High-frequency modulation experiments directly reveal the same resonance frequency where a strong maximum in modulation intensity occurs.
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  • 22
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    Optical and quantum electronics 5 (1973), S. 223-236 
    ISSN: 1572-817X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract Numerical analysis of the characteristics of silicon solar cells underγ-ray or fast neutron irradiation is presented. The degradation of spectral response, short-circuit current, maximum power, open-circuit voltage and curve power factor are discussed. The calculation is based on estimating the minority carrier lifetime by the Shockley-Read equation, assuming the introduction rate, capture cross-section and the energy level to be equal to those of various predominant recombination centres, such as E-centre (phosphorus-vacancy complex), A-centre (oxygen-vacancy complex) and J′-centre (boron-vacancy complex) inγ-irradiated silicon single crystals. The simulated results show good agreement with experiment for N-type F·Z and C·Z bulk crystals with E-centres, and for P-type C·Z bulk crystal with J′-centres.
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  • 23
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    Optical and quantum electronics 5 (1973), S. 243-248 
    ISSN: 1572-817X
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    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract The expression for inversion density in a gas laser includes an additional term if one allows elastic and/or resonant collisions among the active atoms. This term is a function of the line parametersγ 1, andγ 2 and describes the effect of homogeneous broadening on the saturated gain profile. Measurements of these parameters show that the homogeneous broadening in a 0.63 μm He-Ne laser plays an important role.
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  • 24
    ISSN: 1572-817X
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    Notes: Abstract The conversion is considered of infra-red radiation into visible in a proustite crystal with the pump and signal waves perpendicular to each other. The angular and spectral parameters as well as the efficiency of such interactions are determined. The advantages of this interaction are discussed.
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  • 25
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    Optical and quantum electronics 5 (1973), S. 255-256 
    ISSN: 1572-817X
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  • 26
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    Optical and quantum electronics 5 (1973), S. 256-259 
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  • 27
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    Optical and quantum electronics 5 (1973), S. 260-260 
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  • 28
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    Optical and quantum electronics 5 (1973), S. 249-254 
    ISSN: 1572-817X
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    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract The photoconductive response of an ORP10 InSb detector has been found to be dependent on the cube root of illuminating intensity for high levels of irradiation at 5.3 μm. The limiting power for a linear response (∼1 W) is consistent with the predictions of a theory developed by Moss for a high mobility semiconductor.
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  • 29
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    Optical and quantum electronics 5 (1973), S. ii 
    ISSN: 1572-817X
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  • 30
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    Optical and quantum electronics 5 (1973), S. 285-288 
    ISSN: 1572-817X
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    Notes: Abstract A technique is described for melting high purity glasses in which heat is generated within the glass by R.F. induction. Losses at c. 1060 nm were less than 50 dB Km−1 Multimode fibres have been made from those materials with little increase in loss resulting from the fibre drawing process.
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  • 31
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    Optical and quantum electronics 5 (1973), S. 261-274 
    ISSN: 1572-817X
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    Notes: Abstract Interest in fibre-optic communication systems was aroused by Kao and Hockham in 1966. This survey endeavours to relate how the concept has grown within the United Kingdom from that inception. The work is reviewed from the standpoint of a systems engineer, but briefly covers the components vital to fibre-optic communication systems and mentions the more fundamental studies on which all other aspects have been based.
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  • 32
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    Optical and quantum electronics 5 (1973), S. 275-284 
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    Notes: Abstract This paper offers a review of the contributions of German research groups in the field of fibre-optical communications until now. Since the latest publications are also taken into account which in part are not yet printed, a survey is given at the same time of current activities in this field in Germany.
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  • 33
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    Optical and quantum electronics 5 (1973), S. 289-296 
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    Notes: Abstract Glasses prepared from high purity starting materials were used for pulling optical waveguide fibre by a double crucible technique. The observed optical loss of the glasses and fibres can be accounted for by absorption bands arising from the presence of traces of transition metal ion impurities and the low energy tails of u.v. absorption bands. The relatively high loss of the fibres is attributed to leaching of impurities from the platinum crucibles.
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  • 34
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    Optical and quantum electronics 5 (1973), S. 297-307 
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    Notes: Abstract A preform technique for drawing cladded-glass and hollow fibres suitable for application to optical communications is described. The parameters which need to be controlled are discussed and the preparation of the preforms is described. The resulting fibres have a high geometric uniformity and a probe beam remains largely at the same angle to the axis after more than 106 reflections at the core/cladding interface. Fibre attenuations of 150, 60 and 5.8 dB km−1 have been obtained with commercial glasses, preforms made from a special melt at Sheffield University [5], and a commercial liquid, respectively. The fibre drawing process does not appear to introduce any additional impurities and heat treatment has produced a significant reduction of transmission loss in glass fibres.
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  • 35
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    Optical and quantum electronics 5 (1973), S. 309-321 
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    Notes: Abstract Focusing optical fibre and thin film guide can be made to have nearly the same group velocity for every mode if the optimum distribution of refractive index or thickness of the film is realized. A focusing optical fibre is manufactured from a multilayer glass rod by solid state diffusion. A thin film waveguide is prepared from nitrocellulose by controlling the airflow distribution. Undulation of light propagating in the film is observed, and it is confirmed that the focusing property is determined by the distribution of the film thickness. The field distributions of the TE modes have been analysed for an optical waveguide fabricated by solid state diffusion. Glass waveguide has been manufactured with the appropriate concentration of lead ions to give the maximum propagation constant. A low loss waveguide is fabricated by the diffusion of lead or thallium ion into glass followed by selective etching.
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    Optical and quantum electronics 5 (1973), S. 335-344 
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    Notes: Abstract Improvements are described to a twin-beam spectrophotometer for measuring the bulk attenuation of optical quality glass over the wavelength range 0.4 to 1.1 μm. Results are presented for a number of glasses and a comparison is shown between the attenuation of a multimode fibre with a core of F7 glass and various samples of F7 rods.
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  • 37
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    Optical and quantum electronics 5 (1973), S. 323-334 
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    Notes: Abstract A thin rod sample is thermally clamped at both ends to provide a rigid mounting and a thermal short-circuit for heating effects associated with surface losses. The ends are index matched with liquid to minimize sample preparation. A laser beam is focused through the sample and the temperature rise due to the absorbed energy is monitored at its centre. Sensitivity is limited to a few dB km−1 optical loss with a laser of 100 mW power. The theory is discussed in detail for this particular geometry and experimental verification presented.
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  • 38
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    Optical and quantum electronics 5 (1973), S. 367-368 
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  • 39
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    Optical and quantum electronics 5 (1973), S. 345-350 
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    Notes: Abstract The transmission of optical multimode carriers via clad glass fibres has many advantages, but in general introduces severe signal distortion because of mode delay differences. We describe a simple semiconductor receiver capable of equalizing these delay differences at the fibre end. A tenfold increase in bandwidth (data rate) should be possible by this means if mode coupling in the fibre is not excessive.
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    Optical and quantum electronics 5 (1973), S. ii 
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    Optical and quantum electronics 5 (1973), S. 351-366 
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    Notes: Abstract Linear photodiode-amplifier combinations will be required for optical communication systems, in particular for those using fibre optics as the transmission medium. The noise performance of photodiode-amplifier combinations is derived and presented, and some parameters affecting photodiode and first stage amplifier design are reviewed. It is shown that, of foreseen devices, silicon JFETs will be quietest as amplifier first stages for base bandwidths of up to 10 MHz, GaAs FETs up to 100 MHz and bipolar transistors will be preferred for broader bandwidths. In tuned applications the JFET is to be preferred up to 8 MHz and GaAs FETs will be the best devices above that frequency.
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    Optical and quantum electronics 5 (1973), S. 411-413 
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    Optical and quantum electronics 5 (1973), S. 405-410 
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    Notes: Abstract A study has been made of photoconductivity in Cdln2S4 induced by 1.17 eV photons from a Q-switched neodymium laser. Both three-photon absorption, and two-photon absorption involving the emission of a phonon, have been investigated. The experimental data are in satisfactory agreement with the theory of multi-quantum transitions which takes into account the peculiarities of crystal zone structure. The investigation of competing multi-quantum transitions is a new method which permits one to obtain information on the fundamental optical constants of solids.
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    Notes: Abstract A variable sensitivity technique using the projection of a fringe pattern is demonstrated for mapping deformations, vibrations, contour lines and differences between two objects. The method does not require laser illumination and gives an opportunity for studying large objects with incoherent light, and is compared with other techniques such as holography or speckle. The limitations likely to be encountered in industrial environments are discussed. The realization and incoherent projection of gratings is also discussed.
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    Optical and quantum electronics 5 (1973), S. 393-403 
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    Notes: Abstract Many studies on an optical ULM correlator have been carried out by various workers. Different types of correlation are usually produced, depending not only on the combinations of signals to be processed but also on the optical and electrical filters used in the detecting stage. This paper investigates the effects of these conditions on the performance of the optical ULM correlator in some detail on the basis of a unified analysis. It is also shown, by considering in the course of this analysis the propagation of a spatial coherence function, that the coherence property of light used for the illumination does not affect the correlation-output signal. Some experiments are performed concerned with the effect of spatial coherence, binary or intensity correlation and the linear response for correlation in the ULM correlator.
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    Optical and quantum electronics 5 (1973), S. 429-437 
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    Notes: Abstract An analysis is given of dispersion in an optical fibre waveguide having a continuous radial variation of refractive index using the scalar wave approximation. Solutions are presented for the particular case of Selfoc fibre taking into account mode dispersion, material dispersion and group delay. It is shown that for a correctly matched input Gaussian beam the pulse dispersion is small although in practice it is likely to be ∼ 1 ns over a length of 1 km.
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    Optical and quantum electronics 5 (1973), S. 415-428 
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    Notes: Abstract The propagation of electromagnetic surface waves along a radially inhomogeneous dielectric waveguide is investigated. The problem is formulated in terms of differential equations to be satisfied by the radially dependent parts of the electromagnetic field vectors. The dielectric waveguide is assumed to consist of a homogeneous cladding of infinite extent and a radially inhomogeneous core of higher permittivity. Numerical solutions of the differential equations in the core are obtained by two different methods, viz. by direct numerical integration and by substitution of an appropriate power series expansion. In the cladding the field is expressed in terms of modified Bessel functions. Imposing the boundary conditions at the interface of core and cladding, an equation for the unknown propagation coefficient is obtained. From this equation the propagation coefficients for the lower order modes are computed numerically. Numerical results are presented for some permittivity profiles of practical interest in single-mode transmission along optical fibres.
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    Optical and quantum electronics 5 (1973), S. 457-477 
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    Notes: Abstract This paper presents theoretical results concerning pulse-broadening in multimode fibres. All the calculations are based on the geometric optic hypothesis. The results are given for different kinds of input functions in the case of a loss-free guide and an energy equidistribution. Subsequently, material and interface losses are included. The influence of angle-dependent energy distributions is also investigated. For all these cases analytical expressions are obtained. Experimental results are presented: they are in good agreement with theory.
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    Optical and quantum electronics 5 (1973), S. 478-478 
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    Optical and quantum electronics 5 (1973), S. 439-456 
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    Notes: Abstract After a brief summary of the main factors causing pulse distortion in optical fibres, expressions are derived for phase velocity, group velocity and dispersion, that is velocity variation with frequency, of each mode. The analysis is carried out by making extensive use of the functiony(x) (y andx being the arguments of the first and second kind Bessel functions that appear in the solutions of Maxwell equations), that we call characteristic function. By using this function we obtain particularly simple and compact formulas that make easier the analysis of the behaviour of velocity and dispersion near and far from cut-off. It will also be seen that the ratio between the power propagating in the core,W 1, and the power in the cladding,W 2, for each mode takes a very simple form if expressed by means of the characteristic function: this fact permits a direct relation to be found between group velocity and power flow in an optical fibre. The study of the ratioW 1/W 2 will show that, contrary to expectation, for some modes, a substantial fraction of energy travels inside the core, even near cut-off. Expressions are given forW 1/W 2 at cut-off, and far from cut-off. Plots of velocity and dispersion are shown. On the grounds of the obtained results pulse distortion in optical fibres is discussed.
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    Optical and quantum electronics 5 (1973), S. 479-489 
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    Notes: Abstract The exact solutions are given of the relativistic equations of motion for both the momentum and displacement of a charged particle which is injected into an arbitrary number of intense electromagnetic waves of any polarization and frequency, including zero, all of which propagate parallel to a uniform magnetostatic field with the speed of light. The solutions are implicit in time.
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    Optical and quantum electronics 5 (1973), S. 503-508 
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    Notes: Abstract The optical third harmonic generation of focused Gaussian light beams is studied theoretically in uniaxial crystals with third order non-linearity. The numerical integration of the parabolic equation for optimum focusing condition shows that, for strong focusing, the third harmonic power is independent of the focusing parameterξ=I/b (I=crystal length,b=confocal parameter). Therefore, the third harmonic generation differs from the second harmonic generation. We neglect in our calculations pump depletion and the intensity dependence of the refractive index.
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    Optical and quantum electronics 5 (1973), S. 491-501 
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    Notes: Abstract Starting from the non-linear relativistic equations of motion for charged particles in the very high intensity fields of laser radiation, the maximum kinetic energy ɛkin of the resulting oscillation is derived exactly. In non-relativistic conditions ɛkin agrees with the well-known valuee 2 E v 2/(2m0ω2|n|), showing a dependence on the rest massm 0 of the particle. In the relativistic case, the mass dependence vanishes. The multipole radiation is calculated on the basis of Sommerfeld's formula for relativistic conditions. It is shown that this radiation is not important for oscillation energies up to $$ \in _{kin^{mr} } $$ =70m 0 c 2 for electrons in neodymium glass laser radiation and up to higher values for CO2 lasers and for protons. With the limitationm 0 c 2 〈 εkin 〈 $$ \in _{kin^{mr} } $$ , the formula for ɛkin is used to calculate the pair production (a) for singly oscillating particles in vacuum without collisions and (b) for plasmas with collisions. Taking into account the local increase of the effective electric laser field near the cut-off density due to the decrease of ¦n¦ (n is the complex refractive index), there is the possibility of efficient proton pair production at intensities of 1019 W cm−2 for neodymium glass lasers and of 1017 W cm−2 for CO2 lasers, besides electron pair production.
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    Optical and quantum electronics 5 (1973), S. 509-516 
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    Notes: Abstract The stability of a plasma/semiconductor for small fluctuations in the intensity of plane electromagnetic beam has been studied when a non-linearity in the dielectric constant appears on account of the diffusion of non-uniformly heated carriers (due to fluctuations in the intensity of the beam). Fluctuations of optimum size and long duration have been found to grow at moderate powers. The effect of absorption is, however, to suppress this effect.
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    Optical and quantum electronics 5 (1973), S. 517-532 
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    Notes: Abstract A formulation has been developed to treat the effects of alignment errors of the optical system used in a differential laser Doppler velocimeter. It is then applied to analyse the properties of output beat signals obtained by the velocimeter. The effects of optical alignment errors on the spectral width and signal-to-noise ratio of the output beat signals and on the probing volume are investigated in some detail. The spectral width is not affected very much by the deviation of the angle between two beams incident on the probing volume, but depends mainly on the number of interference fringes produced in that volume. The signal-to-noise ratio is very sensitive to the displacement of two incident beams on the probing volume and is also affected by the intensity and beam width differences of these two beams. The probing volume is evaluated in the case of two incident beams having different beam widths.
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    Optical and quantum electronics 5 (1973), S. 551-555 
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    Optical and quantum electronics 5 (1973), S. 539-549 
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    Notes: Abstract Thin unclad glass ribbon optical waveguides have been made which can be used to connect two optical integrated circuits. The launching of light into and out of the ribbons is described and, from the far-field patterns of the light coupled out of the ribbons, the propagation and scattering behaviour of the waveguide modes may be observed. Although the ribbons are capable of supporting several modes, single-mode operation is shown to be feasible.
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    Optical and quantum electronics 5 (1973), S. 533-538 
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    Notes: Abstract In the presence of a strong Gaussian laser beam, the non-linearity in the dielectric constant of a strongly ionized plasma has been investigated. The non-linearity arises due to the heating and redistribution of the electrons; the loss of electron energy gained from the field has been assumed to be due to thermal conduction. This self-induced non-linearity causes a self-focusing and oscillatory waveguide propagation of the beam even when the non-linear dielectric constant does not fall in the saturating range. In a typical case of a 1010 W laser, the enhancement of axial intensity by a factor of 25 has been predicted in a length of 0.6 cm.
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    Optical and quantum electronics 5 (1973), S. 561-562 
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    Journal of applied electrochemistry 3 (1973), S. 1-15 
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    Notes: Abstract A method for determining the carrier concentration of n-type gallium arsenide by an electrochemical technique is described. The minority carrier diffusion length is also obtained, and using subsidiary measurements the minority carrier lifetime can be estimated. The extension of this treatment to the characterization of epitaxial layers is discussed.
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    Journal of applied electrochemistry 3 (1973), S. 23-29 
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    Notes: Abstract The thermal reaction products in the Ag2S-Ag1.70 Te-Ag4P2O7, Ag2S-Ag1.70 Te-Ag3PO4 and Ag2S-Ag1.70 Te-AgPO3 systems were found to exhibit both high ionic and electronic conductivity at room temperature. For example, the ionic conductivities of (Ag2S)0.69 (Ag1.70Te)0.285 (Ag4P2O7)0.025, (Ag2S)0.5(Ag1.70Te)0.45 (Ag3PO4)0.05 and (Ag2S)0.65 (Ag1.70Te)0.25(AgPO3)0.1 were 0.25, 0.25 and 0.22 (ohm. cm)−1 at 25°C, respectively. Differential thermal analysis and X-ray diffraction showed that these high ionic conductivity solids had an α-Ag2S-like structure at room temperature.
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    Journal of applied electrochemistry 3 (1973), S. 37-44 
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    Notes: Abstract Accurate and fast measurements of electrolytic hydrogen-deuterium separation factors are required to study short-term time effects and the effects of other variables, for example overpotential, before the cathode has suffered irreversible changes such as hydrogen embrittlement. A system for fast measurement of the hydrogen-deuterium ratio of the liberated hydrogen isotopes in argon as the sweep gas has been developed and is described in detail. Unique features include a modified Cartesian manostat and an automatic Toepler pump in the gas collection system, and an automatic mass spectrometer inlet system whose cycle time is about 4 min. Calibration procedures are outlined. The accuracy and reproducibility in the H/D ratio are ±1% and ±0.5% respectively, for the range 0.75 to 5.0 mol. % deuterium in mixtures containing 0 to 80 vol.% argon.
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    Journal of applied electrochemistry 3 (1973), S. 53-60 
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    Notes: Abstract The anode products formed when electrowinning lead from lead sulphate dissolved in LiCl-KCl eutectic have been determined when using a carbonaceous anode. Results indicate that electrolytic decomposition proceeds by the overall reaction $$PbSO_4 + C \to Pb + CO_2 + SO_2 $$ However at low current densities the CO2 content increases by the reaction $$C + SO_2 \rightleftharpoons CO_2 + \frac{1}{v}S_v $$ The secondary reactions of the cathodically produced lead also increase the CO2 and sulphur yields according to the following overall reactions $$2PbO + C \to 2Pb + CO_2 $$ and $$PbS \to Pb + \frac{1}{v}S_v $$ All the above electrochemical reactions are extensively polarized and chlorine co-evolution starts at low current densities.
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    Journal of applied electrochemistry 3 (1973), S. 77-78 
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    Journal of applied electrochemistry 3 (1973), S. 168-168 
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    Notes: Abstract The influence of high temperature annealing and heavy current treatments of porous Pt electrodes is investigated with scanning electron microscopy. The results are discussed on the basis of the kinetic behaviour of these electrodes, known from the literature or deduced from our still unpublished results. It is demonstrated that both the structure and the catalytic activity are influenced by the treatments.
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    Journal of applied electrochemistry 3 (1973), S. 179-184 
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    Notes: Abstract Alkaline sodium silicates have been prepared by heating sodium carbonate and silica mixtures in the mole ratio of 2.5∶1. The silicates have been examined by chronopotentiometric and thermogravimetric methods. The electro-analytical technique has allowed the identification of the oxy-anions SiO4 4−, Si2O7 6− and Si3O10 8− by their electro-reduction at cathodic potentials with reference to a graphite anode of approximately −1.0, −1.6, −2.0 V respectively.
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    Journal of applied electrochemistry 3 (1973), S. 185-191 
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    Notes: Abstract The analytical and potentiometric study (using an Ag/Ag+ reference electrode) of the behaviour of pure iron in molten sodium metaphosphate at 750°C shows that a non-polarized electrode corrodes: iron is oxidized to soluble Fe2+ ions and, simultaneously, an Fe2P and FeP2 deposit resulting from phosphate anion reduction is formed on the electrode surface. The variations of the mixed potential and of the total mass of oxidized iron show that the corrosion rate decreases as the immersion time increases. Such an inhibition comes from the gradual coating of the electrode surface with the iron phosphides: the corrosion rate is controlled by the iron diffusion through the deposit, the thickness of which increases with time.
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    Journal of applied electrochemistry 3 (1973), S. 213-218 
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    Notes: Abstract The catalytic properties of polymeric phthalocyanines with Fe and Co as central atoms for the electroreduction of oxygen in 0.5–2.3m H2SO4 were studied. No noticeable dependence of the electrode potential on the concentration of H2SO4 was found. The electroactivity of the catalyst with a central Fe atom undergoes considerable deterioration under the given conditions, whereas the stability of the catalyst with a central Co atom is very good and the potential of an electrode containing 30% catalyst in the active mass is 100 mV more positive than that of an electrode with 13% platinum, both at 40 mA cm−2. The electrode performance depends markedly on the sort of carbon substrate, showing a parallelism with respect to oxygen electrodes in alkaline medium. The gold mesh current collector can be replaced by the addition of carbon black to the active layer.
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    Journal of applied electrochemistry 3 (1973), S. 201-211 
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    Notes: Abstract The electrolysis of a soda-lime silica glass has been studied using Pb, Pb/Cu and Bi/Cu anodes at temperatures from 500 to 800°C. Generally, electrolyses at Pb/Cu anodes obeyed 1/I 2 againstt equations under these conditions whereas a 1/I againstt relationship would be obtained for a Pb anode. At the Bi/Cu anode, containing a larger concentration of copper (9.9% as compared to 1.9%), the electrolysis current was almost constant for periods of seconds even at 600°C and less. With Pb anodes the temperature at which 1/I 2 againstt behaviour changed to 1/I againstt increased as the temperature increased; it was 2.5 and 50 V at 600 and 700°C, respectively. On the basis of these results and some pulse experiments which showed polarization at Pb but not at Pb/Cu anodes it is proposed that the behaviour at the latter, at least, can be explained by the electromigration of copper ions into the glass replacing the interstitial sodium ions and resulting in the formation of a surface layer of higher specific resistance than that of the bulk glass. A similar mechanism may occur at Pb anodes at higher temperatures.
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    Journal of applied electrochemistry 3 (1973), S. 253-253 
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    Journal of applied electrochemistry 3 (1973), S. 241-249 
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    Notes: Abstract The electrochemical behaviour of cobalt in molten alkali nitrates in the temperature range from 141 to 321°C has been investigated. At lower temperatures the metal dissolves as Co(II); the oxidation product at higher temperatures is Co3O4. Nitrogen oxides are also formed. Passivation and localized corrosion occur under definite anode potential, Co(II) concentration and temperature conditions. These effects have been studied by non-stationary measurements. Co(II) dissolved in the melt can be electrodeposited either on cobalt or platinum cathodes.
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    Journal of applied electrochemistry 3 (1973), S. 285-289 
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    Notes: Abstract The hysteresis effect in the anodic passivation of a series of stainless steels in acid solutions has been evaluated coulometrically from the polarization curves obtained by forward and reverse potential scanning. Based on such effects, an index of passivity retention has been drawn differentiating the stainless grades and reflecting the surface preparation.
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    Journal of applied electrochemistry 3 (1973), S. 271-283 
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    Notes: Abstract To increase the overload capacity of the carbon-air electrode in alkaline electrolyte, without seriously changing the electrode potential during short-time overload periods, small amounts of MnO2 were added to carbon and the effects investigated. The potentiodynamic investigations revealed the existence of two reducible manganese species with reduction potentials of about −280 mV and −400 mV. The second potential corresponds to the known reduction process Mn(III) → Mn(II) whilst the first one corresponds to a reversible process (the product is easily reoxidized by air or anodically), not reported in literature as yet. It was explained in terms of a new redox potential for the system Mn(III)/Mn(II), both species being strongly and irreversibly adsorbed at the carbon surface. The galvanostatic discharge curves in the absence of air indicate that a sufficient overload capacity of about 40 C cm−2 is available if 22% (wt) MnO2 is added. Steady-state polarization curves in the presence of air indicate the catalytic effect of small amounts of MnO2 for the oxygen reduction reaction.
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    Journal of applied electrochemistry 3 (1973), S. 297-301 
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    Notes: Abstract The zinc-air electrochemical system in 5m NH4Cl was studied. The optimum electrolyte-zinc ratio was found to be 50 ml g−1 Zn and the optimum electrolyte-cathode ratio, 15 ml cm−2 of carbon cathode. The air cathode polarization is not increased by intermittent usage of the cell. Electrodes made from zinc sponge with addition of lead show the smallest corrosion in the given electrolyte. The cell voltage is about 0.9–0.95 V at a load of 10 mA cm−2 of carbon cathode at ambient temperature.
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    Journal of applied electrochemistry 3 (1973), S. 307-314 
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    Notes: Abstract The individual activity of hypochlorite ion in concentrated neutral salt (NaCl-NaClO3) solutions has been estimated kinetically by measurement of the Faradaic efficiency in a chlorate producing system comprised of a cell and external reactor, with provision for brine re-circulation. By use of this activity in the diffusion relationships developed by Ibl and Landolt [1–3], reasonable agreement has been achieved between the experimental chlorate yield and the yield expected based on the combined hydrolytic and diffusional flux of active chlorine. In this way it has been shown as expected from basic theory that the gradient of chemical potential rather than the concentration difference represents the driving force of diffusion. A formal activity coefficient for active chlorine species is suggested as being a useful term when considering the chlorate cell system.
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    Journal of applied electrochemistry 3 (1973), S. 337-339 
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    Journal of applied electrochemistry 3 (1973), S. 321-325 
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    Notes: Abstract An electrolyte for the high-rate plating of aluminium from the tetrahydrofuran solutions of aluminium chloride and lithium aluminium hydride has been developed. A smooth and coherent deposit of aluminium has been obtained at the current density of 18 A dm−2 without stirring, whereas the conventional diethyl ether solvent bath allows good plating up to 5 A dm−2 under the same condition. The current densities applicable are increased with an increase in the molar fraction of aluminium chloride in tetrahydrofuran. The conductivity of the plating solution was measured at various molar ratios of aluminium chloride to lithium aluminium hydride. A plateau region of the conductivity curve plotted against the molar ratio is consistent with the composition of the plating bath giving a good plating. The plateau region is enlarged with an increase in total aluminium concentration.
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    Journal of applied electrochemistry 3 (1973), S. 341-341 
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    Journal of applied electrochemistry 3 (1973), S. 315-319 
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    Notes: Abstract The double layer (d.l.) capacity of pyrolytic graphite in cryolite-alumina melts at 1010°C was found to exhibit a minimum of 20μF cm−2 at 0·9 V positive to the aluminium electrode. The d.l. capacity attained a plateau of ∼60μF cm−2 at 1·1–1·4 V, while it rose steeply at potentials below 0·7 V. During electrolytic consumption involving CO2 evolution the d.l. capacity of pyrolytic graphite remained unaffected, while that of baked carbon was changed, reflecting changes in surface area. At low current densities (cds) the surface area increased substantially and the surface was noticeably roughened, while the opposite behaviour was observed at above 2.5 A cm−2.
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    Journal of applied electrochemistry 3 (1973), S. 327-335 
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    Notes: Abstract Lithium orthosilicate, Li4SiO4, and its solid solutions are a new group of solids of high ionic conductivity. Either Li or Si may be at least partially replaced by several other di-, tri- or tetra-valent cations. Highest conductivities were found for solid solutions with Si partially replaced by Ti; typical values were 10−3 to 10−4 Ω−1 cm−1 at 300°C rising toc. l Ω−1 cm−1 by 700°C. The solid solutions are easy to prepare and are stable in air. Conductivities were measured on pressed cubes of powdered material using variable frequency a.c. methods. The conductivities of these Li4SiO4 solid solutions are compared with those of other known Li-conducting solids; Li4SiO4 solid solutions are probably the best all-round, polycrystalline Li-electrolytes yet found for temperatures abovec. 200°C.
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    Journal of applied electrochemistry 3 (1973), S. 65-72 
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    Notes: Abstract The ionic conduction in sintered oxides of the system Bi2O3-WO3 was investigated by measuring conductivities and ion transference numbers under various conditions. The ion transference number was measured by an oxygen concentration cell employing the specimen tablet as the electrolyte. It was found that a compound 3Bi2O3 WO3 and its solid solution were high oxide ion conductors, the conductivities of which were about one order of magnitude higher than those of the well-known oxide ion conductors such as stabilized zirconias. In contrast to pure Bi2O3 which is a completely electronic conductor below 730°C, these materials showed high oxide ion conduction even below 700°C accompanied by little electronic conduction. 3Bi2O3 WO3 has the face centered cubic structure, probably of the fluorite type, and the oxide ion conduction was thought to be attributed to the migration of oxide ion vacancies in the crystal.
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    Journal of applied electrochemistry 3 (1973), S. 99-102 
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    Notes: Abstract The cathodic polarization characteristics of the electrode consisting of poly (4-vinylpyridine) bromine complex and graphite powder were investigated. The electrolyte was propylene carbonate containing 1 M LiBr. The rest potential of the electrode was approx. 0.5 V (versus SCE). The coulometric efficiency of the continuous discharge was 52–53%.
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    Journal of applied electrochemistry 3 (1973), S. 91-98 
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    Notes: Abstract The radial growth rate of crystalline areas during the anodization of tantalum is found to be related to the nature and concentration of both the solute and the solvent and also to the pH of the electrolyte. In general, the use of high solute concentrations or the addition of certain organic solvents produces reduced growth rates in aqueous electrolytes. Structural examinations indicate that for bright rolled tantalum foil of nominal purity 99.99%, the density of nucleation sites is approximately 107 cm−2, of which about 1% undergo active radial growth. The nucleation sites, which can be related to impurity inclusions, are believed to maintain contact with the electrolyte through narrow pores. As the amorphous oxide is rolled back by the growing crystals, a layer of relatively uniform thickness is stripped from the top surface of the crystalline area and remains in intimate contact with the detached amorphous oxide. The use of field crystallization to study the location and distribution of impurities at both exterior and interior surfaces of sintered powder anodes is described.
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    Journal of applied electrochemistry 3 (1973), S. 129-135 
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    Notes: Abstract A new type analog memory cell with variable output voltage has been proposed and its performance examined. The cell construction is $$\begin{gathered} {\text{Ag|RbAg}}_{\text{4}} {\text{I}}_{\text{5}} {\text{|(Ag}}_{\text{2}} {\text{Se)}}_{{\text{0}} \cdot {\text{925}}} {\text{(Ag}}_{\text{3}} {\text{PO}}_{\text{4}} {\text{)}}_{{\text{0}} \cdot {\text{075}}} {\text{|RbAg}}_{\text{4}} {\text{I}}_{\text{5}} {\text{|Ag}} \hfill \\ {\text{ }} \uparrow \hfill \\ {\text{ Pt}} \hfill \\ \end{gathered} $$ in which (Ag2Se)0.925(Ag3PO4)0.075 is a mixed conductor exhibiting high ionic and electronic conductivity at room temperature. The potential difference between the silver electrode and the platinum electrode depends on the silver activity in the mixed conductor, and it is changed by passing the current between one silver electrode and the platinum electrode. The output voltage of the cell is changed in the range of 150 to 0 mV. At open circuit, the memorized cell voltage decreased by only 1% over several hours.
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    Journal of applied electrochemistry 3 (1973), S. 137-141 
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    Notes: Abstract Dispersion-hardened nickel has been produced by electrodepositing Ni from a Watts' bath containing Al2O3, TiO2 and ZrO2 particles (0.005–0.06μm) in suspension. The effect of these particles on the onset of recrystallization at elevated temperatures (up to 1400°C) has been studied and it has been shown that Al2O3 is the most effective in stabilizing the electrodeposited structure. Thin films of Ni-Al2O3 examined by transmission electron microscopy showed a high dislocation density and restricted twinning, the Al2O3 particles being present both within the grains and at the grain boundaries. For optimum thermal stability the oxide should be present in the nickel matrix as discrete particles, but electron microscopy has shown that in all cases agglomeration occurs and that the particles are present as large clusters. Attempts to avoid this difficulty have proved unsuccessful.
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    Journal of applied electrochemistry 3 (1973), S. 17-22 
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    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Interfacial capacitance measurements have been used to study the effects of mercury on diamond polished copper, tin and zinc surfaces in 10M KOH. In the case of copper, microgram quantities of mercury were sufficient to inhibit the adsorption of hydrogen and reduce the surface heterogeneity. In contradistinction to copper, similar concentrations of mercury were found to increase the heterogeneity of tin and zinc surfaces. A decrease in surface heterogeneity for zinc was only observed at very high mercury concentrations. The increased surface heterogeneity is thought to arise from dissolution at the intercrystalline grain boundaries by mercury.
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    Journal of applied electrochemistry 3 (1973), S. 31-36 
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    Notes: Abstract Experiments in 6 N KOH at room temperature with air-zinc and air-cadmium cells show clearly that the anodes have an influence on the polarization of the porous air cathode. The electrolyte volume is also found to have an effect. At a constant load of 30 mA/cm2 the polarization curve for oxygen reduction at the air cathode was, depending on cell arrangement, shifted by up to about 150 mV in the direction of more negative values compared to that measured in the half-cell. Moreover, in some cases, this negative shift was followed by a smaller positive one. These effects are discussed in terms of the concentration of HO2 −-ions, which are produced by Berl's reaction mechanism, and of the potential and the surface state of the anode.
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    Journal of applied electrochemistry 3 (1973), S. 45-52 
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    Notes: Abstract Low faradaic yields of Pb were found when electrolysing melts containing PbSO4 in solvents of either LiCl-KCl eutectic or Li2SO4-K2SO4-Na4SO4 eutectic and employing low current densities. For all current densities employed, the decrease in current efficiency became greater as the lead sulphate concentration was increased but the influence of other sulphates was less pronounced. From studies of the reaction of lead with the melt and a chronopotentiometric study of cathodic processes, we have found the following two reactions occur: (a) Cathodic deposition of lead by the reversible reaction Pb2+ +2e⇌Pb (b) Secondary non-electrochemical reaction of the electrodeposit 4Pb+5PbSO4→PbS+4PbO.PbSO4 The rate of the latter reaction is sufficient to account for the lowering in current efficiencies. No evidence could be found to support direct reduction of the sulphate anion.
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    Journal of applied electrochemistry 3 (1973), S. 61-64 
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    Notes: Abstract The potentiostatic pulse method was used to study the electrochemical evolution of hydrogen on polycrystalline iron electrodes in concentrated KOH solutions. It was found that in pure KOH solutions there appeared to be two reaction mechanisms for hydrogen evolution, one at high the other at low overpotentials. The addition of Li+, at constant hydroxide ion concentration, altered the kinetic parameters of these two mechanisms. Furthermore in pure LiOH only one reaction mechanism for all overpotentials was observed.
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    Journal of applied electrochemistry 3 (1973), S. 73-75 
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    Journal of applied electrochemistry 3 (1973), S. 79-90 
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    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Materials exhibiting high ionic mobilities in the solid state at room temperature have mainly been found in the silver ion conductors which are based on silver iodide. Though silver iodide is a low conductivity solid at room temperature, it exhibits high ionic conductivity at relatively higher temperatures. In order to stabilize this high conductivity phase of silver iodide at room temperature, the introduction of foreign cations or anions into the lattice of silver iodide has been attempted. In this paper, the various silver ion high conductivity solids are reviewed, together with those showing both high ionic and electronic conductivity.
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    Journal of applied electrochemistry 3 (1973), S. 103-112 
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    Notes: Abstract The electrolysis of zinc chloride-sodium chloride mixtures to yield zinc and chlorine has been examined. The optimum electrolyte composition was found to extend from 75% to 60% zinc chloride. In order to obtain the maximum current and energy efficiencies, it was found necessary to use horizontal electrodes with perforations to allow easy escape of the electrolysis products.
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    Journal of applied electrochemistry 3 (1973), S. 113-121 
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    Notes: Abstract Three methods of approximation were developed to predict the metal distribution in electroplating systems. The results were compared with Watson's experimental data for the Watts-nickel (close to 100% current efficiency), tin-nickel (alloy deposition, also close to 100% current efficiency), and the standard chromium (approximately 20% current efficiency) systems. Method 1 predicted too uniform a distribution whereas Methods 2 and 3 showed good agreements with all three systems. The same experimental data were also used to evaluate three predictive methods frequently used in the literature. The primary current distribution and an empirical formula by Hull were found to be inadequate in describing these systems. The secondary current distribution which involved a great deal of numerical analysis showed a considerable improvement.
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    Journal of applied electrochemistry 3 (1973), S. 123-127 
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    Notes: Abstract Mercury cells of conventional design embody an elongated cathode, with a length which is a multiple of the width. For commercial cells installed to date this multiple is never less than 5 and for most models it is greater than 7. This elongated configuration has also been retained for cell sizes of highest current rating (up to 500 kA) and highest current density (up to 15 kA m−2) as allowed by activated titanium anodes. While being in conformity with tradition, such geometry, when applied to the largest cells, neglects some fundamental rules based on hydrodynamics. New requirements must in fact be fulfilled to obtain optimum mercury flow at the highest current capacities and the highest current densities that characterize the ultimate trend. When the length-to-width ratio is kept below the present typical range, the cell performance also improves because of a decrease of the harmful effects due to accumulation of mercury butter on the cathode surface.
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    Journal of applied electrochemistry 3 (1973), S. 143-151 
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    Notes: Abstract The electroreduction of difluorodichloromethane, CF2Cl2, has been studied at porous electrodes in LiCl-KCl eutectic. Tetrafluoroethylene is produced in high efficiency at low conversions; the reaction is believed to proceed via difluorocarbene. At high conversions carbon is a major product. In the presence of oxygen, trifluorochloromethane is also formed. Application of fuel cell electrodes to electrosynthesis of gaseous products from gaseous reagents is briefly discussed.
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    Journal of applied electrochemistry 3 (1973), S. ii 
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    Journal of applied electrochemistry 3 (1973), S. 161-167 
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    Notes: Abstract A method of input current shape synthesis, applied to the process of the electrodeposition of metals, is given. It is shown that the optimal control theory can be successfully applied to this kind of problem. Essentials of the mathematics of the method and the computer program flow chart are also given. Theory is checked using experiments on the electrodeposition of copper. The agreement between theoretical and experimental results is satisfactory.
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    Journal of applied electrochemistry 3 (1973), S. 169-177 
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    Notes: Abstract The electrical resistances, transference numbers and Li+↔Cu++ and Br−↔ClO 4 − interdiffusion rates through a variety of cation-exchange and neutral membranes were measured in propylene carbonate (PC) solutions at 25°C. Of the 19 commercial and specially prepared membranes which were studied, the only membranes with electrical resistances in 0.50m LiClO4/PC low enough to be of further interest as separators for organic electrolyte batteries were the AMF C-322, Amicon UM-05, Ionac MC-3470 and Corning No. 7930 porous glass (0.25 mm thick). The resistances of these membranes were 117, 2.3×102, 3.4×102 and 75.0 Ω, cm2, respectively. In order to benefit from the reduced resistance of thin membranes without sacrificing mechanical strength, laminated phenolsulfonic acid-formaldehyde (PF) membranes consisting of a thin layer of cation exchange resin on an inert porous support were prepared. Interdiffusion measurements showed that the laminated PF membranes are a more effective diffusion barrier towards anions in PC solutions than a commercial ultrafiltration membrane, the Amicon UM-05. The anion inter-diffusion fluxes for Br− between 0.10m LiBr/PC and 0.10m LiClO4/PC through the PF and UM-05 membranes were 6.17×10−11 and 1.5×10−10 mole s−1 cm2, respectively.
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