ALBERT

Description: Experimental observations on pathways of water movement are discussed in relation to anatomical and micromorphological features of five moss species from Signy Island, South Orkney Islands. Significant internal uptake of water was recorded only in the mesic species Polytrichum alpinum (internal=〉60% of total) and Bartramia patens (internal=c.30% of total), in experiments in which uptake by cut shoots was compared in individuals with the external pathway blocked, and others with both external and internal pathways open. Internal uptake maintained shoot water content close to full turgor in P. alpinun and at 30% of full tugor in B. patens, whereas water content fell to 12-15% dry wt. in the lithophytes Andreaea gainii and Schistidium antarctici and in the mesic/hydric species Drepanocladus uncinatus, with the external pathway blocked. Where both pathways were open water uptake from below maintained water content at or above full turgor in shoots of all five species. External water uptake by capillarity occurred most rapidly in the lithophytes, and was slower in initially air-dry than in hydrated shoots of the other species. The spreading limbs of leaves in B. patens and P. alpinum are water-repellent, as are the bright green leaves in the apical 1-2 mm of dry shoots of the lithophytes. A central strand of hydroids is well-developed only in B. patens and P. alpinum. These two species have deposits of surface wax on parts of the leaves, and surface wax also occurs on the green apical leaves in some specimens of S. antarcticum and other lithophytes from Signy Island.

Description: Laboratory experiments show that undercooling to about -5°C occurs in colonized Beacon sandstones of the Ross Desert, Antarctica. High-frequency temperature oscillations between 5°C and -5°C or -10°C (which occur in nature on the rock surface) did not damage Hemichloris antarctica. In a cryomicroscope, H. antarctica appeared to be undamaged after slow or rapid cooling to -50°C. l4CO2 incorporation after freezing to -20°C was unaffected in H. antarctica or in Trebouxia sp. but slightly depressed in Stichococcus sp. (isolated from a less extreme Antarctic habitat). These results suggest that the freezing regime in the Antarctic desert is not injurious to endolithic algae. It is likely that the freezing-point depression inside the rock makes available liquid water for metabolic activity at subzero temperatures. Freezing may occur more frequently on the rock surface and contribute to the abiotic nature of the surface.

Description: Cores, submarine photography and dredges described in this report were taken during the R/V Eltanin Cruise 5 in 1962 by the Department of Geology, Florida State University. Cores and dredges were recovered for 31 stations and are available at the Antarctic Research Facility, Florida State University for sampling and study.

Description: In May 1964 the Institute of Marine Science (University of Miami), Scripps Institution of Oceanography (University of California), Woods Hole Oceanographic Institution, and Lamont Geological Observatory (Columbia University) joined in the establishment of the JOINT OCEANOGRAPHIC INSTITUTIONS DEEP EARTH SAMPLING (JOIDES) program. The long range purpose of this organization is to obtain continuous core samples of the entire sedimentary column from the floors of the oceans. It was decided that initial efforts would be limited to water depths of less than 1000 fathoms (6000 feet), and tentative locations were selected for drilling operations off the eastern, western and Gulf coasts of the United States. Near the end of December 1964 it was found that the M/V Caldrill I, a drilling vessel capable of working to depths of 6000 feet, was to engage in drilling operations on the Grand Banks of Newfoundland during the summer of 1965 for the Pan American Petroleum Corporation. Thus it was agreed to organize a drilling program along the track of Caldrill between California and the Grand Banks. Selection was made of an area on the continental shelf and the Blake Plateau off Jacksonville, Florida. Based upon many previous geological and geophysical investigations by the participating laboratories, a considerable body of knowledge had been gained about this region of the continental-oceanic border. For this initial program of JOIDES, the Lamont Geological Observatory was chosen as the operating institution with J. L. Worzel as principal investigator, and C. L. Drake and H. A. Gibbon as program planners.

Description: Cores, submarine photography and dredges described in this report were taken during the R/V Eltanin Cruise 6 in 1963 by the Department of Geology, Florida State University. Cores and dredges were recovered for 32 stations along with bottom photography and are available at the Antarctic Research Facility, Florida State University for sampling and study.

Description: The technique of accelerator mass spectrometry (A.H.S.) has opened up a number of new potential geochronological applications of long lived cosmogenic nuclei- However the absence of any obvious stage leading to equilibrium between the radioactive and corresponding stable isotope(s) in the geochemical cycle of many of these species, complicates considerably their potential dating applications. The radioisotope 10Be (half-life 1.5 My) is formed by spallation reactions between cosmic rays and 14N, 16O in the atmosphere. It is transferred to the oceans in soluble form by precipitation and dry deposition. The 10Be et 16Al having similar chemical behaviours and being influenced by the same geophysical and geochemical phenomena before being incorporated into the marine sediments, their ratio is tested in order to date those sediments. This approach is also applied to manganese nodules and ferromanganese crusts.

Description: A German coring device (Reineck, 1958) has been improved to obtain oriented, undisturbed cores at any depth of water. The samples are rectangular in shape, 8 × 12 inches in plan and a maximum of 18 inches high. Good cores have been obtained from clayey material as well as from gravelly sand. No disturbances due to coring were observed on the collected samples. These large samples make it possible to conduct many varieties of investigations, such as study of living organisms and shear strength measurements, as soon as the sample is on deck of a ship; radiography on slices, peeling and impregnation techniques, granulometry, mineralogy, porosity, fossil content, etc. Construction and use of the box corer and applications of some of these analytical techniques are described.

Description: Based on chemical, spectrographic and X-ray analyses, 34 samples from the experimental Mohole consist of variable proportions of calcite (0-60 percent), biogenic opal (0-50 percent), and normal lithogenous matter (14-97 percent) with an average of 20, 32, and 48 percent, respectively. Contamination with trachytic ash, rhyolitic ash, and saponite and dolomite occurring as alteration products of basaltic material affects the composition of a few samples. Magnesium, manganese, and phosphorus seem to have been derived from basaltic material also. The amounts of barium in the samples seems to be inversely related to sedimentation rates.

Description: Pelagic sediment recovered at DOMES Site A in the equatorial North Pacific (151°W, 9° 15?N) consists of a surface homogeneous layer, approximately 10 cm thick, overlying a strongly mottled layer that is lighter in color. The radiolarian composition of both units is Quaternary. In areas where this sediment was only a few centimeters thick, the underlying sediment was early Tertiary. Clay mineralogy and major oxide composition of the two Quaternary sediments are uniform. Their similarity to continental shale suggests that the sediment has a terrigenous source. Clay mineralogy and major oxide composition of the Tertiary sediment also are uniform, although they differ markedly from the Quarternary sediment. In contrast to the major oxides, concentrations of Mn, Co, Cu, and Ni soluble in hydroxylamine hydrochloride-acetic acid are strongly different in the surface and subsurface Quaternary sediment. Mn and Ni exhibit pronounced depletions in the subsurface sediment, Ni slightly more than Mn. Cu is also depleted in the subsurface sediment, but less than Mn. It is also depleted in the subsurface Tertiary sediment, whereas the Mn concentration remains high. Concentration of Co relative to Mn increases into the subsurface Quaternary sediment to a constant Co:Mn ratio of 3 %. The trivalent REE (the REE exclusive of Ce) and Fe exhibit little down-core variation. Distribution of elements in these sediments is closely related to their concentration in associated surface ferromanganese nodules. The nodules are of two distinct types: those from the area where the Quaternary sediment is relatively thick have delta-MnO2 as the dominant manganese mineral. The ratios of Ni:Mn, Cu:Mn, and Fe:Mn in these nodules approximate the corresponding ratios of the soluble fraction of surface sediment. Todorokite is the dominant mineral of nodules recovered from areas where the Quaternary sediment is thin. Relatively high Cu/Mn, Ni/Mn, and low Fe/Mn ratios of these nodules mirror differences between the soluble fraction of surface and subsurface Quaternary sediment. These compositional trends of sediment and nodules at DOMES Site A reflect a diagenetic origin for the todorokite nodules and a predominantly hydrogenous origin for the delta-MnO2 nodules.

Description: The cores and dredges described in this report were taken on the DODO Expedition in May 1964 until December 1964 by the Scripps Institution of Oceanography from the R/V Argo. A total of 290 cores and dredges were recovered and are available at Scripps for sampling and study.

Description: Pelagic clay and Mn nodules from DOMES sites in the North Pacific and a varved glacial lake deposit from Connecticut were analysed for Os concentration and isotopic composition by isotope-dilution secondary ion mass spectrometry after treatment by NiS fusion or oxalic acid leaching. Bulk pelagic clay from DOMES site C has 187Os/186Os = 6.5 and Os = 0.14 ng/g. Oxalic acid leaches of this same sediment and of Mn nodules from DOMES sites A and C have more radiogenic 187Os/186Os ratios which average 8.3. Bulk glacial Lake Hitchcock sediment has 187Os/186Os = 12.5 and Os = 0.06 ng/g. The total Os flux to North Pacific pelagic clay is 7 to 10 ng Os/cm**2/10**6 y. Lake Hitchcock sediment provides an integrated value for the local crustal 187Os/186Os ratio. The oxalic acid leaches are assumed to attack hydrogenous phases selectively. A simple model in which the only sources of Os to the ocean are continental crust with the isotopic composition of Lake Hitchcock (187Os/186Os = 12.5) and extraterrestrial particles with 187Os/186Os = 1.1 results in a cosmic flux of osmium to the sediment of 4.9 ng Os/cm**2/10**6 y of which 20% is hydrogenous. A model in which the sources of Os to the ocean are continental crust with an 187Os/186Os ratio of 30 (from the model of Palmer and Turekian, 1986), oceanic mantle or crust with 187Os/186Os = 1.04 and extraterrestrial particles with 187Os/186Os = 1.1 results in a cosmic flux of Os to the sediment of 5.7 ng Os/cm**2/10**6 y of which none is hydrogenous. These extraterrestrial Os fluxes correspond to maximum C-1 chondrite accretion rates of between 4.9 × 104 and 5.6 × 104 tonnes/y.

Description: This report gives a comprehensive general description of the scientific activities of Cruise 2 of R. R. S. 'Discovery'. These were largely geological and geophysical and were part of the British contribution to the International Indian Ocean Expedition. In addition to the thirteen geophysicists and geologists on board, there were five scientists involved in ocean chemistry, temperature measurements and ornithology making continuous observations - their accounts are also included. The report of a geological expediton ashore in the Seychelles is given in section 6.

Description: A criterion is suggested for discrimination between ferromanganese oxide minerals, deposited after the introduction of manganese and associated elements in sea water solution at submarine vulcanism, and minerals which are slowly formed from dilute solution, largely of continental origin. The simlultaneous injection of thorium into the ocean by submarine vulcanism is indicated, and its differentiation from continental thorium introduced into the ocean by runoff is discussed.

Description: Prof. H. H. W. Menard has brought together nearly all that was known of the Pacific geology in the early 1960s. His book contains a particular chapter on manganese nodules giving a stimulating review of the features and processes known to govern their distribution and chemical composition.

Description: Late Cretaceous and younger sediments dredged from the upper continental slope and canyon walls in the Great Australian Bight Basin between 126° and 136°E broadly confirm the stratigraphy which had been established previously from scattered exploration wells. Late Cretaceous to Early Eocene marine and marginal marine terrigenous sediments are overlain by Middle Eocene and younger pelagic carbonate (fine limestone and calcareous ooze). The samples provide the first evidence of truly marine Maastrichtian sedimentation, with abundant calcareous nannoplankton, on the southern margin of the continent. Other samples of interest include Precambrian sheared granodiorite on the upper slope south of Eyre Terrace, Paleocene phosphatic sediment in 'Eucla' Canyon at 128° 30'E, and terrigenous Early Miocene mudstone at 133° 20' and 134° 50'E. The mudstone is of note as an exception to the uniform pelagic carbonate wackestone and ooze which characterise Middle Eocene and younger sedimentation at all other sites. Fragments of alkali basalt lava of unknown age were recovered in 'Eucla' Canyon. Cores are mostly pelagic calcareous ooze, but those from submarine canyons include terrigenous turbidites.

Description: This report gives a comprehensive general description of the scientific activities of Cruise 2 of R. R. S. 'Discovery'. These were largely geological and geophysical and were part of the British contribution to the International Indian Ocean Expedition. In addition to the thirteen geophysicists and geologists on board, there were five scientists involved in ocean chemistry, temperature measurements and ornithology making continuous observations - their accounts are also included. The report of a geological expediton ashore in the Seychelles is given in section 6.

Description: The cores and dredges described in this report were taken during the Robert Conrad Cruise 8 from November 1963 until August 1964 by the Lamont Geological Observatory, Columbia University from the R/V Robert Conrad. A total of 140 cores and dredges were recovered and are available at Lamont-Doherty Earth Observatory for sampling and study.

Description: We have generated approx. 300 Kyr records of biogenic opal, calcite, and organic carbon (Corg) for three cores in the eastern and central equatorial Pacific Ocean and have compared the records to determine whether common periods of biogenic sedimentation have occurred throughout the region. We find that Corg has been deposited in common pulses throughout the area, while opal has a much more local pattern of variation. Calcite varies regionally, but the record is shaped by superimposed dissolution and productivity processes. The most intense Corg peak occurs at 18 ka and can have greater than 2 times the Holocene Corg content. Other major Corg peaks occur 150 ka and perhaps at 280 ka. We have compared the Corg record in one of the cores, V19-28, to a model deepwater oxygen record developed from d13C data in the nearby V19-30 to test whether the Corg record has been mostly shaped by degradation or by the rain of organic matter from the euphotic zone. We found no coherence between the two records, implying that the Corg record is primarily a measure of productivity. By comparing the opal, calcite, and Corg records in V19-28, a core which is at or above the lysocline, we found that both increased calcite and opal deposition matches high Corg accumulation. We also found, however, that the calcite and opal records were uncorrelated, so that episodes of high opal deposition do not necessarily accumulate calcite rapidly. We hypothesize that at least two different plankton communities have been dominant in the waters above this site, one rich in opal-secreting plankton and one more dominated by calcite producers. The opal-rich plankton community was dominant during the intervals 10-15 ka and 35-60 ka.

Description: Material from the Deep Sea Drilling Project (DSDP) Site 527 from the Angola Basin, South Atlantic Ocean, has been analyzed to determine whether Upper Cretaceous benthonic foraminiferal taxa are differentially sensitive to calcite dissolution, and, if so, to rank their order of susceptibility. Two regimes of dissolution, established on the basis of the degree of planktonic foraminiferal fragmentation, representing stronger and less prominent dissolution within the section studied, were used as a framework for reference. A total of 60 calcareous and eight agglutinated benthonic foraminiferal taxa were identified at the species or genus level; of these, twenty-three calcareous and five agglutinated taxa were selected for the dissolution study. Relative abundance of each of the various taxa was tested statistically, using t-test, between dissolution regimes to assess the significance of the change induced by increased dissolution. Nuttallides truempyi and Neoeponides sp. intermediate form are interpreted as resistant to dissolution. Pullenia spp., Alabamina sp. a, Anomalina sp. a, Praebulimina sp. fusiform, and Nuttallinella sp. a are susceptible to dissolution. The majority of the taxa (16 in number) are unaffected by dissolution because they show no change between dissolution regimes. Among the agglutinated taxa Gaudryina pyramidata is resistant to dissolution, whereas the remaining four taxa are unaffected by dissolution. At the level of superfamilies, one calcareous superfamily (Discorbacea) is resistant, two (Orbitoidacea and Cassidulinacea) are unaffected, and two (Nodosariacea and Buliminacea) are susceptible to dissolution.

Description: It has been shown that in the Sevastopol Bay during the year primary production and chlorophyll "a" created by picoplankton (0.45-2.5 µm) consisted on the average 20-44% of total production. It was approximately a half of the level for oligotrophic waters of the ocean. Picoplankton of waters studied is represented by eucaryotes, cell diameter of which is, as a rule, about 2-3 µm. Contribution of the finest fraction of phytoplankton (0.43-0.85 µm) to primary production and con¬tent of chlorophyll "a" was insignificant (0-4%).

Description: The geochemistry of ferromanganese crusts and iron pisoliths from the Jurassic of Mallorca is investigated. The deposits are associated with Toarcian condensed sequences and hardgrounds which overlie Lower Lias platform limestones. Goethite is the principal mineral in the crusts and the pisoliths. which are both rich in iron; ramsdellite is the manganese phase in the ferromanganese crusts which contain 3-5% Mn. Inter-element relationships established by electron microprobe analysis show that P, V and perhaps Cr are sorbed with Fe, while Ni, Ti, Si and perhaps Ba and Co correlate positively with Mn. Submarine hydrothermal exhalations were the likely source of much of the material, though continental run-off waters probably contributed elements towards the growth of the ferromanganese crusts. Composition-depth curves suggest a gradual deepening of the drowned margin, though appear to over-estimate the depth of formation of the deposits. Deposition occurred on a limestone seamount on subsiding continental crust during the early rifting phase which preceded the opening of the Ligurian Tethys.

Description: A synoptic review of the studies of well-known occurrences of palagonite tuffs is presented. Included are palagonite tuffs from Iceland, and pillow-lava palagonite complexes from Columbia River basalts and from the central Oregon coast. Additional petrologic and x-ray defraction data for selected samples are presented. Petrologic evidence shows that basaltic glass of aqueous tuffs and breccias consists of sideromelane, which is susceptible to palagonitization. It is shown that palagonitization is a selective alteration process, involving hydration, oxidation and zeolitization. Some of the manganese nodules dredged from the Pacific Ocean floor contain nucleus of palagonite-tuff breccias or of zeolite. A brief megascopic and microscopic description of nodules from the south Pacific, the Mendocino ridge and the 'Horizon' Nodule from the north Pacific is presented. Petrographic studies of palagonite-tuff breccias of manganese nodules and other palagonites suggest that migration and segregation of metallic elements occur during and subsequent to palagonitization. During the palagonitization of sideromelane, nearly 30 percent of sea water is absorbed. The hydration of sideromelane is also accompanied by oxidation of iron and other elements. These oxides may be released either in colloidal form or in true solution and tend to precipitate first from the unstable palagonite.

Description: This collection of data on manganese nodules on the floor of the Pacific Ocean represents all the information that was available to the authors in May, 1964. It is compiled from both published references and original data. No attempt is made here to generalize or to speculate on the origin of the manganese or associated elements further discussion of these aspects of the subject may be had by reference to the literature.

Description: One the most interesting features of ocean sedimentation is the manganese formations on the surface of the ocean floor in some areas. These are especially widespread in the Pacific Ocean as concretions, grains, and crusts on rock fragments and bedrock outcrops. Iron-manganese concretions are the most abundant as they completely cover about 10% of the bottom of the Pacific Ocean where there are ore concentrations. The concretions occupy from 20-50% of the bottom and up to 80-90% on separate submarine rises. Such concretions are found in different types of bottom deposits, from abyssal red clays to terrigenous muds, but they occur most widely in red clays and quite often in carbonate muds. Their shape and their dimensions are very diverse and change from place to place, from station to station, varying from 0.5-20 cm. They may be oval, globular, reniform, or slaggy and often they are fiat or isometric concretions of an indefinite shape. The concretions generally have nuclei of pumice, basalt fragments, clayey and tuffaceous material, sharks' teeth, whale ossicles, and fossil sponges. Most concretions have concentric layers, combined with dendritic ramifications of iron and manganese oxides.

Description: The ostracoda fauna recovered from site 95, JOIDES leg 10, consists of Albian and Senonian species, some of which have previously been described from the southeastern United States. These are Cytherella aff. bullata, Brachycythere acuminata, B. cf. crenulata, Hazelina austinensis, Phacorabdotus texanus, Cythereis cf. caudata, Fossocytheridea cf. lenoirensis, and the following species referred to in open nomenclature: Neocythere? sp. 19, Aversovalva? sp. and Paracypris spp. The stratigraphic and paleoecological data derived from the study of this fauna are compared with those based on planktonic foraminifers and nannofossils.

Description: As a test of the reliability of paleocean ventilation rates reconstructed from radiocarbon age differences between planktonic and benthic foraminifera, measurements have been made on coexisting species of planktonic foraminifera. While ideally no differences should exist, we do find them. In this paper we discuss the possible causes for these differences and attempt to evaluate their impact on the interpretation of benthic-planktonic age differences.

Description: On the shelf and upper slope off Peru the signal of coastal upwelling productivity and bottom-water oxygen is well preserved in alternately laminated and bioturbated diatomaceous Quaternary sediments. Global sea-level fluctuations are the ultimate cause for these cyclic facies changes. During late Miocene time, coastal upwelling was about 100 km west of the present centers, along the edge of an emergent structure that subsequently subsided to form the modern slope. The sediments are rich in organic carbon, and intense microbially mediated decomposition of organic matter is evident in sulfate reduction and methanogenesis. These processes are accompanied by the formation of diagenetic carbonates, mostly Ca-rich dolomites and Mg-calcites. The downhole isotopic signatures of these carbonate cements display distinct successions that reflect the vertical evolution of the pore fluid environment. From the association of methane gas hydrates, burial depth, and low-chloride interstitial fluids, we suggest an additional process that could contribute to the characteristic chloride depletion in pore fluids of active margins: release of interlayer water from clays without a mineral phase change. The shelf sediments also contain a subsurface brine that stretches for more than 500 km from north to south over the area drilled. The source of the brine remains uncertain, although the composition of the oxygen isotopes suggests dissolution of evaporites by seawater.

Description: Site 639, drilled during Leg 103 of the Ocean Drilling Program, penetrated an Upper Jurassic to Lower Cretaceous carbonate platform on a tilted fault block along the Galicia margin off the northwest Iberian Peninsula. The carbonate platform is composed primarily of a sequence of dolomite overlying limestone. Samples were analyzed for mineral chemistry, stable isotope geochemistry, fluid inclusion microthermometry, and volatile contents and by dolomite pyrolysis mass spectrometry for trace sulfate minerals. The dolomite recovered from the Galicia margin at Site 639 formed during shallow burial from sulfate-bearing, hypersaline brines at slightly elevated temperatures. The light oxygen isotopic signatures of the dolomite are interpreted as the result of the evaporative loop and slightly elevated temperatures during dolomite formation or from reequilibration at higher temperatures during deeper burial. The hypersalinity is interpreted to be associated with a nearby, shallow restricted basin that formed during rifting of the Iberian margin from Newfoundland. The dolomitization of the platform is therefore a by-product of the rifting.

Description: The Galicia margin lies northwest of the Iberian Peninsula and is a passive ocean margin with thin sedimentary cover. Altered peridotite was recovered from ODP Site 637, on the north-trending ridge at the western edge of the margin, near the oceanic/continental crust boundary. The altered ultramafics were originally clinopyroxene-rich upper mantle harzburgites and are now extensively serpentinized (〉85%) and cut by very late-stage carbonate veins. Despite pervasive late, low-temperature alteration, evidence of early, high-temperature alteration remains. Alteration is apparent as (1) amphibole rims on clinopyroxene (〉800°C), (2) hornblende + tremolite (450° to 800°C), (3) breakdown of hornblende to form tremolite + chlorite (〈450°C), (4) zoned Cr-spinels, (5) hydration of orthopyroxene and olivine to serpentine, (6) serpentine veins, (7) replacement of pyroxene and olivine by calcite, and (8) calcite veins and vugs. Both the relict igneous and the high-temperature alteration minerals (amphiboles) show evidence of brittle deformation. Subsequent low-temperature alteration veins and minerals are deformed only in faulted and brecciated zones. This textural evidence suggests that the low-temperature alteration occurred after emplacement of the ultramafics at the surface. Serpentine fills tension fractures in orthopyroxene, and both serpentine and calcite fill tension cracks in olivine. The high-temperature alterations in these samples are similar to those found in oceanic fracture zone and ophiolite ultramafics. This widespread occurrence of high-temperature alteration suggests that hot fluids were pervasive in these ultramafic blocks. Localization of high-temperature alteration close to large carbonate veins suggests channelization of the late, low-temperature fluids. Earlier hydrations (e.g., high-temperature alterations and serpentinization) were pervasive.