ALBERT

Description: Igneous rocks were recovered from three sites on Hess Rise during Deep Sea Drilling Project Leg 62: altered basalt at Site 464, at the northern end of Hess Rise; and altered trachyte from Site 465, and rounded basalt pebbles in upper Albian to middle Miocene sediments from Site 466, both at the southern end of Hess Rise. Major-, minor-, and trace-element data for basalt from Hole 464 are consistent with these rocks being transitional tholeiites that have undergone low-temperature alteration by reaction with sea water. Trachyte from Hole 465A exhibits as many as three generations of plagioclase along with potash feldspar that are flow aligned in groundmasses alterted to smectites and random mixed-layer clays. Textural evidence indicates that these rocks were eruped subaerially. Chemical data show a range of values when plotted on two- and three-component variation diagrams. The observed variations may result in part from differentiation, but they also reflect the high degree of alteration. Several oxides and elements show strong correlation with H2O+: K2O, SiO2, Rb and Lu decrease and MgO increases with increasing H2O+. These trends, except for that of Lu, are consistent with experimentally determined changes in chemistry that accompany alteration. The trend for Lu has not been previously reported; it may result from a more-intense alteration of the HREE-rich mafic minerals than of the LREE-rich feldspars. Despite their alteration, the trachytes compare favorably with alkalic differentiates from oceanic islands. We interpret Hess Rise as a volcanic platform formed by eruption of off-ridge volcanic rocks onto MORB oceanic crust during the Aptian and Albian stages, after the basement had migrated away from the spreading center. By analogy with present oceanic islands, we propose that early tholeiitic basalts were followed by alkalic basalts and their differentiation products (trachytes), producing a volcanic archipelago of islands and seamounts. Subsequent tectonism and subsidence led to the present state of Hess Rise.

Description: Atomic-absorption spectrophotometry and instrumental neutron activation analysis were used to determine concentrations of SiO2, Al2O3, FeOt, MgO, CaO, Na2O, K2O, MnO, La, Ce, Sm, Eu, Tb, Yb, Lu, Sc, Co, Cr, Th, Hf, and Ta for 14 basalt samples from the lower portion of Hole 462A in the Nauru Basin. The basalts are similar to normal midocean ridge basalt (MORB) for the elements analyzed, and light rare-earth elements (LREE) are depleted relative to heavy rare-earth elements (HREE). Two samples are extensively altered to smectites and show significant reductions in Al2O3, CaO, MnO, Na2O, REE, Sc, Co, and Hf and gains in MgO and FeOt relative to unaltered samples. The increase in MgO and decrease in CaO indicate that alteration was caused by hydrothermal solutions.

Description: At Deep Sea Drilling Project (DSDP) Site 462, from mudline to 447 meters below the sea floor, Cenozoic nannofossil oozes and chalks have acoustic anisotropies such that horizontal sonic velocities are 0 to 2.5% faster than those in the vertical direction. In laminated chalk, anisotropy of 5% is typical, and in limestones, radiolarian oozes, porcellanites, and cherts, the anisotropies range from 4 to 13%. Middle Maestrichtian volcaniclastics from 447 meters to 560 meters below the sea floor have an acoustic anisotropy of 2 to 32%; 4 to 13% is typical. Basalt flows and sills occur between 560 meters and 1068 meters, and have no apparent anisotropy, but minor interbedded volcaniclastics have anisotropies from 0 to 20% (5% is typical). These volcaniclastics frequently have very small anisotropies, however, compared with the volcaniclastic sequence above the basalt section. Data in cross-plots of the laboratory-measured compressional sound velocity versus wet-bulk density, wet-water content, and porosity of sediments and sedimentary rock typically lie between the equations derived by Wyllie et al. (1956) and Wood (1941); the Wyllie et al. (1956) equation has a fair fit with similar basalt velocity cross-plots. Crossplots of thermal conductivity and sound velocity indicate only a fair correlation. Cross-plots of thermal conductivity versus porosity, wet-water content, and wet-bulk density correlate well with equations derived by Maxwell (1904), Ratcliff (1960), Parasnis (1960), and Bullard and Day (1961). Electrical formation factor versus porosity for sediments and sedimentary rock agrees with the Archie (1942) equation, with m values of 2.6; for basalt, an m of about 2.1 is typical. Basalt pore-water resistivities do not appear to be greatly different from sea water. Formation factors are greater than those derived from equations in Maxwell (1904), Winsauer et al. (1952), Boyce (1968), and Kermabon et al. (1969). An "apparent interstitial water resistivity" (Rwa) curve was derived from the density and induction logs. This Rwa curve indicated an anomaly, at 393.5 to 396.5 meters, which could be interpreted as (1) 76% hydrocarbons, (2) relatively fresh pore water (1.8 per mil salinity), or (3) low-grain-density (2.2 g/cm**3) semi-lithified porcellanite-chert. Porcellanite-chert is the most plausible interpretation. In situ temperatures measured by the Uyeda temperature probe were about 2 to 5°C (50%) higher than the equilibrium temperature (Lachenbruch and Brewer, 1959) extrapolated from two Gearhart-Owen continuous temperature logs; this discrepancy probably arises because the hole was washed out in this depth interval, so these extrapolated temperatures are probably not reliable. If one ignores all precautions as to temperature artifacts, then the equilibrium temperatures of the Gearhart-Owen temperature logs suggest that hydrothermal circulation is occurring in at least the upper 40 meters of the basalt section and heat is transferred by convection and not conduction. Hydrothermal circulation is probably not indicated, however, and the temperature anomalies probably result from excessive artificial cooling of the fractured basalt zones by circulation of water during drilling.

Description: The stratigraphic position of the glacially transported 'Scholle' (large-size erratic block) at Schobüll near Husum (Schleswig-Holstein) is now considered to be Devonian rather than 'Rotliegendes'. The 'Scholle', consisting of red clay and dolomite, is overlain by red-colored till without any flint but with up to 90% carbonate clasts (containing 15% dolomite), which indicates an eastern Baltic origin. The relationship of the 'Scholle' with the glacial till also points to an eastern Baltic origin for it, with up to 1 000 km transport distance.

Description: Ferromanganese nodules in the deep-sea and in freshwater lakes usually accrete layers rich in manganese oxides alternating with layers rich in iron oxides. The mechanism producing these alternating layers is unknown; indeed, the mechanism producing the nodules themselves is unknown. In Oneida Lake, New York, precipitants from the lake water and the surfaces of nodules at the sediment-water interface are enriched in Mn, whereas nodules buried in lake sediments have surface layers enriched in Fe. It is hypothesized here, using field and laboratory evidence, that reduction and mobilization of Mn from the nodule surface during periods of anoxic sediment cover produce the high Fe layers observed in the nodules.

Description: Since 1954 the Blake Plateau has interested the geophysical group at Woods HOle. Early cruises gathered data on this region incidental to other work. It became apparent that the area was worthy of more intense study. Questions about the bathymetry and underlying structure had been raised. This is a report of the most recent cruise undertaken to study the northern portion of the Plateau. It is intended to summarize the data collected and to be useful as art aid to investigators in preparation of manuscripts for publication.

Description: Cores, submarine photography and dredges described in this report were taken during the R/V Eltanin Cruise 5 in 1962 by the Department of Geology, Florida State University. Cores and dredges were recovered for 31 stations and are available at the Antarctic Research Facility, Florida State University for sampling and study.

Description: This report is Volume 3 of Descriptions of WHOI rock dredge samples. This series represents a major effort to catalog the rock dredge samples in the WHOI Sea Floor samples collection, and to disseminate this information throughout the scientific community. Volume 3 contains sample descriptions and station data for the dredge stations from five cruises during the period September 1978 through December 1980. The material in this and subsequent volumes of rock descriptions was largely prepared onboard ship by the participating scientists. Volume 3 was printed prior to volumes 1 and 2 because of the excellent documentation of the samples represented in this volume.

Description: The minor-element composition of concentric layers within a single ferromanganese nodule from the eastern North Pacific exhibits strong correlations with Fe and Mn contents but appears to be independent of pronounced mineralogic variations. On the basis of these correlations, the elemental composition of individual layers apparently is controlled by the relative contribution of two sources: seawater, and interstitial water of associated sediment. In contrast, the mineralogy of the nodule, consisting of birnessite in the outer few layers and todorokite in the inner layers, is considered to be a function of nodule diagenesis.

Description: In May 1964 the Institute of Marine Science (University of Miami), Scripps Institution of Oceanography (University of California), Woods Hole Oceanographic Institution, and Lamont Geological Observatory (Columbia University) joined in the establishment of the JOINT OCEANOGRAPHIC INSTITUTIONS DEEP EARTH SAMPLING (JOIDES) program. The long range purpose of this organization is to obtain continuous core samples of the entire sedimentary column from the floors of the oceans. It was decided that initial efforts would be limited to water depths of less than 1000 fathoms (6000 feet), and tentative locations were selected for drilling operations off the eastern, western and Gulf coasts of the United States. Near the end of December 1964 it was found that the M/V Caldrill I, a drilling vessel capable of working to depths of 6000 feet, was to engage in drilling operations on the Grand Banks of Newfoundland during the summer of 1965 for the Pan American Petroleum Corporation. Thus it was agreed to organize a drilling program along the track of Caldrill between California and the Grand Banks. Selection was made of an area on the continental shelf and the Blake Plateau off Jacksonville, Florida. Based upon many previous geological and geophysical investigations by the participating laboratories, a considerable body of knowledge had been gained about this region of the continental-oceanic border. For this initial program of JOIDES, the Lamont Geological Observatory was chosen as the operating institution with J. L. Worzel as principal investigator, and C. L. Drake and H. A. Gibbon as program planners.

Description: Compositional data for coexisting manganese nodules, micronodules, sediments and pore waters from five areas in the equatorial and S.W. Pacific have been obtained. This represents the largest study of its type ever undertaken to establish the distribution of elements between the various phases within the sediment column. The composition of manganese nodules, micronodules and sediments (on a carbonate-free basis) shows marked differences between the equatorial high productivity zone and the low productivity region of the S.W. Pacific. In the case of the nodules, th is reflects an increased supply of transition elements (notably Ni, Cu and Zn) to the nodules as a result of the in situ dissolution of siliceous tests within the sediment column in the equatorial Pacific high productivity zone. Micronodules display similar, but somewhat different, compositions to those of the associated nodules in each area. Micronodule composition is therefore influenced by the same basic factors that control nodule composition, but is modified by dissolution of the micronodules in situ within the sediment column. Locally, as in the area immediately south of the Marquesas Fracture Zone, the micronodule population is contaminated by small, angular volcanic rock fragments; this leads to apparently anomalous micronodule compositions. Micronodules appear to be a transient feature in the sediment column, especially in the equatorial Pacific. Dissolution of micronodules in the sediment column therefore represents an important source of elements for the growth of manganese nodules in the equatorial Pacific. Sediment composition is markedly influenced by the carbonate content. On a carbonate-free basis, the sediments from the equatorial high productivity zone are quite distinct in composition from those in the S.W. Pacific. This reflects differences in the lithology of the sediments. In the Aitutaki Passage, the local influence of volcanoclastic material in sediment composition has been established. The major cations and anions in pore waters measured here show no major differences between equatorial and S.W. Pacific sediments. Silica is, however, higher in equatorial Pacific pore waters reflecting the dissolution of siliceous tests in these sediments.

Description: Cores, submarine photography and dredges described in this report were taken during the R/V Eltanin Cruise 6 in 1963 by the Department of Geology, Florida State University. Cores and dredges were recovered for 32 stations along with bottom photography and are available at the Antarctic Research Facility, Florida State University for sampling and study.

Description: Initial data on the hydrogen-isotopic compositions in hydrous Mn minerals from various occurrences fall in a wide range from -298 to -84 per mil, relative to SMOW. DeltaD-values of todorokite and cryptomelane from Tertiary deposits show -89 and -150 per mil. 10 Angström-manganite and Delta-MnO2 from deep-sea nodules have relatively restricted DeltaD-values ranging from -96 to -84 per mil. The DeltaD-values for manganese bog ores from recent hot springs show almost -105 per mil. It is recognized that the isotopic values obtained for the deep-sea nodules and recent bog ores are slightly different ranged. Manganite and groutite are unique in their hydrogen-isotopic compositions, having the most depleted DeltaD-values ranging from -298 to -236 per mil. MnO(OH) minerals are more deuterium-depleted hydrous minerals than any other hydrothermal minerals from various ore deposits. Hydrogen-isotope fractionation factors between manganite and water were experimentally determined to be 0.7894, 0.7958 and 0.8078 at 150°, 200° and 250°C, respectively. the present experimental results indicate that if manganites were formed at temperatures below 250°C, under isotopic equilibrium conditions, most of the manganite mineralization in the Tertiary manganese deposits must have precipitated from meteoric hydrothermal solutions.

Description: This report is Volume 1 in the series of reports entitled "Descriptions of W.H.O.I. rock dredge samples". This series represents a major effort to catalog and prepare initial descriptions for all rock dredge samples in the W.H.O.I. Sea Floor Samples Collection, and to distribute this information throughout the scientific community. Volume 1 contains sample descriptions from approximately 382 dredging stations executed during the period 1960 through 1977. It also represents a digitized listing of all dredge station data for the entire W.H.O.I. Dredge Collection through 1980. This data is sorted by Marsden Square and can serve as a regional index for all rock descriptions included in Volumes 1-3.

Description: A submersible study has been conducted in February - March 1978 at the axis of the East Pacific Rise near 21°N. The expedition CYAMEX, the first submersible program to be conducted on the East Pacific Rise, is part of the French-American-Mexican project RITA (Rivera - Tamayo), a 3-year study devoted to detailed geological and geophysical investigations of the East Pacific Rise Crest. On the basis of the 15 dives made by CYANA in the axial area of the Rise, a morphological and tectonic zonation can be established for this moderately-fast spreading center. A narrow, 0.6 to 1.2 km wide zone of extrusion (zone 1), dominated by young lava flows, is flanked by a highly fissured and faulted zone of extension (zone 2) with a width of 1 to 2 km. Further out, zone 3 is dominated by outward tilted blocks bounded by inward-facing fault scarps. Active or recent faults extend up to 12 km from the axis of extrusion of the East Pacific Rise. This represents the first determination from direct field evidence of the width of active tectonism associated with an accreting plate boundary. Massive sulfide deposits, made principally of zinc, copper and iron, were found close to the axis of the Rise. Other signs of the intense hydrothermal activity included the discovery of benthic fauna of giant size similar to that found at the axis of the Galapagos Rift. We emphasize the cyclic character of the volcanicity. The main characteristics of the geology of this segment of the East Pacific Rise can be explained by the thermal structure at depth below this moderately-fast spreading center. The geological observations are compatible with the existence of a shallow magma reservoir centered at the axis of the Rise with a half-width of the order of 10 km.

Description: Of numerous island-arc systems in the western Pacific, the Mariana arc-trench system and the basins and submerged ridges lying west of them in the Philippine Sea seemed to be best suited to answer questions regarding arc-trench and back-arc basin formation. Three years of planning by the JOIDES Active Margin Panel, Ocean Crust Panel, and Planning Committee resulted in a proposed transect of drill sites aligned more or less along the 18th parallel. This South Philippine Sea transect was designed to investigate each major basin and ridge between the central part of the West Philippine Sea and the Mariana Trench and the Pacific Ocean plate immediately to the east.

Description: The goal of Site 462 was to study the paleontologic, sedimentary, petrologic, tectonic, and magnetic histories of that area through Recent to Late Jurassic time by drilling a deep re-entry site into the Nauru Basin west of the Ralik Chain of the Marshall Islands. This area formed at a fast-spreading Pacific Plate boundary 145 to 155 m.y. ago, in the Late Jurassic. Cores from this area allow to better understand the biostratigraphic evolution and sedimentary processes in a Mesozoic open-ocean environment, the petrologic nature of fast-spreading oceanic crust, the tectonic history of the Late Jurassic Pacific Plate, and the nature of the Jurassic magnetic quiet zone.

Description: The four sites drilled during Leg 62 were needed to establish better regional coverage of the North Pacific Ocean. Although paleoenvironments were to be stressed on Leg 62, studies of igneous rocks from acoustic basement were planned, to determine ages, petrogenesis, alteration effects, rock magnetism, and Paleomagnetism of old parts of the Pacific crust. These studies were emphasized in order to establish the early history of oceanic plateaus and whether they are the result of midocean-ridge or intraplate volcanism.

Description: A primary objective of Leg 63 was to investigate the fluctuations of this eastern boundary current along a north-south transect off the Gulf of California. This information would aid in biostratigraphically correlating open-ocean planktonic zones with local California zonations. Spanning the last 30 m.y., the complicated tectonic history of the continental margin off California and Baja California comprises changes from a subduction zone to a transform boundary and then to an inactive margin. A second objective of Leg 63 was to define and clarify this history using information on sedimentation, unconformities, basement ages, and paleomagnetic reconstructions gained from drilling, in conjunction with geophysical data and pre-existing bottom samples.

Description: Undamaged deep-sea manganese nodules were retrieved from a box core from the central North Pacific and quickly preserved in formaldehyde solution. Light and scanning electron microscope studies of the nodule surface reveal the presence of a variety of fragile filamentous and coccoid bacterial morphotypes, associated with an organic film that covers the botryoid surface.

Description: A German coring device (Reineck, 1958) has been improved to obtain oriented, undisturbed cores at any depth of water. The samples are rectangular in shape, 8 × 12 inches in plan and a maximum of 18 inches high. Good cores have been obtained from clayey material as well as from gravelly sand. No disturbances due to coring were observed on the collected samples. These large samples make it possible to conduct many varieties of investigations, such as study of living organisms and shear strength measurements, as soon as the sample is on deck of a ship; radiography on slices, peeling and impregnation techniques, granulometry, mineralogy, porosity, fossil content, etc. Construction and use of the box corer and applications of some of these analytical techniques are described.

Description: Based on chemical, spectrographic and X-ray analyses, 34 samples from the experimental Mohole consist of variable proportions of calcite (0-60 percent), biogenic opal (0-50 percent), and normal lithogenous matter (14-97 percent) with an average of 20, 32, and 48 percent, respectively. Contamination with trachytic ash, rhyolitic ash, and saponite and dolomite occurring as alteration products of basaltic material affects the composition of a few samples. Magnesium, manganese, and phosphorus seem to have been derived from basaltic material also. The amounts of barium in the samples seems to be inversely related to sedimentation rates.

Description: The unusual petrological diversity of abyssal lavas erupted along some segments of the Galapagos spreading center is a direct consequence of the propagation (elongation) of these segments into older oceanic crust. With increasing distance behind propagating rift tips, relatively unfractionated MORB erupted close to the tips are joined first by FeTi basalts (bimodal assemblage) and then by a wide range of basaltic and siliceous lavas. Further behind propagating rift tips, this broad range diminishes again, approaching the narrow compositional range of adjacent normal ridge segments. These compositional variations reflect the evolution of the subaxial magmatic system beneath the newly forming spreading center as it propagates through a pre-existing plate. We envisage this evolution as proceeding from small, isolated, ephemeral magma chambers through increasing numbers of larger, increasingly interconnected chambers to the steady-state buffered system of a normal ridge. Throughout this evolution, magma supply rates gradually increase and cooling rates of crustal magma bodies decrease. High degrees of crystal fractionation are favored only when a delicate balance between cooling rate and resupply rate of primitive magma is achieved. At other propagating and non-propagating ridge-transform intersections the degree to which the balance is achieved and the length of ridge over which it evolves control the distribution of fractionated lavas. These effects may be evaluated provided a number of tectonic variables including transform length, spreading and propagation rates are taken into account.

Description: The southernmost part of the Sohm Abyssal Plain in the Northwest Atlantic Basin is geographically distal with respect to the major source of Quaternary terrigenous material transported from the Canadian Maritime Provinces. An assessment of the proportion of more locally introduced sediment relative to that derived from distal sources is based largely on size and compositional analyses of Quaternary piston core samples. These data are supplemented by radiocarbon dating of selected core samples, bottom photographs, conductivity-temperature-depth profiles, and seismic records. The premises of the study are that (a) locally derived sediment should be most abundant near high-relief bathymetric features such as seamounts and abyssal hills, and (b) such material should contain enhanced proportions of reworked volcanic debris and alteration products. Core analyses reveal that the amounts of these are directly related to proximity of volcanic ocean-bottom features, and that a significant, although not total, amount of such volcanic materials recovered from cores are derived from submarine weathering of basalt. Associated with this assemblage are nannofossils, dating from the Quaternary to the Upper Cretaceous, reworked from older strata. This increased proportion of volcanic and related products and reworked faunas near seamounts and basement rises strongly implies that such topographic features continue to serve as major source terrains. Locally derived volcanic materials, however, are usually disseminated and masked on the Sohm Abyssal Plain, particularly in sectors receiving large amounts of terrigenous turbidites and biogenic suspensates, and/or undergoing reworking by bottom currents. We propose that the volcanic fraction can serve as a useful index, or "yardstick," to interpret the role of locally derived material in abyssal plain sedimentation. A sedimentation model is developed to illustrate the premise that as access to land-derived sources diminishes, the proportion of terrigenous components is reduced while pelagic and volcanic fractions are enhanced. Thus, sediment accumulating in abyssal plains almost totally isolated from terrigenous sources would comprise significant amounts of pelagic (including wind-blown) and volcanic components.

Description: Nine nodules collected from throughout the deep North Pacific were analyzed for their mineralogy and major-element composition before and after leaching with Chester-Hughes solution. Data indicate that the mineral phillipsite accounts for the major part (〉 75%) of the aluminosilicate fraction of all nodules. It is suggested that formation of phillipsite takes place on growing nodule surfaces coupled with the oxidation of absorbed manganous ion. All the nodules could be described as ternary mixtures of amorphous iron fraction (Fe-Ti-P), manganese oxide fraction (Mn-Mg Cu-Ni), and phillipsite fraction (Al-Si-K-Na), these fractions accounting for 96% of the variability of the chemical composition.

Description: The cores and dredges described in this report were taken on the DODO Expedition in May 1964 until December 1964 by the Scripps Institution of Oceanography from the R/V Argo. A total of 290 cores and dredges were recovered and are available at Scripps for sampling and study.

Description: Crusts composed of nontronite and ferromanganese oxides were recovered from Explorer Ridge, a spreading ridge segment in the northeastern Pacific Ocean located off the west coast of Canada. The chemical and mineralogical composition of the crusts closely resembles that of the mound-like hydrothermal deposits recently discovered at the FAMOUS site on the Mid-Atlantic Ridge and on the Galapagos spreading centre. Compositional anomalies suggest that the crusts are precipitates of hydrothermal vent solutions which were ejected discontinuously and subsequently mixed with seawater.

Description: Submersible exploration on the eastern Pacific Ridge near 21 ° N has revealed an active hydrothermal system. It is manifested by the emission in the marine environment of hot and Highly mineralized fluids (370 ° C maximum). These fluids precipitate on contact with seawater and deposits of massive sulphides are built at the outlet of their sources. The mineralogical and geochemical study of the products associated with the emissions of hot fluids provides an initial evaluation of this type of deposit and leads to a comparison between the hydrothermalism responsible for the formation of sulphides and the hydrothermalism responsible for the formation of metal rich crusts formed of iron smectites and manganese oxides. This study is carried out with conventional mineralogical and geochemical investigations (optical and electronic microscopy, X-ray diffraction, X-ray fluorescence spectrometry, electron microprobe, neutron activation and mass spectrometry).

Description: This report gives a comprehensive general description of the scientific activities of Cruise 2 of R. R. S. 'Discovery'. These were largely geological and geophysical and were part of the British contribution to the International Indian Ocean Expedition. In addition to the thirteen geophysicists and geologists on board, there were five scientists involved in ocean chemistry, temperature measurements and ornithology making continuous observations - their accounts are also included. The report of a geological expediton ashore in the Seychelles is given in section 6.

Description: A criterion is suggested for discrimination between ferromanganese oxide minerals, deposited after the introduction of manganese and associated elements in sea water solution at submarine vulcanism, and minerals which are slowly formed from dilute solution, largely of continental origin. The simlultaneous injection of thorium into the ocean by submarine vulcanism is indicated, and its differentiation from continental thorium introduced into the ocean by runoff is discussed.

Description: Prof. H. H. W. Menard has brought together nearly all that was known of the Pacific geology in the early 1960s. His book contains a particular chapter on manganese nodules giving a stimulating review of the features and processes known to govern their distribution and chemical composition.

Description: This report gives a comprehensive general description of the scientific activities of Cruise 2 of R. R. S. 'Discovery'. These were largely geological and geophysical and were part of the British contribution to the International Indian Ocean Expedition. In addition to the thirteen geophysicists and geologists on board, there were five scientists involved in ocean chemistry, temperature measurements and ornithology making continuous observations - their accounts are also included. The report of a geological expediton ashore in the Seychelles is given in section 6.

Description: The cores and dredges described in this report were taken during the Robert Conrad Cruise 8 from November 1963 until August 1964 by the Lamont Geological Observatory, Columbia University from the R/V Robert Conrad. A total of 140 cores and dredges were recovered and are available at Lamont-Doherty Earth Observatory for sampling and study.

Description: The cores and dredges described in this report were taken during the Vema 17 Expedition from December 1960 until October 1961 by the Lamont Geological Observatory, Columbia University from the R/V Vema. An approximate total of 210 cores, dredges and camera stations were recovered and are available at Lamont-Doherty Earth Observatory for sampling and study.

Description: The sulfide deposit at Site 471 occurs between overlying pelagic sediment and underlying basalt. The deposit is vertically zoned and consists, from top to bottom, of the following mineral assemblages: (1) pyrite, chalcopyrite, and Zn-sulfide in chert and calcite gangue (~ 35 cm thick); (2) a 5-cm-thick metalliferous sediment layer and (3) a 4-cm-thick chert layer. The calcite gangue appears at a later stage than chert gangue in the sequence of deposition, also filling in voids and fractures. The manganese content of calcite is particularly high and varies systematically, reaching a maximum at the top of the massive sulfide portion of the deposit.

Description: Elevated regions in the central parts of ocean basins are excellent for study of accumulation of eolian material. The mass-accumulation rates of this sediment component appear to reflect changes in the influx of volcanic materials through the Early Cretaceous to Recent history of Deep Sea Drilling Project Site 463, on the Mid-Pacific Mountains. Four distinct episodes of eolian accumulation occurred during the Cretaceous: two periods of moderate accumulation, averaging about 0.2 to 0.3 g/cm**2/10**3 yr, 67 to 70.5 m.y. ago and 91 to 108 m.y. ago; a period of low accumulation, approximately 0.03 g/cm**2/10**3 yr, 70.5 to 90 m.y. ago; and a period of high accumulation, about 0.9 g/cm**2/10**3 yr, 109 to 117 m.y. ago (bottom of the hole). Much of the Cenozoic section is missing from Site 463. Upper Miocene to Recent sediments record an upward increase in accumulation rates, from less than 0.01 to about 0.044 g/cm**2/10**3 yr. The late Pliocene-Pleistocene peak may reflect the change to glacial-wind regimes, as well as an increase in volcanic source materials.

Description: Neogene palynofloras of southern California have been all too infrequently studied. Previous investigations of Pacific Coast sediments have been largely restricted to Pacific Northwest locales. Some important studies include those by Gray (1964), Wolfe, Hopkins, and Leopold (1966), Wolfe and Leopold (1967), Hopkins (1968), Piel (1969, 1977), Ballog, Sparks, and Waloweek (1972), and Musich (1973). The only published study of southern California materials is that of Heusser (1978) on Holocene sediments of the Santa Barbara basin. Most of these studies are concerned with the microflora from a particular formation; thus they have limited stratigraphic value and in most cases involve nonmarine to marginal marine rocks where no planktonic zonation was available. Musich's (1973) study was the first attempt at tying pollen assemblages to a planktonic zonation over an extended stratigraphic interval (Miocene to Pleistocene).Its location in the southern California Borderland and the sedimentary sections sampled make Leg 63 extremely valuable in deciphering the palynologic history of the Pacific Coast Neogene. Site 467 was chosen for our initial detailed study, because the relatively slow sedimentation rate provides an almost complete Neogene sequence of mainly terrigenous sediments and reliable planktonic age control is available.The goals of this study were to: (1) establish a reference section of Neogene palynomorph assemblages; (2) develop biostratigraphic criteria for use in correlation with other localities; (3) correlate the palynologic assemblages with the planktonic zonations; and (4) study the paleoenvironmental history in the southern California Neogene.

Description: From 1950 through 1900 studies on the glacial geology of northern Greenland have been made in cooperation with the U.S. Air Force Cambridge Research Laboratories. As a result of these studies four distinct phases of the latest glaciation have been recognized. The last glaciation extended over most of the land and removed traces of previous anes. Retreat of the ice mass began some time previous to 6000 years ago. This was followed by a rtse in sea level which deposited clay-silt succeeded by karne gravels around stagnant ice lobes in the large valleys. Marine terraces, up to 129 meters above present sea level, developed as readjustment occurred in the land free of ice. About 3700 years ago an advance of glaciers down major fjords took place followed by retreat to approximately the present position of the ice. Till in Peary Land, north of Frederick E. Hyde Fjord, contains only locally derived matertals indicating that the central Greenland ice cap did not cover the area.

Description: Chemical analyses are presented for two Cretaceous clays from Noil Tobee, Timor. Mineralogical examination has shown that they consist principally of quartz, feldspar, illite and chlorite, together with minor amounts of montmorillonite. Both chemically and mineralogically the clays are very similar to the recent argillaceous deep-sea sediments of the Pacific and Indian Oceans, which confirms Molengraaff's theory (1921) that they are of deep-sea origin. Further confirmation of this theory is provided by comparison of the composition of micromanganese nodules, separated from one of these clays, with that of manganese nodules from the Pacific Ocean.

Description: The cores and dredges described at this site were taken on the SAFARI II cruise from 21 July until 1 September 1981 by the MusÈum National d'Histoire Naturelle from the R/V Marion Dufresne. A total of 65 cores, dredges and camera stations were recovered and are available at MNHN for sampling and study.

Description: Various manganese nodules donated to the Scripps Institution of Oceanography from the Hakurei Maru Cruise GH77-1, January-March, 1977, in the Central Pacific Basin have been analysed for their lithium content by J. Korkish from the Institute of Analytical Chemistry, Analysis of Nuclear Raw Materials Division, University of Vienna, Austria. The author has used a Perkin-Elmer atomic-absorption spectrometer 303 after speration by dissolution in hydrochloric acid.

Description: The vast extent of pelagic deposits, covering about 70 per cent of the ocean floor, thus about half of the earth, makes them of obvious importance to all Earth Science. All the pelagic (eupelagic) sediments, whether largely of plankton remains or fine inorganic particles, have certain distinctive characteristics to reflect their environment of accumulation. The great segregation of manganese in pelagic sediments presents many problems. It is hypothesized that in the formation of present day nodules a relatively slow accumulation in order to permit deposition of more of the manganese as large nodules, rather than as the disseminated micronodules that are in larger proportion in the Tertiary.

Description: A synoptic review of the studies of well-known occurrences of palagonite tuffs is presented. Included are palagonite tuffs from Iceland, and pillow-lava palagonite complexes from Columbia River basalts and from the central Oregon coast. Additional petrologic and x-ray defraction data for selected samples are presented. Petrologic evidence shows that basaltic glass of aqueous tuffs and breccias consists of sideromelane, which is susceptible to palagonitization. It is shown that palagonitization is a selective alteration process, involving hydration, oxidation and zeolitization. Some of the manganese nodules dredged from the Pacific Ocean floor contain nucleus of palagonite-tuff breccias or of zeolite. A brief megascopic and microscopic description of nodules from the south Pacific, the Mendocino ridge and the 'Horizon' Nodule from the north Pacific is presented. Petrographic studies of palagonite-tuff breccias of manganese nodules and other palagonites suggest that migration and segregation of metallic elements occur during and subsequent to palagonitization. During the palagonitization of sideromelane, nearly 30 percent of sea water is absorbed. The hydration of sideromelane is also accompanied by oxidation of iron and other elements. These oxides may be released either in colloidal form or in true solution and tend to precipitate first from the unstable palagonite.

Description: New information on possible resource value of sea floor manganese nodule deposits in the eastern north Pacific has been obtained by a study of records and collections of the 1972 Sea Scope Expedition. Nodule abundance (percent of sea floor covered) varies greatly, according to photographs from eight stations and data from other sources. All estimates considered reliable are plotted on a map of the region. Similar maps show the average content of Ni, Cu, Mn and Co at 89 stations from which three or more nodules were analyzed. Variations in nodule metal content at each station are shown graphically in an appendix, where data on nodule sizes are also given. Results of new analyses of 420 nodules from 93 stations for mn, fe, ni, cu, CO, and zn are listed in another appendix. Relatively high Ni + Cu content is restricted chiefly to four groups of stations in the equatorial region, where group averages are 1.86, 1.99, 2.47, and 2.55 weight-percent. Prepared for United States Department of the Interior, Bureau of Mines. Grant no. GO284008-02-MAS. - NTIS PB82-142571.

Description: Basal metalliferous sediments from sites 77B, 80 and 81 of the Deep Sea Drilling Project represent mixtures of pelagic clay, biogenic ooze, and a metalliferous component of hydrothermal origin. The metalliferous end-member of the sediments displays a strong inverse relationship (r = -0.88) between Mg and Mn. Mg is most likely tied up in an X-ray amorphous Mg-silicate ("sepiolite"), whereas Mn occurs almost exclusively in an oxide phase. Precipitation of the Mg-rich phase is favored by high flow rates and limited mixing of the hydrothermal end-member (source of silica) with seawater (source of Mg). Under those conditions much of the hydrothermal Mn(2+), with its slow oxidation kinetics, may escape to the free water column. In contrast, in highly-diluted hydrothermal fluids, which provide a source solution for Mn-rich sediments, dissolved silica is diluted below saturation with respect to "sepiolite". The separation of the Mn and Mg phases may be further compounded by hydraulic fractionation.

Description: This collection of data on manganese nodules on the floor of the Pacific Ocean represents all the information that was available to the authors in May, 1964. It is compiled from both published references and original data. No attempt is made here to generalize or to speculate on the origin of the manganese or associated elements further discussion of these aspects of the subject may be had by reference to the literature.

Description: We report here chemical analyses of sulfide and other minerals occurring in the massive sulfide deposit cored at Site 471. Details of the mineralogy and inferred paragenesis of the deposit will be reported elsewhere. The sulfide deposit at Site 471 occurs between overlying pelagic sediment and underlying basalt. The deposit is vertically zoned and consists, from top to bottom, of the following mineral assemblages: (1) pyrite, chalcopyrite, and Zn-sulfide in chert and calcite gangue (about 35 cm thick); (2) a 5-cm-thick metalliferous sediment layer described in detail by Leinen (this volume); and (3) a 4-cm-thick chert layer. The overlying sediment is a calcareous silty claystone that contains middle Miocene coccoliths (Bukry, this volume). The underlying basalt has been extensively chloritized and veined with calcite. In places feldspars are albitized, and calcite occurs as pseudomorphs after olivine. Relict textures suggest that the basalt grades into diabase and gabbro with increasing depth. Neither stock work nor disseminated sulfides was observed in the altered rocks.

Description: The investigation of the sediments at the bottom of a lake provides a record of past geologic and climatic events that have influenced the lake and its associated drainage basin. The most recent sediments of a lake are indicators of man's impact on the surrounding watershed and emphasize the complex nature of interaction between chemical, biological, and physical processes that affect the distribution of sediments and their associated minerals and chemical species. The conclusions of this report are based on samples and measurements obtained during an extensive research cruise conducted in Lake Michigan by the Canada Survey Ship Limnos in August, 1975. Grab samples were collected at the intersections of a 12-by-12-km Universal Transverse Mercator (UTM) grid over most of the lake bottom; a more detailed 7-by-7-km UTM grid was used in Green Bay and in the northeastern corner of the lake. Systematic chemical analysis was performed on the sediment samples over 23 elements. In Green Bay, elevated levels of a number of chemical elements in the sediments - notably arsenic, barium, manganese, and iron - suggest that a local geochemical process or source is important. One possible explanation is that ferromanganese nodules or concretions were observed in surface sediments from a number of locations in Green Bay and extreme northwestern Lake Michigan.

Description: One the most interesting features of ocean sedimentation is the manganese formations on the surface of the ocean floor in some areas. These are especially widespread in the Pacific Ocean as concretions, grains, and crusts on rock fragments and bedrock outcrops. Iron-manganese concretions are the most abundant as they completely cover about 10% of the bottom of the Pacific Ocean where there are ore concentrations. The concretions occupy from 20-50% of the bottom and up to 80-90% on separate submarine rises. Such concretions are found in different types of bottom deposits, from abyssal red clays to terrigenous muds, but they occur most widely in red clays and quite often in carbonate muds. Their shape and their dimensions are very diverse and change from place to place, from station to station, varying from 0.5-20 cm. They may be oval, globular, reniform, or slaggy and often they are fiat or isometric concretions of an indefinite shape. The concretions generally have nuclei of pumice, basalt fragments, clayey and tuffaceous material, sharks' teeth, whale ossicles, and fossil sponges. Most concretions have concentric layers, combined with dendritic ramifications of iron and manganese oxides.

Description: A compilation of chemical analyses of Pacific Ocean nodules using an x-ray fluorescence technique. The equipment used was a General Electric XRD-5 with a tungsten tube. Lithium fluoride was used as the diffraction element in assaying for all elements above calcium in the atomic table and EDDT was used in conjunction with a helium path for all elements with an atomic number less than calcium. Flow counters were used in conjunction with a pulse height analyzer to eliminate x-ray lines of different but integral orders in gathering count data. The stability of the equipment was found to be excellent by the author. The equipment was calibrated by the use of standard ores made from pure oxide forms of the elements in the nodules and carefully mixed in proportion to the amounts of these elements generally found in the manganese nodules. Chemically analyzed standards of the nodules themselves were also used. As a final check, a known amount of the element in question was added to selected samples of the nodules and careful counts were taken on these samples before and after the addition of the extra amount of the element. The method involved the determination and subsequent use of absorption and activation factors for the lines of the various elements. All the absorption and activation factors were carefully determined using the standard ores. The chemically analyzed samples of the nodules by these methods yielded an accuracy to at least three significant figures.

Description: On a cruise from the eastern into western Mediterranean Sea in November/December 1978 a total of 126 samples were collected from 8 vertical profiles and 7 coastal stations for trace metal analysis. The sampling, processing and analysis was performed under strict "clean room" conditions. The concentration of the open-sea samples are close to oceanic results gathered under similar conditions. The grand averages from all profiles (± st. dev. of the individual samples) of 0.40 ± 0.16 µg/l Zn, 17.4 ± 7.4 ng/l Cd, 0.21 ± 0.07 µg/l Cu, 0.21 ± 0.13 µg/l Mn and 0.25 ± 0.09 µg/l Fe indicate that a "metal problem" does not exist in the open Mediterranean. A biologically mediated deplition in surface waters or correlation with nutrients have not been observed under the conditions established on this cruise. This is probably due top low primary production and seasonal advection processes prevailing in this sea. The data for manganese show generally higher values in the surface layer (0-75 m) than in deep waters. This could evidently proved in the nearshore profile indicating a terrigenous source for manganese.