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  • Articles  (78,588)
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  • 1
    ISSN: 1089-7666
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: PHF online publishes articles that emphasize understanding of the physics underlying modern technology. The subject coverage includes, but is not limited to, experimental or theoretical physics applied to all aspects of materials: for example, charge and mass transport, superconductivity magnetism; surfaces, interfaces, thin films, crystal lattice defects; electrical, optical, magnetic, and structural properties; processing; ion implantation. Materials covered include semiconductors, superconductors, metals and alloys, amorphous materials, and oxides.
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  • 2
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    Amsterdam : Elsevier
    Nuclear Physics, Section B 373 (1992), S. 3-34 
    ISSN: 0550-3213
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
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  • 3
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    Amsterdam : Elsevier
    Nuclear Physics, Section B 386 (1992), S. 471-492 
    ISSN: 0550-3213
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
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  • 4
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    Amsterdam : Elsevier
    Physics Letters B 294 (1992), S. 466-478 
    ISSN: 0370-2693
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
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  • 5
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    Amsterdam : Elsevier
    Physics Letters B 289 (1992), S. 199-210 
    ISSN: 0370-2693
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
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  • 6
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    Amsterdam : Elsevier
    Physics Letters B 274 (1992), S. 230-238 
    ISSN: 0370-2693
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
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  • 7
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    Stochastic environmental research and risk assessment 6 (1992), S. 1-2 
    ISSN: 1436-3259
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering , Geography , Geosciences
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  • 8
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    Stochastic environmental research and risk assessment 6 (1992), S. 5-25 
    ISSN: 1436-3259
    Keywords: Solute transport ; Heterogeneity ; Dispersion
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering , Geography , Geosciences
    Notes: Abstract Macrodispersion is spreading of a substance induced by spatial variations in local advective velocity at field scales. Consider the case that the steady-state seepage velocity and the local dispersion coefficients in a heterogeneous formation may be modeled as periodic in all directions in an unbounded domain. The equations satisfied by the first two spatial moments of the concentration are derived for the case of a conservative non-reacting solute. It is shown that the moments can be calculated from the solution of well-defined deterministic boundary value problems. Then, it is described how the rate of increase of the first two moments can be calculated at large times using a Taylor-Aris analysis as generalized by Brenner. It is demonstrated that the second-order tensor of macrodispersion (or effective dispersion) can be computed through the solution of steady-state boundary-value problems followed by the determination of volume averages. The analysis is based solely on volume averaging and is not limited by the assumption that the fluctuations are small. The large-time results are valid when the system is in a form of equilibrium in which a tagged particle samples all locations in an appropriately defined “phase space” with equal probability.
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  • 9
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    Stochastic environmental research and risk assessment 6 (1992), S. 89-101 
    ISSN: 1436-3259
    Keywords: Detention storage ; Pollution control ; Non-point pollutant runoff
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering , Geography , Geosciences
    Notes: Abstract A simple expression is presented on the capability of storage-treatment systems to reduce non-point pollutant runoff load to natural waters. Their efficiency depends on the capacities of the facilities and probabilistic properties of runoff, such as interval, duration, volume, and concentration of runoff events. Assuming the compound Poisson process for runoff time series, the exact expressions of the ratio of treated load in terms of storage and treatment capacities are theoretically derived on the neighbourhoods of all boundaries of the domain on which the problem is defined. Then, an approximate expression over the whole domain is presented, of which the value and the first-order derivative coincide with those of the exact derived expressions near the boundaries. Accuracy is checked by Monte Carlo simulations.
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  • 10
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    Stochastic environmental research and risk assessment 6 (1992), S. 55-68 
    ISSN: 1436-3259
    Keywords: Drought severity ; Drought duration ; Renewal-reward process
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering , Geography , Geosciences
    Notes: Abstract This research study focused on the hypothesis that extreme drought and high streamflow events come from different independent populations with different probability distributions which need to be studied separately, rather than considering the streamflow population as a whole. The inability of traditional streamflow generator models to consistently reproduce the frequency of occurrence of severe droughts observed in the historical record has been questioned by many researchers. Our study focused on the development of astochastic event generator model which would be capable of doing so. This was accomplished in a two-step process by first generating the drought event, and then deriving the streamflows which comprised that event. The model considered for this analysis was an alternating renewal-reward procedure that cycles between eventon andoff times, and is representative of drought or high streamflow event duration. The reward gained while the event ison oroff represents drought severity or high streamflow surplus. Geometric and gamma distributions were considered for drought duration and deficit respectively. Model validation was performed using calculated required capacities from the sequent peak algorithm.
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  • 11
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    Stochastic environmental research and risk assessment 6 (1992), S. 103-121 
    ISSN: 1436-3259
    Keywords: Probabilistic model ; Sensitivity ; Contaminant transport
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering , Geography , Geosciences
    Notes: Abstract A reliability approach is used to develop a probabilistic model of two-dimensional non-reactive and reactive contaminant transport in porous media. The reliability approach provides two important quantitative results: an estimate of the probability that contaminant concentration is exceeded at some location and time, and measures of the sensitivity of the probabilistic outcome to likely changes in the uncertain variables. The method requires that each uncertain variable be assigned at least a mean and variance; in this work we also incorporate and investigate the influence of marginal probability distributions. Uncertain variables includex andy components of average groundwater flow velocity,x andy components of dispersivity, diffusion coefficient, distribution coefficient, porosity and bulk density. The objective is to examine the relative importance of each uncertain variable, the marginal distribution assigned to each variable, and possible correlation between the variables. Results utilizing a two-dimensional analytical solution indicate that the probabilistic outcome is generally very sensitive to likely changes in the uncertain flow velocity. Uncertainty associated with dispersivity and diffusion coefficient is often not a significant issue with respect to the probabilistic analysis; therefore, dispersivity and diffusion coefficient can often be treated for practical analysis as deterministic constants. The probabilistic outcome is sensitive to the uncertainty of the reaction terms for early times in the flow event. At later times, when source contaminants are released at constant rate throughout the study period, the probabilistic outcome may not be sensitive to changes in the reaction terms. These results, although limited at present by assumptions and conceptual restrictions inherent to the closed-form analytical solution, provide insight into the critical issues to consider in a probabilistic analysis of contaminant transport. Such information concerning the most important uncertain parameters can be used to guide field and laboratory investigations.
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  • 12
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    Stochastic environmental research and risk assessment 6 (1992), S. 191-207 
    ISSN: 1436-3259
    Keywords: Hydrodynamic dispersion ; Fokker-Planck equation ; backward equation ; boundary layer ; complex potential function ; fraction of contaminated particles that enter a well
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering , Geography , Geosciences
    Notes: Abstract In this paper we describe the transport of pollution in groundwater in the neighbourhood of a well in a uniform background flow. We compute the rate at which contaminated particles reach the well as a function of the place of the source of pollution. The motion of a particle in a dispersive flow is seen as a random walk process. The Fokker-Planck equation for the random motion of a particle is transformed using the complex potential for the advective flow field. The resulting equation is solved asymptotically after a stretching transformation. Finally, the analytical solution is compared with results from Monte Carlo simulations with the random walk model. The method can be extended to arbitrary flow fields. Then by a numerical coordinate transformation the analytical results can still be employed.
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  • 13
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    Stochastic environmental research and risk assessment 6 (1992), S. 255-269 
    ISSN: 1436-3259
    Keywords: Emprical Orthogonal Functions ; interpolating runoff ; kriging
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering , Geography , Geosciences
    Notes: Abstract The method of Empirical Orthogonal Functions (EOF method) is combined with an objective interpolation technique, kriging, to generate runoff series at ungauged locations. In a case study the results are compared to series interpolated by a combination of EOF analysis and regression using catchment characteristics as independent variables. The results are also compared to linear weighting of an existing runoff series, a commonly used method for spatial interpolation. The influence of altitude on the runoff is studied comparing kriging based on 2 and 3 coordinates. The study showed that the capacity of EOF analysis combined with kriging is as good as the traditionally used linear weighting. The results, when altitude is included in the kriging, are improved.
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  • 14
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    Stochastic environmental research and risk assessment 6 (1992), S. 270-288 
    ISSN: 1436-3259
    Keywords: Periodicities ; hydraulic cycle ; spectral methods
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering , Geography , Geosciences
    Notes: Abstract Periodicites in hydrologic data are frequently estimated and studied. In some cases the periodic components are subtracted from the data to obtain the stochastic components. In other cases the physical reasons for the occurrence of these periodicities are investigated. Apart from the annual cycle in the hydrologic data, periods corresponding to the 11 year sunspot cycle, the Hale cycle and others have been detected. The conclusions from most of these studies depend on the reliability and robustness of the methods used to detect these periodicities. Several spectral analysis methods have been proposed to investigate periodicities in time series data. Several of these have been compared to each other. The methods by Siddiqui and Wang and by Damsleth and Spjotvoll, which are stepwise procedures of spectrum estimation, have not been evaluated. Two of the methods of spectral analysis proposed by Siddiqui and Wang and by Damsleth and Spjotvoll are investigated in this study by using generated and observed data. Siddiqui and Wang's method is found to be superior to the Damsleth and Spjotvoll's method.
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  • 15
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    Stochastic environmental research and risk assessment 6 (1992), S. 289-303 
    ISSN: 1436-3259
    Keywords: Stream flow series ; shot-noise model ; sadolle-point approximation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering , Geography , Geosciences
    Notes: Abstract In this paper we consider the shot-noise model of streamflow series. We show how design discharge can be obtained by the stochastic intensity of thinned Poisson processes describing the peaks over a threshold. The main result concerns the stationary distribution of peaks. We derive an explicit expression for this limit distribution in terms of its Laplace transform. Approximation formulas are developed making use of the saddle point method for the asymptotic evaluation of contour integrals and the Post-Widder formula for inversion of Laplace transforms. We illustrate this methods on the case of Gamma-distributed shots. The stationary peak distribution is used to approximate the maximum value distribution for larger time intervals.
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  • 16
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    Meteorology and atmospheric physics 47 (1992), S. 107-115 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary A number of cut-off processes are investigated, with the Alpine region in most cases lying at the margins of these upper lows. Our aim was to determine whether the thermal front parameter (TFP) can be used to objectively define the areas of bad weather from analysis charts and prognostic charts. An attempt is made to formulate two synoptic “guidelines”, for the eastern Alpine region, on front-sides and northern margins of upper lows, into objective synoptic rules.
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  • 17
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    Meteorology and atmospheric physics 47 (1992), S. 127-144 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary This study examined ECMWF operational analyses of the outflow layer of two tropical cyclones (Allen, 1980; Elena, 1985) during their passage across the Atlantic and Caribbean. Wind fields and related derived quantities were compared to those from objective analyses of specialized data sets. Errors in center position and storm motion from the ECMWF analyses were also evaluated. Analyses of wind and angular momentum flux in 1985, subsequent to upgrading of the operational model, were superior to those from 1980. High-resolution, uninitialized analyses from 1985, however, provided no advantages over lower resolution, initialized analyses for the same time period. For all ECMWF analyses, azimuthally averaged (mean) tangential velocity, and thus mean vorticity, were well represented. Mean radial velocity and mean divergence were poorly represented. Problems with the latter arose primarily due to underestimation of outflow, especially in the 1980 analyses. Azimuthaleddy fluxes of angular momentum in the ECMWF analyses quantitatively differed from but qualitatively resembled, the control analyses. Vorticity maxima at 850 mb in the operational analyses most accurately defined the center position of the storms, with a mean error less than or equal to one grid point. In contrast, surface pressure minima failed to provide reliable estimates. Over open ocean and at early stages of storms, analysis quality was uneven, with occasional large position errors and widely varying locations of vorticity maxima in the vertical. Nevertheless, in regions surrounded by even a few rawinsondes, such as the Caribbean or Gulf of Mexico, ECMWF analyses contained sufficient information to allow individual case studies of the tropical cyclone environment. In the same regions, estimates of the eddy flux convergence of angular momentum were found to be accurate enough to aid in operational hurricane intensity prediction. Enhancements in resolution and model initialization at ECMWF since 1985 should further improve operational analyses of the tropical cyclone environment.
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  • 18
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    Meteorology and atmospheric physics 47 (1992), S. 205-227 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary This paper describes the evolution of two thunderstorms which developed over northeastern Colorado on 23 July 1983, and more significantly discusses the possible causal relationship between them. In particular, a disturbance apparently created by the first thunderstorm, which developed over the eastern slopes of the Rocky mountains, seems to have triggered the second thunderstorm, which developed further east over the high plains. We present evidence that suggests that the disturbance is a rapidly propagating gravity wave (possibly a solitary wave of depression) that occupied most of the troposphere and was generated by the explosive convective development of the first thunderstorm. Detailed observations of the interactions between these two storms were possible because both storms developed over a dense network of automated weather stations that provided high temporal and spatial resolution surface measurements of pressure, temperature, precipitation, and horizontal wind velocity. Also located within this mesonetwork was a high power 915 MHz wind profiler that provided radial velocities throughout most of the troposphere. These measurements were supplemented with GOES visible and infrared satellite imagery and operational data from National Weather Service rawinsondes and weather radars.
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  • 19
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    Meteorology and atmospheric physics 47 (1992), S. 237-245 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary Problems of turbulent dissipation of a cold air lake (CAL) and the inversion layer bordering CAL on the upper boundary are presented and studied with the compound model. In wintertime such cold air lakes can persist for days even if rather strong winds are blowing above them. The required conditions for CAL dissipation are removed processes of its formation or maintenance, as well as a sufficiently strong invasion of turbulence in the inversion layer from above down-wards. By this, the inversion layer at first becomes stronger and dissipation is stopped, until the increase of turbulent kinetic energy of the upper flow enables further dissipation. Such turbulent dissipation process is shown by the model for typical conditions and for different initial values of the relevent variables.
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  • 20
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    Meteorology and atmospheric physics 47 (1992), S. 259-265 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary THETAPLOT is a diagram useful for the display and analysis of atmospheric thermodynamic soundings, particularly in relation to conditionally and convectively instable summertime weather situations. The basic coordinates of THETAPLOT are the equivalent potential temperature and the negative logarithm of pressure. The body of the diagram contains families of curves of constant potential temperature, mixing ratio and temperature. From any given sounding, three curves are plotted on the diagram: 1) Theta-ed, the equivalent potential temperature of air saturated at its dew point temperature; 2) Theta-e, equivalent potential temperature; and 3) Theta-es, the saturated equivalent potential temperature. The winds are plotted along the margin of the diagram.
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  • 21
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    Meteorology and atmospheric physics 49 (1992), S. 187-207 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary This paper is concerned with the simulation of deep convection for the CCOPE 19 July 1981 case study. Clark's three-dimensional (3D) cloud model modified to use the bulk water parameterization scheme of Lin et al. has been used in the simulation of the CCOPE 19 July 1981 case in coarse mesh, fine mesh, and interactive grid nested schemes, respectively. Comparisons with observations show this 3D grid nested cloud model is capable of both capturing both the dynamic and microphysical properties of the cloud. In the nested grid fine mesh model simulation, the timing and mode of cloud growth, the diameter of liquid cloud, the cloud top rate of rise, the maximum cloud water content, and the altitude of first radar echo are consistent with observations. The simulated thunderstorm begins to dissipate, after precipitation reaches the ground as indicated by the decreasing values of maximum updraft and maximum liquid cloud water content, and ends as a precipitating anvil as was observed in the actual thunderstorm. The model precipitation developed through ice phase processes consistent with the analysis of observations from the actual thunderstorm. Qualitative comparisons of the actual radar RHIs with simulated reflectively patterns from the 3D model show remarkable similarity, especially after the mature stage is reached. Features of the actual RHI patterns, such as the weak echo region, upshear anvil bulge, strong upwind reflectivity gradients, and the upwind outflow region near the surface are reproduced in the simulation. Comparison of the actual radar PPIs with horizontal cross sections of radar reflectivity simulated by the 3D model, however, show modest differences in the storm size with the 3D simulated thunderstorm being 1–2 km longer in the west-east direction than the actual thunderstorm. The model-predicted maximum updraft speed is smaller than the 2D model-predicted maximum updraft speed, but still greater than what was observed. Comparisons among the nested grid fine mesh model (MB), nested grid coarse mesh model (MA), fine mesh model (FM), coarse mesh model (CM), and 2D model results previously published show that the nested grid fine mesh model (MB) gives the best simulation result. The various 3D model simulation results are generally similar to each other except for the difference in the domain maximum values. The domain maximum values in the fine mesh models (MB and FM) are generally higher than the coarse mesh models as a result of averaging over a smaller area.
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  • 22
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary The Penn State University/National Center for Atmospheric Research (PSU/NCAR) mesoscale model is a widely used research tool that has been applied in a wide variety of real-data, mesoalpha-scale applications. Recently a nonhydrostatic version of this model has been developed by Dudhia (1993). It is the purpose of this paper to illustrate the capabilities of this modeling system by describing four examples of mesobeta-scale simulations: two of the cases involve maritime processes and two deal with continental weather events. All utilize fully three-dimensional sets of initial conditions that are based on real data, both standard data and from special measurements programs. One case employs the model in a data-assimilation configuration, wherein Newtonian relaxation terms are used in the equations to assimilate data from a variety of platforms. This example of nonhydrostatic four-dimensional data assimilation (FDDA) is performed for the purpose of generating a dynamically consistent four-dimensional data-set, however the same procedure can be used for model initialization. The first case, described in section 2, involves the simulation of a coastal front that forms offshore near the western edge of the Gulf Stream. In the second case, described in section 3, the model is used in the FDDA mode to define the mesobeta-scale windfield over the complex terrain of the region around Grand Canyon, Arizona. In sections 4 and 5 will be described the mesobeta-scale structure of cold fronts, one within a marine cyclone, and another near the Rocky Mountains.
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  • 23
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary Hydrostatic and nonhydrostatic simulation models are employed to study the intensification of a terrain drag-induced dryline. The study develops a multi-stage theory for the evolution of the dryline including the concentration of potential vorticity accompanying meso-gamma scale dryline “bulges”. The numerical simulations indicate three fundamental stages of dryline intensification all of which are either directly or indirectly a result of the terrain-drag on the mid/upper-tropospheric jet stream by the Front Range of the Colorado Rocky Mountains. The first stage involves the downward momentum flux accompanying a large amplitude hydrostatic mountain wave which induces a downslope windstorm along the lee slopes. The surge of momentum (i.e., the dry, warm air associated with the downslope windstorm) propagates down the leeslope and modifies an existing weak dryline boundary. As the downslope windstorm initiates an undular bore along the lee slopes, the high momentum gradient which propagates downstream accompanying the bore, as well as the strong lower tropospheric sinking motions ahead of the bore, contract the scale of the surface moisture boundary between the dry air from above the leeslope and the moist air over the High Plains. This process further strengthens the dryline. The second stage involves the coupling of the terrain drag-induced along-stream ageostrophic front within the midtroposphere to the boundary layer through a thermally-indirect circulation. As the along-stream ageostrophic circulation intensifies within the middle troposphere down-stream from the mountain wave, sinking air parcels originating above 40 kPa descend to below 60 kPa over the High Plains where surface pressures are, only ∼85 kPa. These descending air parcels within the upstream branch of the along-stream ageostrophic thermally-indirect circulation contain high values of momentum and very low dewpoint values. As the planetary boundary layer (PBL) deepens due to surface warming during the morning hours, momentum and dry air from the midtropospheric along-stream ageostrophic front are entrained into the PBL. This process amplifies the bore-induced hydrostatic dryline bulge via low-level ageostrophic confluence. Finally, regions of low Richardson number (arising from strong vertical shears) within the amplifying midtropospheric along-stream ageostrophic thermally-indirect circulation become preferred regions for the development of non-hydrostatic evanescent internal gravity waves. These waves are embedded within the hydrostatic along-stream front above the low-level dryline and are accomapanied by very significant values of vertical momentum flux which act to focus the meso-gamma scale structure of the dryline into smaller scale bulges where low-level winds and vorticities are very high. This meso-gamma scale process follows the hydrostatic tilting and vortex tube stretching which creates meso-beta scale maxima of mid-lower tropospheric vorticity. The turbulent momentum fluxes accompanying wavebreaking within the nonhydrostatic dryline bulge create very large (i.e., stratospheric values of) potential vorticity near 70 kPa due to the nonconservation of potential vorticity on isentropic surfaces.
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  • 24
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    Meteorology and atmospheric physics 49 (1992), S. 229-254 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary A nonhydrostatic numerical simulation of a tropical cyclone is performed with explicit representation of cumulus on a meso-β scale grid and for a brief period on a meso-γ scale grid. Individual cumulus plumes are represented by a combination of explicit resolution and a 1.5 level closure predicting turbulent kinetic energy (TKE). The results demonstrate a number of expected and unexpected important scale interaction processes. Within the central core of the developing cyclone, meso-β convective regions grow and breakdown into propagating inertiagravity waves throughout the lifecycle of the cyclone. In the early stages, the amplitude of pressure fluctuations associated with the meso-β scale convection exceed the central pressure of the cyclone and strongly modulate its intensity. With each meso-β scale pulsation, the cyclone core increases in strength, measured by the central pressure deficit. The increasingly strong inertial frequency of the storm core acts to increasingly trap the convection induced heating within the core by balancing the tangential wind against the low central pressure, before the meso-β scale convection breaks down and sends the warmth away as a propagating wave. Eventually, the slow manifold's amplitude exceeds the amplitude of the meso-β scale oscillations and a stable eye region is formed. As inertial instability increases, increasingly high thermal warmth can be protected in the core, allowing persistent subsidence to form and to clear out the cyclone eye. On the outside of the eye wall, strong inertial stability gradients in the troposphere cause convective warming to split the inflow to the eye wal! and spawn outwardly propagating inertia gravity waves. These waves carry away all of the heating forced by convection that is not inertially trapped by the eye wall and act as a moderating influence on storm intensity. Inertia gravity waves are also spawned in the stratosphere at the top of the eye wall by the revolution of asymmetric cumulus structures. In all instances, the tropospheric waves are coupled to the propagating stratospheric waves which both move at 35 ms−1, although there are many instances where the stratospheric waves seem to have no tropospheric counterpart. Hence the anvil top forcing and low level breakdown are linked. The outwardly propagating inertia gravity waves act to initiate outer bands of convection. This initiation is with the assistance of low level boundary layer variations of density related to previous convection and to virga falling from the anvil which moistens and destabilizes the mid levels ofθ e minimum. The convection initiated by these waves does not move substantially outward with the wave, although may appear to develop outward discontinuously.
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  • 25
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    Meteorology and atmospheric physics 50 (1992), S. 75-88 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary The set of fully compressible nonhydrostatic equations governing a broad spectrum of atmospheric motion was transformed fromz coordinates to sigma coordinates under a hydrostatic base state. The hydrostatic base state may be either time-independent, such as a hydrostatic balance with-out motion or with motion such as a thermal wind balance, or time-dependent such as might be obtained from the result of integrating a hydrostatic model. The transformed set of equations can be used to predict and study all scales of at mospheric phenomena. The set of perturbation equations was also derived under the same condition. The computational sensitivity in computation of pressure gradient force in sigma coordinate can be improved by computing the pressure gradient interms of perturbations under a certain hydrostatic state. The hydrostatic regional spectral model developed by Juang and Kanamitsu (1991) was modified to be a nonhydrostatic spectral model based on the nonhydrostatic equations in sigma coordinates with time-dependent hydrostatic base states. A semi-implicit time integration scheme was used. Two experiments were performed to test this nonhydrostatic spectral model with acceptable results.
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  • 26
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    Meteorology and atmospheric physics 50 (1992), S. 61-73 
    ISSN: 1436-5065
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Summary Most finite-difference numerical weather prediction models employ vertical discretizations that are staggered, and are low-order (usually second-order) approximations for the important terms such as the derivation of the geopotential from the hydrostatic equation, and the calculation of the vertically integrated divergence. In a sigma-coordinate model the latter is used for computing both the surface pressure change and the vertical velocity. All of the above-mentioned variables can diminish the accuracy of the forecast if they are not calculated accurately, and can have an impact on related quantities such as precipitation. In this study various discretization schemes in the vertical are compared both in theory and in practice. Four different vertical grids are tested: one unstaggered and three staggered (including the widely-used “Lorenz” grid). The comparison is carried out by assessing the accuracy of the grids using vertical numerics that range from second-order up to sixth-order. The theoretical part of the study examines how faithfully each vertical grid reproduces the vertical modes of the governing equations linearized with a basic state atmosphere. The performance of the grids is evaluated for 2nd, 4th and 6th-order numerical schemes based on Lagrange polynomials, and for a 6th-ordercompact scheme. Our interpretation of the results of the theoretical study is as follows. The most important result is that the order of accuracy employed in the numerics seems to be more significant than the choice of vertical grid. There are differences between the grids at second-order, but these differences effectively vanish as the order of accuracy increases. The sixth-order schemes all produce very accurate results with the grids performing equally well, and with the compact scheme significantly outperforming the Lagrange scheme. A second major result is that for the number of levels typically used in current operational forecast models, second-order schemes (which are used almost universally) all appear to be relatively poor, for other than the lowest modes. The theoretical claims were confirmed in practice using a large number (100) of forecasts with the Australian Bureau of Meteorology Research Centre's operational model. By comparing “test” model forecasts using the four grids and the different orders of numerics with very high resolution “control” model forecasts, the results of the theoretical study seem to be corroborated.
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    Meteorology and atmospheric physics 50 (1992), S. 127-142 
    ISSN: 1436-5065
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    Topics: Geography , Physics
    Notes: Summary Convective to planetary scale processes govern the motion and structure of tropical storms. A model with a high resolution and a large domain is required for accurate prediction of a storm's track and intensity. A series of integrations are performed using a primitive equation model and an initial state that defines a tropical storm that later developed into a hurricane in the real atmosphere. Increasing the horizontal resolution or domain of the model improves the forecast track. However only the increase in the horizontal resolution produces a better hurricane structure. Banded structure in the vertical motion field, asymmetries in the low tropospheric winds similar to those observed and upper tropospheric cyclonic outflow develop in high horizontal resolution experiments. It is shown that horizontal advection and pressure gradient terms produce wind tendencies in the low troposphere that displace the vortex in the observed direction. A high pressure area surrounding the central low pressure area appears in the upper troposphere. Around this high pressure area large pressure gradients develop that induce outflow winds in the distal storm area.
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    Meteorology and atmospheric physics 50 (1992), S. 105-126 
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    Topics: Geography , Physics
    Notes: Summary In this paper we present some recent work on typhoon prediction with a high resolution global model. The emphasis of this paper is on typhoon recurvature. Here we include examples of successful typhoon recurvature track forecasts made from a very high resolution global spectral model. The main objective of this study however is to go beyond the forecasts, i.e. to interrogate the history tapes and to diagnose residue-free budgets of the divergence and vorticity. The premise of this paper is that the recurvature of the typhoons depends on both the usual advection of vorticity by the layer mean winds and the advection of divergence in the outflow layers of the storm. The region immediately outside the heavy rain area of the storm experiences large values of divergent outflows which contribute a significant advection of divergence. Through the Dine's compensation this region must, in consort, experience an enhancement of low level convergence and of deep convection, thus contributing to the storm motion. We distinguish two facets of storm motion and recurvature, one based on the conventional steering that invokes the advection of vorticity by a vertical integrated flow, the other is the generation mechanism proposed here. During recurvature the storm appears to move in a direction which is influenced by the rotational and the divergent flow dynamics. Increased vertical resolution in the outflow layer is shown to resolve stronger amplitudes in the outflow layer divergence and thus to contribute to improved forecasts of recurvature. A number of processes seem to simultaneously evolve, these include the strong advection of divergence part of the wind, enhancement of cumulus convection over this region, an enhancement of lower tropospheric convergence, generation of vorticity of the lower troposphere and the attendant recurvature.
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    Meteorology and atmospheric physics 50 (1992), S. 143-163 
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    Topics: Geography , Physics
    Notes: Summary A number of forecast experiments were performed in order to assess the capability of reproducing, by means of a limited-area numerical model, the highly structured mesoscale circulations occurring in the Po Valley of Northern Italy during a north-westerly cold front passage across the Alpine chain, with particular attention to the modelling of the effects of organized convection. The case-study occurred during summer 1987 and the model used throughout was the 1989 version of the UB/NMC Limited Area Model (University of Belgrade, National Meteorological Centre of Washington). The model was integrated both with eta, η, and sigma, ϑ, as vertical coordinates and ECMWF initialized analyses were always used as initial conditions. ECMWF initialized analysis or operational forecast fields were also used for updating in time the lateral boundary conditions. Experiments show qualitative and quantitative agreement with observations, both in upper-air geopotential height fields, in MSLP and in cumulated precipitation. Several modelling issues were also investigated, e.g. sensitivity of the results to horizontal and vertical model resolution and to the influence of the lateral boundaries poitioning, finding large effects of the latter on quantitative precipitation fields. Difficulties in modelling very localized mesoscale phenomena, e.g. organized convective thunderstorms in the Po Valley and Alpine North Foehn in the Milan area, were generally encounted.
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    Meteorology and atmospheric physics 50 (1992), S. 165-174 
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    Topics: Geography , Physics
    Notes: Summary In this paper we present a methodology for evaluating rain rates from a mix of satellite and surface based observations. The component data sets include the outgoing longwave radiation (OLR), microwave radiometric data from the special sensor microwave imager (SSM/I) and surface raingauge data from the World Weather Watch. We have noted some deficiencies in the SSM/I algorithm-based rain rate over land areas; the OLR-based rain rates exhibit a larger lateral spread and lower intensities than the observed rainfall structures. The proposed combined method assimilates these three data sets to provide improved fields of global tropical rainfall.
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    Meteorology and atmospheric physics 50 (1992), S. 175-187 
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    Notes: Summary The Kuo-type cumulus parameterization and rainfall rate scheme is extended by including the outgoing longwave radiation (OLR), the local time rate of change of OLR, and the horizontal Laplacian of OLR to include the additional source of mesoscale moisture supply. The extended scheme remains simple and efficient. A series of 5-day forecasts of the 1979 monsoon for the tropical belt between the Arabian Sea and the western Pacific Ocean show improvement in the 3-day forecast in the daily accumulated precipitation in both the amount and location. Further RMS error analyses indicate that using OLR and the Laplacian of OLR also produces a significant improvement in a 3-day forecast. Additional tests of the extended scheme for the 1987 and 1988 monsoons produced consistent and characteristic areal rainfall rates in the tropics. The improvement in the “OLR model” forecasts is attributed to the improved skill of OLR forecast in the forecast model as the RMS errors for 5 consecutive days in the 6 experimental forecasts are smaller than those of the 3 control forecasts.
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    Meteorology and atmospheric physics 50 (1992), S. 189-195 
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    Notes: Summary A special analytical solution is derived for the classical orographic configuration of two-dimensional, stratified, linear, non-hydrostatic and dry model (without friction and Coriolis force). The well-known differential equation for the vertical velocity involves the vertical distribution of the Scorer parameterl 2(z) and in this casel 2 is specified such that the lower atmosphere has a stable duct near the surface and is capped by a layer which acts as a good reflector. Examination of the solution for the vertical amplitude in the vicinity of singularities indicates the dominant lee wavelength and observations confirm that in comparable settings resonant trapped gravity waves develop in the lee of mountains. Comparison with a real atmospheric lee-wave events gives good predictions for the wavelength and wave drag, but, as in other linear models, the amplitude is underestimated.
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    Meteorology and atmospheric physics 50 (1992), S. 237-238 
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    Meteorology and atmospheric physics 50 (1992), S. 231-236 
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    Notes: Summary In this paper we combine chaotic theory with statistics to present three forecast models: a model of equal distance ind-dimensional phase space, a mode regression model of twelve units and a model of neighborhood model regression. Many experiments show that all these models can generate accurate forcasts.
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    Engineering with computers 8 (1992), S. 31-49 
    ISSN: 1435-5663
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    Topics: Computer Science , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract Data base management systems for nonstandard applications (nonstandard data base systems, NDBS), in particular for engineering applications, nowadays constitute one of the most important challenges in the area of data base research. Some major obstacles are concerned with problems of modeling and processing complex engineering objects. Some new system architectures have been proposed, and appropriate concepts for handling the new types of application objects have been developed over the past few years. Based on PRIMA, an NDBS-kernel prototype implementation, we motivate a workstation-oriented architecture for NDBS application systems. We explain a prototypical application system in the environment of VLSI-chip design, which serves as a practical examples in handling complex objects. Analyzing the weaknesses of this initial approach, we derive general concepts for application linkage, discussing, in particular, key issues for an efficient object processing and language binding.
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    Engineering with computers 8 (1992), S. 1-12 
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    Topics: Computer Science , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract Automatic meshing algorithms for finite element analysis are based on a computer understanding of the geometry of the part to be discretized. Current mesh generators understand the part as either a boundary representation, an octree, or a point set. A higher-level understanding of the part can be achieved by associating engineering significance and engineering data, such as loading and boundary conditions, with generic shapes in the part. This technique, called feature-based modeling, is a popular approach to integrating computer-aided design (CAD) and computer-aided manufacturing through the use of machinable shapes in the CAD model. It would seem that feature-based design also could aid in the finite element mesh generation process by making engineering information explicit in the model. This paper describes an approach to feature-based mesh generation. The feature representation of a fully functioning feature-based system that does automatic process planning and inspection was extended to include finite element mesh generation. This approach is based on a single feature representation that can be used for design, finite element analysis, process planning, and inspection of prismatic parts. The paper describes several advantages that features provide to the meshing process, such as improved point sets and a convenient method of simplifying the geometry of the model. Also discussed are possible extensions to features to enhance the finite element meshing process.
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    Engineering with computers 8 (1992), S. 93-100 
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    Topics: Computer Science , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract A system developed earlier for reinforced concrete halls layout is studied and justified from different aspects. Also, updates of both capabilities and limitations, which were recently incorporated in the system, are emphasized. Some of the original aspects of the system were reviewed and modified, to overcome some of the drawbacks in the earlier presentation. The system's organization remains almost the same. Some suggestions for further improvements to the system are presented as well. Finally the function of the system is illustrated by a sample run of the system.
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    Engineering with computers 8 (1992), S. 101-119 
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    Topics: Computer Science , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract Applying sweep operations on 2-D closed contours is a well known method for modelling 3-D solid objects. This paper deals with the implementation of a solid modeler with sweep as the basic representational scheme. In the modeler, a solid is defined by sweeping a planar polygon along a linear or curved trajectory. A sculptured solid may also be defined by using a beta-spline curve for the sweep polygon and a cubic B-spline curve for the sweep trajectory. By incorporating Boolean operations, a hybrid sweep-CSG solid modeler is implemented. The current implementation allows translational, rotational, and twisted sweep operations on a planar polygon composited of lines and arcs. In addition, a solid primitive can also be created by sweeping a planar closed beta-spline curve along a cubic B-spline curve.
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    Engineering with computers 8 (1992), S. 121-137 
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    Topics: Computer Science , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract We present an algorithm for the generation of coarse and fine finite element (FE) meshes on multiply connected surfaces, based on the medial axis transform (MAT). The MAT is employed to automatically decompose a complex shape into topologically simple subdomains, and to extract important shape characteristics and their length scales. Using this technique, we can create a coarse subdivision of a complex surface and select local element size to generate fine triangular meshes within those subregions in an automated manner. Therefore, this approach can lead to integration of fully automatic FE mesh generation functionality into FE preprocessing systems.
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    Engineering with computers 8 (1992), S. 139-149 
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    Topics: Computer Science , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract Effective product design that satisfies functional requirements and can be manufactured easily requires vast amounts of knowledge on the part of the design engineer. This paper focuses on the complementary roles of expert systems and database management systems as they relate to the Intelligent Design System (IDS) in a Design for Manufacture (DFM) environment. Each technology complements the other in its strengths and abilities. The database management system provides during the design process. The expert system provides a reasoning mechanism for identifying manufacturing violations and generating meaningful recommendations. These components work cooperatively with a CAD interface to form a unified, intelligent design environment. An information flow analysis of the Intelligent Design System resulted in the development of three distinct classifications of information within the database: CAD data, a design catalog, and a knowledge base. The CAD data tables employ an, object oriented approach to store specific information about the physical contains cost, weight, and strength characteristics of the standard parts and fasteners used within the system. The knowledge base contains rules and heuristics concerning design and manufacturing methodologies. The placement of the expert system rules in the database represents an innovation. As a result, the expansion and updating of the materials, fasteners, standard parts, or manufacturing processes used by the Intelligent Design System is facilitated without increased due to the efficient management of the knowledge base by the database management system. This allows the designer to modify the knowledge and help the system to learn without the need for a knowledge engineer.
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    Engineering with computers 8 (1992), S. 197-211 
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    Topics: Computer Science , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract Recent research in design theory has sought to formalize the engineering design process without particular concern for the paradigm used to model design information. The authors propose that no correct formalization of the design process can be achieved without first formalizing the semantics of the information used in the process. To this end, the authors present a new formal theory of design information. The theory, called the hybrid model (HM), is an extended form of axiomatic set theory, and relies on it for consistency and logical rigor. The theory is stated as a collection of axioms, using a standard logic notation. Design entities are modeled by formal units calledobjects. Generalized functions and relations are used to formalize important ordering schemes and abstraction mechanisms relevant to design, including classification by structure and by function, aggregation, specialization, and generalization. The hybrid model is meant not only to aid in the study of the design process itself, but also to improve communications between designers, assist standardization of design specifications, and develop new, powerful software tools to aid the designer in his work.
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    Engineering with computers 8 (1992), S. 213-232 
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    Topics: Computer Science , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract This paper discusses the various novel functionalities of a transaction management system for collaborative engineering applications. These features include grouped and shared transactions, dynamic database partitioning, communicative locking, dependency maintenance, update notification schemes, and version management of data configurations. It also establishes protocols for data consistency maintenance on the basis of application semantics and encapsulation of nonserializable data sharing in local databases rather than by the notion of global database consistency. Finally, it presents strategies for implementing these features using a commercial object oriented database management system (OODBMS) environment (ONTOS).
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    Engineering with computers 8 (1992), S. 243-252 
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    Topics: Computer Science , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract Materials properties information systems are poorly understood. Many databases of materials properties and designations have been produced but, except in the most modest of cases, they have been less successful than their creators had hoped Knowledge based systems (KBS) are subject to exactly the same problems as data based materials information systems and it is important to realize what these are before the special character of KBSs can be used to alleviate them. This paper surveys the unusual and difficult aspects of engineering materials information that must be handled by any organizing methodology, whether manual or computerized, data based or knowledge based, handling information which is stored or inferred.
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    Research in engineering design 3 (1992), S. 149-162 
    ISSN: 1435-6066
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract For the field of design to become a discipline, it must have the prerequisites of a discipline: principles and a process of solving problems using these principles. This paper presents a case study for axiomatic design, illustrating the process of using the design axioms (i.e., the Independence Axiom and the Information Axiom) in designing an artificial skin. The axioms are used to guide the analysis of a process design for an artificial skin graft. The analysis indicates that the current design does not meet the requirements specified by the axioms and should be redesigned to overcome the difficulties it has experienced in the field. Alternative solutions are generated following a systematic analysis of the design problem, and the best alternative is identified.
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    Research in engineering design 3 (1992), S. 243-246 
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    Research in engineering design 3 (1992), S. 193-193 
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    Research in engineering design 3 (1992), S. 179-189 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract This paper presents a taxonomy that provides a basis for characterizing mechanical design methods and theories. The taxonomy has three primary divisions: the environment, the problem, and the process. Each of these factors is further subdivided into its important characteristics. For example, the process is divided into plan, processing action, effect, and failure action. This paper discusses the options for each characteristic. An overview of the proposed taxonomy is given in section 2 of this paper. Section 3 describes details of the design environment; section 4 gives details on the description of the design problem itself; and section 5 provides details on the design process. In section 6, the taxonomy is applied in two ways: it is first used to clarify the meaning of differing, commonly used design terms, such as selection design, configurational design, parametric design, and redesign; and, second, the taxonomy is used to classify a representative sample of design process research efforts.
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    Research in engineering design 3 (1992), S. 211-221 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract Engineering design research has historically been evaluated in terms of its computational performance. However, in many cases this research implies hypotheses about human behavior which are ignored. In this paper, we argue that the systems emerging from design research will benefit from investigating how people use them to accomplish work, and from the incorporation of principles of Participatory Design (Floyed et al., 1989) at the earliest stages of the development process. Using a case study, we present the evolution of a CAD system that supports complex mathematical modeling. This design effort is examined according to principles outlined in another well-documented effort in Participatory Design. Finally, despite the common misconception that such considerations impede basic research, we argue that continuous user involvement can guide research by validating experimental hypotheses and pointing to areas for future inquiry.
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    Research in engineering design 3 (1992), S. 233-242 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract Collaborative design projects place additional burdens on design documentation practices. The literature on group design has repeatedly documented the existence of problems in design decision-making due to the unavailability of design information. This paper describes a data representation developed for collaborative mechanical design information. The data representation is used to record the history of the design as a sequence of design decisions. The resulting data base records the final specifications, the alternatives which were considered during the design process, and the designers' rationale for choosing the final design parameters. It is currently implemented in a computerized data base system under development at Oregon State University (OSU).
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    Research in engineering design 4 (1992), S. 43-50 
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    Notes: Abstract Modern designs are more than ever before required to be understandable and usable by their intended audience. As machines get ever more complex, it becomes essential for designers to provide a user-centered design that focuses upon the needs and abilities of the user. This paper presents an analysis of cognitive artifacts—devices designed to maintain, display, or operate upon information in order to serve a representational function. An important design consideration is the human action cycle which means that artificial devices must support both execution and evaluation.
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    Research in engineering design 4 (1992), S. 51-60 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract Available statistical data suggest that human error in design causes a significant proportion of performance failures; namely, structural failure, cost overruns, and delays. A Human Reliability Analysis (HRA) model has been developed to simulate the effect of human error on the design computations of a reinforced concrete beam. The proposed HRA model incorporates the effect of “self-corrections”; this is a process where tasks are re-evaluated if the result appears to be not within “reasonable” expectations. Calculation, table look-up, chart look-up, and table ranking microtasks were incorporated into the proposed HRA model; human perormance data are described for each of these microtasks. It was found that human error, particularly multiple errors, lead to a significant loss of structural safety.
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    Research in engineering design 3 (1992), S. 191-191 
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    Research in engineering design 3 (1992), S. 195-210 
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    Notes: Abstract A method for machine interpretation of architectural (or other) schematic drawings is presented. The central problem is to build an efficient drawing parser (i.e., a program that identifies the semantic entities, characteristics, and relationships that are represented in the drawing). The parser is built from specifications of the drawing grammar and an underlying spatial model. The grammar describes what to look for, and the spatial model enables the parser to find it quickly. Coupled with existing optical recognition technology, this technique enables the use of drawings directly as: (1) a database to drive various Architecture-Engineering-Construction (AEC) applications; (2) a communication protocol to integrate CAD systems; (3) a traditional user interface.
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    Research in engineering design 4 (1992), S. 1-1 
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    Research in engineering design 3 (1992), S. 247-248 
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    Research in engineering design 4 (1992), S. 23-42 
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    Notes: Abstract This paper presents a new unifying theme for design theory by emphasizing the importance of context. We arrive at our conclusions by examining and then criticizing the legitimacy of universal methods in design upon which the critical importance of context emerges. The collaborative aspects of design focuses attention on the conception of shared meaning. We introduce and elaborate the concept of shared memory as the embodiment both of context and of shared meaning. Using the concept of shared memory in vertical and horizontal forms, within and between disciplines, respectively, we both account for past observations of design in practice and recommend actions to improve design in the future. We examine several practical implications of the growing importance of shared memory in industrial firms and for design teams. We then consider and recommend specific research programs which will help designers capture and make better use of this critical resource.
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    Research in engineering design 4 (1992), S. 67-74 
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    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Technology
    Notes: Abstract Within mechanical computer-aided design (CAD), pattern-recognition techniques are fundamental to feature recognition. The use of neural net software as the pattern-recognition element depends upon encoding schemes which extract critical information from candidate geometric subsets. The trained memory can then determine if a particular candidate geometric subset corresponds to a feature of interest. Successful experiments with particular encoding schemes over a restricted class of features will be presented. Neural nets were chosen with the long-term view toward a feature-recognition architecture where the end-user could customize the domain of features that can be recognized. The training of the neural net memory would be achieved through a graceful graphics interface. Extensive programming and knowledge bases would be avoided. This envisioned architecture will be presented to provide a context for the encoding schemes.
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    Research in engineering design 4 (1992), S. 147-158 
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    Notes: Abstract One of the fundamental axioms of concurrent engineering is that undertaking functional design without foreseeing the manufacturing process leads to production delays and increased costs. This widely accepted concurrent engineering principle is given a formal basis by development of a mathematical model for the conversion of a feature-based design representation to a manufacturing representation. Within the domain of thin-walled components, it is shown that the conversion to tooling cost representations can result in a discontinuous function when the sets of design and manufacturing representations have been formulated as topological spaces. This discontinuity formally reflects the folklore that a small design change can significantly increase product cost. The mathematical sophistication required within this model is suggestive of why manufacturability evaluations can be quite difficult.
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    Research in engineering design 4 (1992), S. 191-194 
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    Research in engineering design 4 (1992), S. 203-213 
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    Notes: Abstract The realization of concepts into products is an extremely complex and poorly understood process. Companies and researchers are developing software aids and tools in a somewhat ad hoc manner. Differing claims are made for such tools, without there being much underlying understanding about what they are supposed to do. As part of a project to develop a strategy for applying computer-based tools to the process of realizing products, this paper proposes a taxonomy which encompasses most of the factors involved and defines the environments in which computer-based tools operate. Several other uses for this taxonomy are suggested, including identifying how the different types of computer-based tools support or replace various human activities or tasks; outlining a strategy for automating the process, as part of a strategy for applying the right tool for the task; and identifying where new tools might be developed.
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    Polymer bulletin 28 (1992), S. 33-40 
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    Notes: Summary Substituted poly(cyclohexene)s, used as poly(phenylene) precursors, have been prepared by radical polymerization of cyclohexadiene-1,2-diol derivatives containing various leaving groups. The precursors were converted into poly(phenylene) either by curing at elevated temperatures or by deep-UV exposure in the presence of a photoacid generator. These reactions were investigated by both IR and UV analysis. Our results with the conversion of precursors into poly(phenylene) via photoaromatization suggest that polyphenylene precursors can be imaged by deep-UV microlithography (as a new class of photoimageable thermally stable polymers).
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    Polymer bulletin 28 (1992), S. 117-122 
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    Notes: Summary The cationic polymerization of various α- and β-substituted vinyl ethers, initiated by 1-iodo-1-(2-methylpropyloxy)ethane 1 and tetrabuty lammonium perchlorate (TBAP) was investigated. The polymerization of 2,3-dihydrofuran (DHF, 3a) in CH2Cl2 at -40°C proceeds via opening of the ethylenic double bond and yields polymers with narrow molar mass distributions and high glass transitions. The number average of molar mass increased linearly with conversion. Under these conditions, a controlled polymerization of two propenyl ethers (1-ethoxypropene 2a and 2-methoxypropene 2b) and two other cyclic unsaturated ethers (3,4-dihydro-2H-pyran 3b and 5-methyl-2,3-dihydrofuran 3c) could not be achieved. Either transfer reactions or the decomposition of 1 prevented the formation of high molar mass polymers of these vinyl ethers.
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    Polymer bulletin 28 (1992), S. 555-560 
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    Notes: Summary 3-Vinylbenzothiophene was synthesized and its copolymerization with methyl methacrylate and n-butyl acrylate was investigated. The copolymerizations were performed according to an experimental design scheme and the results were analyzed using a nonlinear error-in-variables method. The 3-vinylbenzothiophene was found to be a reactive monomer with reactivity ratio values similar to those of 2-vinyl thiophene.
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    Polymer bulletin 28 (1992), S. 561-568 
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    Notes: Summary Isotactic (it-) and syndiotactic (st-) MMA oligomers from 19-mer to 29-mer could be isolated efficiently from it-PMMA ( $$\overline {DP}$$ = 28.6) and st-PMMA ( $$\overline {DP}$$ = 28.6) (sample load: 50 mg) by the SFC using a 10 mm i. d. x 250 mm column packed with silica gel. DP of each isolated oligomer was determined by FD mass spectroscopy, and the values agreed well with those calculated from the relative intensity of 1H NMR signals due to CH3O- and the terminal t-C4H9-groups. Glass transition temperature (T g) of the it-28-mer measured by DSC was 34.5°C, which was higher than that of the it-PMMA by 6.5°C. T g of both the it-and st-oligomers increased linearly with DP in the range of DP=20∼29. A 1: 1 mixture of the it- and st-27-mers annealed at 140°C showed an endothermic transition at 102.3°C which was attributable to melting of stereocomplex, whereas an annealed 1: 1 mixture of the it- and st-PMMAs had a much broader endotherm around 80∼140°C.
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    Notes: Summary The coordination structures of Cu(II) complexes of amino functions supported on polyacrylamides with varying extents of NNMBA-crosslinks were followed by EPR techniques. The geometry of the Cu(II) complexes changes with increasing crosslinking. The covalency of the Cu-N bond also depends on the extent of the NNMBA-crosslinking in the polymer-support.
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    Polymer bulletin 28 (1992), S. 601-606 
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    Notes: Summary The sorption behaviour of copper (II) and uranium (VI) ions on branched poly(ethylenimine) (BPEI) bridged with bifunctional crosslinkers (CR), 1-chloro-2,3-epoxypropane, 1,3-dibromopropane and 1,2-dibromoethane with various degress of crosslinks has been examined. The effect of crosslinking on the extent of sorption and thermal stability is reported.
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    Notes: Summary The mesophase formation was observed from the system of mixed organic polymer (hydroxypropyl cellulose) and inorganic polymer (imogolite) in acetic acid aqueous solution. The phase diagram of the mesophase formation was drawn as a function of imogolite content. The mesophase structure was found to change from the helicoidall arrangement of nematic sheets to the pile of pleated nematic sheets with increasing imogolite content.
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    Notes: Summary First unsaturated polyester fibers were prepared starting from stereoregular, macromolecular poly(octamethylene fumarate). Fibers obtained from octamethylene copolyesters of fumaric and terephthalic acids manifested improved mechanical properties and higher melting points. All unsaturated polyester fibers prepared in the study, based on the homopolymer and on copolymers of fumaric acid, even those containing as low as 10% of fumaric acid residues, are able to be covalently bonded to an unsaturated polyester matrix.
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    Polymer bulletin 28 (1992), S. 633-638 
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    Notes: Summary Propylene oligomers containing isopropenyl end group have been prepared by thermolysis of atactic polypropylene. The chain-end structures and the number-avarage isopropenyl chain end functionality was determined in the product by C-13 NMR spectroscopy. Molecular weight of the oligomers were between 300 and 1000, as characterized by GPC. Conditions leading to the formation of propylene oligomers with number-average isopropenyl chain end functionality of 1.0, have been worked out.
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    Polymer bulletin 28 (1992), S. 653-656 
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    Notes: Summary The photoaddition of aromatic dithiols (1) onto aliphatic alkenes (2a-2c) yielding polysulfides is studied. Polysulfides having anti-Markownikow and Markownikow moieties in the main chain are obtained by the reaction of dithiols (1) with ethyleneglycoldivinylether (2a). The unusual Markownikow orientation is explained on the basis of a radical cation intermediate.
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    Notes: Summary Radical polymerizations of vinyl monomers using a initiator of 2,2′-azobis(2-amidinopropane) dihydrochloride on monodispersed silica colloid led to formation of spherical polymer/SiO2 composites, retained particle size. Addition of hydroxypropyl cellulose to the reaction system resulted in yielding excellent dispersible composites into ethanol by short period ultrasonic irradiation. The polymerization of styrene in the presence of mercapto-amine or carboxylic acid derivatives could successfully introduce amino or carboxyl group on the Poly(styrene)/SiO2 composite.
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    Polymer bulletin 28 (1992), S. 689-695 
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    Notes: Summary The interrelation between the electrical conductance, σ and some chemically modified cellulose molecule produced through partial substitution of the hydroxyl groups by different groups namely, acetate, methoxyl, carboxymethyl and sodium carboxymethyl has been studied in the temperature ranges 283–333 k. The results show that σ of the examined samples change in the descending order: sodium carboxymethyl cellulose 〉carboxymethyl cellulose 〉methyl cellulose〉cotton cellulose〉cellulose acetate. The variable response of σ to the chemical modification and the physical changes of cellulose accompanying such modification has been discussed in terms of the molecular structure, chain flexibility and degree of polymerization of the examined samples.
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    Polymer bulletin 28 (1992), S. 697-702 
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    Notes: Summary Acidic parameters according to the GUTMANN's acceptor numbers (AN) of cellulose acetates and unmodified cellulose have been determined by means of the negatively solvatochromic probe dye Fe(phen)2(CN)2. Unmodified cellulose possesses a relatively high acceptor strength due to cooperative hydrogen bonds while increasing acetate contents in the polymer chain lower the acceptor strength. The dependence of AN on the acetate content can be used to estimate the degree of substitution (DS). Pecularities in the substitution interval (DS=0 to DS=1.5) are discussed.
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    Polymer bulletin 28 (1992), S. 677-681 
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    Notes: Summary The complex forming poly[(ethylene glycol-co-proplene glycol)-g-acrylamide]: polyacrylic acid interpenetrating polymer network hydrogel is able to bend under electric field “stimuli”. pH, ionic strength gradients and voltage can influence it's bending degree. So we may improve the sample' “responsive” speed through manipulating those factor in the further study in order to put it into the biomedical application.
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    Polymer bulletin 28 (1992), S. 449-450 
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    Notes: Summary An original way of reducing composition heterogeneity has been proposed for copolymers obtained at high conversions. The main idea underlying this method consists in application as initiators of special compounds (iniferters) leading to alteration of the mechanism of polymer chain growth.
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    Notes: Summary A reaction scheme based on propagation and intramolecular chain transfer steps is proposed for the anionic homopolymerization of epoxides initiated by tertiary amines. Chain transfer regenerates a living chain and gives a dead chain with terminal vinilydene unsaturations and hydroxy groups. The possibility of generating phenols or substituted phenols is also considered. Molecular-mass distributions were predicted as a function of conversion by both kinetic and Monte Carlo methods. Predictions were compared with experimental results reported in the literature. The evolution of the number-average degree of polymerization could be reasonably predicted.
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    Polymer bulletin 28 (1992), S. 481-487 
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    Notes: Summary The coefficient of thermal expansion is measured for irradiated Polyvinyl Chloride (PVC) from 10K to 340K. The samples of PVC are irradiated, up to 500 Mrad in steps of 100 Mrad, in air at room temperature by using Co gamma rays with a dose rate of 0.3 Mrad/h. The PVC is an amorphous sample which is confirmed by X-ray diffraction. The coefficient of thermal expansion is found to decrease with radiation dose from 10K to 110K and it increaseswith radiation dose from 110K to 340K. The results are explained on the basis of radiation induced degradation of the sample.
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    Polymer bulletin 28 (1992), S. A4 
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    Polymer bulletin 28 (1992), S. 497-503 
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    Notes: Summary The synthesis of telechelic monodispersed diols produced from the radical telomerization of an excess of undecylenol with commercialy available α, ω-dithiols HSC2H4XC2H4SH (X=0, S or CH2) initiated by peroxides is presented. In each case, the diols were obtained selectively and quantitatively and they were characterized by both 1H and 13C NMR. Their physical characteristics (Tg, Tm and decomposition temperatures) were determined. Such compounds are thermally more stable than polydispersed telechelic commercially available diols.
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    Polymer bulletin 28 (1992), S. 505-509 
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    Notes: Summary The anionic polymerization of dimethylphenylvinylsilane with sec-butyllithium/N,N,N′,N′-tetramethylethylenediamine (TMEDA) was investigated. The polymerization proceeded up to 100% yield and afforded the polymer having isomerized-structure units. The polymerization was accompanied by chain transfer reaction to the monomer and the polymerization rate in the presence of TMEDA was much lower than in the absence of TMEDA.
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    Notes: Summary Methacrylation of triglycidyl triphenyl methane (via methacrylic acid) has been done using three catalysts: dimethyl dodecyl amine (DMDA), tetrabutyl ammonium bromide (TBAB) and chromium (III) diisopropyl salicylate (Cr Dips). The reaction has been followed by epoxy colorimetric titration, CPG and 1H NMR. This study has shown the superiority of chromium catalysis because of its rapidity and ease of process. Then, these cured products (TACTIX and methacrylated TACTIX) show homogeneous Tg values which are higher than 200°C.
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    Polymer bulletin 28 (1992), S. 639-644 
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    Notes: Summary Polyesters from 3,3′-bis(chloromethyl)oxacyclobutane and dipotassium isophthalate were obtained by phase transfer catalysis using different catalysts and solvents. The products were characterised by IR,1H-NMR and DSC.
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    Polymer bulletin 28 (1992), S. 645-652 
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    Notes: Summary Polycarbonates, polythiocarbonates, and polyesters from 1,1,3-trimethyl-3-(4′-hydroxy-phenyl)-4-indanol were synthesized using phase transfer conditions. THe effects of several catalysts and reactions times were evaluated by the yields and inherent viscosities. Phase transfer catalysis was not an efficient technique due to the rigid structure of the diphenol with the indanic group. The results were compared with that obtained with a diphenol having the same number of carbon atoms but forming an aliphatic side chain.
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    Polymer bulletin 28 (1992), S. 657-662 
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    Notes: Summary 1,2,3-Triphenylcyclopropene (TPCP) is a powerful retarder for polymerizations of methyl methacrylate (MMA) and styrene initiated by benzoyl peroxide or azobisisobutyronitrile. End-groups in polymers of MMA were studied by 13C-NMR spectroscopy and also, in the case of the peroxide, by using radioactive initiator. It was shown that, towards the benzoyloxy and 1-cyano-1-methylethyl radicals, the reactivity of TPCP exceeds that of MMA by factors of about 60 and three respectively at 60°C. TPCP can be used to introduce into polymers end-groups of special types.
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    Notes: Summary The influence of solvent on polyvinylpyrrolidone (PVP) and polyitaconic acid monomethylester (PMMI) sterecomplex formation was studied by means of laser light scattering and viscometry. Several phase changes were observed, from homogeneous solution to precipitates and gels. Responsible of this behaviour are hydrogen bonding, Coulombic forces, or hydrophobic interaction in aqueous medium.
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    Polymer bulletin 28 (1992), S. 703-707 
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    Notes: Summary The Lewis and Mayo's rule, used so far for the determination of r1 and r2, is presently applied for the simultaneous determination of partial monomers conversions α1 and α2; whereas the integration of the Skeist's rule gave global conversion α only. An experimental verification is performed for the cotelomerization of MMA and maleic anhydride with dodecyl mercaptan as telogen, and it gives a very good correlation.
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    Notes: Abstract An anomalous effect on the twisted intramolecular charge transfer (TICT) phenomenon of 4-(N,N-dimethylamino) benzonitrile (DMABN) dissolved in elastomers such as poly(propylene oxide), poly(ethylene oxide) has been observed. Under irradiation, the normal fluorescence of DMABN in these matrices has been found to increase strongly while the emission arising from the TICT state decreases slightly.
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    Polymer bulletin 29 (1992), S. 661-668 
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    Notes: Summary In this paper, the polymerisation of a conjugated liquid crystalline diacetylene is reported. The structure of the polymer is discussed in relation to results from spectroscopic studies and molecular weight determinations. The polymer has a backbone structure analogous to that of other polydiacetylenes.
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    Polymer bulletin 29 (1992), S. 675-679 
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    Notes: Summary The preparation of a novel family of “liquid-crystalline” polyamide network gels is described. In these networks, the segments are stiff and longer than the critical axial ratio for mesomorphic behavior. The junctions are trifunctional and flexible. The gels are intensely birefringent in the relaxed nascent state, unlike fully rigid or fully flexible gels. The birefringence of the present gels is clearly associated with the coexistence in them of both long, stiff mesogenic segments and flexible trifurcated junctions. Thermal studies of the gels indicate very strong attractive interactions between the networks and the solvent.
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    Polymer bulletin 29 (1992), S. 697-704 
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    Notes: Abstract Novel poly(acenaphtylene-b-isobutylene-b-acenaphtylene) (PAc-PIB-PAc) triblock copolymers exhibiting thermoplastic elastomer (TPE) properties have been prepared. The synthesis involved the addition of acenaphtylene (Ac) to living polyisobutylene dications (⊕PIB⊕) obtained by living isobutylene (IB) polymerization induced by the dicumyl methyl ether (DiCumOMe)/TiCl4 initiating system at-80°C. The triblocks contain very short polyacenaphtylene (PAc) blocks (Mn≈9,000) and consequently yield very soft, low modulus TPEs. Efforts to develop conditions for the living carbocationic polymerization (LC⊕Pzn) of Ac have failed.
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  • 91
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The cyanoethylation of cyclopentadiene was examined under a variety of reaction conditions. Approximately 9% of cyclopentadiene was converted to the desired hexa(β-cyanoethyl)cyclopentadiene when the amount of acrylonitrile to cyclopentadiene was increased from 2 to 7 equivalents under phase transfer conditions. The low conversion is due to competitive formation of various unreactive side-products. For example, termination leading to less-highly substituted products was confirmed by isolation of crystalline 1,1,2,3,4-penta(β-cyanoethyl)cyclopentadiene. Another side product isolated and characterized by 13C NMR was an oligomer of acrylonitrile attached to hexa(β-cyanoethyl)cyclopentadiene; the anion (at a β-alkyl position) of the latter apparently acted as anionic initiator. Attempts to induce thermal polymerization and cyclotrimerization of the pendent cyano groups of hexa(β-cyanoethyl)cyclopentadiene were unsuccessful even with added Lewis acid catalysts. Reduction to the hexaamine was only partially successful.
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  • 92
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    Polymer bulletin 27 (1992), S. 407-411 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Ternary catalyst systems for the polymerisation of 1,3-butadiene to high cis content were studied. The systems Nd(carboxylate)3/tert-butyl chloride/diisobutylaluminium hydride (carboxylate = naphthenate, versatate) were studied with respect to the order of catalyst component addition on catalyst activity and polymer characteristics. Stable catalysts which give relatively narrow molecular weight distribution are give by component addition order Nd(carboxylate)3+diisobutylaluminium hydride+tert-butyl chloride. Less stable systems giving broader polymer molecular weight distributions are given by addition orders tert-butyl chloride+diisobutylaluminium hydride+Nd(carboxylate)3 and Nd(carboxylate)3 +tert-butyl chloride+diisobutylaluminium hydride.
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  • 93
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The present study describes the preparation of polyorganosiloxanes containing dialkylaminopyridines in their side chains (POS-DAAPs) and the use of them as catalysts for esterolyses of p-nitrophenyl esters of CH3(CH2) n COOH (n=0–5). The POS-DAAPs (4, 5) were prepared from poly[(3-chlorocarbonylpropyl)methylsiloxane] (PCCPMS, 1) and two pyridine derivatives, such as 4-[(2-hydroxyethyl)methylamino]pyridine (HEMAP, 2) and 4-[4-(2-hydroxyethyl)piperidino]pyridine (HEPP, 3). Pyridyl groups of POS-DAAPs 4 and 5 were partially quaternized with dimethylsulfate (6, 7) in order to carry out esterolysis in homogenious systems. The esterolyses were examined in methanol/tris(hydroxymethyl)-aminomethane-hydrochloric acid buffer solution (vol. ratio 2/1, pH of buffer solution: 7.5) and analyzed following Michaelis-Menten like kinetics. The second-order rate constants (k 2/K m) of the esterolyses catalyzed by POSs 6 and 7 were 22–38 fold values of those catalyzed by the corresponding monomolecular catalysts 2 and 3. In addition, the effects of POSs were discussed from the kinetic, thermodynamic, and activation parameters.
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  • 94
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Copolymerizations of styrene and methyl methacrylate (MMA) have been carried out with azo-bis-(methyl isobutyrate-α-13C) (AIBMe-α-13C) as initiator and in the presence of ethyl aluminium sesquichloride (EASC). The specificity of the 1-methyl-1-(methoxycarbonyl)ethyl radical (I) for reaction with styrene over MMA is substantially enhanced by the presence of very low concentrations of EASC. This behaviour is consistent with the involvement of a complexes radical and suggests that such species may play an important role in Lewis acid induced alternating copolymerization.
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  • 95
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    Polymer bulletin 27 (1992), S. 429-434 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The model compound 1,4-bis(anisylimido)benzene has been characterized by solution and CP/MAS 13C NMR to assist in the characterization of liquid crystalline polyazomethines (PAM) based on the same mesogenic structure. Thermal behavior of several homologs of this PAM series have been compared before and after treatment with the end capping agent benzaldehyde. The results suggest that PAM oligomers containing large quantities of amine termination can strongly effect thermal behavior at constant oligomer molecular weight.
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  • 96
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary A low temperature ESR technique has been developed for the observation of free radical intermediates generated in clear polymer films during photolysis by UV light under nitrogen. The technique is simple and reproducible, and can be used for polymers having glass transition temperatures at or about room temperature without the need to employ spin traps. The generation of free radicals can be monitored and quantified during exposure, and the radical yields obtained can then be correlated with the chemical structure of the polymer to provide a rapid predictive evaluation of the exterior durability of the polymer.
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  • 97
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Electrical conductivities and ESR spectra were obtained for polyaniline salts that contained different counter anions. The electrical properties were markedly different from one salt to another, although the concentrations of counteranions were almost identical. The ESR spectra showed that different types of unpaired electrons were created upon protonation. There was a close correlation between the charge-transport property and the nature of unpaired electrons created upon protonation.
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  • 98
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Multicomponent intermacromolecular complexes have been prepared from some typical phenolic copolymers with a non-ionic polymer (e.g. PVP), and a polyelectrolyte (e.g. PAA). Some transition metal ions (e.g. Cu(II) and Ni (II)) have been incorporated in the complex through its unreacted co-ordinating groups. The formation of these complexes has been studied by several techniques, such as viscometry, conductometry, potentiometry, IR and UV spectrophotometry. A scheme has been presented to explain the mode of interaction of the various components.
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  • 99
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    Polymer bulletin 27 (1992), S. 577-583 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary The swelling and mechanical behaviour of networks of copolymers of acrylamide, methylenebisacrylamide and sodium 2-(2-carboxybenzoyloxy)ethylmethacrylate (mole fraction of salt x s =0–0.2) in water-acetone mixtures was investigated. In the range x s ≥0.01 phase transition (collapse) was observed, with both the extent of the collapse and the critical acetone concentration in the mixture at collapse, a c , increasing with increasing concentration of the salt. A comparison between these results and those obtained for networks with a quaternary ammonium salt led to a conclusion that an exchange of the positive charge of the ammonium salt (N⊕Cl⊖) for the negative charge of the sodium salt (COO⊖Na⊕) in the side chain decreases the critical content of salt necessary for the collapse, X s c , from 0.03 to 0.01, and the collapse takes place at lower concentrations of acetone. The collapse may also take place in a mixed solvent waterethanol; the dependence of network swelling on the concentration of ethanol is roughly the same as that on the concentration of acetone.
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  • 100
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    Polymer bulletin 27 (1992), S. 607-613 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Polysilanes containing cyclodisilazane units in the backbone were synthesized by the modified Wurtz-type coupling of available dichlorosilanes with N,N′-bis (chlorodimethylsilyl)tetramethylcyclodisilazane in the mixture of solvents. The effect of solvent additives on the polymerization process was examined. These polymers are soluble in common solvents and very easily handled by molding or casting.
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