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  • American Association for the Advancement of Science (AAAS)  (99)
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  • 1
    Publication Date: 2007-04-28
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Peng, Changhui -- Ouyang, Hua -- Gao, Qiong -- Jiang, Yuan -- Zhang, Feng -- Li, Jun -- Yu, Qiang -- New York, N.Y. -- Science. 2007 Apr 27;316(5824):546-7.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Institut des Sciences de L'Environnement, Departement des Sciences Biologiques, Universite du Quebec a Montreal, Montreal, QC, Canada, H3C 3P8.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/17463272" target="_blank"〉PubMed〈/a〉
    Keywords: Animal Migration ; Animals ; China ; *Conservation of Natural Resources/legislation & jurisprudence ; *Ecosystem ; *Environment ; Fresh Water ; Plants ; *Railroads ; Refuse Disposal ; Temperature ; Travel
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 2
    Publication Date: 2007-05-15
    Description: Titan's lower atmosphere has long been known to harbor organic aerosols (tholins) presumed to have been formed from simple molecules, such as methane and nitrogen (CH4 and N2). Up to now, it has been assumed that tholins were formed at altitudes of several hundred kilometers by processes as yet unobserved. Using measurements from a combination of mass/charge and energy/charge spectrometers on the Cassini spacecraft, we have obtained evidence for tholin formation at high altitudes (approximately 1000 kilometers) in Titan's atmosphere. The observed chemical mix strongly implies a series of chemical reactions and physical processes that lead from simple molecules (CH4 and N2) to larger, more complex molecules (80 to 350 daltons) to negatively charged massive molecules (approximately 8000 daltons), which we identify as tholins. That the process involves massive negatively charged molecules and aerosols is completely unexpected.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Waite, J H Jr -- Young, D T -- Cravens, T E -- Coates, A J -- Crary, F J -- Magee, B -- Westlake, J -- New York, N.Y. -- Science. 2007 May 11;316(5826):870-5.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Space Science and Engineering Division, Southwest Research Institute (SWRI), 6220 Culebra Road, San Antonio, TX 78238, USA. hwaite@swri.edu〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/17495166" target="_blank"〉PubMed〈/a〉
    Keywords: Aerosols ; Atmosphere ; *Benzene ; Extraterrestrial Environment ; *Hydrocarbons ; Ions ; Molecular Weight ; *Nitriles ; Photochemistry ; *Saturn ; Spacecraft ; Temperature ; Ultraviolet Rays
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 3
    Publication Date: 2007-05-05
    Description: The initial electron transfer dynamics during photosynthesis have been studied in Rhodobacter sphaeroides reaction centers from wild type and 14 mutants in which the driving force and the kinetics of charge separation vary over a broad range. Surprisingly, the protein relaxation kinetics, as measured by tryptophan absorbance changes, are invariant in these mutants. By applying a reaction-diffusion model, we can fit the complex electron transfer kinetics of each mutant quantitatively, varying only the driving force. These results indicate that initial photosynthetic charge separation is limited by protein dynamics rather than by a static electron transfer barrier.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Wang, Haiyu -- Lin, Su -- Allen, James P -- Williams, Joann C -- Blankert, Sean -- Laser, Christa -- Woodbury, Neal W -- New York, N.Y. -- Science. 2007 May 4;316(5825):747-50.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Biodesign Institute, Arizona State University, 1001 South McAllister Avenue, Tempe, AZ 85287-5201, USA.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/17478721" target="_blank"〉PubMed〈/a〉
    Keywords: Bacterial Proteins/*chemistry/genetics/*metabolism ; Bacteriochlorophylls/metabolism ; *Electron Transport ; Kinetics ; Light ; Models, Chemical ; Mutation ; *Photosynthesis ; Photosynthetic Reaction Center Complex Proteins/*chemistry/genetics/*metabolism ; Rhodobacter sphaeroides/genetics/*metabolism ; Spectrum Analysis ; Temperature ; Thermodynamics ; Tryptophan/chemistry
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 4
    Publication Date: 2007-10-13
    Description: When the solar wind hits Jupiter's magnetic field, it creates a long magnetotail trailing behind the planet that channels material out of the Jupiter system. The New Horizons spacecraft traversed the length of the jovian magnetotail to 〉2500 jovian radii (RJ; 1 RJ identical with 71,400 kilometers), observing a high-temperature, multispecies population of energetic particles. Velocity dispersions, anisotropies, and compositional variation seen in the deep-tail (greater, similar 500 RJ) with a approximately 3-day periodicity are similar to variations seen closer to Jupiter in Galileo data. The signatures suggest plasma streaming away from the planet and injection sites in the near-tail region (approximately 200 to 400 RJ) that could be related to magnetic reconnection events. The tail structure remains coherent at least until it reaches the magnetosheath at 1655 RJ.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉McNutt, R L Jr -- Haggerty, D K -- Hill, M E -- Krimigis, S M -- Livi, S -- Ho, G C -- Gurnee, R S -- Mauk, B H -- Mitchell, D G -- Roelof, E C -- McComas, D J -- Bagenal, F -- Elliott, H A -- Brown, L E -- Kusterer, M -- Vandegriff, J -- Stern, S A -- Weaver, H A -- Spencer, J R -- Moore, J M -- New York, N.Y. -- Science. 2007 Oct 12;318(5848):220-2.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Applied Physics Laboratory, Johns Hopkins University, Laurel, MD 20723, USA. ralph.mcnutt@jhuapl.edu〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/17932283" target="_blank"〉PubMed〈/a〉
    Keywords: Electrons ; Extraterrestrial Environment ; Ions ; *Jupiter ; Oxygen ; Protons ; Spacecraft ; Sulfur ; Temperature
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 5
    Publication Date: 2007-01-20
    Description: Litter decomposition provides the primary source of mineral nitrogen (N) for biological activity in most terrestrial ecosystems. A 10-year decomposition experiment in 21 sites from seven biomes found that net N release from leaf litter is dominantly driven by the initial tissue N concentration and mass remaining regardless of climate, edaphic conditions, or biota. Arid grasslands exposed to high ultraviolet radiation were an exception, where net N release was insensitive to initial N. Roots released N linearly with decomposition and exhibited little net N immobilization. We suggest that fundamental constraints on decomposer physiologies lead to predictable global-scale patterns in net N release during decomposition.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Parton, William -- Silver, Whendee L -- Burke, Ingrid C -- Grassens, Leo -- Harmon, Mark E -- Currie, William S -- King, Jennifer Y -- Adair, E Carol -- Brandt, Leslie A -- Hart, Stephen C -- Fasth, Becky -- New York, N.Y. -- Science. 2007 Jan 19;315(5810):361-4.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Natural Resource Ecology Laboratory, Colorado State University, 200 West Lake, Campus Mail 1499, Fort Collins, CO 80523-1499, USA.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/17234944" target="_blank"〉PubMed〈/a〉
    Keywords: *Biodegradation, Environmental ; Carbon/metabolism ; Climate ; *Ecosystem ; Humidity ; Mathematics ; Nitrogen/*metabolism ; Plant Leaves/metabolism ; Plant Roots/metabolism ; Plants/*metabolism ; Poaceae ; Regression Analysis ; Seasons ; Soil Microbiology ; Temperature ; Time Factors ; Trees
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 6
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2007-09-01
    Description: Selectivity rules in organic chemistry have been inferred largely from nonaqueous environments. In contrast, enzymes operate in water, and the chemical effect of the medium change remains only partially understood. Structural characterization of the "ladder" polyether marine natural products raised a puzzle that persisted for 20 years: Although the stereochemistry of adjacent tetrahydropyran (THP) cycles would seem to arise from a biosynthetic cascade of epoxide-opening reactions, experience in organic solvents argued consistently that such a pathway would be kinetically disfavored. We report that neutral water acts as an optimal promoter for the requisite ring-opening selectivity, once a single templating THP is appended to a chain of epoxides. This strategy offers a high-yielding route to the naturally occurring ladder core and highlights the likely importance of aqueous-medium effects in underpinning certain noteworthy enzymatic selectivities.〈br /〉〈br /〉〈a href="https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2810534/" target="_blank"〉〈img src="https://static.pubmed.gov/portal/portal3rc.fcgi/4089621/img/3977009" border="0"〉〈/a〉   〈a href="https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2810534/" target="_blank"〉This paper as free author manuscript - peer-reviewed and accepted for publication〈/a〉〈br /〉〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Vilotijevic, Ivan -- Jamison, Timothy F -- R01 GM-72566/GM/NIGMS NIH HHS/ -- R01 GM072566/GM/NIGMS NIH HHS/ -- R01 GM072566-05/GM/NIGMS NIH HHS/ -- New York, N.Y. -- Science. 2007 Aug 31;317(5842):1189-92.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/17761875" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Chemistry, Organic/*methods ; Dinoflagellida/metabolism ; Epoxy Compounds/*chemistry ; Ethers/chemical synthesis/*chemistry/metabolism ; Marine Toxins/biosynthesis/chemistry ; Molecular Conformation ; Pyrans/*chemistry ; Solvents ; Temperature ; Thermodynamics ; Water/*chemistry
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    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 7
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2007-01-16
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Fisher, Charles R -- Girguis, Peter -- New York, N.Y. -- Science. 2007 Jan 12;315(5809):198-9.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Biology, Pennsylvania State University, University Park, PA 16801, USA. cfisher@psu.edu〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/17218516" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Bacterial Proteins/analysis/*metabolism ; Carbon/metabolism ; Carbon Isotopes/analysis ; Chemoautotrophic Growth ; Citric Acid Cycle ; *Ecosystem ; Gammaproteobacteria/*metabolism ; Metabolic Networks and Pathways ; Oxidation-Reduction ; Pacific Ocean ; Polychaeta/*microbiology/*physiology ; Proteome ; *Proteomics ; Reproduction ; Sulfides/metabolism ; *Symbiosis ; Temperature
    Print ISSN: 0036-8075
    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 8
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2007-05-05
    Description: 〈br /〉〈br /〉〈a href="https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3984475/" target="_blank"〉〈img src="https://static.pubmed.gov/portal/portal3rc.fcgi/4089621/img/3977009" border="0"〉〈/a〉   〈a href="https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3984475/" target="_blank"〉This paper as free author manuscript - peer-reviewed and accepted for publication〈/a〉〈br /〉〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Skourtis, Spiros S -- Beratan, David N -- R01 GM048043/GM/NIGMS NIH HHS/ -- New York, N.Y. -- Science. 2007 May 4;316(5825):703-4.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Physics, University of Cyprus, Nicosia 1678, Cyprus. skourtis@ucy.ac.cy〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/17478711" target="_blank"〉PubMed〈/a〉
    Keywords: Bacterial Proteins/*chemistry/*metabolism ; Bacteriochlorophylls/metabolism ; *Electron Transport ; Kinetics ; Light ; Models, Chemical ; *Photosynthesis ; Photosynthetic Reaction Center Complex Proteins/*chemistry/*metabolism ; Rhodobacter sphaeroides/genetics/*metabolism ; Spectrum Analysis ; Temperature ; Thermodynamics ; Tryptophan/chemistry
    Print ISSN: 0036-8075
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  • 9
    Publication Date: 2007-03-31
    Description: A marine ecosystem model seeded with many phytoplankton types, whose physiological traits were randomly assigned from ranges defined by field and laboratory data, generated an emergent community structure and biogeography consistent with observed global phytoplankton distributions. The modeled organisms included types analogous to the marine cyanobacterium Prochlorococcus. Their emergent global distributions and physiological properties simultaneously correspond to observations. This flexible representation of community structure can be used to explore relations between ecosystems, biogeochemical cycles, and climate change.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Follows, Michael J -- Dutkiewicz, Stephanie -- Grant, Scott -- Chisholm, Sallie W -- New York, N.Y. -- Science. 2007 Mar 30;315(5820):1843-6.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Earth, Atmospheric and Planetary Sciences, Massachusetts Institute of Technology, 54-1514 MIT, Cambridge, MA 02139, USA. mick@mit.edu〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/17395828" target="_blank"〉PubMed〈/a〉
    Keywords: Biomass ; Computer Simulation ; *Ecosystem ; Geography ; Light ; Mathematics ; Models, Biological ; Oceans and Seas ; Phytoplankton/growth & development/*physiology ; Prochlorococcus/growth & development/*physiology ; Seawater/*microbiology ; Temperature
    Print ISSN: 0036-8075
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    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 10
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    American Association for the Advancement of Science (AAAS)
    Publication Date: 2007-03-17
    Description: 〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Krajick, Kevin -- New York, N.Y. -- Science. 2007 Mar 16;315(5818):1527.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/17363662" target="_blank"〉PubMed〈/a〉
    Keywords: Animals ; Arctic Regions ; Biodiversity ; *Cold Climate ; *Ecosystem ; Food Chain ; Ice Cover ; Invertebrates ; Plankton/growth & development ; Population Dynamics ; *Seawater ; Temperature
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    Electronic ISSN: 1095-9203
    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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