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  • 04. Solid Earth::04.08. Volcanology::04.08.01. Gases  (10)
  • Salinity  (5)
  • American Geophysical Union  (12)
  • Elsevier  (3)
  • Public Library of Science
  • 2015-2019  (15)
  • 1940-1944
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  • 1
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124(4), (2019):2861-2875, doi: 10.1029/2018JC014175.
    Description: Strong variability in sea surface salinity (SSS) in the Eastern Tropical Pacific (ETPac) on intraseasonal to interannual timescales was studied using data from the Soil Moisture and Ocean Salinity, Soil Moisture Active Passive, and Aquarius satellite missions. A zonal wave number‐frequency spectral analysis of SSS reveals a dominant timescale of 50–180 days and spatial scale of 8°–20° of longitude with a distinct seasonal cycle and interannual variability. This intraseasonal SSS signal is detailed in the study of 19 individual ETPac eddies over 2010–2016 identified by their sea level anomalies, propagating westward at a speed of about 17 cm/s. ETPac eddies trap and advect water in their core westward up to 40° of longitude away from the coast. The SSS signatures of these eddies, with an average anomaly of 0.5‐pss magnitude difference from ambient values, enable the study of their dynamics and the mixing of their core waters with the surroundings. Three categories of eddies were identified according to the location where they were first tracked: (1) in the Gulf of Tehuantepec, (2) in the Gulf of Papagayo, and (3) in the open ocean near 100°W–12°N. They all traveled westward near 10°N latitude. Category 3 is of particular interest, as eddies seeded in the Gulf of Tehuantepec grew substantially in the vicinity of the Clipperton Fracture Zone rise and in a region where the mean zonal currents have anticyclonic shear. The evolution of the SSS signature associated with the eddies indicates the importance of mixing to their dissipation.
    Description: This research was carried out in part at the Jet Propulsion Laboratory (JPL), California Institute of Technology, under a contract with NASA and part at LOCEAN (Sorbonne Université, CNRS, IRD, MNHN) under a CNES Postdoctoral fellowship. This work is supported by NASA Grants NNX11AE83G and NNX14AH38G and is a contribution to the TOSCA/SMOS‐Ocean proposal supported by CNES. We thank the reviewers for their thoughtfully comments that lead to a much‐improved manuscript. We benefited from numerous data sets made freely available and are listed here: The SMOS debias_v2 SSS have been produced by LOCEAN laboratory and ACRI‐st company that participate to the Ocean Salinity Expertise Center (CEC‐OS) of Centre Aval de Traitement des Donnees SMOS (CATDS). of CATDS at IFREMER, Plouzane, France (http://www.catds.fr/Products, see documentation: http://www.catds.fr/Products/Available‐products‐from‐CEC‐OS/L3‐Debiased‐Locean‐v2); the Aquarius/SAC‐D and SMAP data was produced by Remote Sensing Systems and distributed by PODAAC (https://podaac.jpl.nasa.gov/dataset/AQUARIUS_L3_SSS_SMI_7DAY_V4; https://podaac.jpl.nasa.gov/dataset/SMAP_RSS_L3_SSS_SMI_8DAY‐RUNNINGMEAN_V2); the SLA product is processed and distributed by CMEMS (http://marine.copernicus.eu); the global atlas of eddies is produced by AVISO (https://www.aviso.altimetry.fr/en/data/products/value‐added‐products/global‐mesoscale‐eddy‐trajectory‐product.html); the GPCP precipitation data set (http://eagle1.umd.edu/GPCP_CDR/Monthly_Data) is described in the project technical report (http://eagle1.umd.edu/GPCP_ICDR/GPCPmonthlyV2.3.pdf); Woods Hole Oceanographic Institution OAFlux evaporation data set (ftp://ftp.whoi.edu/pub/science/oaflux/data_v3); UCAR high‐resolution terrain data set (High res terrain data set https://rda.ucar.edu/datasets/ds759.2/#!description); Chelton et al. (1998) Global Atlas of the First‐Baroclinic Rossby Radius of Deformation and Gravity‐Wave Phase Speed (http://www‐po.coas.oregonstate.edu/research/po/research/rossby_radius/).
    Description: 2019-09-28
    Keywords: Eddies ; Mesoscale ; Salinity ; Pacific
    Repository Name: Woods Hole Open Access Server
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  • 2
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124(2), (2019): 1322-1330, doi:10.1029/2018JC014106.
    Description: A Lagrangian model is constructed for a surface column of initial height h(0) that propagates at an average speed u and is subject to excess (i.e., net) evaporation of q m/year. It is shown that these parameters combine to form an evaporation length, L = uh(0)/q, which provides an estimate for the distance the column must travel before evaporating completely. While these changes in the surface water level due to evaporation are compensated by entrainment of water into the overall column, the changes in either near‐surface salinity or isotopic compositions are retained and can be measured. Observations of surface salinity and isotopic compositions of δ18O and δD along 1,000‐ to 3,500‐km long transects are used to estimate values of L in the Red Sea, Mediterranean Sea, Indian Ocean, and Gulf Stream. The variations of salinity, δ18O and δD in all four basins are linear. As anticipated, the estimated value of L is smallest in the slowly moving and arid Red Sea and is greatest in the fast‐moving Gulf Stream.
    Description: The salinity and δ18O data collected aboard the Indian Ocean cruise described in Srivastava et al. (2007) can be accessed at this website (https://www.nodc.noaa.gov). The salinity, δ18O and δD data collected during the Red Sea cruise of the Interuniversity Institute for Marine Sciences, Eilat, described in Steiner et al. (2014) and can be accessed in the supporting information section of doi: 10.1073/pnas.1414323111. H. B. acknowledges the support provided by the Eshkol Foundation of the Israel Ministry of Science.
    Description: 2019-07-26
    Keywords: Air-sea interaction ; Evaporation ; Semienclosed basins ; Salinity ; Stable isotopes ; Thermohaline circulation
    Repository Name: Woods Hole Open Access Server
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  • 3
    Publication Date: 2022-05-25
    Description: © The Author(s), 2017. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Regional Studies in Marine Science 18 (2018): 1-10, doi:10.1016/j.rsma.2017.12.004.
    Description: The variations of temperature and salinity in the Sudanese coastal zone of the Red Sea are studied for the first time using measurements acquired from survey cruises during 2009–2013 and from a mooring during 2014–2015. The measurements show that temperature and salinity variability above the permanent pycnocline is dominated by seasonal signals, similar in character to seasonal temperature and salinity oscillations observed further north on the eastern side of the Red Sea. Using estimates of heat flux, circulation and horizontal temperature/salinity gradients derived from a number of sources, we determined that the observed seasonal signals of temperature and salinity are not the product of local heat and mass flux alone, but are also due to alongshore advection of waters with spatially varying temperature and salinity. As the temperature and salinity gradients, characterized by warmer and less saline water to the south, exhibit little seasonal variation, the seasonal salinity and temperature variations are closely linked to an observed seasonal oscillation in the along-shore flow, which also has a mean northward component. We find that the inclusion of the advection terms in the heat and mass balance has two principal effects on the computed temperature and salinity series. One is that the steady influx of warmer and less saline water from the south counteracts the long-term trend of declining temperatures and rising salinities computed with only the local surface flux terms, and produces a long-term steady state in temperature and salinity. The second effect is produced by the seasonal alongshore velocity oscillation and most profoundly affects the computed salinity, which shows no seasonal signal without the inclusion of the advective term. In both the observations and computed results, the seasonal salinity signal lags that of temperature by roughly 3 months.
    Description: The SPS surveys were funded by the Norwegian Norad’s Program for Master Studies and organized by IMR–RSU in Port Sudan. The central Red Sea mooring data were acquired as part of a WHOI–KAUST collaboration funded by Award Nos. USA00001, USA00002, and KSA00011 to the WHOI by the KAUST in the Kingdom of Saudi Arabia. The work of I. Skjelvan and A.M. Omar was partly supported by the Research Council of Norway through the MIMT Center for Research-based Innovation. This work is part of a Ph.D. project at GFI–UiB funded by the Norwegian Quota program .
    Keywords: Coastal Red Sea ; Temperature ; Salinity ; Time series ; Seasonality ; Alongshore advection
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  • 4
    Publication Date: 2021-03-01
    Description: A new period of eruptive activity started at Turrialba volcano, Costa Rica, in 2010 after almost 150 years of quiescence. This activity has been characterized by sporadic explosions whose frequency clearly increased since October 2014. This study aimed to identify the mechanisms that triggered the resumption of this eruptive activity and characterize the evolution of the phenomena over the past 2 years. We integrate 3He/4He data available on fumarole gases collected in the summit area of Turrialba between 1999 and 2011 with new measurements made on samples collected between September 2014 and February 2016. The results of a petrological investigation of the products that erupted between October 2014 and May 2015 are also presented. We infer that the resumption of eruptive activity in 2010 was triggered by a replenishment of the plumbing system of Turrialba by a new batch of magma. This is supported by the increase in 3He/4He values observed since 2005 at the crater fumaroles and by comparable high values in September 2014, just before the onset of the new eruptive phase. The presence of a number of fresh and juvenile glassy shards in the erupted products increased between October 2014 and May 2015, suggesting the involvement of new magma with a composition similar to that erupted in 1864–1866. We conclude that the increase in 3He/4He at the summit fumaroles since October 2015 represents strong evidence of a new phase of magma replenishment, which implies that the level of activity remains high at the volcano.
    Description: Published
    Description: 3V. Proprietà dei magmi e dei prodotti vulcanici
    Description: 4V. Dinamica dei processi pre-eruttivi
    Description: 5V. Dinamica dei processi eruttivi e post-eruttivi
    Description: JCR Journal
    Keywords: Turrialba volcano ; eruptive activity ; 3He/4He ; fumarole gases ; glassy shards ; juvenile component ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.08. Volcanic arcs ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
    Publication Date: 2020-12-15
    Description: We report on a systematic record of SO2 flux emissions from individual vents of Etna volcano (Sicily), which we obtained using a permanent UV camera network. Observations were carried out in summer 2014, a period encompassing two eruptive episodes of the New South East Crater (NSEC) and a fissure-fed eruption in the upper Valle del Bove. We demonstrate that our vent-resolved SO2 flux time series allow capturing shifts in activity from one vent to another and contribute to our understanding of Etna’s shallowplumbingsystemstructure.We findthatthe fissureeruptioncontributed~50,000tofSO2 or~30%of the SO2 emitted by the volcano during the 5 July to 10 August eruptive interval. Activity from this eruptive ventgraduallyvanishedon10August,markingaswitchofdegassingtowardtheNSEC.Onsetofdegassingat the NSEC was a precursory to explosive paroxysmal activity on 11–15 August.
    Description: Published
    Description: 7511-7519
    Description: 3V. Dinamiche e scenari eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Records of SO2 flux emissions from Etna’sindividualventsallowcapturing shifts in volcanic activity ; Vent-resolved SO2 flux time series provide constraints on geometry of the shallow plumbing system ; Vent-resolved SO2 flux time series demonstrate SO2 flux increase precursory to paroxysmal (lava fountaining) activity ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
    Publication Date: 2022-05-25
    Description: © The Author(s), 2016. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Journal of Hydrology: Regional Studies 11 (2017): 147-165, doi:10.1016/j.ejrh.2015.12.056.
    Description: The study region encompasses the nearshore, coastal waters off west Maui, Hawaii. Here abundant groundwater—that carries with it a strong land-based fingerprint—discharges into the coastal waters and over a coral reef. Coastal groundwater discharge is a ubiquitous hydrologic feature that has been shown to impact nearshore ecosystems and material budgets. A unique combined geochemical tracer and oceanographic time-series study addressed rates and oceanic forcings of submarine groundwater discharge at a submarine spring site off west Maui, Hawaii. Estimates of submarine groundwater discharge were derived for a primary vent site and surrounding coastal waters off west Maui, Hawaii using an excess 222Rn (t1/2 = 3.8 d) mass balance model. Such estimates were complemented with a novel thoron (220Rn, t1/2 = 56 s) groundwater discharge tracer application, as well as oceanographic time series and thermal infrared imagery analyses. In combination, this suite of techniques provides new insight into the connectivity of the coastal aquifer with the near-shore ocean and examines the physical drivers of submarine groundwater discharge. Lastly, submarine groundwater discharge derived constituent concentrations were tabulated and compared to surrounding seawater concentrations. Such work has implications for the management of coastal aquifers and downstream nearshore ecosystems that respond to sustained constituent loadings via this submarine route.
    Description: This research was primarily funded by the USGS Coastal and Marine Geology Program (CMGP). CRG acknowledges support from the National Oceanic and Atmospheric Administration, Project R/SB-12, which is sponsored by the University of Hawaii Sea Grant College Program, SOEST, under Institutional Grant No. NA14OAR4170071 from NOAA Office of Sea Grant, Department of Commerce.
    Keywords: Regional groundwater flow ; Submarine groundwater discharge ; Radon ; Thoron ; Thermal infrared ; Oceanographic time series ; Salinity
    Repository Name: Woods Hole Open Access Server
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  • 7
    Publication Date: 2021-06-25
    Description: Airborne and ground-based differential optical absorption spectroscopy observations have been carried out at the volcano Nyiragongo (Democratic Republic of Congo) tomeasure SO2 and bromine monoxide (BrO) in the plume inMarch 2004 and June 2007, respectively. Additionally filter pack andmulticomponent gas analyzer system (Multi-GAS)measurements were carried out in June 2007. Ourmeasurements provide valuable information on the chemical composition of the volcanic plume emitted fromthe lava lake of Nyiragongo. The main interest of this study has been to investigate for the first time the bromine emission flux of Nyiragongo (a rift volcano) and the BrO formation in its volcanic plume. Measurement data and results from a numerical model of the evolution of BrO in Nyiragongo volcanic plume are compared with earlier studies of the volcanic plume of Etna (Italy). Even though the bromine flux from Nyiragongo (2.6 t/d) is slightly greater than that from Etna (1.9 t/d), the BrO/SO2 ratio (maximum 7 × 10 5) is smaller than in the plume of Etna (maximum 2.1 × 10 4). A one-dimensional photochemical model to investigate halogen chemistry in the volcanic plumes of Etna and Nyiragongo was initialized using data from Multi-GAS and filter pack measurements. Model runs showed that the differences in the composition of volcanic volatiles led to a smaller fraction of total bromine being present as BrO in the Nyiragongo plume and to a smaller BrO/SO2 ratio.
    Description: Published
    Description: 277-291
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: Intraplate volcano Nyiragongo is bromine rich although chlorine poor ; BrO/Br in volcanic plumes depends on initial plume composition ; Determination of Nyiragongo chlorine, bromine, sulfur emission strength ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
    Publication Date: 2017-04-04
    Description: Piton de la Fournaise (PdF) is recognised as one of the world’s most active volcanoes in terms of eruptive frequency and the substantial quantity of lava produced. Yet, with the sole exception of rather modest intracrateric fumarole activity, this seems to be in contrast with an apparent absence of any type of natural fluid emission during periods of quiescence. Measurement campaigns were undertaken during a long-lasting quiescent period (2012-2014) and just after a short lived summit eruption (June 2014) in order to identify potential degassing areas in relation to the main structural features of the volcano (ex. rift zones) with the aim of developing a broader understanding of the geometry of the plumbing and degassing system. In order to assess the possible existence of anomalous soil CO2 flux, 513 measurements were taken along transects roughly orthogonal to the known tectonic lineaments crossing PdF edifice. In addition, 53 samples of gas for C isotope analysis were taken at measurement points that showed a relatively high CO2 concentration in the soil. CO2 flux values range from 10 to 1300 g m-2 d-1 while 13C are between -26.6 to -8‰. The results of our investigation clearly indicate that there is a strong spatial correlation between the anomalous high values of diffusive soil emissions and the main rift zones cutting the PdF massif and, moreover, that generally high soil CO2 fluxes show a d13C signature clearly related to a magmatic origin.
    Description: INSU (CNRS) and La Réunion Préfecture (Projet pour la quantification de l’aléa volcanique à La Réunion)
    Description: Published
    Description: 4388–4404
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: CO2 soil degassing anomalies at Piton de la Fournaise ; d13C magmatic signature ; Close link between anomalous CO2 degassing and the main seismotectonic structures ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 9
    Publication Date: 2022-05-25
    Description: © The Author(s), 2016. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Continental Shelf Research 124 (2016): 165-181, doi:10.1016/j.csr.2016.06.005.
    Description: A new hydrographic climatology has been created for the continental shelf region, extending from the Labrador shelf to the Mid-Atlantic Bight. The 0.2-degree climatology combines all available observations of surface and bottom temperature and salinity collected between 1950 and 2010 along with the location, depth and date of these measurements. While climatological studies of surface and bottom temperature and salinity have been presented previously for various regions along the Canadian and U.S. shelves, studies also suggest that all these regions are part of one coherent system. This study focuses on the coherent structure of the mean seasonal cycle of surface and bottom temperature and salinity and its variation along the shelf and upper slope. The seasonal cycle of surface temperature is mainly driven by the surface heat flux and exhibits strong dependency on latitude (r≈−0.9). The amplitude of the seasonal cycle of bottom temperature is rather dependent on the depth, while the spatial distribution of bottom temperature is correlated with latitude. The seasonal cycle of surface salinity is influenced by several components, such as sea-ice on the northern shelves and river discharge in the Gulf of St. Lawrence. The bottom salinity exhibits no clear seasonal cycle, but its spatial distribution is highly correlated with bathymetry, thus Slope Water and its intrusion on the shelf can be identified by its relatively high salinity compared to shallow, fresher shelf water. Two different regimes can be identified, especially on the shelf, separated by the Laurentian Channel: advection influences the phasing of the seasonal cycle of surface salinity and bottom temperature to the north, while in the southern region, river runoff and air-sea heat flux forcing are dominant, especially over the shallower bathymetry.
    Description: Support from NSF OCE PO to Y-OK (OCE-1242989 and OCE-1435602) and SJL (OCE-1332666).
    Keywords: Seasonal climatology ; Temperature ; Salinity ; Dataset ; Shelf
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  • 10
    Publication Date: 2022-05-04
    Description: Abstract San Miguel volcano, El Salvador, erupted on 29 December 2013, after a 46 year period characterized by weak activity. Prior to the eruption a trend of increasing SO2 emission rate was observed, with all values measured after mid-November greater than the average value of the previous year (~310 t d 1). During the eruption, SO2 emissions increased from the level of ~330 t d 1 to 2200 t d 1, dropping after the eruption to an average level of 680 t d 1. Wind measurements and SO2 emission rates during the preeruptive, syneruptive, and posteruptive stages were used to model SO2 dispersion around the volcano. Atmospheric SO2 concentration exceeded the dangerous threshold of 5 ppm in the crater region and in some sectors with medium elevation of the highly visited volcanic cone. Combining the SO2 emission rate with measured CO2/SO2, HCl/SO2, and HF/SO2 plume gas ratios, we estimate the CO2, HCl, and HF outputs for the first time on this volcano.
    Description: Published
    Description: 5847–5854
    Description: 3V. Dinamiche e scenari eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: SO2 flux, Clorine and CO2 at San miguel, cloud dispersion and hazard ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 11
    Publication Date: 2021-06-16
    Description: This study performed the first assessment of the volcanic gas output from the Central Volcanic Zone (CVZ) of northern Chile. We present the fluxes and compositions of volcanic gases (H2O, CO2, H2, HCl, HF, and HBr) from five of the most actively degassing volcanoes in this region—Láscar, Lastarria, Putana, Ollagüe, and San Pedro—obtained during field campaigns in 2012 and 2013. The inferred gas plume compositions for Láscar and Lastarria (CO2/Stot = 0.9–2.2; Stot/HCl = 1.4–3.4) are similar to those obtained in the Southern Volcanic Zone of Chile, suggesting uniform magmatic gas fingerprint throughout the Chilean arc. Combining these compositions with our own UV spectroscopy measurements of the SO2 output (summing to ~1800 t d 1 for the CVZ), we calculate a cumulative CO2 output of 1743–1988 t d 1 and a total volatiles output of 〉20,200 t d 1. 1.
    Description: Published
    Description: 4961-4969
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: Gas output from the Central Volcanic Zone ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 12
    Publication Date: 2017-04-04
    Description: A new eruption started at Stromboli on August 6, 2014, which had been preceded by 2 months of increased Strombolian activity and several lava overflows from the craters. The eruption was characterized by a lava effusion in Sciara del Fuoco from a fracture at 650 m a.s.l. that lasted until November 13–17. Here we present the first geochemical observations of this eruption, based on the soil CO2 flux in the summit area, and on 3He/4He ratios in the thermal waters near Stromboli village. We infer that this eruption was triggered by the gradual replenishment of the feeding system by a CO2- and 3He-rich magma at the end of 2013 and after June 2014, suggested by the increase in 3He/4He ratio before eruption, which reached its highest value since 2007. We thus infer that this eruption was unusual and we finally speculate on the evolutionary scenario of post eruption.
    Description: Published
    Description: 2235–2243
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: 3V. Dinamiche e scenari eruttivi
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: Stromboli ; eruption ; soil CO2 flux ; 3He/4He ratio ; thermal waters ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 13
    Publication Date: 2017-04-04
    Description: La Fossa quiescent volcano and its surrounding area on the Island of Vulcano (Italy) are characterized by intensive, persistent degassing through both fumaroles and diffuse soil emissions. Periodic degassing crises occur, with marked increase in temperature and steam and gas output (mostly CO2) from crater fumaroles and in CO2 soil diffuse emission from the crater area as well as from the volcano flanks and base. The gas hazard of the most inhabited part of the island, Vulcano Porto, was investigated by simulating the CO2 dispersion in the atmosphere under different wind conditions. The DISGAS (DISpersion of GAS) code, an Eulerian model based on advection-diffusion equations, was used together with the mass-consistent Diagnostic Wind Model. Numerical simulations were validated by measurements of air CO2 concentration inside the village and along the crater’s rim by means of a Soil CO2 Automatic Station and a Tunable Diode Laser device. The results show that in the village of Vulcano Porto, the CO2 air concentration is mostly due to local soil degassing, while the contribution from the crater gas emission is negligible at the breathing height for humans and always remains well below the lowest indoor CO2 concentration threshold recommended by the health authorities (1000 ppm). Outdoor excess CO2 maxima up to 200 ppm above local background CO2 air concentration are estimated in the center of the village and up to 100 ppm in other zones. However, in some ground excavations or in basements the health code threshold can be exceeded. In the crater area, because of the combined effect of fumaroles and diffuse soil emissions, CO2 air concentrations can reach 5000–7000 ppm in low-wind conditions and pose a health hazard for visitors.
    Description: Published
    Description: 5398–5413
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: reserved
    Keywords: Volcanogenic carbon dioxide plume ; Air CO2 concentration ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 14
    Publication Date: 2017-04-04
    Description: The fumarolic gas output has not been quantified for any of the currently deforming calderas worldwide, due to the lack of suitable gas flux sensing techniques. In view of resumption of ground uplift (since 2005) and the associated variations in gas chemistry, Campi Flegrei, in southern Italy, is one of the restless calderas where gas flux observations are especially necessary. Here we report the first ever obtained estimate of the Campi Flegrei fumarolic gas output, based on a set of MultiGAS surveys (performed in 2012 and 2013) with an ad-hoc-designed measurement setup. We estimate that the current Campi Flegrei fumarolic sulphur (S) flux is low, on the order of 1.5–2.2 tons/day, suggesting substantial scrubbing of magmatic S by the hydrothermal system. However, the fumarolic carbon dioxide (CO2) output is ∼460±160 tons/day (mean±SD), which is surprisingly high for a dormant volcano in the hydrothermal stage of activity, and results in a combined (fumaroles + soil) CO2 output of ∼1560 tons/day. Assuming magma to be the predominant source, we propose that the current CO2 output can be supplied by either (i) a large (0.6–4.6 km3), deeply stored (〉7 km) magmatic source with low CO2 contents (0.05–0.1 wt%) or (ii) by a small to medium-sized (∼0.01–0.1 km3) but CO2-rich (2 wt%) magma, possibly stored at pressures of ∼100 to 120 MPa. Independent geophysical evidence (e.g., inferred from geodetic and gravity data) is needed to distinguish between these two possibilities.
    Description: Published
    Description: 4153–4169
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Campi Flegrei ; calderas ; gas output ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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    Type: article
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  • 15
    Publication Date: 2017-04-04
    Description: The volcanic plumes from degassing Etna (Italy) were extensively probed with instruments onboard the Deutsches Zentrum für Luft- und Raumfahrt research aircraft Falcon during the contrail, volcano, and cirrus experiment CONCERT on 29/30 September 2011. Up to 10.4 ppmv SO2 and 0.3 ppmv HCl were detected with the atmospheric chemical ionization mass spectrometer AIMS at 3.1 km altitude and 20 km distance to the summit. HNO3 is the dominant reactive nitrogen component in the plumes. Linking aircraft and ground-based observations by Hybrid Single-Particle Lagrangian Integrated Trajectory dispersion modeling, we identify two crater plumes with different compositions primarily injected by the Bocca Nuova and North East craters. Uniquely, we follow their chemical evolution up to 5 h plume age. Our results show that CO2/SO2 and SO2/HCl molar ratios are stable in the ageing plumes. Hence, conversion of SO2 to H2SO4 and partitioning of HCl in acidic plume particles play a minor role at dry tropospheric conditions. Thus, these trace gases allow monitoring volcanic activity far from the crater.
    Description: Published
    Description: 2196–2203
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: aircraft measurements ; CO2/SO2 and SO2/HCl molar ratios are stable during atmospheric plume evolution ; These trace gas ratios allow monitoring volcanic activity far from the crater ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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