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  • Articles  (190)
  • acidification  (98)
  • monitoring  (75)
  • Chemical Engineering
  • Fisheries
  • Organic Chemistry
  • Energy, Environment Protection, Nuclear Power Engineering  (180)
  • Economics  (13)
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  • 1
    ISSN: 1573-0840
    Keywords: acid rain ; photochemical smog ; ground-level ozone ; particulate matter ; modelling ; monitoring ; real-time prediction ; policy application
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geography , Geosciences
    Notes: Abstract Acid rain and photochemical smog are two regionalair-quality issues that have received considerableattention in the last two decades due to their harmfuleffects. Health impacts of particulate matter (PM) inthe atmosphere is another issue of concern. Sulphur dioxide emission controls were introducedin both Canada and the U.S.A. to reduceacid-deposition-related damage. While these emissionreductions have already resulted in reduced sulphatedeposition, based on results from modelling studiesmuch of southeastern Canada is still expected toexperience damaging levels of acid deposition evenafter all currently legislated emission controls arefully implemented. Moreover, there has not been acorresponding reduction in the acidity ofprecipitation. This may be attributable to aconcurrent reduction in base-cation concentration inprecipitation. Models were also developed to understand theformation, transport and diffusion of troposphericozone. The models have been used to provide policyguidance for emission control options to reduceground-level ozone to acceptable limits. In thesummer of 1997 a Canadian pilot project was initiatedto provide real-time forecasts of ground-level ozonein the southeastern part of the province of NewBrunswick in eastern Canada. With the emergence of fine Particulate Matter(PM2.5) as a health concern, efforts are underwayin Canada to develop a “unified'' regional air-qualitymodel that will address the combined impacts ofvarious pollutants in the atmosphere. In this effortthe atmosphere is viewed as a single entity where theimpacts of multiple pollutants are considered at thesame time.
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  • 2
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    Journal of management & governance 4 (2000), S. 53-67 
    ISSN: 1572-963X
    Keywords: asymmetries between managers and employees ; incentive contracts ; monitoring ; time constraints ; time horizon
    Source: Springer Online Journal Archives 1860-2000
    Topics: Economics
    Notes: Abstract Governance in organizations according to traditionalagency theory is based on the premise that managersand employees do not have identical goals. As aconsequence, employees need to be monitored andcontrolled. If legal contracts are not sufficient forproper control, incentive contracts should be used. This paper argues that incentive contracts are notsufficient to solve governance issues in organizationsdue to problems in measurability and enforceability ofpresumed contract violations. Such problems arecomplicated by asymmetries in power, perspectives andaspirations between managers and employees. Acognitive argument is advanced suggesting that timeconstraints and bounded rationality render the idea ofmonitoring relatively ineffective. Governance ideasthat focus on communication flow and informationsharing are described. The role that other cognitiveelements such as memory play in a more comprehensiveand interdisciplinary framework for understandinggovernance relations is discussed.
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  • 3
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    Review of quantitative finance and accounting 15 (2000), S. 325-347 
    ISSN: 1573-7179
    Keywords: earnings management ; information asymmetry ; monitoring ; seasoned equity offerings
    Source: Springer Online Journal Archives 1860-2000
    Topics: Economics
    Notes: Abstract This paper conducts an empirical investigation of the relationship between information asymmetry and earnings management predicted by Dye (1988) and Trueman and Titman (1988). When information asymmetry is high, stakeholders do not have sufficient resources, incentives, or access to relevant information to monitor manager's actions, which gives rise to the practice of earnings management (Schipper, 1989; Warfield et al., 1995). Empirical results suggest a systematic relationship between the magnitude of information asymmetry and the level of earnings management in two different settings.
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  • 4
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    Open economies review 11 (2000), S. 69-109 
    ISSN: 1573-708X
    Keywords: bank crises ; bad banking practices ; incentives ; moral hazard ; monitoring ; supervision ; regulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Economics
    Notes: Abstract Recent bank crises in developed and developing countries have underlined the question of a good “regulatory regime,” which is a wider concept than the set of prudential principles and business rules established by external regulatory agencies. The role of external regulation in fostering a safe and sound banking system is limited. The incentive's structure for private banks and the efficiency of monitoring and supervision have to play a great role. Liberalization of markets can have bad effects in the transitional period, but advantages can be enormous after the system starts to work correctly. The main lesson of recent bank crises is that there needs to be more effective surveillance of financial institutions both by supervisory authorities and by markets. Effective regulation (internal and external) and supervision of banks and financial institutions have the potential to give a major contribution to the stability and robustness of financial system.
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  • 5
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    Mitigation and adaptation strategies for global change 5 (2000), S. 189-216 
    ISSN: 1573-1596
    Keywords: certification ; Clean Development Mechanism ; energy efficiency ; evaluation ; global climate change ; greenhouse gas emissions ; joint implementation ; monitoring ; reporting ; verification
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Abstract In this paper, we present an overview of guidelinesdeveloped for the monitoring, evaluation, reporting,verification, and certification (MERVC) ofenergy-efficiency projects for climate changemitigation. The monitoring and evaluation ofenergy-efficiency projects is needed to determine moreaccurately their impact on greenhouse gas (GHG)emissions and other attributes, and to ensure that theglobal climate is protected and that countryobligations are met. Reporting, verification andcertification will be needed for addressing therequirements of the Kyoto Protocol. While the cost ofmonitoring and evaluation of energy-efficiencyprojects is expected to be about 5–10% of a project'sbudget, the actual cost of monitoring and evaluationwill vary depending on many factors, including thelevel of precision required for measuring energy andGHG reductions, type of project, and amount of fundingavailable.
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  • 6
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    Journal of business ethics 28 (2000), S. 255-265 
    ISSN: 1573-0697
    Keywords: email ; internet ; monitoring ; privacy ; surveillance ; workplace ; World Wide Web
    Source: Springer Online Journal Archives 1860-2000
    Topics: Philosophy , Economics
    Notes: Abstract This paper examines workplace surveillance and monitoring. It is argued that privacy is a moral right, and while such surveillance and monitoring can be justified in some circumstances, there is a presumption against the infringement of privacy. An account of privacy precedes consideration of various arguments frequently given for the surveillance and monitoring of employees, arguments which look at the benefits, or supposed benefits, to employees as well as to employers. The paper examines the general monitoring of work, and the monitoring of email, listservers and the World Wide Web. It is argued that many of the common justifications given for this surveillance and monitoring do not stand up to close scrutiny.
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  • 7
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    Environmental monitoring and assessment 64 (2000), S. 379-390 
    ISSN: 1573-2959
    Keywords: monitoring ; research ; CISNet ; environmental stressors
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The U.S. Environmental Protection Agency (EPA), National Oceanic and Atmospheric Administration (NOAA), and National Aeronautics and Space Administration (NASA) have formed a partnership to establish pilot sites for the development of a network known as the Coastal Intensive Site Network (CISNet). CISNet is composed of intensive, long-term monitoring and research sites around the U.S. marine and Great Lakes coasts. In this partnership, EPA and NOAA are funding research and monitoring programs at pilot sites that utilize ecological indicators and investigate the ecological effects of environmental stressors. NASA is funding research aimed at developing a remote sensing capability that will augment or enhance in situresearch and monitoring programs selected by EPA and NOAA. CISNet has three objectives: 1) to develop a sound scientific basis for understanding ecological responses to anthropogenic stresses in coastal environments, including the interaction of exposure, environment/climate, and biological/ecological factors in the response, and the spatial and temporal nature of these interactions, 2) to demonstrate the value of developing data from selected sites intensively monitored to examine the relationships between changes in environmental stressors, including anthropogenic and natural stresses, and ecological response, and 3) to provide intensively monitored sites for development and evaluation of indicators of change in coastal systems.
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  • 8
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    Environmental monitoring and assessment 64 (2000), S. 409-419 
    ISSN: 1573-2959
    Keywords: monitoring ; assessment ; water ; sediment ; bioaccumulation ; toxicity ; pesticides ; mercury ; PCB
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The San Francisco Estuary Regional Monitoring Program for Trace Substances (RMP) began in 1993 and is sponsored by 74 local, state, and federal agencies and companies through their discharge or Bay use permits. The RMP monitors water, sediment, toxicity, and bivalve bioaccumulation at 25 sites in the Bay that are considered to represent "background" conditions. Several major environmental issues have been identified by the RMP. Polychlorinated biphenyls and mercury were often above water quality guidelines, and often occurred in fish tissues above U.S. Environmental Protection Agency (U.S. EPA) screening values. Concentrations do not appear to be decreasing, suggesting continuing inputs. Episodes of aquatic toxicity often occurred following runoff events that transport contaminants into the Bay from urbanized and agricultural portions of the watershed. Sediment toxicity occurred throughout the Bay, and has been correlated with concentrations of specific contaminants (chlordanes, polynuclear aromatic hydrocarbons) at some locations; mixtures of contaminants were probably also important. Since the RMP does not monitor all ecosystem components, assessments of the overall condition of the Bay cannot be made. However, in terms of contamination, the RMP samples suggest that the South Bay, and North Bay sites are moderately contaminated.
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  • 9
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    Environment, development and sustainability 2 (2000), S. 277-304 
    ISSN: 1573-2975
    Keywords: Systems of Knowledge ; Local Knowledge ; Fisheries ; Resource Management
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Sociology
    Notes: Abstract During the last 20 years, the existence of rich systems of local knowledge, and their vital support to resource use and management regimes, has been demonstrated in a wide range of biological, physical and geographical domains, such as agriculture, animal husbandry, forestry and agroforestry, medicine, and marine science and fisheries. Local knowledge includes empirical and practical components that are fundamental to sustainable resource management. Among coastal-marine fishers, for example, regular catches and, often, long-term resource sustainment are ensured through the application of knowledge that encompasses empirical information on fish behaviour, marine physical environments, fish habitats and the interactions among ecosystem components, as well as complex fish taxonomies. Local knowledge is therefore an important cultural resource that guides and sustains the operation of customary management systems. The sets of rules that compose a fisheries management system derive directly from local concepts and knowledge of the resources on which the fishery is based. Beyond the practical and the empirical, it is essential to recognise the fundamental socio-cultural importance of local knowledge to any society. It is through knowledge transmission and socialisation that worldviews are constructed, social institutions perpetuated, customary practices established, and social roles defined. In this manner, local knowledge and its transmission, shape society and culture, and culture and society shape knowledge. Local knowledge is of great potential practical value. It can provide an important information base for local resources management, especially in the tropics, where conventionally-used data are usually scarce to non-existent, as well as providing a shortcut to pinpoint essential scientific research needs. To be useful for resources management, however, it must be systematically collected and scientifically verified, before being blended with complementary information derived from Western-based sciences. But local knowledge should not be looked on with only a short-term utilitarian eye. Arguments widely accepted for conserving biodiversity, for example, are also applicable to the intellectual cultural diversity encompassed in local knowledge systems: they should be conserved because their utility may only be revealed at some later date or owing to their intrinsic value as part of the world's global heritage. At least in cultures with a Western liberal tradition, more than lip-service is now being paid to alternative systems of knowledge. The denigration of alternative knowledge systems as backward, inefficient, inferior, and founded on myth and ignorance has recently begun to change. Many such practices are a logical, sophisticated and often still-evolving adaptation to risk, based on generations of empirical experience and arranged according to principles, philosophies and institutions that are radically different from those prevailing in Western scientific circles, and hence all-but incomprehensible to them. But steadfastly held prejudices remain powerful. In this presentation I describe the 'design principles' of local knowledge systems, with particular reference to coastal-marine fishing communities, and their social and practical usefulness. I then examine the economic, ideological and institutional factors that combine to perpetuate the marginalisation and neglect of local knowledge, and discuss some of the requirements for applying local knowledge in modern management.
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  • 10
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    Environmental monitoring and assessment 64 (2000), S. 1-8 
    ISSN: 1573-2959
    Keywords: assessment ; ecology ; estuaries ; indicators ; mid-Atlantic ; monitoring ; scale ; trends ; West
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Management for the future sustainability and integrity of our nation's ecological resources requires concepts and tools for measuring status and trends in these resources at multiple spatial and temporal scales and at multiple levels of biological organization. Key elements of this process are ecologically meaningful indicators and cost-effective monitoring designs. The Environmental Monitoring and Assessment Program (EMAP) advances the science needed for measuring ecosystem condition and trends. Most recently the EMAP approach has been successfully used by participants in the Mid-Atlantic Integrated Assessment (MAIA), including EPA's Office of Research and Development, EPA's Region III, and the States of the Mid-Atlantic. The participants in MAIA have produced a regional landscape atlas, state of the estuaries report, and state of the streams report. The work in MAIA is currently moving from monitoring into the assessment phase. The Western EMAP Pilot (Western Pilot), will be a test of our current MAIA indicators and technology for applicability in western ecosystems. New indicators and designs may be needed in the Western Pilot for assessments at the level of EPA's Regions, of the states, and of the Tribes; these assessments will be done so that they can be combined to provide regional assessments. Our coastal monitoring program in the Western estuaries will also be initiated shortly. Subsequently, this will be expanded to the Gulf and Atlantic coasts to provide the current condition of our national estuaries. By continuing to improve the science of monitoring, EMAP researchers will remove data gaps and allow the unequivocal assessment of the health of the nation's resources.
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  • 11
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    Environmental monitoring and assessment 65 (2000), S. 119-127 
    ISSN: 1573-2959
    Keywords: DOAS ; Differential Optical Absorption Spectroscopy ; urban air quality ; monitoring ; vertical distribution ; ozone
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The concentrations of ozone, NO2 and SO2, measured with a DOAS system 70 m above ground level in the city of Graz were compared with data from conventional ground stations. The dependence of vertical trace-gas distributions on stability categories and time of the day or year was investigated. Concerning the maximum ozone concentrations in summer, the DOAS data are representative for the ground-level situation. In average, the concentrations 70 m above ground are more than twice the ground-level concentrations. It has been shown that beside the reaction with NO, dry deposition is an important sink for ozone near the surface. The DOAS NO2-concentrations are representative for ground-level conditions in summer, except for the morning maximum of NO2. In winter the DOAS NO2-concentrations amount for 73% of the ground level values in average. Concerning the slow reacting trace gas SO2, the DOAS data are always representative for the ground-level conditions.
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  • 12
    ISSN: 1573-2959
    Keywords: mercury ; mining ; monitoring ; aquatic ; acid mine drainage ; floc ; Clear Lake ; remediation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Mercury (Hg) in the aquatic ecosystem of Clear Lake has been documented since the 1970s when fishes were found to have elevated levels of toxic methyl mercury (meHg). Mining practices at the Sulphur Bank Mercury Mine (active intermittently from 1872–1957) along the shoreline of Clear Lake included the bulldozing of waste rock and overburden ore into the shallow nearshore regions of the lake and the creation of steeply sloped piles of waste rock at the water's edge. This process, plus erosion of the waste rock piles, resulted in the accumulation of an estimated 100 metric tons of Hg in Clear Lake. A monitoring program to assess Hg in Clear Lake was established in 1992, and conducted continuously from 1994. Drought conditions in California had persisted for ca. 6 yrs prior to 1992, when the U.S. Environmental Protection Agency (USEPA) remediated the steeply sloped eroding waste rock piles, which appeared to reduce sediment Hg concentrations significantly. In April 1995, a white flocculent material was observed in Clear Lake adjacent to the mine and has been observed every year since, leading to the discovery of ongoing acid mine drainage (AMD), low pH fluids high in Hg and extremely high in sulfate. AMD is now believed to be the most likely cause of elevated meHg in Clear Lake. The discovery of this source of meHg production in Clear Lake, which will significantly influence remedial options, was only made possible by implementation of a diligent monitoring program.
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  • 13
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    Water, air & soil pollution 118 (2000), S. 231-244 
    ISSN: 1573-2932
    Keywords: acidification ; air pollution ; critical loads ; ecological factors
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Ecosystem sensitivity to acid deposition can be a basis for thederivation of cost-effective strategies to sulfur and nitrogenpollutant control, consequently is widely concerned around theworld. In the article, the relative sensitivity of terrestrialecosystem to acid deposition in South China is assessed andmapped using a new sensitivity classification system suitable tosubtropical ecosystem. The result shows that the distribution ofecosystem sensitivity to acid deposition in South China isalmost zonal, on the whole, sensitivity increases from the northand west to the south and east. The most sensitive areas are thenorthwest and southeast of Zhejiang province, the central partof Fujian province, and the northeast of Guangdong province andGuangxi Zhuang Autonomous Region, which are all in the old acidsoil areas with high precipitation and coniferous forests. Theresulting distribution of sensitive regions is different othermaps, including the sensitivity map which is implemented in theRAINS-Asia model.
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  • 14
    ISSN: 1573-2932
    Keywords: acid deposition ; acidification ; air pollution ; critical load ; defoliation ; drought ; meteorological stress ; N deposition ; nitrogen oxides ; ozone ; sulphur
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This paper is the first in a series of four,describing the hypothesis and approach of acorrelative study between observed data on crowncondition in Europe, monitored since 1986 at asystematic 16 × 16 km grid, and site-specificestimations of various natural and anthropogenicstress factors. The study was based on the hypothesisthat forests respond to various natural andanthropogenic stress factors, whose contributiondepend on the geographic region considered. In view ofthis hypothesis, major stand and site characteristics,chemical soil composition, meteorological stressfactors (temperature and drought stress indices) andair pollution stress (concentrations and/ordepositions of SOx, NOy, NHx andO3) were included as predictor variables. Theresponse variables considered were actual defoliationand changes/trends in defoliation for five major treespecies. The spatial distribution of the averagedefoliation during the period 1986–1995 shows highdefoliation in Central Europe and in parts ofScandinavia and of Southern Europe. There are,however, sharp changes at country borders, which aredue to methodological differences between countries.The spatial distribution of the calculated trends showa distinct cluster of large deterioration in parts ofCentral and Eastern Europe and in Spain and a ratherscattered pattern of positive and negative trends for most of Europe, indicating that other factors than airpollution only have a strong impact on defoliation.The limitations of the study are discussed in view ofthe quality of the considered response and predictor variables.
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  • 15
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    Water, air & soil pollution 120 (2000), S. 89-105 
    ISSN: 1573-2932
    Keywords: acidification ; cation exchange ; denitrification ; element fluxes ; lysimetry ; proton buffering ; silicateweathering ; Solling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The acidification of the soil and percolation water at soildepths from 150 to 500 cm was studied at the Solling spruce sitefrom 1991 to 1996. NH4Cl exchangeable cations of the fineearth and bedrock fractions were obtained from different depthsand the soil solution composition was monitored at 150, 200,300, 400 and 500 cm depths using seven suction lysimeters at each depth.In the seepage water collected from 150 and 200 cm depth, pHvalues decreased in the period 1991 to 1996, but no significantchanges were observed in solutions collected below 200 cm depth.Element budgets of Al and Mb (Na, K, Mg, Ca) cationsindicated that buffering by exchange of Al with Mb cationsoccurred mainly in surface 200 cm soil depth. High variabilities in concentrations of SO4 (at 150 cm) andMa (Al, Mn, H, Fe) cations (at 300 and 500 cm) wereobserved. High variabilities in Ma cations could beassigned to one of the lysimeters at each depththat extracted low pH solutions. The amount of exchangeablecations in the fine earth and the bedrock fractions indicatedthat the acidification front (exchangeable Mb cations 〈 80equivalent percent) had occurred to soil depth of more than 360cm, but the extent of acidification that might have occurred inthe preindustrial period is not known. In both fine earth andbedrock fractions, depthwise changes of exchangeable Ma andMb cations were quite similar, suggesting that rockfractions have contributed to proton buffering not only bysilicate weathering but also by cation exchange.
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  • 16
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    Environmental monitoring and assessment 61 (2000), S. 207-229 
    ISSN: 1573-2959
    Keywords: benthos ; birds ; diatoms ; ecologicalindicators ; integrated assessment ; fish ; lakes ; monitoring ; zooplankton
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Biological indicators of communitiestypically reflect a common environmental signalreflecting the general condition of the ecosystem, as well asindividual signals by indicators differentiallysensitive to particular environmental conditions. Wedescribe here a method of integrating and interpretingsuch indicators from 19 New England lakes for fivetaxonomic groups (diatoms, benthos, zooplankton, fish,and birds). Our approach provides a systematicstandardized way to integrate multiple metrics fromdifferent taxonomic groups by addressing four elementscrucial to analyzing data from multiple indicators: covariate control, re-scaling of data, standardizing the sign of responses, and dimensional reduction. We evaluated the biologicalmetrics against individual environmental stressors andagainst multivariate physicochemical metricscharacterizing general anthropogenic stress among thelakes. The method detected a response to variationin the gross environmental condition of the lakes thatwas correlated across taxa and metrics. In addition,a differential response to near shore conditions wasdemonstrated for fish. The success of the approach inthis study lends support to its general application toecological monitoring involving complex data sets.
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  • 17
    ISSN: 1573-2959
    Keywords: monitoring ; ecosystem processes ; conceptual modeling ; indicators ; human impacts
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Monitoring at large geographic scales requires a framework for understanding relationships between components and processes of an ecosystem and the human activities that affect them. We created a conceptual model that is centered on ecosystem processes, considers humans as part of ecosystems, and serves as a framework for selecting attributes for monitoring ecosystems in the Sierra Nevada. The model has three levels: 1) an ecosystem model that identifies five spheres (Atmosphere, Biosphere, Hydrosphere, Lithosphere, Sociocultural), 2) sphere models that identify key ecosystem processes (e.g., photosynthesis), and 3) key process models that identify the "essential elements"that are required for the process to operate (e.g., solar radiation), the human activities ("affectors") that have negative and positive effects on the elements (e.g., air pollution), and the "consequences"of affectors acting on essential elements (e.g., change in primary productivity). We discuss use of the model to select attributes that best reflect the operation and integrity of the ecosystem processes. Model details can be viewed on the web at http://www.r5.fs.fed.us/sncf/spam_report/index.htm(Appendix section).
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  • 18
    ISSN: 1573-3017
    Keywords: authorisation ; field research ; model ecosystems ; monitoring ; pesticides
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract On request of the Dutch government a committee of the Health Council of the Netherlands has reviewed the role that results of field research in its broadest sense (i.e., including multi-species toxicity tests in the laboratory, research on model ecosystems et cetera) can play in ecotoxicological risk assessment for the authorisation of pesticides. The Committee believes that field research can provide valuable additional data about the exposure of non-target organisms and the resultant effects at population, community and ecosystem level. However, it frequently is unclear how these data might be used in reaching a decision about authorisation. To solve this problem, it is necessary to specify what is understood by “unacceptable damage”. Both more clearly formulated protection goals of the government and a better understanding of the ecological significance of effects are needed to clarify this. Furthermore, the Committee points out that the statistical power of field trials must be sufficient to allow for the detection of changes that might be regarded as ecologically relevant. Finally, it recommends keeping a finger on the pulse in relation to authorised pesticides by monitoring their presence in environmental compartments and by investigating their role in suddenly occurring mortality among conspicuous animal species, such as birds, fish and honeybees. This kind of research forms a safety net for substances that have been wrongly authorised.
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  • 19
    ISSN: 1573-2932
    Keywords: acidification ; air pollution ; atmospheric deposition ; Brazil ; Cubatão ; element fluxes ; element budgets ; Serra do Mar ; tropical rain forest
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Three rain forest ecosystems in the Serra do Mar, theatlantic coastal mountain range of Brazil, have beeninvestigated in the frame of an interdisciplinaryGerman-Brazilian research project on dispersion,transformation and deposition of air pollutants in andaround the industrial area of Cubatão. Part I ofthis paper gives a description of the overall goals ofthe project, the area of investigation, and thematerials and methods used. It reports on the resultsof the field measurements conducted from 1991 to 1995,covering concentrations of chemicals in precipitation,soil water, surface water and litter fluxes. In thepresent paper, part II, the element fluxes arepresented with calculated concentrations in thetransport media (precipitation, seepage water,litterfall) and their respective flow rates. Elementbudgets for the ecosystem and for the soil compartmentare interpreted with respect to turnover of chemicals,including nutrients, in forest vegetation, and toprocesses of soil acidification.The forests under investigation are characterized bya very high input from the atmosphere. Between 100 and200 kg S ha-1 are annually carried into soil byprecipitation in the form of sulfate, 20 to 70 kg ofnitrogen mainly in the form of ammonium, 3 to 24 kg offluoride. Input of ammonium and organic bound nitrogenis followed by nitrification in the top soil. At themost polluted site, nitrate output with seepageamounts to 300 kg N ha-1 yr-1, sulfate output tomore than 400 kg S. Soil acidification associated withturnover of sulfur and nitrogen is followed by therelease of aluminum from soil minerals, and leachingof ionic forms of Al (up to 280 kg Al ha-1annually). Transfer of aluminum ions to groundwaterand surface water can have serious ecologicaleffects. Alkalinity is consumed, and the water issubject to acidification.
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  • 20
    ISSN: 1573-2932
    Keywords: acid precipitation ; acid vain ; Atlantic salmon ; LRTAP ; monitoring ; Nova Scotia ; rivers ; toxicity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The Atlantic salmon (Salmo salar) resource of eastern Canada is impacted by acid rain in the Southern Upland (Atlantic Coast) area of Nova Scotia. Salmon runs in this area have become extinct in 14 rivers, are severely impacted in 20 rivers, and lightly impacted in 15 rivers. Water chemistry and fish communities in nine Southern Upland salmon rivers were studied from 1982 to 1996 as part of the effort to monitor the effects of the emission controlprograms in Canada and the United States. There hasbeen no statistically significant change in total ioncontent of Southern Upland river water, but there wasa significant decline in sulfate levels that was balanced by an increase in organic anions, and declines in calcium and magnesium that were balanced by increases in sodium and potassium. A geochemical scenario is proposed to account for these chemical changes. River water pH levels showed no overall linear trend, but at borderline toxicity sites the year-to-year variations in pH were correlated withchanges in juvenile salmon population densities. Tenfish species were collected, but none showed anysignificant overall time trend in population density.Fish species diversity was positively correlated with pH.
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  • 21
    ISSN: 1573-2932
    Keywords: acidification ; air pollution ; Brazil ; Cubatão ; precipitation ; Serra do Mar ; tropical rain forest
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The effects of atmospheric deposition upon elementcycling and turnover in three rain forest ecosystems ofthe Serra do Mar, a mountain range along the atlanticcoast of Brazil, have been investigated as part of aninterdisciplinary German-Brazilian research project ondispersion, transformation and deposition of airpollutants in the vicinity the industrial complex ofCubatão, State of São Paulo. The projectincluded on-site measurements from 1991 to 1995, fieldexperiments and mathematical modelling with the goalof providing damage evaluation and risk assessment,and elucidating damage mechanisms with respect tosoils and vegetation. The role of the `Soil Module'sub-project reported here was to assess atmosphericdeposition and fluxes with precipitation and soilwater, and to investigate possible soil changesinduced by atmospheric deposition as well asbiological effects of pollutants via the soil path.Part I of this paper deals with concentrations ofchemicals in precipitation, soil water, surface waterand in litter. Part II will cover fluxes of chemicalsand element budgets.Three sites were chosen which differed significantlywith respect to pollution impact. Annual averages ofionic concentrations in precipitation found in openfield and below the tree canopy amounted to 5 and10 mg L-1, respectively, for sulfate-S, 0.4 and0.7 mg L-1 for nitrate, 0.65 and 1.1 mg L-1 for fluoride,1.8 and 2.6 mg L-1 for ammonium-N, 0.76 and 2.3 mg L-1for Mg, and 3.5 and 7.5 mg L-1 for Ca at the mostpolluted site. The relatively `clean' reference siteattained 1/3 to 1/9 of these averages, thus clearlyreflecting the difference in air pollution load.Chemical composition in the liquid phase is completelychanged when precipitation infiltrates the soilprofile. Nitrate concentration increases by the factor5 to 20. A clear increase is also found for sulfateand chloride. Concentration changes during ecosystempassage of seepage are interpreted in relation tochemical reactions taking place in differentcompartments. They are characterized by an almostcomplete retention of ammonium and some retention ofsulfate in the upper soil layers, and at the mostpolluted site by mobilization of Al from soil mineralsand very high leaching of nitrate as a consequence ofnitirification of organic matter.
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    Water, air & soil pollution 122 (2000), S. 93-103 
    ISSN: 1573-2932
    Keywords: base saturation ; deposition ; forest ecosystems ; monitoring ; regeneration ; soil acidification ; total acid load
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Between 1993 and 1995 a system of six intensive monitoring stations in representative stands of Norway spruce (Picea abies), sessile oak (Quercus robur) and Scots pine (Pinus sylvestris) were installed in forests of Saxony (Germany), they are integrated in the European Level II - Programme. As a complementary system, and in addition to the annual nation-wide forest decline survey, 280 sites within the forest soil condition survey (European Level I - Programme) have been examined since 1992. The results of deposition monitoring show that until 1997 the acidity in precipitation and troughfall still was very high, despite of strong reductions in industrial emissions between 1989 and 1992. The annual fluxes (hydrological year 1996) of sulphur in throughfall ranged between 16 and 77 kg-ha-1, whereas the fluxes of total inorganic N varied between 17 and 46 kg-ha-1. The forest soils show high degrees of acidification with only low base saturation. In most cases the nutrient status of the soils has to be improved in the course of a regeneration programme in order to rebuild more natural forest ecosystems.
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    Water, air & soil pollution 122 (2000), S. 281-297 
    ISSN: 1573-2932
    Keywords: landfill ; leachate ; monitoring ; MSW ; prediction ; refuse
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Parameters such as pH, concentrations of Cl-, turbidity,NH3-N, CODCr and BOD5 (simplified as COD and BODrespectively in the following text) in leachate generated inthe large-scale testing landfill unit and closed landfill unitsat Shanghai Refuse Landfill were monitored from April 1995 toOctober 1998. The mathematical simulation formula between theseparameters and refuse age were established based on the dataobtained from the testing landfill unit and justified by thedata obtained at the closed landfill units from 1989 to 1993.The long-term predictions for the leachate concentrations forthe Landfill were made using the mathematical simulation formulaestablished. It was predicted that the COD and BOD may bereached to the strictest standard for pollution control on municipal solid wastes landfill in China, i.e., COD 〈 100 mg L-1 and BOD 〈 30 mg L-1, after 15 yr natural attenuation. The time predicted for NH3-N concentrations to reach the discharging standard, 15 mg L-1, was found to be at least 23–26 yr or even longer. The predictions for concentrations of Cl-, turbidity, and pH values in leachate are also given. The natural attenuation of Cl- is the slowest and might be decreased to 200 mg Cl- L-1, the agricultural irritation standard, after at least 58 yr.
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    Water, air & soil pollution 123 (2000), S. 159-166 
    ISSN: 1573-2932
    Keywords: coagulation ; Cryptosporidium ; filtration ; Giardia ; monitoring ; turbidity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The most commonly used water filtration technique involves coagulation and rapid rate filtration, either in conventional plants with flocculation and sedimentation, or in direct filtration plants in which the sedimentation process is omitted. Both versions of coagulation and filtration can be effective for controlling Giardia cysts and Cryptosporidium oocysts, but research done by several investigators has shown that coagulation and filtration must be operated very carefully to attain the best results. When filtered water turbidity is 0.1 ntu or lower, the process is most effective. Careful control of coagulation chemistry and of filtration rate increases, continuous monitoring of filtered water turbidity, and proper management of backwash water are keys to successful filtration.
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    Water, air & soil pollution 119 (2000), S. 139-156 
    ISSN: 1573-2932
    Keywords: aldicarb ; herbicides ; insecticides ; monitoring ; organochlorine ; organophosphate ; surface water
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A survey was conducted of pesticide distribution in the water ofthe upper Jordan basin, due to the importance of its quality asthe main source of drinking water in Israel.A preliminary survey of pesticide distributers and farmersrevealed intensive use of many pesticides in agriculture. Fourof these were selected as targets for monitoring in the surfacewater of the region, at seven sampling stations. The highestresidue found was of aldicarb and its metabolites, with lowercontent of organophosphate and organochlorine insecticides. Noconcentrations reached the maximum levels permitted by the EPAfor drinking water, but recommendations were made, nonetheless,for continuous monitoring of pesticides in the region.Subsequent monitoring (1993–1997) showed a steady decrease in aldicarb residues.
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    ISSN: 1573-2932
    Keywords: acidification ; afforestation ; catchments ; geology
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    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This paper investigates the regional relationships between highflow water chemistry and conifer forest cover in 95 streamsspread over an area of approximately 2000 km2 in Galloway,south-west Scotland, paying particular attention to the use ofdetailed catchment area data. Catchment forest data areextracted from a 30 m resolution tree height map derived fromsatellite imagery; geology data from a digital geology map; andaltitude and slope data from a 50 m resolution Digital TerrainModel (DTM). The results show that over the entire region pHlevels are lower with increasing catchment afforestation whilstaluminium concentrations are higher. Concentrations of sulphate arealso higher with increasing afforestation, which suggests thatconifers play a primary role in increasing the acidity levels ofstreams by exacerbating aerial acid deposition in the entireregion.
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    Water, air & soil pollution 119 (2000), S. 59-74 
    ISSN: 1573-2932
    Keywords: acidification ; chemical weathering ; liming ; mine spoil
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Chemical processes affecting the acidity of asulphide-rich lignite mine spoil treated with high orlow doses of a CaCO3-rich industrial waste slurrywere studied in the laboratory under two moistureprogrammes (cycles of alternate waterlogging anddrying, and percolation) so as to determine the slurrydose neutralizing spoil acidity and the possibledetrimental effects of high doses. The most importantacidity-reducing process was the dissolution ofapplied calcium carbonate, and CaCO3 consumptionwas greater under percolation conditions than underwaterlogging and drying conditions. The most importantacidity-increasing process was the oxidation ofsulphides, which was again more intense underpercolation. Under waterlogging and drying conditions,the formation of hydroxysulphates may also havecontributed to acidification.
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    European journal of law and economics 8 (1999), S. 231-250 
    ISSN: 1572-9990
    Keywords: lender liability ; limited liability effect ; monitoring ; vague negligence rule
    Source: Springer Online Journal Archives 1860-2000
    Topics: Law , Economics
    Notes: Abstract A firm strictly liable for any harm done will choose an inefficiently low care level if there is a possibility that it goes bankrupt. One possibility to improve care is extending liability to secured lenders, as applied under CERCLA and as currently being discussed in the EU. I compare strict liability, partial liability and vague negligence for lenders in a model with moral hazard and environmental auditing. While auditing is socially valuable only if it increases the firm's care level, the creditor also calculates the reduction in the information rent. Thus, for each possible care level, monitoring is always too high. This effect is aggravated by a vague negligence rule, where the probability that a lender is found liable decreases in the level of auditing. It is demonstrated that partial liability is superior, because the incentive for excessive monitoring is diminished.
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    Environmental monitoring and assessment 56 (1999), S. 269-291 
    ISSN: 1573-2959
    Keywords: grid approach ; mapping ; monitoring ; National Forests ; purposive sampling ; random sampling ; statistical inventory
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A forest ecological inventory and monitoring system combining information derived from maps and samples is proposed based on ecosystem regions (Bailey, 1994). The system extends the design of the USDA Forest Service Region 6 Inventory and Monitoring System (R6IMS) in the Pacific Northwest of the United States. The key uses of the information are briefly discussed and expected results are illustrated with examples. The system is flexible, allowing regions based on ecological considerations to be modified. Sampling intensities that are affordable are likely to be insufficient to provide meaningful estimates for key parameters relating to rare and endangered species, watersheds, and other ecological units. Methods are proposed for collecting additional information in follow-up surveys and combining it with relevant information obtained in R6IMS. Near-continuous information on weather and possible pollution variables recorded by instruments at sampling sites is needed to develop meaningful models to understand what is happening in the ecoregions. R6IMS and the proposed additions constitute a dynamic system which will be modified further as data are analyzed.
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    Environmental monitoring and assessment 57 (1999), S. 1-20 
    ISSN: 1573-2959
    Keywords: dissolved oxygen ; EMAP ; estuary ; Gulf of Mexico ; monitoring
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Because deficient dissolved oxygen (DO) levels may have severe detrimental effects on estuarine and marine life, DO has been widely used as an indicator of ecological conditions by environmental monitoring programs. The U.S. EPA's Environmental Monitoring and Assessment Program for Estuaries (EMAP-E) monitored DO conditions in the estuaries of the Gulf of Mexico from 1991 to 1994. DO was measured in two ways: 1) instantaneous profiles from the surface to the bottom were taken during the day, and 2) continuous measurements were taken near the bottom at 15 min intervals for at least 12 h. This information was summarized to assess the spatial distribution and severity of DO conditions in these estuaries. Depending on the criteria used to define hypoxia (DO concentrations usually 〈2 mg L-1 or 〈5 mg L-1) and the method by which DO is measured, we estimate that between 5.2 and 29.3% of the total estuarine area in the Louisianian Province was affected by low DO conditions.
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  • 31
    ISSN: 1573-3017
    Keywords: Swainson's hawk ; monocrotophos ; ecotoxicology ; monitoring ; mortality
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Approximately 6,000 dead Swainson's hawks (Buteo swainsoni) were discovered in the Pampas of Argentina in 1995–96. Subsequent meetings held between Argentine, US, Canadian, and Swiss personnel led to an agreement whereby chemical companies removed the organophosphate (OP) monocrotophos (MCP) from the area where mortalities had occurred in northern La Pampa province. We monitored hawks in the MCP exclusion zone from 28 November 1996 through 25 January 1997. We sampled 133 hawks for exposure to anti-cholinesterase insecticides, 131 of which showed no apparent signs of adverse effects. Two hawks had inhibited ChE that recovered over time. Feather and footwash samples from captured birds were tested for OP residues. One feather sample was positive for dimethoate; no footwash sample was positive for any of the OPs screened. Cholinesterase (ChE) activities from hawks in Argentina were (mean±SE, n=131) 0.674±0.014 total ChE, 0.236±0.006 acetylcholinesterase (AChE), and 0.438±0.013 butyrylcholinesterase (BChE). Mean plasma AChE from Argentine hawks was significantly depressed below North American reference values. Total ChE and BChE activities were not significantly different. Mortality due to OP poisoning was not found in the MCP exclusion zone in northern La Pampa, though it continued outside of the zone where MCP was used, both legally and illegally. Education campaigns and extension efforts, emphasizing the local MCP restrictions, were effective in controlling Swainson's hawk mortalities in the study area where substantial mortality occurred the previous two years.
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    International tax and public finance 6 (1999), S. 317-337 
    ISSN: 1573-6970
    Keywords: redistribution ; monitoring ; unemployment ; targeting
    Source: Springer Online Journal Archives 1860-2000
    Topics: Economics
    Notes: Abstract Redistribution programs are constrained because those not working may be either unable to work, voluntarily unemployed or involuntarily unemployed. The inability to distinguish among these three cases inhibits the targeting of transfers to those most in need. Enabling the government to monitor whether unemployed individuals are searching for work and accepting any offered jobs increases its ability to redistribute income. We show that these monitoring activities are complementary, and consider how a minimum wage might be a useful adjunct to monitoring contingent tax-transfer policies.
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    Mitigation and adaptation strategies for global change 4 (1999), S. 43-60 
    ISSN: 1573-1596
    Keywords: carbon offsets ; emission trading ; energy efficiency ; evaluation ; forestry ; global climate change ; greenhouse gas emissions ; joint implementation ; monitoring ; reporting ; verification
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Abstract Because of concerns with the growing threat of global climate change from increasing emissions of greenhouse gases, the United States and other countries are implementing, by themselves or in cooperation with one or more other nations, climate change projects. These projects will reduce greenhouse gas (GHG) emissions or sequester carbon, and will also result in non-GHG benefits (i.e., environmental, economic, and social benefits). Monitoring, evaluating, reporting, and verifying (MERV) guidelines are needed for these projects to accurately determine their net GHG, and other, benefits. Implementation of MERV guidelines is also intended to: (1) increase the reliability of data for estimating GHG benefits; (2) provide real-time data so that mid-course corrections can be made; (3) introduce consistency and transparency across project types and reporters; and (4) enhance the credibility of the projects with stakeholders. In this paper, we review the issues involved in MERV activities. We identify several topics that future protocols and guidelines need to address, such as: (1) establishing a credible baseline; (2) accounting for impacts outside project boundaries through leakage; (3) net GHG reductions and other benefits; (4) precision of measurement; (5) MERV frequency and the persistence (sustainability) of savings, emissions reduction, and carbon sequestration; (6) reporting by multiple project participants; (7) verification of GHG reduction credits; (8) uncertainty and risk; (9) institutional capacity in conducting MERV; and (10) the cost of MERV.
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    Journal of business ethics 22 (1999), S. 39-49 
    ISSN: 1573-0697
    Keywords: Computer Based Performance Monitoring ; Electronic Performance Monitoring ; employment ; health and safety ; home workers ; interception of communications ; monitoring ; surveillance ; telecommuting ; telework
    Source: Springer Online Journal Archives 1860-2000
    Topics: Philosophy , Economics
    Notes: Abstract This paper looks at various ways teleworking can be linked to surveillance in employment, making recommendations about how telework can be made more acceptable. Technological methods can allow managers to monitor the actions of teleworkers as closely as they could monitor "on site" workers, and in more detail than the same managers could traditionally. Such technological methods of surveillance or monitoring have been associated with low employee morale. For an employer to ensure health and safety may require inspections of the teleworkplace. When the teleworkplace is in the home, there may be an invasion of privacy associated with such inspections, that could be perceived and resented as surveillance. A problem of telework is that teleworkers may feel isolated. Methods to counter this could be associated with further forms of surveillance, and fear of such surveillance may inhibit them from reaching their potential as methods to counter isolation. The idea that teleworking may also allow communications to be intercepted by third parties is also looked at. Some, but not all, of the issues considered are applicable, to some extent, in non-teleworked employment situations. The overall conclusion of the paper is that the potential exists for surveillance to be associated with telework. Fears of such surveillance may turn actors against telework. However, much can be done to reduce such fears.
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    Biodegradation 10 (1999), S. 399-404 
    ISSN: 1572-9729
    Keywords: acidification ; biofilter ; dimethyl sulphide ; dolomite ; inoculation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The applicability of dolomite particlesto control acidificationin a Hyphomicrobium MS3inoculated biofilter removingdimethyl sulphide (Me2S) wasstudied. While direct inoculationof the dolomite particles with theliquid microbial culture was notsuccessful, start-up ofMe2S-degradation in thebiofilter was observed when thedolomite particles were mixed with33% (wt/wt) of Hyphomicrobium MS3-inoculatedcompost or wood bark material.Under optimal conditions, anelimination capacity (EC) of 1680~g Me2S m-3 d-1 wasobtained for the compost/dolomitebiofilter. Contrary to a wood barkor compost biofilter, no reductionin activity due to acidificationwas observed in these biofiltersover a 235 day period because ofthe micro environmentneutralisation of the microbialmetabolite H2SO4 with thecarbonate in the dolomite material.However, performance of thebiofilter decreased when themoisture content of the mixedcompost/dolomite material droppedbelow 15%. Next to this, nutrientlimitation resulted in a gradualdecrease of the EC andsupplementation of a nitrogensource was a prerequisite to obtaina long-term high EC (〉 250 gMe2S m-3 d-1) forMe2S. In relation to thisnitrogen supplementation, it wasobserved that stable ECs forMe2S were obtained when thisnutrient was dosed to the biofilterat a Me2S-C/NH4Cl-Nratio of about 10.Abbreviations:DW – dry weight,EC – elimination capacity,Me2S – dimethyl sulphide,OL – organic loading rate,VS - volatile solids
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    Ecotoxicology 8 (1999), S. 49-56 
    ISSN: 1573-3017
    Keywords: mercury ; methylmercury ; fish ; acidification ; biomagnification
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Two small drainage lakes of similar surface area (0.4–0.6 km 2 ) and depth, and situated in close proximity to one another (about 9 km apart) in the Muskoka-Haliburton district of rural Ontario, Canada were chosen to investigate the effects of differing pH on Hg accumulation in fish and other biota. Blue Chalk Lake is circumneutral (pH = 6.3–6.9) with an average dissolved organic carbon (DOC) concentration of 2.69 mg/L; Plastic Lake is acidic (pH = 5.2–5.6) with a similar DOC level (2.72 mg/L). Neither lake is an impoundment, and neither receives inputs from point-source urban or industrial waste emissions. Surficial (top 4 cm) sediments and various aquatic biota, including crayfish (Orconectes virilis)], and 5 species of fish [brown bullhead (Ictalurus nebulosus), creek chub (Semotilus atromaculatus), pumpkinseed sunfish (Lepomis gibbosus), yellow perch (Perca flavenscens) and rock bass (Ambloplites rupestris)] were sampled for Hg analysis. Only creek chub and pumpkinseed occurred in both lakes. Significant size (length) vs. Hg-concentration relationships were observed for brown bullhead, pumpkinseed, yellow perch and rock bass, but not for crayfish nor for creek chub in either lake. Rock bass had the highest mean Hg concentration (1.02 ± 0.98 μg/g dry wt.). Pumpkinseed from Plastic Lake had the highest overall rate of accumulation with increasing size. Several individual pumpkinseed and rock bass sampled from the acidic Plastic Lake had Hg concentrations equal to or greater than levels reported to be hazardous to breeding piscivorous birds, such as common loons (Gavia immer), whereas no fish from Blue Chalk approached this threshold (0.3 μg/g wet wt). This study illustrates the importance of within-lake parameters, particularly pH, and species trophic level, in determining Hg accumulation in fish in lakes of similar size that receive similar atmospheric Hg inputs.
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    Environmental monitoring and assessment 55 (1999), S. 279-298 
    ISSN: 1573-2959
    Keywords: biological indicators ; change ; epilithic lichens ; global climate ; Israel ; monitoring ; Negev desert
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The issue of biological monitoring of the local consequences of anticipated global climate change is considered for the Central Negev Highlands, Israel. Epilithic lichens are suggested as biological monitors. The proposed methodology of such monitoring consists of a sampling scheme, including lichen measurement along transects on flat calcareous rocks, and construction of a trend detection index (TDI). TDI is a sum of lichen species cover with coefficients chosen so as to ensure maximum ability to detect global climate trends. Coefficients have been estimated in a study of lichens along an altitudinal gradient from 500 to 1000 m a.s.l. The gradient study demonstrated that the TDI index is performed better than other integrated indices. Recommendations on this system to monitor climate change with epilthic lichens are given. Measuring, for instance, a hundred transects in fifty plots (two transet per plot scheme) allows one to detect a climate-driven change in the epilithic lichen community corresponding to a 0.8 °C shift in annual mean temperature. Such resolution appears sufficient in view of global warming of 2.5 °C considered by the Intergovernmental Panel on Climate Change as a realistic prediction for the end of the next century.
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  • 38
    ISSN: 1573-2932
    Keywords: acidification ; Brown trout ; calcium ; density ; juveniles ; streams
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract We examined the relationship between young brown trout ( Salmo trutta) density in lake tributaries, and water chemistry and habitat variables. The study was carried out during the autumn in three acidic, softwater river systems in western and southwestern Norway; Gaular and Vikedal (1987–1993) and Bjerkreim (1988–1993). The streams had mean calcium concentrations of 0.35 mg L-1 (Gaular), 0.52 mg L-1 (Vikedal) and 0.84 mg L-1 (Bjerkreim). The concentration of inorganic Al was generally low, with mean values of 8.40 (Gaular), 22.22 (Vikedal) and 43.36 μg L-1 (Bjerkreim). In multiple regressions that involved different water chemistry variables, brown trout density correlated best with calcium concentration and with a combination of calcium and pH; the Ca2+:H+ ratio. In Vikedal and Gaular, calcium explained 51 and 57%, respectively, of the variability in brown trout densities. Althoug alkalinity exhibited the best correlation with brown trout density in Bjerkreim ( r2=0.33), it was similar to that of the model that included all major ions plus pH. The Ca2+:H+ ratio had a larger effect for variability in brown trout density in Gaular (r2=0.66) than calcium alone. In Vikedal and Bjerkreim, the Ca2+:H+ ratio also correlated with brown trout density, but considerably less than in Gaular. The predictive power of habitat variables was much lower than that of water chemistry; the single most important factors were altitude in Gaular (r2=0.22), mean water temperature in Vikedal (r2=0.11) and depth SD (index of heterogeneity) in Bjerkreim (r2=0.07). Models that included both habitat and water chemistry variables showed that the density of young brown trout was predicted primarily by calcium concentrations in Gaular (r2=0.75) and Vikedal (r2=0.54), as opposed to pH in Bjerkreim (r2=0.25). Habitat had low effect in all three river systems (r2=0.01–0.04). The final model explained 86, 68 and 32%, respectively, of the variability in brown trout density in the three catchments. Thus, water chemistry variables seem to be factors that limit the density of young brown trout in acidic softwater streams.
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    Environmental monitoring and assessment 59 (1999), S. 47-72 
    ISSN: 1573-2959
    Keywords: flow-normalisation ; long-term trends ; monitoring ; nitrogen ; riverine load ; statistical analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Concern about nitrogen loads in marine environments has drawn attention to the existence and possible causes of long-term trends in nitrogen transport in rivers. The present study was based on data from the Swedish environmental monitoring programme for surface water quality; the continuity of these data is internationally unique. A recently developed semiparametric method was employed to study the development of relationships between runoff and river transport of nitrogen since 1971; the observed relationships were then used to produce time series of flow-normalised transports for 66 sites in 39 river basins. Subsequent statistical analyses of flow-normalised data revealed only few significant downward trends (p ≤0.05) during the time period 1971–1994, and the most pronounced of these downward trends were caused by reduced point emissions of nitrogen. The number of significant upward trends was substantially larger (15 for total-N and 18 for NO3-N). Closer examination of obtained results revealed the following: (i) the most pronounced upward trends were present downstream of lakes, and (ii) observed increases in nitrogen transport coincided in time and space with reduced point emissions of phosphorus or organic matter. This indicated that changes in the retention of nitrogen in lakes were responsible for the upward nitrogen trends. The hypothesis that nitrogen saturation of forest soils has caused a general increase in the riverine export of nitrogen from forested catchments in Sweden was not confirmed. Neither did the results indicate that improved agricultural practices have reduced the export of nitrogen from agricultural catchments.
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  • 40
    ISSN: 1573-2967
    Keywords: critical loads ; acidification ; area exceeded ; integrated assessment ; emission scenarios ; sulfur oxides ; nitrogen oxides ; ammonia ; deposition modeling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract An integrated model system was developed and used to assess the effects of alternative energy production scenarios and reduction policies on acidification of lakes and forest soils in Finland. The analysis covered different energy scenarios and resulting emissions of sulfur oxides and nitrogen oxides in Finland, as well as ammonia emissions with various control requirements. In addition, emission reduction scenarios of varied ambition levels in the bordering areas of Finland and in other parts of Europe were included in the analysis. The impacts of the different scenarios were quantified with exceedances of critical loads for acidification and with the total areas where the critical loads are exceeded. The possibilities for reducing the areas with critical load exceedances with national or bilateral measures were investigated. The differences in areas at risk, if depositions from domestic and nearby sources are estimated with a regional model and point-source databases or with a continental scale model and coarser-scale emission data, were analyzed. The reasons for the differences and the implications for national-level assessment are discussed.
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    ISSN: 1573-2932
    Keywords: acidification ; fertilizer ; forest decline ; sugar maple
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The effects of two year's addition of simulated acid precipitation, with and without added fertilizer, on mycorrhizae, litter decomposition and soil and tree chemistry in a sugar maple (Acer saccharum Marsh.) dominated forest were investigated. The forest floor beneath mature sugar maple trees was irrigated at monthly intervals between May and September with local lake water acidified to pH 3, pH 4 or untreated lakewater of pH 4.9. In addition, a commercial organic slow-release fertilizer (Maple Gro) was added to the soil prior to irrigation with pH 3 spray. Trees to which no experimental spray was applied were also included as controls. Eight trees were used for each of the five treatments. Application of the acid spray alone did not acidify surface soil nor cause visible symptoms of decline in trees. The pH of the soil solution and soil leachate was increased by addition of acidified lakewater. An increase in the concentration of sulphate (SO4 2-), calcium (Ca), and magnesium (Mg) in soil leachate was only recorded in plots irrigated with water acidified to pH 3 + Maple Gro. The initial rate of litter decomposition tended to be higher following application of the acid sprays, although mycorrhizal infection of sugar maple roots was reduced in the pH 3 and pH 4 treatments. Concentrations of zinc (Zn), chromium (Cr) and nickel (Ni) were highest in wood formed during the period irrigated with water acidified to pH 3. Foliar nitrogen (N) concentrations tended to be higher in all irrigated treatments, although there were no differences between treatment in any of the other nutrients measured in foliage after two years of treatment. It is concluded that the application of simulated acid rain under field conditions results in a complex interaction of events which are not reproduced in pot trials and must be fully understood before the impact of acid rain on sugar maple forests can be evaluated.
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  • 42
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    Water, air & soil pollution 116 (1999), S. 479-499 
    ISSN: 1573-2932
    Keywords: acidification ; base cations ; bromide ; forest ecosystems ; mobile anion ; soil solution ; TFA ; trifluoroacetate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Experimental plots within the Hubbard Brook Experimental Forest, NH, were treated with sodium trifluoroacetate (TFA) and lithium bromide (Br), to study the impact of TFA alone and in the presence of increased anion concentrations (e.g. acid deposition) on the soil solution chemistry of a northern hardwood forest soil. Trifluoroacetate is a major atmospheric degradation product of replacement compounds of chlorofluorocarbons (CFC) and Br is widely used as a hydrologic tracer. Calculated drainage losses via soil water flow were less than 60% of inputs, added during the summer, and TFA and Br were temporarily retained in the soil until fall. The initial indication of an acid input of the treatments (HTFA, HBr) in the Bs2 horizon, which reflects stream water chemistry as well, was an increase of base cations in the soil solution, decreasing the soil's acid neutralizing capacity. Thereafter, trifluoroacetate and Br concentrations peaked after the peak in base cations, synchronous with peaks in H+ and Al concentrations. Organic anions, nitrate and chloride played the major role in accompaning base cations out of the solum. Sulfate retention at soil adsorption sites was increased by the presence of TFA and Br, reducing its role as a mobile anion of base cations in this experiment. Relative retention of anions for the whole profile of this northern hardwood forest soil was estimated by correlation analyses and input-output balances in decreasing order on an equivalant basis: SO4 〉 TFA = Br ≥ Cl 〉 NO3 〉 organic anions. Recovery from acid additions were recorded within several weeks after the treatments were stopped. Evaluating the impact of added chemical compounds to soils must be considered within the context of linkages among element cycles and pools.
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  • 43
    ISSN: 1573-2932
    Keywords: dry deposition ; dry deposition velocity ; forest ; monitoring ; surface resistance ; SO2
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In 1990 a project to develop a dry deposition monitoring method of SO2, NH3 and NO2 to Speulder forest in the Netherlands began. Detailed annual deposition fluxes for these gases were measured throughout November 1992 to December 1995. This paper describes the measurement set-up and the analysis of the deposition parameters for SO2. The dry deposition velocity was usually smaller than the maximum Vd, showing a resistance to surface uptake, except for periods when the canopy is wet and surface resistance is negligible. Several methods were tested to estimate annual average fluxes from the gradient measurements. Annual fluxes were estimated by selecting the data for periods fulfilling gradient theory and extending the data by using an inferential method for the other periods. The surface resistance parametrisation used in the inferential method was tested using the selected data and was found to yield systematic larger fluxes of the order of 20%. Annual fluxes were 465 mol ha-1 a-1 in 1992/1993, 460 mol ha-1 a-1 in 1994 and 330 mol ha-1 a-1 in 1995. The uncertainty in the annual flux was estimated to be 25%. The annual average dry deposition velocity was 1.5 cm s-1. No large differences were found in deposition parameters between each of the three years.
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  • 44
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    Water, air & soil pollution 112 (1999), S. 217-227 
    ISSN: 1573-2932
    Keywords: acidification ; dust deposition ; high mountain lakes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract For a long time studies on precipitation and lake-water chemistry have focussed on the deposition of strong acids. Dust in snow and rain was analyzed much less intensively, but recent findings suggest that it may be the missing link which explains why many low-alkalinity lakes in the Alps and the Pyrenees did not become acidic and nutrient levels are seasonally high, whereas lakes in areas which are rarely influenced by dust depositions, for instance in Scandinavia, have acidified. Beside being a dominant factor for nutrient inputs to oceans, rain forests and remote lakes, dust can also play a major role in global warming and cooling, and it may significantly contribute to soil formation at mountain sites in the Mediterranean. I suggest that future changes in dust deposition and warming will be key factors for the development of alpine lakes.
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  • 45
    ISSN: 1573-2932
    Keywords: acidification ; base cations ; dendrochemistry ; forest decline ; Jack pine (Pinus banksiana Lamb.)
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The impact of simulated acid rain on soil leachate and xylem chemistry in a young Jack pine (Pinus banksiana Lamb.) stand in the boreal forest of northern Ontario was evaluated. Permanent plots (5 × 2 m) were established in 1981 which were sprayed twice monthly with simulated acid rain, adjusted to pH 5.6, 4.0, 3.5, 3.0 or 2.5 with a 2:1 molar ratio of sulphuric (H2SO4) to nitric acid (HNO3) in addition to ambient rainfall. Sprays were applied between June and September for 5 yr. Unsprayed plots were also monitored. The pH of soil leachate collected between 1981–1985 was reduced significantly by the acid sprays and concentrations of sulphate (SO42-), nitrate (NO3-), calcium (Ca), magnesium (Mg), aluminium (Al), manganese (Mn), and zinc (Zn) increased in the A, B and C horizons. The soil recovered rapidly from the spray treatments, although residual effects were found in soil leachate samples collected during 1986–1987, particularly in the C horizon. Trees receiving spray acidified to pH 2.5 had higher concentrations of Ca, Mn, Cd and Rb in tree-rings formed between 1981–1985 compared to trees receiving spray acidified to pH 4.0 or to trees receiving ambient rainfall alone. Some of the changes in soil chemistry resulting from the application of acidic sprays are reflected in the chemistry of Jack pine tree rings and these chemical signals in tree rings may be used as indicators of soil acidification.
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  • 46
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    Water, air & soil pollution 116 (1999), S. 65-74 
    ISSN: 1573-2932
    Keywords: Forests ; N deposition ; soil nitrogen transformations ; nitrification ; tree growth ; acidification ; BC/A1 ratio ; 15N
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The effects of pollutant nitrogen on forest soils and the potential feedbacks on tree growth are discussed using data from recent plot and catchment manipulation studies. Results indicate that N applied to the soil affects both soil N transformations and base cation status in some forest soils. Whilst reductions in tree growth are infrequently reported, a greater understanding of the effect of increased N deposition on soil N transformations, and associated changes in soil acidification and nutritional balance, is essential if sensitive stands are to identified. In particular, the factors controlling soil N accumulation rates and thus the onset of nitrate leaching are not clearly understood with increased nitrogen availability potentially increasing nitrogen accumulation due to abiotic fixation and lignolytic enzyme suppression, whilst the onset of nitrification as the C/N ratio of forest floor material declines, may reduce N retention efficiency. The switch from increased to decreased tree growth rate in response to N additions in some experiments highlights the need for long-term studies as a necessary component of future research.
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  • 47
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    Water, air & soil pollution 115 (1999), S. 21-70 
    ISSN: 1573-2932
    Keywords: atmospheric transport ; current-use pesticides ; deposition ; field measurements ; long-range transport ; monitoring ; organochlorine pesticides ; pesticides ; rainwater
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Recently, evidence has accumulated that the extensive use of modern pesticides results in their presence in the atmosphere at many places throughout the world. In Europe over 80 current-use pesticides have been detected in rain and 30 in air. Similar observations have been made in North America. The compounds most often looked for and detected are the organochlorine insecticide lindane and triazine herbicides, especially atrazine. However, acetanilide and phenoxyacid herbicides, as well as organophosphorus insecticides have also frequently been found in rain and air. Concentrations in air normally range from a few pg/m3 to many ng/m3. Concentrations in rain generally range from a few ng/L to several µg/L. In fog even higher concentrations are observed. Deposition varies between a few mg/ha/y and more than 1 g/ha/y per compound. However, these estimates are usually based on the collection and analysis of (bulk) precipitation and do not include dry particle deposition and gas exchange. Nevertheless, model calculations, analysis of plant tissue, and first attempts to measure dry deposition in a more representative way, all indicate that total atmospheric deposition probably does not normally exceed a few g/ha/y. So far, little attention has been paid to the presence of transformation products of modern pesticides in the atmosphere, with the exception of those of triazine herbicides, which have been looked for and found frequently. Generally, current-use pesticides are only detected at elevated concentrations in air and rain during the application season. The less volatile and more persistent ones, such as lindane, but to some extent also triazines, are present in the atmosphere in low concentrations throughout the year. In agricultural areas, the presence of modern pesticides in the atmosphere can be explained by the crops grown and pesticides used on them. They are also found in the air and rain in areas where they are not used, sometimes even in remote places, just like their organochlorine predecessors. Concentrations and levels are generally much lower there. These data suggest that current-use pesticides can be transported through the atmosphere over distances of tens to hundreds, and sometimes even more than a thousand kilometres. The relative importance of these atmospheric inputs varies greatly. For mountainous areas and remote lakes and seas, the atmosphere may constitute the sole route of contamination by pesticides. In coastal waters, on the other hand, riverine inputs may prevail. To date, little is known about the ecological significance of these aerial inputs.
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  • 48
    ISSN: 1573-2959
    Keywords: risk assessment ; chlorinated compound ; environmental ; marine ; exposure ; aquatic toxicity ; monitoring ; trichloroethylene
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This risk assessment on trichloroethylene (TRI) was carried out specifically for the marine environment, according to the methodology laid down in the EU risk assessment Regulation (1488/94) and the Guidance Document of the EU New and Existing Substances Regulation (TGD, 1997). The study consists of the collection and evaluation of data on effects and environmental concentrations from analytical monitoring programs in large rivers and estuaries in the North Sea area. The risk is indicated by the ratio of the "predicted environmental concentrations" (PEC) and the "predicted no effect concentrations" (PNEC) for the marine aquatic environment. In total, 19 studies for fish, 30 studies for invertebrates and 14 studies for algae have been evaluated. Both acute and chronic toxicity studies have been taken into account and the appropriate assessment factors have been used to define a PNEC value of 150 µg/l. Most of the available monitoring data apply to rivers and estuaries and were used to calculate PECs. The most recent data (1991-1995) support a typical PEC of 0.1 µg TRI/l water and a worst case PEC of 3.5 µg TRI/l water. The calculated PEC/PNEC ratios give a safety margin of 40 to 1,500 between the predicted no effect concentration and the exposure concentration. Additional evaluation of environmental fate and bioaccumulation characteristics showed that no concern for food chain accumulation is expected.
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  • 49
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    Environmental and ecological statistics 5 (1998), S. 81-91 
    ISSN: 1573-3009
    Keywords: density estimation ; distance sampling ; detection function ; monitoring ; Pollard-Yates
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Line transect sampling is an effective survey method for estimating butterfly densities because it provides unbiased estimates of site-density (provided key assumptions are met), and estimates are comparable among sites. For monitoring Karner blue butterflies in Wisconsin, USA, comparable estimates are required because each year a different selection of sites will be monitored. Annual state-wide indices of species abundance can be derived from the site-surveys and compared to previous year's indices to monitor trends. We advocate that line transect sampling is preferable to Pollard-Yates transects as a survey technique for monitoring Karner blue butter- flies. The Pollard-Yates surveys do not adjust for diferences in site detectability. As a consequence, estimates of among-site from Pollard-Yates surveys can be biased. © Rapid Science 1998
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  • 50
    ISSN: 1573-1642
    Keywords: watershed ; water quality ; monitoring ; science education ; environmental data
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract From 1992 to 1994, Saturday Academy and the Oregon Graduate Institute of Science and Technology instituted the pilot phase of a long-term monitoring program called the Student Watershed Research Project (SWRP). The SWRP program was developed to create and maintain collaboration among eighth through twelfth grade teachers and students, scientists, businesses, governmental agencies, and community members which would couple environmental education with the collection of high quality, reproducible watershed health data. The original authors of this paper set out to evaluate the impacts of the SWRP program in terms of changes in educational attitudes of participants and collection of accurate data. Findings demonstrate that assuring accuracy of student collected data was challenging, that teachers and students benefited greatly from a hands-on research approach to science education, and that such an approach would be difficult without the support of a program like SWRP. The SWRP program is entering its seventh year in the Portland, Oregon and Vancouver, Washington metropolitan areas with approximately half of the pilot phase participants still involved. A Quality Assurance Project Plan has been developed to assure data accuracy. Evaluation student science education attitudes documents improved results on a yearly basis.
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  • 51
    ISSN: 1573-2959
    Keywords: risk assessment ; chlorinated compound ; environmental ; marine ; exposure ; aquatic toxicity ; monitoring ; chloroform
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This risk assessment on chloroform was carried out specifically for the marine environment, according to the methodology laid down in the EU risk assessment Regulation (1488/94) and the Guidance Document of the EU New and Existing Substances Regulation (TGD, 1997). The study consists of the collection and evaluation of data on effects and environmental concentrations from analytical monitoring programs in large rivers and estuaries in the North Sea area. The risk is indicated by the ratio of the "predicted environmental concentrations" (PEC) and the "predicted no effect concentrations" (PNEC) for the marine aquatic environment. In total, 23 studies for fish, 17 studies for invertebrates and 10 studies for algae have been evaluated. Both acute and chronic toxicity studies have been taken into account and the appropriate assessment factors have been used to define a typical PNEC value of 72 µg/l. Due to limitations of the studies evaluated, a worst PNEC of 1 µg/l could also be used. Most of the available monitoring data apply to rivers and estuaries and were used to calculate PECs. The most recent data (1991-1995) support a typical PEC of 0.2 µg chloroform per litre of water and a worst case PEC of 5 to 11.5 µg chloroform per litre of water. The calculated PEC/PNEC ratios give a safety margin of 6 to 360 between the predicted no effect concentration and the exposure concentrations. A worst case ratio, however, points to a potential risk for sensitive species. Refinement of the assessment is necessary by looking for more data. Additional evaluation of environmental fate and bioaccumulation characteristics showed that no concern is expected for food chain accumulation.
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  • 52
    ISSN: 1573-2959
    Keywords: risk assessment ; chlorinated compound ; environmental ; marine ; exposure ; aquatic toxicity ; monitoring ; tetrachloroethylene
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This risk assessment on tetrachloroethylene (PER) was carried out specifically for the marine environment, according to the methodology laid down in the EU risk assessment Regulation (1488/94) and the Guidance Document of the EU New and Existing Substances Regulation (TGD, 1997). The study consists of the collection and evaluation of data on effects and environmental concentrations from analytical monitoring programs in large rivers and estuaries in the North Sea area. The risk is indicated by the ratio of the "predicted environmental concentrations" (PEC) and the "predicted no effect concentrations" (PNEC) for the marine aquatic environment. In total, 18 studies for fish, 13 studies for invertebrates and 8 studies for algae have been evaluated. Both acute and chronic toxicity studies have been taken into account and the appropriate assessment factors have been used to define a PNEC value of 51 µg/l. Most of the available monitoring data apply to rivers and estuary waters and were used to calculate PECs. The most recent data (1991-1995) support a typical PEC of 0.2 µg PER/l water and a worst case PEC of 2.5 µg PER/l water. The calculated PEC/PNEC ratios give a safety margin of 20 to 250 between the predicted no effect concentration and the exposure concentration. Additional evaluation of environmental fate and bioaccumulation characteristics showed that no concern is expected for food chain accumulation.
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  • 53
    ISSN: 1573-2932
    Keywords: acidification ; acid rain ; catchment ; China ; geochemistry ; soil ; soil water
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Acid deposition is considered to be a major environmental problem in China, but information about effects on soils and waters is scarce. To contribute to increased knowledge about the problem a small catchment (about 7 ha) in the outskirts of Guiyang, the provincial capital of Guizhou in south-western China, was instrumented for collection of precipitation, throughfall, soil water and stream water. In addition soil samples have been collected and analyzed for key properties. Median pH in the precipitation is 4.40 (quartiles: 4.19 and 4.77) and the median sulfate concentration 228 µeq/L (quartiles: 147 and 334 µeq/L). The dry deposition of both SO2 and alkaline dust is considerable. The sum of wet deposition of sulfate and dry deposition of SO2 has been estimated to about 8.5 gSm-2yr-1. The total S-deposition may be somewhat higher due to dry deposition of sulfate and occult deposition. In soil water, SO4 2- is the major anion, generally ranging from 300 to 2500 µeq/L in the different plots. Calcium is an important cation, but there is also a considerable contribution of aluminum from the soil. In some of the plots the concentrations of inorganic monomeric aluminum (Ali) are typically between 200 and 400 µm. Potential harmful levels of aluminum and/or high Ali/(Ca2+ + Mg2+) molar ratios occur in the catchment, but damages to vegetation have not yet been reported. In most cases exchangeable aluminum accounts for between 75 and 95% of the total effective cation exchange capacity (CECE) in the mineral soils. The aluminum chemistry cannot easily be explained by conventional models as the Gaines-Thomas ion-exchange equation or equilibrium with an Al(OH)3 mineral phase. The stream water is generally less acidic and has considerably lower concentrations of aluminum than the soil water, even though quite acid events have been observed (pH 〈 4.4). The median pH values are 4.9 and 5.0 in the two first order streams and 6.3 in the dam at the lower boarder of the catchment.
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  • 54
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    Water, air & soil pollution 105 (1998), S. 31-41 
    ISSN: 1573-2932
    Keywords: acidification ; catchments ; freshwater critical loads ; predictive model ; Scotland ; statistical modeling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Current applications of the critical loads concept are geared primarily toward targeting emission control strategies at a national and international level. Maps of critical loads for freshwaters have been produced in grid form based on water samples of representative sites within each grid square. However, the water chemistry data required to calculate freshwater critical loads are not always readily available at a national level and maps are therefore limited to catchments where such data exist. This paper describes the development of an approach that uses nationally available secondary data to predict freshwater critical loads for catchments lacking the appropriate water chemistry information. An empirical statistical model is calibrated using data from 78 catchments throughout Scotland. Water chemistry for each catchment has been determined. Each catchment is characterized according to a number of attributes. Redundancy analysis of these data shows clear relationships between catchment attributes and the critical load derived from the water chemistry. The key variables that explain most of the variation in critical load relate to soil, geology and land use within the catchment. Using these variables as predictors in a regression analysis, the critical load can be predicted across a broad gradient of sensitivity (R2 adj=0.81). The predictive power of the model was maintained when different combinations of explanatory variables were used. This accords the approach a degree of flexibility in that model parameterization can be geared toward availability of secondary data. There are limitations with the model as presently calibrated. However, the approach offers considerable scope for environmental managers to undertake national inventories of catchment sensitivity and specific assessments of individual catchments.
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  • 55
    ISSN: 1573-2932
    Keywords: catchment ; monitoring ; nitrogen deposition ; nitate leaching ; runoff chemistry ; stream chemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Samples were collected from 13 upland sites (main inflow and loch outflow) in the UK along an N deposition gradient of 12-50 kg ha-1 yr-1 to determine the relationship between N deposition and NO3 - concentrations in surface waters. There was no direct correlation between NO3 - leaching and soluble inorganic N deposition at these sites, but a significant relationship with NO3 - was found using a deposition function incorporating dissolved organic carbon (DOC) flux from each catchment. A similar but less significant relationship was found between NO3 - concentration and DOC:DON ratio in runoff water. Catchments showed evidence of N saturation, i.e., when mean NO3 - concentration exceeded 5 µeq L-1, when the mean DOC:DON ratio fell below an approximate value of 25. Five other large loch sites (LLS) with multiple subcatchments were used to test these relationships and for four of these mostly heathland sites the predicted NO3 - concentrations closely matched measured values. At the fifth site, where most subcatchments were forested, the deposition function and DOC:DON ratios gave conflicting predictions and both methods generally underestimated measured NO3 - concentrations. If the capacity of these catchments to retain deposited N is determined by C supply then many upland catchments in the UK may experience increasing NO3 - concentrations in runoff in the future at current or increased levels of N deposition.
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  • 56
    ISSN: 1573-2932
    Keywords: acidification ; atmospheric deposition ; forest canopy ; Japan ; leaching ; proton budgets
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The proton budgets of deciduous and coniferous forest ecosystems on volcanogenous regosols in Hokkaido, northern Japan, were studied by measuring the biogeochemical fluxes (atmospheric deposition, canopy leaching, vegetation uptake and leaching from soil) at each site during a three year period. The proton budgets were developed for individual compartments of the ecosystem: vegetation canopy, organic and mineral soil layers. At both sites, atmospheric S deposition was the dominant proton source in the vegetation canopy. In organic horizons, dissociation of weak acids (bicarbonate and/or organic acids) and vegetation uptake of base cations were the dominant proton sources, and the net mineralization of base cations was the dominant proton sink. Atmospheric acid deposition was almost neutralized in the forest canopy and organic horizon. At both sites, weathering and/or ion exchange of base cations and protonation of weak acids (mainly bicarbonate) were the dominant proton sinks in the mineral soil. In both organic and mineral soil, internal proton sources (mainly vegetation uptake of base cations and dissociation of weak acids) exceeded external proton sources, indicating that acid deposition was not the main driving force of soil acidification in the studied forest ecosystems.
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  • 57
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    Water, air & soil pollution 105 (1998), S. 11-20 
    ISSN: 1573-2932
    Keywords: acidification ; recovery ; forest soils ; regional dynamic modeling ; Switzerland
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A regionalized version of the dynamic, process-oriented, multi-layer soil chemistry model SAFE was applied to 622 forest sites in Switzerland to assess effects of acidifying atmospheric deposition on the soil chemistry between 1850 and 2050. Simulation indicates that the present day chemical status of Swiss soils is a result of the last 50 years of acid deposition. Indicative soil parameters such as soil solution pH, acid neutralizing capacity, total Al concentration, base cation to total A1 molar ratio and base saturation consistently deteriorate since the beginning of the 1950s, when acid loads start to increase. The simulated adverse evolution of soil chemistry persists until some time between 1975 and 2010, and apart from being site-dependent, the turning-point is also dependent on which parameter is considered at which soil depth.
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  • 58
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    Water, air & soil pollution 105 (1998), S. 83-94 
    ISSN: 1573-2932
    Keywords: acidification ; river water chemistry ; sea salt deposition ; Scotland ; soil solution chemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The majority of Scottish upland soils are particularly sensitive to acid deposition because of their low weathering rates. The compositions of the exchangeable base cations of such soils in the United Kingdom are dominated by sea salt inputs rather than by mineral weathering inputs of base cations. Catchments with low mineral weathering rates are also those particularly susceptible to freshwater acidification. Therefore, catchments exhibiting a high sea salt effect should also exhibit the most acid waters under base flow and storm flow conditions. A field evaluation study based on 61 catchments in NE Scotland has shown that this is indeed the case. River water pH under both base flow and high flow conditions is correlated stronhly with the relative contribution of Na+ to the sum of Ca2+, Mg2+ and Na+. From these results, an attempt is being made to produce a quantitative signature of weathering for the soils within the catchment upstream of the sampling point. Representative soil samples from the LFH, AE, B and C horizons and on 4 different parent materials have been obtained from the surrounding catchments to validate the above results for associated soil solutions. Sampling took place on upland moorland podzols under Calluna vulgaris. Tension lysimeters were used to sample the soil solutions so that their chemistry could be compared with that of the relevant river water.
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  • 59
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    Water, air & soil pollution 105 (1998), S. 471-480 
    ISSN: 1573-2932
    Keywords: benzo(a)pyrene deposition ; Lithuania ; monitoring ; moss chemistry ; plant tissue chemistry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Benzo(a)pyrene (BP) has been investigated in bulk atmospheric deposition, moss, needles of pine and some species of vascular plants. At two remote Lithuanian sites, for 1990-1995 the flux of benzo(a)pyrene from the atmosphere to the ground surface varied between 0.3 to 4.8 μg-2 mo-1. Consequently the territory of Lithuania (65,000 km2) yearly was exposed to 624-2574 kg of carcinogen. The distribution of BP in soil and various vascular plant tissues (Trifolium tepens, Elitrygea repens, Thymus serpyllum) indicates that benzo(a)pyrene is assimilated by flora. The concentration of BP is different in various organs of vascular plants and mostly depends on the degree of soil pollution. More than 300 samples of moss, mostly Hylocomium splendens and Pleurozium schreberi were analyzed for BP. From 3.1 to 896.0 μg kg-1 of BP were measured in the moss samples. The flux of BP to the ground surface correlates well with its concentration in moss. A map of BP flux across Lithuania was created.
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  • 60
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    Water, air & soil pollution 105 (1998), S. 643-659 
    ISSN: 1573-2932
    Keywords: acid deposition ; acidification ; aluminium ; modeling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Although the increased mobilization of aluminum from soils to surface waters is widely recognized as one of the most important ecological effects of acidic deposition, lumped-parameter mathematical models of acidification response typically overestimate the change in Al concentration under changing deposition by a considerable margin. The assumption of equilibrium with gibbsite (Al(OH)3) in the MAGIC model and other models of acid-base chemistry is shown to be inconsistent with measured values for a large variety of lake and stream databases. A modified algorithm for predicting Al concentration, based on empirical relationships evident in field data, provided superior estimates of changes in Al concentration in three long-term monitoring data sets and under experimental conditions at two experimental watershed manipulation sites.
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  • 61
    ISSN: 1573-2959
    Keywords: risk assessment ; chlorinated compound ; marine ; environmental ; exposure ; aquatic toxicity ; monitoring
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This risk assessment on 1,1,2-trichloroethane (T112) was carried out specifically for the marine environment, according to the methodology laid down in the EU risk assessment Regulation (1488/94) and the Guidance Document of the EU New and Existing Substances Regulation (TGD, 1997). The study consists of the collection and evaluation of data on effects and environmental concentrations from analytical monitoring programs in large rivers and estuaries in the North Sea area. The risk is indicated by the ratio of the "predicted environmental concentrations" (PEC) and the "predicted no effect concentrations" (PNEC) for the marine aquatic environment. In total, 22 studies for fish, 45 studies for invertebrates and 9 studies for algae have been evaluated. Both acute and chronic toxicity studies have been taken into account and the appropriate assessment factors have been used to define a PNEC value of 300 µg/l. Most of the available monitoring data apply to rivers and estuaries and were used to calculate PECs. The most recent data (1991-1995) support a typical PEC of 0.01 µg T112/l water and a worst case PEC of 5 µg T112/l water. The calculated PEC/PNEC ratios give a safety margin of 60 to 30,000 between the predicted no effect concentration and the exposure concentration. Additional evaluation of environmental fate and bioaccumulation characteristics showed that no concern is expected for food chain accumulation.
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  • 62
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    Environmental monitoring and assessment 53 (1998), S. 279-295 
    ISSN: 1573-2959
    Keywords: acidification ; dry and wet deposition ; euthrophication ; monitoring
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A monitoring station for atmospheric deposition was designed and constructed. Three such stations were applied in a pilot project for a year on three sites (Speulder forest in The Netherlands, Auchencorth in Scotland and Melpitz in Germany) in different regions in Europe to estimate local inputs and to validate deposition models which are currently used or developed to estimate ecosystem specific deposition in Europe. Fluxes at Auchencorth Moss are lowest for all components, except for those much influenced by the sea as a source. As Melpitz is located far away from seas, these components are lowest at this site. Wet deposition is the dominant source of input at Auchencorth, whereas at Speulder forest, through its roughness and pollution climate, dry deposition is dominant. At this site dry deposition velocities are highest. Melpitz is a polluted site. Particularly sulphur deposition is high. It is recommended to equip several locations in Europe with intensive deposition monitoring methods. Such a network will be an extension of existing monitoring programmes on air pollution, such as that run by Eurepean Monitoring and Evaluation Programme for the long-range transmission of air pollutants in Europe (EMEP). The intensive monitoring locations should be selected based on pollution climates and type of vegetation, common in Europe.
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  • 63
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    Environmental monitoring and assessment 53 (1998), S. 395-399 
    ISSN: 1573-2959
    Keywords: risk assessment ; chlorinated compound ; marine ; environmental ; exposure ; aquatic toxicity ; monitoring
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A voluntary programme on risk assessment for chlorinated chemicals was initiated by Euro Chlor (the European Chlorine Producers Federation). The study was targeted on the marine environment, starting with the North Sea, and the methodology used was based on the European Union risk assessment principles. Details of the method used are described in this paper. A first set of five compounds is published in this special issue: chloroform, 1,2-dichloroethane, 1,1,2-trichloroethane, trichloroethylene, tetrachloroethylene.
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  • 64
    ISSN: 1573-2959
    Keywords: risk assessment ; chlorinated compound ; environmental ; marine ; exposure ; aquatic toxicity ; monitoring ; 1,2-dichloroethane
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract This risk assessment on 1,2-dichloroethane (EDC) was carried out specifically for the marine environment, according to the methodology laid down in the EU risk assessment Regulation (1488/94) and the Guidance Document of the EU New and Existing Substances Regulation (TGD, 1997). The study consists of the collection and evaluation of data on effects and environmental concentrations from analytical monitoring programs in large rivers and estuaries in the North Sea area. The risk is indicated by the ratio of the "predicted environmental concentrations" (PEC) and the "predicted no effect concentrations" (PNEC) for the marine aquatic environment. In total, 21 studies for fish, 17 studies for invertebrates and 7 studies for algae have been evaluated. Both acute and chronic toxicity studies have been taken into account and the appropriate assessment factors have been used to define a PNEC value of 1100 µg/l. Most of the available monitoring data apply to rivers and estuaries and were used to calculate PECs. The most recent data (1991-1995) support a typical PEC of 0.5 µg EDC/l and a worst case PEC of 6.4 µg EDC/l. The calculated PEC/PNEC ratios give a safety margin of 170 to 2200 between the predicted no effect concentration and the exposure concentration. Additional evaluation of environmental fate and bioaccumulation characteristics showed that no concern is expected for food chain accumulation.
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  • 65
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    Environmental modeling and assessment 3 (1998), S. 19-29 
    ISSN: 1573-2967
    Keywords: acidification ; LRTAP ; integrated environmental assessment
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Over recent years Integrated Assessment (IA) has been presented as a new and innovative approach to modern decision making. In this paper we explore some of the key features that we consider characterise IA; we present IA as a framework that allows a flexible approach to uncertainty in decision making and to which a broad palette of expertise can contribute. The example of the development of an international agreement to reduce acidic deposition is used to illustrate the current practical status of an IA. The scientific process leading to this agreement has previously been described as IA but we argue that, although it marks a change from traditional approaches, further progress is still required to satisfy the requirements for a successful and durable IA.
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  • 66
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    Water, air & soil pollution 104 (1998), S. 57-75 
    ISSN: 1573-2932
    Keywords: acidification ; liming ; trace metals
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Sediment cores from two lakes, connected by a limed river, were analyzed for organic matter, calcium (Ca), iron (Fe), manganese (Mn), zinc (Zn), copper (Cu), lead (Pb), cadmium (Cd), and ion exchange capacity. The distribution of trace metals in the pristine upper lake is governed primarily by changes in the long distance atmospheric transported pollutants. In the lake down stream of the liming station the distribution of trace metals in sediments deposited before liming started (1985) is similar to that in the pristine lake. Liming of the connecting river raises the pH value by about 1.8 units from 5.1 enhancing the accumulation rate of trace metals in the downstream lake. Iron enriched acid insoluble particles are likely to be important carriers of trace metals. The liming agent itself is the most important source for Pb, while increased accumulation of Zn and Cd is caused primarily by enhanced scavenging of dissolved metals. For Cu the two sources are of about equal importance.
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  • 67
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    Water, air & soil pollution 104 (1998), S. 269-283 
    ISSN: 1573-2932
    Keywords: acidification ; air pollution ; modelling
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A model, MAKEDEP, was developed for reconstructing historic atmospheric deposition and nutrient uptake for forests using present day values. Deposition is reconstructed by separation of wet deposition and throughfall into five different categories. Dry deposition is assumed to depend linearly on needle biomass. Non-marine deposition is scaled using general European emission and deposition trends for sulphur, nitrate and ammonia. Historic nutrient uptake is reconstructed using current biomass and nutrient content, a logistic forest growth curve and information on historic land use.
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  • 68
    ISSN: 1573-2932
    Keywords: acidification ; catchment ; first-order acidity model ; nitrate leaching ; predictive model
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The relative contribution of N deposition to the acidification of freshwaters in Great Britain has increased over the last few years as S deposition has fallen in line with reduced emissions. In certain high deposition areas of Great Britain, NO3 --based acidity can equal or exceed the contribution of SO4 2--based acidity in some upland waters. Here we apply the first-order acidity balance model (FAB) to predict the maximum N leaching from 13 study catchments at future steady state. Using mean water chemistry and catchment soils data, along with long-term default values for N sink processes, we predict NO3-N leaching at much higher rates than currently are being measured in surface waters, with a mean increase of 10.5 kg ha-1 yr-1. As a result, mean acid neutralizing capacity would decline to less than 0 meq L-1 at 4 sites. While there are uncertainties associated with model parameterization relating to the short-term storage of N within catchment soils and vegetation, model outputs do indicate much greater leaching of N at some time in the future as steady-state is achieved.
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  • 69
    ISSN: 1573-2932
    Keywords: northern Norway ; lakes ; acidification ; brown trout ; Arctic charr
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In this paper we document the effects of acidification on fish populations in lakes in Sør-Varanger near the Russian border in northern Norway. We used questionnaires in order to assess the current status and distribution of different fish species, and conducted test-fishing to determine relative abundance (CPUE-T) and age structure. Acidification of surface waters in this area is due to emissions of SO2 from smelters on the Kola Peninsula in Russia (Nikel and Zapoljarnij) between 10 and 30 km from the Norwegian border. Sulphur deposition in Sør-Varanger ranges from 0.6 to 2.0 g S m-2 yr-1, which is similar to levels in the most acidified areas in southern Norway. However, a dominant fraction of the acidic deposition reaches the ground in particulate form during summer and autumn. Coastal areas in Sør-Varanger receive small amounts of precipitation; the annual mean is 580 mm. We obtained fish status from 401 lakes, about 40% of all lakes larger than 3 ha, which were inhabited by 236 and 293 populations of Arctic charr (Salvelinus alpinus) and brown trout (Salmo trutta), respectively. The extent of fish damage was small as only three populations of Arctic charr were lost, while three populations of Arctic charr and eight populations of brown trout were at various stages of reduction. Damaged and lost fish populations were identified in smaller lakes at relatively high elevations (172–349 m) in six areas in the Jarfjord Mountains, covering a land area of 30.0 km2. Most of the damage probably occurred during the 1970s and 1980s. In lakes that supported or had supported Arctic charr and brown trout, we found a significant relationship between CPUE-T, and acid neutralizing capacity (ANC) and pH, and also between alkalinity and the concentration of inorganic Al for brown trout. In both species, the catch of fish in age groups 1+ and 2+ (CPUE-R) increased significantly with CPUE-T. Affected populations typically exhibited irregular age composition, and age-classes were missing, indicating that reductions in fish populations were due to recruitment failure. The limited fish damage is related to relatively good catchment resistance to acidic inputs, small amounts of wet deposition as well as precipitation. These conditions result in low accumulation of acidic compounds, producing less acidic run-off waters and few episodes of unfavourable water quality.
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  • 70
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    Water, air & soil pollution 104 (1998), S. 223-236 
    ISSN: 1573-2932
    Keywords: acidification ; bioindicators ; macroinvertebrates ; streams
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Recently developed weighted averaging (WA) models and widely used tolerance-limit approaches for inferring stream minimum pH from macroinvertebrates were tested in northeastern Finnish Lapland. Surface waters there are threatened by large sulphur emissions in the Russian Kola Peninsula. The modelled sulphur deposition increases from west to east approximately parallel to longitude. The effect of deposition on stream minimum pH was assessed by relating the macroinvertebrate-inferred stream minimum pH to longitude. In a test set of 17 streams, the minimum pH inferred from pooled invertebrate samples of three seasons by WA models showed a strong correlation (r = 0.67–0.72) with the minimum pH (range 6.3–7.1) observed during the spring snow-melt period. The relationship was slightly weaker (r = 0.59–0.69) using autumn samples only. The tolerance-limit approaches assigned the streams into the correct acidity class, but the inferred pH was not related to the observed minimum pH. This further demonstrates the superiority of the WA approach, especially in detecting early signs of acidification. The minimum pH inferred by WA from autumn assemblages of 37 streams along the deposition gradient showed a significant negative correlation with longitude, suggesting that the emissions from the Kola region contribute to low pH events in streams of northeastern Finnish Lapland. The results demonstrate the potential of bioassessment and monitoring using invertebrates in detecting impacts and changes that could remain unnoticed by conventional water quality-analyses.
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  • 71
    ISSN: 1573-2932
    Keywords: acidification ; emission ; MAGIC ; model ; nitrogen ; SAFE ; SMART ; sulfur
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Three well-known dynamic acidification models (MAGIC, SAFE, SMART) were applied to data sets from five Integrated Monitoring sites in Europe. The calibrated models were used in a policy-oriented framework to predict the long-term soil acidification of these background forest sites, given different scenarios of future deposition of S and N. Emphasis was put on deriving realistic site-specific scenarios for the model applications. The deposition was calculated with EMEP transfer matrices and official emissions for the target years 2000, 2005 and 2010. The alternatives for S deposition were current reduction plans and maximum feasible reductions. For N, the NOx and NHy depositions were frozen at the present level. For NOx, a reduction scenario of flat 30% reduction from present deposition also was utilized to demonstrate the possible effects of such a measure. The three models yielded generally consistent results. The ‘Best prediction’-scenario (including the effects of the second UN/ECE protocol for reductions of SO2 emissions and present level for NOx-emissions), resulted in many cases in a stabilization of soil acidification, although significant improvements were not always shown. With the exception of one site, the ‘Maximum Feasible Reductions’ scenario always resulted in significant improvements. Dynamic models are needed as a complement to steady-state techniques for estimating critical loads and assessing emission reduction policies, where adequate data are available.
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  • 72
    ISSN: 1573-2932
    Keywords: acidification ; decreasing SO2 emissions ; lake water chemistry ; Ontario ; sulfate deposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract We monitored the chemistry of 603 small water bodies in three acid-sensitive regions of central Ontario, Canada (Algoma n=235, Muskoka n=216, Sudbury n=152) between 1988-1996 to determine whether they have responded to recent SO2 emission reductions, and whether any chemical changes were related to lake characteristics. During the study, 27-56% of lakes declined in SO4 2- concentrations, 41-57% declined in base cation concentrations, but only 26-28% increased in pH or ANC (acidity status). Increases in pH were greatest in lakes with low ANC, but had weak relationships to lake color or volume. No consistent trends were observed for DOC, NO3 - or TP concentrations. Clearly, the long-term biological recovery of these sensitive aquatic ecosystems will depend on interactions among several environmental stressors, including acidification.
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  • 73
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    Water, air & soil pollution 108 (1998), S. 107-127 
    ISSN: 1573-2932
    Keywords: acid deposition ; acidification ; base cations ; Bohemian lakes ; chloride ; Czech Republic ; lake water ; nitrate ; pH ; reversibility ; sulphate ; temporal changes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Temporal changes in major solute concentrations in six Czech Republic lakes were monitored during the period 1984–1995. Four chronically-acidic lakes had decreasing concentrations of strong-acid anions (CSA = SO4 2- + NO3 - + Cl-), at rates of 3.0 to 9.0 μeq L-1 yr-1. Decreases in SO4 2-, NO3 -, and Cl- (at rates up to 5.1 μeq L-1 yr-1, 3.2 μeq L-1 yr-1, and 0.6 μeq L-1 yr-1, respectively) occurred. The response to the decrease in deposition of S was rapid and annual decline of SO4 2- in lake water was directly proportional to SO4 2- concentrations in the acidified lakes. Changes in NO3 - concentrations were modified by biological consumption within the lakes. The decline in CSA was accompanied in the four most acidic lakes by decreases in AlT, increases in pH at rates of 0.011 to 0.016 pH yr- 1, and decreases of Ca2+ and Mg2+ (but not Na+) in three lakes. The acid neutralizing capacity (ANC) increased significantly in all six lakes. Increases in base cation concentrations (CB = Ca2+ + Na+ + Mg2+ + K+) were the principal contributing factor to ANC increases in the two lakes with positive ANC, whereas decrease in CSA was the major factor in ANC increases in the four chronically-acidic lakes. The continued chemical recovery of these lakes depends on the uncertain trends in N deposition, the cycling of N in the lakes and their catchments, and the magnitude of the future decrease in S deposition.
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    Water, air & soil pollution 108 (1998), S. 425-443 
    ISSN: 1573-2932
    Keywords: acidic deposition ; acidification ; aluminum ; atmosphericdeposition ; Bohemia ; Czech Republic ; fluoride ; lake ; trace metal ; trace element ; reversibility ; restoration
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The concentrations of Al, Be, Cd, Cu, F, Fe, Mn, Pb, and Zn were monitored in five glacial lakes and one man-made lake in the southwestern part of the Czech Republic. The lakes had median pHs of 4.4 to 6.5 during 1984 to 1995. Decreases in the concentrations of Mn and Pb occurred in five acidified lakes. The concentrations of AlT, Be, Cd, and F decreased in the four chronically acidified lakes, Zn decreased in two lakes. Concentrations of Cu and Fe remained unchanged. The decreases in Be, Mn, and Zn concentrations were proportional to the decrease in CSA (CSA = SO4 2- + NO3 -+ Cl-); decreases in AlT, Cd, and Pb concentrations were proportionately higher, while F was lower. The greater decrease in the Pb concentrations (61 to 79%, at a rate up to 0.15 μg L-1yr-1) was caused by pronounced decreases in deposition of Pb derived from mobile sources. The decrease of AlT concentrations was dominated by a decrease in Al3+, whose concentration decreased by 51 to 86%. The concentrations of complexes Al(OH)2+, Al(OH)2 +, AlF2+, and AlH3SiO4 2+ also decreased. The decrease in the concentrations of inorganic forms of Al (Ali) compensated 65% of the decrease in CSA. The Cd concentrations were highly variable in the years 1986 to 1988 because of variable amounts of accumulation on particles.
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    Water, air & soil pollution 108 (1998), S. 51-68 
    ISSN: 1573-2932
    Keywords: Crustacea ; growth ; heavy metals ; monitoring
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The dynamics of lead (Pb) and cadmium (Cd) accumulation in juvenile Porcellio scaber were studied over 6 months after exposing them to three different concentrations of lead and cadmium in their food. Subsequently the ability of P. scaber to eliminate lead and cadmium was studied over two months. Growth was measured to determine whether metal contamination leads to physiological stress in the animals. The accumulation of Pb and Cd in P. scaber shows two different phases. Up to the age of 2–3 months the assimilation exceeds the rate of growth and leads to rapidly increasing concentrations. After 3 months the rate of accumulation is proportional to the rate of growth and the heavy metal concentrations remain on a stabilized level. P. scaber was able to eliminate about 40% of the assimilated lead within 2 weeks but there was no elimination of Cd within 7 weeks. Contaminated P. scaber shows significant growth reduction. The physiological response of P. scaber to heavy metal contamination is discussed.
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  • 76
    ISSN: 1573-2932
    Keywords: acidification ; assessment ; eutrophication ; Speulder forest ; vitality
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Within the framework of the Dutch Priority Program on Acidification, 10 yr of research was conducted in a Douglas fir stand at Speulder forest. Research was conducted to establish the loads and levels of acidifying and eutrophying pollutants and ozone, to determine forest vitality characteristics and follow growth parameters and nutrient status in time and to determine the effects of reduction of loads and levels by manipulation experiments. Results indicate that during the last 20 yr critical levels for air pollutants have hardly been exceeded except for ozone, which slightly affected assimilation. Elevated nitrogen deposition has caused several adverse effects including (i) inhibited mycorrhizal development, leading to a decreased base cation and phosphorus uptake; (ii) elevated foliage/root (fine and coarse) ratios, making the forest more sensitive to drought and windthrow; (iii) elevated nitrogen and arginine concentrations in the foliage, associated with relative base cation and phosphorus deficiency, and (iv) elevated nitrate leaching polluting the groundwater. High inputs of acidity have caused elevated ratios of Al to base cations, affecting fine root (uptake) and depletion of the readily available Al pool, thus affecting the long-term sustainability. Despite these effects, forest vitality, in terms of defoliation/discoloration, is reasonable and forest growth even increased in response to nitrogen. The exceedances of critical loads for nitrogen and acidity, however, implies a (large) risk for the long-term sustainability of the Speulder forest.
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  • 77
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    Water, air & soil pollution 101 (1998), S. 257-288 
    ISSN: 1573-2932
    Keywords: acidification ; forest lakes ; lime treatment ; planktonic crustaceans
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In Sweden, approximately 16 000 of a total of about 85 000 lakes have been acidified due to acidic deposition. Of these about 8000 have been treated with limestone powder in order to detoxify the acidified waters and protect sensitive fauna. The present study was performed in ten lakes in the southern part of the country. The lakes belong to four different catchments and were in different stages of acidification at the time of lime treatment. The composition of the zooplankton and fish communities also differed and three lakes were empty of fish at the beginning of the studies. Quantitative sampling of planktonic crustaceans was performed during the ice free season between 1976–87 in five of the lakes and between 1977–87 in the other five. After treatment the pH increased significantly in all lakes except one. The average number of crustacean taxa found per sampling occasion increased in all lakes. Increases were statistically significant in four of the lakes. In the lakes empty of fish, increased abundances of chaoborids inhibited, by predation, the increase of species richness. Species richness increased after the introduction of fish and the subsequent reduction of the chaoborids. At the end of the study, more taxa were found in the limed study lakes than in non-treated west coast lakes with an alkalinity of 0.04–0.10 meq L-1. Most species normally occurring in oligotrophic forest lakes were found. It was shown that the water quality after liming made the occurrence of sensitive species possible and that predation from fish and interactions within the zooplankton assemblage were of great importance to the species composition and structure of the zooplankton community.
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    Water, air & soil pollution 105 (1998), S. 217-226 
    ISSN: 1573-2932
    Keywords: California ; monitoring ; nitrate export ; Sierra Nevada ; stream water chemistry ; sulfate export ; watershed
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Based on studies of high-elevation, Sierra Nevada catchments during the period from 1983 through 1996, we describe temporal variations in the concentrations of NO3 - and SO4 2- in surface waters. During snowmelt, some catchments had a pattern of NO3 - increase to a plateau between the start of snowmelt and some weeks before runoff peaked, and a decline as runoff increased to its maximum. In other catchments, NO3 - concentrations peaked during the autumn and winter. Long-term trends in surface water chemistry were evident in only two catchments: an increase in SO4 2- concentrations in surface waters of the Ruby Lake basin, and a lowering of annual maxima and minima of NO3 - concentrations at Emerald Lake. From October 1987 through April 1994, SO4 2- concentrations increased from about 6 µeq L-1 to about 12 µeq L-1 in Ruby Lake, and in Emerald Lake, NO3 - maxima declined by 25-50 %.
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  • 79
    ISSN: 1573-2932
    Keywords: sulfur ; sulfate ; desiccation ; acidification ; nutrients ; water quality ; pollution ; wetlands
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In recent decades, SO4 2- concentrations have increased in groundwater and surface water of freshwater wetlands. For many minerotrophic peatlands, S originating from SO4 2--polluted groundwater and surface water is a more significant source of SO4 2- than the actual atmospheric deposition of S compounds. Lowered groundwater tables in wetlands, as a result of either natural or anthropogenic desiccation, may cause acidification because of concomitant geochemical oxidation processes. The impact of the enhanced availability of reduced S compounds, due to preceding SO4 2- pollution, on these processes was tested in a mesocosm experiment, using soil cores including vegetation from a mesotrophic wet meadow. The soils had been maintained in waterlogged condition for seven months, using two environmentally relevant SO4 2- concentrations (2 and 4 mmol L-1). The groundwater table was reduced in two successive steps: 10 cm below soil surface, and complete desiccation. Control pretreated soils did not show a decrease in soil pH during desiccation, due to adequate buffering by bicarbonate. However, both SO4 2--pretreated groups showed a significant drop in pH (from 6.5 to 4.5) caused by additional sulfide oxidation, leading to high SO4 2- concentrations (10 and 16 mmol L-1, respectively). Cation exchange and acidification-related solubilization processes induced the mobiliztation of base cations and potentially phytotoxic metals like Al. Nutrient concentrations in soil moisture were influenced strongly by SO4 2- pretreatment, showing distinct patterns for P, N and K. Therefore, S polluted groundwater and surface water may severely increase the sensitivity of wetlands to desiccation. The results are discussed in relation to wetland management.
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    Mitigation and adaptation strategies for global change 2 (1997), S. 101-115 
    ISSN: 1573-1596
    Keywords: Carbon dioxide ; costs ; forests ; Joint Implementation ; mitigation ; monitoring ; policies
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Abstract Forest sector mitigation options can be grouped into three categories: (1) management for carbon (C) conservation, (2) management for C storage, and (3) management for C substitution. The paper provides background information on the technical potential for C conservation and sequestration worldwide and the average costs of achieving it. It reviews policy measures that have been successfully applied at regional and project levels toward the reduction of atmospheric greenhouse gases. It also describes both national programs and jointly implemented international activities. The monitoring methods, and the items to monitor, differ across these categories. Remote sensing is a good approach for the monitoring of C conservation, but not for C substitution, which requires estimation of the fossil fuels that would be displaced and the continued monitoring of electricity generation sources. C storage, on the other hand, includes C in products which may be traded internationally. Their monitoring will require that bi- or multi-lateral protocols be set up for this purpose.
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    Mitigation and adaptation strategies for global change 2 (1997), S. 191-202 
    ISSN: 1573-1596
    Keywords: Carbon storage ; Joint Implementation ; monitoring ; remote sensing
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Abstract Adequate monitoring of carbon sequestered by forestry activities is essential to the future of forestry as a climate change mitigation option. A wide range of approaches has been taken to monitor changes in forest carbon attributable to project activities. This paper describes simple, least-cost/least-precision methods, remote sensing, periodic carbon inventories, and traditional research methods. Periodic carbon inventories are the preferred approach because they are cost-effective, provide measurements with known levels of precision, and allow the monitoring of other values such as biodiversity and commercial timber volumes. Verification of monitoring estimates is discussed as an auditing process designed to evaluate reported carbon sequestration values. The limitations of remote sensing for biomass determination and the potential for changes in monitoring approaches due to improvements in technology are briefly reviewed.
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    Mitigation and adaptation strategies for global change 2 (1997), S. 231-246 
    ISSN: 1573-1596
    Keywords: Farm forestry ; carbon sequestration ; monitoring ; evaluation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Abstract In Mexico an estimated 4.5 × 106ha are available for farm forestry, while up to 6.1 × 106 ha could be saved from deforestation by making shifting agriculture more productive and sustainable. Various farm forestry systems are technically, socially, and economically viable, including live fences, coffee with shade trees, plantations, tree enrichment of fallows, and taungya, with a C-sequestration potential varying from 17.6 to 176.3 Mg C ha−1. A self-reporting system with on-site spot checks is presented for the monitoring and evaluation (M&E), and will be tested in a farm forestry C-sequestration pilot project, to begin in Chiapas, Mexico, in 1997. The M&E procedure will facilitate the collection of field data at low cost, help ensure that the systems continue to address the needs of farmers, and give farmers an understanding of the value of the service that they are providing.
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    Mitigation and adaptation strategies for global change 2 (1997), S. 101-115 
    ISSN: 1573-1596
    Keywords: Carbon dioxide ; costs ; forests ; Joint Implementation ; mitigation ; monitoring ; policies
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Abstract Forest sector mitigation options can be grouped into three categories: (1) management for carbon (C) conservation, (2) management for C storage, and (3) management for C substitution. The paper provides background information on the technical potential for C conservation and sequestration worldwide and the average costs of achieving it. It reviews policy measures that have been successfully applied at regional and project levels toward the reduction of atmosphere greenhouse gases. It also describes both national programs and jointly implemented international activities. The monitoring methods, and the items to monitor, differ across these categories. Remote sensing is a good approach for the monitoring of C conservation, but not for C substitution, which requires estimation of the fossil fuels that would be displaced and the continued monitoring of electricity generation sources. C storage, on the other hand, includes C in products which may be traded internationally. Their monitoring will require that bi- or multi-lateral protocols be set up for this purpose.
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  • 84
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    Mitigation and adaptation strategies for global change 2 (1997), S. 231-246 
    ISSN: 1573-1596
    Keywords: Farm forestry ; carbon sequestration ; monitoring ; evaluation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Abstract In Mexico an estimated 4.5×106ha are available for farm forestry, while up to 6.1×106ha could be saved from deforestation by making shifting agriculture more productive and sustainable. Various farm forestry systems are technically, socially, and economically viable, including live fences, coffee with shade trees, plantations, tree enrichment of fallows, and taungya, with a C-sequestration potential varying from 17.6 to 176.3 Mg C ha−1. A self-reporting system with on-site spot checks is presented for the monitoring and evaluation (M&E), and will be tested in a farm forestry C-sequestration pilot project, to begin in Chiapas, Mexico, in 1997. The M&E procedure will facilitate the collection of field data at low cost, help ensure that the systems continue to address the needs of farmers, and give farmers an understanding of the value of the service that they are providing.
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  • 85
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    Water, air & soil pollution 93 (1997), S. 255-266 
    ISSN: 1573-2932
    Keywords: Ratcliffe index ; egg size ; acidification
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Eggs of dippers Cinclus cinclus from a chronically acidified area in Southern Norway werecompared with eggs from a non-acidified area in Central Norway. There were no differences inegg size, as measured by volume, weight, length and calculated surface area, between the twoareas. Eggshells were 7.0% lighter and 6.1% thinner, as measured by the Ratcliffe index and 7.0%as measured by the eggshell index (shell weight/surface area) in Southern Norway than in CentralNorway. The Ratcliffe and eggshell indices were highly correlated. Scanning electron micrographsshowed that the palisade layer of eggshells of eggs from the acidified area was 10.7% thinner thanthat of eggshells of eggs from the non-acidified area. Eggshell vapour permeability was notsignificantly influenced by area. Since the moderately lower thickness in Southern Norway wasnot accompanied by higher vapour permeability, this indicates that the reduced eggshell thicknessdid not cause desiccation of dipper eggs in the acidified area. The possibility of underestimatingthe environmental effects of acidification on dippers is discussed.
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  • 86
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    Environmental and ecological statistics 4 (1997), S. 131-152 
    ISSN: 1573-3009
    Keywords: biodiversity ; geographic information systems ; geostatistics ; monitoring ; response surfaces ; spatial analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Echelons provide an objective approach to prospecting for areas of potential concern in synoptic regional monitoring of a surface variable. Echelons can be regarded informally as stacked hill forms. The strategy is to identify regions of the surface which are elevated relative to surroundings (Relative ELEVATIONS or RELEVATIONS). These are areas which would continue to expand as islands with receding (virtual) floodwaters. Levels where islands would merge are critical elevations which delimit echelons in the vertical dimension. Families of echelons consist of surface sectors constituting separate islands for deeper waters that merge as water level declines. Pits which would hold water are disregarded in such a progression, but a complementary analysis of pits is obtained using the surface as a virtual mould to cast a counter-surface (bathymetric analysis). An echelon tree is a family tree of echelons with peaks as terminals and the lowest level as root. An echelon tree thus provides a dendrogram representation of surface topology which enables graph theoretic analysis and comparison of surface structures. Echelon top view maps show echelon cover sectors on the base plane. An echelon table summarizes characteristics of echelons as instances or cases of hill form surface structure. Determination of echelons requires only ordinal strength for the surface variable, and is thus appropriate for environmental indices as well as measurements. Since echelons are inherent in a surface rather than perceptual, they provide a basis for computer-intelligent understanding of surfaces. Echelons are given for broad-scale mammalian species richness in Pennsylvania.
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  • 87
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    Mitigation and adaptation strategies for global change 2 (1997), S. 191-202 
    ISSN: 1573-1596
    Keywords: Carbon storage ; Joint Implementation ; monitoring ; remote sensing
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Abstract Adequate monitoring of carbon sequestered by forestry activities is essential to the future of forestry as a climate change mitigation option. A wide range of approaches has been taken to monitor changes in forest carbon attributable to project activities. This paper describes simple, least-cost/least-precision methods, remote sensing, periodic carbon inventories, and traditional research methods. Periodic carbon inventories are the preferred approach because they are cost-effective, provide measurements with known levels of precision, and allow the monitoring of other values such as biodiversity and commercial timber volumes. Verification of monitoring estimates is discussed as an auditing process designed to evaluate reported carbon sequestration values. The limitations of remote sensing for biomass determination and the potential for changes in monitoring approaches due to improvements in technology are briefly reviewed.
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  • 88
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    Journal of fusion energy 16 (1997), S. 231-236 
    ISSN: 1572-9591
    Keywords: Dust ; radioactive inventory ; removal ; monitoring
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract In the future fusion reactor, dust control may become more important for safety, than for existing fusion facilities. Some estimations show more than hundreds kg/yr dust will be generated from the plasma facing materials in the vacuum vessel. If we consider continuously operating plant, dust should be monitored and removed during the operation time. Optical monitoring methods and electrostatic removal methods are useful approaches to accomplish this. An investigation of the development of the dust removal system for a fusion reactor is reported in this paper.
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  • 89
    ISSN: 1573-2932
    Keywords: nitrogen ; acidification ; Adirondack Mountains ; atmospheric deposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Assessments of the aquatic effects of acidic deposition have focused on sulfur, as have recent efforts to control the emissions of acidifying compounds. Nitrogen dynamics were excluded from most acidic deposition modeling studies because it was believed that terrestrial ecosystems strongly retain N and because modeling N is a more formidable task than modeling S due to the influence of complex biological processes on N cycling. Re-examination of available data for the Adirondack Mountains of New York suggests that N deposition may be contributing to both chronic and episodic acidification of freshwaters to a greater extent than is generally believed. Previous research concluded that N has played a limited role in acidification processes in these lakes, based on regional averages of chronic chemistry. However, it is now known that historic acidification responses have been spatially variable within the Adirondack Mountains and that the declines in lakewater pH have been less than previously believed. Lakewater NO3 − concentrations are commonly in the range of 5 to 25 μeq L−1 on a chronic basis in portions of the Adirondack region that have experienced significant chronic acidification. These NO3 − concentrations correspond in magnitude to inferred historical acidification. Furthermore, the relative importance of NO3 − as an agent of acidification increases dramatically during snowmelt when conditions are most toxic to fish. The consequence of not addressing N in formulating acidification recovery strategies for the Adirondacks includes the likelihood that we will overestimate the response of surface water to the mandated sulfur emissions reductions.
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  • 90
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    Water, air & soil pollution 96 (1997), S. 347-366 
    ISSN: 1573-2932
    Keywords: acidification ; chemical weathering ; hydroxysulfates formation ; mine spoil ; sulfides oxidation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Processes contributing to acid release/consumption during weathering of a lignite mine spoil (2.3% w/w S as sulfides) from As Pontes (N.W. Spain) were studied under three moisture conditions (at field capacity or under alternate wetting-drying or forced percolation), which were simulated in laboratory experiments. Oxidation of sulfides to sulfates was favoured under all three moisture conditions, releasing most acid in spoil kept at field capacity. Hydroxysulfates formed in spoil kept at field capacity or under alternate wetting-drying conditions, thereby contributing to acid release. Acid consumption by dissolution of clay minerals, especially micas, was favoured under all three moisture conditions, but was particularly intense in spoil at field capacity. Dissolution of aluminium oxides was also favoured under all the moisture conditions studied.
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  • 91
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    Water, air & soil pollution 96 (1997), S. 17-38 
    ISSN: 1573-2932
    Keywords: acid-sensitive lakes ; acidification ; organics peatlands ; Sphagnum
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract About a third of the lakes surveyed in the Birch Mountains Upland of northeastern Alberta, Canada, have pH below 7.0; 25% have alkalinities below 10 mg/L identifying them as acid-sensitive following criteria established by the National Research Council of Canada (1981). Lakes in this region vary greatly as to surface area and depth. Watersheds also vary in area and in amount of peatland cover. Peatlands in the form of peat plateaus and collapse scars, continental bogs, treed and open fens, and shallow organic deposits cover over 50% of some watersheds. Surface water chemistries of these peatlands form three distinct classes: bogs, poor fens and shallow organic deposits. The acidity of certain lakes in this northern area is best explained by effects from high cover of Sphagnum-dominated peatlands in surrounding watersheds. Due to greater flow-through, poor fens appear to be more important than bogs in affecting the acidity of associated lakes.
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  • 92
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    Water, air & soil pollution 96 (1997), S. 347-366 
    ISSN: 1573-2932
    Keywords: acidification ; chemical weathering ; hydroxysulfates formation ; mine spoil ; sulfides oxidation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Processes contributing to acid release/consumption during weathering of a lignite mine spoil (2.3% w/w S as sulfides) from As Pontes (N.W. Spain) were studied under three moisture conditions (at field capacity or under alternate wetting-drying or forced percolation), which were simulated in laboratory experiments. Oxidation of sulfides to sulfates was favoured under all three moisture conditions, releasing most acid in spoil kept at field capacity. Hydroxysulfates formed in spoil kept at field capacity or under alternate wetting-drying conditions, thereby contributing to acid release. Acid consumption by dissolution of clay minerals, especially micas, was favoured under all three moisture conditions, but was particularly intense in spoil at field capacity. Dissolution of aluminium oxides was also favoured under all the moisture conditions studied.
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  • 93
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    Water, air & soil pollution 96 (1997), S. 17-38 
    ISSN: 1573-2932
    Keywords: acid-sensitive lakes ; acidification ; organics peatlands ; Sphagnum
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract About a third of the lakes surveyed in the Birch Mountains Upland of northeastern Alberta, Canada, have pH below 7.0; 25% have alkalinities below 10 mg/L identifying them as acid-sensitive following criteria established by the National Research Council of Canada (1981). Lakes in this region vary greatly as to surface area and depth. Watersheds also vary in area and in amount of peatland cover. Peatlands in the form of peat plateaus and collapse scars, continental bogs, treed and open fens, and shallow organic deposits cover over 50% of some watersheds. Surface water chemistries of these peatlands form three distinct classes: bogs, poor fens and shallow organic deposits. The acidity of certain lakes in this northern area is best explained by effects from high cover ofSphagnum-dominated peatlands in surrounding watersheds. Due to greater flow-through, poor fens appear to be more important than bogs in affecting the acidity of associated lakes.
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  • 94
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    Water, air & soil pollution 93 (1997), S. 255-266 
    ISSN: 1573-2932
    Keywords: Ratcliffe index ; egg size ; acidification
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Eggs of dippersCinclus cinclus from a chronically acidified area in Southern Norway were compared with eggs from a non-acidified area in Central Norway. There were no differences in egg size, as measured by volume, weight, length and calculated surface area, between the two areas. Eggshells were 7.0% lighter and 6.1% thinner, as measured by the Ratcliffe index and 7.0% as measured by the eggshell index (shell weight/surface area) in Southern Norway than in Central Norway. The Ratcliffe and eggshell indices were highly correlated. Scanning electron micrographs showed that the palisade layer of eggshells of eggs from the acidified area was 10.7% thinner than that of eggshells of eggs from the non-acidified area. Eggshell vapour permeability was not significantly influenced by area. Since the moderately lower thickness in Southern Norway was not accompanied by higher vapour permeability, this indicates that the reduced eggshell thickness did not cause desiccation of dipper eggs in the acidified area. The possibility of underestimating the environmental effects of acidification on dippers is discussed.
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  • 95
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    Water, air & soil pollution 94 (1997), S. 59-69 
    ISSN: 1573-2932
    Keywords: fly-ash particles ; ombrotrophic peats ; air pollution history ; monitoring
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The movement of fly-ash particles in a sequence ofSphagnum moss was studied in laboratory experiments and field investigations. The data obtained in the laboratory show that only 0.8% of particles, placed on the surface of a 6–10 cm thickSphagnum layer, were washed out with water (700–750 mm) during the 241 days of the experiment. The majority of added particles were fixed in the upper part (90% in 1–3 cm) of the moss layer. A SEM study indicates that sorption is slightly species-dependent due to the micromorphological parameters of theSphagnum species. The storage of particles bySphagnum mosses allows the use of natural sequences to study the history of atmospheric pollution. The distribution of particles in the upper part of moss layers in Viru Bog (50 km east of Tallinn, North Estonia) shows good agreement with the known air pollution history in Tallinn.
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  • 96
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    Water, air & soil pollution 94 (1997), S. 225-245 
    ISSN: 1573-2932
    Keywords: acid precipitation ; Quebec ; lakewater quality ; acidification and recovery ; monitoring
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A total of 51 lakes in southern Quebec, Canada, were sampled between 1985 and 1993 to study changes in water chemistry following reductions in SO2 emissions (main precursor of acid precipitation). Time series analysis of precipitation chemistry revealed significant reductions in concentrations and deposition of SO4 2- from 1981 to 1992 in southern Quebec as well as reductions in concentrations and deposition of base cations (Ca2+, Mg2+), NO3 - and H+ in the western section of the study area. Reductions in atmospheric inputs of SO4 2- have resulted in decreased lakewater SO4 2- concentrations in the majority of the lakes in our study, although only a small fraction (9 of 37 lakes used in the temporal analysis) have improved significantly in terms of acidity status (pH, acid neutralizing capacity – ANC). The main response of the lakes to decreased SO4 2- is a decrease in base cations (Ca2++Mg2+), which was observed in 17 of 37 lakes. Seventeen lakes also showed significant increases in dissolved organic carbon (DOC) over the period of study. The resulting increases in organic acidity as well as the decrease in base cations could both play a role in delaying the recovery of our lakes.
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  • 97
    ISSN: 1573-2932
    Keywords: nitrogen ; acidification ; Adirondack Mountains ; atmospheric deposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Assessments of the aquatic effects of acidic deposition have focused on sulfur, as have recent efforts to control the emissions of acidifying compounds. Nitrogen dynamics were excluded from most acidic deposition modeling studies because it was believed that terrestrial ecosystems strongly retain N and because modeling N is a more formidable task than modeling S due to the influence of complex biological processes on N cycling. Re-examination of available data for the Adirondack Mountains of New York suggests that N deposition may be contributing to both chronic and episodic acidification of freshwaters to a greater extent than is generally believed. Previous research concluded that N has played a limited role in acidification processes in these lakes, based on regional averages of chronic chemistry. However, it is now known that historic acidification responses have been spatially variable within the Adirondack Mountains and that the declines in lakewater pH have been less than previously believed. Lakewater NO3 - concentrations are commonly in the range of 5 to 25 μeq L-1 on a chronic basis in portions of the Adirondack region that have experienced significant chronic acidification. These NO3 - concentrations correspond in magnitude to inferred historical acidification. Furthermore, the relative importance of NO3 - as an agent of acidification increases dramatically during snowmelt when conditions are most toxic to fish. The consequence of not addressing N in formulating acidification recovery strategies for the Adirondacks includes the likelihood that we will overestimate the response of surface water to the mandated sulfur emissions reductions.
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  • 98
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    Environmental monitoring and assessment 47 (1997), S. 223-237 
    ISSN: 1573-2959
    Keywords: contamination ; groundwater ; monitoring ; nitrate ; pesticide
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract A shallow aquifer in central South Dakota was monitored for thepresence of nitrate and pesticides. A total of 593 nitrate samples and428 pesticide samples were analyzed from nine different sites and 14wells between 1989 and 1994. Nested wells were installed at four sitesto characterize the distribution pattern of nitrate and pesticidemovement in ground water. Nitrate concentrations and pesticidedetections were qualitatively compared with area precipitation and watertable fluctuations. The results indicate that nitrates tend to betransported by a leaching mechanism in a matrix flow and may appearin ground water within months after the fertilizer application in thefields. The pesticide movement is primarily controlled by geologicaland chemical characteristics of medium and pesticides.
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  • 99
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    Water, air & soil pollution 96 (1997), S. 203-210 
    ISSN: 1573-2932
    Keywords: acidification ; blood ; environment ; fish
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Certain blood morphology parameters: red blood cell (RBC) sizes; percentage of polymorphonuclear leukocytes and ratio polychromatocyte/RBC in Brown trout (Salmo trutta L.) from acidified water (mean pH value 4.94) and limed water (mean pH value 5.66) were investigated. The sizes of RBC long axises were significantly larger in fish from acidic environment than from limed condition (14.37 and 12.96μm respectively). The percentage of polymorphonuclear cells (7.86 and 3.32) and polychromatocyte/RBC ratio (0.079 and 0.019) were also significantly larger in fish from the acidified environment. Blood morphology parameters are concluded to be usefull for testing and detection of long-term acidic stress in fish in nature.
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    Water, air & soil pollution 96 (1997), S. 203-210 
    ISSN: 1573-2932
    Keywords: acidification ; blood ; environment ; fish
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Certain blood morphology parameters: red blood cell (RBC) sizes; percentage of polymorphonuclear leukocytes and ratio polychromatocyte/RBC in Brown trout (Salmo trutta L.) from acidified water (mean pH value 4.94) and limed water (mean pH value 5.66) were investigated. The sizes of RBC long axises were significantly larger in fish from acidic environment than from limed condition (14.37 and 12.96 μm respectively). The percentage of polymorhonuclear cells (7.86 and 3.32) and polychromatocyte/RBC ratio (0.079 and 0.019) were also significantly larger in fish from the acidified environment. Blood morphology parameters are concluded to be usefull for testing and detection of long-term acidic stress in fish in nature.
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