ALBERT

Description: The Latest Danian Event (LDE; ~62.15 Ma) is a major double-spiked eccentricity-driven transient warming event and carbon cycle perturbation (hyperthermal) in the early Paleocene, which has received significantly less attention compared to the larger events of the late Paleocene–early Eocene. A better understanding of the nature of the LDE may broaden our understanding of hyperthermals more generally and improve our knowledge of Earth system responses to extreme climate states. Here we present planktic and benthic foraminiferal Mg/Ca and B/Ca records that shed new light on changes in South Atlantic temperature and carbonate chemistry during the LDE. Our planktic Mg/Ca record reveals a pulsed increase in sea surface temperature of at least ~1.5°C during the older carbon isotope excursion, and ~0.5°C during the younger isotope excursion. We observe drops in planktic and benthic B/Ca, synchronous with pronounced negative excursions in benthic δ13C, which suggest a shift in the carbonate system towards more acidic, dissolved inorganic carbon-rich conditions, in both the surface and deep ocean. Conditions remain more acidic following the LDE, which we suggest may be linked to an enhanced ocean alkalinity sink due to changes in the make-up of planktic calcifiers, hinting at a novel feedback between calcifier ecology and ocean-atmosphere CO2.

Description: Paired benthic foraminiferal trace metal and stable isotope records have been constructed from equatorial Pacific Ocean Drilling Program Site 1218. The records include the two largest abrupt (〈1 Myr) increases in the Cenozoic benthic oxygen isotope record: Oi‐1 in the earliest Oligocene (∼34 Ma) and Mi‐1 in the earliest Miocene (∼23 Ma). The paired Mg/Ca and oxygen isotope records are used to calculate seawater δ18O (δw). Calculated δw suggests that a large Antarctic ice sheet formed during Oi‐1 and subsequently fluctuated throughout the Oligocene on both short (〈0.5 Myr) and long (2–3 Myr) timescales, between about 50 and 100% of its maximum earliest Oligocene size. The magnitudes of these fluctuations are consistent with estimates of sea level derived from sequence stratigraphy. The transient expansion of the Antarctic ice sheet at Mi‐1 is marked in the benthic δ18O record by two positive excursions between 23.7 and 22.9 Ma, each with a duration of 200–300 kyr. Bottom water temperatures decreased by ∼2°C over the 150 kyr immediately prior to both rapid δ18O excursions. However, the onset of each of these phases of ice growth is synchronous, within the resolution of the records, with the onset of a 2°C warming over ∼150 kyr. We suggest that the warming during these glacial expansions reflect increased greenhouse forcing prompted by a sudden decrease in global chemical weathering rates as Antarctic basement silicate rocks became blanketed by an ice sheet. This represents a negative feedback process that might have operated during major abrupt growth phases of the Antarctic ice sheet.

Description: Current climate change may induce positive carbon cycle feedbacks that amplify anthropogenic warming on time scales of centuries to millennia. Similar feedbacks might have been active during a phase of carbon cycle perturbation and global warming, termed the Paleocene-Eocene Thermal Maximum (PETM, 56 million years ago). The PETM may help constrain these feedbacks and their sensitivity to warming. We present new high-resolution carbon isotope and sea surface temperature data from Ocean Drilling Project Site 959 in the Equatorial Atlantic. With these and existing data from the New Jersey shelf and Maud Rise, Southern Ocean, we quantify the lead-lag relation between PETM warming and the carbon input that caused the carbon isotope excursion. We show ~2 ºC of global warming preceded the CIE by millennia, strongly implicating CO2-driven warming triggered a positive carbon cycle feedback. We further compile new and published barium (Ba) records encompassing continental shelf, slope and deep-ocean settings. Based on this compilation, average Ba burial rates approximately tripled during the PETM, which may require an additional source of Ba to the ocean. Although the precipitation pathway is not well constrained, dissolved Ba stored in sulfate-depleted pore-waters below methane hydrates could represent an additional source. We speculate the most complete explanation for early warming and rise in Ba supply is that hydrate dissociation acted as a positive feedback and caused the CIE. This could imply hydrates are more temperature-sensitive than previously considered, and may warrant reconsideration of the political assignment of 2 °C warming as a safe future scenario.

Description: It contains three tables that correspond to the supplementary information of the article mentioned above. Tables S3 and S4 can be found within the Supplementary Information document. Table S1 contains high-resolution bulk and benthic carbon and oxygen stable isotope data from ODP Hole 702B across the Middle Eocene Climatic Optimum (40 Ma). Table S2 contains benthic foraminiferal data (relative abundance and ecology index) and accumulation rates from ODP Hole 702B across the Middle Eocene Climatic Optimum (40 Ma). Table S5 contains middle Eocene ODP Hole 702B XRF core scanning data, high-resolution bulk and benthic carbon and oxygen stable isotope data from ODP Site 1263 and age model correlation tie points between drill sites for ODP Sites 1263, 738 and 702B as well tie points for a detailed astronomical age model for ODP Site 1263 (La2010b solution).

Description: This paper introduces an integrated Neogene microfossil biostratigraphic chart developed within post-merger BP for the Gulf of Mexico Basin and is the first published industrial framework "fully-tuned" to orbital periodicities. Astronomical-tuning was accomplished through a 15-year research program on ODP Leg 154 sediments (offshore NE Brazil) with sampling resolution for calcareous nannofossils and planktonic foraminifera about 20 k.y. and 40 k.y. (thousand year), respectively. This framework extends from the Late Oligocene (25.05 Ma) to Recent at an average Chart Horizon resolution for the Neogene of 144 k.y., approximately double that of published Gulf of Mexico biostratigraphic charts and a five-fold increase over the highest resolution global calcareous microfossil biozonation. Such resolution approximates that of 4th to 5th order parasequences and is a critical component in the verification of seismic correlations between mini-basins in the deep-water Gulf of Mexico. Its utility in global time-scale construction and correlation has been proven, in part, by application of the scheme in full to internal research for the Oligocene-Miocene boundary interval on the Global Boundary Stratotype Section and Point (GSSP) in northern Italy and offshore wells in the eastern Mediterranean Sea. This step change in Neogene resolution, now at the level of cyclostratigraphy (the orbital periodicity of eccentricity) and the magnetostratigraphic chron, demonstrates the potential for calcareous microfossil biostratigraphy to more consistently reinforce correlations of these time scale parameters. The integration of microfossil disciplines, consistent taxonomies, and rigorous analytical methodologies are all critical to obtaining and reproducing this new level of biostratigraphic resolution.

Description: The Late Cretaceous-Early Paleogene is the most recent period of Earth history that experienced sustained global greenhouse warmth and was characterised by a dynamic carbon cycle. Yet, knowledge of ambient climate conditions and the evolution of atmospheric pCO2 at this time, along with their relation to forcing mechanisms, are still poorly constrained. Here we present an unprecedented 14.75 million year long high-resolution orbitally-tuned record of paired climate change and carbon-cycling (based on the oxygen and carbon isotope composition of benthic foraminiferal tests) compiled to date for the enigmatic Late Cretaceous to Early Eocene, and compare these records to the most up-to-date compilation of atmospheric pCO2 records for this time. We identify eccentricity as the dominant pacemaker of the observed climate and carbon cycle changes, through the modulation of precession. The carbon cycle (e.g., d13C) lagged changes in climate by ~22,800 years within the long eccentricity (405,000 year) band and ~3,000-4,500 years within the short eccentricity (100,000 year) band, suggesting that light carbon was released as a positive feedback to warming induced by small changes in orbital forcing. The majority of the hyperthermals of this time period occur during maxima in the long eccentricity cycle, with the exception of the Paleocene-Eocene Thermal Maximum and Late Maastrichtian warming event, which are likely to have been triggered by Large Igneous Province volcanism.

Description: Micropaleontological and geochemical analyses reveal distinct millennial-scale increases in carbonate preservation in the deep Southeast Atlantic (Cape Basin) during strong and prolonged Greenland interstadials that are superimposed on long-term (orbital-scale) changes in carbonate burial. These data suggest carbonate oversaturation of the deep Atlantic and a strengthened Atlantic Meridional Overturning Circulation (AMOC) during the most intense Greenland interstadials. However, proxy evidence from outside the Cape Basin indicate that AMOC changes also occurred during weaker and shorter Greenland interstadials. Here we revisit the link between AMOC dynamics and carbonate saturation in the deep Cape Basin over the last 400 kyr (sediment cores TN057-21, TN057-10 and ODP Site 1089) by reconstructing centennial changes in carbonate preservation using mm-scale X-ray fluorescence (XRF) scanning data. We observe close agreement between variations in XRF Ca/Ti, sedimentary carbonate content and foraminiferal shell fragmentation, reflecting a common control primarily through changing deep-water carbonate saturation. We suggest that the high-frequency (sub-orbital) component of the XRF Ca/Ti records indicates the fast and recurrent redistribution of carbonate ions in the Atlantic basin via the AMOC during both long/strong- and short/weak North Atlantic climate anomalies. In contrast, the low-frequency (orbital) XRF Ca/Ti component is interpreted to reflect slow adjustments through carbonate compensation, and/or changes in the deep-ocean respired carbon content. Our findings emphasize the recurrent influence of rapid AMOC variations on the marine carbonate system during past glacial periods, providing a mechanism for transferring the impacts of North Atlantic climate anomalies to the global carbon cycle via the Southern Ocean.