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  • 1
    Publication Date: 2023-08-08
    Description: The unknown cooling-rate history of natural silicate melts can be investigated using differential scanning heat capacity measurements together with the limiting fictive temperature analysis calculation. There are a range of processes occurring during cooling and re-heating of natural samples which influence the calculation of the limiting fictive temperature and, therefore, the calculated cooling-rate of the sample. These processes occur at the extremes of slow cooling and fast quenching. The annealing of a sample at a temperature below the glass transition temperature upon cooling results in the subsequent determination of cooling-rates which are up to orders of magnitude too low. In contrast, the internal stresses associated with the faster cooling of obsidian in air result in an added exothermic signal in the heat capacity trace which results in an overestimation of cooling-rate. To calculate cooling-rate of glass using the fictive temperature method, it is necessary to create a calibration curve determined using known cooling- and heating-rates. The calculated unknown cooling-rate of the sample is affected by the magnitude of mismatch between the original cooling-rate and the laboratory heating-rate when using the matched cooling-/heating-rate method to derive a fictive temperature/cooling-rate calibration curve. Cooling-rates slower than the laboratory heating-rate will be overestimated, while cooling-rates faster than the laboratory heating-rate are underestimated. Each of these sources of error in the calculation of cooling-rate of glass materials—annealing, stress release and matched cooling/heating-rate calibration—can affect the calculated cooling-rate by factor of 10 or more.
    Description: Georg-August-Universität Göttingen (1018)
    Keywords: ddc:550.78 ; Fictive temperature ; Annealing ; Thermal stress ; Cooling-rate ; Calorimetry
    Language: English
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  • 2
    Publication Date: 2023-08-08
    Description: In this study, the influence of CO〈sub〉2〈/sub〉 on the rheology of silica poor and K-rich melts from highly explosive eruptions from the Colli Albani Volcanic District (Italy) (CAVD) is measured for the first time. The investigated melts range from foidite to tephri-phonolite to tephrite from the CAVD to a phonolite from the Vesuvius (Italy) with CO〈sub〉2〈/sub〉 concentrations up to 0.50 wt%. Viscosity and calorimetric measurements are performed in the glass transition range Tg between 600 and 780 °C. Although nominally anhydrous, the investigated melts contain H〈sub〉2〈/sub〉O concentrations up to 0.23 wt%. The data exhibit a decrease in viscosity of approx. 100.40 Pa s for the phonolitic composition with ~ 0.07 wt% CO〈sub〉2〈/sub〉 and a Tg reduced by approx. 14 °C. For the tephritic composition, Tg is approx. 5 °C lower and has a viscosity reduced by 100.25 Pa s for the sample containing ~ 0.5 wt% CO〈sub〉2〈/sub〉. Calorimetric measurements of the tephri-phonolite show lowered onset of Tg by approx. 6 °C for the melt with ~ 0.11 wt% CO2 and Tg of the foidite appears not to be influenced by a CO〈sub〉2〈/sub〉 concentration of ~ 0.37 wt% CO〈sub〉2〈/sub〉. However, these tephri-phonolitic and foiditic melts foamed during calorimetric measurements preventing a reliable measurement. It would appear that most of this overall drop in viscosity is caused by the small amounts of H〈sub〉2〈/sub〉O in the melts with CO〈sub〉2〈/sub〉 slightly reducing the viscosity or having no effect on viscosity. Additionally, it is shown that the reduction in viscosity decreases with an increasing degree of the depolymerisation for the investigated melts. Consequently, the explosive style of the CAVD eruptions is mainly caused by crystals and bubbles which form and rise during magma storage and ascent which increases the magma viscosity whereas the CO〈sub〉2〈/sub〉 in the melt slightly reduces the viscosity.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Georg-August-Universität Göttingen (1018)
    Keywords: ddc:550.78 ; Viscosity ; Calorimetry ; Colli Albani ; Carbon dioxide ; Glass transition ; Foidite
    Language: English
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  • 3
    Publication Date: 2023-08-08
    Description: Equilibria between Ti oxides and silicate melt lead to Ti isotope fractionation in terrestrial samples, with isotopically light Ti oxides and isotopically heavy coexisting melt. However, while Ti is mostly tetravalent in terrestrial samples, around 10% of the overall Ti is trivalent at f〈sub〉O2〈/sub〉 relevant to lunar magmatism (~ IW-1). The different valences of Ti in lunar samples, could additionally influence Ti stable isotope fractionation during petrogenesis of lunar basalts to an unknown extent. We performed an experimental approach using gas mixing furnaces to investigate the effect of Ti oxide formation at different f〈sub〉O2〈/sub〉 on Ti stable isotope fractionation during mare basalt petrogenesis. Two identical bulk compositions were equilibrated simultaneously during each experiment to guarantee comparability. One experiment was investigated with the EPMA to characterize the petrology of experimental run products, whereas the second experiment was crushed, and fabricated phases (i.e., oxides, silicates and glass) were handpicked, separated and digested. An aliquot of each sample was mixed with a Ti double-spike, before Ti was separated from matrix and interfering elements using a modified HFSE chemistry. Our study shows f〈sub〉O2〈/sub〉-dependent fractionation within seven samples from air to IW-1, especially ∆49Ti〈subs〈armalcolite〈/sub〉-melt and ∆49Ti〈sub〉armalcolite-orthopyroxene〈/sub〉 become more fractionated from oxidized to reduced conditions (− 0.092 ± 0.028-  − 0.200 ± 0.033 ‰ and  − 0.089 ± 0.027- − 0.250 ± 0.049 ‰, respectively), whereas ∆49Ti〈sub〉orthopyroxene〈/sub〉-melt shows only a minor fractionation (− 0.002 ± 0.017-0.050 ± 0.025 ‰). The results of this study show that Ti isotope fractionation during mare basalt petrogenesis is expected to be redox dependent and mineral-melt fractionation as commonly determined for terrestrial fO2 may not be directly applied to a lunar setting. This is important for the evaluation of Ti isotope fractionation resulting from lunar magmatism, which takes place under more reducing conditions compared to the more oxidized terrestrial magmatism.
    Description: Deutsche Forschungsgemeinschaft
    Description: Projekt DEAL
    Keywords: ddc:550.78 ; Titanium isotopes ; Lunar magma ocean ; Fractionation ; Experiments ; Ti oxides ; Armalcolite
    Language: English
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  • 4
    Publication Date: 2023-08-08
    Description: Aquifer storage and recovery systems using multiple partially penetrating wells (MPPW-ASR) can form a viable solution to the problem of freshwater buoyancy when using brackish aquifers for freshwater storage. This study presents the result of a series of laboratory experiments that aimed at visualizing the shape of freshwater bodies injected into a brackish aquifer and determining the effect on the recovery efficiency (RE) of several MPPW-ASR operational variables. A model aquifer was built in a Plexiglas tank using glass beads and water was injected and abstracted through point and vertical wells, which were operated in various combinations. Numerical models were used to support the interpretation of the time-lapse photographs, and showed that three-dimensional flow effects had to be considered for a correct interpretation of the visible dye patterns. Upward migration of both fresh (during injection) and brackish water (during recovery) along the vertical wells was observed, indicating that the role of well infrastructure as conduits is a critical design criterion for real-world systems. Gravitational instabilities formed when freshwater did not extend all the way to the top of the aquifer, and this negatively impacted the RE by causing greater mixing. The positive freshwater buoyancy led to freshwater bodies that became narrower with depth, and the formation of thin, elongated buffer zones along the aquifer top in multicycle experiments. Up-coning below abstraction wells resulted in lower RE values, reinforcing the potential of scavenger wells to enhance MPPW-ASR system performance.
    Description: Bundesanstalt für Geowissenschaften und Rohstoffe (BGR) (4230)
    Keywords: ddc:550.78 ; Artificial recharge ; Laboratory experiments/measurements ; Numerical modelling ; Multiple partially penetrating wells ; Salt-water/fresh-water relations
    Language: English
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  • 5
    Publication Date: 2023-08-08
    Description: The partitioning of a large suite of trace elements between biotite and water-saturated granitic melt was measured at 2 kbar and 700—800 ˚C. To reach equilibrium and to grow biotite crystals large enough for analysis, runs usually lasted from 30 to 45 days. In every charge, a few trace elements were initially doped at the 0.1—0.5 wt. % level and analyzed by electron microprobe after the run. First-row transition metal ions are highly compatible in biotite with D〈sup〉biotite/melt〈/sup〉 of 17 for Ti, 35 for V, 47 for Co, 174 for Ni, and 5.8 for Zn. A very notable exception is Cu with D〈sup〉biotite/melt〈/sup〉 〈 0.9. This is likely one of the reasons why Cu is enriched together with Mo (D〈sup〉biotite/melt〈/sup〉 = 0.29) in porphyry deposits associated with intermediate to felsic plutons, while the other transition metals are not. Both Nb and Ta are mildly compatible in biotite with D〈sup〉biotite/melt〈/sup〉 being larger for Nb (3.69) than for Ta (1.89). Moderate (15—30%) biotite fractionation would be sufficient to reduce the Nb/Ta ratio from the chondritic value to the range observed in the continental crust. Moreover, the strong partitioning of Ti into biotite implies that already modest biotite fractionation suppresses the saturation of Ti-oxide phases and thereby indirectly facilitates the enrichment of Ta over Nb in the residual melt. The heavy alkalis, alkaline earths, and Pb are only mildly fractionated between biotite and melt (D〈sup〉biotite/melt〈/sup〉 = 3.8 for Rb, 0.6 for Cs, 0.6 for Sr, 1.8 for Ba, 0.7 for Pb). The rare earth elements are generally incompatible in biotite, with a minimum for Dbiotite/melt of 0.03–0.06 at Gd, Tb, and Dy, while both the light and heavy rare earths are less incompatible (e.g. D〈sup〉biotite/melt〈/sup〉 = 0.6 for La and 0.3 for Yb). This behavior probably reflects a partitioning into two sites, the K site for the light rare earths and the octahedral Mg site for the heavy rare earths. There is no obvious dependence of the rare earth partition coefficients on tetrahedral Al in the biotite, presumably because charge balancing by cation vacancies is possible. Allanite was found as run product in some experiments. For the light rare earths, D〈sup〉allanite/melt〈/sup〉 is very high (e.g. 385 to 963 for Ce and Nd) and appears to increase with decreasing temperatures. However, the rather high solubility of allanite in the melts implies that it likely only crystallizes during the last stages of cooling of most magmas, except if the source magma is unusually enriched in rare earths.
    Description: Deutsche Forschungsgemeinschaft
    Description: Universität Bayreuth (3145)
    Keywords: ddc:550.78 ; Biotite ; Allanite ; Granite ; Partitioning ; Solubility ; Rare earths ; Niobium ; Tantalum ; Nb/Ta ratio ; Porphyry copper deposits
    Language: English
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  • 6
    Publication Date: 2023-07-29
    Description: It is commonly assumed that dry and saturated sands exhibit similar cone resistance–relative density relationships. Some studies pointed out that partial saturation and calcareous sands with considerable fines content are potential factors affecting these relationships. However, there is experimental evidence in Shaqour Bull Eng Geol Environ 66:59-70, (2006) that clean uncemented quartz sand may exhibit lower cone resistance in saturated conditions. The present study aims on contributing towards better understanding the effect of water saturation on cone resistance in sand. For this purpose, Ticino sand samples were prepared dry and saturated in a calibration chamber and cone penetration tests were performed over a wide range of relative densities and at two consolidation stresses. Overall, it was observed that dry and saturated samples exhibited similar cone resistances. Only slightly higher cone resistances were observed for dry samples at the lower consolidation stress. Two anomalous samples, which were tested dry at medium relative density, were found to exhibit way higher cone resistances than expected from published cone resistance–relative density relationships. The Young's modulus was observed to be proportional to cone resistance and independent of whether a sample was tested dry or saturated, being therefore considered as more robust soil property for cone resistance relationships.
    Description: Bundesministerium für Wirtschaft und Energie http://dx.doi.org/10.13039/501100006360
    Keywords: ddc:550.78 ; Cone penetration test ; Water saturation ; Dry sand ; Calibration chamber ; Relative density ; Young’s modulus
    Language: English
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  • 7
    Publication Date: 2023-08-02
    Description: Predicting the onset, style and duration of explosive volcanic eruptions remains a great challenge. While the fundamental underlying processes are thought to be known, a clear correlation between eruptive features observable above Earth’s surface and conditions and properties in the immediate subsurface is far from complete. Furthermore, the highly dynamic nature and inaccessibility of explosive events means that progress in the field investigation of such events remains slow. Scaled experimental investigations represent an opportunity to study individual volcanic processes separately and, despite their highly dynamic nature, to quantify them systematically. Here, impulsively generated vertical gas-particle jets were generated using rapid decompression shock-tube experiments. The angular deviation from the vertical, defined as the “spreading angle”, has been quantified for gas and particles on both sides of the jets at different time steps using high-speed video analysis. The experimental variables investigated are 1) vent geometry, 2) tube length, 3) particle load, 4) particle size, and 5) temperature. Immediately prior to the first above-vent observations, gas expansion accommodates the initial gas overpressure. All experimental jets inevitably start with a particle-free gas phase (gas-only), which is typically clearly visible due to expansion-induced cooling and condensation. We record that the gas spreading angle is directly influenced by 1) vent geometry and 2) the duration of the initial gas-only phase. After some delay, whose length depends on the experimental conditions, the jet incorporates particles becoming a gas-particle jet. Below we quantify how our experimental conditions affect the temporal evolution of these two phases (gas-only and gas-particle) of each jet. As expected, the gas spreading angle is always at least as large as the particle spreading angle. The latter is positively correlated with particle load and negatively correlated with particle size. Such empirical experimentally derived relationships between the observable features of the gas-particle jets and known initial conditions can serve as input for the parameterisation of equivalent observations at active volcanoes, alleviating the circumstances where an a priori knowledge of magma textures and ascent rate, temperature and gas overpressure and/or the geometry of the shallow plumbing system is typically chronically lacking. The generation of experimental parameterisations raises the possibility that detailed field investigations on gas-particle jets at frequently erupting volcanoes might be used for elucidating subsurface parameters and their temporal variability, with all the implications that may have for better defining hazard assessment.
    Description: Seventh Framework Programme http://dx.doi.org/10.13039/501100004963
    Description: Deutsche Forschungsgemeinschaft
    Description: European Research Council http://dx.doi.org/10.13039/501100000781
    Description: https://doi.org/10.5880/fidgeo.2020.030
    Keywords: ddc:550.78 ; Explosive volcanism, ; Experimental volcanology, ; Spreading angle, ; Shock-tube
    Language: English
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  • 8
    Publication Date: 2023-11-13
    Description: The aim of this work is to provide a complete data set of direct shear tests and to propose a corresponding simulation approach. Tests have been conducted on crystalline rock samples applying constant normal load (CNL) and constant normal stiffness (CNS) boundary conditions. A physical consistent algorithm which explicitly calculates the forces acting on the fracture surface (FFS) has been developed. This FFS approach can explain the occurrence of surface degradation and shows the main shear characteristics. After all, shearing of rough rock joints remains a complex process and the differences between laboratory and simulation results are still significant in some cases. All data and input files are provided free for download and testing.
    Description: Bundesministerium für Bildung und Forschung http://dx.doi.org/10.13039/501100002347
    Description: Technische Universität Bergakademie Freiberg (3135)
    Description: http://www.ufz.de/record/dmp/archive/7925
    Description: http://www.ufz.de/record/dmp/archive/7924
    Description: https://github.com/Poetschke/Ecodist
    Keywords: ddc:550.78 ; GeomInt project ; Direct shear test ; Rock surface scanning ; Rock joint ; Joint constitutive model
    Language: English
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  • 9
    Publication Date: 2023-11-15
    Description: Silicate liquid immiscibility leading to formation of mixtures of distinct iron-rich and silica-rich liquids is common in basaltic and andesitic magmas at advanced stages of magma evolution. Experimental modeling of the immiscibility has been hampered by kinetic problems and attainment of chemical equilibrium between immiscible liquids in some experimental studies has been questioned. On the basis of symmetric regular solutions model and regression analysis of experimental data on compositions of immiscible liquid pairs, we show that liquid–liquid distribution of network-modifying elements K and Fe is linked to the distribution of network-forming oxides SiO2, Al2O3 and P2O5. We use the responding equation for testing chemical equilibrium in experiments not included in the regression analysis and compositions of natural immiscible melts found as glasses in volcanic rocks. Departures from equilibrium that the test revealed in crystal-rich multiphase experimental products and in natural volcanic rocks imply kinetic competition between liquid–liquid and crystal–liquid element partitioning. Immiscible liquid droplets in volcanic rocks appear to evolve along a metastable trend due to rapid crystallization. Immiscible liquids may be closer to chemical equilibrium in large intrusions where cooling rates are lower and crystals may be spatially separated from liquids.
    Description: DeutscheForschungsGemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: Russian Science Foundation http://dx.doi.org/10.13039/501100006769
    Description: Helmholtz-Zentrum Potsdam Deutsches GeoForschungsZentrum - GFZ (4217)
    Keywords: ddc:550.78 ; Experimental petrology ; Igneous rocks ; Silicate melts ; Liquid–liquid element distribution ; Symmetric regular solutions
    Language: English
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  • 10
    Publication Date: 2023-11-16
    Description: This research work presents an experimental and numerical study of the coupled thermo-hydro-mechanical (THM) processes that occur during soil freezing. With focusing on the artificial ground freezing (AGF) technology, a new testing device is built, which considers a variety of AGF-related boundary conditions and different freezing directions. In the conducted experiments, a distinction is made between two thermal states: (1) The thermal transient state, which is associated with ice penetration, small deformations, and insignificant water suction. (2) The thermal (quasi-) steady state, which has a much longer duration and is associated with significant ice lens formation due to water suction. In the numerical modeling, a special focus is laid on the processes that occur during the thermal transient state. Besides, a demonstration of the micro-cryo-suction mechanism and its realization in the continuum model through a phenomenological retention-curve-like formulation is presented. This allows modeling the ice lens formation and the stiffness degradation observed in the experiments. Assuming a fully saturated soil as a biphasic porous material, a phase-change THM approach is applied in the numerical modeling. The governing equations are based on the continuum mechanical theory of porous media (TPM) extended by the phase-field modeling (PFM) approach. The model proceeds from a small-strain assumption, whereas the pore fluid can be found in liquid water or solid ice state with a unified kinematics treatment of both states. Comparisons with the experimental data demonstrate the ability and usefulness of the considered model in describing the freezing of saturated soils.
    Description: Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659
    Description: RWTH Aachen (3131)
    Keywords: ddc:550.78 ; Experimental study ; Frost heave ; Ice lens formation ; Phase-field modeling ; Soil freezing ; Thermo-hydro-mechanical coupling
    Language: English
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  • 11
    Publication Date: 2023-09-14
    Description: Discrete randomly distributed fibers are commonly used to improve the engineering characteristics of the soil and thus soil properties such as shear strength, compressibility, density, and hydraulic conductivity. Most studies have so far focused on describing the behavior of soils containing randomly distributed fibers under dried or saturated conditions. However, the water table may seasonally fluctuate, thus generating unsaturated soil conditions. Therefore, a better understanding of the hydro-mechanical properties of unsaturated improved soils is of high necessity. In this research, the shear strength parameters of fine-grained soils were evaluated using the biaxial device available at Ruhr Universität Bochum. The applied device was modified to test unsaturated fine-grained soils with various degrees of saturation using axis translation and vapor equilibrium techniques. The experiments were conducted on fine soils containing 0, 0.5, and 1% fiber contents under a wide range of matric suctions. The ductile behavior was more noticeable in samples with lower suctions and higher straw contents. Furthermore, the shear strength of both unreinforced and reinforced fine-grained soils considerably increased by an increase in the suction. Finally, shear band inclination increased by the suction while decreasing by straw content.
    Description: Ruhr-Universität Bochum (1007)
    Keywords: ddc:550.78 ; Plane strain condition ; Shear strength ; Soil reinforcement ; Suction ; SWCC
    Language: English
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  • 12
    Publication Date: 2023-12-19
    Description: The paper presents an experimental study on the effect of plastic fines content on the undrained behavior and liquefaction susceptibility of sand–fines mixtures under monotonic loading. The results of undrained monotonic triaxial compression tests conducted on mixtures of Hostun sand with varying amount (0–20%) and type (kaolin and calcigel bentonite) of plastic fines are presented. The specimens were prepared with different initial densities using the moist tamping method and consolidated at two different isotropic effective stresses. The results demonstrate that for both types of plastic fines, an increase in the fines content leads to a more contractive response and lower values of mobilized deviatoric stress. Despite similar relative density and fines content, the sand–kaolin mixtures showed a more contractive behavior than the sand–calcigel specimens. The steady-state lines (SSLs) in e–p´ space generally move downwards with increasing clay content. While the slopes of the SSLs for the clean Hostun sand and the mixtures with 10 and 20% kaolin are quite similar, the SSL lines for the specimens containing 10% or 20% calcigel run steeper or flatter, respectively. The inclination of the SSL in the q–p′ plane was found independent of clay type and content. The sand–kaolin mixtures were observed to be more susceptible to instability and flow liquefaction than the sand–calcigel mixtures.
    Keywords: ddc:550.78 ; Instability line ; Plastic fines content ; Sand–fines mixtures ; Steady-state line ; Undrained monotonic triaxial tests
    Language: English
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  • 13
    Publication Date: 2023-06-23
    Description: Many explosive volcanic eruptions produce underexpanded starting gas-particle jets. The dynamics of the accompanying pyroclast ejection can be affected by several parameters, including magma texture, gas overpressure, erupted volume and geometry. With respect to the latter, volcanic craters and vents are often highly asymmetrical. Here, we experimentally evaluate the effect of vent asymmetry on gas expansion behaviour and gas jet dynamics directly above the vent. The vent geometries chosen for this study are based on field observations. The novel element of the vent geometry investigated herein is an inclined exit plane (5, 15, 30° slant angle) in combination with cylindrical and diverging inner geometries. In a vertical setup, these modifications yield both laterally variable spreading angles as well as a diversion of the jets, where inner geometry (cylindrical/diverging) controls the direction of the inclination. Both the spreading angle and the inclination of the jet are highly sensitive to reservoir (conduit) pressure and slant angle. Increasing starting reservoir pressure and slant angle yield (1) a maximum spreading angle (up to 62°) and (2) a maximum jet inclination for cylindrical vents (up to 13°). Our experiments thus constrain geometric contributions to the mechanisms controlling eruption jet dynamics with implications for the generation of asymmetrical distributions of proximal hazards around volcanic vents.
    Description: European Research Council http://dx.doi.org/10.13039/501100000781
    Keywords: ddc:550.78 ; Explosive eruptions ; Crater asymmetry ; Vent asymmetry ; Gas jets ; Inclined jets ; Tilted eruptions
    Language: English
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  • 14
    Publication Date: 2023-06-23
    Description: The ascent of hydrous magma prior to volcanic eruptions is largely driven by the formation of H2O vesicles and their subsequent growth upon further decompression. Porosity controls buoyancy as well as vesicle coalescence and percolation, and is important when identifying the differences between equilibrium or disequilibrium degassing from textural analysis of eruptive products. Decompression experiments are routinely used to simulate magma ascent. Samples exposed to high temperature (T) and pressure (P) are decompressed and rapidly cooled to ambient T for analysis. During cooling, fluid vesicles may shrink due to decrease of the molar volume of H2O and by resorption of H2O back into the melt driven by solubility increase with decreasing T at P 〈 300 MPa. Here, we quantify the extent to which vesicles shrink during cooling, using a series of decompression experiments with hydrous phonolitic melt (5.3–3.3 wt% H2O, T between 1323 and 1373 K, decompressed from 200 to 110–20 MPa). Most samples degassed at near-equilibrium conditions during decompression. However, the porosities of quenched samples are significantly lower than expected equilibrium porosities prior to cooling. At a cooling rate of 44 K·s−1, the fictive temperature Tf, where vesicle shrinkage stops, is up to 200 K above the glass transition temperature (Tg), Furthermore, decreasing cooling rate enhances vesicles shrinkage. We assess the implications of these findings on previous experimental degassing studies using phonolitic melt, and highlight the importance of correctly interpreting experimental porosity data, before any comparison to natural volcanic ejecta can be attempted.
    Description: German Science Foundation
    Keywords: ddc:550.78 ; Decompression experiments ; Vesiculation ; Vesicle shrinkage ; Quench effect ; H2O resorption ; Fictive temperature
    Language: English
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  • 15
    Publication Date: 2023-06-23
    Description: Supersaturation of H2O during magma ascent leads to degassing of melt by formation and growth of vesicles that may power explosive volcanic eruptions. Here, we present experiments to study the effect of initially dissolved H2O concentration (cH2Oini) on vesicle formation, growth, and coalescence in phonolitic melt. Vesuvius phonolitic melts with cH2Oini ranging between 3.3 and 6.3 wt% were decompressed at rates of 1.7 and 0.17 MPa·s−1 and at temperatures ≥ 1323 K. Decompression started from 270 and 200 MPa to final pressures of 150–20 MPa, where samples were quenched isobarically. Optical microscopy and Raman spectroscopic measurements confirm that the glasses obtained were free of microcrystals and Fe-oxide nanolites, implying that the experiments were superliquidus and phase separation of the hydrous melt was homogeneous. A minimum number of the initially formed vesicles, defined by the number density normalized to vesicle-free glass volume (VND), is observed at ~ 5 wt% cH2Oini with a logVND of ~ 5 (in mm−3). The logVND increases strongly towards lower and higher cH2Oini by one order of magnitude. Furthermore, an important transition in evolution of vesiculation occurs at ~ 5.6 wt% cH2Oini. At lower cH2Oini, the initial VND is preserved during further decompression up to melt porosities of 30–50%. At higher cH2Oini, the initial vesicle population is erased at low melt porosities of 15–21% during further decompression. This observation is attributed to vesicle coalescence favored by low melt viscosity. In conclusion, cH2Oini determines the VND of initial phase separation and the evolution of vesiculation during decompression that controls the style of volcanic eruptions.
    Description: German Science Foundation
    Keywords: ddc:550.78 ; Vesicle number density ; Phonolitic melt ; Spinodal decomposition ; Melt degassing ; H2O concentration ; Fe-oxide nanolites
    Language: English
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