ALBERT

Description: Santorini, Greece is a major explosive volcano. The Santorini volcanic complex is composed of two active volcanoes—Nea Kameni and Mt. Columbo. Holocene eruptions have generated a variety of processes and deposits and eruption mechanisms pose significant hazards of various types. It has been recognized that, for major European volcanoes, few studies have focused on the social aspects of volcanic activity and little work has been conducted on public perceptions of hazard, risk and vulnerability. Such assessments are an important element of establishing public education programmes and developing volcano disaster management plans. We investigate perceptions of volcanic hazards on Santorini. We find that most residents know that Nea Kameni is active, but only 60% know that Mt. Columbo is active. Forty percent of residents fear that negative impacts on tourism will have the greatest effect on their community. In the event of an eruption, 43% of residents would try to evacuate the island by plane/ferry. Residents aged N50 have retained a memory of the effects of the last eruption at the island, whereas younger residents have no such knowledge. We find that dignitaries and municipal officers (those responsible for planning and managing disaster response) are informed about the history, hazards and effects of the volcanoes. However, there is no bemergency planQ for the island and there is confusion between various departments (Civil Defense, Fire, Police, etc.) about the emergency decision-making process. The resident population of Santorini is at high risk from the hazards associated with a future eruption.

Description: Late glacial to post glacial sea-level changes provide direct evidence of the progress of melting of large ice sheets during the last deglaciation but, although the correlation between ice and ocean volumes is incontrovertible, the causal link is commonly obscured. Local effects including tectonics, isostatic and hydroisostatic responses and equatorial ocean-syphoning impose additional signals that hide the true picture. A detailed regional study of the Western Indian Ocean based on the analysis of drill cores carried out through modern reefs, in combination with observations and sampling of reef foreslopes, and investigations of outcrops provides a comprehensive data base. Sites from a range of tectonic settings include the microcontinental margins of Madagascar, the granitic Seychelles, and the isolated volcanic islands of Réunion, Mauritius and the Comoros in which the effects of subsidence can be shown to be small. These cover a range of latitudes, and comparisons with adjacent sites on continental margins allow the construction of sea-level curves that closely reflect the eustatic response and disengage this from the effects of other mechanisms. The Mayotte foreslope in the Comoro Islands provides the first coral reef record of sea-level change during the early deglaciation in the Indian Ocean (110–115 m below present sea level between 18,000 and 17,000 yr BP). Two distinctive reef terraces, at 90 and 60 m water depth are dated at 13,600 yr BP and partly attributed to the Younger Dryas period (12,700–11,600 cal yr BP). Reef drowning at around 13,500 yr BP may correspond to Meltwater Pulse 1A, and although there were surges in the rate of sea-level rise, most notably between 11,950 and 11,350 yr BP, there is little evidence to support a well-defined Meltwater Pulse 1B. Reconstructed Holocene sea-level curves are in good agreement and reflect a rapid sea-level rise of about 6 mm yr−1 between 10,000 and 7500 yr BP, followed by a clear inflection around 7500 yr BP when the rate fell to 1.1 mm yr−1. Modern reefs started to grow 8000–9000 years ago. In the post-glacial period the rate of sea-level rise was 1–1.5 mm yr−1 before stabilization at its present level 3000–2500 years ago. Curves for the 10,000–6000 yr−1 BP interval correspond closely with those predicted by theoretical models but lie below these in the subsequent period. In particular, and with the exception of the margins of the Madagascar microcontinent influenced by hydroisostatic processes, they do not reflect predicted higher sea-level stands during the late Holocene.

Description: New data obtained during re-mapping of the northern part of Syros (Cyclades, Greece) allow the refinement of existing concepts about the structural evolution of this island. A metabasite belt and its metasedimentary envelope near Kampos and San Michali were mapped at a 1:5000 scale, with special emphasis on the structural inventory. The HP/LT rocks (P , 1.5 GPa; T , 500 8C at ,50 Ma) exposed are intensely deformed by at least two isoclinal folding events. Relative age relations between deformation and peak metamorphism indicate that isoclinal folding took place before or during peak metamorphism. Later deformation stages include Miocene non-penetrative upright kink folding and crenulation, transpressional strike-slip faulting, and open upright cylindrical folding, followed by the development of steep normal faults. Taking into account recent zircon U–Pb geochronological constraints, lithostratigraphic observations, and published data on the Neogene structural evolution of the Aegean, we present a history for the rocks of Syros, beginning with the formation of the oceanic crust(represented by the metabasites) to the present.

Description: Carbonate precipitates on mounds and along tectonic scarps off the Costa Rica margin are manifestations of subduction-induced dewatering. The long-term dewatering history is recorded in mineralogical, petrological and isotope signals of carbonates recovered from these sites. The carbonates are strongly depleted in δ13C (−11 to −53‰ PDB) and enriched in δ18O (+4 to +8‰ PDB). Thermogenic methane and biogenic methane were identified as sources of the carbon. Chemoherm carbonates and seepage-associated carbonates formed in a focused flow regime have lighter δ13C values, while others formed in a more diffusive flow regime have slightly enriched C isotope values. Three fluid components were inferred based on the calculation of equilibrium δ18O: clay dehydration water, gas hydrate water and seawater. Calculated equilibrium δ18O values of carbonates from different down-core depths as well as from different precipitation stages show that the δ18O of the precipitating fluid is progressively depleted with time. Dolostones showing a methane-C source and a well constrained O-isotope signature are thought to have formed at depth in the sediment and subsequently became exhumed. Glauconitic sandstones cemented by methane-derived carbonate provide evidence that fluid and solid material have been expelled by the mud volcano.

Description: Measurements of δ18O and δ13C isotopes in three benthic foraminiferal species from surface sediments of the eastern Laptev Sea are compared to water δ18O values and δ13C values of dissolved inorganic carbon (DIC). Samples investigated originate from two environmentally contrasting core locations, which are influenced by riverine freshwater runoff to a varying degree. At the river-distal site, located within relatively stable marine conditions on the outer shelf, Elphidiella groenlandica, Haynesina orbiculare and Elphidium excavatum forma clavata show a positive specific offset of 1.4‰, 1.5‰ and 1‰, respectively, in their δ18O values relative to the expected value for inorganic calcite precipitated under equilibrium conditions. At the site close to the Lena River confluence, with enhanced seasonal hydrographic contrasts, calculated δ18O offsets in E. groenlandica and in H. orbiculare remain about the same whereas E. e. clavata displays a distinctly negative offset of −1.8‰. The δ18O variation in E. e. clavata is interpreted as a vital effect, a finding which limits the potential of this species for reconstructing freshwater-influenced shelf paleoenvironments on the basis of oxygen isotopes. This interpretation gains support when comparing foraminiferal δ13C with the δ13CDIC of the water. While some of the difference in the carbonate δ13C seems to be controlled by a riverine-related admixture of DIC, clearly defined δ13C ranges in each of the three foraminifera at the river-proximal site shows that also the carbon isotopic signature in E. e. clavata is particularly affected by environmental factors.

Description: Extensive methane hydrate layers are formed in the near-surface sediments of the Cascadia margin. An undissociated section of such a layer was recovered at the base of a gravity core (i.e. at a sediment depth of 120 cm) at the southern summit of Hydrate Ridge. As a result of salt exclusion during methane hydrate formation, the associated pore waters show a highly elevated chloride concentration of 809 mM. In comparison, the average background value is 543 mM. A simple transport-reaction model was developed to reproduce the Cl- observations and quantify processes such as hydrate formation, methane demand, and fluid flow. From this first field observation of a positive Cl- anomaly, high hydrate formation rates (0.15–1.08 mol cm-2 a-1) were calculated. Our model results also suggest that the fluid flow rate at the Cascadia accretionary margin is constrained to 45–300 cm a-1. The amount of methane needed to build up enough methane hydrate to produce the observed chloride enrichment exceeds the methane solubility in pore water. Thus, most of the gas hydrate was most likely formed from ascending methane gas bubbles rather than solely from CH4 dissolved in the pore water.

Description: A composite record (LO09-14) of three sediment cores from the subpolar North Atlantic (Reykjanes Ridge) was investigated in order to assess surface ocean variability during the last 11 kyr. The core site is today partly under the influence of the Irminger Current (IC), a branch of the North Atlantic Drift continuing northwestward around Iceland. However, it is also proximal to the Sub-Arctic Front (SAF) that may cause extra dynamic hydrographic conditions. We used statistical methods applied to the fossil assemblages of diatoms to reconstruct quantitative sea surface temperatures (SSTs). Our investigations give evidence for different regional signatures of Holocene surface oceanographic changes in the North Atlantic. Core LO09-14 reveal relatively low and highly variable SSTs during the early Holocene, indicating a weak IC and increased advection of subpolar water over the site. A mid-Holocene thermal optimum with a strong IC occurs from 7.5 to 5 kyr and is followed by cooler and more stable late Holocene surface conditions. Several intervals throughout the Holocene are dominated by the diatom species Rhizosolenia borealis, which we suggest indicates proximity to a strongly defined convergence front, most likely the SAF. Several coolings, reflecting southeastward advection of cold and ice-bearing waters, occur at 10.4, 9.8, 8.3, 7.9, 6.4, 4.7, 4.3 and 2.8 kyr. The cooling events recorded in the LO09-14 SSTs correlate well with both other surface records from the area and the NADW reductions observed at ODP Site 980 indicating a surface-deepwater linkage through the Holocene.

Description: Variability in the chemical composition, textures and electrical properties of the major sulphide mineral pyrite may be one cause of variation in the flotation and leaching properties of different sulphide ores. This report summarises the results of a review that has been conducted to establish the range in variability of natural pyrite with regard to chemical composition, texture and electrical properties. The S/Fe ratio in pyrite is generally very close to 2, suggesting that stoichiometric variability is small in this mineral. However, minor deviations from the ideal are reported. Pyrite typically contains a host of minor and trace elements, including: Ag, As, Au, Bi, Cd, Co, Cu, Hg, Mo, Ni, Pb, Pd, Ru, Sb, Se, Sb, Sn, Te, Tl and Zn. Minor elements are often present within the mineral lattice at levels up to several percent, these include; As, Co, Ni, Sb and possibly Cu, Ag, Au and Sn. Arsenian pyrites may contain up to 10% As, and such specimens are typically rich in other minor and trace elements, particularly Au. As-rich pyrites typically appear to have formed at relatively low temperatures and often exhibit habits that suggest rapid precipitation; these As-rich pyrites may be metastable and, therefore, relatively reactive. Considerable variation has been reported in the semiconducting properties of pyrite. Natural pyrites are either n- or p-type semiconductors and reported conductivities vary by four orders of magnitude. The rates of galvanic processes in mineral pulps are likely to vary with the mineral conductivities. Typically p-type pyrites exhibit low conductivities and are As-rich and are suggested to have formed at relatively low temperature, whereas relatively highly conducting n-type pyrites are typically As-poor and suggested to have formed at high temperature. Based on comparative measurements of rest potential, iron pyrite is the most electrochemically inert of the common sulphide minerals, with a rest potential of the order of 0.6 (cf. sphalerite and galena with rest potentials of 0.46 and 0.40 V. vs. SHE, respectively). Variability in the rest potential of different samples of this mineral are generally small. However, based on the extent of pyrite reaction during a peroxide dissolution procedure, the chemical reactivity of pyrite samples may differ significantly.

Description: A continuous lacustrine sequence from the western part of Lama Lake (69°32′N, 90°12′E), complemented by a peat sequence from the lake catchment provides the first detailed environmental reconstruction for the Late Glacial and Holocene on the Taymyr Peninsula. Scarce steppe-like communities with Artemisia, Poaceae, and Cyperaceae dominated during the Late Glacial. Tundra-like communities with Betula nana, Dryas, and Salix grew on more mesic sites. There are distinct climatic signals, which may be correlated with the Bølling and Allerød warming and Middle and Younger Dryas cooling. The Late Glacial/Preboreal transition, at about 10,000 14C yr BP, was characterized by changes from predominantly open herb communities to shrub tundra ones. Larch forest might have been established as early as 9700–9600 14C yr BP, whilst shrub alder came to the area ca 9500–9400 14C yr BP, and spruce did not reach area before ca 9200 14C yr BP. Spruce-larch forests with shrub alder and tree birch dominated the vegetation around the Lama Lake from ca 9000 14C yr BP. Dwarf birch communities were also broadly distributed. The role of spruce in the forest gradually decreased after 4500 14C yr BP. The vegetation cover in the Lama Lake area became similar to the modern larch-spruce forest ca 2500 14C yr BP. A pollen-based biome reconstruction supports a quantitative interpretation of the pollen spectra. Climate reconstructions obtained with information-statistical and plan-functional-type methods show very similar trends in reconstructed July temperature since ca 12,300 14C yr BP, while precipitation anomalies are less coherent, especially during the Late Glacial–Holocene transition.

Description: Radiocarbon-dated pollen, rhizopod, chironomid and total organic carbon (TOC) records from Nikolay Lake (73°20′N, 124°12′E) and a pollen record from a nearby peat sequence are used for a detailed environmental reconstruction of the Holocene in the Lena Delta area. Shrubby Alnus fruticosa and Betula exilis tundra existed during 10,300–4800 cal. yr BP and gradually disappeared after that time. Climate reconstructions based on the pollen and chironomid records suggest that the climate during ca. 10,300–9200 cal. yr BP was up to 2–3 °C warmer than the present day. Pollen-based reconstructions show that the climate was relatively warm during 9200–6000 cal. yr BP and rather unstable between ca. 5800–3700 cal. yr BP. Both the qualitative interpretation of pollen data and the results of quantitative reconstruction indicate that climate and vegetation became similar to modern-day conditions after ca. 3600 cal. yr BP. The chironomid-based temperature reconstruction suggests a relatively warm period between ca. 2300 and 1400 cal. yr BP, which corresponds to the slightly warmer climate conditions reconstructed from the pollen. Modern chironomid and rhizopod assemblages were established after ca. 1400 cal. yr BP.

Description: Review is given about the main results of the oceanographic component of the BALTEX research programme (one of the six continental scale experiments within GEWEX-WCRP to study water and energy cycles in the regional climate system) and related programmes/projects over the last 10 years. Working closely together with two other components – regional meteorology and hydrology of the Baltic Sea drainage basin – oceanographic research has considerably improved the understanding of and ability to model the Baltic Sea marine system. In the Baltic Sea physics seven different broad topics are identified where knowledge has significantly improved. These are reviewed together with a discussion of gaps in knowledge. The focus is on the water and energy cycles of the Baltic Sea, but various aspects of forcing and validation data and modelling are also discussed. The major advances achieved through BALTEX and related programmes are: • Meteorological, hydrological, ocean and ice data are now available for the research community. • Progress in understanding of the strong impact of large-scale atmospheric circulation on Baltic Sea circulation, water mass exchange, sea ice evolution, and changes in the ocean conditions of the Baltic Sea. • Progress in understanding of the importance of strait flows in the exchange of water into and within the Baltic Sea. • Progress in understanding of intra-basin processes. • Ocean models introduced into Baltic Sea water and energy studies. • Development of turbulence models and 3D ocean circulation models for application to the Baltic Sea. • Improved Baltic Sea ice modelling and increased understanding of the need for coupled atmosphere–ice–ocean-land models.

Description: Most simple models for cooling of sheet like intrusions, the Hawaiian lava lakes being one example, neglect the effect of side wall heat loss on the overall thermal evolution. In this paper we extend a conventional one-dimensional (1D) model for cooling of sheet like intrusions to account for lateral heat loss by either prescribing a fixed side wall heat flux, or a heat flux controlled by heat transport in the surrounding wall rock. In the first part of the study we analyze the general interplay between side wall cooling and the thermal evolution of the system; the second part focuses on a comparison between our modeling results including models without and with lateral heat flux, and the Hawaiian lava lake data. This comparison leads to the following three main conclusions: (1) Side wall cooling does have a significant impact on the cooling history of lava lakes. (2) Models assuming a time dependent temperature profile in the wall rock lead to a better fit with the measured temperature data. (3) Due to the sluggish conductive heat transfer in the mush its thermal evolution is significantly decoupled from the temperature evolution of the convecting bulk liquid.

Description: The behavior of dissolved Hf in the marine environment is not well understood due to the lack of direct seawater measurements of Hf isotopes and the limited number of Hf isotope time-series obtained from ferromanganese crusts. In order to place better constraints on input sources and develop further applications, a combined Nd-Hf isotope time-series study of five Pacific ferromanganese crusts was carried out. The samples cover the past 38 Myr and their locations range from sites at the margin of the ocean to remote areas, sites from previously unstudied North and South Pacific areas, and water depths corresponding to deep and bottom waters. For most of the samples a broad coupling of Nd and Hf isotopes is observed. In the Equatorial Pacific εNd and εHf both decrease with water depth. Similarly, εNd and εHf both increase from the South to the North Pacific. These data indicate that the Hf isotopic composition is, in general terms, a suitable tracer for ocean circulation, since inflow and progressive admixture of bottom water is clearly identifiable. The time-series data indicate that inputs and outputs have been balanced throughout much of the late Cenozoic. A simple box model can constrain the relative importance of potential input sources to the North Pacific. Assuming steady state, the model implies significant contributions of radiogenic Nd and Hf from young circum-Pacific arcs and a subordinate role of dust inputs from the Asian continent for the dissolved Nd and Hf budget of the North Pacific. Some changes in ocean circulation that are clearly recognizable in Nd isotopes do not appear to be reflected by Hf isotopic compositions. At two locations within the Pacific Ocean a decoupling of Nd and Hf isotopes is found, indicating limited potential for Hf isotopes as a stand-alone oceanographic tracer and providing evidence of additional local processes that govern the Hf isotopic composition of deep water masses. In the case of the Southwest Pacific there is evidence that decoupling may have been the result of changes in weathering style related to the buildup of Antarctic glaciation.

Description: We examined the thermoregulatory behaviour (TRB) of roosting Humboldt penguins (Spheniscus humboldti) in north central Chile during summer and winter, when ambient temperatures (Ta) are most extreme. Each body posture was considered to represent a particular TRB, which was ranked in a sequence that reflected different degrees of thermal load and was assigned an arbitrary thermoregulatory score. During summer, birds exhibited eight different TRBs, mainly oriented to heat dissipation, and experienced a wide range of Ta (from 14 to 31°C), occasionally above their thermoneutral zone (TNZ, from 2 to 30°C), this being evident by observations of extreme thermoregulatory responses such as panting. In winter, birds exhibited only three TRBs, mainly oriented to heat retention, and experienced a smaller range of Ta (from 11 to 18°C), always within the TNZ, even at night. The components of behavioural responses increased directly with the heat load which explains the broader behavioural repertoire observed in summer. Since penguins are primarily adapted in morphology and physiology to cope with low water temperatures, our results suggest that behavioural thermoregulation may be important in the maintenance of the thermal balance in Humboldt penguins while on land.

Description: We quantified the nitrogen and enzyme hydrolyzable amino acid (EHAA) concentrations of sediments prior to and after corals sloughed, ingested, and egested sediments layered onto their surfaces, for the three coral species Siderastrea siderea, Agaricia agaricites, and Porites astreoides in Jamaica. The percent nitrogen of the sediments egested by all three species was lower than in the sediments available to the corals. Additionally, the sediments sloughed (not ingested) by A. agaricites and P. astreoides were lower in percent nitrogen, while the sediments sloughed by S. siderea had the same percent nitrogen as that of the available sediments. The percent nitrogen of the sediments sloughed and egested by P. astreoides showed significant negative and positive relationships, respectively, to increasing sediment loads, while the percent nitrogen of the sediments sloughed and egested by both S. siderea and A. agaricites showed no relationship to sediment load. EHAA concentrations were not significantly different between the sloughed and available sediments but were significantly lower in the sediments egested by S. siderea and A. agaricites (EHAA concentrations were not measured for P. astreodies sediment fractions). Comparisons of the nitrogen and EHAA concentrations in the sloughed and egested sediments to what was available prior to coral processing show that maximum ingestion was between 0.1 and 0.2 µg N µg−1 coral N cm−2 and between 0.5 and 0.6 µg EHAA·cm−2. Maximum assimilation efficiencies were estimated to be 30–60% of the available nitrogen. The data show that corals ingest and alter the nitrogen concentration of particles that land on their surfaces. The corals’ abilities to process these sediments, and the sediments’ possible contributions to coral nutrition, are discussed based on these results.

Description: Hydrate Ridge, Cascadia convergent margin, is characterized by abundant methane hydrates at and below the seafloor, active venting of fluids and gases, chemosynthetic communities composed of giant sulfide-oxidizing bacteria and clams, authigenic carbonates, and some of the highest methane oxidation rates ever found in the marine environment. Fluid flow rates vary over six orders of magnitude among closely spaced settings at the crest of Hydrate Ridge. The distribution of benthic communities is mainly related to the sulfide flux from the subsurface sediments produced by anaerobic oxidation of methane (AOM). Even at high flux rates, AOM removes most of the methane seeping from the subsurface. Less than 50% of the methane escapes from bacterial mats, from Calyptogena fields 〈15%, and from Acharax beds, no methane is emitted to the water column. The precipitation of carbonate derived from AOM is a significant and permanent carbon sink. Hence, compared to the amount of gas hydrates and methane-derived carbonates stored at the summit of Hydrate Ridge, the emission of methane is relatively low due to the efficient filtering capacity of methanotrophic microbial communities. This present review updates current knowledge of the geology of Hydrate Ridge, summarizes recently published data on geomicrobiology and biogeochemistry, and derives a local methane budget.

Description: Understanding the hydrology of cold seep environments is crucial to perform accurate estimates of fluid and chemical fluxes at sedimentary wedges. Shallow convection processes may affect fluid flux estimates and could favor the destabilization of gas hydrate accumulations, increasing the sediment-ocean methane flux. Evidence for the occurrence of convection at cold seeps, however, is still limited. We use the concentration of 14C (D14C) in carbonate crusts formed at cold seeps of the eastern Mediterranean Sea as a tracer for convective recirculation of seawater-derived fluids. A numerical model is applied to investigate the controls on 14C incorporation in cold seep carbonates. Our simulations show that increased amounts of CH4 in the expelled fluids result in elevated crust D14C, while high Ca2+ and HCO3− concentrations produce the opposite effect. Convection is the only transport process that can significantly increase crust D14C. Advection, bioirrigation, eddy diffusion and bioturbation instead, have little effect on, or produce a decrease of, crust D14C. In addition, the presence of old or modern carbon (MC) in host sediments prior to cementation and the 14C-decay associated to the time needed to form the crust contribute in defining the D14C of carbonate crusts. We then use the model to reproduce the 14C content of the eastern Mediterranean Sea crusts to constrain the chemical and hydrological conditions that led to their formation. Some crusts contain relatively low amounts of 14C (−945.0〈D14C ‰〈−930.2) which, assuming no ageing after crust formation, can be reproduced without considering convection. Other crusts from two sites (the Amsterdam and Napoli mud volcanoes), instead, have a very high 14C-content (−899.0〈D14C ‰〈−838.4) which can only be reproduced by the model if convection mixes deep fluids with seawater. Order-of-magnitude calculations using the Rayleigh criterion for convection suggest that the slow seepage (about 10 cm year−1) of low salinity (20‰) fluids at the Amsterdam sites could trigger haline convection there. On the Napoli mud volcano, where high-density brines are expelled, density-driven convection cannot take place and other processes, possibly involving the rapid movement of free gas in the sediment, could be important.

Description: Here, we present a new technique for the direct measurement of 44Ca/40Ca isotope ratios on a Multicollector Inductively Coupled Plasma Mass Spectrometer (MC–ICP–MS, AXIOM) using the “cool plasma” technique. By reducing the plasma energy to about 400 W, the isobaric effect resulting from 40Ar+ can be significantly reduced, enabling the simultaneous and precise measurement of 44Ca and 40Ca beam intensities in different Faraday cups. In contrast to the TIMS technique requiring a 43Ca/48Ca double spike, the isotope measurements on MC–ICP–MS can be performed by bracketing standards. We express the calcium isotope variation relative to NIST SRM 915a (δ44/40Ca [‰]=[((44Ca/40Ca)sample/(44Ca/40Ca)NIST SRM 915a)−1]*1000). Isobaric effects of 24Mg16O+ and 23Na16OH+ interfering with 40Ca and 26Mg16OH2+ with 44Ca can be neglected by measuring calcium isotopes near the low-mass edge of the peaks. No influence of 87Sr2+ monitored on 43.5 atomic mass units (amu) was found. Repeated measurements of two Johnson Matthey CaCO3 standards (lot No. 4064 and lot No. 9912) revealed values of about −11.29 (‰ SRM 915a) and 0.57 (‰ SRM 915a). These values are in accordance with previous values published by Russell et al. [Geochim. Cosmochim. Acta 42 (1978) 1075], Heuser et al. [Int. J. Mass Spectrom. 220 (2002) 385], Hippler et al. [Geostand. Newsl. 27 (2003) 267] and Schmitt et al. [Geochim. Cosmochim. Acta 67 (2003) 2607]. Repeated measurement of the NIST SRM 915a CaCO3 standard showed that the variance of a single δ44/40Ca measurement is about 0.14‰ RSD being comparable with TIMS. MC–ICP–MS-based δ44/40Ca values measured on inorganically precipitated aragonite samples are indistinguishable from earlier measurements based on TIMS, confirming the positive correlation of δ44/40Ca and temperature. MC–ICP–MS-based δ44/40Ca measurements on cultured Orbulina universa showed a slope of about 0.026‰/°C being similar to the TIMS-based δ44/40Ca measurements showing a slope of about 0.019‰/°C. The large offset of about 5‰ between the two techniques is shown to be caused by a “matrix” effect, indicating that any δ44/40Ca measurements on MC–ICP–MS are sensitively controlled by the Ca concentration and the acidity of the solution. Our study demonstrates the possibility to measure the whole dispersion of calcium isotopes with MC–ICP–MS, showing that 40Ca can be used for normalization of 44Ca.

Description: Climate variability in the northeast Atlantic was investigated on glacial–interglacial and millennial time scales during the last 200 000 years, using sea surface temperature (SST) records derived from planktonic foraminiferal diversities and from Mg/Ca measurements on Globigerina bulloides. Paleoceanographical interpretations are supported by species composition analyses, benthic and planktonic isotopic data as well as records of iceberg-rafted debris (IRD). Differences of climate development are recognized for both interglacial and glacial periods. Temperature estimates indicate slightly warmer conditions (up to 2°C) during marine oxygen isotope stage (MIS) 5e than during the Holocene. In contrast to the last glaciation, when the SST minimum coincided with a minimum in solar insolation immediately before Termination I, during the penultimate glaciation a long SST minimum occurred at times of intermediate solar insolation well preceding the onset of Termination II. This discrepancy between two glacial terminations may be explained by an inherently different orbital configuration characteristic for each glacial interval. Despite these differences between the two glacial trends, the superimposed shorter-lived climatic events reveal the same order of principal steps, implying their common causal nature. A direct comparison of faunal SSTs with those retrieved from Mg/Ca analysis shows that Mg/Ca-derived temperatures follow the general glacial–interglacial trend; however, the latter appear to be largely overestimated. Supported by δ18O data in G. bulloides, which show little response to millennial-scale variability, there seems to be a need for species-dependent calibration experiments that also consider the different oceanographic settings this particular species can live in.

Description: A numerical model of the Atlantic Ocean was used to study the low-frequency variability of meridional transports in the North Atlantic. The model shows a behaviour similar to those used in previous studies, and the temporal variability of certain variables compares favourably to observed time series. By changing the depth and width of the sills between the subpolar North Atlantic and the Nordic Seas, the mean horizontal and overturning circulation as well as some water mass properties are modified significantly. The reaction of meridional oceanic transports to atmospheric forcing fluctuations remains, however, unchanged. The critical role of the surface heat flux retroaction term for the meridional heat transport in stand-alone ocean models is discussed. The experiments underline the role of atmospheric variability for fluctuations of the large-scale ocean circulation on time scales from years to decades, and they support the hypothesis that the mean overturning strength is controlled by the model representation of the density of the overflow water masses.

Description: Seismic reflection data document for the first time the existence of a BSR in a limited area west of the Dnieper Canyon in the northwestern Black Sea. Seismic wide-angle data suggest that gas hydrates occupy in average 15±2% of the pore space in a zone of 100 m in thickness. A conservative quantification of the amount of methane associated with this gas hydrate occurrence is about 12±3×1011 m3 (0.6±0.2 Gt of methane carbon). Conductive heat flow deduced from the BSR depth is in the range of 21±6 to 55±15 mW m−2.

Description: In this paper, we summarize data on terrigenous sediment supply in the Kara Sea and its accumulation and spatial and temporal variability during Holocene times. Sedimentological, organic-geochemical, and micropaleontological proxies determined in surface sediments allow to characterize the modern (riverine) terrigenous sediment input. AMS-14C dated sediment cores from the Ob and Yenisei estuaries and the adjacent inner Kara Sea were investigated to determine the terrigenous sediment fluxes and their relationship to paleoenvironmental changes. The variability of sediment fluxes during Holocene times is related to the post-glacial sea-level rise and changes in river discharge and coastal erosion input. Whereas during the late/middle Holocene most of the terrigenous sediments were deposited in the estuaries and the areas directly off the estuaries, huge amounts of sediments accumulated on the Kara Sea shelf farther north during the early Holocene before about 9 Cal. kyr BP. The maximum accumulation at that time is related to the lowered sea level, increased coastal erosion, and increased river discharge. Based on sediment thickness charts, echograph profiles and sediment core data, we estimate an average Holocene (0–11 Cal. kyr BP) annual accumulation of 194×106 t yr−1 of total sediment for the whole Kara Sea. Based on late Holocene (modern) sediment accumulation in the estuaries, probably 12×106 t yr−1 of riverine suspended matter (i.e., about 30% of the input) may escape the marginal filter on a geological time scale and is transported onto the open Kara Sea shelf. The high-resolution magnetic susceptibility record of a Yenisei core suggests a short-term variability in Siberian climate and river discharge on a frequency of 300–700 yr. This variability may reflect natural cyclic climate variations to be seen in context with the interannual and interdecadal environmental changes recorded in the High Northern Latitudes over the last decades, such as the NAO/AO pattern. A major decrease in MS values starting near 2.5 Cal. kyr BP, being more pronounced during the last about 2 Cal. kyr BP, correlates with a cooling trend over Greenland as indicated in the GISP-2 Ice Core, extended sea-ice cover in the North Atlantic, and advances of glaciers in western Norway. Our still preliminary interpretation of the MS variability has to be proven by further MS records from additional cores as well as other high-resolution multi-proxy Arctic climate records.

Description: Sponges (phylum Porifera) are sessile marine filter feeders that have developed efficient defense mechanisms against foreign attackers such as viruses, bacteria, or eukaryotic organisms. Protected by a highly complex immune system, as well as by the capacity to produce efficient antiviral compounds (e.g., nucleoside analogues), antimicrobial compounds (e.g., polyketides), and cytostatic compounds (e.g., avarol), they have not become extinct during the last 600 million years. It can be assumed that during this long period of time, bacteria and microorganisms coevolved with sponges, and thus acquired a complex common metabolism. It is suggested that (at least) some of the bioactive secondary metabolites isolated from sponges are produced by functional enzyme clusters, which originated from the sponges and their associated microorganisms. As a consequence, both the host cells and the microorganisms lost the ability to grow independently from each other. Therefore, it was—until recently—impossible to culture sponge cells in vitro. Also the predominant number of “symbiotic bacteria” proved to be nonculturable. In order to exploit the bioactive potential of both the sponge and the “symbionts,” a 3D-aggregate primmorph culture system was established; also it was proved that one bioactive compound, avarol/avarone, is produced by the sponge Dysidea avara. Another promising way to utilize the bioactive potential of the microorganisms is the cloning and heterologous expression of enzymes involved in secondary metabolism, such as the polyketide synthases.

Description: Polyclonal antibodies that recognize the two subunits AmoA and AmoB of the ammonia monooxygenase (AMO) were applied to identify ammonia-oxidizing bacteria by immunofluorescence (IF) labeling in pure, mixed, and enriched cultures. The antibodies against the AmoA were produced using a synthetic peptide of the AmoA of Nitrosomonas eutropha, whereas the antibodies against the AmoB had been developed previously is against the whole B-subunit of the AMO [Pinck et al. (2001) Appl Environ Microbiol 67:118–124]. Using IF labeling, the AmoA antibodies were specific for the detection of all species of the genus Nitrosomonas. In contrast, the antiserum against AmoB labeled all genera of ammonia oxidizers of the β-subclass of Proteobacteria (Nitrosomonas, Nitrosospira, Nitrosolobus, and Nitrosovibrio). The fluorescence signals of the AmoA antibodies were spread all over the cells, whereas the signals of the AmoB antibodies were associated with the cytoplasmic membranes. The specificity of the reactions of the antisera with ammonia oxidizers were proven in pure and mixed cultures, and the characteristic IF labeling and the morphology of the cells enabled their identification at the genus level. The genus-specific IF labeling could be used to identify ammonia oxidizers enriched from various habitats. In enrichment cultures of natural sandstone, cells of the genera Nitrosomonas, Nitrosovibrio, and Nitrosospira were detected. Members of the genus Nitrosovibrio and Nitrosolobus were most prominent in enriched garden soil samples, whereas members of the genus Nitrosomonas dominated in enriched activated sludge. The antibodies caused only slight background fluorescence on sandstone and soil particles compared to oligonucleotide probes, which could not be used to detect ammonia oxidizers on these materials because of strong nonspecific fluorescence.

Description: In the past decade, within the framework of joint Russian–German marine and terrestrial studies on the Arctic shelf, New Siberian Islands, and coastal lowlands of the Laptev and East Siberian seas, fundamentally new data have been obtained on terrestrial and offshore permafrost in this area. Field and laboratory investigations supplemented with numerical modeling and generalization of the results of numerous geological surveys, exploratory works, and scientific researches performed in previous years have made it possible to revise existing knowledge about the distribution, thickness, physical state, and history of development of terrestrial and offshore permafrost in the East Siberian part of the Arctic. The main results of these studies and their interpretation are discussed in this paper.

Description: This paper summarizes the results of studies of the Late Weichselian periglacial environments carried out in key areas of northern Eurasia by several QUEEN teams (European Science Foundation (ESF) programme: “Quaternary Environment of the Eurasian North”). The palaeoglaciological boundary conditions are defined by geological data on timing and extent of the last glaciation obtained in the course of the EU funded project “Eurasian Ice Sheets”. These data prove beyond any doubt, that with the exception of the northwestern fringe of the Taymyr Peninsula, the rest of the Eurasian mainland and Severnaya Zemlya were not affected by the Barents–Kara Sea Ice Sheet during the Last Glacial Maximum (LGM). Inversed modelling based on these results shows that a progressive cooling which started around 30 ka BP, caused ice growth in Scandinavia and the northwestern areas of the Barents–Kara Sea shelf, due to a maritime climate with relatively high precipitation along the western flank of the developing ice sheets. In the rest of the Eurasian Arctic extremely low precipitation rates (less than 50 mm yr−1), did not allow ice sheet growth in spite of the very cold temperatures. Palaeoclimatic and palaeoenvironmental conditions for the time prior to, during, and after the LGM have been reconstructed for the non-glaciated areas around the LGM ice sheet with the use of faunal and vegetation records, permafrost, eolian sediments, alluvial deposits and other evidences. The changing environment, from interstadial conditions around 30 ka BP to a much colder and drier environment at the culmination of the LGM at 20–15 ka BP, and the beginning of warming around 15 ka BP have been elaborated from the field data, which fits well with the modelling results.

Description: The bacterial community composition of the active layer (0–45 cm) of a permafrost-affected tundra soil was analysed by fluorescence in situ hybridisation (FISH). Arctic tundra soils contain large amounts of organic carbon, accumulated in thick soil layers and are known as a major sink of atmospheric CO2. These soils are totally frozen throughout the year and only a thin active layer is unfrozen and shows biological activity during the short summer. To improve the understanding of how the carbon fluxes in the active layer are controlled, detailed analysis of composition, functionality and interaction of soil microorganisms was done. The FISH analyses of the active layer showed large variations in absolute cell numbers and in the composition of the active microbial community between the different horizons, which is caused by the different environmental conditions (e.g., soil temperature, amount of organic matter, aeration) in this vertically structured ecosystem. Universal protein stain 5-(4,6-dichlorotriazin-2-yl)aminofluorescein (DTAF) showed an exponential decrease of total cell counts from the top to the bottom of the active layer (2.3 × 109–1.2 × 108 cells per gram dry soil). Using FISH, up to 59% of the DTAF-detected cells could be detected in the surface horizon, and up to 84% of these FISH-detected cells could be affiliated to a known phylogenetic group. The amount of FISH-detectable cells decreased with increasing depth and so did the diversity of ascertained phylogenetic groups.

Description: Durch Vermittlung von Jörn Thiede gelangte das Geologenarchiv in den Besitz eines Videobands von einem Fernsehinterview mit Rosenqvist (auch gelegentlich Rosenquist), das Elen Roaldset (E.R.) im Geologischen Institut der Universität Oslo am 8.September 1988 führen konnte. Es umfasst den gesamten Lebenslauf und die wichtigsten wissenschaflichen Leistungen dieses aussergewöhnlichen Geologen und Mineralogen. Er wurde in Wien am 17. Mai 1916 geboren, kam aber mit seinen Eltern schon 1917 nach Oslo, wo er am 8. Oktober 1994 starb (K. Bjørlykke 1995). Im Folgenden sollen aus dem Interview nur seine wegweisenden Untersuchungen der Quicktone, seine fachliche Vielseitigkeit, sein gesellschaftliches Engagement und seine schwierigen Erfahrungen mit Deutschland herausgegriffen werden. Das in der Landessprache geführte Gespräch wurde von Geir Ebelfoff und Lars Erik Kastilan ins Deutsche transkribiert.

Description: Testate amoebae (Protozoa: Testacea) were studied in the Late Quaternary permafrost deposits in the Siberian Arctic (Bykovsky Peninsula of the Laptev Sea coast, 71°40′ –71°80′ N and 129°–129°30′ E). The Testacea associations studied reflect specific environmental conditions in paleocryosols, which were controlled by the local micro-relief as well as by regional climate conditions. In total, 86 species, varieties, and forms of testate amoebae were found in 38 Pleistocene and Holocene samples. The rhizopods indicate that soil conditions at ca. 53,000 14C years BP were probably rather similar to the modern cold and wet arctic tundra environment. More moisture and warmer soil conditions were relatively favorable for rhizopods ca. 45,300–43,000 14C years BP, but it was significantly drier at about 42,000 14C years BP. Drier and colder environmental conditions were also present about 39,300–35,000 14C years BP. The Late Pleistocene samples, radiocarbon dated to 33,000–12,000 years BP, are characterized by a low species diversity and density indicating that this period may have been extremely cold and dry. This conjecture is also supported by the polymorphism of some species. Hydrophilic Difflugia species (mostly obligate hydrobiotes) are broadly represented in the studied Holocene samples. The species composition and density of rhizopods in the majority of Holocene samples suggest wet and relatively warm conditions. Changes in rhizopod assemblages during the last 53,000 years were not very dramatic, mostly consisting of rare species and changes in the dominant species complexes during the Pleistocene and Holocene. However, these changes were more drastic during the Pleistocene. They were probably at least partly responsible for the disappearance of some rare testacean species such as Argynnia sp.

Description: Portable and automated field screening equipment would be very effective in assessing contamination due to explosives at many defense sites. A droplet based microfluidic lab-on-a-chip utilizing electrowetting has been presented for fully automated detection of TNT. Microliter droplets of TNT in DMSO and KOH in water are reacted on a chip in a programmed way. The same platform has integrated colorimetric detection. The detection of TNT is linear in the range of 12.5–50 µg/mL.

Description: In July 2001, samples of surface suspended particulate material (SPM) of the Irtysh river in its middle and lower reaches (from Omsk City to the confluence with the Ob river) and its main tributaries were collected (18 stations along 1834 km). The SPM samples were analyzed for major and trace element composition. The results show that the geochemistry of Irtysh river SPM is related to landscape and geochemical peculiarities of the river basin on one hand and to industrial activities within the drainage area on the other hand. In the upper basin polymetallic and cinnabar deposits and phosphorite deposits with high As content are widespread. The open-cut mining and developed oil-refining, power plants and other industries lead to the contamination of the environment by heavy metals and other contaminants. The territory of the West Siberian lowland, especially the Ob-Irtysh interfluve, is characterized by the occurrence of swamps and peat-bogs. Tributaries of the Irtysh river originating in this region, have a brown color and the chemical composition of the SPM is specific for stagnant water. In the first 500–700 km downstream from Omsk City the Irtysh river has the typical Al–Si-rich suspended matter composition. After the inflow of the tributaries with brown water the SPM composition is significantly changed: an increase of POC, Fe, P, Ca, Sr, Ba and As concentrations and a strong decrease of the lithogenic elements Al, Mg, K, Na, Ti, Zr can be observed. The data show that Fe-organic components (Fe-humic amorphous compounds, which contribute ca. 75–85% to the total Fe) play a very important role in SPM of the tributaries with brown water and in the Irtysh river in its lower reaches. Among the trace metals significant enrichments relative to the average for global river SPM could only be observed for As and Cd (coefficient of enrichment up to 16 for As and 3–3.5 for Cd). It can be shown that the enrichment of As in the SPM is related to natural processes, i.e. the weathering of phosphate containing deposits with high As concentrations in the upper Irtysh basin and the high As–P affinity in the swamp peaty soil. Dissolved P and As are absorbed by amorphous organic C/Fe oxyhydroxide components which act as carriers during the transport to the main stream of the Irtysh river. The role of anthropogenic factors is probably insignificant for As. In contrast, the enrichment of Cd is mainly related to anthropogenic input. The threefold enrichment of Cd in the SPM just below Omsk City and its continuous decrease down to background level at a distance of 500–700 km downstream points quite definitely to the municipal and industrial sewage of Omsk City as the main source of Cd in the SPM of the Irtysh river.

Description: The spatio-temporal pattern of peak Holocene warmth (Holocene thermal maximum, HTM) is traced over 140 sites across the Western Hemisphere of the Arctic (0–180°W; north of ∼60°N). Paleoclimate inferences based on a wide variety of proxy indicators provide clear evidence for warmer-than-present conditions at 120 of these sites. At the 16 terrestrial sites where quantitative estimates have been obtained, local HTM temperatures (primarily summer estimates) were on average 1.6±0.8°C higher than present (approximate average of the 20th century), but the warming was time-transgressive across the western Arctic. As the precession-driven summer insolation anomaly peaked 12–10 ka (thousands of calendar years ago), warming was concentrated in northwest North America, while cool conditions lingered in the northeast. Alaska and northwest Canada experienced the HTM between ca 11 and 9 ka, about 4000 yr prior to the HTM in northeast Canada. The delayed warming in Quebec and Labrador was linked to the residual Laurentide Ice Sheet, which chilled the region through its impact on surface energy balance and ocean circulation. The lingering ice also attests to the inherent asymmetry of atmospheric and oceanic circulation that predisposes the region to glaciation and modulates the pattern of climatic change. The spatial asymmetry of warming during the HTM resembles the pattern of warming observed in the Arctic over the last several decades. Although the two warmings are described at different temporal scales, and the HTM was additionally affected by the residual Laurentide ice, the similarities suggest there might be a preferred mode of variability in the atmospheric circulation that generates a recurrent pattern of warming under positive radiative forcing. Unlike the HTM, however, future warming will not be counterbalanced by the cooling effect of a residual North American ice sheet.

Description: The effect of microrelief and vegetation on methane (CH4) emission was investigated in a wet polygonal tundra of the Lena Delta, Northern Siberia (72.37N, 126.47E). Total and plant-mediated CH4 fluxes were measured by closed-chamber techniques at two typical sites within a low-centred polygon. During the study period, total CH4 flux averaged 28.0 ± 5.4 mg m−2 d−1 in the depressed polygon centre and only 4.3 ± 0.8 mg m−2 d−1 at the elevated polygon rim. This substantial small-scale spatial variability of CH4 emission was caused by strong differences of hydrologic conditions within the microrelief of the polygon, which affected aeration status and organic matter content of the soils as well as the vegetation cover. Beside water table position, the vegetation cover was a major factor controlling CH4 emission from polygonal tundra. It was shown that the dominant vascular plant of the study area, Carex aquatilis, possesses large aerenchyma, which serve as pathways for substantial plant-mediated CH4 transport. The importance of plant-mediated CH4 flux was strongly influenced by the position of the water table relative to the main root horizon. Plant-mediated CH4 transport accounted for about two-thirds of the total flux in the wet polygon centre and for less than one-third of the total flux at the moist polygon rim. A clipping experiment and microscopic-anatomical studies suggested that plant-mediated CH4 transport via C. aquatilis plants is driven only by diffusion and is limited by the high diffusion resistance of the dense root exodermes.

Description: Diatom assemblages and organic carbon records from two sediment cores located within an estuarian bay of the inner Kara Sea trace changes in Yenisei River runoff and postglacial depositional environments. Paleosalinity and sea-ice reconstructions are based on modern relationships of local diatom assemblages and summer surface-water salinity. Approximately 15,500 cal yr B.P., rivers and bogs characterized the study area. When sea level reached the 38- to 40-m paleo-isobath approximately 9300 cal yr B.P., the coring site was flooded. From 9300–9100 cal yr B.P., estuarine conditions occurred proximal to the depocenter of fluvially derived material, and salinity was 〈7–8. Paleosalinity increased to 11–13 by 7500 cal yr B.P., following postglacial sea-level rise and the southward shift of the Siberian coast. Sharp decreases in diatom accumulation rates, total sediment, and organic carbon also occurred, suggesting the presence of brackish conditions and greater distance between the coast and study site. Maximum paleosalinity (up to 13) was recorded between 7500 and 6000 cal yr B.P., which was likely caused by the enhanced penetration of Atlantic waters to the Kara Sea. Stepwise decreases to modern salinity levels happened over the last 6000 cal yr.

Description: From cell cultures of Suberites domuncula was isolated a bacterial strain, SDC-1, which was identified by 16S ribosomal RNA sequence analysis as an α-Proteobacterium of the genus Ruegeria. The occurrence of the strain in sponge cell culture could be explained by its resistance to the antibiotics used in the isolation of sponge cell cultures or by the preservation of SDC-1 by host sponge cells. The fatty acid composition of SDC-1 is characterized by branched C-12 methyl fatty acids. Two new and 8 known cyclic dipeptides were isolated and characterized from the fermentation broth of SDC-1. Cyclodipeptides are one of the families of cell-cell signaling compounds and may have some role to play in sponge-bacteria interactions.

Description: Maintaining deep sea animals in in situ conditions has always been technically difficult because of the high-pressure requirements. Even more difficult are any attempts in manipulating or sampling these organisms while keeping them alive in high-pressure aquaria. We present a technique to withdraw blood samples by vascular catheterization which allows withdrawal of samples of during maintenance of specimens under high-pressure conditions. We have developed this technique to answer a long debated question, how carbon dioxide is transported from the ambient sea water to the bacterial symbionts inside the trophosome of the hydrothermal vent tubeworm Riftia pachyptila. Our results indicate that the carbon supply to the symbionts is mainly through inorganic CO2 while its incorporation into malate and succinate may serve storage functions at periods of low CO2 availability in the environment.

Description: Culture pelleting and morphology has a strong influence on process productivity and success for fungal and filamentous bacterial cultures. This impact is particularly evident with early phase secondary metabolite processes with limited process definition. A compilation of factors affecting filamentous or pelleting morphology described in the literature indicates potential leads for developing process-specific control methodologies. An evaluation of the factors mediating citric acid production is one example of an industrially important application of these techniques. For five model fungal and filamentous bacterial processes in an industrial fermentation pilot plant, process development strategies were developed and effectively implemented with the goal of achieving reasonable fermentation titers early in the process development cycle. Examples of approaches included the use of additives to minimize pelleting in inoculum shake flasks, the use of large-volume frozen bagged inoculum obtained from agitated seed fermentors, and variations in production medium composition and fermentor operating conditions. Results were evaluated with respect to productivity of desired secondary metabolites as well as process scalability. On-line measurements were utilized to indirectly evaluate the cultivation impact of changes in medium and process development. Key laboratory to pilot plant scale-up issues also were identified and often addressed in subsequent cultivations.

Description: Large uncertainties about the energy resource potential and role in global climate change of gas hydrates result from uncertainty about how much hydrate is contained in marine sediments. During Leg 204 of the Ocean Drilling Program (ODP) to the accretionary complex of the Cascadia subduction zone, we sampled the gas hydrate stability zone (GHSZ) from the seafloor to its base in contrasting geological settings defined by a 3D seismic survey. By integrating results from different methods, including several new techniques developed for Leg 204, we overcome the problem of spatial under-sampling inherent in robust methods traditionally used for estimating the hydrate content of cores and obtain a high-resolution, quantitative estimate of the total amount and spatial variability of gas hydrate in this structural system. We conclude that high gas hydrate content (30–40% of pore space or 20–26% of total volume) is restricted to the upper tens of meters below the seafloor near the summit of the structure, where vigorous fluid venting occurs. Elsewhere, the average gas hydrate content of the sediments in the gas hydrate stability zone is generally 〈2% of the pore space, although this estimate may increase by a factor of 2 when patchy zones of locally higher gas hydrate content are included in the calculation. These patchy zones are structurally and stratigraphically controlled, contain up to 20% hydrate in the pore space when averaged over zones ∼10 m thick, and may occur in up to ∼20% of the region imaged by 3D seismic data. This heterogeneous gas hydrate distribution is an important constraint on models of gas hydrate formation in marine sediments and the response of the sediments to tectonic and environmental change.

Description: Detrital zircon ages are commonly used to investigate sediment provenance and supply routes. Here, we explore the advantages of employing multiple, complimentary techniques via a case study of the Neoproterozoic and Cambrian of the Adelaide Rift Complex, South Australia. Detrital muscovite Ar–Ar ages are presented from stratigraphic units, or equivalents, that have previously been the subject of U–Pb detrital zircon dating, and, in some cases, whole-rock Sm–Nd isotope studies. The zircon age ranges and whole-rock Sm–Nd isotope data suggest that early Neoproterozoic sediments from near the base of the Adelaide Rift Complex comprise a mixture of detritus derived from the adjacent Gawler Craton (Palaeoproterozoic to earliest Mesoproterozoic) and overlying Gairdner flood basalts. In contrast, detrital muscovites from this level have a broad scatter of Mesoproterozoic infrared (IR) laser total fusion Ar–Ar ages, while UV laser traverses indicate that the age spread reflects partial resetting by multiple heating events, rather than a mixture of sources. Younger Neoproterozoic sediments document replacement of the Gawler Craton by the more distant Musgrave and/or Albany–Fraser Orogens as the main provenance. The Cambrian Kanmantoo Group marks an abrupt change in depositional style and a new sediment source. The Kanmantoo Group have older Nd model ages than underlying strata, yet are dominated by near to deposition-aged (∼500–650 Ma) detrital zircons and muscovites, suggesting rapid cooling and exhumation of a tectonically active provenance region. Although this source remains uncertain, evidence points towards the distant Pan-African orogenic belts. Deposition in the Adelaide Rift Complex was terminated in the late Early Cambrian by the Delamerian Orogeny, and the results of previous detrital mineral dating studies from the Lachlan Fold Belt to the east are consistent with at least partial derivation of these sediments from reworked upper Adelaide Rift Complex (Kanmantoo Group), rather than a continuation of sediment supply from the Kanmantoo Group sediment source. More broadly, the data suggest a close link between basin formation and orogen exhumation, and we also speculate that mantle plumes have played a significant role in crustal evolution at this Palaeo-Pacific margin of Gondwanaland, challenging the notion that subduction zones are the principle sites of crustal growth and sediment provenance.

Description: Hydroacoustic methods are particularly suitable for investigations of the occurrence, cyclicity and amount of bubbles released at cold seeps without disturbing them. Experiments with a horizontally looking single beam transducer (40 and 300 kHz) directed towards artificially produced bubbles show that the backscattering strength of the bubbles increases with the gas flux rate independently of the bubble radii distribution. It is demonstrated that an acoustic system can be calibrated in such a way that gas flux rates of bubble-size spectra, as observed at natural seeps, can be directly related to the echo level of a known, acoustically insonified volume. No system-specific parameters have to be known except the beam width.

Description: The distribution of platinum group elements (PGE) in Cu- and Zn-rich samples from the Roman Ruins and Satanic Mills vent sites in the PACMANUS hydrothermal field (Papua New Guinea) was studied and compared to that from selected ancient volcanogenic massive sulfide (VMS) deposits. Samples from the Satanic Mills site are enriched in Pd and Rh when compared to samples from Roman Ruins and reach highest values in active and inactive Cu-rich black smoker chimneys and chalcopyrite-cemented dacite breccias (up to 356 ppb Pd and up to 145 ppb Rh). A significant positive correlation was established between Cu and Pd and Rh in samples from both vent sites. Comparisons of chondrite normalized patterns and values of Pd/Pt and Pd/Ir ratios in Cu-rich sulfides and probable source rocks (felsic volcanic rocks/MORB) along with the evidence for a magmatic component in the PACMANUS hydrothermal system indicate that leaching of back-arc volcanic rocks together with addition of magmatic volatiles to the convecting hydrothermal system was the most important factor for PGE enrichment at PACMANUS and likely at some PGE-enriched ancient VMS deposits.

Description: At many cold vent sites authigenic carbonates precipitate due to the release of carbonate alkalinity during the anaerobic oxidation of methane. Carbonate precipitation often induces the formation of massive crusts at the sediment surface or within surface sediments. The range of physical and biogeochemical conditions allowing for the formation of carbonate crusts is largely unknown so that the significance of these widespread manifestations of fluid flow is unclear. Here, we use numerical modeling to investigate the conditions that induce carbonate crust formation in the sediment and the effect of crust formation on sediment porosity and fluid flow rate. Starting with the conditions prevailing at a previously investigated reference site located on Hydrate Ridge, off Oregon, several parameters are systematically varied in a number of numerical experiments. These parameters include coefficients of bioturbation and bioirrigation, sedimentation rate, fluid flow velocity, methane concentration in the ascending vent fluids, and pH and saturation state at the sediment–water interface. The simulations show that carbonate crusts in the sediments only form if the fluids contain sufficient dissolved methane (〉50 mM) and if bioturbation coefficients are low (〈0.05 cm2 a−1). Moreover, high sedimentation rates (〉50 cm ka−1) inhibit crust formation. Bioirrigation induces a downward displacement of the precipitation zone and accelerates the formation of a solid crust. Crusts only form over a rather narrow range of upward fluid flow velocities (20–60 cm a−1), which is somewhat enlarged (up to 90 cm a−1) if the overlying bottom waters are supersaturated with respect to calcite. At higher flow rates, methane is rapidly exported into the water column so that methane oxidation and carbonate precipitation cannot proceed within the surface sediment. The formation of a several centimeters thick carbonate crust in surface sediments is typically completed after a few hundred years (100–500 a). Crust formation reduces the supply of methane to surface sediments which imposes a strong resistance against diffusive and advective methane transport. Therefore, rates of anaerobic methane oxidation and sulfide production are diminished and thus the density and metabolism of chemosynthetic biological communities is limited by crust formation. Due to the moderate flow rates and the slow diffusive transport, only very little methane escapes into the bottom water overlying carbonate-encrusted vent areas.

Description: The Greens Creek polymetallic massive sulphide deposit is hosted in a typical polyphase deformed lower greenschist facies orogenic setting. The structure of the host rocks is well constrained, exhibiting a series of three superimposed ductile deformations followed by two brittle episodes. The ore is found both in fold hinges where early-formed depositional features are preserved and in fold limbs where primary features are typically strongly modified or obliterated. Samples from both settings have been investigated using electron backscatter diffraction (EBSD) coupled with forescatter orientation contrast (OC) imaging in order to observe the effects of deformation and lower greenschist facies metamorphism on pyrite. Results suggest that colloform pyrite may preserve information relevant to palaeoenvironment, that apparently simple textures are generally more complex, and that pyrite can deform plastically by dislocation glide and creep processes at lower temperatures and/or strain rates than generally accepted. This analysis indicates that EBSD and OC imaging provide powerful tools for observing textural relationships in pyrite that are not shown by more traditional methods. They should become routine tools for pyrite texture analysis.

Description: A high-resolution early diagenetic model for the North Sea sediments has been coupled with a pelagic ecosystem model to quantify the three-dimensional processes in the coupled sediment–water system from the sea surface to a sediment depth of 11 cm focussing on the processes in the sediments of the North Sea. The pelagic ecosystem model ECOHAM1 simulates the 1986 phytoplankton dynamics considering circulation, temperature, nutrient availability in the water column and the resulting flux of particulate organic carbon (POC) onto the sediment. These seasonal and regional variable water column processes are considered as forcing for the early diagenetic model C. CANDI, which calculates the processes in the upper sediment column, represented by 14 dissolved and 6 solid species, resolved with 84 vertical levels. With the coupled model the daily benthic fluxes of POC, oxygen, nitrate, phosphate, and sulphate at the sediment–water interface for each of the 1158 horizontal cells covering the whole North Sea area has been determined. The simulations show the seasonal and regional variations in the pelagic and the sediment system. The coupled model reproduces very well measured oxygen and nitrate penetration depths at selected validation stations. A vertical section from Fair Isle into the German Bight in summer demonstrates high spatial phosphate variability in the water column and in the sediment. Observations on the sediment–water interface fluxes and of concentration distributions in the sediment are very sparse. The results of this high-resolution model allows the calculation of budgets at the sediment–water interface for the whole simulation area. The annual cumulated phosphate flux across the sediment–water interface exhibits strong fluxes concentrated in a narrow band off the continental coast in shallow waters over 40 mmol m−2 yr−1, whereas in the central North Sea fluxes are lower than 30 mmol m−2 yr−1. Simulated annual cycle of fluxes at the sediment–water interface at a position located in the central North Sea showed a phosphate flux shifted by 1 month compared to the organic matter flux, whereas the sulphate flux into the sediment showed an overall time lag of about 5 months.

Description: While the majority of research on ultraviolet radiation (UVR) has focused on UVR-induced changes in the productivity and abundance of single taxonomic groups, only a few field studies have considered the influence of ambient UVR on complete assemblages, in particular of the macrobenthos. Using cutoff filters, we followed the effects of three radiation treatments, (1) PAR+UVAR+UVBR, (2) PAR+UVAR, (3) PAR, on macrobenthic community structure at Luderitz, Namibia, SE Atlantic, for 3 months. Species composition, biomass, evenness, and species richness were not significantly affected by UVR. while the diversity IT of PAR+UVAR+UVBR-exposed communities was significantly lower compared to PAR treatments. However, this effect was only observed early in succession. Increased abundance of the red alga Ceramium sp. coincided with vanishing UVR effects on the community, suggesting a muted UVR microclimate under the Ceramium canopy. Our results demonstrate that UVR could neither decrease diversity persistently, nor affect any of the other tested community parameters. Single UVR-tolerant species may provide protective shading for UVR-sensitive species, thus buffering harmful UVR effects at the community level. Missing UVBR effects suggest a limited influence of ozone depletion on shallow water macrobenthic diversity. (C) 2003 Elsevier B.V. All rights reserved.

Description: Pelado, Guespalapa, and Chichinautzin monogenetic scoria cones located within the Sierra del Chichinautzin Volcanic Field (SCVF) at the southern margin of Mexico City were dated by the radiocarbon method at 10,000, 2,800–4,700, and 1,835 years b.p., respectively. Most previous research in this area was concentrated on Xitle scoria cone, whose lavas destroyed and buried the pre-Hispanic town of Cuicuilco around 1,665±35 years b.p. The new dates indicate that the recurrence interval for monogenetic eruptions in the central part of the SCVF and close to the vicinity of Mexico City is 〈2,500 years. If the entire SCVF is considered, the recurrence interval is 〈1,700 years. Based on fieldwork and Landsat imagery interpretation a geologic map was produced, morphometric parameters characterizing the cones and lava flows determined, and the areal extent and volumes of erupted products estimated. The longest lava flow was produced by Guespalapa and reached 24 km from its source; total areas covered by lava flows from each eruption range between 54 (Chichinautzin) and 80 km2 (Pelado); and total erupted volumes range between 1 and 2 km3/cone. An average eruption rate for the entire SCVF was estimated at 0.6 km3/1,000 years. These findings are of importance for archaeological as well as volcanic hazards studies in this heavily populated region.

Description: The magmatic evolution of the Alboran region (westernmost Mediterranean) contains important clues for improving our understanding of the origin of Mediterranean-style back-arc basins and the desiccation of the Mediterranean Sea in the Messinian. We use new laser 40Ar/39Ar age and geochemical (major and trace element and O–Sr–Nd–Pb isotope) data from igneous rocks from southern Spain, the Alboran Sea and northern Morocco to reconstruct the magmatic evolution of the westernmost Mediterranean since the Eocene. Lower Oligocene dikes near Malaga (33.6±0.6 Ma) and Middle to Upper Miocene volcanic rocks from the Alboran Sea area (6.57±0.04 to 11.8±0.4 Ma) can be subdivided into two groups: (1) LREE-depleted (relative to N-MORB), primarily tholeiitic series, and (2) LREE-enriched, primarily calc-alkaline series volcanic rocks. Both groups are generally enriched in fluid-mobile elements (e.g. Rb, Th, U, K and Pb) relative to fluid-immobile elements (e.g. Nb, Ta, LREE). The LREE-depleted group has 143Nd/144Nd (0.5128–0.5130) isotope ratios similar to Atlantic MORB but higher 87Sr/86Sr (0.7046–0.7100). In contrast, the LREE-enriched group has less radiogenic Nd (0.5121–0.5126) and tend to more radiogenic Sr (0.7066–0.7205) isotopic composition. Pb isotope ratios are surprisingly uniform and have compositions similar to marine sediments. Analyses of mineral separates show that mafic melts with relatively low δ18O (5.6–7.2‰) had high 87Sr/86Sr (0.7048–0.7088), Δ7/4 (10.6–14.1) and Δ8/4 (40.0–49.3). Modeling of the trace elements and Sr–Nd–Pb–O isotopic compositions provides compelling evidence for the contamination of the mantle source with hydrous fluids/melts, which can be explained through subduction of oceanic lithosphere beneath the Alboran Basin but not through detachment/delamination of lithospheric mantle. We present a geodynamic model that reconstructs the Late Eocene to Quaternary evolution of the western Mediterranean through westward roll-back of subducted Tethys oceanic lithosphere. Slab roll-back resulted in a large-scale reorganization of the western Mediterranean paleogeography, causing the closure of marine gateways linking the Atlantic Ocean to the Mediterranean Sea. Isolation of the Mediterranean Sea led to its desiccation, causing the Messinian Salinity Crisis.

Description: Several epibiotic species reduce starfish (Asterias rubens) preference for the blue mussel Mytilus edulis in the Baltic. The aim of this study was to reveal whether this associational resistance was caused by structural or chemical aspects of the different epibionts. To assess structural epibiont effects, an in situ experiment was conducted with unfouled mussels and mussels equipped with artificial epibionts ('dummies') exposed to natural predation by A. rubens. The chemically inert dummies closely matched the structural properties of the locally common epibionts Balanus improvisus (barnacle), Ceramium strictum (red alga), Halichondria panicea (sponge), and Laomedea flexuosa (hydrozoan). Starfish fed indiscriminately in all treatments. Chemical effects of epibionts on the attractiveness of mussels for A. rubens were investigated by incorporating freeze-dried epibionts or mussel tissue into Phytagel pellets at natural concentrations. Starfish were allowed to choose among these structurally similar but chemically different prey items in an in vitro experiment. The predators exhibited significant preferences among the food pellets, which closely matched their preferences for corresponding natural mussel-epibiont associations. Thus, chemical aspects of epibionts appear to play a larger role in this associational resistance than do structural aspects. Implications of these indirect interactions for benthic communities are discussed.

Description: The validity of predictions derived from the intermediate disturbance hypothesis (IDH) was tested in situ by manipulating mussel dominated Western Baltic fouling communities. Assemblages of two different successional stages, 3 and 12 months old, underwent a 3-month period of disturbance treatment in terms of various frequencies of emersion. Emersion frequency levels ranged from 1×15 to 48×15 min emersion day−1. The study on the 3-month-old communities was repeated in 2 subsequent study years. Species richness, evenness and diversity (Shannon index) were recorded to measure the effects of frequency treatments on community structure. The IDH was confirmed in the first year, when diversity was found to be a unimodal function of the applied emersion frequency gradient. Diversity–disturbance relationships were inverse unimodal or non-significant in the second year, which was true for both successional stages. This ambiguous picture partially confirms the validity of the mechanisms proposed by the IDH, but also shows that their forcing can be masked by fluctuations in environmental parameters, such as climatic conditions. Diversity increased again under severe disturbance conditions, due to a disturbance-induced change in community structure, namely the shift from mussel to algal dominance. This is a new aspect in the discussion concerning disturbance–diversity relationships

Description: Late Holocene volcanic activity at Ruapehu has been characterizedby the generation of small (〈105 m3) to very large (〉107 m3) lahars and repeated,small to medium (VEI 1-3) tephra-producing eruptions. The Onetapu Formation groupsall lahar deposits that accumulated during the last 2,000 years on the southeastern Ruapehu ring plain. The andesitic tephras are grouped within the Tufa Trig Formation and are intercalated within the laharic sequence. By correlating these two formations with new radiocarbon ages obtained on interbedded paleosols, we reconstruct a detailed volcanic history of Ruapehu for this period. Clast assemblages identified in the laharic sequences record thelithologies of synchronous tephras and rocks within the source region. These assemblages suggest a strong genetic link between the development of Crater Lake, the variation in eruptivestyles, and the production of lahars. Lahar-triggering mechanisms include: (1) flank collapse ofhydrothermally altered and unstable portions of the cone; (2) phreatic and phreatomagmatic eruptions favoring the generation of snow-rich slurries and hyperconcentrated stream flows; (3) suddenCrater Lake rim collapse, releasing large amounts of water inducing debris flows; and (4) eruptions that generate large volumes of tephra on snow-covered slopes, later remobilized by heavy rain. Two major lahars in the Onetapu sequence had a volume≥ 4 × 107 m3, roughly 1 to 2 orders of magnitude larger than the 1953event leading to the Tangiwai disaster (151 casualties). One of these lahars crossed over a lowinterfluve currently separating the Whangaehu River from a stream feeding the Tongariro River,sometime since peat accumulated between AD 1400 and AD 1660. A repetition of such a large-scaleevent would have devastating consequences on the infrastructure, economy and environment withinthe distal areas of the two catchments. The 1995–1996 eruptions were a timely reminder ofthe hazards posed by the volcano.

Description: Biogenic structures in Late Quaternary sediments from the southwestern Iberian continental slope were studied by using X-ray images from two cores from 580 and 1750 m water depth. Eight different ichnocoenoses were observed: indistinct bioturbation, Planolites-dominated, Thalassinoides-dominated, Chondrites-dominated, Planolites and Thalassinoides-dominated, pyritized microburrows such as Trichichnus and ‘Mycellia’-dominated, Chondrites, Trichichnus, and ‘Mycellia’-dominated and Zoophycos. Variations of the ichnocoenoses within the cores show a striking correlation with climatically induced changes in the hydrographical regime, i.e. current strength and bathymetric position of the Mediterranean Outflow Water (MOW). Comparison of the response of the ichnocoenoses to changes in bottom-water conditions and substrate between the two cores studied indicate that bottom-water oxygenation and enrichment of particulate organic matter at the base of the MOW layer are the primary factors controlling the ichnocoenoses. The traces even recorded short-term climatic changes such as the Younger Dryas cold event. The spatial and temporal distribution patterns are in good agreement with earlier models of the MOW history, which gives reason to see a refinement of trace fossils as a complementary tool for paleoceanographical studies.

Description: We have analyzed the stable oxygen isotopic composition of two Porites corals from the Chagos Archipelago, which is situated in the geographical center of the Indian Ocean. Coral δ18O at this site reliably records temporal variations in precipitation associated with the Intertropical Convergence Zone (ITCZ). Precipitation maxima occur in boreal winter, when the ITCZ forms a narrow band across the Indian Ocean. The Chagos then lies within the center of the ITCZ, and rainfall is strongly depleted in δ18O. A 120-yr coral isotopic record indicates an alternation of wet and dry intervals lasting 15 to 20 yr. The most recent 2 decades are dominated by interannual variability, which is tightly coupled to the El Niño–Southern Oscillation (ENSO). This is unprecedented in the 120 yr of coral record. As the ITCZ is governed by atmospheric dynamics, this provides evidence of a major change in the coupled ENSO–monsoon system.

Description: The δ18O values of planktonic foraminifera increased in the Caribbean by about 0.5‰ relative to the equatorial East Pacific values between 4.6 and 4.2 Ma as a consequence of the closure of the Central American Gateway (CAG). This increase in δ18O can be interpreted either as an increase in Caribbean sea surface (mixed layer) salinity (SSS) or as a decrease in sea surface temperatures (SST). This problem represents an ideal situation to apply the recently developed paleotemperature proxy δ44/40Ca together with Mg/Ca and δ18O on the planktic foraminifer Globigerinoides sacculifer from ODP Site 999. Although differences in absolute temperature calibration of δ44/40Ca and Mg/Ca exist, the general pattern is similar indicating a SST decrease of about 2–3 °C between 4.4 and 4.3 Ma followed by an increase in the same order of magnitude between 4.3 and 4.0 Ma. Correcting the δ18O record for this temperature change and assuming that changes in global ice volume are negligible, the salinity-induced planktonic δ18O signal decreased by about 0.4‰ between 4.4 and 4.3 Ma and increased by about 0.9‰ between 4.3 and 4.0 Ma in the Caribbean. The observed temperature and salinity trends are interpreted to reflect the restricted exchange of surface water between the Caribbean and the Pacific in response to the shoaling of the Panamanian Seaway, possibly accompanied by a southward shift of the Intertropical Convergence Zone (ITCZ) between 4.4 and 4.3 Ma. Differences in Mg/Ca- and δ44/40Ca-derived temperatures can be reconciled by corrections for secular variations of the marine Mg/Casw and δ44/40Ca, a salinity effect on the Mg/Ca ratio and a constant temperature offset of ∼2.5 °C between both SST proxy calibrations.

Description: Halogenated transient tracers such as the chlorofluorocarbons CFC-11, CFC-12 and CFC-113 are commonly used in oceanographic studies. These compounds enter the ocean via the atmosphere and their transient atmospheric concentrations make them valuable as oceanic tracers. The trends of rapidly rising atmospheric concentrations of these tracers are however broken, and the oceanic signal becomes increasingly more difficult to decipher. There is a need for a new transient tracer to complement the existing suit of tracers, especially for recently ventilated water masses. One compound that looks promising in this respect is sulphur hexafluoride (SF6), an inert gas whose atmospheric concentration is rising rapidly. In this paper, the use of SF6 as a transient tracer in recently ventilated waters is discussed and the method for determination of SF6 in seawater is described. Tracer data from a section in the Atlantic sector of the Southern Ocean along 6°E, from 60°S to 40°S, occupied during January 1998, are presented. The Antarctic Polar Front, found close to 50°S, was studied with a densely sampled section down to 400 m depth and SF6/CFC-12 ratios are used to deduce ventilation ages and dilution factors. A comparison of apparent ages derived from a variety of tracers is presented together with the uncertainties in these estimates. This work demonstrates that SF6 is a useful and valuable transient tracer for waters ventilated during the last 20 years

Description: Effects of two presumably dominant competitors, the blue mussel Mytilus edulis and the barnacle Balanus improvisus on recruitment, population dynamics and community structure on hard substrata were experimentally investigated in the subtidal Kiel Fjord, Western Baltic. The hypothesis that blue mussels and/or barnacles are local dominants and strongly influence succession and community structure was tested by monitoring succession in the presence and absence of simulated predation on either or both species. Manipulations included blue mussel removal, barnacle removal, combined blue mussel and barnacle removal, as well as a control treatment for natural (non-manipulated) succession. In the second part of the experiment, recovery from the treatments was monitored over 1 year. During the manipulative phase of the experiment, blue mussels had a negative effect on recruitment of species, whereas barnacles had no significant effect. Even so, a negative synergistic effect of blue mussels and barnacles was detected. Calculation of species richness and diversity H-1 (Shannon Index) showed a negative synergistic effect of blue mussels and barnacles on community structure. Additionally, diversity H-1 was negatively affected by the dominant competitor M. edulis. These effects were also detectable in the ANOSIM-Analysis. The non-manipulative phase of the experiment brought about a drastic loss of diversity and species richness. Blue mussels dominated all four communities. Barnacles were the only other species still being able to coexist with mussels. Effects of simulated predation disappeared fast. Thus, in the absence of predation on blue mussels, M. edulis within a few months dominates available space, and diversity of the benthic community is low. In contrast, when mussel dominance is controlled by specific predators, more species may persist and diversity remains high

Description: Slope failure along the Costa Rica convergent margin commonly results from steepening of the continental slope above underthrust relief on the subducting plate. The 50-km-wide prehistoric Nicoya Slump was a big event that was followed by small slides from its headwall. Estimated maximum wave height above the slide is 27 m. The headwall occurs along a tectonized and unstable zone that extends northwest. An expected great earthquake in the adjacent Nicoya seismic gap could trigger future tsunamigenic landslides along this zone. The central Nicaragua slope, where the 1992 tsunamigenic earthquake occurred, has failed from steepening by tectonic erosion and perhaps subducting relief. The steep middle slope displays several large slide scars, each of which had the potential to generate a 6–7-m-high wave. A relation between the youngest slide and the 1992 earthquake is uncertain. Principal causes of landslides off Middle America were tectonic steepening and elevated fluid pressure. A mid-slope tectonized zone off Costa Rica allowed detachment of a huge slump involving the entire lower slope to the plate boundary. It may pose a hazard during rupture of the Nicoya locked zone.

Description: Polymetallic sulfide-sulfate mineralization enriched in Pb-Ag-As-Sb-Hg occurs in the Bransfield Strait, a late Tertiary-Quaternary marginal basin close to the Antarctic Peninsula. The mineralization is associated with bimodal volcanism and pelagic and volcaniclastic sediment in rifted continental crust. Hydrothermal precipitates have been recovered from two shallow (1,050–1,000 m water depth) submarine volcanoes (Hook Ridge and Three Sisters) in the Central Bransfield Strait. Mineralization at Hook Ridge consists of polymetallic sulfides, massive barite, and pyrite and marcasite crusts in semilithified pelagic and volcaniclastic sediment. Native sulfur commonly infills void space and cements the volcaniclastic sediment. The polymetallic sulfides are dominated by sphalerite with minor galena, enargite, tetrahedrite-tennantite, pyrite, chalcopyrite, and traces of orpiment cemented by barite and opal-A. The presence of enargite at Hook Ridge, the abundance of native sulfur, and the low Fe content of sphalerite indicate a high sulfur activity of the hydrothermal fluids responsible for mineralization. The sulfur isotopic composition of Hook Ridge precipitates documents the complexity of the sulfur sources in this hydrothermal system with variable influence of biological activity and possibly magmatic contributions. Homogenization temperatures and salinities of fluid inclusions in barite and opal-A suggest that boiling may have affected the hydrothermal fluids during their ascent. The discovery of massive barite-silica precipitates at another shallow marine volcano (Three Sisters volcano) attests to the potential for hydrothermal mineralization at other volcanic edifices in the area. The characteristics of the mineralization in the Bransfield Strait with rifting of continental crust, the presence of bimodal volcanism, including highly evolved felsic volcanic rocks, the association with sediments, and the Pb-Ag-As-Sb-Hg enrichment are similar to the setting of massive sulfide deposits in the Okinawa Trough, and distinct from those of sediment-dominated hydrothermal systems such as Escanaba Trough, Middle Valley, and Guaymas Basin. The geological setting of the Bransfield Strait is also broadly similar to that of some of the largest volcanogenic massive sulfide deposits in the ancient record, such as the Iberian Pyrite Belt.

Description: We present evidence for the origin of the Lyngen Gabbro of the Ordovician Lyngen Magmatic Complex in Troms, Northern Norway. The two magmatic suites of the Lyngen Gabbro strike parallel NNE-SSW, and have distinct magmatic signatures. We define these signatures by using major and trace-element analyses together with selected major- and trace-element mineral analyses and 143Nd/144Nd-isotope whole-rock analyses of gabbroic to tonalitic plutonic rocks from seven detailed cross-sections from this large gabbro-complex. The Western suite of the Lyngen Gabbro precipitated from magma that may have been derived from the same system as the associated volcanic rocks. The gabbros have high An-content (An〉90) of their plagioclases relative to co-existing mafic minerals. Together with somewhat high ɛNd(t) values (+6), this implies that the parental magmas were hydrous tholeiites similar to those found in back arc basins today. The Eastern suite, on the other hand, consist of cumulates that were precipitated from melts resembling those of ultra-depleted high-Ca boninitic magmas found in fore-arcs. Extremely high-An plagioclases (An〉95) co-exist with evolved mafic minerals and oxides, and the ɛNd(t) values are lower (+4) than in the Western suite. The Eastern suite has no volcanic counterpart, but dikes intersecting the suites have compositions that possibly represent its parental magma. The oceanic Rypdalen Shear Zone generally separates the two suites in the north, but several non-tectonic transitions from boninitic to tholeiitic signatures southwards advocate that the magmatism happened concurrently. The magmatic proximity between the suites, the hydrous magmatism and the absence of a silicic or calc-alkaline mature arc section, suggests that the Lyngen Gabbro formed in the Iapetus Ocean under conditions presently found in incipient arcs later emplaced as outer arc highs.

Description: Holocene Pelado, Guespalapa and Chichinautzin monogenetic scoria cones and associated lava flows located within the Sierra del Chichinautzin Volcanic Field (SCVF) at the southern margin of Mexico City were mapped and sampled for mineralogical and chemical analyses. With the exception of Parı́cutin volcano in western Mexico, few scoria cones in the Trans-Mexican Volcanic Belt have ever been sampled in greater detail. Chemical analyses of rocks indicate that mafic products (e.g. Guespalapa and Chichinautzin) from individual volcanoes in the Sierra del Chichinautzin are characterized by substantial chemical variability, whereas high-silica andesite volcanoes (e.g. Pelado) are very uniform in composition. These findings have important bearings for regional tephrochronology. As a whole, rock compositions form a continuous coherent calc–alkaline suite, explicable by polybaric fractional crystallization±assimilation associated with successive stagnation at different depths along the ascent path. Trace element and Sr–Nd isotope analyses point toward a 〈1-km-scale heterogeneous (enriched/depleted) mantle wedge underneath the SCVF. The recently proposed plume-origin for these rocks is not in accord with our data. Instead, magma origin is discussed in relation to the tectonically complex subduction process of the oceanic Cocos Plate underneath the continental North American Plate.

Description: Nabukelevu volcano (805 m) is a small (ca. 3.4 km3) hornblende/biotite–andesite dome–breccia complex. It is the youngest in a Plio–Pleistocene series of volcanoes related to a presently inactive subduction zone in southern Fiji. We present new evidence of up to four Holocene eruption episodes from this volcano, with onshore evidence of the latest activity post-1686±40 years BP, and offshore evidence of tephra falls between 2250±70 and 780±50 years BP. Scoriaceous pyroclastic flow deposits of one eruptive episode contain pottery fragments, presumably entrained from habitation areas during emplacement. Like many composite edifices in moist climates, Nabukelevu is prone to failure, the propensity in this case exacerbated by up to three edifice-cutting fault zones. The fault-induced weak and saturated zones have been the focus of repeated edifice failure through late Holocene debris avalanches of between 10–100 million m3. Many of these avalanches entered the sea, and these or additional submarine failures of the lower island flanks have led to emplacement of at least one major late Holocene submarine mass-flow deposit with distinctive mineralogy in the Suva Basin to the north. Two of the debris avalanches dated at post-2350±140 and post-1750±60 years BP apparently inundated local habitation areas, and the deposits incorporate pottery and human remains. A widespread local legend describing catastrophic events on Nabukelevu corresponds in content with geologic findings to provide additional evidence of a late Holocene eruptive and debris avalanche disaster on Kadavu during the latter part of the last ca. 2000 years of human occupation, possibly as recent as between AD 1630 and 1680. The present hazardscape of the Nabukelevu area includes common landslides induced by frequent earthquake swarms and cyclones. Larger edifice failures, possibly related to volcanism or fault movement, have the potential to create local tsunami, which under favourable conditions could reach areas near Fiji’s capital, Suva, 110 km to the north.

Description: Rising atmospheric CO2 and deliberate CO2 sequestration in the ocean change seawater carbonate chemistry in a similar way, lowering seawater pH, carbonate ion concentration and carbonate saturation state and increasing dissolved CO2 concentration. These changes affect marine plankton in various ways. On the organismal level, a moderate increase in CO2 facilitates photosynthetic carbon fixation of some phytoplankton groups. It also enhances the release of dissolved carbohydrates, most notably during the decline of nutrient-limited phytoplankton blooms. A decrease in the carbonate saturation state represses biogenic calcification of the predominant marine calcifying organisms, foraminifera and coccolithophorids. On the ecosystem level these responses influence phytoplankton species composition and succession, favouring algal species which predominantly rely on CO2 utilization. Increased phytoplankton exudation promotes particle aggregation and marine snow formation, enhancing the vertical flux of biogenic material. A decrease in calcification may affect the competitive advantage of calcifying organisms, with possible impacts on their distribution and abundance. On the biogeochemical level, biological responses to CO2 enrichment and the related changes in carbonate chemistry can strongly alter the cycling of carbon and other bio-active elements in the ocean. Both decreasing calcification and enhanced carbon overproduction due to release of extracellular carbohydrates have the potential to increase the CO2 storage capacity of the ocean. Although the significance of such biological responses to CO2 enrichment becomes increasingly evident, our ability to make reliable predictions of their future developments and to quantify their potential ecological and biogeochemical impacts is still in its infancy.

Description: A new optical instrument for the investigation of submarine fluid flows based on a ‘schlieren’ technique was developed and successfully deployed at cold seep sites. With this application it is possible to visualize the discharge and distribution of fluids in the ambient bottom water and to resolve microstructures and mixing processes at a scale of centimeters. The system is sensitive to small refractive index anomalies caused by temperature and salinity variations. Density anomalies of Δσt=0.049 are detectable evaluated by in-situ temperature variations of ΔT=0.1°C and salinity variations of ΔS=0.045 psu. In flume experiments the smallest detectable density variation was even lower with Δσt=0.023. The technique has been successfully applied in two different environments. First field experiments were performed to observe submarine groundwater discharge in Eckernförde Bay (western Baltic Sea) at shallow water depths. Subsequently, the ‘schlieren’ technique was successfully brought to a cold seep location at the Cascadia convergent margin (800 m water depth). The discharge of fluids was recorded in both field experiments which enabled a qualitative seep site identification.

Description: All four naturally occurring radium isotopes (223Ra, 224Ra, 226Ra, 228Ra) and 222Rn in the groundwater affected Eckernförder Bay (EB) of the Baltic Sea (Germany) were measured using alpha-spectrometry and liquid scintillation (LS) counting. The applied analytical methods are optimally adapted for extensive field surveillance of short-lived radiotracers. Dispersive physical mixing acting over time scales on the order of days is responsible for the distribution of 223Ra, 224Ra and 222Rn in EB. The distribution of these natural tracers is controlled by the strength of the sedimentary source, the influence of direct groundwater input, the dispersive mixing coefficient in the water column and their radioactive decay. Using a simple one-dimensional transport model, the distribution of 224Ra near the sea floor can be described with a horizontal dispersivity in the range between 100 to 5×101 m2 s−1. From the inventory of 222Rn (72.4±7.4 Bq m−2) in the EB, the groundwater discharge rate is estimated to be 〈1.7 m3 s−1. In order to balance the inventory of 223Ra (0.52±0.22 Bq m−2) and 224Ra (6.46±2.6 B qm−2) a source other than groundwater seepage has to be responsible for almost all of the 224Ra and 223Ra inventory of the EB. Diffusion from sediments seems to be the major source for short-lived Ra isotopes in the lower water column of EB.

Description: A method for direct measurement of the natural 10Be/9Be ratio in a sample by AMS is presented. Samples of 100 ng of Be with 10Be concentrations orders of magnitude higher than in conventional 10Be AMS samples were produced without the addition of 9Be carrier and analysed using the accelerator secondary ion mass spectrometry (Accelerator SIMS) source of the PSI/ETH AMS facility. Special mounting techniques and the analysis procedure using a focussed Cs+ beam of up to 600 nA and beam spot diameter of 100 μm are described. The results of measurements on two test samples from Pacific ferromanganese crust D11–1 are presented and compared with similar measurements by conventional secondary ion mass spectrometry (SIMS). Background measurements at a level of ∼5 × 10−11 indicate that ratios of a few times 10−10 could be measured to a precision of ∼10%. PACS 29.17.+w; 29.30.−h; 82.80.Ms; 89.60.+x

Description: Most conceptual marine eutrophication models predict that ephemeral and epiphytic macroalgae will become substantially more abundant with increasing nutrient richness. This expectation is based on the fact that most of these fast-growing algae possess high requirements for inorganic N and P and, therefore, suffer from nutrient limitation under nutrient poor conditions. We tested the hypothesis that nutrient enrichment will stimulate the abundance of ephemeral macroalgae by studying the abundance and species composition of these algae on several types of substrata along an artificial nutrient gradient. The total biomass of ephemeral macroalgae differed considerably among different types of substrata. The total ephemeral load was significantly higher on consolidated substrata than on large perennial algae, but we were unable to detect any systematic increase in the abundance of these ephemerals with increasing nutrient richness. We found, however, indications that the composition of the ephemeral assemblage changed with nutrient richness. Hence, corticated filamentous algae (mostly red algae) were more abundant at low nutrient richness while thin foliose algae (mainly green species) tended to become more abundant with increasing nutrient richness in most of the surveyed assemblages.

Description: A Modern Analog Technique (MAT5201/31) has been applied to fossil diatom assemblages to provide down-core estimates of February sea-surface temperatures (SSTs) and of sea ice duration over the past 220 000 years at 56°40′S, 160°14′E. At the core location, sea ice progression lagged the SST drop by ∼1 ka at interglacial–glacial transitions, and sea ice retreat was almost synchronous to the SST increase at glacial–interglacial terminations. Sea ice increased continuously during glacial periods to reach its maximum extent at the end of glacial times, although SSTs were almost constant during glacials. This indicates that SSTs are the major parameter determining the advance and retreat of sea ice at transitions, but that the sea ice advance during glacial conditions may be related to positive feedbacks of the ice on albedo, air temperature and meridional wind stress. The strong correlation (r=0.75) between sea ice duration at the core location and the Vostok CO2 record argues for a control of Antarctic sea ice extent on atmospheric CO2 concentration via the modification of the ocean-to-atmosphere gas balance.

Description: The most important archive of Earth’s climate change through geologic history is the sedimentary rock record. Rhythmic sedimentary alternations are usually interpreted as a consequence of periodic variations in the orbital parameters of the Earth. This interpretation enables the application of cyclostratigraphy as a very precise chronometer, when based on the assumption that orbital frequencies are faithfully recorded in the sedimentary archive. However, there are numerous uncertainties with the application of this concept. Particularly in carbonates, sediment properties such as mineralogical composition and fossil associations are severely altered during post-depositional alteration (diagenesis). We here point out that the assumption of a 1:1 recording of orbital signals in many cases is questionable for carbonate rhythmites. We use computer simulations to show the effect of diagenetic overprint on records of orbital signals in the carbonate record. Such orbital signals may be distorted in terms of frequency, amplitude, and phase by diagenetic processes, and cycles not present in the insolation record may emerge. This questions the routine use of carbonate rhythmites for chronostratigraphic dating

Description: A numerical model was applied to investigate and quantify the biogeochemical processes fueled by the expulsion of barium and methane-rich fluids in the sediments of a giant cold-seep area in the Derugin Basin (Sea of Okhotsk). Geochemical profiles of dissolved Ba2+, Sr2+, Ca2+, SO42−, HS−, DIC, I− and of calcium carbonate (CaCO3) were fitted numerically to constrain the transport processes and the kinetics of biogeochemical reactions. The model results indicate that the anaerobic oxidation of methane (AOM) is the major process proceeding at a depth-integrated rate of 4.9 μmol cm−2 a−1, followed by calcium carbonate and strontian barite precipitation/dissolution processes having a total depth-integrated rate of 2.1 μmol cm−2 a−1. At the low seepage rate prevailing at our study site (0.14 cm a−1) all of the rising barium is consumed by precipitation of barite in the sedimentary column and no benthic barium flux is produced. Numerical experiments were run to investigate the response of this diagenetic environment to variations of hydrological and biogeochemical conditions. Our results show that relatively low rates of fluid flow (〈∼5 cm a−1) promote the dispersed precipitation of up to 26 wt% of barite and calcium carbonate throughout the uppermost few meters of the sedimentary column. Distinct and persistent events (several hundreds of years long) of more vigorous fluid flow (from 20–110 cm a−1), instead, result in the formation of barite-carbonate crusts near the sediment surface. Competition between barium and methane for sulfate controls the mineralogy of these sediment precipitates such that at low dissolved methane/barium ratios (〈4–11) barite precipitation dominates, while at higher methane/barium ratios sulfate availability is limited by AOM and calcium carbonate prevails. When seepage rates exceed 110 cm a−1, barite precipitation occurs at the seafloor and is so rapid that barite chimneys form in the water column. In the Derugin Basin, spectacular barite constructions up to 20 m high, which cover an area of roughly 22 km2 and contain in excess of 5 million tons of barite, are built through this process. In these conditions, our model calculates a flux of barium to the water column of at least 20 μmol cm−2 a−1. We estimate that a minimum of 0.44 × 106 mol a−1 are added to the bottom waters of the Derugin Basin by cold seep processes, likely affecting the barium cycle in the Sea of Okhotsk.

Description: Copepoda (Calanus finmarchicus n=1,722, Paraeuchaeta norvegica n=1,955), Hyperiidae (n=3,019), Euphausiacea (Meganyctiphanes norvegica n=4,780), and the fishes Maurolicus muelleri (n=500) and Pollachius virens (n=33) were collected in the Norwegian Deep (northern North Sea) during summer 2001 to examine the importance of pelagic invertebrates and vertebrates as hosts of Anisakis simplex and their roles in the transfer of this nematode to its final hosts (Cetaceans). Third stage larvae (L3) of A. simplex were found in P. norvegica, M. muelleri and P. virens. The prevalence of A. simplex in dissected P. norvegica was 0.26%, with an intensity of 1. Prevalences in M. muelleri and P. virens were 49.6% and 100.0%, with mean intensities of 1.1–2.6 (total fish length ≥6.0–7.2) and 193.6, respectively. All specimens of C. finmarchicus and M. norvegica examined were free of anisakid nematode species and no other parasites were detected. P. norvegica, which harboured the third stage larvae, is the obligatory first intermediate host of A. simplex in the investigated area. Though there was no apparent development of larvae in M. muelleri, this fish can be considered as the obligatory second intermediate host of A. simplex in the Norwegian Deep. However, it is unlikely that the larva from P. norvegica can be successfully transmitted into the cetacean or pinniped final hosts, where they reach the adult stage. An additional growth phase and a second intermediate host is the next phase in the life cycle. Larger predators such as P. virens serve as paratenic hosts, accumulating the already infective stage from M. muelleri. The oceanic life cycle of A. simplex in the Norwegian Deep is very different in terms of hosts and proposed life cycle patterns of A. simplex from other regions, involving only a few intermediate hosts. In contrast to earlier suggestions, euphausiids have no importance at all for the successful transmission of A. simplex in the Norwegian Deep. This demonstrates that this nematode is able to select definite host species depending on the locality, apparently having a very low level of host specificity. This could explain the wide range of different hosts that have been recorded for this species, and can be seen as the reason for the success of this parasite in reaching its marine mammal final hosts in an oceanic environment.

Description: The distribution of deposits, sediment transport pathways and processes on the lower Monterey Fan channel and channel-mouth lobe (CML) are studied through the integration of GLORIA and TOBI sidescan sonar data with 7-kHz subbottom profiler records and sediment cores for ground-truthing. The lower Monterey channel is characterised by an up to 30-m-deep channel with poorly developed levees and alternating muddy and silty muddy overbank deposits. The channel is discontinuous, disappearing where gradients are less than about 1:350. Ground-truthing of the large CML shows that the entire CML is characterised by widespread deposits of generally fine sand, with coarser sand at the base of turbidites. Sand is particularly concentrated in finger-like areas of low-backscatter intensity and is interpreted as the result of non-turbulent sediment-gravity flows depositing metres thick massive, fine sand. TOBI sidescan sonar data reveal recent erosional features in the form of scours, secondary channels, large flow slides, and trains of blocks at the distal end of the CML. Erosion is probably related to increasing gradient as the CML approaches Murray Fracture zone and to differential loading of sandy submarine fan deposits onto pelagic clays. Reworking of older flow slides by sediment transport processes on the lobe produces trains of blocks that are several metres in diameter and aligned parallel to the flow direction.

Description: The sprat (Sprattus sprattus balticus S.) population size in the Bornholm Basin, one of the major spawning areas of the species in the Baltic Sea, was estimated with the daily egg production method. Egg abundance, stock structure, sexual and gonadal maturation, spawning frequency and the batch fecundity of sprat throughout the sprat spawning season were simultaneously investigated to obtain an estimate of the population size at spawning time. The results confirmed the population estimate from a hydroacoustic survey, but contrasted spatially down-scaled results from an area dis-aggregated stock assessment model applying fisheries statistics. Conflicting results from both latter methods have previously hampered quantitative studies on recruitment processes of sprat and cod, for example the estimation of predation pressure on cod eggs by sprat. The egg production method did not allow an estimation of the population size of sprat in the entire assessment area larger than the Bornholm Basin, i.e. ICES sub-division 25. This failure is caused by sprat spawning activity outside the Bornholm Basin, not covered by the standard egg surveys and has consequences for the general applicability of available egg abundance time series to retrospectively estimate sprat stock development.

Description: We used marine phytoplankton from mesocosms seeded with different zooplankton densities to study the impact of mesozooplankton on phytoplankton nutrient limitation. After 7 d of grazing (copepod mesocosms) or 9 d (appendicularian mesocosms) phytoplankton nutrient limitation was studied by enrichment bioassays. After removal of mesozooplankton, bioassay bottles received either no nutrients, phosphorus or nitrogen alone, or a combination of nitrogen and phosphorus and were incubated for 2 d. Phytoplankton reproductive rates in the bottles without nutrient addition were calculated after correction for grazing by ciliates and indicated increasing nitrogen limitation with increasing copepod abundance. No nutrient limitation was found in the appendicularian mesocosms. The increase of nutrient limitation with increasing copepod density seems to be mainly the result of a trophic cascade effect: Copepods released nanoplankton from ciliate grazing pressure, and thereby enhanced nitrogen exhaustion by nanophytoplankton and reduced nitrogen excretion by ciliates. Nitrogen sequestration in copepod biomass, the mechanism predicted by the ecological stoichiometry theory, seems to have been a weaker effect because there was only little copepod growth during the experiment.

Description: Mg-calcite-cemented bioturbation traces, glendonite aggregates of idiomorphic, bi-pyramidal crystals and porous, amber-colored carbonate concretions were recovered from a methane-dominated cold vent area in 380 m water depth at the northern Sakhalin Slope, Sea of Okhotsk. Bioturbation traces consist of Mg-calcite cemented sediment with δ13C values between −37 and −46‰ PeeDee Belemnite (PDB), which implicate methane as the carbon source. Glendonite, a calcite pseudomorphosis after ikaite (CaCO3·6H2O), and amber-colored concretions are both composed of varying amounts of calcite and Mg-calcite with δ13C values between −19 and −34‰ PDB. Isotope analyses of an ikaite crystal recovered in the vicinity reveals δ13C values between −20‰ and −22‰ PDB indicating organic matter as the carbon source. Microscopic investigations of glendonites and amber-colored concretions show a porous fabric of a primary calcite phase that is overgrown by a secondary Mg-calcite cement. As ikaite pseudomorphs to porous calcite and as carbon isotope values are the same for the ikaite and the high end member values of glendonite samples, the primary calcite phase is suggested to be a former ikaite phase. Because they share the equal color, fabric, mineral and isotopic composition with glendonites, the amber-colored concretions are also suggested to represent calcite that transformed from ikaite. A mixture of pseudomorph calcite (δ13C −20‰ PDB), which originally formed as ikaite from degraded organic matter, and Mg-calcite (δ13C −43‰ PDB), which crystallized due to the anaerobic oxidation of methane, can explain the varying carbon isotope data of the glendonites and the amber-colored concretions. The growth of ikaite, the transformation of ikaite to calcite, and the crystallization of Mg-calcite indicate changing geochemical conditions within a cold vent environment at different times. Ideal conditions for the ikaite formation are given during the establishment of a cold vent site when upward-migrating, methane-rich fluids enhance the anaerobe decomposition of organic matter, which again increases the phosphate and alkalinity concentrations near the sediment surface. Lower rates of organic matter decomposition during on-going venting decrease these high phosphate but also sulphate concentrations and allows other carbonate phases as Mg-calcite to form. This additional carbonate precipitation and the ikaite formation itself lower the high alkalinity and destabilize ikaite, which pseudomorphs to porous calcite. Triggered by the further upward-shifting SO4/H2S boundary and increasing methane oxidation rates, the typical cold vent methane-derived carbonate genesis takes place, which cements the sediment pore space and induces the secondary Mg-calcite crystallization within the glendonite fabric. Taking this scenario into account, ikaite formation should be a common process in the beginning of methane-dominated vent activity at cold bottom water temperatures; glendonite pseudomorphs can be assumed to represent a typical manifestation at fossil and recent cold vents at high latitudes.

Description: Participatory rural appraisal (PRA) methods and philosophies were trialed in a volcanic risk management planning and awareness activity for Savo Island, a historically highly destructive volcano in the Solomon Islands. Through a combination of methods we tried to combine the roles of facilitators and educators, and to involve the input of all stakeholders (from community to national government) in the process of volcanic risk management. The PRA approach was an ideal way to address the fundamental differences in outlook, education, needs, and roles of individuals and groups involved or affected. It was also an important catalyst to Savo island- or community-based planning initiatives, which are arguably the most important step toward the preparedness of the 2500 inhabitants of the island for any future destructive volcanic activity. We adapted almost every tenet of the PRA philosophy through inexperience, self-perceived importance and desire to combine both scientific and traditional views for Savo volcanic risk management planning. Nevertheless, what emerged from our experiences was an idea of how fundamentally well suited many PRA approaches are to initiating dialogue within diverse stakeholder groups, and deriving combined scientific/geologic and local/community risk assessments and mitigation action plans. The main challenge remaining includes increasing the involvement or voice of less powerful community members (women, youth, non-landowners) in risk management decision-making in such male-dominated hierarchical societies.

Description: Spatially closely associated gabbros and eclogites of central Zambia represent relics of subducted oceanic crust in a suture zone. The eclogites, which formed at 630–690 °C and 2.6–2.8 GPa, yield Lu–Hf ages between 607±14 and 659±14 Ma, suggesting that subduction was active for at least 24 Myr. The trace element- and isotope compositions of the gabbros and eclogites range from those of incompatible-element depleted gabbros from the lower oceanic crust to those of enriched ocean–island basalts. Several eclogites display a large fractionation of the light rare earth elements from heavy rare earth- and high field strength elements, an effect that cannot be of magmatic origin but must have resulted from the passage of fluids through the rocks during metamorphism. In some samples, fluid pathways are marked by veins of eclogite facies minerals. Garnet-whole rock ages based on the Sm–Nd (relatively mobile) and Lu–Hf (relatively immobile) systems are identical, consistent with light rare earth elements being fractionated during eclogitization. Modeling using fluid–mineral partition coefficients suggests that the fractionated rocks have reacted with an amount of fluid equal up to 80% of their mass. The most likely source for such a large volume of fluid is the serpentinized lithospheric mantle of the subducting slab. The Zambian eclogites and their veins represent relict fluid pathways through subducted oceanic crust and provide direct evidence for channelized fluid flow and element transport within a slab. The transformation of dry, metastable slab gabbros to eclogites upon fluid-infiltration, accompanied by the transport of fluid-mobile elements, could be responsible for generating the slab component in arc magmas.

Description: Barium (Ba), aluminium (Al), and zirconium (Zr) were measured in sediment trap material deployed at two margin settings of the NE Atlantic: the Bay of Biscaye at Goban Spur and the NW Iberian Margin. The Particulate Organic Carbon (POC)/Ba ratios of the trapped material in both margin environments are clearly higher compared to the open ocean. Although lateral advection of POC may partly explain these higher POC/Ba ratios for margin systems, it is clear that the yield of authigenic particulate Ba during organic matter degradation in the water column is lower in margin environments. In order to assess export production in margin settings we optimised transfer functions based on trapped Ba fluxes that were originally elaborated for open ocean settings. Calculations of export production based on trapped Ba flux and POC/Ba ratio were compared with calculations based on trapped POC flux only. Export production based on Ba flux show greater internal consistency amongst traps along the same mooring, suggesting that this approach has advantages over the one based on POC flux only. Estimated export productions are of the same order of magnitude as estimates of new production, but systematically fall short of the latter. This systematic discrepancy needs further investigation.

Description: Three classes of bottom simulating reflectors (BSR) cross-cut the post-breakup sediments of the mid-Norwegian margin. The first class is caused by free gas at the base of the pressure- and temperature-dependent gas hydrate stability zone. The second class of BSR is caused by the diagenetic transition from opal A to opal CT. The third class of BSR is always observed underneath the opal A/opal CT transition, but heat flow data and the amplitude characteristics of this arrival exclude one of the known silicate diagenetic transitions or gas hydrates as the explanation for this reflector. ODP Site 643 drilling results from the Vøring Plateau suggest two possible processes as the reason for this third BSR: (a) smectite illite conversion or (b) a sudden increase in the abundance of authigenic carbonates. The genesis of both is pressure- and temperature-dependent and could potentially result in a cross-cutting seismic reflector. The data are not conclusive as to which process is causing the third class of observed BSR.

Description: The carbon to nitrogen ratio of net community production, (C:N)NCP, during the spring phytoplankton bloom in the temperate northeast Atlantic is estimated from a re-analysis of published data from the North Atlantic Bloom Experiment (NABE, 1989) and a north–south transect along 20°W carried out in 1996. The average seasonally integrated cumulative (C:N)NCP ratio between winter mixing and the end of the diatom bloom ranges between 5.9±0.4 (1996 study) and 6.9±0.9 (NABE) and is not significantly different (p〉0.1) from the ‘Redfield’-C:N ratio. The instantaneous ΔDIC:ΔNO3 ratio, uncorrected for CO2 air–sea exchange and CaCO3 production, during the diatom bloom is 8.0±0.9, which is significantly (p〈0.01) lower than previous estimates (9.9±0.7) drawn from the same data sets. This difference reflects regional variation in pre-formed winter total CO2 and nitrate concentrations, which is corrected for in the data analysis presented here. The instantaneous (C:N)NCP, including air–sea exchange and CaCO3 production correction during the diatom bloom is 7.3±0.7. DIC and nitrate changes between winter pre-formed values and observations early during the NABE diatom bloom study indicate a lower instantaneous ΔDIC:ΔNO3 of 3.7–5.9, and an elevated NO3:Si(OH)4 uptake ratio of about 2.9 early in the growth season. Following the diatom bloom, a second bloom, dominated by non-siliceous phytoplankton, takes up carbon and nitrate largely in Redfield proportion; the cumulative (C:N)NCP ratio integrated until nitrate depletion ranges from 7.2±0.9 (NABE) to 7.9±0.6 (1996 study). It is concluded that significantly elevated cumulative (C:N)NCP in the temperate and subarctic Northeast Atlantic, which have been reported elsewhere, generate from carbon overconsumption during summer, not from spring bloom new production. Consequences for carbon export into the deep ocean are discussed.

Description: A planar problem of nonlinear transverse oscillations of the surface (warm) front of a finite width is considered within the framework of a reduced-gravity model of the ocean. The source of oscillations is the departure of the front from its geostrophic equilibrium. When the current velocity is linear in the horizontal coordinate and the front's depth is quadratic in this coordinate, the problem is reduced to a system of four ordinary differential equations in time. As a result, the solution is obtained in a weakly nonlinear approximation and strongly nonlinear oscillations of the front are studied by numerically solving this system of equations by the Runge-Kutta method. The front's oscillations are always superinertial. Nonlinearity can lead to a decrease or increase in the oscillation frequency in comparison with the linear case. The oscillations are most intense when the current velocity is disturbed in the direction of the front's axis. A weakly nonlinear solution of the second order describes the oscillations very accurately even for initial velocity disturbances reaching 50% of its geostrophic value. An increase in the background-current shear leads to the damping of oscillations of the front's boundary. The amplitude of oscillations of the current velocity increases as the intensity of disturbances increases, and it is relatively small if background-current shears are small or large.

Description: The abundance of transparent exopolymer particles (TEP) was determined in the northeast Atlantic Ocean (40–55°N, ∼20°W) during several cruises from June to November 1996. An accumulation of TEP in the water column was observed at bloom and post-bloom sites along a 20°W transect in June/July (maximum concentration: 124 μg Gum Xanthan equivalents (Xeq.) l−1), but concentrations were uniformly low (mean concentration: 28.5±10.2 μg Xeq. l−1) during autumn at the BIOTRANS site (47°N, 20°W). TEP concentrations in the open northeast Atlantic were considerably lower than previously published values from coastal sites. However, during June/July TEP:Chl a (weight/weight) ratios were comparable to values at coastal seas. It is suggested that phytoplankton production modulates TEP concentration in the open ocean as it does in coastal systems. TEP contributed significantly to the organic carbon pool as derived from the ratio TEP-C:POC, in summer (mean percentage: 17±7.5; w/w), as well as in autumn (mean percentage: 18±11, w/w). The potential influence of TEP on particle coagulation rates in the northeast Atlantic was assessed from estimates of their influence on particle stickiness and on particle volume concentrations. This indicated that TEP may be essential for initiating particle aggregation at low biomass concentrations, typical for open ocean sites.

Description: U-series dating can be an effective means to obtain accurate and precise ages on Quaternary carbonates. However, most samples require a correction for U and Th in admixed detritus. This complication is often addressed through generation of U-Th isochrons, requiring analyses of several coeval samples. In addition, presence of water-derived (hydrogenous) Th in the carbonate can cause inaccuracies in isochron ages. This study reports a high-resolution U-series chronology of sediments deposited by Lake Lisan, the last glacial precursor of the Dead Sea. The strategy employed combines multiple measurements from a few stratigraphic heights and fewer analyses from many heights in a single described and measured section. The resulting chronology is based on ages at 22 heights in a ∼40-m-thick section covering the interval of ∼70–14 calendar ka BP. The effects of admixed detritus are evaluated using trace elements. Nearly pure aragonite samples, indicated by very low abundances of insoluble elements such as Nb and Zr, were found to contain hydrogenous Th, which causes the uncorrected U-230Th age of a modern sample to be ∼2.5 ka. Nevertheless, accurate ages have been obtained by correcting for the detrital and aqueous interferences. The resulting ages are in stratigraphic order, and their accuracy is evidenced by consistency of Lisan Formation U-series and 14C ages with the coral-based calendar-radiocarbon age calibration. The U-Th ages provide a context to unravel the limnological history of Lake Lisan. Boundaries between the Lower, Middle, and Upper stratigraphic units correspond to the MIS 4/3 and 3/2 transitions, respectively. During MIS 2 and 4 the lake generally showed a stable two-layer configuration and a positive fresh-water balance, reflected by deposition of laminated aragonite-detritus. Dry intervals during MIS 2 and 4 are indicated by thick gypsum layers and an inferred depositional hiatus, which are temporally associated with Heinrich events H1 at ∼17 ka and H6 at ∼65 ka, respectively. During MIS 3 the lake level was unstable with intermittent dry periods indicated by abundant clastic layers and a significant hiatus between ∼43–49 ka. Clastic layers are associated with Dansgaard-Oeschger events during MIS 3, and indicate lake level declines during abrupt Northern Hemisphere warmings. Overall, the climate of the Eastern Mediterranean region shows a strong linkage to the Northern Hemisphere climate, with increasing lake size and stability during cold periods, and fluctuations and dessication during warmings and Heinrich events.

Description: Significant sediment–ocean chemical fluxes are produced by the expulsion of sedimentary fluids at continental margins. Although such fluxes could play a role in global geochemical cycles, few quantitative estimates of their global, or even regional, significance exist. We carried out a pore water geochemical study of fluids expelled from the Dvurechenskii mud volcano (DMV) in the Black Sea, with the aim of understanding the role played by mud volcanoes in Black Sea geochemical cycles. The DMV is presently expelling highly saline fluids particularly enriched in geochemically important species such as Li+ (1.5 mM), B (2.17 mM), Ba2+ (0.57 mM), Sr2+ (0.79 mM), I (0.4 mM) and dissolved inorganic nitrogen (DIN) (22 mM). A combination of geochemical indicators shows that this geochemical signature was acquired via organic matter and silicate alteration processes in the subsurface down to 3-km depth and near-surface gas hydrate formation. We used a simple transport model to estimate the benthic fluxes of these solutes at the DMV. Our results show that the DMV is expelling fluids at a rather low seepage rate (8–25 cm year−1) resulting in a total water flux of 9.4×10−5 km3 year−1. This gentle regime of fluid expulsion results in Li+, B, Sr2+, I and DIN fluxes between 3.8×104 and 2.1×106 mol year−1. Surface biogeochemical processes affect the benthic fluxes of Ba2+ such that the deep Ba2+ flux is completely consumed through the precipitation of authigenic barite (BaSO4) in surface sediments. The Black Sea I cycle is likely to be affected by mud volcanism, if the 50 known Black Sea mud volcanoes share the rather sluggish activity of the DMV. Mud volcano fluxes of Li, B, Sr and DIN, instead, are too small to affect Black Sea geochemical cycles. On a global scale, mud volcanism could play a role in the marine cycles of Li, B, Sr, I and DIN if current estimates of mud volcano abundance are correct.

Description: Coccolithophores first became significant participants in the carbonate cycle in the Jurassic, but throughout the Jurassic they were largely restricted to shelf and epeiric sea environments. They spread into the open ocean in the Cretaceous, and with this became a major factor in governing the carbonate cycle in the sea. With the development of dissolution-resistant forms, such as Watznaueria barnesae, the coccolithophores perturbed the carbonate system and switched the major site of carbonate deposition from shallow seas to the deep ocean. Several major evolutionary steps in the development of the coccolithophores have forced further changes in the carbon cycle, favoring the deep sea as a site of carbonate deposition. Samples of recent coccolith assemblages from bottom sediments differ from those of living coccolithophores in surface waters. Many of the coccoliths of more delicate species, particularly holococcoliths, are dissolved in the water column or at the sediment surface and are only rarely preserved as fossils. They, along with the pteropods, form an important part of the shallow carbonate cycle. There appears to be a continuous gradation in the level of susceptibility of coccoliths to dissolution, from forms that dissolve in the near-saturated waters of the surface ocean to those that are among the most dissolution-resistant forms of calcite. This continuous dissolution spectrum is in contrast to the planktic foraminifera, in which dissolution of the tests also occurs in a sequence, but through a much more restricted depth range, the lysocline. Whereas the order of dissolution of planktic foraminifera follows their habitat, with warm-water species being most susceptible and cold-water forms most resistant to dissolution, the order of dissolution of coccoliths appears to be related to phylogeny. The steepness of the coccolith carbonate dissolution gradient appears to have changed over time. In the Oligocene almost pure nannofossil carbonate oozes devoid of terrigenous material were widespread, perhaps reflecting unusual climatic conditions on land. The overall effect of coccolithophore evolution has been to move carbonate deposition to the deep sea, where coccolith oozes accumulate on ocean crust and will ultimately be subducted. Only a fraction of the carbon in the subducted carbonate is returned to the surface through volcanic activity. If their activity were to continue for several hundreds of millions of years the coccolithophores would remove much of the carbon from the surface of the Earth to be emplaced in the mantle.

Description: Gas emissions from mud volcanoes on Sakhalin Island and water-column gas flares arising from cold seeps in the Okhotsk Sea appear to be related. They are likely activated by tectonic movements along the transform plate boundary separating the Okhotsk Sea Plate from the Eurasian and Amur plates. Gas vents (flares) and methane anomalies occur in the waters offshore Sakhalin Island, along with NE-SW-trending mounds and fluid escape structures on the seafloor. The intersection of the NE-striking transverse faults on land with the Central Sakhalin and Hokkaido-Sakhalin shear zones apparently determines the sites of mud volcanoes, a pattern that continues offshore where the intersection with the East Sakhalin and West Derugin shear zones determines the sites of the submarine gas vents.

Description: The distribution and speciation of iron was determined along a transect in the eastern Atlantic sector (6°E) of the Southern Ocean during a collaborative Scandinavian/South African Antarctic cruise conducted in late austral summer (December 1997/January 1998). Elevated concentrations of dissolved iron (〉0.4 nM) were found at 60°S in the vicinity of the Spring Ice Edge (SIE) in tandem with a phytoplankton bloom, chiefly dominated by Phaeocystis sp. This bloom had developed rapidly after the loss of the seasonal sea ice cover. The iron that fuelled this bloom was mostly likely derived from sea ice melt. In the Winter Ice Edge (WIE), around 55°S, dissolved iron concentrations were low (View the MathML source〈0.2nM) and corresponded to lower biological productivity, biomass. In the Antarctic Polar Front, at approximately 50°S, a vertical profile of dissolved iron showed low concentrations (View the MathML source〈0.2nM); however, a surface survey showed higher concentrations (1–3 nM), and considerable patchiness in this dynamic frontal region. The chemical speciation of iron was dominated by organic complexation throughout the study region. Organic iron-complexing ligands ([L]) ranged from 0.9 to 3.0 nM Fe equivalents, with complex stability View the MathML sourcelogKFeL′=21.4–23.5. Estimated concentrations of inorganic iron (Fe′) ranged from 0.03 to 0.79 pM, with the highest values found in the Phaeocystis bloom in the SIE. A vertical profile of iron-complexing ligands in the WIE showed a maximum consistent with a biological source for ligand production and near surface minimum possibly consistent with loss via photodecomposition. This work further confirms the role iron that has in the Southern Ocean in limiting primary productivity.

Description: A DNA fingerprinting method for the characterization of Legionella pneumophila serogroup I strains was established. This method was based on the DNA extraction using Chelex 100 and subsequent PCR analysis using primers under conditions of low stringency. Sixteen single primers were tested for the typing of the 10 epidemiologically unrelated reference strains of L. pneumophila serogroup I as well as patient isolates and environmental strains isolated from the water system of a hospital where patients with legionellosis were treated. In addition, a combination of two primers (Lpm-1 and Lpm-2) originally established for the specific detection of Legionella strains was tested. The PCR results were compared with two further subtyping methods, i.e. monoclonal antibody analysis and pulsed-field gel electrophoresis. The type strains Philadelphia 1, Knoxville 1, Allentown 1, Benidorm 0303E, Bellingham 1, and France 5811 could be distinguished clearly in experiments using all of the primers. Depending on the primer used, Heysham 1 and Oxford 4032E showed different DNA profiles. The strains Olda and Camperdown I were nearly indistinguishable. In contrast, the analysis by PFGE and MAb subtyping revealed distinct types for all 10 reference strains. The discrimination of the patient isolates from two suspected cases of nosocomial legionellosis and environmental isolates was not possible with the 16 single primers used in the study. However, the PCR assay with the combination of Lpm-1 and Lpm-2 as well as the PFGE and MAb analysis were able to differentiate distinct types. The use of the sequence-specific primers under low-stringency annealing conditions allowed both simultaneous gene detection as well as epidemiological typing of Legionella strains.

Description: We provide two new determinations of the oxygen isotopic composition of seawater during the last glacial maximum (LGM). High-resolution oxygen isotopic measurements were made on interstitial waters from Ocean Drilling Program (ODP) Sites 1168 and 1170 in the southeast Indian Ocean sector of the Southern Ocean. We use a diffusion–advection numerical model to calculate the glacial–interglacial change in bottom-water δ18Osw from the pore water δ18O profiles; the first such determinations from this part of the oceans. Statistical analyses of the model runs indicate that Circumpolar Deep Water (CDW) δ18Osw changed by 1.0–1.1±0.15‰ since the last glacial maximum (LGM). Our results are consistent with a previous calculation from a South Atlantic Southern Ocean location (ODP Site 1093) also situated within CDW. The new values determined in this study, together with previous estimates, are converging on a global average Δδ18Osw of 1.0–1.1‰. Using the calculated bottom-water δ18Osw, we have extracted the temperature component from the benthic foraminiferal δ18O record at Sites 1168 and 1170. Since the LGM, bottom waters at these two sites warmed by 2.6 and 1.9°C, respectively. The absolute temperature estimates for the LGM (−0.5°C [Θ=−0.6°C] at Site 1168 and −0.2°C [Θ=−0.4°C] at Site 1170) are slightly warmer than those reported from previous studies using the same technique, but are consistent with more homogenous deep-ocean temperatures during the LGM relative to the modern.

Description: The maximum limits of the Eurasian ice sheets during four glaciations have been reconstructed: (1) the Late Saalian (〉140 ka), (2) the Early Weichselian (100–80 ka), (3) the Middle Weichselian (60–50 ka) and (4) the Late Weichselian (25–15 ka). The reconstructed ice limits are based on satellite data and aerial photographs combined with geological field investigations in Russia and Siberia, and with marine seismic- and sediment core data. The Barents-Kara Ice Sheet got progressively smaller during each glaciation, whereas the dimensions of the Scandinavian Ice Sheet increased. During the last Ice Age the Barents-Kara Ice Sheet attained its maximum size as early as 90–80,000 years ago when the ice front reached far onto the continent. A regrowth of the ice sheets occurred during the early Middle Weichselian, culminating about 60–50,000 years ago. During the Late Weichselian the Barents-Kara Ice Sheet did not reach the mainland east of the Kanin Peninsula, with the exception of the NW fringe of Taimyr. A numerical ice-sheet model, forced by global sea level and solar changes, was run through the full Weichselian glacial cycle. The modeling results are roughly compatible with the geological record of ice growth, but the model underpredicts the glaciations in the Eurasian Arctic during the Early and Middle Weichselian. One reason for this is that the climate in the Eurasian Arctic was not as dry then as during the Late Weichselian glacial maximum.

Description: Methane investigations carried out in the Okhotsk Sea show that the methane flux from the earth’s interior into the water column increased during periods of seismo-tectonic activity between 1988 and 2002. In this case, methane gas hydrates found on the northeast Sakhalin slope may have decomposed due to a reactivation of fault zones. Methane emissions in the Okhotsk Sea generally can be divided into two forms. Firstly, methane vents from decomposing gas hydrates and/or free gas exist below gas hydrate saturated sediments via fault zones, venting into the water column with high bubble concentrations that were recorded by echosounding. These hydro-acoustic anomalies were named “flares”. Methane concentration inside these flares reached 10,000–20,000 nl/l (background methane concentrations in the Okhotsk Sea are less than 90–100 nl/l). Secondly, methane migrates as seepage into the water column from oil- and gas-bearing sedimentary source rocks on the eastern Sakhalin shelf, without showing acoustic anomalies in the water column, probably by filtration and diffusion processes. In these areas methane concentration reached 500–3,000 nl/l. In seismo-tectonically active regions, like the northwestern part of the Okhotsk Sea, many new flares were observed. Their distribution and orientation are usually controlled by fault zones (East Sakhalin Shear Zone in the Okhotsk Sea).