ALBERT

Description: Natural sites in urban spaces can have a key role in citizen well-being, providing fundamental ecosystem services to the population and assuring a multitude of benefits. Therefore, cities should guarantee a number of green areas and their conservation in time as an essential part of urban architecture. In this framework, cooperation between scientists, decision makers and citizens is critical to ensure the enhancement of green public spaces. Social and scientific communities are called to work in a tuned way to combine scientific knowledge and methods to local socio-economic contexts, driven by the values of geoethics. The Bullicante Lake case study, discussed in this work, represents an example of application of geoethical values, such as inclusiveness, sharing, sustainability and conservation of bio- and geodiversity. This urban lake in Rome appeared following illegal excavation works in 1992 and remained closed until 2016 favouring re-naturalization processes. Over time, this site was often threatened by pending actions for building. The aim of this study was to highlight how fruitful cooperation between science and citizens is able to transform a degraded urban area into a place of knowledge, recreation, enjoyment and eco-systemic preservation. Moreover, on the basis of this experience, the authors proposed a generalised approach/strategy to be developed and applied in other contexts. The active involvement of citizens and the cooperation among scientists, artists and institutions were able to redress opportunistic behaviours well by preventing site degradation and its improper use, favouring environmental safeguarding and making possible the site’s recognition as a natural monument. The results of these actions led to the improved quality of citizen life, showing an excellent example of virtuous cooperation between science and society.

Description: Published

Description: 4429

Description: 1TM. Formazione

Description: 2TM. Divulgazione Scientifica

Description: JCR Journal

Description: The Adventure Plateau, located in the NW sector of the Sicilian Channel, experienced several episodes of exposure/erosion and subsequent drowning, with the most recent occurring after the Last Glacial Maximum (LGM). Unlike other parts of the Sicilian Channel, the Adventure Plateau is relatively tectonically stable and is therefore best suitable for reconstructing its coastal configuration before the post-LGM marine transgression. Here, we use high-resolution seismic data to identify and map the palaeo-coastline at the LGM on the basis of the internal architecture of the prograding wedges (i.e., the location of the subaqueous clinoform rollover point) and the erosional markers such as the subaerial unconformities and the wave ravinement surfaces. These data, which show an extreme variability in the palaeo-morphology of the coastal margins of the Adventure Plateau, have been complemented with vintage seismic profiles in order to entirely cover its perimeter. The mapped LGM coastline has then been compared to predictions from glacial isostatic adjustment (GIA) modeling, which considers the horizontal migration of the shorelines in response to sea level rise and to Earth’s rotational and deformational effects associated with deglaciation. The two shorelines (i.e., the coastline derived from the marine data interpretation and the one derived from the GIA model) are in good agreement at 21 kyears BP, although some discrepancies occur in the southern part of the plateau, where the seabed slope is extremely gentle, which makes the clinoform rollover points and the buried erosional unconformities difficult to detect. After 20 kyears BP, an acceleration in the rate of the sea level rise occurred. The results of this study indicate the importance of comparing experimental data with model predictions in order to refine and calibrate boundary parameters and to gain a better picture of the evolution of sea level rise over various time scales. View Full-Text

Description: Published

Description: 125

Description: 4A. Oceanografia e clima

Description: JCR Journal

Description: The pressure-gradient current is among the weaker ionospheric current systems arising from plasma pressure variations. It is also called diamagnetic current because it produces a magnetic field which is oriented oppositely to the ambient magnetic field, causing its reduction. The magnetic reduction can be revealed in measurements made by low-Earth orbiting satellites flying close to ionospheric plasma regions where rapid changes in density occur. Using geomagnetic field, plasma density and electron temperature measurements recorded on board ESA Swarm A satellite from April 2014 to March 2018, we reconstruct the flow patterns of the pressure-gradient current at high-latitude ionosphere in both hemispheres, and investigate their dependence on magnetic local time, geomagnetic activity, season and solar forcing drivers. Although being small in amplitude these currents appear to be a ubiquitous phenomenon at ionospheric high latitudes characterized by well defined flow patterns, which can cause artifacts in the main field models. Our findings can be used to correct magnetic field measurements for diamagnetic current effect, to improve modern magnetic field models, as well as to understand the impact of ionospheric irregularities on ionospheric dynamics at small-scale sizes of a few tens of kilometers.

Description: Published

Description: 1428

Description: 1A. Geomagnetismo e Paleomagnetismo

Description: JCR Journal

Description: The study concerns the analysis of 220Rn (thoron) recorded in the surface soil in two sites of the Campi Flegrei caldera (Naples, Southern Italy) characterized by phases of volcanic unrest in the seven-year period 1 July 2011–31 December 2017. Thoron comes only from the most surface layer, so the characteristics of its time series are strictly connected to the shallow phenomena, which can also act at a distance from the measuring point in these particular areas. Since we measured 220Rn in parallel with 222Rn (radon), we found that by using the same analysis applied to radon, we obtained interesting information. While knowing the limits of this radioisotope well, we highlight only the particular characteristics of the emissions of thoron in the surface soil. Here, we show that it also shows some clear features found in the radon signal, such as anomalies and signal trends. Consequently, we provide good evidence that, in spite of the very short life of 220Rn compared to 222Rn, both are related to the carrier effect of CO2, which has significantly increased in the last few years within the caldera. The hydrothermal alterations, induced by the increase in temperature and pressure of the caldera system, occur in the surface soils and significantly influence thoron’s power of exhalation from the surface layer. The effects on the surface thoron are reflected in both sites, but with less intensity, the same behavior of 222Rn following the increasing movements and fluctuations of the geophysical and geochemical parameters (CO2 flux, fumarolic tremor, background seismicity, soil deformation). An overall linear correlation was found between the 222−220Rn signals, indicating the effect of the CO2 vector. The overall results represent a significant step forward in the use and interpretation of the thoron signal.

Description: Published

Description: 5809

Description: 4V. Processi pre-eruttivi

Description: JCR Journal

Description: Here, we describe the dataset of seismic envelopes used to study the S-wave Q-coda attenuation quality factor Qc of the Gargano Promontory (Southern Italy). With this dataset, we investigated the crustal seismic attenuation by the Qc parameter. We collected this dataset starting from two different earthquake catalogues: the first regarding the period from April 2013 to July 2014; the second regarding the period from July 2015 to August 2018. Visual inspection of the envelopes was carried out on recordings filtered with a Butterworth two-poles filter with central frequency fc = 6 Hz. The obtained seismic envelopes of coda decay can be linearly fitted in a bilogarithmic diagram in order to obtain a series of single source-receiver measures of Qc for each seismogram component at different frequency fc. The analysis of the trend Qc(fc) gives important insights into the heterogeneity and the anelasticity of the sampled Earth medium.

Description: Published

Description: 98

Description: 4T. Sismicità dell'Italia

Description: JCR Journal

Description: As a result of changes in approach from traditional to virtual banking system, security in data exchange has become more important; thus, it seems essentially necessary to present a pattern based on smart models in order to reduce fraud in this field. A new algorithm has been provided in this article to improve security and to specify the limits of giving special services to Internet banking users in order to pave appropriate ground for virtual banking. In addition to identifying behavioral models of customers, this algorithm compares the behaviors of any customer with this model and finally computes the rate of trust in customer’s behavior. The hybrid data-mining and knowledge based structure has been adapted in this algorithm according to fuzzy systems. In this research, qualitative data was gathered from interviews with banking experts, analyzed by Expert Choice to identify the most important variables of customer behavior analysis, and to analyze customer behavior and customer bank Internet transaction data for a period of one year by MATLAB and Clementine. The results of this survey indicate that the potential of the given structure to recognize the rate of trust in Internet bank user’s behavior might be at reasonable level for experts in this area.

Description: Published

Description: 916

Description: 3IT. Calcolo scientifico

Description: JCR Journal

Description: The investigation of submerged speleothems for sea level studies has made significant contributions to the understanding of the global and regional sea level variations during the Middle and Late Quaternary. This has especially been the case for the Mediterranean Sea, where more than 300 submerged speleothems sampled in 32 caves have been analysed so far. Here, we present a comprehensive review of the results obtained from the study of submerged speleothems since 1978. The studied speleothems cover the last 1.4 Myr and are mainly focused on Marine Isotope Stages (MIS) 1, 2, 3, 5.1, 5.3, 5.5, 7.1, 7.2, 7.3, and 7.5. The results reveal that submerged speleothems represent extraordinary archives providing accurate information on former sea level changes. New results from a stalagmite collected at Palinuro (Campania, Italy) and characterized by marine overgrowth are also reported. The measured elevations of speleothems are affected by the local response to glacial and hydro-isostatic adjustment (GIA), and thus might significantly deviate from the global eustatic signal. A comparison of the ages and altitude values of the Mediterranean speleothems and flowstone from the Bahamas with local GIA provides a new scenario for MIS 5 and 7 sea level reconstructions

Description: Published

Description: 77

Description: 4A. Oceanografia e clima

Description: JCR Journal

Description: Areas of the Mediterranean Sea are dynamic habitats in which human activities have been conducted for centuries and which feature micro-tidal environments with about 0.40 m of range. For this reason, human settlements are still concentrated along a narrow coastline strip, where any change in the sea level and coastal dynamics may impact anthropic activities. We analyzed light detection and ranging (LiDAR) and Copernicus Earth observation data. The aim of this research is to provide estimates and detailed maps (in three coastal plain of Sardinia (Italy) and in the Pontina Plain (southern Latium, Italy) of: (i) the past marine transgression occurred during MIS 5.5 highstand 119 kyrss BP; (ii) the coastline regression occurred during the last glacial maximum MIS 2 (21.5 krs cal BP); and (iii) the potential marine submersion for 2100 and 2300. The objective of this multidisciplinary study is to provide maps of sea level rise future scenarios using the IPCC RCP 8.5 2019 projections and glacio-hydro-isostatic movements for the above selected coastal zones (considered tectonically stable), which are the locations of touristic resorts, railways and heritage sites. We estimated a potential loss of land for the above areas of between about 146 km2 (IPCC 2019-RCP8.5 scenario) and 637 km2 along a coastline length of about 268 km.

Description: Published

Description: 2597

Description: 4A. Oceanografia e clima

Description: JCR Journal

Description: The eruptions of Campi Flegrei (Southern Italy), one of the most studied and dangerous active volcanic areas of the world, are fed by mildly potassic alkaline magmas, from shoshonite to trachyte and phonotrachyte. Petrological investigations carried out in past decades on Campi Flegrei rocks provide crucial information for understanding differentiation processes in its magmatic system. However, the compositional features of rocks are a palimpsest of many processes acting over timescales of 100–104 years, including crystal entrapment from multiple reservoirs with different magmatic histories. In this work, olivine, clinopyroxene and feldspar crystals from volcanic rocks related to the entire period of Campi Flegrei’s volcanic activity are checked for equilibrium with combined and possibly more rigorous tests than those commonly used in previous works (e.g., Fe–Mg exchange between either olivine or clinopyroxene and melt), with the aim of obtaining more robust geothermobarometric estimations for the magmas these products represent. We applied several combinations of equilibrium tests and geothermometric and geobarometric methods to a suite of rocks and related minerals spanning the period from ~59 ka to 1538 A.D. and compared the obtained results with the inferred magma storage conditions estimated in previous works through different methods. This mineral-chemistry investigation suggests that two prevalent sets of T–P (temperature–pressure) conditions, here referred to as “magmatic environments”, characterized the magma storage over the entire period of Campi Flegrei activity investigated here. These magmatic environments are ascribable to either mafic or differentiated magmas, stationing in deep and shallow reservoirs, respectively, which interacted frequently, mostly during the last 12 ka of activity. In fact, open-system magmatic processes (mixing/mingling, crustal contamination, CO2 flushing) hypothesized to have occurred before several Campi Flegrei eruptions could have removed earlier-grown crystals from their equilibrium melts. Moreover, our new results indicate that, in the case of complex systems such as Campi Flegrei’s, in which different pre-eruptive processes can modify the equilibrium composition of the crystals, one single geothermobarometric method offers little chance to constrain the magma storage conditions. Conversely, combined methods yield more robust results in agreement with estimates obtained in previous independent studies based on both petrological and geophysical methods

Description: Published

Description: 308

Description: 2V. Struttura e sistema di alimentazione dei vulcani

Description: JCR Journal

Description: On Vulcano Island (Italy), many geochemical crises have occurred during the last 130 years of solfataric activity. The main crises occurred in 1978–1980, 1988–1991, 1996, 2004–2007, 2009–2010 and the ongoing 2021 anomalous degassing activity. These crises have been characterized by early signals of resuming degassing activity, measurable by the increase of volatiles and energy output emitted from the summit areas of the active cone, and particularly by increases of gas/water ratios in the fumarolic area at the summit. In any case, a direct rather than linear correspondence has been observed among the observed increase in the fluid output, seismic release and ground deformation, and is still a subject of study. We present here the results obtained by the long-term monitoring (over 13 years of observations) of three extensive parameters: the SO2 flux monitored in the volcanic plume, the soil CO2 flux and the local heat flux, monitored in the mild thermal anomaly located to the east of the high-temperature fumarole. The time variations of these parameters showed cyclicity in the volcanic degassing and a general increase in the trend in the last period. In particular, we focused on the changes in the mass and energy output registered in the period of June–December 2021, to offer in near-real-time the first evaluation of the level and duration of the actual exhalative crisis affecting Vulcano Island. In this last event, a clear change in degassing style was recorded for the volatiles emitted by the magma. For example, the flux of diffused CO2 from the soils reached the maximum never-before-recorded value of 34,000 g m−2 d −1 and the flux of SO2 of the plume emitted by the fumarolic field on the summit crater area reached values higher than 200 t d−1 . The interpretation of the behavior of this volcanic system, resulting from the detailed analyses of these continuous monitoring data, will complete the framework of observations and help in defining and possibly forecasting the next evolution of the actual exhaling crisis.

Description: This research was funded by the INGV-DPCN (Italian National Institute of Geophysics and Volcanology—Italian National Department for Civil Protection) volcanic surveillance program of Vulcano island, ObFu 0304.010. Moreover, this investigation was partially funded by the TORS project in the framework of institutional INGV projects “Ricerca Libera” ObFu 9999.549; and Pianeta Dinamico Task V2, ObFu 1020.010.

Description: Published

Description: 1283

Description: 4V. Processi pre-eruttivi

Description: JCR Journal

Description: An accurate understanding of dissimilarities in geomagnetic variability between quiet and disturbed periods has the potential to vastly improve space weather diagnosis. In this work, we exploit some recently developed methods of dynamical system theory to provide new insights and conceptual ideas in space weather science. In particular, we study the co-variation and recurrence statistics of two geomagnetic indices, SYM-H and AL, that measure the intensity of the globally symmetric component of the equatorial electrojet and that of the westward auroral electrojet, respectively. We find that the number of active degrees of freedom, required to describe the phase space dynamics of both indices, depends on the geomagnetic activity level. When the magnetospheric substorm activity, as monitored by the AL index, increases, the active number of degrees of freedom increases at high latitudes above the dimension obtained through classical time delay embedding methods. Conversely, a reduced number of degrees of freedom is observed during geomagnetic storms at low latitude by analysing the SYM-H index. By investigating time-dependent relations between both indices we find that a significant amount of information is shared between high and low latitude current systems originating from coupling mechanisms within the magnetosphere–ionosphere system as the result of a complex interplay between processes and phenomena of internal origin activated by the triggering of external source processes. Our observations support the idea that the near-Earth electromagnetic environment is a complex system far from an equilibrium

Description: Published

Description: 226

Description: 1A. Geomagnetismo e Paleomagnetismo

Description: JCR Journal

Description: The dynamics of magma is often studied through 2D numerical simulations because 3D simulations are usually complex and computationally expensive. However, magmatic systems and physical processes are 3D and approximating them in 2D requires an evaluation of the information which is lost under different conditions. This work presents a physical and numerical model for 3D magma convection dynamics. The model is applied to study the dynamics of magma convection and mixing between andesitic and dacitic magmas. The 3D simulation results are compared with corresponding 2D simulations. We also provide details on the numerical scheme and its parallel implementation in C++ for high-performance computing. The performance of the numerical code is evaluated through strong scaling exercises involving up to 〉 12,000 cores.

Description: Published

Description: 760773

Description: 4V. Processi pre-eruttivi

Description: JCR Journal

Description: The recent Chinese Seismo-Electromagnetic Satellite (CSES-01) provides a good opportunity to investigate some features of plasma properties and its motion in the topside ionosphere. Using simultaneous measurements from the electric field detector and the magnetometers onboard CSES-01, we investigate some properties of the plasma ExB drift velocity for a case study during a crossing of the Southern auroral region in the topside ionosphere. In detail, we analyze the spectral and scaling features of the plasma drift velocity and provide evidence of the turbulent character of the ExB drift. Our results provide an evidence of the occurrence of 2D ExB intermittent convective turbulence for the plasma motion in the topside ionospheric F2 auroral region at scales from tens of meters to tens of kilometers. The intermittent character of the observed turbulence suggests that the macro-scale intermittent structure is isomorphic with a quasi-1D fractal structure, as happens, for example, in the case of a filamentary or thin-tube-like structure. Furthermore, in the analyzed range of scales we found that both magnetohydrodynamic and kinetic processes may affect the plasma dynamics at spatial scales below 2 km. The results are discussed and compared with previous results reported in the literature.

Description: Published

Description: 1936

Description: 2A. Fisica dell'alta atmosfera

Description: JCR Journal

Description: Constraining the magmatic 3He/4He signature of fluids degassed from a magmatic system is crucial for making inferences on its mantle source. This is especially important in arc volcanism, where variations in the composition of the wedge potentially induced by slab sediment fluids must be distinguished from the effects of magma differentiation, degassing, and crustal contamination. The study of fluid inclusions (FIs) trapped in minerals of volcanic rocks is becoming an increasingly used methodology in geochemical studies that integrates the classical study of volcanic and geothermal fluids. Here, we report on the first noble gas (He, Ne, Ar) concentrations and isotopic ratios of FI in olivine (Ol) and pyroxene (Px) crystals separated from eruptive products of the Telica and Baru volcanoes, belonging to the Nicaraguan and Panamanian arc-segments of Central America Volcanic arc (CAVA). FIs from Telica yield air corrected 3He/4He (Rc/Ra) of 7.2–7.4 Ra in Ol and 6.1–7.3 in Px, while those from Baru give 7.1–8.0 Ra in Ol and 4.2–5.8 Ra in Px. After a data quality check and a comparison with previous 3He/4He measurements carried out on the same volcanoes and along CAVA, we constrained a magmatic Rc/Ra signature of 7.5 Ra for Telica and of 8.0 Ra for Baru, both within the MORB range (8 1 Ra). These 3He/4He differences also reflect variations in the respective arc-segments, which cannot be explained by radiogenic 4He addition due to variable crust thickness, as the mantle beneath Nicaragua and Panama is at about 35 and 30 km, respectively. We instead highlight that the lowest 3He/4He signature observed in the Nicaraguan arc segment reflects a contamination of the underlying wedge by slab sediment fluids. Rc/Ra values up to 9.0 Ra are found at Pacaya volcano in Guatemala, where the crust is 45 km thick, while a 3He/4He signature of about 8.0 Ra was measured at Turrialba volcano in Costa Rica, which is similar to that of Baru, and reflects possible influence of slab melting, triggered by a change in subduction conditions and the contemporary subduction of the Galapagos hot-spot track below southern Costa Rica and western Panama.

Description: Published

Description: 2076-3417

Description: 1V. Storia eruttiva

Description: 2V. Struttura e sistema di alimentazione dei vulcani

Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici

Description: JCR Journal

Description: Geogenic and anthropogenic sources of atmospheric particulate and CO2 can lead to threats to human health in volcanic areas. Although the volcanic CO2 hazard is a topic frequently debated in the related scientific literature, space and time distribution of PM2.5 are poorly known. The results of combined CO2/PM2.5 surveys, carried out at Salina, Stromboli, and Vulcano islands (Aeolian archipelago, Italy) in the years 2020-2021, and integrated with investigations on bioaccumulation of metallic particulate matter by the mean of data on the magnetic properties of oleander leaves, are presented in this work. The retrieved results indicate that no significant anthropogenic sources for both CO2 and PM2.5 are active in these islands, at the net of a minor contribution due to vehicular traffic. Conversely, increments in volcanic activity, as the unrest experienced by Vulcano island since the second half of 2021, pose serious threats to human health, due to the near-ground accumulation of CO2, and the presence of suspended micro-droplets of condensed hydrothermal vapor, fostering the diffusion of atmophile viruses, such as the COVID-19. Gas hazard conditions can be generated, not only by volcanic vents or fumarolic fields, but also by unconventional sources, such as the outgassing from shallow hydrothermal aquifers through drilled or hand-carved wells.

Description: Published

Description: 4833

Description: 6A. Geochimica per l'ambiente e geologia medica

Description: JCR Journal

Description: Rocky reefs provide complex structures in the otherwise largely sand-dominated coastal North Sea. Therefore, these reefs are highly important natural habitats for the functioning of coastal ecosystems, as they provide shelter, refuge and nursery grounds for various mobile and sessile species. In the North Sea, the spatial distribution of these habitats has been intensively investigated over recent years. However, these studies generally provide static accounts of the current state of these reef systems, but limited data exist on the temporal variations in sediment dynamics at and around natural rocky reefs. In this study, we provide observations from a multiannual time series of hydroacoustic seafloor surveys conducted at an isolated rocky reef in the North Sea. We use multibeam bathymetry and side-scan sonar backscatter data in combination with video observations, sediment sampling, and sub-bottom profiler data to assess the long-term variations of the rocky reef system. The reef is located in water depths between 11 and 17 m with an areal extent of ~0.5 km2 and is surrounded by mobile sands. The topography of the rocky reef appears to create a distinct hydrodynamic system that permits mobile sands to settle or move into bathymetrical deeper parts of the reef. Our results suggest a very dynamic system surrounding the reef with large scale scouring, sediment reworking and transport, while the shallower central part of the reef remains stable over time. We demonstrate the importance of hydrodynamics and current scouring around reefs for the local variability in seafloor properties over time. These small-scale dynamics are likewise reflected in the spatial distribution of sessile species, which are less abundant in proximity to mobile sands. The hydroacoustic mapping and monitoring of seafloor dynamics at higher spatial and temporal resolutions presents an important future direction in the study of valuable coastal habitats.

Description: Based on the review of the available stratigraphic, tectonic, morphological, geodetic, and seismological data, along with new structural observations, we present a reappraisal of the potential seismogenic faults and fault systems in the inner northwest Apennines, Italy, which was the site, one century ago, of the devastating Mw ~6.5, 1920 Fivizzano earthquake. Our updated fault catalog provides the fault locations, as well as the description of their architecture, large-scale segmentation, cumulative displacements, evidence for recent to present activity, and long-term slip rates. Our work documents that a dense network of active faults, and thus potential earthquake fault sources, exists in the region. We discuss the seismogenic potential of these faults, and propose a general tectonic scenario that might account for their development.

Description: Published

Description: 139

Description: 2T. Deformazione crostale attiva

Description: 4T. Sismicità dell'Italia

Description: JCR Journal

Description: In this paper, we present two novel experimental setups specifically designed to perform in situ long-term monitoring of the aging behaviour of commercial plastic granules (HDPE, PP, PLA and PBAT). The results of the first six months of a three year monitoring campaign are presented. The two experimental setups consist of: (i) special cages positioned close to the sea floor at a depth of about 10 m, and (ii) a box containing sand exposed to atmospheric agents to simulate the surface of a beach. Starting from March 2020, plastic granules were put into the cages and plunged in sea water in two different locations in the sand boxes. Chemical spectroscopic and thermal analyses (GPC, SEM, FTIR-ATR, DSC, TGA) were performed on the granules before and after exposure to natural elements for six months, in order to identify the physical-chemical modifications occurring in marine environmental conditions (both in seawater and in sandy coastal conditions). Changes in colour, surface morphology, chemical composition, thermal properties and molecular weight, and the polydispersity of the materials, showed the different influences of the environmental conditions. Photooxidative reaction pathways were prevalent in the sandbox. Abrasive phenomena acted specially in the sea environment. PLA and PBAT did not show significant degradation after six months, making the possible reduction of marine pollution due to this process negligible

Description: Published

Description: 1111

Description: 4A. Oceanografia e clima

Description: JCR Journal

Description: Wetlands are hotspots of CH4 emissions to the atmosphere, mainly sustained by microbial decomposition of organic matter in anoxic sediments. Several knowledge gaps exist on how environmental drivers shape CH4 emissions from these ecosystems, posing challenges in upscaling efforts to estimate global emissions from waterbodies. In this work, CH4 and CO2 diffusive fluxes, along with chemical and isotopic composition of dissolved ionic and gaseous species, were determined from two wetlands of Tuscany (Italy): (i) Porta Lake, a small wetland largely invaded by Phragmites australis reeds experiencing reed die‐back syndrome, and (ii) Massaciuccoli Lake, a wide marsh area including open‐water basins and channels affected by seawater intrusion and eutrophication. Both wetlands were recognized as net sources of CH4 to the atmosphere. Our data show that the magnitude of CH4 diffusive emission was controlled by CH4 production and consumption rates, being mostly governed by (i) water temperature and availability of labile carbon substrates and (ii) water column depth, wind exposure and dissolved O2 contents, respectively. This evidence suggests that the highest CH4 diffusive fluxes were sustained by reed beds, providing a large availability of organic matter supporting acetoclastic methanogenesis, with relevant implications for global carbon budget and future climate models.

Description: Published

Description: 12156

Description: 6A. Geochimica per l'ambiente e geologia medica

Description: JCR Journal

Description: Mediterranean wetlands are severely affected by habitat degradation and related loss of biodiversity. In this scenario, the wide number of artificial farm ponds can play a significant role in the biodiversity conservation of aquatic flora. In the present contribution we show the preliminary results of a study on Mediterranean farm ponds of north-western Sicily (Italy), aimed to investigating the environmental factors linked to the occurrence of submerged macrophytes (vascular plants and charophytes). We studied the aquatic flora of 30 ponds and determined the chemical and isotopic composition of their water bodies on a subset of the most representative 10 sites. Results show that (1) farm ponds host few but interesting species, such as Potamogeton pusillus considered threatened at regional level; (2) Chara vulgaris, C. globularis and P. pusillus behave as disturbance-tolerant species, occurring both in nitrates-poor and nitrates-rich waters, whereas Stuckenia pectinata and Zannichellia palustris occur only in nitrates-poor waters. Although farm ponds are artificial and relatively poor habitats, these environments seem to be important for the aquatic flora and for the conservation of the local biodiversity, and can give useful information for the use of macrophytes as bioindicators in the Mediterranean area.

Description: Published

Description: 1292

Description: 6A. Geochimica per l'ambiente e geologia medica

Description: JCR Journal

Description: The Campi Flegrei geothermal system sets in one of the most famous and hazardous volcanic caldera in the world. The geothermal dynamics is suspected to have a crucial role in the monitored unrest phases and in the eruption triggering as well. Numerical models in the literature do not properly consider the geochemical effects of fluid-rock interaction into the hydrothermal circulation and this gap limits the wholly understanding of the dynamics. This paper focuses on fluid-rock interaction effects at the Campi Flegrei and presents relevant information requested for reactive transport simulations. In particular, we provide: (1) an extensive review of available data and new petrographic analyses of the San Vito cores rearranged in a conceptual model useful to define representative geochemical and petrophysical parameters of rock formations suitable for numerical simulations and (2) the implemented thermodynamic and kinetic data set calibrated for the San Vito 1 well area, central in the geothermal reservoir. A preliminary 0D-geochemical model, performed with a different contribution of CO2 at high (165 ◦C) and low (85 ◦C) temperatures, firstly allows reproducing the hydrothermal reactions over time of the Campanian Ignimbrite formation, the most important deposits in the case study area.

Description: Published

Description: 810

Description: 2V. Struttura e sistema di alimentazione dei vulcani

Description: 1TR. Georisorse

Description: 4IT. Banche dati

Description: JCR Journal

Description: The ionospheric plasma density irregularities are known to play a role in the propagation of electromagnetic signals and to be one of the most important sources of disturbance for the Global Navigation Satellite System, being responsible for degradation and, sometimes, interruptions of the signals received by the system. In the equatorial ionospheric F region, these plasma density irregularities, known as plasma bubbles, find the suitable conditions for their development during post-sunset hours. In recent years, important features of plasma bubbles such as their dependence on latitude, longitude, and solar and geomagnetic activities have been inferred indirectly using their magnetic signatures. Here, we study the scaling properties of both the electron density and the magnetic field inside the plasma bubbles using measurements on board the Swarm A satellite from 1 April 2014 to 31 January 2016. We show that the spectral features of plasma irregularities cannot be directly inferred from their magnetic signatures. A relation more complex than the linear one is necessary to properly describe the role played by the evolution of plasma bubbles with local time and by the development of turbulent phenomena.

Description: Published

Description: 918

Description: 2A. Fisica dell'alta atmosfera

Description: JCR Journal

Description: A systematic multiparametric and multiplatform approach to detect and study geo-space perturbations attributed to preparation processes related to natural hazards is fundamental in order to obtain useful insights on a series of complex dynamic phenomena of the Earth system, namely, earthquakes, volcanic and Saharan dust events, as well as geomagnetic disturbances. In particular, integrated analysis and interpretation of data from ground-based and spaceborne observations of the lower and upper atmospheres are of paramount importance for understanding the associated physical processes. In this Special Issue, we include pertinent studies on this field of research, presenting recent results and highlighting future directions for advances in the topic.

Description: Published

Description: 496

Description: 7T. Variazioni delle caratteristiche crostali e "precursori"

Description: JCR Journal

Description: Low Earth orbit satellites collect and study information on changes in the ionosphere, which contributes to the identification of earthquake precursors. Swarm, the European Space Agency three-satellite mission, has been launched to monitor the Earth geomagnetic field, and has successfully shown that in some cases it is able to observe many several ionospheric perturbations that occurred as a result of large earthquake activity. This paper proposes the SafeNet deep learning framework for detecting pre-earthquake ionospheric perturbations. We trained the proposed model using 9017 recent (2014–2020) independent earthquakes of magnitude 4.8 or greater, as well as the corresponding 7-year plasma and magnetic field data from the Swarm A satellite, and excellent performance has been achieved. In addition, the influence of different model inputs and spatial window sizes, earthquake magnitudes, and daytime or nighttime was explored. The results showed that for electromagnetic pre-earthquake data collected within a circular region of the epicenter and with a Dobrovolsky-defined radius and input window size of 70 consecutive data points, nighttime data provided the highest performance in discriminating pre-earthquake perturbations, yielding an F1 score of 0.846 and a Matthews correlation coefficient of 0.717. Moreover, SafeNet performed well in identifying pre-seismic ionospheric anomalies with increasing earthquake magnitude and unbalanced datasets. Hypotheses on the physical causes of earthquake-induced ionospheric perturbations are also provided. Our results suggest that the performance of pre-earthquake ionospheric perturbation identification can be significantly improved by utilizing SafeNet, which is capable of detecting precursor effects within electromagnetic satellite data.

Description: Published

Description: 5033

Description: 7T. Variazioni delle caratteristiche crostali e "precursori"

Description: JCR Journal

Description: The polyphase structural evolution of a sector of the internal Central Apennines, where the significance of pelagic deposits atop neritic carbonate platform and active margin sediments has been long debated, is here documented. The results of a new geological survey in the Volsci Range, supported by new stratigraphic constraints from the syn-orogenic deposits, are integrated with the analysis of 2D seismic reflection lines and available wells in the adjacent Latin Valley. Late Cretaceous syn-sedimentary faults are documented and interpreted as steps linking a carbonate platform to the adjacent pelagic basin, located to the west. During Tortonian time, the pelagic deposits were squeezed off and juxtaposed as mélange units on top of the carbonate platform. Subsurface data highlighted stacked thrust sheets that were first involved into an initial in-sequence propagation with top-to-the-ENE, synchronous to late Tortonian foredeep to wedge-top sedimentation. We distinguish up to four groups of thrust faults that occurred during in-sequence shortening (thrusts 1–3; about 55–60 km) and backthrusting (thrust 4). During Pliocene to recent times, the area has been uplifted and subsequently extended by normal faults cross-cutting the accretionary wedge. Beside regional interest, our findings bear implications on the kinematic evolution of an orogenic wedge affected by far-traveled units.

Description: Published

Description: 160

Description: 4T. Sismicità dell'Italia

Description: JCR Journal

Description: A crystal chemical investigation of a natural specimen of whitlockite, ideally Ca9Mg(PO4)6[PO3(OH)], from Palermo Mine (USA), was achieved by means of a combination of electron microprobe analysis (EMPA) in WDS mode, single‐crystal neutron diffraction probe (NDP) and single‐crystal X‐ray diffraction (XRD), and Fourier transform infrared (FTIR) spectroscopy. The crystal‐chemical characterization resulted in the empirical formula (Ca8.682Na0.274Sr0.045)Σ9.000(Ca0.034□0.996)Σ1.000(Mg0.533Fe2+0.342Mn2+0.062Al0.046)Σ0.983(P1.006O4)6[PO3(OH0.968F0.032)Σ1.000]. Crystal‐structure refinement, in the space group R3c, converged to R1 = 7.12% using 3273 unique reflections from NDP data and to R1 = 2.43% using 2687 unique reflections from XRD data. Unit cell parameters from NDP are a = 10.357(3) Å, c = 37.095(15) Å and V = 3446(2) Å3, and from XRD, the parameters are a = 10.3685(4) Å, c = 37.1444(13) Å and V = 3458.2(3) Å3. NDP results allowed a deeper definition of the hydrogen‐bond system and its relation with the structural unit [PO3(OH)]. The FTIR spectrum is very similar to that of synthetic tricalcium phosphate Ca3(PO4)2 and displays minor band shifts due to slightly different P‐O bond lengths and to the presence of additional elements in the structure. A comparison between whitlockite, isotypic phases from the largest merrillite group, and its synthetic counterpart Ca3(PO4)2 is provided, based on the XRD/NDP and FTIR results.

Description: Published

Description: 225

Description: 1TR. Georisorse

Description: JCR Journal

Description: Seismic prediction was considered impossible, however, there are no reasons in theoretical physics that explicitly prevent this possibility. Therefore, it is quite likely that prediction is made stubbornly complicated by practical difficulties such as the quality of catalogs and data analysis. Earthquakes are sometimes forewarned by precursors, and other times they come unexpectedly; moreover, since no unique mechanism for nucleation was proven to exist, it is unlikely that single classical precursors (e.g., increasing seismicity, geochemical anomalies, geoelectric potentials) may ever be effective in predicting impending earthquakes. For this reason, understanding the physics driving the evolution of fault systems is a crucial task to fine-tune seismic prediction methods and for the mitigation of seismic risk. In this work, an innovative idea is inspected to establish the proximity to the critical breaking point. It is based on the mechanical response of faults to tidal perturbations, which is observed to change during the “seismic cycle”. This technique allows to identify different seismic patterns marking the fingerprints of progressive crustal weakening. Destabilization seems to arise from two different possible mechanisms compatible with the so called preslip patch, cascade models and with seismic quiescence. The first is featured by a decreasing susceptibility to stress perturbation, anomalous geodetic deformation, and seismic activity, while on the other hand, the second shows seismic quiescence and increasing responsiveness. The novelty of this article consists in highlighting not only the variations in responsiveness of faults to stress while reaching the critical point, but also how seismic occurrence changes over time as a function of instability. Temporal swings of correlation between tides and nucleated seismic energy reveal a complex mechanism for modulation of energy dissipation driven by stress variations, above all in the upper brittle crust. Some case studies taken from recent Greek seismicity are investigated.

Description: Published

Description: 9596

Description: 2T. Deformazione crostale attiva

Description: JCR Journal

Description: The purpose of the present paper is to investigate the effects of variable eruption source parameters on volcanic plume transport in the Mediterranean basin after the paroxysm of Mount Etna on 23 November 2013. This paroxysm was characterized by a north-east transport of ash and gas, caused by a low-pressure system in northern Italy. It is evaluated here in a joint approach considering the WRF-Chem model configured with eruption source parameters (ESPs) obtained elaborating the raw data from the VOLDORAD-2B (V2B) Doppler radar system. This allows the inclusion of the transient and fluctuating nature of the volcanic emissions to accurately model the atmospheric dispersion of ash and gas. Two model configurations were considered: the first with the climax values for the ESP and the second with the time-varying ESP according to the time profiles of the mass eruption rate recorded by the V2B radar. It is demonstrated that the second configuration produces a considerably better comparison with satellite retrievals from different sensors platforms (Ozone Mapping and Profiler Suite, Meteosat Second-Generation Spinning Enhanced Visible and Infrared Imager, and Visible Infrared Imaging Radiometer Suite). In the context of volcanic ash transport dispersion modeling, our results indicate the need for (i) the use of time-varying ESP, and (ii) a joint approach between an online coupled chemical transport model like WRF-Chem and direct near-source measurements, such as those carried out by the V2B Doppler radar system.

Description: Published

Description: 4037

Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio

Description: 7A. Geofisica per il monitoraggio ambientale

Description: 7SR AMBIENTE – Servizi e ricerca per la società

Description: 1IT. Reti di monitoraggio e sorveglianza

Description: 3IT. Calcolo scientifico

Description: 6IT. Osservatori non satellitari

Description: JCR Journal

Description: The Mediterranean Basin is characterized by a significant variability in tectonic behaviour, ranging from subsidence to uplifting. However, those coastal areas considered to be tectonically stable show coastal landforms at elevations consistent with eustatic and isostatic sea level change models. In particular, geomorphological indicators—such as tidal notches or shore platforms—are often used to define the tectonic stability of the Mediterranean coasts. We present the results of swim surveys in nine rocky coastal sectors in the central Mediterranean Sea using the Geoswim approach. The entire route was covered in 22 days for a total distance of 158.5 km. All surveyed sites are considered to have been tectonically stable since the last interglacial (Marine Isotope Stage 5.5 [MIS 5.5]), because related sea level markers fit well with sea level rise models. The analysis of visual observations and punctual measurements highlighted that, with respect to the total length of surveyed coast, the occurrence of tidal notches, shore platforms, and other indicators accounts for 85% of the modern coastline, and only 1% of the MIS 5.5 equivalent. Therefore, only 1% of the surveyed coast showed the presence of fossil markers of paleo sea levels above the datum. This significant difference is mainly attributable to erosion processes that did not allow the preservation of the geomorphic evidence of past sea level stands. In the end, our research method showed that the feasibility of applying such markers to define long-term tectonic behaviour is much higher in areas where pre-modern indicators have not been erased, such as at sites with hard bedrock previously covered by post-MIS 5.5 continental deposits, e.g., Sardinia, the Egadi Islands, Ansedonia, Gaeta, and Circeo. In general, the chances of finding such preserved indicators are very low.

Description: Published

Description: 2127

Description: 4A. Oceanografia e clima

Description: 7A. Geofisica per il monitoraggio ambientale

Description: JCR Journal

Description: We applied a new version of physics-based earthquake simulator upon a seismogenic model of the Italian seismicity derived from the latest version of the Database of Individual Seismogenic Sources (DISS). We elaborated appropriately for their use within the simulator all fault systems identified in the study area. We obtained synthetic catalogs spanning hundreds of thousands of years. The resulting synthetic seismic catalogs exhibit typical magnitude, space and time features that are comparable to those obtained by real observations. A typical aspect of the observed seismicity is the occurrence of earthquake sequences characterized by multiple main shocks of similar magnitude. Special attention was devoted to verifying whether the simulated catalogs include this notable aspect, by the use of an especially developed computer code. We found that the phenomenon of Coulomb stress transfer from causative to receiving source patches during an earthquake rupture has a critical role in the behavior of seismicity patterns in the simulated catalogs. We applied the simulator to the seismicity of the northern and central Apennines and compared the resulting synthetic catalog with the observed seismicity for the period 1650–2020. The result of this comparison supports the hypothesis that the occurrence of sequences containing multiple mainshocks is not just a casual circumstance.

Description: Published

Description: 2062

Description: 2T. Deformazione crostale attiva

Description: 3T. Fisica dei terremoti e Sorgente Sismica

Description: 4T. Sismicità dell'Italia

Description: JCR Journal

Description: The interaction between fluids and tectonic structures such as fault systems is a muchdiscussed issue. Many scientific works are aimed at understanding what the role of fault systems in the displacement of deep fluids is, by investigating the interaction between the upper mantle, the lower crustal portion and the upraising of gasses carried by liquids. Many other scientific works try to explore the interaction between the recharge processes, i.e., precipitation, and the fault zones, aiming to recognize the function of the abovementioned structures and their capability to direct groundwater flow towards preferential drainage areas. Understanding the role of faults in the recharge processes of punctual and linear springs, meant as gaining streams, is a key point in hydrogeology, as it is known that faults can act either as flow barriers or as preferential flow paths. In this work an investigation of a fault system located in the Nera River catchment (Italy), based on geo-structural investigations, tracer tests, geochemical and isotopic recharge modelling, allows to identify the role of the normal fault system before and after the 2016–2017 central Italy seismic sequence (Mmax = 6.5). The outcome was achieved by an integrated approach consisting of a structural geology field work, combined with GIS-based analysis, and of a hydrogeological investigation based on artificial tracer tests and geochemical and isotopic analyses.

Description: Published

Description: 1499

Description: 2IT. Laboratori analitici e sperimentali

Description: JCR Journal

Description: In the Tethyan realm, leucocratic rocks were recognized as dikes and layers outcropping in the ophiolitic rocks of the Western Alps, in Corsica, and in the Northern Apennines. Several authors have suggested that the origin of leucocratic rocks is associated with partial melting of cumulate gabbro. Major and trace elements composition and paragenesis provided information about the leucocratic rocks genetic processes. This research aims at disclosing, for the first time, the petrographical and geochemical features of Timpa delle Murge leucocratic rocks, Pollino Massif (southern Italy), in order to discuss their origin and geodynamic significance through a comparison with other Tethyan leucocratic rocks. These rocks are characterized by high amounts of silica with moderate alumina and iron-magnesium contents showing higher potassium contents than plagiogranites, due to plagioclase alteration to sericite. Plagioclase fractionation reflects negative Eu anomalies indicating its derivation from gabbroic crystal mushes. The chondrite normalized REEs patterns suggest the participation of partial melts derived from a metasomatized mantle in a subduction environment. The results reveal some similarities in composition with other Tethyan leucocratic rocks, especially those concerning Corsica and the Northern Alps. These new data provide further clues on the origin of these leucocratic rocks and the Tethyan area geodynamic evolution.

Description: Published

Description: 1264

Description: 2TR. Ricostruzione e modellazione della struttura crostale

Description: JCR Journal

Description: We investigate crustal seismic attenuation by the coda quality parameter (Qc) in the Gargano area (Southern Italy), using a recently released dataset composed of 191 small earthquakes (1.0 ≤ ML ≤ 2.8) recorded by the local OTRIONS and the Italian INGV seismic networks, over three years of seismic monitoring. Following the single back-scattering theoretical assumption, Qc was computed using different frequencies (in the range of 2–16 Hz) and different lapse times (from 10 to 40 s). The trend of Qc vs. frequency is the same as that observed in the adjacent Umbria-Marche region. Qc at 1 Hz varies between 11 and 63, indicating that the area is characterized by active tectonics, despite the absence of high-magnitude earthquakes in recent decades. The 3D mapping procedure, based on sensitivity kernels, revealed that the Gargano Promontory is characterized by very low and homogeneous Qc at low frequencies, and by high and heterogeneous Qc at high frequencies. The lateral variations of Qc at 12 Hz follow the trend of the Moho in this region and are in good agreement with other geophysical observations.

Description: The computational work has been executed on the IT resources of the ReCaS- Bari data center, which have been made available by two projects financed by the MIUR (Italian Ministry for Education, University and Re-search) in the “PON Ricerca e Competitività 2007–2013” Program: ReCaS (Azione I-Interventi di rafforzamento strutturale, PONa3_00052, Avviso 254/Ric) and PRISMA (Asse II-Sostegno all’innovazione, PON04a2_A).

Description: Published

Description: 7512

Description: 7T. Variazioni delle caratteristiche crostali e "precursori"

Description: JCR Journal

Description: Within an E.U.-funded project, BESS (Pocket BeachManagement and Remote Surveillance System), the notion of a geographic information system is an indispensable tool for managing the dynamics of georeferenced data and information for any form of territorial planning. This notion was further explored with the creation of aWebGIS portal that will allow local and regional stakeholders/authorities obtain an easy remote access tool tomonitor the status of pocket beaches (PB) in theMaltese Archipelago and Sicily. In this paper, we provide a methodological approach for the implementation of aWebGIS necessary for very detailed dynamic mapping and visualization of geospatial coastal data; the description of the dataset necessary for the monitoring of coastal areas, especially the PBs; and a demonstration of a case study for the PBs of Sicily andMalta by using the methodology and the dataset used during the BESS project. Detailed steps involved in the creation of theWebGIS are presented. These include data preparation, data storage, and data publication and transformation into geo-services. With the help of different Open Geospatial Consortium protocols, theWebGIS displays different layers of information for 134 PBs including orthophotos, sedimentological/geomorphological beach characteristics, shoreline evolution, geometric and morphological parameters, shallow water bathymetry, and photographs of pocket beaches. TheWebGIS allows not only for identifying, evaluating, and directing potential solutions to present and arising issues, but also enables public access and involvement. It reflects a platform for future local and regional coastal zone monitoring and management, by promoting public/private involvement in addressing coastal issues and providing local public administrations with an improved technology to monitor coastal changes and help better plan suitable interventions.

Description: Published

Description: 8233

Description: 7SR AMBIENTE – Servizi e ricerca per la società

Description: JCR Journal

Description: This study was developed to carry out a comprehensive radiological assessment of natural radioactivity for river sediment samples from Calabria, southern Italy, and to define a baseline background for the area on a radiation map. In the studied area, elevated levels of natural radionuclides are expected, due to the outcropping acidic intrusive and metamorphic rocks from which the radioactive elements derive. To identify and quantify the natural radioisotopes, ninety river sediment samples from nine selected coastal sampling points (ten samples for each point) were collected as representative of the Ionian and the Tyrrhenian coastline of Calabria. The samples were analyzed using a gamma ray spectrometer equipped with a high-purity germanium (HPGe) detector. The values of mean activity concentrations of 226Ra, 232Th and 40K measured for the studied samples are (21.3 6.3) Bq kg􀀀1, (30.3 4.5) Bq kg􀀀1 and (849 79) Bq kg􀀀1, respectively. The calculated radiological hazard indices showed average values of 63 nGy h􀀀1 (absorbed dose rate), 0.078 mSv y􀀀1 (effective dose outdoors), 0.111 mSv y􀀀1 (effective dose indoors), 63 Bq kg􀀀1 (radium equivalent), 0.35 (Hex), 0.41 (Hin), 0.50 (activity concentration index) and 458 Sv y􀀀1 (Annual Gonadal Equivalent Dose, AGED). In order to delineate the spatial distribution of natural radionuclides on the radiological map and to identify the areas with low, medium and high radioactivity values, the Surfer 10 software was employed. Finally, the multivariate statistical analysis was performed to deduce the interdependency and any existing relationships between the radiological indices and the concentrations of the radionuclides. The results of this study, also compared with values of other locations of the Italian Peninsula characterized by similar local geological conditions, can be used as a baseline for future investigations about radioactivity background in the investigated area.

Description: Published

Description: 1729

Description: 7SR AMBIENTE – Servizi e ricerca per la società

Description: JCR Journal

Description: This Special Issue focuses on three main aspects of coastal-transitional systems, namely, complexity, vulnerability, and sensitivity; underlining the key role played by highly integrated multidisciplinary approaches to unraveling the records of the present and the past. This Issue aims to illustrate a set of recent advances in field and remote sensing observations, laboratory techniques, numerical modelling, and statistical analyses applied to the quantitative monitoring of coastal areas and the reconstruction of past landscape dynamics under changing climate-RSL conditions.

Description: Published

Description: 1182

Description: 5A. Ricerche polari e paleoclima

Description: JCR Journal

Description: The Gulf of La Spezia (GLS) in Northwest Italy is a rocky embayment with low fluvial influence facing the Mediterranean Sea. Past landscape dynamics were investigated through a multiproxy, facies-based analysis down to a core depth of 30 m. The integration of quantitative ostracod, foraminifera, and pollen analyses, supported by radiocarbon ages, proved to be a powerful tool to unravel the late Quaternary palaeoenvironmental evolution and its forcing factors. The complex interplay between relative sea-level (RSL), climatic changes, and geomorphological features of the embayment drove four main evolution phases. A barrier–lagoon system developed in response to the rising RSL of the Late Pleistocene (likely the Last Interglacial). The establishment of glacial conditions then promoted the development of an alluvial environment, with generalised erosion of the underlying succession and subsequent accumulation of fluvial strata. The Holocene transgression (dated ca. 9000 cal year BP) caused GLS inundation and the formation of a low-confined lagoon basin, which rapidly turned into a coastal bay from ca. 8000 cal year BP onwards. This latter environmental change occurred in response to the last Holocene stage of global sea-level acceleration, which submerged a morphological relief currently forming a drowned barrier-island complex in the embayment.

Description: Published

Description: 427

Description: 5A. Ricerche polari e paleoclima

Description: JCR Journal

Description: High-resolution images of Mars from National Aeronautics and Space Administration (NASA) rovers revealed mm-size loose haematite spherulitic deposits (nicknamed “blueberries”) similar to terrestrial iron-ooids, for which both abiotic and biotic genetic hypotheses have been proposed. Understanding the formation mechanism of these haematite spherules can thus improve our knowledge on the possible geologic evolution and links to life development on Mars. Here, we show that shape, size, fabric and mineralogical composition of the Martian spherules share similarities with corresponding iron spherules currently forming on the Earth over an active submarine hydrothermal system located off Panarea Island (Aeolian Islands, Mediterranean Sea). Hydrothermal fluids associated with volcanic activity enable these terrestrial spheroidal grains to form and grow. The recent exceptional discovery of a still working iron-ooid source on the Earth provides indications that past hydrothermal activity on the Red Planet is a possible scenario to be considered as the cause of formation of these enigmatic iron grains.

Description: Published

Description: 460

Description: 7SR AMBIENTE – Servizi e ricerca per la società

Description: JCR Journal

Description: We report a geophysical study across an active normal fault in the Southern Apennines. The surveyed area is the “Il Lago” Plain (Pettoranello del Molise), at the foot of Mt. Patalecchia (Molise Apennines, Southern Italy), a small tectonic basin filled by Holocene deposits located at the NW termination of the major Quaternary Bojano basin structure. This basin, on the NE flank of the Matese Massif, was the epicentral area of the very strong 26 July, 1805, Sant’Anna earthquake (I0 = X MCS, Mw = 6.7). The “Il Lago” Plain is bordered by a portion of the right-stepping normal fault system bounding the whole Bojano Quaternary basin (28 km long). The seismic source responsible for the 1805 earthquake is regarded as one of the most hazardous structures of the Apennines; however, the position of its NW boundary of this seismic source is debated. Geological, geomorphological and macroseismic data show that some coseismic surface faulting also occurred in correspondence with the border fault of the “Il Lago” Plain. The study of the “Il Lago” Plain subsurface might help to constrain the NW segment boundary of the 1805 seismogenic source, suggesting that it is possibly a capable fault, source for moderate (Mw 〈 5.5) to strong earthquakes (Mw ≥ 5.5). Therefore, we constrained the geometry of the fault beneath the plain using low-frequency Ground Penetrating Radar (GPR) data supported by seismic tomography. Seismic tomography yielded preliminary information on the subsurface structures and the dielectric permittivity of the subsoil. A set of GPR parallel profiles allowed a quick and high-resolution characterization of the lateral extension of the fault, and of its geometry at depth. The result of our study demonstrates the optimal potential of combined seismic and deep GPR surveys for investigating the geometry of buried active normal faults. Moreover, our study could be used for identifying suitable sites for paleoseismic analyses, where record of earthquake surface faulting might be preserved in Holocene lacustrine sedimentary deposits. The present case demonstrates the possibility to detect with high accuracy the complexity of a fault-zone within a basin, inferred by GPR data, not only in its shallower part, but also down to about 100 m depth.

Description: Published

Description: 1555

Description: 6T. Studi di pericolosità sismica e da maremoto

Description: JCR Journal

Description: Reliable seismic hazard analyses are crucial to mitigate seismic risk. When dealing with induced seismicity the standard Probabilistic Seismic Hazard Analysis (PSHA) has to be modified because of the peculiar characteristics of the induced events. In particular, the relative shallow depths, small magnitude, a correlation with field operations, and eventually non-Poisson recurrence time. In addition to the well-known problem of estimating the maximum expected magnitude, it is important to take into account how the industrial field operations affect the temporal and spatial distribution of the earthquakes. In fact, during specific stages of the project the seismicity may be hard to be modelled as a Poisson process—as usually done in the standard PSHA—and can cluster near the well or migrate toward hazardous known or—even worse—not known faults. Here we present a technique in which we modify the standard PSHA to compute time-dependent seismic hazard. The technique allows using non-Poisson models (BPT, Weibull, gamma and ETAS) whose parameters are fitted using the seismicity record during distinct stages of the field operations. As a test case, the procedure has been implemented by using data recorded at St. Gallen deep geothermal field, Switzerland, during fluid injection. The results suggest that seismic hazard analyses, using appropriate recurrence model, ground motion predictive equations, and maximum magnitude allow the expected ground-motion to be reliably predicted in the study area. The predictions can support site managers to decide how to proceed with the project avoiding adverse consequences.

Description: Published

Description: 2747

Description: 6T. Studi di pericolosità sismica e da maremoto

Description: JCR Journal

Description: .

Description: Published

Description: 11460

Description: 3T. Fisica dei terremoti e Sorgente Sismica

Description: JCR Journal

Description: In this work, we propose a geodetic model for the March 2021 Thessaly seismic sequence (TSS). We used the interferometric synthetic aperture radar (InSAR) technique and exploited a dataset of Sentinel-1 images to successfully detect the surface deformation caused by three major events of the sequence and constrain their kinematics, further strengthened by seismic data analysis. Our geodetic inversions are consistent with the activation of distinct blind faults previously unknown in this region: three belonging to the NE-dipping normal fault associated with the Mw 6.3 and Mw 6.0 events, and one belonging to the SW-dipping normal fault associated with the Mw 5.6, the last TSS major event. We performed a Coulomb stress transfer analysis and a 1D pore pressure diffusivity modeling to investigate the space–time evolution of the sequence; our results indicate that the seismic sequence developed in a sort of domino effect. The combination of the lack of historical records of large earthquakes in this area and the absence of mapped surface features produced by past faulting make seismic hazard estimation difficult for this area: InSAR data analysis and modeling have proven to be an extremely useful tool in helping to constrain the rupture characteristics.

Description: Published

Description: 3410

Description: 3T. Fisica dei terremoti e Sorgente Sismica

Description: JCR Journal

Description: Sediments infilling in intermontane basins in areas with high seismic activity can strongly affect ground-shaking phenomena at the surface. Estimates of thickness and density dis- tribution within these basin infills are crucial for ground motion amplification analysis, especially where demographic growth in human settlements has implied increasing seismic risk. We em- ployed a 3D gravity modeling technique (ITerative RESCaling—ITRESC) to investigate the Fucino Basin (Apennines, central Italy), a half-graben basin in which intense seismic activity has recently occurred. For the first time in this region, a 3D model of the Meso-Cenozoic carbonate basement morphology was retrieved through the inversion of gravity data. Taking advantage of the ITRESC technique, (1) we were able to (1) perform an integration of geophysical and geological data con- straints and (2) determine a density contrast function through a data-driven process. Thus, we avoided assuming a priori information. Finally, we provided a model that honored the gravity anomalies field by integrating many different kinds of depth constraints. Our results confirmed evidence from previous studies concerning the overall shape of the basin; however, we also high- lighted several local discrepancies, such as: (a) the position of several fault lines, (b) the position of the main depocenter, and (c) the isopach map. We also pointed out the existence of a new, un- known fault, and of new features concerning known faults. All of these elements provided useful contributions to the study of the tectono-sedimentary evolution of the basin, as well as key infor- mation for assessing the local site-response effects, in terms of seismic hazards.

Description: Published

Description: 398

Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica

Description: JCR Journal

Description: Investigations of seismic hazard across the range of tectonic environments on Earth are challenging because they require high quality data from multiple disciplines (e.g., seismology, structural geology, geomorphology, geochronology, archaeology, and geodesy) covering a wide range of temporal (days to millennial) and spatial (e.g., microns to hundreds of kilometers) scales and because seismogenic conditions and drivers are variable and fluctuating. The international earthquake science community has become more inter-disciplinary over the past several decades with the establishment of collaborative geological and geophysical centers such as (but not limited to) the Southern California Earthquake Center (SCEC, https://www.scec.org/), United States Geological Survey (USGS, https://earthquake.usgs.gov/), the National Institute of Geophysics and Volcanology (INGV, https://www.ingv.it/), the Interuniversity Center for 3D Seismotectonics with territorial applications (CRUST, https://www.crust.unich.it/). Collaborations along with improvements in data sources such as the implementation of denser seismic and geodetic arrays, high resolution (meter-scale and better) topographic data, improvements in geochronology, and the widespread availability of catalogued geophysical data, all present opportunities to unveil new details about active faulting. With that in mind, we proposed this Frontiers in Earth Science Research Topic as a venue for publishing disparate approaches for addressing seismic hazard. This Research Topic includes sixteen published articles investigating diverse tectonic regions of the Earth, at different time- and resolution scales, spanning from low-to-fast deformation rates contexts, using complementary data approaches spanning from earthquake geology to seismology, seismotectonics, and geomechanics (Figure 1). Here we provide a short review of the contributions organized by the investigation’s primary methodology.

Description: Published

Description: 738164

Description: 2T. Deformazione crostale attiva

Description: JCR Journal

Description: The identification of the mechanisms responsible for the deformation of calderas is of primary importance for our understanding of the dynamics of magmatic systems and the evaluation of volcanic hazards. We analyze twenty years (1997–2018) of geodetic measurements on Ischia Island (Italy), which include the Mt. Epomeo resurgent block, and is affected by hydrothermal manifestations and shallow seismicity. The data from the GPS Network and the leveling route show a constant subsidence with values up to 􀀀15 2.0 mm/yr and a centripetal displacement rate with the largest deformations on the southern flank of Mt. Epomeo. The joint inversion of GPS and levelling data is consistent with a 4 km deep source deflating by degassing and magma cooling below the southern flank of Mt. Epomeo. The depth of the source is supported by independent geophysical data. The Ischia deformation field is not related to the instability of the resurgent block or extensive gravity or tectonic processes. The seismicity reflects the dynamics of the shallow hydrothermal system being neither temporally nor spatially related to the deflation.

Description: Published

Description: 4648

Description: 1V. Storia eruttiva

Description: 2V. Struttura e sistema di alimentazione dei vulcani

Description: 4V. Processi pre-eruttivi

Description: 5V. Processi eruttivi e post-eruttivi

Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio

Description: JCR Journal

Description: The 56 ka Monte Epomeo Green Tuff (MEGT) resulted from the largest volume explosive eruption from Ischia island (south Italy). Its tephra is one of the main stratigraphic markers of the central Mediterranean area. Despite its importance, a detailed characterisation of the petrography and mineral chemistry of MEGT is lacking. To fill this gap, we present detailed petrographic description and electron microprobe mineral chemistry data on samples collected on-land from the MEGT. Juvenile clasts include pumice, scoria, and obsidian fragments with porphyritic/glomeroporphyritic, vitrophyric, and fragmental textures. The porphyritic index is 13–40 vol.%, and phenocryst phases include alkali-feldspar, plagioclase, clinopyroxene, ferrian phlogopite, and titano-magnetite, in order of decreasing abundance; accessory phases include sphene, hydroxy-fluor-apatite, and rare edenite. Plagioclase varies from predominant andesine to subordinate oligoclase, whereas alkali-feldspar is more variable from sanidine to anorthoclase; quasi-pure sanidine commonly occurs as either rim or recrystallisation overgrowth of large phenocrysts due to hydrothermal alteration. Secondary minerals include veins and patches of carbonate minerals, Fe-Mn oxyhydroxides, clay minerals, and zeolites. Clinopyroxene is ferroan diopside (En45–29Fs7–27) and never reaches Na-rich compositions. This feature allows the discrimination of MEGT from aegirine-bearing, distal tephra layers erroneously attributed to MEGT, with implications for the areal distribution of Ischia explosive deposits

Description: Published

Description: 955

Description: 6A. Geochimica per l'ambiente e geologia medica

Description: JCR Journal

Description: his contribution exposes the relative uncertainties associated with prediction patterns of landslide susceptibility. The patterns are based on relationships between direct and indirect spatial evidence of landslide occurrences. In a spatial database constructed for the modeling, direct evidence is the presence of landslide trigger areas, while indirect evidence is the presence of corresponding multivariate context in the form of digital maps. Five mathematical modeling functions are applied to capture and integrate evidence, indirect and direct, for separating landslide-presence areas from the areas of landslide assumed absence. Empirical likelihood ratios are used first to represent the spatial relationships. These are then combined by the models into prediction scores, ordered, equal-area ranked, displayed, and synthesized as prediction-rate curves. A critical task is assessing how uncertainty levels vary across the different prediction patterns, i.e., the modeling results visualized as fixed, colored groups of ranks. This is obtained by a strategy of iterative cross validation that uses only part of the direct evidence to model the pattern and the rest to validate it as a predictor. The conducted experiments in a mountainous area in northern Italy point at a research challenge that can now be confronted with relative rank-based statistics and iterative cross-validation processes. The uncertainty properties of prediction patterns are mostly unknown nevertheless they are critical for interpreting and justifying prediction results.

Description: This contribution was initially and partly supported by the European Commission Project “Mountain Risks: from Prediction to Management and Governance” (MRTN-CT-2006-035978, 2007–2010), Mountainrisk (2007).

Description: Published

Description: 3341

Description: 2TR. Ricostruzione e modellazione della struttura crostale

Description: JCR Journal

Description: Studying the spatiotemporal distribution and motion of water vapour (WV), the most variable greenhouse gas in the troposphere, is pivotal, not only for meteorology and climatology, but for geodesy, too. In fact, WV variability degrades, in an unpredictable way, almost all geodetic observation based on the propagation of electromagnetic signal through the atmosphere. We use data collected on a dense GPS network, designed for the purposes of monitoring the active Neapolitan (Italy) volcanoes, to retrieve the tropospheric delay parameters and precipitable water vapour (PWV). This study has two main targets: (a) the analysis of long datasets (11 years) to extract trends of climatological meaning for the region; (b) studying the main features of the time evolution of the PWV during heavy raining events to gain knowledge on the preparatory stages of highly impacting thunderstorms. For the latter target, both differential and precise point positioning (PPP) techniques are used, and the results are compared and critically discussed. An increasing trend, amounting to about 2 mm/decades, has been recognized in the PWV time series, which is in agreement with the results achieved in previous studies for the Mediterranean area. A clear topographic effect is detected for the Vesuvius volcano sector of the network and a linear relationship between PWV and altitude is quantitatively assessed. This signature must be taken into account in any modelling for the atmospheric correction of geodetic and remote-sensing data (e.g., InSAR). Characteristic temporal evolutions were recognized in the PWV in the targeted thunderstorms (which occurred in 2019 and 2020), i.e., a sharp increase a few hours before the main rain event, followed by a rapid decrease when the thunderstorm vanished. Accounting for such a peculiar trend in the PWV could be useful for setting up possible early warning systems for those areas prone to flash flooding, thus potentially providing a tool for disaster risk reduction.

Description: TRYAT (TRack Your ATmosphere) project (2017-1-DE02-KA202-004229) Co-funded by ERASMUS + Programme of the European Union.

Description: Published

Description: 1225

Description: 7A. Geofisica per il monitoraggio ambientale

Description: JCR Journal

Description: Investigation of sea-level positions during the highly-dynamic Marine Isotope Stage 3 (MIS 3: 29–61 kyrs BP) proves difficult because: (i) in stable and subsiding areas, coeval coastal sediments are currently submerged at depths of few to several tens of meters below the present sea level; (ii) in uplifting areas, the preservation of geomorphic features and sedimentary records is limited due to the erosion occurred during the Last Glacial Maximum (LGM) with sea level at a depth of −130 m, followed by marine transgression that determined the development of ravinement surfaces. This study discusses previous research in the Mediterranean and elsewhere, and describes new fossiliferous marine deposits overlaying the metamorphic bedrock at Cannitello (Calabria, Italy). Radiocarbon ages of marine shells (about 43 kyrs cal BP) indicate that these deposits, presently between 28 and 30 m above sea level, formed during MIS 3.1. Elevation correction of the Cannitello outcrops (considered in an intermediate-to-far-field position with respect to the ice sheet) with the local vertical tectonic rate and Glacial Isostatic Adjustment (GIA) rate allows the proposal of a revision of the eustatic depth for this highstand. Our results are consistent with recently proposed estimates based on a novel ice sheet modelling technique

Description: Published

Description: 2647

Description: 2T. Deformazione crostale attiva

Description: 3A. Geofisica marina e osservazioni multiparametriche a fondo mare

Description: JCR Journal

Description: In the polar regions, the atmospheric boundary layer (ABL) characteristics are strongly influenced by convection over leads, which are elongated channels in the sea ice covered ocean. The effects on the ABL depend on meteorological forcing and lead geometry. In non-convection-resolving models, in which several leads of potentially different characteristics might be present in a single grid cell, such surface characteristics and the corresponding ABL patterns are not resolved. Our main goal is to investigate potential implications for such models when these subgrid-scale patterns are not considered appropriately. We performed non-eddy-resolving microscale simulations over five different domains with leads of different widths separated by 100% sea ice. We also performed coarser-resolved simulations over a domain representing a few grid cells of a regional climate model, wherein leads were not resolved but accounted for via a fractional sea ice cover of 91% in each cell. Domain size and mean sea ice concentration were the same in all simulations. Differences in the domain-averaged ABL profiles and patterns of wind, temperature, and turbulent fluxes indicate a strong impact of both the leads and their geometry. Additional evaluations of different turbulence parameterizations show large effects by both gradient-independent heat transport and vertical entrainment.

Description: The depositional environments offshore of the Cilento Promontory have been reconstructed based on the geological studies performed in the frame of the marine geological mapping of the geological sheet n. 502 “Agropoli”. The littoral environment (toe-of-coastal cliff deposits and submerged beach deposits), the inner continental shelf environment (inner shelf deposits and bioclastic deposits), the outer continental shelf environment (outer shelf deposits and bioclastic deposits), the lowstand system tract and the Pleistocene relict marine units have been singled out. The littoral, inner shelf and outer shelf environments have been interpreted as the highstand system tract of the Late Quaternary depositional sequence. This sequence overlies the Cenozoic substratum (ssi unit), composed of Cenozoic siliciclastic rocks, genetically related with the Cilento Flysch. On the inner shelf four main seismo-stratigraphic units, overlying the undifferentiated acoustic basement have been recognized based on the geological interpretation of seismic profiles. On the outer shelf, palimpsest deposits of emerged to submerged beach and forming elongated dunes have been recognized on sub-bottom profiles and calibrated with gravity core data collected in previous papers. The sedimentological analysis of sea bottom samples has shown the occurrence of several grain sizes occurring in this portion of the Cilento offshore.

Description: Published

Description: 1083

Description: 3A. Geofisica marina e osservazioni multiparametriche a fondo mare

Description: JCR Journal

Description: The global sea-level rise (SLR) projections for the next few decades are the basis for developing flooding maps that depict the expected hazard scenarios. However, the spatially variable land subsidence has generally not been considered in the current projections. In this study, we use geodetic data from global navigation satellite system (GNSS), synthetic aperture radar interferometric measurements (InSAR) and sea-level data from tidal stations to show the combined effects of land subsidence and SLR along the coast between Catania and Marzamemi, in south-eastern Sicily (southern Italy). This is one of the most active tectonic areas of the Mediterranean basin, which drives accelerated SLR, continuous coastal retreat and increasing effects of flooding and storms surges. We focus on six selected areas, which show valuable coastal infrastructures and natural reserves where the expected SLR in the next few years could be a potential cause of significant land flooding and morphological changes of the coastal strip. Through a multidisciplinary study, the multi-temporal flooding scenarios until 2100, have been estimated. Results are based on the spatially variable rates of vertical land movements (VLM), the topographic features of the area provided by airborne Light Detection And Ranging (LiDAR) data and the Intergovernmental Panel on Climate Change (IPCC) projections of SLR in the Representative Concentration Pathways RCP 2.6 and RCP 8.5 emission scenarios. In addition, from the analysis of the time series of optical satellite images, a coastal retreat up to 70 m has been observed at the Ciane river mouth (Siracusa) in the time span 2001–2019. Our results show a diffuse land subsidence locally exceeding 10 ± 2.5 mm/year in some areas, due to compacting artificial landfill, salt marshes and Holocene soft deposits. Given ongoing land subsidence, a high end of RSLR in the RCP 8.5 at 0.52 ± 0.05 m and 1.52 ± 0.13 m is expected for 2050 AD and 2100 AD, respectively, with an exposed area of about 9.7 km2 that will be vulnerable to inundation in the next 80 years.

Description: Published

Description: 1108

Description: 7A. Geofisica per il monitoraggio ambientale

Description: JCR Journal

Description: SO2 cameras are able to measure rapid changes in volcanic emission rate but require accurate calibrations and corrections to convert optical depth images into slant column densities. We conducted a test at Masaya volcano of two SO2 camera calibration approaches, calibration cells and co-located spectrometer, and corrected both calibrations for light dilution, a process caused by light scattering between the plume and camera. We demonstrate an advancement on the image-based correction that allows the retrieval of the scattering efficiency across a 2D area of an SO2 camera image. When appropriately corrected for the dilution, we show that our two calibration approaches produce final calculated emission rates that agree with simultaneously measured traverse flux data and each other but highlight that the observed distribution of gas within the image is different. We demonstrate that traverses and SO2 camera techniques, when used together, generate better plume speed estimates for traverses and improved knowledge of wind direction for the camera, producing more reliable emission rates. We suggest combining traverses and the SO2 camera should be adopted where possible.

Description: Published

Description: 935

Description: 5V. Processi eruttivi e post-eruttivi

Description: JCR Journal

Description: We developed a new retrieval algorithm based on the Infrared Atmospheric Sounding Interferometer (IASI) observations, called AEROIASI-H2SO4, to measure the extinction and mass concentration of sulphate aerosols (binary solution droplets of sulphuric acid and water), with moderate random uncertainties (typically 35% total uncertainty for column mass concentration estimations). The algorithm is based on a self-adapting Tikhonov–Phillips regularization method. It is here tested over a moderate-intensity eruption of Mount Etna volcano (18 March 2012), Italy, and is used to characterise this event in terms of the spatial distribution of the retrieved plume. Comparisons with simultaneous and independent aerosol optical depth observations from MODIS (Moderate Resolution Imaging Spectroradiometer), SO2 plume observations from IASI and simulations with the CHIMERE chemistry/transport model show that AEROIASI-H2SO4 correctly identifies the volcanic plume horizontal morphology, thus providing crucial new information towards the study of volcanic emissions, volcanic sulphur cycle in the atmosphere, plume evolution processes, and their impacts. Insights are given on the possible spectroscopic evidence of the presence in the plume of larger-sized particles than previously reported for secondary sulphate aerosols from volcanic eruptions.

Description: Published

Description: 1808

Description: 5V. Processi eruttivi e post-eruttivi

Description: JCR Journal

Description: Radon (222Rn) is a natural radioactive gas formed in rocks and soil by the decay of its parent nuclide (238-Uranium). The rate at which radon migrates to the surface, be it along faults or directly emanated from shallow soil, represents the Geogenic Radon Potential (GRP) of an area. Considering that the GRP is often linked to indoor radon risk levels, we have conducted multi-disciplinary research to: (i) define local GRPs and investigate their relationship with associated indoor Rn levels; (ii) evaluate inhaled radiation dosages and the associated risk to the inhabitants; and (iii) define radon priority areas (RPAs) as required by the Directive 2013/59/Euratom. In the framework of the EU-funded LIFE-Respire project, a large amount of data (radionuclide content, soil gas samples, terrestrial gamma, indoor radon) was collected from three municipalities located in different volcanic districts of the Lazio region (central Italy) that are characterised by low to high GRP. Results highlight the positive correlation between the radionuclide content of the outcropping rocks, the soil Rn concentrations and the presence of high indoor Rn values in areas with medium to high GRP. Data confirm that the Cimini-Vicani area has inhalation dosages that are higher than the reference value of 10 mSv/y.

Description: European LIFE projects, LIFE-Respire (LIFE16 ENV/IT/000553) projects; Istituto Nazionale per l’Assicurazione contro gli Infortuni sul Lavoro, project number: INAIL/CNR-IGAG (P19L06)

Description: Published

Description: 666

Description: 6A. Geochimica per l'ambiente e geologia medica

Description: JCR Journal

Description: The characterisation of aerosol emissions from volcanoes is a crucial step towards the assessment of their importance for regional air quality and regional-to-global climate. In this paper we present, for the first time, the characterisation of aerosol emissions of the Stromboli volcano, in terms of their optical properties and emission flux rates, carried out during the PEACETIME oceanographic campaign. Using sun-photometric observations realised during a near-ideal full plume crossing, a plume-isolated aerosol optical depth of 0.07–0.08 in the shorter-wavelength visible range, decreasing to about 0.02 in the near infrared range, was found. An Ångström exponent of 1.40 0.40 was also derived. This value may suggest the dominant presence of sulphate aerosols with a minor presence of ash. During the crossing, two separate plume sections were identified, one possibly slightly affected by ash coming from a mild explosion, and the other more likely composed of pure sulphate aerosols. Exploiting the full crossing scan of the plume, an aerosol emission flux rate of 9–13 kg/s was estimated. This value was 50% larger than for typical passively degassing volcanoes, thus pointing to the importance of mild explosions for aerosol emissions in the atmosphere.

Description: Published

Description: 4016

Description: 4V. Processi pre-eruttivi

Description: JCR Journal

Description: We propose a multi-temporal-scale analysis of ground deformation data using both high-rate tilt and GNSS measurements and the DInSAR and daily GNSS solutions in order to investigate a sequence of four paroxysmal episodes of the Voragine crater occurring in December 2015 at Mt. Etna (Italy). The analysis aimed at inferring the magma sources feeding a sequence of very violent eruptions, in order to understand the dynamics and to image the shallow feeding system of the volcano that enabled such a rapid magma accumulation and discharge. The high-rate data allowed us to constrain the sources responsible for the fast and violent dynamics of each paroxysm, while the cumulated deformation measured by DInSAR and daily GNSS solutions, over a period of 12 days encompassing the entire eruptive sequence, also showed the deeper part of the source involved in the considered period, where magma was stored. We defined the dynamics and rates of the magma transfer, with a middle-depth storage of gas-rich magma that charges, more or less continuously, a shallower level where magma stops temporarily, accumulating pressure due to the gas exsolution. This machine-gun-like mechanism could represent a general conceptual model for similar events at Etna and at all volcanoes.

Description: Published

Description: 4630

Description: 5V. Processi eruttivi e post-eruttivi

Description: JCR Journal

Description: The M6.3 earthquake that occurred in southern Lazio (Central Italy) in 1654 is the strongest seismic event to have occurred in the area. However, our knowledge about this earthquake is scarce and no study has been devoted to the individuation of its causative source. The main purpose of this study is putting together all of the information available for this shock to provide reliable landmarks to identify its seismic source. To this end, we present and discuss historical, hydrological, geological, and seismological data, both reviewed and newly acquired. An important, novel part of this study relies on an analysis of the coseismic hydrological changes associated with the 1654 earthquake and on the comparison of their distribution with models of the coseismic strain field induced by a number of potential seismogenic sources. We find more satisfactory results when imposing a lateral component of slip to the faults investigated. In particular, oblique left-lateral sources display a better fit between strain and hydrological signatures. Finally, the cross-analysis between the results from modeling and the other pieces of evidence collected point to the Sora fault, with its trend variability, as the probable causative source of the 1654 earthquake.

Description: Published

Description: 1150

Description: 4T. Sismicità dell'Italia

Description: JCR Journal

Description: In this study, we present a preliminary recognition of geohazards at the natural reserve archipelago “Lachea Islet and Cyclop Rocks” by integrating infrared thermography (IRT) and morphological-aerial interpretation. The study area, located in the wider setting of the UNESCO (United Nations Educational, Scientific and Cultural Organization) World Heritage Mount Etna (eastern Sicily), is a worldwide renowned tourist destination suffering from a limited fruition due to the instability of rock masses. The peculiar setting of the area, represented by steep sea rocks and an islet, requires the employment of remote surveying methodologies for the preliminary slope characterization in the perspective of safe ground surveys. In this paper, IRT analysis allowed the recognition of signs of past rockfalls, as well as the presence of loose rock material likely laying in unstable conditions, thanks to the variation of the surface temperature characterizing the slope. The combination of IRT outcomes with morphological-aerial data allowed recognizing the potential source areas of future rockfalls, which were modeled through trajectory simulations. Results showed that a relevant strip of sea surrounding the studied sea rock could be crossed by falling blocks, suggesting the need of instituting a forbidden area for a safe fruition of the reserve. Furthermore, IRT allowed for the recognition of some peculiar features linked to the presence of tectonic lines. Such correspondence was validated by a comparison with literature structural data, proving the potential of such remote methodological approach. This represents a new aspect of the application of IRT to other fields of geosciences, thus representing a starting point for the scientific development of new technological branches.

Description: Published

Description: 1082

Description: 2T. Deformazione crostale attiva

Description: JCR Journal

Description: In Antarctica, the severe climatic conditions and the thick ice sheet that covers the largest and most internal part of the continent make it particularly difficult to systematically carry out geophysical and geodetic observations on a continental scale. It prevents the comprehensive understanding of both the onshore and offshore geology as well as the relationship between the inner part of East Antarctica (EA) and the coastal sector of Victoria Land (VL). With the aim to reduce this gap, in this paper multiple geophysical dataset collected since the 1980s in Antarctica by Programma Nazionale di Ricerche in Antartide (PNRA) were integrated with geodetic observations. In particular, the analyzed data includes: (i) Geodetic time series from Trans Antarctic Mountains DEFormation (TAMDEF), and Victoria Land Network for DEFormation control (VLNDEF) GNSS stations installed in Victoria Land; (ii) the integration of on-shore (ground points data and airborne) gravity measurements in Victoria Land and marine gravity surveys performed in the Ross Sea and the narrow strip of Southern Ocean facing the coasts of northern Victoria Land. Gravity data modelling has improved the knowledge of the Moho depth of VL and surrounding the offshore areas. By the integration of geodetic and gravitational (or gravity) potential results it was possible to better constrain/identify four geodynamic blocks characterized by homogeneous geophysical signature: the Southern Ocean to the N, the Ross Sea to the E, the Wilkes Basin to the W, and VL in between. The last block is characterized by a small but significant clockwise rotation relative to East Antarctica. The presence of a N-S to NNW-SSE 1-km step in the Moho in correspondence of the Rennick Geodynamic Belt confirms the existence of this crustal scale discontinuity, possibly representing the tectonic boundary between East Antarctica and the northern part of VL block, as previously proposed by some geological studies.

Description: Published

Description: 87

Description: 2T. Deformazione crostale attiva

Description: JCR Journal

Description: The atmospheric humidity in the Polar Regions is an important factor for the global budget of water vapour, which is a significant indicator of Earth’s climate state and evolution. The Global Navigation Satellite System (GNSS) can make a valuable contribution in the calculation of the amount of Precipitable Water Vapour (PW). The PW values retrieved from Global Positioning System (GPS), hereafter PWGPS, refer to 20-year observations acquired by more than 40 GNSS geodetic stations located in the polar regions. For GNSS stations co-located with radio-sounding stations (RS), which operate Vaisala radiosondes, we estimated the PW from RS observations (PWRS). The PW values from the ERA-Interim global atmospheric reanalysis were used for validation and comparison of the results for all the selected GPS and RS stations. The correlation coefficients between times series are very high: 0.96 for RS and GPS, 0.98 for RS and ERA in the Arctic; 0.89 for RS and GPS, 0.97 for RS and ERA in Antarctica. The Root-Mean-Square of the Error (RMSE) is 0.9 mm on average for both RS vs. GPS and RS vs. ERA in the Arctic, and 0.6 mm for RS vs. GPS and 0.4 mm for RS vs. ERA in Antarctica. After validation, long-term trends, both for Arctic and Antarctic regions, were estimated using Hector scientific software. Positive PWGPS trends dominate at Arctic sites near the borders of the Atlantic Ocean. Sites located at higher latitudes show no significant values (at 1σ level). Negative PWGPS trends were observed in the Arctic region of Greenland and North America. A similar behaviour was found in the Arctic for PWRS trends. The stations in the West Antarctic sector show a general positive PWGPS trend, while the sites on the coastal area of East Antarctica exhibit some significant negative PWGPS trends, but in most cases, no significant PWRS trends were found. The present work confirms that GPS is able to provide reliable estimates of water vapour content in Arctic and Antarctic regions too, where data are sparse and not easy to collect. These preliminary results can give a valid contribution to climate change studies.

Description: Published

Description: 4871

Description: 5A. Ricerche polari e paleoclima

Description: JCR Journal

Description: Immersive virtual reality can potentially open up interesting geological sites to students, academics and others who may not have had the opportunity to visit such sites previously. We study how users perceive the usefulness of an immersive virtual reality approach applied to Earth Sciences teaching and communication. During nine immersive virtual reality-based events held in 2018 and 2019 in various locations (Vienna in Austria, Milan and Catania in Italy, Santorini in Greece), a large number of visitors had the opportunity to navigate, in immersive mode, across geological landscapes reconstructed by cutting-edge, unmanned aerial system-based photogrammetry techniques. The reconstructed virtual geological environments are specifically chosen virtual geosites, from Santorini (Greece), the North Volcanic Zone (Iceland), and Mt. Etna (Italy). Following the user experiences, we collected 459 questionnaires, with a large spread in participant age and cultural background. We find that the majority of respondents would be willing to repeat the immersive virtual reality experience, and importantly, most of the students and Earth Science academics who took part in the navigation confirmed the usefulness of this approach for geo-education purposes.

Description: This research has been provided in the framework of the following projects: (i) the MIUR project ACPR15T4_00098–Argo3D (http://argo3d.unimib.it/ (accessed on 26 November 2021)); (ii) 3DTeLC Erasmus + Project 2017-1-UK01-KA203-036719 (http://www.3dtelc.com (accessed on 26 November 2021)); (iii) EGU 2018 Public Engagement Grant (https://www.egu.eu/outreach/peg/ (accessed on 26 November 2021)). Agisoft Metashape is acknowledged for photogrammetric data processing. This article is also an outcome of Project MIUR–Dipartimenti di Eccellenza 2018–2022. Finally, this paper is an outcome of the Virtual Reality lab for Earth Sciences—GeoVires lab (https://geovires.unimib.it/ (accessed on 26 November 2021)). The work supports UNESCO IGCP 692 ‘Geoheritage for Resilience’.

Description: Published

Description: 9

Description: 1TM. Formazione

Description: JCR Journal

Description: IONORING (IONOspheric RING) is a tool capable to provide the real-time monitoring and modeling of the ionospheric Total Electron Content (TEC) over Italy, in the latitudinal and longitudinal ranges of 35°N–48°N and 5°E–20°E, respectively. IONORING exploits the Global Navigation Satellite System (GNSS) data acquired by the RING (Rete Integrata Nazionale GNSS) network, managed by the Istituto Nazionale di Geofisica e Vulcanologia (INGV). The system provides TEC real-time maps with a very fine spatial resolution (0.1° latitude x 0.1° longitude), with a refresh time of 10 min and a typical latency below the minute. The TEC estimated at the ionospheric piercing points from about 40 RING stations, equally distributed over the Italian territory, are interpolated using locally (weighted) regression scatter plot smoothing (LOWESS). The validation is performed by comparing the IONORING TEC maps (in real-time) with independent products: (i) the Global Ionospheric Maps (GIM) - final product- provided by the International GNSS Service (IGS), and (ii) the European TEC maps from the Royal Observatory of Belgium. The validation results are satisfactory in terms of Root Mean Square Error (RMSE) between 2 and 3 TECu for both comparisons. The potential of IONORING in depicting the TEC daily and seasonal variations is analyzed over 3 years, from May 2017 to April 2020, as well as its capability to account for the effect of the disturbed geospace on the ionosphere at mid-latitudes. The IONORING response to the X9.3 flare event of September 2017 highlights a sudden TEC increase over Italy of about 20%, with a small, expected dependence on the latitude, i.e., on the distance from the subsolar point. Subsequent large regional TEC various were observed in response to related follow-on geomagnetic storms. This storm is also used as a case event to demonstrate the potential of IONORING in improving the accuracy of the GNSS Single Point Positioning. By processing data in kinematic mode and by using the Klobuchar as the model to provide the ionospheric correction, the resulting Horizontal Positioning Error is 4.3 m, lowering to, 3.84 m when GIM maps are used. If IONORING maps are used as the reference ionosphere, the error is as low as 2.5 m. Real-times application and services in which IONORING is currently integrated are also described in the conclusive remarks.

Description: This research is part of “Progetto INGV Pianeta Dinamico (Codice Unico Progetto: CUP D53J19000170001) funded by MUR ("Fondo finalizzato al rilancio degli investimenti delle amministrazioni centrali dello Stato e allo sviluppo del Paese, legge 145/2018”), Tema 8–ATTEMPT–2021

Description: Published

Description: 3290

Description: 2A. Fisica dell'alta atmosfera

Description: JCR Journal

Description: The Lau Basin is a back-arc region formed by the subduction of the Pacific plate below the Australian plate. We studied the regional morphology of the back-arc spreading centers of the Northern Lau basin, and we compared it to their relative spreading rates. We obtained a value of 60.2 mm/year along the Northwest Lau Spreading Centers based on magnetic data, improving on the spreading rate literature data. Furthermore, we carried out numerical models including viscoplastic rheologies and prescribed surface velocities, in an upper plate-fixed reference frame. Although our thermal model points to a high temperature only near the Tonga trench, the model of the second invariant of the strain rate shows active deformation in the mantle from the Tonga trench to ~800 km along the overriding plate. This explains the anomalous magmatic production along all the volcanic centers in the Northern Lau Back-Arc Basin.

Description: Published

Description: 50

Description: 3A. Geofisica marina e osservazioni multiparametriche a fondo mare

Description: JCR Journal

Description: This study discusses the siliciclastic to bioclastic deposits (in particular, the rhodolith deposits) in the Gulf of Naples based on sedimentological and seismo-stratigraphic data. The selected areas are offshore Ischia Island (offshore Casamicciola, Ischia Channel), where a dense network of sea-bottom samples has been collected, coupled with Sparker Multi-tip seismic lines, and offshore Procida–Pozzuoli (Procida Channel), where sea-bottom samples are available, in addition to Sparker seismic profiles. The basic methods applied in this research include sedimentological analysis, processing sedimentological data, and assessing seismo-stratigraphic criteria and techniques. In the Gulf of Naples, and particularly offshore Ischia, bioclastic sedimentation has been controlled by seafloor topography coupled with the oceanographic setting. Wide seismo-stratigraphic units include the bioclastic deposits in their uppermost part. Offshore Procida–Pozzuoli, siliciclastic deposits appear to prevail, coupled with pyroclastic units, and no significant bioclastic or rhodolith deposits have been outlined based on sedimentological and seismo-stratigraphic data. The occurrence of mixed siliciclastic–carbonate depositional systems is highlighted in this section of the Gulf of Naples based on the obtained results, which can be compared with similar systems recognized in the central Tyrrhenian Sea (Pontine Islands).

Description: Published

Description: 44

Description: 1T. Struttura della Terra

Description: JCR Journal

Description: The present research represents an approach toward the recycling of extractive waste inspired by circular economy and sustainability that is developed in accordance with Goal 12 of the United Nations 2030 Agenda for Sustainable Development Goals. A new procedure for the recovery of REEs from fluorite–barite–galena ores with calcite gangue from the Silius mine (Sardinia, Italy) is presented. The considered samples are waste materials of Silius mineralization, collected in the old processing plant of Assemini (near Cagliari). In this orebody, REE minerals consist of prevailing synchysite (a REE-bearing fluorocarbonate) and subordinate xenotime-Y (a Y-bearing phosphate). REE fluorocarbonates are extracted using 50% K2CO3 as the leaching solution, at 100 °C. Using a solution (mL)/sample (g) ratio of 25, about 10% of the total REE content of the considered sample is extracted within 1 h. At the laboratory scale, such alkaline leaching of REE from the waste materials allows the recovery of the CO2 produced as K2CO3 from concentrated KOH, in accordance with a circular flow. Further work is ongoing to scale up the process into a pilot plant, to prove that the method developed within this research can be economically feasible, socially suitable, and environmentally respectful.

Description: Published

Description: 14000

Description: 1TR. Georisorse

Description: JCR Journal

Description: Volcanology, seismology and Earth Sciences in general, like all quantitative sciences, are increasingly dependent on the quantity and quality of data acquired. In recent dec-ades, a marked evolution has characterized Earth sciences towards a greater use of ana-lytical and numerical approaches, shifting these fields from the natural to the physical sciences. Understanding the physical behavior of active volcanoes and faults is critical to as-sess the hazards affecting the population living close to active volcano and seismic areas, and thus to mitigate the risks posed by those threats [1,2]. The knowledge of a physical process requires the acquisition of a huge amount of information (data) on that particular phenomenon. Today, different kinds of data record the processes that operate in volcanic and tec-tonic systems and provide insights that can lead to improved predictions of potential hazards, both immediate and long term. The geoscience community has collected an enormous wealth of data that require further analysis. The diversity and quantity of these geoscience data and collections continue to expand [3]. The increasing amount of data and the availability of new technologies and instru-mentation at an ever-greater rate open new frontiers and challenges for acquiring, trans-mitting, archiving, processing and analyzing the newly available datasets. Guo [4] pre-dicted growth for the general digital universe size of factor 10 from 2016 to 2025. Among all digital data, scientific data are those relevant to the observation of natural phenomena and characterized by non-repeatability, high uncertainty, high dimensionality and a high degree of computational complexity [4]. This means that scientific data need to be well preserved, due to the non-repeatability, and implies a parallel growth of processing capa-bilities to be well exploited. Cheng et al. [5] highlighted the striking growth of Earth Sci-ence data from molecular to astronomical scales and the increasing use of supercompu-ting tools for supporting geoscience research. The authors evidence how, with the contin-uously increasing availability of digital data, Earth Sciences are also turning from the tra-ditional question-driven or problem-driven approach, where scientists seek to find an-swers to known questions, to the new data-driven one where scientists apply a data dis-covery process that might find answers to still unknown questions. In agreement with Cheng et al. [5], we believe that new integrated multi-disciplinary knowledge systems and new data discovery techniques for handling and mining big data for knowledge discovery would spur the integration of transdisciplinary and mul-ti-dimensional Earth science data. Furthermore, this will help the transition from a nar-row focus on separate disciplines to a holistic, comprehensive and integrative focus of the different disciplines linked to the Earth Sciences. With this aim, for this special issue titled “Data Processing and Modeling on Volcan-ic and Seismic Areas”, we invited articles on all aspects of solid Earth Science that made use of data to analyze and model processes related to volcanoes or earthquakes. Manuscripts with various types of analyses, including volcanic ground deformation modeling, seismic swarm characterization and volcanic gas measurement, have been proposed and published. The collection provides an insight into the enormous need for increasingly complex data analysis and modeling techniques to try to describe the natural phenomena here considered. This special issue was introduced to collect the latest research on the processing and modeling of Earth Sciences data, and to address challenging problems with all topics re-lated to volcanoes and seismic areas. Various subjects have been addressed in this collec-tion, mainly on data processing for volcanic studies (three papers), tectonics (two papers) and one paper on data analysis of a new instrument to measure gases. The first contribution to this collection [6] reports the results of the processing and combination of high-rate and low-rate geodetic data for revealing the dynamics underly-ing violent volcanic eruptions at Mount Etna. This study evidences the wide spectrum of ground deformation produced by these phenomena, to be investigated, processed and modeled in order to generate a picture of the feeding system of the volcano and better un-derstand its dynamics and rates of magma transfer in the upper crust. Another contribution focuses on volcanoes [7]: the authors exploit 20 years of high temporal resolution satellite Thermal Infra-Red (TIR) data collected over three active vol-canoes (Etna, Shishaldin and Shinmoedake). They present the results of an analysis of this dataset performed through a preliminary RST (Robust Satellite Techniques) algorithm implementation to TIR data from the Advanced Spaceborne Thermal Emission and Re-flection Radiometer (ASTER). This approach ensures efficient identification and mapping of volcanic thermal features even of a low intensity level, which is also useful in the per-spective of an operational multi-satellite observing system. The contribution by Woohyun Son et al. [8] proposes specific depth-domain data processing of migration velocity analysis (MVA) of seismic data collected during a survey on a saline aquifer sediment in the Southern Continental Shelf of Korea. This analysis al-lowed the authors to identify and determine the precise depth of a basalt flow that could act as a cap rock for CO2 storage beneath the aquifer. The investigation, through the geo-logical model obtained from both time- and depth-domain processing, provides suitable information for locating the best drilling sites for CO2 injection, maximizing the storage volume. In volcanic areas, gases represent important physical evidence of volcanic processes that need to be measured. Parracino et al. [9] have shown how novel range-resolved DI-AL-Lidar (Differential Absorption Light Detection and Ranging) could herald a new era in the observation of long-term volcanic CO2 gases. An accurate and integrated analysis of different types of data such as GNSS, seismic and MT-InSAR, has led, in the work by Gatsios et al. [10], to a first account of deformation processes and their temporal evolution over recent years for Methana (Greece), thus providing initial information to feed into a volcano baseline hazard assessment and mon-itoring system. Seismic data are among the most important data to understand the dynamics of the Earth’s interior. A consistent analysis of a seismic swarm allowed Kostoglou et al. [11] to shed more light on the regional geodynamics of the Kefalonia Transform Fault Zone (Greece), and to follow the temporal evolution of the b-value to distinguish between fore-shock and aftershock behaviors.

Description: Published

Description: 10759

Description: 6SR VULCANI – Servizi e ricerca per la società

Description: JCR Journal

Description: The Neapolitan volcanic area includes three active and high-risk volcanoes: Campi Flegrei caldera, Somma–Vesuvius, and Ischia island. The Campi Flegrei volcanic area is a typical example of a resurgent caldera, characterized by intense uplift periods followed by subsidence phases (bradyseism). After about 21 years of subsidence following the 1982–1984 unrest, a new inflation period started in 2005 and, with increasing rates over time, is ongoing. The overall uplift from 2005 to December 2019 is about 65 cm. This paper provides the history of the recent Campi Flegrei caldera unrest and an overview of the ground deformation patterns of the Somma–Vesuvius and Ischia volcanoes from continuous GPS observations. In the 2000–2019 time span, the GPS time series allowed the continuous and accurate tracking of ground and seafloor deformation of the whole volcanic area. With the aim of improving the research on volcano dynamics and hazard assessment, the full dataset of the GPS time series from the Neapolitan volcanic area from January 2000 to December 2019 is presented and made available to the scientific community

Description: Published

Description: 2725

Description: 4V. Processi pre-eruttivi

Description: JCR Journal

Description: This Special Issue of Minerals collects seven different scientific contributions highlighting how magma chamber processes and eruption dynamics studied either in the laboratory or in nature may ultimately control the evolutionary histories and geochemical complexities of igneous rocks. The main purpose is to report novel results bearing on the most important mechanisms that govern the textural and compositional changes of minerals and their host rocks. Different scenarios and case studies are presented here regarding the polybaric–polythermal solidification of magmas under either closed or open conditions. Results from these scientific contributions have the potential to elucidate those physicochemical parameters which play key roles in crystallizing systems, when degassing, magma mixing, and magma–fluid–crust interaction phenomena take place over different temporal and spatial scales. Rare-earth element (REE) modeling based on bulk rock analyses of crustal and mantle xenoliths from alkaline lavas and pyroclastic rocks is used to highlight magma–crust interaction processes between MORB oceanic crust and overlying sediments located beneath the Cape Verde oceanic plateau [1]. Clinopyroxene-based thermobarometric calculations indicate crystallization from magmas stored within the oceanic lithospheric mantle. During ascent towards the surface, these magmas encountered overlying sedimentary rocks and, occasionally, incorporated xenoliths, recording variable degrees of crustal contamination [1]. By integrating geochronological (U-Pb and 40Ar/39Ar) and isotope (Sr-Nd-Pb-Hf) data, a geotectonic model is proposed for Mesozoic magmatic rocks from the South China Sea by involving subduction of an early Neo-Tethyan lithospheric domain [2]. The geochronological and geochemical signatures of adakitic granodiorites and Nb-enriched basalts from the Xiaozhenzhu Seamount outline contemporaneous formation of these products during northward subduction of the proto-South China Sea along the SE Asian continental margin in the Early Cretaceous [2]. A singularity analysis (frequency anomalies) is also applied to U–Pb ages of zircons from the Great Xing’an Range to characterize the causative relationship between age abnormality and Pacific Plate subduction [3]. Data interpretation is consistent with independent geological and geochemical constraints, thus emphasizing the importance of singularity analysis for quantitative characterization of the time scales involved in long-term volcanic activity and past tectonic regimes [3]. The Bushveld Complex (South Africa) is one of the largest igneous complexes on Earth and is also a major deposit of economically viable mineralization. The Merensky Unit, within the Bushveld Complex, indicates origin by magma mixing phenomena resulting from multiple replenishment events [4]. The final solidification process is governed by variable degrees of undercooling, with a role also played by crystal compaction and migration of interstitial fluids. In this perspective, the Merensky Unit is not a cyclic unit sensu strictu as the product of closed-system fractional crystallization but rather the Bushveld magma chamber was characterized by open-system processes leading to formation of the Merensky Unit [4]. The Zhesang gold deposit (southeastern Yunnan, China) is another important mining area, located in the Dian-Qian-Gui region. Calcite is a common gangue mineral of the Zhesang deposit, and its origin is related to both ore-stage or post-ore-stage processes [5]. REE and C-O isotopic characteristics of calcite suggest that fluids feeding the growth of ore-stage crystals were derived from a mixture of crustal fluids by meteoric water-leaching wall rocks and a small amount of basic magmatic fluids. On the other hand, the formation of post-ore calcite crystals was driven by fluid–rock interaction phenomena between meteoric water and marine carbonates [5]. Mt. Etna (Sicily, Italy) is the largest volcano in Europe and one of the most active and most intensely monitored on Earth. Hydrous crystallization experiments conducted on trachybasaltic compositions document the intriguing role of H2O in the differentiation of magmas ascending throughout the entire plumbing system [6]. The crystallization regime at shallow crustal levels suddenly shifts from H2O-undersaturated to H2O-saturated conditions due to the impulsive and irregular arrival of volatile-rich magmas from mantle depths. Abundant release of H2O leads to upward acceleration of magmas feeding gas-dominated, sustained explosive eruptions, as well as to the voluminous gas emissions measured at summit craters and flank vents [6]. Furthermore, kinetically controlled cation redistributions in phenocrysts from sill-like magmatic intrusions at Mt. Etna testify to dynamic crystallization conditions that are principally controlled by degassing-induced undercooling paths [7]. Early formation of clinopyroxene at depth was the main controlling factor for the REE signature of the sill, whereas subsequent H2O loss at lower pressures enlarged the stability field of plagioclase, causing trace element enrichments at pre- and syn-eruptive conditions [7].

Description: Published

Description: 102

Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici

Description: JCR Journal

Description: Two paroxysmal explosions occurred at Stromboli on July 3 and August 28, 2019, the first of which caused the death of a young tourist. After the first paroxysm an effusive activity began from the summit vents and affected the NW flank of the island for the entire period between the two paroxysms. We carried out an unsupervised analysis of seismic and infrasonic data of Strombolian explosions over 10 months (15 November 2018–15 September 2019) using a Self- Organizing Map (SOM) neural network to recognize changes in the eruptive patterns of Stromboli that preceded the paroxysms. We used a dataset of 14,289 events. The SOM analysis identified three main clusters that showed different occurrences with time indicating a clear change in Stromboli’s eruptive style before the paroxysm of 3 July 2019. We compared the main clusters with the recordings of the fixed monitoring cameras and with the Ground-Based Interferometric Synthetic Aperture Radar measurements, and found that the clusters are associated with different types of Strombolian explosions and different deformation patterns of the summit area. Our findings provide new insights into Strombolian eruptive mechanisms and new perspectives to improve the monitoring of Stromboli and other open conduit volcanoes.

Description: This work was supported by the project Progetto Strategico Dipartimentale INGV 2019 “Forecasting eruptive activity at Stromboli volcano: timing, eruptive style, size, intensity and duration” (FIRST). This work is also supported by a Marie Sklodowska-Curie Innovative Training Network Fellowship of the European Commission’s Horizon 2020 Programme under Contract Number 765710 INSIGHTS. This work benefited from the EU (DG ECHO) Project EVE n. 826292. This work has been partially supported by the “Presidenza del Consiglio dei Ministri–Dipartimento della Protezione Civile” (Presidency of the Council of Ministers–Department of Civil Protection; Scientific Responsibility: N.C.). However, this publication does not necessarily represent the official opinion and policies of the department.

Description: Published

Description: 1287

Description: 4V. Processi pre-eruttivi

Description: JCR Journal

Description: The Etna volcano is renowned worldwide for its extraordinary lava fountains that rise several kilometers above the vent and feed eruptive columns, then drift hundreds of kilometers away from the source. The Italian Istituto Nazionale di Geofisica e Vulcanologia-Osservatorio Etneo (INGV-OE) is responsible for the monitoring of Mt. Etna, and for this reason, has deployed a network of visible and thermal cameras around the volcano. From these cameras, INGV-OE keeps a keen eye, and is able to observe the eruptive activity, promptly advising the civil protection and aviation authorities of any changes, as well as quantifying the spread of lava flows and the extent of pyroclastic and ash plumes by using a careful analysis of the videos recorded by the monitoring cameras. However, most of the work involves analysis carried out by hand, which is necessarily approximate and time-consuming, thus limiting the usefulness of these results for a prompt hazard assessment. In addition, the start of lava fountains is often a gradual process, increasing in strength from Strombolian activity, to intermediate explosive activity, and eventually leading to sustained lava fountains. The thresholds between these different fields (Strombolian, Intermediate, and lava fountains) are not clear cut, and are often very difficult to distinguish by a manual analysis of the images. In this paper, we presented an automated routine that, when applied to thermal images and with good weather conditions, allowed us to detect (1) the starting and ending time of each lava fountain, (2) the area occupied by hot pyroclasts, (3) the elevation reached by the lava fountains over time, and (4) eventually, to calculate in real-time the erupted volume of pyroclasts, giving results close to the manual analysis but more focused on the sustained portion of the lava fountain, which is also the most dangerous. This routine can also be applied to other active volcanoes, allowing a prompt and uniform definition of the timing of the lava fountain eruptive activity, as well as the magnitude and intensity of the event.

Description: This research was funded by the Project FIRST—ForecastIng eRuptive activity at Stromboli volcano: timing, eruptive style, size, intensity, and duration, INGV-Progetto Strategico Dipartimento Vulcani 2019 (Delibera n. 144/2020; Scientific Responsibility: S.C.).

Description: Published

Description: 2392

Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio

Description: JCR Journal

Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Redaelli, L., Mangia Woods, S., Landea, R., & Sayigh, L. Seasonal trends and diel patterns of downsweep and SEP calls in Chilean blue whales. Journal of Marine Science and Engineering, 10(3), (2022): 316, https://doi.org/10.3390/jmse10030316.

Description: To learn more about the occurrence and behaviour of a recently discovered population of blue whales, passive acoustic data were collected between January 2012 and April 2013 in the Chiloense ecoregion of southern Chile. Automatic detectors and manual auditing were used to detect blue whale songs (SEP calls) and D calls, which were then analysed to gain insights into temporal calling patterns. We found that D call rates were extremely low during winter (June–August) but gradually increased in spring and summer, decreasing again later during fall. SEP calls were absent for most winter and spring months (July–November) but increased in summer and fall, peaking between March and April. Thus, our results support previous studies documenting the austral summer residency of blue whales in this region, while suggesting that some individuals stay longer, highlighting the importance of this area as a blue whale habitat. We also investigated the daily occurrence of each call type and found that D calls occurred more frequently during dusk and night hours compared to dawn and day periods, whereas SEP calls did not show any significant diel patterns. Overall, these findings help to understand the occurrence and behaviour of endangered Chilean blue whales, enhancing our ability to develop conservation strategies in this important Southern Hemisphere habitat.

Description: Financial support for expeditions, deployments, and retrievals of MARUs, and for some of the data analysis, was provided by Fundacion MERI, Av. Pdte. Kennedy 5682, Vitacure, Región Metropolitana, Chile. The data analysis for this study was carried out without external funding.

Description: The recent (〈190 ka) volcanic history of Pantelleria is characterized by the eruption of nine peralkaline ignimbrites, ranging in composition from comenditic trachyte to comendite to pantellerite. The ~46 ka Green Tuff (GT) was the last of these ignimbrites, which was followed by many effusive and explosive low-volume eruptions of pantellerite from vents within the caldera moat and along the caldera rim. Although recent studies have shed additional light on the age, petrochemistry, and volcanology of the older ignimbrites, there is very little knowledge of magmatism that occurred between these older ignimbrites, primarily due to the very scarce exposures. In this paper, we present new field descriptions and geochemical data for three local peralkaline centers never studied before, two pre-GT and one post-GT, which share a similar setting with respect to the caldera scarps but differ in terms of their age, composition, and eruptive style. These centers include: (i) the older (~125 ka) Giache center (comenditic trachyte), (ii) the ~67 ka Attalora center (comendite, pantellerite), and (iii) the younger (~14 ka) Patite center (pantellerite).

Description: Published

Description: 406

Description: 1V. Storia eruttiva

Description: JCR Journal

Description: The investigation of short-term earthquake-clustering features is made feasible through the application of a purely stochastic Epidemic-Type Aftershock Sequence (ETAS) model. The learning period that is used for the estimation of the parameters is composed by earthquakes with M〉= 2.6 that occurred between January 2008 and May 2017. The model predictability is retrospectively examined for the 12 June 2017 Lesvos earthquake (Mw6.4) and the subsequent events. The construction of timedependent seismicity maps and comparison between the observed and expected earthquake number are performed in order to temporally and spatially test the evolution of the sequence, respectively. The generation of 127 target events with M 〉= 3.0 in the period June–July 2017, just before the main shock occurrence, is examined in a quantitative evaluation. The statistical criteria used for assessing the model performance are the Relative Operating Characteristic Diagram, the R-score, and the probability gain. Reliable forecasts are provided through the epidemic model testifying its superiority towards a time-invariant Poisson model.

Description: Published

Description: 249

Description: 6T. Studi di pericolosità sismica e da maremoto

Description: JCR Journal

Description: Between 13 December 2020 and 21 February 2022, Etna volcano produced a sequence of 66 paroxysmal explosive eruptions, with Strombolian activity at the summit craters climaxing in lava fountains and eruption columns extending several kilometers above the craters, accompanied by minor and short-lasting lava flows from the crater rim. We selected three of these episodes that occurred within a short space of time, between 13 December 2020 and 12 March 2021, of different magnitude (i.e., erupted volume) and intensity (i.e., mass eruption rate or instantaneous eruption rate), and analyzed them from a multidisciplinary perspective. The aim was to gain insights into those parameters that mostly reveal the eruptive process for hazard assessment purposes. The multidisciplinary data consist of calibrated visible images, thermal images, seismic and infrasound data, ground deformation detected from the strainmeters, as well as satellite SEVIRI images. From these data, we obtained the timing of each paroxysmal event, the erupted volume in terms of tephra and lava flows, and the corresponding deflation of the source region, together with the development of the lava fountains and eruption columns with time. The results enabled determining that the smallest episode was that of 13 December 2020, which comprised three distinctive pulses but did not produce an eruptive column detectable from either monitoring cameras or satellites. The 28 February 2021 episode was remarkable for the short amount of time required to reach the climax, and was the most intense, whereas the 12 March 2021 event showed the longest duration but with an intensity between that of the previous two. Our results show that these three paroxysmal events display a typical trend, with the first event also being the smallest in terms of both erupted volume and intensity, the second being the most intense, and the third the one of greatest magnitude but less intense than the second. This is coherent with the end of the first paroxysmal phase on 1 April 2021, which was followed by 48 days of eruptive pause before starting again. In this context, the end of the paroxysmal phase was anticipated by a more effusive episode, thus heralding a temporary decline in the gas content within the feeding magma batch.

Description: This research was funded by the Project FIRST-ForecastIng eRuptive activity at Stromboli volcano: Timing, eruptive style, size, intensity, and duration; INGV-Progetto Strategico Dipartimento Vulcani 2019 (Delibera n. 144/2020). A.C. thanks the CHANCE project, II Edition, Università degli Studi di Catania (principal investigator A.C.) and the grant PIACERI, 2020-22 programme (PAROSSISMA project, code 22722132140; principal investigator Marco Viccaro). A.I. thanks the IMPACT project—A Multidisciplinary Insight on the Kinematics and Dynamics of Magmatic Processes at Mt. Etna Aimed at Identifying Rrecursor Phenomena and Developing Early Warning Systems, funded by INGV-Progetto Strategico Dipartimento Vulcani 2019 (Delibera n. 144/2020). S.S. thanks the ‘e-shape’ project, which receives funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement 820852.

Description: Published

Description: 4006

Description: 5V. Processi eruttivi e post-eruttivi

Description: JCR Journal

Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Pease, S. K. D., Brosnahan, M. L., Sanderson, M. P., & Smith, J. L. Effects of two toxin-producing harmful algae, Alexandrium catenella and Dinophysis acuminata (Dinophyceae), on activity and mortality of larval shellfish. Toxins, 14(5), (2022): 335, https://doi.org/10.3390/toxins14050335.

Description: Harmful algal bloom (HAB) species Alexandrium catenella and Dinophysis acuminata are associated with paralytic shellfish poisoning (PSP) and diarrhetic shellfish poisoning (DSP) in humans, respectively. While PSP and DSP have been studied extensively, less is known about the effects of these HAB species or their associated toxins on shellfish. This study investigated A. catenella and D. acuminata toxicity in a larval oyster (Crassostrea virginica) bioassay. Larval activity and mortality were examined through 96-h laboratory exposures to live HAB cells (10–1000 cells/mL), cell lysates (1000 cells/mL equivalents), and purified toxins (10,000 cells/mL equivalents). Exposure to 1000 cells/mL live or lysed D. acuminata caused larval mortality (21.9 ± 7.0%, 10.2 ± 4.0%, respectively) while exposure to any tested cell concentration of live A. catenella, but not lysate, caused swimming arrest and/or mortality in 〉50% of larvae. Exposure to high concentrations of saxitoxin (STX) or okadaic acid (OA), toxins traditionally associated with PSP and DSP, respectively, had no effect on larval activity or mortality. In contrast, pectenotoxin-2 (PTX2) caused rapid larval mortality (49.6 ± 5.8% by 48 h) and completely immobilized larval oysters. The results indicate that the toxic effects of A. catenella and D. acuminata on shellfish are not linked to the primary toxins associated with PSP and DSP in humans, and that PTX2 is acutely toxic to larval oysters.

Description: This research was partially funded by the National Oceanic and Atmospheric Administration, National Centers for Coastal Ocean Science Competitive Research, Ecology and Oceanography of Harmful Algal Blooms Program under award #NA19NOS4780182 to J.L.S. (VIMS) and M.L.B (WHOI), and by a William & Mary, School of Marine Science, Student Research Grant to S.K.D.P. (VIMS). This paper is ECOHAB publication number 1022.

Description: To increase seismic resilience is one of the challenges the developers of new technologies face to reduce seismic risk. We set up an augmented reality (AR) exhibition with which users’ curiosity was confronted with the opportunity to have a wealth of information on damaging earthquakes that could be a multimedia add-on to the plain “single-layer exhibit”. AR is an emergent technology developed to “augment” reality through various devices; it combines the real world with virtual items, such as images and videos. Our AR exhibition aims to: (i) show the effects of earthquakes even in cases of moderate magnitude; and (ii) promote preventive actions to reduce non-structural damage. It can be customized for different seismic scenarios. In addition, it offers a holistic approach to communicate problems and solutions—with the cost and degree of ease of execution for each solution—to reduce non-structural damage at home, school, and office. Our AR exhibition can do more than just a plain text or a preconceived video: it can trigger fruitful interaction between the presenters, or even the stand-alone poster, and the public. Such interactivity offers an easy engagement to people of all ages and cultural backgrounds. AR is, indeed, extremely flexible in raising recipients’ interest; moreover, it is an appealing tool for the digital native generations. The positive feedback received led us to conclude that this is an effective way to raise awareness and individual preparedness to seismic risk.

Description: This study was co-financed by the European Commission’s Humanitarian Aid and Civil Protection (grant agreement ECHO/SUB/2015/718655/PREV28).

Description: Published

Description: 332

Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica

Description: JCR Journal

Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Bachy, C., Sudek, L., Choi, C. J., Eckmann, C. A., Nöthig, E.-M., Metfies, K., & Worden, A. Z. Phytoplankton surveys in the Arctic Fram Strait demonstrate the tiny eukaryotic alga Micromonas and other picoprasinophytes contribute to deep sea export. Microorganisms, 10(5), (2022): 961, https://doi.org/10.3390/microorganisms10050961.

Description: Critical questions exist regarding the abundance and, especially, the export of picophytoplankton (≤2 µm diameter) in the Arctic. These organisms can dominate chlorophyll concentrations in Arctic regions, which are subject to rapid change. The picoeukaryotic prasinophyte Micromonas grows in polar environments and appears to constitute a large, but variable, proportion of the phytoplankton in these waters. Here, we analyze 81 samples from the upper 100 m of the water column from the Fram Strait collected over multiple years (2009–2015). We also analyze sediment trap samples to examine picophytoplankton contributions to export, using both 18S rRNA gene qPCR and V1-V2 16S rRNA Illumina amplicon sequencing to assess the Micromonas abundance within the broader diversity of photosynthetic eukaryotes based on the phylogenetic placement of plastid-derived 16S amplicons. The material sequenced from the sediment traps in July and September 2010 showed that 11.2 ± 12.4% of plastid-derived amplicons are from picoplanktonic prasinophyte algae and other green lineage (Viridiplantae) members. In the traps, Micromonas dominated (83.6 ± 21.3%) in terms of the overall relative abundance of Viridiplantae amplicons, specifically the species Micromonas polaris. Temporal variations in Micromonas abundances quantified by qPCR were also observed, with higher abundances in the late-July traps and deeper traps. In the photic zone samples, four prasinophyte classes were detected in the amplicon data, with Micromonas again being the dominant prasinophyte, based on the relative abundance (89.4 ± 8.0%), but with two species (M. polaris and M. commoda-like) present. The quantitative PCR assessments showed that the photic zone samples with higher Micromonas abundances (〉1000 gene copies per mL) had significantly lower standing stocks of phosphate and nitrate, and a shallower average depth (20 m) than those with fewer Micromonas. This study shows that despite their size, prasinophyte picophytoplankton are exported to the deep sea, and that Micromonas is particularly important within this size fraction in Arctic marine ecosystems.

Description: This research was supported by funding from the National Science Foundation (NSF) DEB-1639033, Gordon and Betty Moore Foundation Marine Investigator Award grant 3788, and fellowships from the Radcliffe Institute for Advanced Research at Harvard University and the Hanse-Wissenschaftskolleg for Marine and Climate Science, awarded to A.Z.W. Contribution to HGF POF-IV 6.1, 6.3, and 6.4.

Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Kalra, T. S., Suttles, S. E., Sherwood, C. R., Warner, J. C., Aretxabaleta, A. L., & Leavitt, G. R. Shoaling wave shape estimates from field observations and derived bedload sediment rates. Journal of Marine Science and Engineering, 10(2), (2022): 223, https://doi.org/10.3390/jmse10020223.

Description: he shoaling transformation from generally linear deep-water waves to asymmetric shallow-water waves modifies wave shapes and causes near-bed orbital velocities to become asymmetrical, contributing to net sediment transport. In this work, we used two methods to estimate the asymmetric wave shape from data at three sites. The first method converted wave measurements made at the surface to idealized near-bottom wave-orbital velocities using a set of empirical equations: the “parameterized” waveforms. The second method involved direct measurements of velocities and pressure made near the seabed: the “direct” waveforms. Estimates from the two methods were well correlated at all three sites (Pearson’s correlation coefficient greater than 0.85). Both methods were used to drive bedload-transport calculations that accounted for asymmetric waves, and the results were compared with a traditional excess-stress formulation and field estimates of bedload transport derived from ripple migration rates based on sonar imagery. The cumulative bedload transport from the parameterized waveform was 25% greater than the direct waveform, mainly because the parameterized waveform did not account for negative skewness. Calculated transport rates were comparable to rates estimated from ripple migration except during the largest event, when calculated rates were as much as 100 times greater, which occurred during high period waves.

Description: USGS Coastal and Marine Hazards and Resources Program.

Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Harman, T. E., Hauff-Salas, B., Haslun, J. A., Cervino, J. M., & Strychar, K. B. Decreased photosynthetic efficiency in response to site translocation and elevated temperature is mitigated with LPS exposure in Porites astreoides symbionts. Water, 14(3), (2022): 366, https://doi.org/10.3390/w14030366.

Description: Coral reefs have been detrimentally impacted causing health issues due to elevated ocean temperatures as a result of increased greenhouse gases. Extreme temperatures have also exacerbated coral diseases in tropical reef environments. Numerous studies have outlined the impacts of thermal stress and disease on coral organisms, as well as understanding the influence of site-based characteristics on coral physiology. However, few have discussed the interaction of all three. Laboratory out-planting restoration projects have been of importance throughout impacted areas such as the Caribbean and southern Florida in order to increase coral cover in these areas. This study analyzes photosynthetic efficiency of Porites astreoides from the lower Florida Keys after a two-year reciprocal transplant study at inshore (Birthday reef) and offshore (Acer24 reef) sites to understand acclimation capacity of this species. Laboratory experiments subjected these colonies to one of three treatments: control conditions, increases in temperature, and increases in temperature plus exposure to an immune stimulant (lipopolysaccharide (LPS)) to determine their influence on photosynthetic efficiency and how stress events impact these measurements. In addition, this study is a continuation of previous studies from this group. Here, we aim to understand if these results are static or if an acclimation capacity could be found. Overall, we observed site-specific influences from the Acer24 reef site, which had significant decreases in photosynthetic efficiencies in 32 °C treatments compared to Birthday reef colonies. We suggest that high irradiance and lack of an annual recovery period from the Acer24 site exposes these colonies to significant photoinhibition. In addition, we observed significant increases in photosynthetic efficiencies from LPS exposure. We suggest host-derived antioxidants can mitigate the negative impacts of increased thermal stress. Further research is required to understand the full complexity of host immunity and symbiont photosynthetic interactions.

Description: We thank the Annis Water Resources Institute for both a graduate fellowship and research funding associated with this project, and Grand Valley State University for a Presidential Research Grant. We also thank Michigan State University RTSF and the Integrative Biology Department at Michigan State University (Graduate Fellowship), and the Coastal Preservation Network (Award 250542) for additional funding opportunities.

Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Manini, E., Baldrighi, E., Ricci, F., Grilli, F., Giovannelli, D., Intoccia, M., Casabianca, S., Capellacci, S., Marinchel, N., Penna, P., Moro, F., Campanelli, A., Cordone, A., Correggia, M., Bastoni, D., Bolognini, L., Marini, M., & Penna, A. Assessment of spatio-temporal variability of faecal pollution along coastal waters during and after rainfall events. Water, 14(3), (2022): 502, https://doi.org/10.3390/w14030502.

Description: More than 80% of wastewaters are discharged into rivers or seas, with a negative impact on water quality along the coast due to the presence of potential pathogens of faecal origin. Escherichia coli and enterococci are important indicators to assess, monitor, and predict microbial water quality in natural ecosystems. During rainfall events, the amount of wastewater delivered to rivers and coastal systems is increased dramatically. This study implements measures capable of monitoring the pathways of wastewater discharge to rivers and the transport of faecal bacteria to the coastal area during and following extreme rainfall events. Spatio-temporal variability of faecal microorganisms and their relationship with environmental variables and sewage outflow in an area located in the western Adriatic coast (Fano, Italy) was monitored. The daily monitoring during the rainy events was carried out for two summer seasons, for a total of five sampling periods. These results highlight that faecal microbial contaminations were related to rainy events with a high flow of wastewater, with recovery times for the microbiological indicators varying between 24 and 72 h and influenced by a dynamic dispersion. The positive correlation between ammonium and faecal bacteria at the Arzilla River and the consequences in seawater can provide a theoretical basis for controlling ammonium levels in rivers as a proxy to monitor the potential risk of bathing waters pathogen pollution.

Description: This research was funded by WATERCARE project (Water management solutions for reducing microbial environment impact in coastal areas, project ID 10044130, https://www.italy-croatia.eu/web/watercare, accessed on 17 October 2021) funded by the European Union under the Interreg Italy–Croatia CBC Programme.

Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Dalpe, A. J., Thein, M.-W. L., & Renken, M. . PERFRM: a metric for evaluating autonomous system performance in marine testbed environments using interval type-2 fuzzy logic. Applied Sciences, 11(24), (2021): 11940, https://doi.org/10.3390/app112411940.

Description: Trust and confidence in autonomous behavior is required to send autonomous vehicles into operational missions. The authors introduce the Performance Evaluation and Review Framework Of Robotic Missions (PERFORM), a framework to enable a rigorous and replicable autonomy test environment, thereby filling the void between that of merely simulating autonomy and that of completing true field missions. A generic architecture for defining the missions under test is proposed and a unique Interval Type-2 Fuzzy Logic approach is used as the foundation for the mathematically rigorous autonomy evaluation framework. The test environment is designed to aid in (1) new technology development (i.e., providing direct comparisons and quantitative evaluations between autonomy algorithms), (2) the validation of the performance of specific autonomous platforms, and (3) the selection of the appropriate robotic platform(s) for a given mission type (e.g., for surveying, surveillance, search and rescue). Three case studies are presented to apply the metric to various test scenarios. Results demonstrate the flexibility of the technique with the ability to tailor tests to the user’s design requirements accounting for different priorities related to acceptable risks and goals of a given mission

Description: This work was sponsored by the Naval Engineering Education Consortium (NEEC), Naval Sea Systems Command (NAVSEA), and New Hampshire SeaGrant.

Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Taenzer, L., Grabb, K., Kapit, J., Pardis, W., Wankel, S. D., & Hansel, C. M. Development of a deep-sea submersible chemiluminescent analyzer for sensing short-lived reactive chemicals. Sensors, 22(5), (2022): 1709, https://doi.org/10.3390/s22051709.

Description: Based on knowledge of their production pathways, and limited discrete observations, a variety of short-lived chemical species are inferred to play active roles in chemical cycling in the sea. In some cases, these species may exert a disproportionate impact on marine biogeochemical cycles, affecting the redox state of metal and carbon, and influencing the interaction between organisms and their environment. One such short-lived chemical is superoxide, a reactive oxygen species (ROS), which undergoes a wide range of environmentally important reactions. Yet, due to its fleeting existence which precludes traditional shipboard analyses, superoxide concentrations have never been characterized in the deep sea. To this end, we have developed a submersible oceanic chemiluminescent analyzer of reactive intermediate species (SOLARIS) to enable continuous measurements of superoxide at depth. Fluidic pumps on SOLARIS combine seawater for analysis with reagents in a spiral mixing cell, initiating a chemiluminescent reaction that is monitored by a photomultiplier tube. The superoxide in seawater is then related to the quantity of light produced. Initial field deployments of SOLARIS have revealed high-resolution trends in superoxide throughout the water column. SOLARIS presents the opportunity to constrain the distributions of superoxide, and any number of chemiluminescent species in previously unexplored environments.

Description: This research was funded by the NSF Oceanographic Technology and Interdisciplinary Coordination (OTIC) program grant number 1736332 and NSF Chemical Oceanography program grant number 1924236. Partial support was provided by the Link Foundation Ocean Engineering and Instrumentation Fellowship (L.T.).

Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Gomez-Ibanez, D., Kukulya, A. L., Belani, A., Conmy, R. N., Sundaravadivelu, D., & DiPinto, L. Autonomous water sampler for oil spill response. Journal of Marine Science and Engineering, 10(4), (2022): 526, https://doi.org/10.3390/jmse10040526.

Description: A newly developed water sampling system enables autonomous detection and sampling of underwater oil plumes. The Midwater Oil Sampler collects multiple 1-L samples of seawater when preset criteria are met. The sampler has a hydrocarbon-free sample path and can be configured with several modules of six glass sample bottles. In August 2019, the sampler was deployed on an autonomous underwater vehicle and captured targeted water samples in natural oil seeps offshore Santa Barbara, CA, USA.

Description: This work was supported by the United States Bureau of Safety and Environmental Enforcement under contract number E18PG00001.

Description: Numerous potentially toxic plankton species commonly occur in the Black Sea, and phycotoxins have been reported. However, the taxonomy, phycotoxin profiles, and distribution of harmful microalgae in the basin are still understudied. An integrated microscopic (light microscopy) and molecular (18S rRNA gene metabarcoding and qPCR) approach complemented with toxin analysis was applied at 41 stations in the northwestern part of the Black Sea for better taxonomic coverage and toxin profiling in natural populations. The combined dataset included 20 potentially toxic species, some of which (Dinophysis acuminata, Dinophysis acuta, Gonyaulax spinifera, and Karlodinium veneficum) were detected in over 95% of the stations. In parallel, pectenotoxins (PTX-2 as a major toxin) were registered in all samples, and yessotoxins were present at most of the sampling points. PTX-1 and PTX-13, as well as some YTX variants, were recorded for the first time in the basin. A positive correlation was found between the cell abundance of Dinophysis acuta and pectenotoxins, and between Lingulodinium polyedra and Protoceratium reticulatum and yessotoxins. Toxic microalgae and toxin variant abundance and spatial distribution was associated with environmental parameters. Despite the low levels of the identified phycotoxins and their low oral toxicity, chronic toxic exposure could represent an ecosystem and human health hazard.

Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Aagaard, T., Brinkkemper, J., Christensen, D. F., Hughes, M. G., & Ruessink, G. Surf Zone Turbulence and suspended sediment dynamics-a review. Journal of Marine Science and Engineering, 9(11), (2021): 1300, https://doi.org/10.3390/jmse9111300.

Description: The existence of sandy beaches relies on the onshore transport of sand by waves during post-storm conditions. Most operational sediment transport models employ wave-averaged terms, and/or the instantaneous cross-shore velocity signal, but the models often fail in predictions of the onshore-directed transport rates. An important reason is that they rarely consider the phase relationships between wave orbital velocity and the suspended sediment concentration. This relationship depends on the intra-wave structure of the bed shear stress and hence on the timing and magnitude of turbulence production in the water column. This paper provides an up-to-date review of recent experimental advances on intra-wave turbulence characteristics, sediment mobilization, and suspended sediment transport in laboratory and natural surf zones. Experimental results generally show that peaks in the suspended sediment concentration are shifted forward on the wave phase with increasing turbulence levels and instantaneous near-bed sediment concentration scales with instantaneous turbulent kinetic energy. The magnitude and intra-wave phase of turbulence production and sediment concentration are shown to depend on wave (breaker) type, seabed configuration, and relative wave height, which opens up the possibility of more robust predictions of transport rates for different wave and beach conditions.

Description: This research received no external funding.

Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Polverari, F., Wineteer, A., Rodríguez, E., Perkovic-Martin, D., Siqueira, P., Farrar, J., Adam, M., Closa Tarrés, M., & Edson, J. A Ka-band wind Geophysical Model Function using doppler scatterometer Measurements from the Air-Sea Interaction Tower experiment. Remote Sensing, 14(9), (2022): 2067, https://doi.org/10.3390/rs14092067.

Description: Physical understanding and modeling of Ka-band ocean surface backscatter is challenging due to a lack of measurements. In the framework of the NASA Earth Ventures Suborbital-3 Submesoscale Ocean Dynamics Experiment (S-MODE) mission, a Ka-Band Ocean continuous wave Doppler Scatterometer (KaBODS) built by the University of Massachusetts, Amherst (UMass) was installed on the Woods Hole Oceanographic Institution (WHOI) Air-Sea Interaction Tower. Together with ASIT anemometers, a new data set of Ka-band ocean surface backscatter measurements along with surface wind/wave and weather parameters was collected. In this work, we present the KaBODS instrument and an empirical Ka-band wind Geophysical Model Function (GMF), the so-called ASIT GMF, based on the KaBODS data collected over a period of three months, from October 2019 to January 2020, for incidence angles ranging between 40° and 68°. The ASIT GMF results are compared with an existing Ka-band wind GMF developed from data collected during a tower experiment conducted over the Black Sea. The two GMFs show differences in terms of wind speed and wind direction sensitivity. However, they are consistent in the values of the standard deviation of the model residuals. This suggests an intrinsic geophysical variability characterizing the Ka-band surface backscatter. The observed variability does not significantly change when filtering out swell-dominated data, indicating that the long-wave induced backscatter modulation is not the primary source of the KaBODS backscatter variability. We observe evidence of wave breaking events, which increase the skewness of the backscatter distribution in linear space, consistent with previous studies. Interestingly, a better agreement is seen between the GMFs and the actual data at an incidence angle of 60° for both GMFs, and the statistical analysis of the model residuals shows a reduced backscatter variability at this incidence angle. This study shows that the ASIT data set is a valuable reference for studies of Ka-band backscatter. Further investigations are on-going to fully characterize the observed variability and its implication in the wind GMF development.

Description: F.P. research was funded by an appointment to the NASA Postdoctoral Program initially administered by Universities Space Research Association and now administered by Oak Ridge Associated Universities, under a contract with National Aeronautics and Space Administration. A.W., E.R., D.P.-M., P.S., M.A., M.C.T. and J.T.F. received support from the S-MODE project, an EVS-3 Investigation awarded under NASA Research Announcement NNH17ZDA001N-EVS3 (JPL/Cal Tech: 80NM0019F0058, WHOI: 80NSSC19K1256, UMass Amherst: 80NSSC19K1282). J.B.E. acknowledges support from NSF under grant number OCE-1756789.

Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Kiang, N. Y., Swingley, W. D., Gautam, D., Broddrick, J. T., Repeta, D. J., Stolz, J. F., Blankenship, R. E., Wolf, B. M., Detweiler, A. M., Miller, K. A., Schladweiler, J. J., Lindeman, R., & Parenteau, M. N. Discovery of chlorophyll d: isolation and characterization of a far-red cyanobacterium from the original site of manning and strain (1943) at Moss Beach, California. Microorganisms, 10(4), (2022): 819, https://doi.org/10.3390/microorganisms10040819.

Description: We have isolated a chlorophyll-d-containing cyanobacterium from the intertidal field site at Moss Beach, on the coast of Central California, USA, where Manning and Strain (1943) originally discovered this far-red chlorophyll. Here, we present the cyanobacterium’s environmental description, culturing procedure, pigment composition, ultrastructure, and full genome sequence. Among cultures of far-red cyanobacteria obtained from red algae from the same site, this strain was an epiphyte on a brown macroalgae. Its Qyin vivo absorbance peak is centered at 704–705 nm, the shortest wavelength observed thus far among the various known Acaryochloris strains. Its Chl a/Chl d ratio was 0.01, with Chl d accounting for 99% of the total Chl d and Chl a mass. TEM imagery indicates the absence of phycobilisomes, corroborated by both pigment spectra and genome analysis. The Moss Beach strain codes for only a single set of genes for producing allophycocyanin. Genomic sequencing yielded a 7.25 Mbp circular chromosome and 10 circular plasmids ranging from 16 kbp to 394 kbp. We have determined that this strain shares high similarity with strain S15, an epiphyte of red algae, while its distinct gene complement and ecological niche suggest that this strain could be the closest known relative to the original Chl d source of Manning and Strain (1943). The Moss Beach strain is designated Acaryochloris sp. (marina) strain Moss Beach.

Description: N.Y.K., M.N.P. and R.E.B. were supported by the NASA Virtual Planetary Laboratory team (VPL), which was funded under NASA Astrobiology Institute Cooperative Agreement Number NNA13AA93A, and Grant Number 80NSSC18K0829. This work also benefited from participation in the NASA Nexus for Exoplanet Systems Science (NExSS) research coordination network (RCN). W.D.S, N.Y.K. and M.N.P. were also supported by a NASA Exobiology grant No. 80NSSC19K0478. J.TB. was supported by the NASA Postdoctoral Program (NPP) award number NPP168014S. N.Y.K. received training support from the NASA Goddard Space Flight Center Training Office to take the Microbial Diversity course at the Marine Biological Laboratory, Woods Hole, MA, USA.

Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Falloon, T., Hoernle, K., Schaefer, B., Bindeman, I., Hart, S., Garbe-Schonberg, D., & Duncan, R. Petrogenesis of lava from Christmas Island, Northeast Indian Ocean: implications for the nature of recycled components in non-plume intraplate settings. Geosciences, 12(3), (2022): 118, https://doi.org/10.3390/geosciences12030118.

Description: Lava samples from the Christmas Island Seamount Province (CHRISP) record an extreme range in enriched mantle (EM) type Sr-Nd-Pb-Hf isotope signatures. Here we report osmium isotope data obtained on four samples from the youngest, Pliocene petit-spot phase (Upper Volcanic Series, UVS; ~4.4 Ma), and four samples from the earlier, Eocene (Lower Volcanic Series, LVS; ~40 Ma) shield building phase of Christmas Island. Osmium concentrations are low (5–82 ppt) with initial Os isotopic values (187Os/188Osi) ranging from (0.1230–0.1679). Along with additional new geochemical data (major and trace elements, Sr-Nd-Pb isotopes, olivine δ18O values), we demonstrate the following: (1) The UVS is consistent with melting of shallow Indian mid-ocean ridge basalt (MORB) mantle enriched with both lower continental crust (LCC) and subcontinental lithospheric mantle (SCLM) components; and (2) The LVS is consistent with recycling of SCLM components related to Gondwana break-up. The SCLM component has FOZO or HIMU like characteristics. One of the LVS samples has less radiogenic Os (γOs –3.4) and provides evidence for the presence of ancient SCLM in the source. The geochemistry of the Christmas Island lava series supports the idea that continental breakup causes shallow recycling of lithospheric and lower crustal components into the ambient MORB mantle.

Description: This research received no external funding.