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  • Articles  (6)
  • Hydrothermal systems  (4)
  • Stable isotopes  (2)
  • Elsevier  (6)
  • American Chemical Society
  • American Institute of Physics (AIP)
  • 2020-2022  (6)
  • 1990-1994
  • 1970-1974
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  • Articles  (6)
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  • Elsevier  (6)
  • American Chemical Society
  • American Institute of Physics (AIP)
  • Springer  (14)
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Year
  • 1
    Publication Date: 2021-06-15
    Description: Sicily hosts many natural manifestations that include thermal waters, gas discharges and mud volcanoes. Due to the significant geodynamic and geological differences, the fluid discharges along a NE-WS–oriented transect that run from the Peloritani Mts. to the Sciacca Plain shows a large variability in water and gas chemical and isotopic compositions. The studied waters are characterized by Ca-HCO3, Ca(Mg)-SO4, Ca-Cl and Na-Cl compositions produced by distinct geochemical processes such as water-rock-gas interactions, mixing between deep and shallow aquifers and seawater and direct and reverse ion exchanges. The gas chemistry is dominated by CO2 to the east and CO2-N2 to the west of the study area, whereas the central part shows mud volcanoes discharging CH4-rich gases. Water isotopes suggest that the thermal waters are fed by a meteoric recharge, although isotopic exchange processes between thermal fluids and host rocks at temperature 〉150°C are recognized. Accordingly, liquid geothermometry suggests equilibrium temperatures up to 220°C. The carbon in CO2 and helium isotopes of the emissions from the westernmost sector of Sicily indicate that these two gases consists of up to 40 % of a mantle component, the latter decreasing to the east down to 10% where CO2 of thermometamorphic origin dominates. Accordingly, conceptual models of the fluid circulation for the western, central and eastern sectors are proposed. The regional geothermal reservoir, hosted in carbonates in the western sector and locally outcropping, is of low to medium temperature. Higher temperature conditions (up to 200-220°C) are suggested by geothermometry and probably related to deeper levels of the system. Sicily can be regarded as a potentially suitable area for future investigations to evaluate specific activities aimed at exploiting the geothermal resource.
    Description: Published
    Description: 102120
    Description: 9T. Geochimica dei fluidi applicata allo studio e al monitoraggio di aree sismiche
    Description: JCR Journal
    Keywords: Fluid geochemistry ; Stable isotopes ; Geothermal exploration ; Dissolved gases ; Tectonics ; 03. Hydrosphere
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2021-05-18
    Description: Anthropogenic emissions of greenhouse gases (GHGs) co-occur with emissions of these gases from volcanic and urban environments. Therefore, it remains a challenge for the scientific community to identify the contamination sources and quantify the specific contributions. Stable isotopes have many applications in different fields under geosciences, including volcanology, environmental surveying, and climatology. Isotopic surveys allow identification of photosynthetic fractionation in tree forests and gas sources in urban zones, and tracking of volcanic degassing. Thus, the stable isotopic composition of the local GHGs allows the evaluation of the environmental impacts and assists in mitigating the emissions. The present study aimed to distinguish the tropospheric sources of CO2 in the different ecosystems based on the stable isotopic composition of CO2. The study relies on field experiments performed in both volcanic and urban zones of the Mediterranean region. Experiments to identify the CO2 origins in the field were designed and conducted in the laboratory. The CO2 in the air in Palermo, the soil CO2 released at Vulcano (Aeolian Islands, Italy), and the CO2 emitted at Cava dei Selci (Rome, Italy) were selected for conducting case studies. Isotope surveying of the CO2-containing air in Palermo revealed that the CO2 content was correlated to human activity. Mobile-based measurements of carbon isotope were conducted to distinguish the different sources of CO2 at the district scale. In particular, the isotopic surveying process distinguished landfill-related CO2 emissions from the fossil fuel burning ones. The underlying geological reservoir was identified as the main source of air CO2 at Cava dei Selci. Finally, partitioning of soil CO2 enabled estimation of the geological CO2 estimation in the Vulcano Porto settled zones. The results of the present study revealed that detailed investigations on stable isotopes assist in tracking the CO2 sources and the fate of gas emissions. The fine-tuned experimental solutions assisted in broadening the research perspectives. In addition, deeper insights into the carbon cycle were obtained.
    Description: Published
    Description: 118446
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Stable isotopes ; Carbon dioxide ; Greenhouse gas emissions ; Volcanic gases ; Mediterranean region ; 01.01. Atmosphere ; 04.08. Volcanology ; 05.08. Risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
    Publication Date: 2021-01-26
    Description: Geophysical and geochemical networks are routinely deployed on active volcanoes to observe and monitor unrest periods. However, changes of the physical parameters with time are related to either magma/fluid movement or variations occurring in the hydrothermal systems hosted in the volcanic edifice. Here we use four years of ambient seismic noise recorded at the Stromboli volcano to reconstruct its shallow structure using the ambient noise cross-correlation method. At the same time, we detect temporal variations of the seismic velocities associated with the volcanic activity. We correlated the most reliable variations both in space and in time with other seismic and geochemical information in order to identify lapses of time of general unrest. We also implemented a method to enhance their spatial visualization for the interpretation. We found that the spatial mapping of the seismic velocity temporal variations obtained processing the data at high frequency (1.5–2.5 Hz) match with the location of the main hydrothermal reservoirs of the volcano. This suggests that there is a relationship between volcanic activity and hydrothermal areas that can be detected and monitored for a better understanding of the volcanic phenomena
    Description: Published
    Description: 107177
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: Hydrothermal systems ; Stromboli volcano
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
    Publication Date: 2020-07-13
    Description: A multidisciplinary field campaign was carried out at Nisyros Island (Greece). Hydrothermal gases were sampled and analysed, and CH4 and CO2 fluxes from the soils were measured with the accumulation chamber method. The sampling area (Lakki plain) covers an area of about 0.08 km2, and includes the main fumarolic areas of Kaminakia, Stefanos, Ramos, Lofos and Phlegeton. Flux values measured at 130 sites range from −3.4 to 1420 mg m−2 d−1 for CH4 and from 0.1 to 383 g m−2 d−1 for CO2. The fumarolic areas show very different CH4 degassing patterns, Kaminakia showing the highest CH4 output values (about 0.8 t a−1 from an area of about 30,000 m2) and Phlegeton the lowest (about 0.01 t a−1 from an area of about 2500 m2). The total output from the entire geothermal system of Nisyros should not exceed 2 t a−1. Previous indirect estimates of the CH4 output at Nisyros, based on soil CO2 output and CH4/CO2 ratios in fumarolic gases, were more than one order of magnitude higher. The present work further underscores the utmost importance of direct CH4 flux data because indirect methods totally disregard methanotrophic activity within the soil. Ten soil samples were collected for CH4 consumption experiments and for metagenomic analysis. Seven of the soil samples showed small but significant CH4 consumption (up to 39.7 ng g−1 h−1) and were positive for the methanotrophs-specific gene (pmoA) confirming microbial CH4 oxidation in the soil, notwithstanding the harsh environmental conditions (high temperature and H2S concentrations and low pH).
    Description: Published
    Description: 119546
    Description: 6A. Geochimica per l'ambiente e geologia medica
    Description: JCR Journal
    Keywords: Methanotrophy ; Soil degassing ; Hydrothermal systems ; Methane output ; Greenhouse gases ; 05.09. Miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
    Publication Date: 2020-06-30
    Description: Quantification of the CO2 released by the volcanoes to the atmosphere is relevant for the evaluation of the balance between deep-derived, biogenic and anthropogenic contributions. The current study estimates the CO2 released from Furnas do Enxofre degassing area (Terceira Island, Azores archipelago) by applying an approach that integrates the flux of CO2 fromthe soilwith the δ13C-CO2 values. A deep-derived CO2 output of 2.54 t d−1 is estimated for an area of ~23,715 m2. High biogenic-derived CO2 flux values (~45 g m−2 d−1) associated with light carbon isotopic content (δ13C=−28‰±1.1‰) are detected and explained by the type of vegetation that characterizes the study site. Carbon isotopic compositions of the CO2 (−6.4‰±1.2‰) measured in olivine-hosted fluid inclusions of the Terceira basalts are presented for the first time and contribute to defining the mantle-CO2 signature. Differences between these values and heavier carbon isotope values from gas in fumaroles at Furnas do Enxofre (−4.66‰to−4.27‰) are explained by the carbon isotopic fractionation occurring when CO2 reacts to form calcite in the geothermal reservoir at temperatures N180 °C. A clear correlation between the soil temperature and deep CO2 fluxes is observed and the integration of the diffuse degassing information with the composition of the fumarolic emissions allows estimating a thermal energy flux of 1.1 MW.
    Description: Published
    Description: 106968
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Soil diffuse degassing ; CO2 fluxes ; Carbon isotopic composition ; Hydrothermal systems ; 04.08. Volcanology ; 04.01. Earth Interior
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
    Publication Date: 2020-05-21
    Description: Fluid primary source(s) and chemical-physical processes controlling water and gas chemistry of thermal springs from Eastern Cordillera, sub-Andean Ranges and Santa Bárbara (Jujuy Province, northern Argentina) were investigated to provide information for a preliminary evaluation of the geothermal potential in these areas. Thermal manifestations in Eastern Cordillera (Reyes) and part of those in the western sector of sub-Andean Range (Aguas Calientes) are fed by shallow aquifers, interacting with Quaternary- Neogene rocks and the upper portion of Pliocene-Miocene formations (Orán Group), whereas the meteoric water recharge area is located at〉2500 m a.s.l., corresponding to Chañi hill. Differently, El Jordán thermal spring in the sub-Andean Range is fed by a hydrothermal aquifer hosted within highly porous and fractured formations of the Salta Group (Yacoraite Formation) and recharged by meteoric water from Sierra de Calilegua (∼1500m a.s.l.). The latter is the recharge area of the La Quinta geothermal waters as well, but these have been fed at higher altitudes (〉 2500 m a.s.l.) in the range. The hydrothermal reservoir feeding the other thermal springs from the Santa Barbara system (Caimancito, El Palmar, and Siete Aguas) is recharged by meteoric water from Zapla Ranges and Santa Barbara Hill at〈2500m a.s.l. The high-TDS (〉 16,000 mg/L) Na+-Cl- La Quinta thermal springs are produced by interaction with the evaporite deposits of Salta Group, including halite, whereas the chemistry of El Palmar, El Jordán and Caimancito thermal springs, showing a Na+-SO4 2-(Cl−) composition, depends on mixing with shallower SO4 2--rich waters interacting with gypsum deposits of Anta Formation. Dissolved and bubbling gases from all the investigated provinces are related to CO2- and CH4-rich crustal fluids produced by both thermogenic processes occurring within the hydrothermal systems and microbial activity at relatively low depth, with low to negligible mantle contribution, as indicated by the 3He/4He values ≤ 0.21 Ra. The fluid reservoir feeding the Quinta thermal springs shows the highest estimated temperatures (〉 200 °C), which, considering the depth of Salta Group in the Santa Barbara system (~2000 m), support the idea, suggested by previous authors, of an anomalous geothermal gradient for this area, a promising pre-requisite for future exploitation of the geothermal resource.
    Description: Published
    Description: 102627
    Description: 1TR. Georisorse
    Description: JCR Journal
    Keywords: Hydrothermal systems ; Fluid geochemistry ; Jujuy province ; Geothermal resource
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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