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  • Life and Medical Sciences  (9,149)
  • Inorganic Chemistry  (8,770)
  • Seismology
  • 1990-1994  (12,700)
  • 1950-1954  (2,329)
  • 1910-1914
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 134 (1990), S. 79-92 
    ISSN: 1420-9136
    Keywords: Seismology ; earthquake prediction ; self-similarity ; algorithm CN ; Central Italy
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The Time of Increased Probability (TIP) for the occurrence of a strong earthquake is determined in Central Italy. This is done with an algorithm that has been successfully applied in other regions of the world (algorithm CN, from the initials of California and Nevada, where the first diagnoses of TIPs were made). The use of normalized functions allows direct application of the orginal algorithm to the new region being studied, without anyad hoc adjustment of the parameters. Retrospective analysis carried on until 1986 shows that TIPs occupy 26 percent of the total time considered and precede four out of five strong earthquakes. Forward monitoring indicates the possible existence of a TIP started in May 1988. Several tests indicate that the results obtained are quite stable, even when using catalogues from different agencies. Apart from obvious practical interest, this research is essential for the worldwide investigation of self-similarity in the origin of strong earthquakes.
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 135 (1991), S. 61-75 
    ISSN: 1420-9136
    Keywords: Seismology ; seismic networks ; artificial intelligence ; expert systems ; automatic interpretation ; seismic event detection ; data compression
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The focus-of-attention techniques implemented in SNA2, a knowledge-based system for seismogram interpretation, are presented. They consist of data compression of the input digital records, scanning of the compressed traces to detect candidate seismograms and extraction of seismogram features. A criterion is given to rate the clarity of seismograms; the clarity defines the order in which the system will consider them to build up the interpretation. The proposed techniques are simple and fast; they allow quick rejection of noise and focussing the attention of the system on the portions of traces containing relevant information.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 76 (1994), S. 703-723 
    ISSN: 1572-9613
    Keywords: Seismology ; migration ; scalar wave equation ; parallel computing
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Prospecting for oil and gas resources poses the problem of determining the geological structure of the earth's crust from indirect measurements. Seismic migration is an acoustic image reconstruction technique based on the inversion of the scalar wave equation. Extensive computation is necessary before reliable information can be extracted from large sets of recorded data. In this paper a collection of “industrial” migration techniques, each giving rise to a data parallel algorithm, is outlined. Computer simulations on synthetic seismic data illustrate the problem and the approach.
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 123 (1990) 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 123 (1990), S. 3-6 
    ISSN: 0009-2940
    Keywords: Pentaarsacyclopentadienyl ligand / Triarsachromatertrahedranes / Triple-decker complexes / Tetrahedrane, triarsachroma- ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Chromium Complexes with cyclo-Asx, LigandsThe interaction of [(η5C5Me4R)(CO)2Cr]2(Cr≡Cr) (1a: R = CH3 1b: R = C2H5) with yellow arsenic (As4) affords the triarsachromatetrahedranes [(η5-C5Me4R)(CO)2Cr(η3-As3)] (2a, b) as well as the 27-VE triple-decker complexes [{(η5-C5Me4R)Cr}2-(μ,η5-As5)] (3a, b) 3 is also formed photochemically from 2. 2a and 3b have been characterized by X-ray structure analyses. The cyclo-As5 ligand forms a regular arsenic pentagon.
    Additional Material: 2 Ill.
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  • 6
    ISSN: 0009-2940
    Keywords: Isocyanide complexes / Carbene complexes / Transition metal complexes / Carbohydrates / Glucose, 2-deoxy-2-isocyano-, as complex ligand ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Metal-Complexes of Biologically Important Ligands, LII. - Binding of Monosaccharides through the Isocyano and Carbene Group to the Metal Atom: Chromium(O), Tungsten(O), Rhodium(III), Iridium(1II). Palladium(I1). Platinum(ZI), and Gold(1) Complexes of 1.3.4.6-Tetra-O-acetyl-2-deoxy-2-isocyano-α-D-glucose and -β-D-glucoseStable isocyanide complexes cis-Cl2Pd(CNR)2 (2), cis-Cl2Pt(CNR)2 (3), cis-Cl2Pt(PPh3)CNR (4), [trans-(Ph3P)2Pt(Cl)CNR]+BF-4 (5), ClAuCNR (6), (OC)5CrCNR (7), (OC)5WCNR (8), (η5-C5Me5)Rh-(CNR)Cl2 (9), (η5-C5Me5)Ir(CNR)Cl2 (10) of 1,3,4,6-tetra-O-acetyl-2-deoxy-2-isocyano-α(β)-D-glucose (CNR) as well as carbene complexes ClAuC(NHR')(NHR) (11, 12) and cis-Cl2Pt(PPh3)C-(OR')NHR (13, 14) have been prepared and characterized by their IR and NMR spectra. The structure of 10 has been determined by X-ray crystal structure analysis.
    Additional Material: 1 Ill.
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  • 7
    ISSN: 0009-2940
    Keywords: Phosphaallyl complexes / Sulfur ylides ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Transition-Metal-Substituted Acylphosphines and Phosphaalkenes. XII. - Transition-Metal Sulfur Ylide Complexes, XXVIIzt - Conversion of a Phosphaalkenyliron Complex (η5-C5Me5)-(CO)2FeP=(SiMe3)2 into (η3-Phosphaallyl)iron Complexes by means of Me2S-(O)=CH2: Synthesis and Molecular Structures of Two Isomeres of (η5-C5Me5)-(CO)η5-P(CH-(SiMe3)2(CHC-0)}The transition-metal-substituted phosphaalkene (η5-C5Me5)-(CO)2FeP=C(SiMe3)2 (1) reacts with the sulfur ylide Me2S-(O)=CH2 (2) to afford the yellow η3-phosphaallyliron complex 4 with a syn-configuration in the organophosphorus ligand. In toluene solution at 40°C this complex undergoes an isomerization to the corresponding anti-configurated complex 5. Constitution and configuration of both compounds were elucidated by spectroscopic methods (IR, 1H, 13C, 31P NMR, and MS) as well as single-crystal X-ray diffraction analyses.
    Additional Material: 2 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 123 (1990), S. 67-69 
    ISSN: 0009-2940
    Keywords: Diphosphabicyclobutanes / Valence isomerization ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: DiphosphabicyclobutanesTwo isomeric diphosphabicyclobutanes (5,11) are obtained by treatment of the phosphaalkenes X-P = C(Ph)Tms (1a) and X - P = CTms2 (1b) (X = halogen Tms = trimethylsilyl) with 2, Mg, or Na. Both syntheses proceed by coupling of two phosphaalkene units affording, however, two different diphospha-butadiene intermediates. 4 and 10 readily undergo isomerization reactions to form the diphosphabicyclobutanes. Irradiation of the phosphaalkenes Cp* - P = C(Ph)Tms (12a) and Cp* - P = CTms2 (12b) (Cp* = C5Me5) gives rise to a different reaction pathway. Dimerization of 12a, followed by homolytic cleavage of the Cp* - phosphorus bond and intramolecular recombination produces the butterfly compound 5, whereas homolytic cleavage of the Cp* - element bond in 12 b, followed by rearrangement and intermolecular recombination, affords the diphosphabicyclobutane 11.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 123 (1990), S. 83-85 
    ISSN: 0009-2940
    Keywords: Diazadienes/Carbon-carbon coupling/Ruthenium(0) complexes/Ethylene complexes ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Complexes (dad)2RuCl2 (1) (dad = diazadiene, RN = CR'- CR'=NR) are reduced to (dad)2Ru (2) which react with L = CO or ethylene to give (dad)2RuL (3,5). Reduction of 1b ( R' = H) with magnesium-butadiene or reaction of 2b with butadiene leads to a new type of C-C coupling of butadiene to one of the diazadiene ligands (6b). Addition of CO induces a rearrangement to 7b by a hydride shift.
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 123 (1990), S. 101-105 
    ISSN: 0009-2940
    Keywords: Enol lactones, photochemistry of / Ketene photoextrusion / Ketones, photoreduction / 0-Heterocycles, photochemistry of ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The photochemical conversion of 4,4,7,7-tetramethyl-4,6,7,8-tetrahydro-2H-benzopyran-2,5(3H)-dione (1) into 3,3,6,6-tetramethyl-3,5,6,7-tetrahydrobenzofuran-4(2H)-one (4) in methanol does not - as previously assumed - proceed by decarbonylation of the primarily formed acyl-vinyloxy biradical 2. This conclusion results from the finding that C-2, i. e. the CH2 group, of benzofuranone 4 stems from the solvent. Similar observations were made for other benzopyrandiones 15. A reaction sequence consisting of (a) ketene elimination from 2 with formation of 2-isopropylidene-5,5-dimethyl-1,3-cyclo-hexanedione and (b) light-induced (reductive) H . and . CH2OH addition to this intermediate followed by cyclization and dehydration to 4, is proposed for the conversion 1→4.
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