ALBERT

Description: The fluorescent properties of dissolved organic matter (DOM) have been used as natural tracers in various water systems. However, only few studies have focused on groundwater systems, specifically, on karst systems. The aim of this study was to develop the use of the DOM fluorescence signal as a natural tracer, considering the multiple compartments of a karst system. This method was applied to the Lez hydrosystem, which supplies the city of Montpellier with drinking water. The hydrodynamics and hydrochemistry of the spring were monitored beginning March 2006. The DOM fluorescence was measured by the excitation–emission matrix spectroscopy technique. The analysis of the total fluorescence signal confirms the efficiency of this tool to trace rapid infiltration flows. Moreover, the decomposition of the signal into different fluorophores complements the information provided by the total signal. Indeed, the fluorescence emitted by the humic compounds seems to be the ideal tool for identifying rapid infiltration flows. Nevertheless, the fluorescence of protein-like compounds is better correlated with the inflow of faecal bacteria at the outlet. This decomposition of the fluorescence signal is an interesting way to provide information on both the rapid infiltration flow as well as the vulnerability of the karst aquifers.

Description: Manned lunar exploration has recently attracted renewed interest. This includes the NASA Constellation program to return humans to the Moon by 2020, the ESA Aurora program which may use the Moon as a way station to prepare for major interplanetary exploration by 2025, and the PRC program to send a human to the Moon by 2030 and build a temporary manned lunar base by 2040. One of the problems demanding a solution is the stresses on the mechanical characteristics of the lunar regolith under the microgravity environment. The gravity on the Moon is about 1/6 that on Earth. The regolith is subject to very low confining stresses under a microgravity environment and the mechanical properties can change correspondingly. Because of the limited amount of lunar regolith brought back to Earth by the Apollo missions, a lunar regolith simulant was developed using silicon carbide to investigate the properties of the lunar regolith. Based on triaxial tests, this study analyzed the mechanical properties of the lunar regolith simulant at low stresses including the shear strength, peak strength and dilatation angle. The research results provide useful information on lunar regolith characteristics for astronauts returning to the Moon and for building a temporary manned lunar base.

Description: The vegetation community succession influences soil nutrient cycling, and this process is mediated by soil microorganisms in the forest ecosystem. A degraded succession series of karst forests were chosen in which vegetation community changed from deciduous broadleaved trees (FO) toward shrubs (SH), and shrubs–grasses (SHG) in the southwest China. Soil organic carbon (SOC), total nitrogen (TN), labile organic carbon (LOC), water extractable organic matter (WEOM), microbial biomass carbon and nitrogen (MBC and MBN), bacterial and fungal diversity, as well as soil enzyme activities were tested. The results showed that SOC, LOC, MBC, MBN, and enzyme activities declined with vegetation succession, with the relatively stronger decrease of microbial biomass and functions, whereas WEOM was higher in SHG than in other systems. In addition, soil bacterial and fungal composition in FO was different from both SH and SHG. Despite positive relationship with SOC, LOC, and TN ( p  〈 0.01), MBC, MBN appeared to be more significantly correlated to LOC than to SOC. It suggested that vegetation conversion resulted in significant changes in carbon fractions and bioavailability, furthermore, caused the change in soil microbial community and function in the forest ecosystem.

Description: The sinuosity factor (SF) is a critical value in karst systems in terms of estimating their hydrodynamic parameters including groundwater velocity, coefficient of dispersion, etc., through dye tracer experiments. SF has been used in a number of different dye tracer experiments in karstic systems to estimate a representative flow path. While knowing SF is crucially important in the estimation of hydrodynamic parameters, its calculation is associated with significant uncertainty due to the complexity of subsurface karstic features. And yet, only a few studies have discussed its uncertainties, which might lead some errors in estimation of hydrodynamic parameters from dye tracer experiment. In this study, dye tracer experiments were conducted in two consecutive years (2003 and 2004) representing low and high flow conditions in the Beyyayla sinkhole (Eskişehir, Turkey) where the flow path is well known. Uranine was used in experiments as a tracer and QTRACER computer program was used to determine the hydrodynamic properties of the Beyyayla karst system as well as to gain insights into the effects of SF from dye tracer experiments on estimated parameters. The results showed that the breakthrough curve follows a unimodal and a bimodal distribution in low and high flow conditions, respectively. These different distributions stem from the water transport mechanisms, where velocities were calculated as 58.2 and 93.6 m h −1 during low and high flow conditions observed in a spring emerging from the south side of the studied system. The results also show that the coefficient of dispersion, Reynolds number, and Peclet number increased and longitudinal dispersivity decreased with the higher flow rate. Furthermore, the estimated parameters did not vary with either the flow conditions or the tracer transit time, but they have shown some variations with SF. When SF was increased by 50 %, a change in these parameters was obtained in the range of 50–125 %.

Description: Arid regions in Asia are commonly characterized by rapidly growing populations with limited land resources and varying rainfall frequencies under climatic change. Despite being one of the most important environmental challenges in Asia, the changing aridity in this region, particularly due to large-scale land cover change, has not been well documented. In this study, we used rainfall data and a new land heterogeneity index to identify recent trend in land cover changes in the Asian arid regions. The result indicates a significant decreasing trend of barren lands and an increasing trend of vegetated lands. Although the potential land cover change is commonly believed to be strongly sensitive to rainfall change, such sensitivity has not been observed during the nine-year period (2001–2009) analyzed. Through the analyses of two separate periods (2001–2005 and 2005–2009), the sensitivity of rainfall to land cover change in arid regions is found to be dependent on the initial spatial heterogeneity of vegetated land cover. The approach used and the findings in this study represent an important step toward better understanding of large-scale land cover change in the Asian arid regions, and have the potential to predict future land cover change under various climate change scenarios.

Description: During 2003–2006, a pilot project of alternating water and CO 2 injection was performed on a limited part of the Upper Miocene sandstone oil reservoir of the Ivanić Field. During the test period oil and gas recovery was significantly increased. Additionally 4,440 m 3 of oil and 2.26 × 10 6  m 3 of gas were produced. It has initiated further modelling of sandstone reservoirs in the Ivanić Field in order to calculate volumes available for CO 2 injection for the purpose of increasing hydrocarbon production from depleted sandstone reservoirs in the entire Croatian part of the Pannonian Basin System. In the first phase, modelling was based on results of laboratory testing on the core samples. It considered applying analogies with world-known projects of CO 2 subsurface storage and its usage to enhance hydrocarbon production. In the second phase, reservoir variables were analysed by variograms and subsequently mapped in order to reach lithological heterogeneities and to determine reliable average values of reservoir volumes. Data on porosity, depth and reservoir thickness for the “Gamma 3” and the “Gamma 4” reservoirs, are mapped by the ordinary kriging technique. Calculated volume of CO 2 expressed at standard condition which can be injected in the main reservoirs of the Ivanić Field at near miscible conditions is above 15.5 billion m 3 .

Description: With this paper, we assess the present-day conductive thermal field of the Glueckstadt Graben in NW Germany that is characterized by large salt walls and diapirs structuring the graben fill. We use a finite element method to calculate the 3D steady-state conductive thermal field based on a lithosphere-scale 3D structural model that resolves the first-order structural characteristics of the graben and its underlying lithosphere. Model predictions are validated against measured temperatures in six deep wells. Our investigations show that the interaction of thickness distributions and thermal rock properties of the different geological layers is of major importance for the distribution of temperatures in the deep subsurface of the Glueckstadt Graben. However, the local temperatures may result from the superposed effects of different controlling factors. Especially, the upper sedimentary part of the model exhibits huge lateral temperature variations, which correlate spatially with the shape of the thermally highly conductive Permian salt layer. Variations in thickness and geometry of the salt cause two major effects, which provoke considerable lateral temperature variations for a given depth. (1) The “chimney effect” causes more efficient heat transport within salt diapirs. As a consequence positive thermal anomalies develop in the upper part and above salt structures, where the latter are covered by much less conductive sediments. In contrast, negative thermal anomalies are noticeable underneath salt structures. (2) The “thermal blanketing effect” is caused by thermally low conductive sediments that provoke the local storage of heat where these insulating sediments are present. The latter effect leads to both local and regional thermal anomalies. Locally, this translates to higher temperatures where salt margin synclines are filled with thick insulating clastic sediments. For the regional anomalies the cumulative insulating effects of the entire sediment fill results in a long-wavelength variation of temperatures in response to heat refraction effects caused by the contrast between insulating sediments and highly conductive crystalline crust. Finally, the longest wavelength of temperature variations is caused by the depth position of the isothermal lithosphere–asthenosphere boundary defining the regional variations of the overall geothermal gradient. We find that a conductive thermal model predicts observed temperatures reasonably well for five of the six available wells, whereas the steady-state conductive approach appears not to be valid for the sixth well.

Description: Ecosystem services are the basis of human living and development. Land use has significant effects on the ecosystem structure and functions, even its services. Using the remote sensing (RS), geographical information system and ecological economy theory, this paper analyzed land use changes of different eco-economic functional areas in Manas River Basin during the period 1958–2006 using different stage RS images. This paper selects the evaluation method obtained by Costanza et al. and Xie Gaodi, and the ecological sensitivity coefficient analysis, which analyzed the variation characteristics of eco-service values of different eco-economic functional areas. The results showed that the land use pattern has changed greatly from 1958 to 2006. The area of farmland and industrial area increased rapidly, while the forest area, grassland, water area and unutilized area decreased greatly. The total eco-service value of the river basin decreased from 3,529.64 US$ × 10 6 in 1958 to 2,559.88 US$ × 10 6 in 2006. There was 27.47 % net loss of 969.76 US$ × 10 6 . The eco-service values of various land use types in the study area were close to the regional real values and the results were credible. There existed apparent temporal and spatial changes in the eco-service values of different eco-economic functional areas, and this significant change in the eco-service values was driven by economic development. Consequently, in view of eco-economic characteristics and ecological issues of various eco-economic functional areas, relevant strategies of ecological conservation were proposed for enhancing the general eco-service value of the river basin and realizing the regional sustainable development. The ‘‘yuan’’ is Chinese money unit (¥), US$1 = ¥6.27 (yuan).

Description: Readily dispersible clay is the part of the clay fraction in soils that potentially disperses in water when a small amount of mechanical energy is applied to soil. Column and batch experiments were conducted to identify the effect of readily dispersible clay on the mobility of some metal ions in a disturbed soil sample. The clay fraction (〈0.002 mm) was separated from an alkaline Vertisol from the Nile River Delta. X-ray diffraction technique was used to identify minerals present in the clay fraction. Clay suspensions and deionized H 2 O solutions of Cd 2+ , Cu 2+ , and Zn 2+ were prepared and used as influents in soil columns. Adsorption capability of the studied soil among the three metal ions was investigated. The results showed high adsorption capacity of Cd 2+ , Cu 2+ , but not Zn 2+ for the studied soil. Cu 2+ was the highest adsorbed metal by soil and its sorption increased at small equilibrium concentrations compared with Cd 2+ and Zn 2+ . For the three studied metal ions, Langmuir model represented the best fit to the adsorption data. The concentration of Zn 2+ and Cd 2+ in leachates increased as the leaching solution volume increased, while Cu 2+ showed a homogeneous distribution throughout the soil column. According to DTPA extractable metals, Zn 2+ was appeared at greater depths than Cd 2+ , while Cu 2+ had homogeneous distribution through the soil column.

Description: Carboniferous black mudrocks with known petroleum potential occur throughout Northern Germany. However, despite numerous boreholes exploring for conventional hydrocarbons, the potential for shale gas resources remains uncertain. Therefore, an integrated investigation was conducted to elucidate the shale gas potential for three different Carboniferous facies incorporating baseline parameters from sedimentological and organic-geochemical analyses. Tournaisian–Namurian fine-grained rocks of the Culm-facies, with Type II + III kerogen were deposited in the basin center. TOC contents of up to 7 % occur in the Lower Alum Shale (3.6 % VRr) and up to 6 % in the Upper Alum Shale (4.4 % VRr). Bands of organic-rich black shales, reflecting sea-level variations controlled by global eustatic cycles, occur within the Tournaisian–Visean “Kohlenkalk” -facies north of the Rhenish Slate Mountains and in the Rügen island area. In both areas the organic matter is characterized by a kerogen Type II + III with TOC contents of up to 7 % and maturities of up to 4.2 and 1.8 % VRr, respectively. Black hemipelagites intercalated with coarser-grained silt- and sandstones occur in the Synorogenic Flysch Formation of the Namurian A along the southern basin margin. TOC contents vary from 0.5 to 2.0 % with Type III kerogen dominated organic matter and maturities of up to 2.5 % VRr. The baseline parameters presented in this paper indicate a shale gas potential for the sediments of the Culm-facies on the southern basin margin and of the “Kohlenkalk” -facies in the Rügen area.

Description: The sensitivity of global climate to the episodicity of fire aerosol emissions Atmospheric Chemistry and Physics Discussions, 13, 23691-23717, 2013 Author(s): S. K. Clark, D. S. Ward, and N. M. Mahowald One of the major ways in which forest and grass fires have an impact on global climate is through the release of aerosols. Most studies focusing on calculating the radiative forcing and other climate impacts of fire aerosols use monthly mean emissions derived from the Global Fire Emissions Database that captures only the seasonal cycle of fire aerosol emissions. Here we present the results of a sensitivity study that investigates the climate response to the episodicity of the fires, based on the standard approach which releases emissions every day, and contrasts that to the response when fires are represented as intense pulses of emissions that occur only over 1–2 days on a monthly, yearly, or five-yearly basis. Overall we find that in the modified cases with increased levels of episodicity, the all sky direct effect radiative forcing increases, the clear sky direct effect radiative forcing remains relatively constant, and the magnitude of the indirect effect radiative forcing decreases by about 1 W m −2 (from −1.6 to −0.6 W m −2 ). In the long term, we find that an increase in aerosol emission episodicity leads to an asymmetric change in indirect radiative forcing in the Northern Hemisphere compared to the Southern Hemisphere contributes to a slight shift in the annual average position of the intertropical convergence zone (ITCZ). This shift is found to have a mixed effect on the overall performance of the model at predicting precipitation rates in the tropics. Given these results we conclude that future studies that look to assess the present day global climate impacts of fire aerosols should consider the need to accurately represent fire episodicity.

Description: The characteristics of dissolved organic nitrogen (DON) in surface water from Beijing Olympic Forest Park (BOFP) were investigated in this study. Nanofiltration (NF) pretreatment procedure using two NF membranes (NF90 and NF270) was applied to increase the accuracy and precision of DON measurements in surface water samples with high dissolved inorganic nitrogen/total dissolved nitrogen (DIN/TDN) ratios. Compared to NF90, NF270 showed better performance in lowering the DIN/TDN ratio and retaining DOC in both the synthetic water and raw water samples. DON concentrations ranged from 0.01 to 0.83 mg N L −1 in water samples collected over four different months and showed a seasonal variation. The DON increased in summer due to the higher activity of decomposers on recent litterfall or because of a higher production of biomass in the surface water body. The molecular weight (MW) fractions of 〈3 kDa accounted for more than 50 % of the total DOC concentration and the fractions of 〈3 kDa contributed to more than 48 % of the total DON concentration. It could be concluded that most of the DON present in surface water of BOFP was composed of small molecules, which were mainly composed of monomers such as amino acids and urea, readily available for the uptake by phytoplankton and heterotrophic bacteria.

Description: A new data set of soil mineralogy for dust-cycle modeling Atmospheric Chemistry and Physics Discussions, 13, 23943-23993, 2013 Author(s): E. Journet, Y. Balkanski, and S. P. Harrison The mineralogy of airborne dust affects the impact of dust particles on direct and indirect radiative forcing, on atmospheric chemistry and on biogeochemical cycling. It is determined partly by the mineralogy of the dust-source regions and partly by size-dependent fractionation during erosion and transport. Here we present a data set that characterizes the clay and silt sized fractions of global soil units in terms of the abundance of 12 minerals that are important for dust-climate interactions: quartz, feldspars, illite, smectite, kaolinite, chlorite, vermiculite, mica, calcite, gypsum, hematite and goethite. The basic mineralogical information is derived from the literature, and is then expanded following explicit rules, in order to characterize as many soil units as possible. We present three alternative realisations of the mineralogical maps that account for the uncertainties in the mineralogical data. We examine the implications of the new database for calculations of the single scattering albedo of airborne dust and thus for dust radiative forcing.

Description: Growth of sulphuric acid nanoparticles under wet and dry conditions Atmospheric Chemistry and Physics Discussions, 13, 24087-24125, 2013 Author(s): L. Škrabalová, D. Brus, T. Anttila, V. Ždímal, and H. Lihavainen New particle formation, which greatly influences the number concentrations and size distributions of an atmospheric aerosol, is often followed by a rapid growth of freshly formed particles. The initial growth of a newly formed aerosol is the crucial process determining the fraction of nucleated particles growing into cloud condensation nuclei sizes, which have a significant influence on climate. In this study, we report the laboratory observations of the growth of nanoparticles produced by nucleation of H 2 SO 4 and water in a laminar flow tube at temperatures of 283, 293 and 303 K, under dry (a relative humidity of 1%) and wet conditions (relative humidity of 30%) and residence times of 30, 45, 60 and 90 s. The initial H 2 SO 4 concentration spans the range from 2 × 10 8 to 1.4 × 10 10 molecule cm −3 and the calculated wall losses of H 2 SO 4 were assumed to be diffusion limited. The detected particle number concentrations, measured by the Ultrafine Condensation Particle Counter (UCPC) and Differential Mobility Particle Sizer (DMPS), were found to depend strongly on the residence time. Hygroscopic particle growth, presented by growth factors, was found to be in good agreement with the previously reported studies. The experimental growth rates ranged from 20 nm h −1 to 890 nm h −1 at RH 1% and from 7 nm h −1 to 980 nm h −1 at RH 30% and were found to increase significantly with the increasing concentration of H 2 SO 4 . Increases in the nucleation temperature had a slight enhancing effect on the growth rates under dry conditions. The influence of relative humidity on growth was not consistent – at lower H 2 SO 4 concentrations, the growth rates were higher under dry conditions while at H 2 SO 4 concentrations greater than 1×10 9 molecule cm −3 the growth rates were higher under wet conditions. The growth rates show only a weak dependence on the residence time. The experimental observations were compared with predictions made using a numerical model, which investigates the growth of particles with three different extents of neutralization by the ammonia NH 3 : (1) pure H 2 SO 4 – H 2 O particles (2) particles formed by ammonium bisulphate, (NH 4 )HSO 4 (3) particles formed by ammonium sulphate, (NH 4 ) 2 SO 4 . The highest growth rates were found for ammonium sulphate particles. Since the model accounting for the initial H 2 SO 4 concentration predicted the experimental growth rates correctly, our results suggest that the commonly presumed diffusional wall losses of H 2 SO 4 are not so significant. We therefore assume that there are not only losses of H 2 SO 4 on the wall but also a flux of H 2 SO 4 molecules from the wall into the flow tube, the effect being more profound under dry conditions and at higher temperatures of the tube wall. Based on a comparison with the atmospheric observations, our results indicate that sulphuric acid alone can not explain the growth rates of particles formed in the atmosphere.

Description: Impacts of different plant functional types on ambient ozone predictions in the Seoul Metropolitan Areas (SMA), Korea Atmospheric Chemistry and Physics Discussions, 13, 24925-24973, 2013 Author(s): H.-K. Kim, J.-H. Woo, R. S. Park, C. H. Song, J.-H. Kim, S.-J. Ban, and J.-H. Park Plant functional type (PFT) distributions affect the results of biogenic emission modeling as well as O 3 and PM simulations using chemistry-transport models (CTMs). This paper analyzes the variations of both surface biogenic VOC emissions and O 3 concentrations due to changes in the PFT distributions in the Seoul Metropolitan Areas, Korea. Also, this paper attempts to provide important implications for biogenic emissions modeling studies for CTM simulations. MM5-MEGAN-SMOKE-CMAQ model simulations were implemented over the Seoul Metropolitan Areas in Korea to predict surface O 3 concentrations for the period of 1 May to 31 June 2008. Starting from MEGAN biogenic emissions analysis with three different sources of PFT input data, US EPA CMAQ O 3 simulation results were evaluated by surface O 3 monitoring datasets and further considered on the basis of geospatial and statistical analyses. The three PFT datasets considered were "(1)KORPFT", developed with a region specific vegetation database; (2) CDP, adopted from US NCAR; and (3) MODIS, reclassified from the NASA Terra and Aqua combined land cover products. Comparisons of MEGAN biogenic emission results with the three different PFT data showed that broadleaf trees (BT) are the most significant contributor, followed by needleleaf trees (NT), shrub (SB), and herbaceous plants (HB) to the total biogenic volatile organic compounds (BVOCs). In addition, isoprene from BT and terpene from NT were recognized as significant primary and secondary BVOC species in terms of BVOC emissions distributions and O 3 -forming potentials in the study domain. Multiple regression analyses with the different PFT data (δO 3 vs. δPFTs) suggest that KORPFT can provide reasonable information to the framework of MEGAN biogenic emissions modeling and CTM O 3 predictions. Analyses of the CMAQ performance statistics suggest that deviations of BT areas can significantly affect CMAQ isoprene and O 3 predictions. From further evaluations of the isoprene and O 3 prediction results, we explored the PFT area-loss artifact that occurs due to geographical disparity between the PFT and leaf area index distributions, and can cause increased bias in CMAQ O 3 . Thus, the PFT-loss artifact must be a source of limitation in the MEGAN biogenic emission modeling and the CTM O 3 simulation results. Time changes of CMAQ O 3 distributions with the different PFT scenarios suggest that hourly and local impacts from the different PFT distributions on occasional inter-deviations of O 3 are quite noticeable, reaching up to 10 ppb. Exponentially diverging hourly BVOC emissions and O 3 concentrations with increasing ambient temperature suggest that the use of representative PFT distributions becomes more critical for O 3 air quality modeling (or forecasting) in support of air quality decision-making and human health studies.

Description: Incidence of rough and irregular atmospheric ice particles from Small Ice Detector 3 measurements Atmospheric Chemistry and Physics Discussions, 13, 24975-25012, 2013 Author(s): Z. Ulanowski, P. H. Kaye, E. Hirst, R. S. Greenaway, R. J. Cotton, E. Hesse, and C. T. Collier The knowledge of properties of ice crystals such as size, shape, concavity and roughness is critical in the context of radiative properties of ice and mixed phase clouds. Limitations of current cloud probes to measure these properties can be circumvented by acquiring two-dimensional light scattering patterns instead of particle images. Such patterns were obtained in situ for the first time using the Small Ice Detector 3 (SID-3) probe during several flights in a variety of mid-latitude mixed phase and cirrus clouds. The patterns are analyzed using several measures of pattern texture, selected to reveal the magnitude of particle roughness or complexity. The retrieved roughness is compared to values obtained from a range of well-characterized test particles in the laboratory. It is found that typical in situ roughness corresponds to that found in the rougher subset of the test particles, and sometimes even extends beyond the most extreme values found in the laboratory. In this study we do not differentiate between small-scale, fine surface roughness and large-scale crystal complexity. Instead, we argue that both can have similar manifestations in terms of light scattering properties and also similar causes. Overall, the in situ data is consistent with ice particles with highly irregular or rough surfaces being dominant. Similar magnitudes of roughness were found in growth and sublimation zones of cirrus. The roughness was found to be negatively correlated with the halo ratio, but not with other thermodynamic or microphysical properties found in situ. Slightly higher roughness was observed in cirrus forming in clean oceanic airmasses than in a continental, polluted one. Overall, the roughness and complexity is expected to lead to increased shortwave cloud reflectivity, in comparison with cirrus composed of more regular, smooth ice crystal shapes. These findings put into question suggestions that climate could be modified through aerosol seeding to reduce cirrus cover and optical depth, as the seeding may result in decreased shortwave reflectivity.

Description: The present study evaluated the effect of plant species on methane (CH 4 ) emission and microbial populations in three types of soil–plant systems. Results showed large variation of CH 4 flux rate ranging from 1.35 to 212.61 mg CH 4  m −2  h −1 . Emission peak of CH 4 occurred in July. No significant difference was found in the non-vegetation system spanning 2 years. Compared with non-vegetation, vegetation systems had much higher flux of CH 4 , and obvious seasonal variation was observed. The polyculture system planted with Zizania latifolia ( Z. latifolia ) and Phragmites australis ( P. australis ) released higher CH 4 fluxes than the mono system ( P. australis ), reflecting that Z. latifolia growth could simulate CH 4 emission. The fluorescence in situ hybridization (FISH) results support the characteristics of CH 4 fluxes. Much higher methanotrophs amount and lower methanogens amount from the mono system than those from the polyculture system was observed indicating that Z. latifolia growth may limit the oxygen transportation resulting in higher CH 4 emission. The polyculture system has the highest potential of CH 4 emission.

Description: Factors controlling pollutant plume length downwind of major roadways in nocturnal surface inversions Atmospheric Chemistry and Physics Discussions, 13, 25253-25290, 2013 Author(s): W. Choi, A. M. Winer, and S. E. Paulson A curve fit method using a Gaussian dispersion model solution was successfully applied to obtain both dispersion coefficients and a particle number emission factor (PNEF) directly from ultrafine particle (UFP) concentration profiles observed downwind of major roadways in California's South Coast Air Basin (SoCAB). The Briggs' formulation for the vertical dispersion parameter σ z was adopted in this study due to its better performance in describing the observed profiles compared to other formulations examined. The two dispersion coefficients in Briggs' formulation, α and β, ranged from 0.02 to 0.07 and from −0.5 × 10 −3 to 2.8 × 10 −3 , respectively, for the four freeway transects studied and are significantly different for freeways passing over vs. under the street on which measurements of the freeway plume were made. These ranges are wider than literature values for α and β under stable conditions. The dispersion coefficients derived from observations showed strong correlations with both surface meteorology (wind speed/direction, temperature, and air stability) and differences in concentrations between the background and plume peak. The relationships were applied to predict freeway plume transport using a multivariate regression, and produced excellent agreement with observed UFP concentration profiles. The mean PNEF for a mixed vehicle fleet on the four freeways was estimated as 1.2 × 10 14 particles mi −1 vehicle −1 , which is about 15% of the value estimated in 2001 for the I-405 freeway, implying significant reductions in UFP emissions over the past decade in the SoCAB.

Description: Summer Sea Ice Albedo in the Arctic in CMIP5 models Atmospheric Chemistry and Physics Discussions, 13, 25219-25251, 2013 Author(s): T. Koenigk, A. Devasthale, and K.-G. Karlsson Spatial and temporal variations of summer sea ice albedo over the Arctic are analyzed using an ensemble of historical CMIP5 model simulations. The results are compared to the CLARA-SAL product that is based on long-term satellite observations. The summer sea ice albedo varies substantially among CMIP5 models and many models show large biases compared to the CLARA-SAL product. Single summer months show an extreme spread of ice albedo among models; July-values vary between 0.3 and 0.7 for individual models. The CMIP5 ensemble mean, however, agrees relatively well in the Central Arctic but shows too high ice albedo near the ice edges and coasts. In most models, the ice albedo is spatially too uniformly distributed. The summer to summer variations seem to be underestimated in many global models and almost no model is able to fully reproduce the temporal evolution of ice albedo throughout the summer. While the satellite observations indicate the lowest ice albedos during August, the models show minimum values in July and substantially higher values in August. Instead, the June values are often lower in the models than in the satellite observations. This is probably due to too high surface temperatures in June, leading to an early start of the melt season and too cold temperatures in August causing an earlier refreezing in the models. The summer sea ice albedo in the CMIP5 models is strongly governed by surface temperature and snow conditions, particularly during the period of melt onset in early summer and refreezing in late summer. The summer surface net solar radiation of the ice covered Arctic areas is highly related to the ice albedo in the CMIP5 models. However, the impact of the ice albedo on the sea ice conditions in the CMIP5 models is not clearly visible. This indicates the importance of other Arctic and large scale processes for the sea ice conditions.

Description: Intercontinental transport and deposition patterns of atmospheric mercury from anthropogenic emissions Atmospheric Chemistry and Physics Discussions, 13, 25185-25218, 2013 Author(s): L. Chen, H.-H. Wang, J.-F. Liu, W. Zhang, D. Hu, C. Chen, and X.-J. Wang Global policies that regulate anthropogenic mercury emissions to the environment require quantitative and comprehensive source–receptor relationships for mercury emissions, transport and deposition among major continental regions. In this study, we use the GEOS-Chem model to establish source–receptor relationships among eleven major continental regions worldwide. Source–receptor relationships for surface mercury concentrations (SMC) show that some regions (e.g. East Asia, the Indian subcontinent and Europe) should be responsible for their local surface Hg(II) and Hg(P) concentrations because of near-field transport and deposition contributions from their local anthropogenic emissions (up to 64% and 71% for Hg(II) and Hg(P), respectively, over East Asia). We define region of primary influence (RPI) and region of secondary influence (RSI) to establish intercontinental influence patterns. Results indicate that East Asia is SMC RPI for almost all other regions, while Europe, Russia and the Indian subcontinent also make some contributions to SMC over some receptor regions because they are dominant RSI source regions. Source–receptor relationships for mercury deposition show that approximately 16% and 17% of dry and wet deposition, respectively, over North America originate from East Asia, indicating that trans-pacific transport of East Asian emissions is the major foreign source of mercury deposition in North America. Europe, Southeast Asia and the Indian subcontinent are also important mercury deposition sources for some receptor regions because they are dominant RSI. We also quantify seasonal variation on mercury deposition contributions over other regions from East Asia. Results show that mercury deposition (including dry and wet) contributions from East Asia over the Northern Hemisphere receptor regions (e.g. North America, Europe, Russia, Middle East and Middle Asia) vary seasonally, with the maximum values in summer and minimum values in winter. The opposite seasonal pattern occurs on mercury dry deposition contributions over Southeast Asia and the Indian subcontinent.

Description: Pannonibacter phragmitetus BB was utilized to treat hexavalent chromium [Cr(VI)] contaminated water. Cr(VI) concentration of the contaminated water (pH 10.85) was 534 mg/L. With the inoculum size ranging from 1 to 20 %, P. phragmitetus BB completely reduced Cr(VI) within 27 h when the initial medium concentration exceeded 20 g/L. The lag time of bio-reduction by Cr(VI)-induced cells was 24 h, which was longer than the non-Cr(VI)-induced cells. Under the agitation condition, an obvious bio-reduction lag phase existed and Cr(VI) was completely reduced within 24 h. However, the lag phase was not observed under the static condition, Cr(VI) was reduced continuously after inoculation and Cr(VI) was completely reduced after 27 h incubation. The main chromium components after Cr(VI) reduction were Cr(OH) 3 , Cr 2 O 3 and CrCl 3 . The results of this study are fundamentally significant to the application of P. phragmitetus BB in the treatment of Cr(VI) contaminated water.

Description: Research on the seepage deformation of saturated soft soil has resulted in many achievements based, mainly, on existing seepage-deformation control equations. In reality, however, these control equations and related parameters suffer from many problems. The conductivity coefficient in the seepage control equation and the consolidation coefficient in the consolidation equation clearly resemble each other in form. However, in existing regulations and practice, soil deformation is rarely calculated by substituting the conductivity coefficient obtained from field hydrogeological experiments for the consolidation coefficient. Similarly, seepage is seldom calculated by substituting the conductivity coefficient with the consolidation coefficient obtained from consolidation experiments. This can be attributed to the fact that the two coefficients have some obvious differences. Moreover, the settlement deformation of soil calculated using the existing seepage and consolidation models does not agree very well with the measured deformation. Also, the values calculated using different models usually deviate markedly. Research indicates that these problems derive from the fact that the seepage and consolidation equations are based on different concepts of elementary volume. This study proposes using two separate elementary volume concepts: deformation elementary volume and control elementary volume. The concepts are adopted for saturated soft soil and the results used to analyze the relationships and differences between the two concepts. Moreover, we developed a conceptual data model (CDM) for the water released from and the deformation of the saturated soil. The model discloses the differences between the consolidation and conductivity coefficients both in their physical significances and magnitudes. The inter-relationship between the two coefficients is also revealed. An analytical solution for the deformation and water released from saturated soft soil is deduced based on the CDM model and the relationship between the hydrogeological and consolidation deformation parameters is established. A physical test model for saturated soft soil under certain conditions is also designed to verify the analytical solution using a method of curve fitting. Seepage and deformation tests and case studies show that the parameters calculated using the consolidation model are in agreement with those obtained from the CDM seepage model based on the measured data for flux and settlement vs. time. Furthermore, the relationship between conductivity and consolidation coefficients is verified. The method suggested in this paper is generally applicable to problems involving the consolidation coefficient, volume compressibility, conductivity coefficient, hydraulic conductivity, and specific storage of saturated soft soil, etc. Thus, its potential applications are numerous.

Description: Geosynthetic clay liners (GCLs) have been widely used as a hydraulic barrier along with HDPE geomembrane (GM) in landfills. Both the internal and interface strengths of GCLs are very important for evaluating landfill stability. An improved simple shear apparatus used in this study does not force the shear failure to occur along a pre-determined plane. The composite specimens can fail along any interface or through shearing of the GCL internally. The displacement of each component of the specimen can also be measured during the tests. When non-woven geotextile side contacts textured GM (NWGT/GMX) and woven geotextile side contacts compacted clay layer (WGT/CCL) for a dry GCL, the failure interface can change from NWGT/GMX interface to WGT/CCL interface with the increases of the normal stresses. Conversely, when woven geotextile side contacts textured GM (WGT/GMX) and non-woven geotextile side contacts compacted clay layer (NWGT/CCL) for a dry GCL, the failure always occurs at the WGT/GMX interface for all applied normal stresses. The internal failure of the GCL did not occur when the normal stress increased up to 1,500 kPa for the GCL in dry condition.

Description: Balloon-borne match measurements of mid-latitude cirrus clouds Atmospheric Chemistry and Physics Discussions, 13, 25417-25479, 2013 Author(s): A. Cirisan, B. P. Luo, I. Engel, F. G. Wienhold, U. K. Krieger, U. Weers, G. Romanens, G. Levrat, P. Jeannet, D. Ruffieux, R. Philipona, B. Calpini, P. Spichtinger, and T. Peter Observations of persistent high supersaturations with respect to ice inside cirrus clouds are challenging our understanding of cloud microphysics and of climate feedback processes in the upper troposphere. Single measurements of a cloudy air mass provide only a snapshot from which the persistence of ice supersaturation cannot be judged. We introduce here the "cirrus match technique" to obtain information of the evolution of clouds and their saturation ratio. The aim of these coordinated balloon soundings is to analyze the same air mass twice. To this end the standard radiosonde equipment is complemented by a frost point hygrometer "SnowWhite" and a particle backscatter detector "COBALD" (Compact Optical Backscatter Aerosol Detector). Extensive trajectory calculations based on regional weather model COSMO forecasts are performed for flight planning and COSMO analyses are used as basis for comprehensive microphysical box modeling (with grid scale 2 km and 7 km, respectively). Here we present the results of matching a cirrus cloud to within 2–15 km, realized on 8 June 2010 over Payerne, Switzerland, and a location 120 km downstream close to Zurich. A thick cirrus was detected over both measurement sites. We show that in order to quantitatively reproduce the measured particle backscatter ratios, the small-scale temperature fluctuations not resolved by COSMO must be superimposed on the trajectories. The stochastic nature of the fluctuations is captured by ensemble calculations. Possibilities for further improvements in the agreement with the measured backscatter data are investigated by assuming a very slow mass accommodation of water on ice, the presence of heterogeneous ice nuclei, or a wide span of (spheroidal) particle shapes. However, the resulting improvements from microphysical refinements are moderate and comparable in magnitude with changes caused by assuming different regimes of temperature fluctuations for clear sky or cloudy sky conditions, highlighting the importance of a proper treatment of subscale fluctuations. The model yields good agreement with the measured backscatter over both sites and reproduces the measured saturation ratios with respect to ice over Payerne. Conversely, the 30% in-cloud supersaturation measured in a massive, 4-km thick cloud layer over Zurich cannot be reproduced, irrespective of the choice of meteorological or microphysical model parameters. The measured supersaturation can only be explained by either resorting to an unknown physical process, which prevents the ice particles from consuming the excess humidity, or – much more likely – by a measurement error, such as a contamination of the sensor housing of the SnowWhite hygrometer by a precipitation drop from a mixed phase cloud just below the cirrus layer or from some very slight rain in the boundary layer. This uncertainty calls for in-flight checks or calibrations of hygrometers under the extreme humidity conditions in the upper troposphere.

Description: An explicit study of aerosol mass conversion and its parameterization in warm rain formation of cumulus clouds Atmospheric Chemistry and Physics Discussions, 13, 25481-25536, 2013 Author(s): J. Sun, J. Fen, and R. K. Ungar The life time of atmospheric aerosols is highly affected by in-cloud scavenging processes. Aerosol mass conversion from aerosols embedded in cloud droplets into aerosols embedded in raindrops is a pivotal pathway for wet removal of aerosols in clouds. The aerosol mass conversion rate in the bulk microphysics parameterizations is always assumed to be linearly related to the precipitation production rate, which includes the cloud water autoconversion rate and the cloud water accretion rate. The ratio of the aerosol mass concentration conversion rate to the cloud aerosol mass concentration has typically been considered to be the same as the ratio of the precipitation production rate to the cloud droplet mass concentration. However, the mass of an aerosol embedded in a cloud droplet is not linearly proportional to the mass of the cloud droplet. A simple linear relationship cannot be drawn between the precipitation production rate and the aerosol mass concentration conversion rate. In this paper, we studied the evolution of aerosol mass concentration conversion rates in a warm rain formation process with a 1.5-dimensional non-hydrostatic convective cloud and aerosol interaction model in the bin microphysics. We found that the ratio of the aerosol mass conversion rate to the cloud aerosol mass concentration can be statistically expressed by the ratio of the precipitation production rate to the cloud droplet mass concentration with an exponential function. We further gave some regression equations to determine aerosol conversions in the warm rain formation under different threshold radii of raindrops and different aerosol size distributions.

Description: The effect of glucose, chicken manure, and filter mud on the ammonium and nitrate concentrations, ammonia-oxidizing bacterial community and bacterial community in latosolic red soils during the incubation of microcosms was investigated. The soil nitrate concentration was significantly lower in the glucose-treated soil than in the filter mud or chicken manure-treated soil from days 2 and 5 to 21 of incubation. The ammonia-oxidizing bacteria community composition, measured by terminal restriction fragment length polymorphism analysis, was different among the treatments 9 days after incubation, suggesting that the control soil without external fertilization had a low 283-bp ( Nitrosospira ) fragment relative abundance (27 %) compared with the glucose-treated (62 %), filter mud (73 %) and chicken manure (78 %) samples. Additionally, 491-bp fragments ( Nitrosomonas ) were detected in all the soil treatments except for the control soil, and 48-bp fragments (from different Nitrosomonas ) were detected in the chicken manure-treated soil. The bacterial community structure was markedly changed in the glucose-treated soil on day 9 and in the filter mud-treated soil on day 31, indicating that the effect of filter mud on the bacterial community is delayed compared to the effect of glucose. The chicken manure-treated soil showed less change, similar to that of the control soil. Glucose fertilization greatly increased the soil bacterial abundance and functional diversity; however, the chicken manure and filter mud did not stimulate soil bacterial activity on day 9. These results indicated that nitrification may have been somewhat suppressed in the glucose-treated soils, which was possibly related to the improving ammonia-oxidizing bacterial community, bacterial community and activity via the available carbon application. The filter manure and chicken manure treatments demonstrated fewer effects. These results suggest that organic carbon quality, e.g., increasing the available carbon, regulates the nitrification process and is beneficial to reducing soil nitrogen losses.

Description: Sediment samples collected from the West Port, the west coastal waters of Malaysia, were analyzed by standard methods to determine the degree of hydrocarbon contamination and identify the sources of polyaromatic hydrocarbons (PAHs). Concentrations of PAHs in the port sediments ranged from 100.3 to 3,446.9 μg/kg dw. The highest concentrations were observed in stations close to the coastline, locations affected by intensive shipping activities and industrial input. These were dominated by high-molecular-weight PAHs (4–6 rings). Source identification showed that PAHs originated mostly pyrogenically, from the combustion of fossil fuels, grass, wood, and coal or from petroleum combustion. Regarding ecological risk estimation, only station 7 was moderately polluted, the rest of the stations suffered rare or slight adverse biological effects with PAH exposure in surface sediment, suggesting that PAHs are not considered as contaminants of concern in the West Port.

Description: Saline water intrusion is degrading water quality in the channelized coastal wetlands of the southern Albemarle estuarine system (AES). The source, transport and fate of the saline water in the southern AES was determined by monitoring specific conductivity and water levels in small artificial channels, the Alligator River, the Alligator–Pungo Canal and the groundwater system for ~12 months. Results indicate that water levels are affected by wind tides which trigger the movement of saline water into the interior of the wetlands via the small canals. The wind tides are mostly driven by episodic southerly winds pushing saline water into the canal network and the groundwater regime proximal to the Alligator River. The saline waters persist in the canals as long as the wind tide events last. Specific conductivities from canals and groundwater are shown to be unexpectedly higher closer to the source of the Alligator River than toward the Albemarle Sound, suggesting that the large Alligator–Pungo Canal facilitates the northward migration of saline water from the Pamlico Sound to the Alligator River. Overwash and reversals in the flow directions between groundwater and surface water bodies suggest that saline water that is present during wind tide events may migrate into the groundwater system from surface water bodies. The results of this study reveal that whereas the large Alligator–Pungo Canal channels saline water to the AES, small artificial channels may also play significant roles in degrading water quality in the interior of channelized coastal wetlands.

Description: The presence of coarse-grained sediment can potentially reduce the effectiveness of conventional sampling methods in recovering fluvial sediments. A modification to freeze-core technology was used to collect fine to coarse sands, silts, and clays in fluvial deposits that contain significant amounts of gravels, cobbles, and boulders for the purpose of characterizing the extent of heavy metal contamination. This modification uses either a 2.5 or 2.9 cm diameter by 30-cm- long finned mechanical or hand-driven samplers. The sediment is frozen to the outside of the sampler by injecting liquid CO 2 into the sampler. The fins protect the sample from coarse material upon removal. Field testing and laboratory testing of the method were completed to establish a methodology and assess possible cross contamination of the sediment layers during the driving of the sampler. The results indicated that this method is effective for recovering non-cohesive sediment samples at depths up to 6 m for the purpose of characterizing the extent of heavy metal contamination.

Description: Geochemical, mineralogical and textural analyses were carried out in core sediments off Adyar estuary, Bay of Bengal, India to record the contamination trend from urban and industrial activities during the historical past. Quartz, feldspar, kaolinite, chlorite and illite were the main lithogenic and clay minerals; carbonate was the predominant biogenic mineral. Trace metals (Fe, Al, Cu, Cr, Ni, Pb and Zn) indicate more enrichment in the surface sediment layers due to recent anthropogenic activities. The mean anthropogenic factor (AF) values for trace metals in core sediments decreased in the following order: Cr 〉 Ni 〉 Zn 〉 Cu 〉 Pb. The pollution load index (PLI) values in Adyar core sediments ranged from 1 to 1.25 with an average of 1.07. Based on AF, PLI, and sediment quality guidelines values for trace metals, significant metal enrichment and ecological risk were obtained in upper-most sediment layer. Multivariate statistical methods such as correlation matrix, principal component analysis and cluster analysis were carried out to find the relationships among the texture size, metals and minerals. The pollution of Adyar estuarine sediments was started in the 1960s, responding to the rapid economic development in Chennai coastal and Adyar estuarine region in the last five decades. Despite these high concentrations in the upper layer, development and expansion of industries are still continuing. The stricter regulations for the discharge and remediation of sediments are urgent for the conservation of environments and human health.

Description: Short duration rainfall data are required for certain hydrological risk assessments. However, short timescale rainfall intensity records are still scarce due to the high cost and low reliability of the monitoring systems. One way to solve this problem is by disaggregating rainfall data using stochastic methods. This study used the Bartlett Lewis Rectangular Pulse model to disaggregate daily rainfall into hourly rainfall for ten stations in the central region of Peninsular Malaysia. The performance of the model was evaluated on its ability to reproduce statistical properties, namely the mean and standard deviation, derived from the historical records over the disaggregated rainfall. The disaggregation of daily to hourly rainfall produced daily and hourly means that closely matched the historical records. However, the standard deviations of the disaggregated daily rainfall were lower than the historical values. Despite the significant differences in the standard deviation, both data series exhibit similar patterns and the model adequately preserved the trends of all the statistical properties used in evaluating its performance.

Description: Global and regional impacts of HONO on the chemical composition of clouds and aerosols Atmospheric Chemistry and Physics Discussions, 13, 23599-23638, 2013 Author(s): Y. F. Elshorban, P. J. Crutzen, B. Steil, A. Pozzer, H. Tost, and J. Lelieveld Nitrous acid (HONO) photolysis can significantly increase HO x (OH+HO 2 ) radical formation, enhancing organic and inorganic oxidation products in polluted regions, especially during winter. It has been reported that chemistry-transport models underestimate sulphate concentrations, mostly during winter. Here we show that HONO can significantly enhance aerosol sulphate (S(VI)), mainly due to the increased formation of H 2 SO 4 . Even though in-cloud aqueous phase oxidation of dissolved SO 2 (S(IV)) is the main source of S(VI), it appears that HONO related enhancement of H 2 O 2 does not significantly affect sulphate because of the predominantly S(IV) limited conditions, except over eastern Asia. Nitrate is also increased via enhanced gaseous HNO 3 formation and N 2 O 5 hydrolysis on aerosol particles. Ammonium nitrate is enhanced in ammonia-rich regions but not under ammonia-limited conditions. Furthermore, particle number concentrations are also higher, accompanied by the transfer from hydrophobic to hydrophilic aerosol modes. This implies a significant impact on the particle lifetime and cloud nucleating properties. The HONO induced enhancements of all species studied are relatively strong in winter though negligible in summer. Simulating realistic HONO levels is found to improve the model-measurement agreement of sulphate aerosols, most apparent over the US. Our results underscore the importance of HONO for the atmospheric oxidizing capacity and the central role of cloud chemical processing in aerosol formation.

Description: Injection heights of springtime biomass burning plumes over the Peninsular Southeast Asia and their impacts on pollutant long-range transport Atmospheric Chemistry and Physics Discussions, 13, 23781-23816, 2013 Author(s): Y. Jian and T.-M. Fu We analyzed observations from the Multi-angle Imaging SpectroRadiometer (MISR) to determine the injection heights of biomass burning smoke plumes over the Peninsular Southeast Asia (PSEA) in spring, with the goal of evaluating the impacts on pollutant long-range transport. We retrieved the heights of twenty-two thousand MISR smoke pixels from 607 smoke plumes over the PSEA during February to April of the years 2001–2010. Forty-five percent of the analyzed smoke pixels were above the local mean boundary layer (1 km) at MISR overpass time (10:30 a.m. local time). We used the GEOS-Chem model to simulate the transport of PSEA biomass burning pollutants in March 2001. We found that the direct injection of 40% of the PSEA biomass burning emissions had little impact on the long-range transport of CO to downwind regions, compared to a control simulation where all biomass burning emissions were released in the boundary layer. This was because CO at the surface over the PSEA was efficiently lifted into the free troposphere by deep convection associated with synoptic-scale weather systems. For pollutants with lifetimes shorter than the synoptic timescale, such as black carbon aerosol (BC), their long-range transport was much more sensitive to the initial plume injection height. The direct injection of NO x from PSEA biomass burning into the free troposphere drove increased formation and transport of PAN, which in turn led to significant increases of ozone over downwind southern China and northwestern Pacific. The Pacific subtropical high transported PSEA biomass burning pollutants to the marine boundary layer over the tropical northwestern Pacific. We compared our model results to aircraft measurements over the northwestern Pacific during the TRACE-P campaign (March 2001). The direct injection of 40% of the PSEA biomass burning pollutants in the free troposphere in the model led to a more pronounced BC peak at 3 km over the northwestern Pacific, which was in better agreement with the aircraft observations compared to the control simulation. Our analyses highlighted the point that the injection heights of smoke plumes pose large uncertainty to the interpretation of BC measurements downwind of biomass burning regions.

Description: Influence of surface morphology on the immersion mode ice nucleation efficiency of hematite particles Atmospheric Chemistry and Physics Discussions, 13, 23757-23780, 2013 Author(s): N. Hiranuma, N. Hoffmann, A. Kiselev, A. Dreyer, K. Zhang, G. Kulkarni, T. Koop, and O. Möhler In this paper, the effect of the morphological modification of aerosol particles with respect to heterogeneous ice nucleation is comprehensively investigated for laboratory-generated hematite particles as a model substrate for atmospheric dust particles. The surface area-scaled ice nucleation efficiencies of monodisperse cubic hematite particles and milled hematite particles were measured with a series of expansion cooling experiments using the Aerosol Interaction and Dynamics in the Atmosphere (AIDA) cloud simulation chamber. Complementary off-line characterization of physico-chemical properties of both hematite subsets were also carried out with scanning electron microscopy (SEM), energy dispersive X-ray (EDX) spectroscopy, dynamic light scattering (DLS), and an electro-kinetic particle charge detector to further constrain droplet-freezing measurements of hematite particles. Additionally, an empirical parameterization derived from our laboratory measurements was implemented in the single-column version of the Community Atmospheric Model version 5 (CAM5) to investigate the model sensitivity in simulated ice crystal number concentration on different ice nucleation efficiencies. From an experimental perspective, our results show that the immersion mode ice nucleation efficiency of milled hematite particles is almost an order of magnitude higher at −35.2 °C 〈 T 〈 −33.5 °C than that of the cubic hematite particles, indicating a substantial effect of morphological irregularities on immersion mode freezing. Our modeling results similarly show that the increased droplet-freezing rates of milled hematite particles lead to about one order magnitude higher ice crystal number in the upper troposphere than cubic hematite particles. Overall, our results suggest that the surface irregularities and associated active sites lead to greater ice activation through droplet-freezing.

Description: Study of the unknown HONO daytime source at an European suburban site during the MEGAPOLI summer and winter field campaigns Atmospheric Chemistry and Physics Discussions, 13, 23639-23690, 2013 Author(s): V. Michoud, A. Colomb, A. Borbon, K. Miet, M. Beekmann, M. Camredon, B. Aumont, S. Perrier, P. Zapf, G. Siour, W. Ait-Helal, C. Afif, A. Kukui, M. Furger, J. C. Dupont, M. Haeffelin, and J. F. Doussin Nitrous acid measurements were carried out during the MEGAPOLI summer and winter field campaigns at SIRTA observatory in Paris surroundings. Highly variable HONO levels were observed during the campaigns, ranging from 10 ppt to 500 ppt in summer and from 10 ppt to 1.7 ppb in winter. Significant HONO mixing ratios have also been measured during daytime hours, comprised between some tenth of ppt and 200 ppt for the summer campaign and between few ppt and 1 ppb for the winter campaign. Ancillary measurements, such as NO x , O 3 , photolysis frequencies, meteorological parameters (pressure, temperature, relative humidity, wind speed and wind direction), black carbon concentration, total aerosol surface area, boundary layer height and soil moisture, were conducted during both campaigns. In addition, for the summer period, OH radical measurements were made with a CIMS (Chemical Ionisation Mass Spectrometer). This large dataset has been used to investigate the HONO budget in a suburban environment. To do so, calculations of HONO concentrations using PhotoStationary State (PSS) approach have been performed, for daytime hours. The comparison of these calculations with measured HONO concentrations revealed an underestimation of the calculations making evident a missing source term for both campaigns. This unknown HONO source exhibits a bell shaped like average diurnal profile with a maximum around noon of approximately 0.7 ppb h −1 and 0.25 ppb h −1 , during summer and winter respectively. This source is the main HONO source during daytime hours for both campaigns. In both cases, this source shows a slight positive correlation with J (NO 2 ) and the product between J (NO 2 ) and soil moisture. This original approach had, thus, indicated that this missing source is photolytic and might be heterogeneous occurring on ground surface and involving water content available at the ground.

Description: The Gavbast karstic aquifer located in southern Iran is in direct contact with an exposed salt diapir. To assess the influence of the diapir on the quality of groundwater in the karstic aquifer, electrical conductivity, total dissolved solids, flow rate, temperature and major ion concentrations were measured at 57 sampling sites, including springs, surface waters and wells. A conceptual model of groundwater flow is proposed for the Gavbast karstic aquifer based on the geological setting, water budget, local base of erosion, and hydrochemistry of the sampling sites. The model suggests two subbasins in the Gavbast Anticline draining into two distinct discharging alluvial sections. Unexpectedly, groundwater discharging from the carbonate Gavbast aquifer is saline or brackish and water is of chloride type. The study indicates that the source of salinity of the Gavbast aquifers is infiltration of surface diapir-derived brine into the aquifer. The contribution of the diapir brine in the Gavbast karst aquifer is calculated about 4 L/s, using chloride mass balance. Construction of salt basins to evaporate brine discharging from the diapir springs is proposed to reduce the salinity of karst water. A row of strategically placed wells in the Gavbast karst aquifer would potentially exploit large volumes of fresh groundwater before it is contaminated by the salt. Such low-cost remediation should allow the agricultural exploitation of 40 km 2 of currently barren land.

Description: The enrichment characteristics and risk of heavy metals were studied in the sediments of Liucha River in Chao Lake Valley, where agricultural intensification has developed rapidly since the 1980s. The results revealed that Cd, Pb and Zn showed the lowest levels in the upper reaches and peak values in the lower reaches, increasing from 0.064, 7.75 and 59.75 mg/kg to 0.176, 12.33 and 96.82 mg/kg on average, respectively. Enrichment factor (EF) analysis showed that the EF values of Cd, Pb and Zn (maximum 4.76, 2.51 and 2.74, respectively) all increased from the upper reaches to the lower reaches (〉1.5), while correlation analysis and cluster analysis showed that they primarily originated from the extensive use of phosphate fertilizer. In addition, the comprehensive potential ecological risk due to Cd, Cr, Cu, Ni, Pb and Zn in the sediments showed low degree, but Cd showed moderate and high risk at some sites. Therefore, heavy metal pollution due to agricultural intensification in the agricultural regions of Chao Lake Valley should be given great attention during management of the water environment.

Description: The biodegradation of various wastewater-derived organic trace pollutants occurring in different aquatic compartments of the environment was previously reported to be influenced by the prevailing redox conditions. However, comparative studies on the redox-dependent degradation behavior of organic trace pollutants are scarce. The objective of the study presented herein, was to compile and evaluate data from several comparable previous tank experiments, thus, providing an overview on the redox-dependent removal of a total of 27 wastewater-derived trace compounds, including phenazone type compounds, antimicrobials, ß-blockers, psychoactive drugs and sulfonamides. Removal rate constants were fitted assuming first-order degradation kinetics. Six compounds were identified to be removed solely under oxic, three compounds solely under anoxic conditions. Others persisted under all experimental conditions, while some were removed under both oxic and anoxic conditions.

Description: Relationship between Amazon biomass burning aerosols and rainfall over La Plata Basin Atmospheric Chemistry and Physics Discussions, 13, 23995-24021, 2013 Author(s): G. Camponogara, M. A. F. Silva Dias, and G. G. Carrió High aerosol loads are discharged into the atmosphere by biomass burning in Amazon and Central Brazil during the dry season. These particles can interact with clouds as cloud condensation nuclei (CCN) changing cloud microphysics and radiative properties and, thereby, affecting the radiative budget of the region. Furthermore, the biomass burning aerosols can be transported by the low level jet (LLJ) to La Plata Basin where many mesoscale convective systems (MCS) are observed during spring and summer. This work proposes to investigate whether the aerosols from biomass burning may affect the MCS in terms of rainfall over La Plata Basin during spring. Since the aerosol effect is very difficult to isolate because convective clouds are very sensitive to small environment disturbances, detailed analyses using different techniques are used. The binplot, 2D histograms and combined empirical orthogonal function (EOF) methods are used to separate certain environment conditions with the possible effects of aerosol loading. Reanalysis 2, TRMM-3B42 and AERONET data are used from 1999 up to 2012 during September-December. The results show that there are two patterns associated to rainfall-aerosol interaction in La Plata Basin: one in which the dynamic conditions are more important than aerosols to generate rain; and a second one where the aerosol particles have a role in rain formation, acting mainly to suppress rainfall over La Plata Basin.

Description: Size-resolved aerosol composition and link to hygroscopicity at a forested site in Colorado Atmospheric Chemistry and Physics Discussions, 13, 23817-23843, 2013 Author(s): E. J. T. Levin, A. J. Prenni, B. Palm, D. Day, P. Campuzano-Jost, P. M. Winkler, S. M. Kreidenweis, P. J. DeMott, J. Jimenez, and J. N. Smith Aerosol hygroscopicity describes the ability of a particle to take up water and form a cloud droplet. Modeling studies have shown sensitivity of precipitation-producing cloud systems to the availability of aerosol particles capable of serving as cloud condensation nuclei (CCN), and hygroscopicity is a key parameter controlling the number of available CCN. Continental aerosol is typically assumed to have a representative hygroscopicity parameter, κ, of 0.3; however, in remote locations this value can be lower due to relatively large mass fractions of organic components. To further our understanding of aerosol properties in remote areas, we measured size-resolved aerosol chemical composition and hygroscopicity in a forested, mountainous site in Colorado during the six-week BEACHON-RoMBAS campaign. This campaign followed a year-long measurement period at this site, and results from the intensive campaign shed light on the previously reported seasonal cycle in aerosol hygroscopicity. New particle formation events were observed routinely at this site and nucleation mode composition measurements indicated that the newly formed particles were predominantly organic. These events likely contribute to the dominance of organic species at smaller sizes, where aerosol organic mass fractions of non-refractory components were between 70–90%. Corresponding aerosol hygroscopicity was observed to range from κ = 0.15–0.22, with hygroscopicity increasing with particle size. Aerosol chemical composition measured by an Aerosol Mass Spectrometer and calculated from hygroscopicity measurements agreed very well during the intensive study with an assumed value of κ org = 0.13 resulting in the best agreement.

Description: Water resources in northern Cameroon have continuously been reducing over the past years. Many studies have suggested two principal causes: (1) human activities such as poor farming practices, unsustainable use of water resources, increased demand of water, deforestation, land-use change, etc., (2) human-induced climate change. Northern Cameroon in this study includes: the Adamawa, North and Far North regions located closer to the Sahel regions of Africa. These regions are already water stressed because of their location and any further change in climate with rising temperature would impact water resource either positively or negatively. Time series analysis and a 12-month standardized precipitation index (SPI12) with digital data between 1957 and 2006 were used to investigate the variation of water resources in northern Cameroon. Results obtained varies between the different regions with an increased annual trend in temperature and precipitation for Ngaoundere (Adamawa region) and Garoua (north region), whereas Maroua (far north region) had a decreased annual trend in both precipitation and temperature. Further variability results obtained from a SPI12 show that wetter period out number drought period in all three regions. The study concluded that water resources vary with the changing climatic condition and the severity of the impact varies from region to region. Furthermore, water deficiency in northern Cameroon might not be due to climate change. The reasons might be a combination of poor water management and other factors such population growth, the environmental condition, etc.

Description: Twenty groundwater samples were collected from Enugu metropolis over two seasonal periods in order to characterize the groundwater and to determine its quality for domestic and irrigation purposes. The results show that groundwater of the area is strongly acidic to slightly alkaline in nature and varied from “soft water” to “moderately hard” water type. The major ionic trend is in the order Cl −  〉 Na +  〉 HCO 3 −  〉 K +  〉 Mg 2+  〉 Ca 2+  〉 SO 4 2− and Mg 2+  〉 Cl −  〉 Na +  〉 K +  〉 Ca 2+  〉 HCO 3 −  〉 SO 4 2− in abundance for dry and rainy seasons, respectively. The results also reveal that there is an increase in trend of the ionic concentrations during the dry season, which arises from weathering of the host rocks and anthropogenic activities. Two hydrochemical facies were identified, namely, Na + –K + –Cl − –SO 4 2− and Ca 2+ –Mg 2+ –Cl − –SO 4 2− , with Na + –K + –Cl − –SO 4 2− as the dominant facies for the two seasons. Groundwater quality ranges from “very poor water” to “good water” and “water unsuitable for drinking purposes” to “good water” for the dry season and rainy season investigations, respectively. The groundwater is suitable for irrigation purposes for the two seasons.

Description: The objective of this work was to study sorption–desorption and/or precipitation–dissolution processes of Hg(II) compounds considering an eventual contact of soils with Hg-bearing wastes. In addition, this study contributes new data about Hg(II) chemistry in alkaline systems. Saline and alkaline soils with low organic matter (〈1 %) and high clay content (60–70 %) were obtained near a chlor-alkali plant. Batch techniques were used to perform the experiments using 0.1 M NaNO 3 solutions. Total Hg(II) concentrations ranged from 6.2 × 10 −8 to 6.3 × 10 −3  M. Sorption of Hg(II) was evaluated at two concentration ranges: (a) 6.2 × 10 −8 to 1.1 × 10 −4  M, and (b) 6.4 × 10 −4 to 6.3 × 10 −3  M. At low Hg(II) concentrations, adsorption occurred with a maximum sorption capacity ranging from 4 to 5 mmol/kg. At high Hg(II) concentrations, sorption–precipitation reactions occurred and maximum sorption capacity ranged from 17 to 31 mmol/kg. The distribution of Hg(II) hydrolysis products showed that Hg(OH) 2 was the predominant species under soil conditions. According to sorption experiments, X-ray diffraction and chemical speciation modelling, the presence of Hg(OH) 2 in the interlayer of the interstratified clay minerals can be proposed. Hg(OH) 2 was partially desorbed by repeated equilibrations in 0.1 M NaNO 3 solution. Desorption ranged from 0.1 to 0.9 mmol/kg for soils treated with 5.8 × 10 −5  M Hg(II), whereas 2.1–3.8 mmol/kg was desorbed from soils treated with 6.3 × 10 −3  M Hg(II). Formation of soluble Hg(II) complexes was limited by low organic matter content, whereas neutral Hg(OH) 2 was retained by adsorption on clay mineral surfaces.

Description: Seawater intrusion is a major threat to the rapidly depleting groundwater resources in the coastal areas of India. Groundwater-based irrigation, significant industrial development and rapid urbanization are some of the key contributors exacerbating the stress on groundwater resources. Vulnerability to seawater intrusion in the Ramanathapuram district of Eastern India is assessed here utilizing the GALDIT method, for a period of 10 years (2001–2010). Results revealed a drastic increase in percent area coverage under moderate vulnerability, from 19.5 to 53.88 %, between the years 2001 and 2010. On the contrary, areas classified as highly vulnerable underwent minor changes over the span of the study. Vulnerability of the study area was also analyzed for the year 2050 considering an average global mean sea level rise of 3.1 mm/year. Results from the analysis for the year 2050 showed that, almost, the entire study area (~97 %) was classified under moderate vulnerability. As a remedial measure to this imminent threat, favorable zones for artificial recharge were delineated on the basis of overlay analysis with weightage values for important controlling factors. Subsequently, the quantity of artificial recharge required to inhibit the intrusion of seawater, at specified favorable zones were estimated to be 674.87, 599.18 and 1,450.66 m 3 /year.

Description: Agricultural nonpoint source (NPS) pollution at the Three Gorges reservoir area in China has been increasingly recognized as a threat to aquatic environment in recent years due to the serious eutrophication problem. Adsorbed NPS pollution is one of the major forms of NPS pollution in mountainous regions, the essential of the adsorbed NPS pollution is soil loss. Thus, simple, highly sensitive and continuous methods are required to simulate and quantify sediments yield at watershed scales. It is imperative to construct an integrated model to estimate the sediment yield and adsorbed NPS pollution load. According to the characteristics of climate, hydrology, topography, geology, geomorphology and land use types in Three Gorges reservoir area, a GIS-based dynamic-integrated-distributed model of annual adsorbed NPS load was presented in view of impacts of the rainfall intensity, sediment delivery ratio (SDR) and land management, where the temporally dynamic-continuous model of annual sediment yield was established by modifying the revised Universal Soil Loss Equation (RUSLE), and the spatially integrated-distributed model of annual adsorbed NPS load was then developed via the correlation between sediment yield and adsorbed NPS load. Furthermore, a case study of the Jialing River basin in China was applied to validate the integrated model, the dynamic-distributed coupling among GIS technology, sediment yield model, and adsorbed NPS load model was achieved successfully. The simulation results demonstrate the following: (1) runoff and sediment are influenced greatly by rainfall intensity, SDR and vegetation cover; rainfall and land management show high sensitivities to the integrated model; the average annual adsorbed TN and TP pollution loads from 2006 to 2010 decreased by 76 and 74 % compared with the previous treatment (1990), respectively. (2) Spatio-temporal variations of adsorbed NPS nitrogen and phosphorus load are mainly related to different land use types and the background level of nutriments in topsoil; different land use types have different contribution rates; the largest contribution rates of adsorbed total nitrogen (TN, 58.9 %) and total phosphorus (TP, 53 %) loads are both from the dryland cropland. (3) The identification of critical source areas can help to implement the prevention and control measures aiming at the reduction of water environmental pollution. These results will provide useful and valuable information for decision makers and planners to take sustainable land use management and soil conservation measures for the control of sediment pollution in the Three Gorges reservoir area. The application of this model in the catchment shows that the integrated model may be used as a major tool to assess sediment yield risks and adsorbed NPS pollution load at mountainous watersheds.

Description: Lakes on the Qinghai-Tibet Plateau (QTP) are of particular interest to researchers because of their unusual high concentrations of lithium (Li), boron (B), and potassium (K). Kurnakovite, a member of the inderite group, is well-distributed on the QTP, however, the geochemical mechanisms of kurnakovite transformation requires further identification and clarification. This study aims to elucidate the geochemical mechanisms of kurnakovite deposits on the QTP from chloropinnoite dissolution using chemical kinetic and spectroscopic techniques. The new borate, chloropinnoite 2MgO · 2B 2 O 3  · MgCl 2  · 14H 2 O, was obtained from the natural concentrated salt lake brine on the QTP. The kinetics of chloropinnoite dissolved in 4.5 % (wt%) boric acid solution at 303, 313, and 323 K were investigated. The characterization of the phase transitions and the kinetics were carried out by chemical titration analysis, X-ray powder diffraction spectrometry, Fourier Transform Infrared (FT-IR), and Raman spectrometry. The results demonstrate that similar kinetic processes occur at all three temperatures and can be divided into dissolution, supersaturation, and precipitation, according to three distinct kinetic curves. Kurnakovite was the final phase transition (terminal secondary mineral) within the chloropinnoite-boric acid solution. The dissolution rate of chloropinnoite (the dissolution stage) could be described by second order pseudo-homogeneous reaction model. According to the spectroscopy data, geochemical mechanism of kurnakovite was identified. The new geochemical hypothesis well explains the geochemical mechanism of kurnakovite minerals on the QTP.

Description: Soil radon ( 222 Rn) has been monitored during winter months under cool-temperate deciduous stands of different surface geology in Tomakomai and in Sapporo, Hokkaido, Japan. Radon level was lower in Tomakomai of immature soil of porous volcanic ash emitted from an active volcano (Mt. Tarumae), compared with those in Sapporo of alluvial sediments. In Tomakomai, mean value of the 222 Rn activity concentration was higher in winter (570 Bq m −3 ) than in summer (350 Bq m −3 ) at a depth of 1 m, which is consistent with the results in cold and dry winter reported in the literature. In contrast, soil radon decreasing with decreasing soil temperature from mid-September (5.0 kBq m −3 ) remained low (2.6 kBq m −3 ) under persistent snow in Sapporo, which had already been observed in the same location. Measurements of the activity concentrations of 222 Rn in snow and in snow air as well as in soil air indicate that the small amount of 222 Rn is released from the ground surface to the overlying snowpack with a 222 Rn flux density of 0.4 mBq m −2  s −1 under thick snow cover in Sapporo.

Description: In the Three Gorges of China, there are frequent landslides, and the potential risk of landslides is tremendous. An efficient and accurate method of generating landslide susceptibility maps is very important to mitigate the loss of lives and properties caused by these landslides. This paper presents landslide susceptibility mapping on the Zigui-Badong of the Three Gorges, using rough sets and back-propagation neural networks (BPNNs). Landslide locations were obtained from a landslide inventory map, supported by field surveys. Twenty-two landslide-related factors were extracted from the 1:10,000-scale topographic maps, 1:50,000-scale geological maps, Landsat ETM + satellite images with a spatial resolution of 28.5 m, and HJ-A satellite images with a spatial resolution of 30 m. Twelve key environmental factors were selected as independent variables using the rough set and correlation coefficient analysis, including elevation, slope, profile curvature, catchment aspect, catchment height, distance from drainage, engineering rock group, distance from faults, slope structure, land cover, topographic wetness index, and normalized difference vegetation index. The initial, three-layered, and four-layered BPNN were trained and then used to map landslide susceptibility, respectively. To evaluate the models, the susceptibility maps were validated by comparing with the existing landslide locations according to the area under the curve. The four-layered BPNN outperforms the other two models with the best accuracy of 91.53 %. Approximately 91.37 % of landslides were classified as high and very high landslide-prone areas. The validation results show sufficient agreement between the obtained susceptibility maps and the existing landslide locations.

Description: Hydrothermally altered bedrock in the Silverton mining area, southwest Colorado, USA, contains sulfide minerals that weather to produce acidic and metal-rich leachate that is toxic to aquatic life. This study utilized a geographic information system (GIS) and statistical approach to identify watershed-scale geologic variables in the Silverton area that influence water quality. GIS analysis of mineral maps produced using remote sensing datasets including Landsat Thematic Mapper, advanced spaceborne thermal emission and reflection radiometer, and a hybrid airborne visible infrared imaging spectrometer and field-based product enabled areas of alteration to be quantified. Correlations between water quality signatures determined at watershed outlets, and alteration types intersecting both total watershed areas and GIS-buffered areas along streams were tested using linear regression analysis. Despite remote sensing datasets having varying watershed area coverage due to vegetation cover and differing mineral mapping capabilities, each dataset was useful for delineating acid-generating bedrock. Areas of quartz–sericite–pyrite mapped by AVIRIS have the highest correlations with acidic surface water and elevated iron and aluminum concentrations. Alkalinity was only correlated with area of acid neutralizing, propylitically altered bedrock containing calcite and chlorite mapped by AVIRIS. Total watershed area of acid-generating bedrock is more significantly correlated with acidic and metal-rich surface water when compared with acid-generating bedrock intersected by GIS-buffered areas along streams. This methodology could be useful in assessing the possible effects that alteration type area has in either generating or neutralizing acidity in unmined watersheds and in areas where new mining is planned.

Description: The aim of this study was to evaluate total mercury concentration and its lithogenic and exogenic fractions in some calcareous soils of western Iran, where water contamination and bioaccumulation of mercury have been reported in the bottomland’s reservoir. In particular, we investigated soil physico-chemical properties and weathering conditions related to lithogenic and exogenic fractions of mercury for two groups of calcareous soils with a known comparative pedological evolution and weathering condition that was evident in the presence or absence of underlying layers of accumulated clay. Our results showed that the total mercury content of the studied soils ranged from 45.40 to 830.36 with a mean of 486.81 μg kg −1 . Furthermore, calculation of mercury fractions revealed that lithogenic and exogenic fractions vary slightly according to the three reference elements (Fe, U and Nb) used in the calculations for the two groups of studied soils. The results also illustrated that most of the mercury content is of exogenic origin; therefore, total mercury variations are closely related to the content of exogenic mercury, while the lithogenic fraction exhibited no relationship with total mercury concentration. Moreover, application of the weathering indexes of Parker and the CaO/ZrO 2 molar ratio supported the dependence of lithogenic mercury accumulation on weathering intensity in the studied calcareous soils. However, the significance of this relationship is stronger for more weathered calcareous soils; in such cases, fine-particle fractions are more developed, which encourages carrier phases such as organic materials and iron oxyhydroxides to become involved in more efficient fixation of mercury. Nevertheless, the formation of underlying layers of accumulated clay, i.e. argillic horizons, may restrain fixation of exogenic mercury by limiting its atmospheric input.

Description: Dar es Salaam Quaternary coastal aquifer is a major source of water supply in Dar es Salaam City used for domestic, agricultural, and industrial uses. However, groundwater overdraft and contamination are the major problems affecting the aquifer system. This study aims to define the principal hydrogeochemical processes controlling groundwater quality in the coastal strip of Dar es Salaam and to investigate whether the threats of seawater intrusion and pollution are influencing groundwater quality. Major cations and anions analysed in 134 groundwater samples reveal that groundwater is mainly affected by four factors: dissolution of calcite and dolomite, weathering of silicate minerals, seawater intrusion due to aquifer overexploitation, and nitrate pollution mainly caused by the use of pit latrines and septic tanks. High enrichment of Na + and Cl − near the coast gives an indication of seawater intrusion into the aquifer as also supported from the Na–Cl signature on the Piper diagram. The boreholes close to the coast have much higher Na/Cl molar ratios than the boreholes located further inland. The dissolution of calcite and dolomite in recharge areas results in Ca–HCO 3 and Ca–Mg–HCO 3 groundwater types. Further along flow paths, Ca 2+ and Na + ion exchange causes groundwater evolution to Na–HCO 3 type. From the PHREEQC simulation model, it appears that groundwater is undersaturated to slightly oversaturated with respect to the calcite and dolomite minerals. The results of this study provide important information required for the protection of the aquifer system.

Description: This study focused on nitritation reactions for the removal of highly concentrated nitrogen from water recycled by a MWTP (Municipal Wastewater Treatment Plant) for the preparation of effluent standards which will be strengthened. To examine the changes that occur during a nitritation reaction with a variety of SRT operations when inducing a stable nitritation reaction, a reactor was operated on a laboratory scale in this study. Digestion tank supernatant flowed into a laboratory-scale reactor and organic matter in the effluent under various operation conditions was classified into four types according to ASM standards using the test known as the OUR (Oxygen Uptake Rate)-test. Most organic matter in the digestion tank supernatant appeared to consist of mainly the S I component out of non-biodegradable organic matter. During the operation period of the effluent in the laboratory-scale reactor, if a nitritation reaction occurs in a stable manner, most biodegradable organic matter is removed, consisting of mainly the S I component, like the influent. Particularly, nitrogen was removed after the S S was removed from the organic matters. Moreover, through a multiple correlation analysis between the operation results from a laboratory-scale reaction bath and the organic composition of the effluent, a method to predict the organic composition of effluents that relies on the operation result of the effluent is proposed.

Description: The aim of this study was to evaluate the release kinetics, speciation, and fractionation of boron (B) in some calcareous soils of western Iran. Ten surface soil samples were incubated with 100 mg B kg −1 for a week at field capacity moisture. After air drying of samples, the trend of B release was experimented using sequential extraction with 10 mM CaCl 2 . B speciation in soil solution was calculated for the first and the last steps of extraction by the visual MINTEQ program. The distribution of B among five fractions including exchangeable (F1), specially adsorbed (F2), bound by Fe–Mn oxides (F3), organically bound (F4) and residual (F5), was determined in control and spiked soils. The results indicated that the release rates were initially rapid followed by a slower reaction and the main proportion of the added B was extracted by CaCl 2 . The release kinetics of B was described well with Elovich, parabolic diffusion, power function, and first-order equations. The speciation results revealed that the uncharged boric acid (H 3 BO 3 0 ) was the dominant species in soil solutions. In control soils, B concentration in different fractions decreased in the following order: F5 〉 F1 〉 F2 〉 F3 〉 F4. In spiked soils, however, the largest and the smallest fractions were exchangeable and residual, respectively. This implies that B transformation from soluble to less mobile and non-labile forms is not a rapid process and requires more than a week. The significant relationship observed between kinetic parameters of power and parabolic equations and organically bound B fraction and OM content indicated that organic matter played an important role in B adsorption and release in calcareous soils.

Description: Atmospheric parameters in a subtropical cloud regime transition derived by AIRS+MODIS – observed statistical variability compared to ERA-Interim Atmospheric Chemistry and Physics Discussions, 13, 24051-24085, 2013 Author(s): M. M. Schreier, B. H. Kahn, K. Sušelj, J. Karlsson, S. C. Ou, Q. Yue, and S. L. Nasiri Cloud occurrence, microphysical and optical properties and atmospheric profiles within a subtropical cloud regime transition in the northeastern Pacific Ocean are obtained from a synergistic combination of the Atmospheric Infrared Sounder (AIRS) and the MODerate resolution Imaging Spectroradiometer (MODIS). The observed cloud parameters and atmospheric thermodynamic profile retrievals are binned by cloud type and analyzed based on their probability density functions (PDFs). Comparison of the PDFs to data from the European Center for Medium Range Weather Forecasting Re-analysis (ERA-Interim) shows a strong difference in the occurrence of the different cloud types compared to clear sky. An increasing non-Gaussian behavior is observed in cloud optical thickness (τ c ), effective radius ( r e ) and cloud top temperature ( T c ) distributions from Stratocumulus to Trade Cumulus, while decreasing values of lower tropospheric stability are seen. However, variations in the mean, width and shape of the distributions are found. The AIRS potential temperature (θ) and water vapor ( q ) profiles in the presence of varying marine boundary layer (MBL) cloud types show overall similarities to the ERA-Interim in the mean profiles, but differences arise in the higher moments at some altitudes. The differences between the PDFs from AIRS+MODIS and ERA-Interim make it possible to pinpoint systematic errors in both systems and helps to understand joint PDFs of cloud properties and coincident thermodynamic profiles from satellite observations.

Description: Establishing the contribution of lawn mowing to atmospheric aerosol levels in American suburbs Atmospheric Chemistry and Physics Discussions, 13, 24435-24480, 2013 Author(s): R. M. Harvey, J. Zahardis, and G. A. Petrucci Green leaf volatiles (GLVs) are a class of wound-induced volatile organic compounds emitted by several plant species. Turfgrasses emit a complex profile of GLVs upon mowing, as evidenced by the "freshly cut grass" smell, some of which are readily oxidized in the atmosphere to contribute to secondary organic aerosol (SOA). The contribution of lawn mowing-induced SOA production may be especially impactful at the urban/suburban interface, where urban hubs provide a source of anthropogenic oxidants and SOA while suburban neighborhoods have the potential to emit large quantities of reactive, mow-induced GLVs. This interface provides a unique opportunity to study aerosol formation in a multi-component system and at a regionally relevant scale. Freshly cut grass was collected from a study site in Essex Junction, Vermont and was placed inside a 775 L Teflon experimental chamber. Thermal desorption gas chromatography mass spectrometry (TD-GC/MS) was used to characterize the emitted GLV profile. Ozone was introduced to the experimental chamber and TD-GC/MS was used to monitor the consumption of these GLVs and the subsequent evolution of gas phase products while a scanning mobility particle sizer was used to continuously measure aerosol size distributions and mass loadings as a result of grass clipping ozonolysis. Freshly cut grass found to emit a complex mixture of GLVs, dominated by cis -3-hexenyl acetate and cis -3-hexenol, which were released at an initial rate of 1.8 (±0.5) μg and 0.07 (±0.03) μg per square meter of lawn mowed with each mowing. Chamber studies using pure standards of cis -3-hexenyl acetate (CHA) and cis -3-hexenol (HXL) were found to have aerosol yields of 1.2 (±1.1)% and 3.3 (±3.1)%, respectively. Using these aerosol yields and the emission rate of these CHA and HXL by grass, SOA evolution by ozonolysis of grass clippings was predicted. However, the measured SOA mass produced from the ozonolysis of grass clippings exceeded the predicted amount, by upwards of ~ 150%. The ozonolysis of a mixture of CHA and HXL representative of environmental mixing ratios also failed to accurately model the SOA mass produced by grass clippings. Aerial photographs and geospatial analysis were used to determine the turfgrass coverage in a suburban neighborhood, which was then used along with measured SOA production as a function of grass mowed to determine that lawn mowing has the potential to contribute 47 μg m −2 SOA to the atmosphere per mowing event by ozonolysis, which cannot be modeled solely by the ozonolysis of CHA, HXL or a representative mixture of the two.

Description: Global distributions and trends of atmospheric ammonia (NH 3 ) from IASI satellite observations Atmospheric Chemistry and Physics Discussions, 13, 24301-24342, 2013 Author(s): M. Van Damme, L. Clarisse, C. L. Heald, D. Hurtmans, Y. Ngadi, C. Clerbaux, A. J. Dolman, J. W. Erisman, and P. F. Coheur Ammonia (NH 3 ) emissions in the atmosphere have strongly increased in the past decades, largely because of the intensive livestock production and use of fertilizers. As a short-lived species, NH 3 is highly variable in the atmosphere and its concentration is generally small, except in and close to local source areas. While ground-based measurements are possible, they are challenging and sparse. Advanced infrared sounders in orbit have recently demonstrated their capability to measure NH 3 , offering a new tool to refine global and regional budgets. In this paper we describe an improved retrieval scheme of NH 3 total columns from the measurements of the Infrared Atmospheric Sounding Interferometer (IASI). It exploits the hyperspectral character of this instrument by using an extended spectral range (800–1200 cm −1 ) where NH 3 is optically active. This scheme consists of the calculation of a dimensionless spectral index from the IASI level1C radiances, which is subsequently converted to a total NH 3 column using look-up-tables built from forward radiative transfer model simulations. We show how to retrieve the NH 3 total columns from IASI quasi-globally and twice daily, above both land and sea, without large computational resources and with an improved detection limit. The retrieval also provides error characterization on the retrieved columns. Five years of IASI measurements (1 November 2007 to 31 October 2012) have been processed to acquire the first global and multiple-year dataset of NH 3 total columns, which are evaluated and compared to similar products from other retrieval methods. Spatial distributions from the five years dataset are provided and analyzed at global and regional scales. We show in particular the ability of this method to identify smaller emission sources than those reported previously, as well as transport patterns above sea. The five year time series is further examined in terms of seasonality and inter-annual variability (in particular as a function of fire activity) separately for the Northern and Southern Hemispheres.

Description: Aircraft measurements of polar organic tracer compounds in tropospheric particles (PM 10 ) over Central China Atmospheric Chemistry and Physics Discussions, 13, 24481-24516, 2013 Author(s): P. Q. Fu, K. Kawamura, Y. F. Cheng, S. Hatakeyama, A. Takami, H. Li, and W. Wang Atmospheric aerosol samples were collected by aircraft at low to middle altitudes (0.8–3.5 km a.g.l.) over Central East to West China during summer 2003 and spring 2004. The samples were analyzed for polar organic compounds using a technique of solvent extraction/BSTFA derivatization/gas chromatography-mass spectrometry. Biogenic secondary organic aerosol (SOA) tracers from the oxidation of isoprene were found to be more abundant in summer (3.3–138 ng m −3 , mean 39 ng m −3 ) than in spring (3.2–42 ng m −3 , 15 ng m −3 ), while α/β-pinene and β-caryophyllene SOA tracers showed similar abundance between these two seasons. A strong positive correlation ( R 2 =0.83) between levoglucosan and β-caryophyllinic acid was found in the spring samples versus a weak correlation ( R 2 =0.17) in the summer samples, implying substantial contributions from biomass burning to the β-caryophyllinic acid production in spring. Two organic nitrogen species (oxamic acid and carbamide) were detected in the aircraft aerosol samples and their concentrations were comparable to those of biogenic SOA tracers. Most of the POA and SOA tracers were less abundant at higher altitudes, suggesting they are of ground surface origin, either being directly emitted from anthropogenic/natural sources on the ground surface, or rapidly formed through photooxidation of their precursors emitted from the ground surface and then diluted during uplifting into the troposphere. This study demonstrates that primary biological aerosols, biogenic SOA, and organic nitrogen species are important components of organic aerosols in the troposphere over Central China.

Description: Black carbon emissions from in-use ships: a California regional assessment Atmospheric Chemistry and Physics Discussions, 13, 24675-24712, 2013 Author(s): G. M. Buffaloe, D. A. Lack, E. J. Williams, D. Coffman, K. L. Hayden, B. M. Lerner, S-M. Li, I. Nuaaman, P. Massoli, T. B. Onasch, P. K. Quinn, and C. D. Cappa Black carbon (BC) mass emission factors (EF BC ; g-BC (kg-fuel) −1 ) from a variety of ocean going vessels have been determined from measurements of BC and carbon dioxide (CO 2 ) concentrations in ship plumes intercepted by the R/V Atlantis during the 2010 California Nexus (CalNex) campaign. The ships encountered were all operating within 24 nautical miles of the California coast and were utilizing relatively low sulphur fuels. Black carbon concentrations within the plumes, from which EF BC values are determined, were measured using four independent instruments: a photoacoustic spectrometer and a particle soot absorption photometer, which measure light absorption, and a single particle soot photometer and soot particle aerosol mass spectrometer, which measure the mass concentration of refractory BC directly. The measured EF BC have been divided into vessel type categories and engine type categories, from which averages have been determined. The geometric average EF BC , determined from over 71 vessels and 135 plumes encountered, was 0.31 g-BC (kg-fuel) −1 . The most frequent engine type encountered was the slow speed diesel (SSD), and the most frequent SSD vessel type was the cargo ship sub-category. Average and median EF BC values from the SSD category are compared with previous observations from the Texas Air Quality Study (TexAQS) in 2006, during which the ships encountered were predominately operating on high sulphur fuels. There is a statistically significant difference between the EF BC values from CalNex and TexAQS for SSD vessels and for the cargo and tanker ship types within this engine category. The CalNex EF BC values are lower than those from TexAQS, suggesting that operation on lower sulphur fuels is associated with smaller EF BC values.

Description: A case study into the measurement of ship emissions from plume intercepts of the NOAA Ship Miller Freeman Atmospheric Chemistry and Physics Discussions, 13, 24635-24674, 2013 Author(s): C. D. Cappa, E. J. Williams, D. A. Lack, G. M. Buffaloe, D. Coffman, K. L. Hayden, S. C. Herndon, B. M. Lerner, S-M. Li, P. Massoli, R. McLaren, I. Nuaaman, T. B. Onasch, and P. K. Quinn Emissions factors (EFs) for gas and sub-micron particle-phase species were measured in intercepted plumes as a function of vessel speed from an underway research vessel, the NOAA Ship Miller Freeman , operating a medium-speed diesel engine on low-sulfur marine gas oil. For many of the particle-phase species, EFs were determined using multiple measurement methodologies, allowing for an assessment of how well EFs from different techniques agree. The total sub-micron PM (PM 1 ) was dominated by particulate black carbon (BC) and particulate organic matter (POM), with an average POM / BC ratio of 1.3. Consideration of the POM / BC ratios observed here with literature studies suggests that laboratory and in-stack measurement methods may over-estimate primary POM EFs relative to those observed in emitted plumes. Comparison of four different methods for black carbon measurement indicates that careful attention must be paid to instrument limitations and biases when assessing EF BC . Particulate sulfate (SO 4 2− ) EFs were extremely small and the particles emitted by Miller Freeman were inefficient as cloud condensation nuclei (CCN), even at high super saturations, consistent with the use of very low sulfur fuel and the overall small emitted particle sizes. All measurement methodologies consistently demonstrate that the measured EFs (fuel mass basis) for PM 1 mass, BC and POM decreased as the ship slowed. Particle number EFs were approximately constant across the speed change, with a shift towards smaller particles being emitted at slower speeds. Emissions factors for gas-phase CO and formaldehyde (HCHO) both increased as the vessel slowed, while EFs for NO x decreased and SO 2 EFs were approximately constant.

Description: Heterogeneous reaction of N 2 O 5 with illite and Arizona Test Dust particles Atmospheric Chemistry and Physics Discussions, 13, 24855-24884, 2013 Author(s): M. J. Tang, G. Schuster, and J. N. Crowley The heterogeneous reaction of N 2 O 5 with airborne illite and Arizona Test Dust particles was investigated at room temperature and at different relative humidities using an atmospheric pressure aerosol flow tube. N 2 O 5 at concentrations in the range 8 to 24×10 12 molecule cm −3 was monitored using thermal-dissociation cavity ring-down spectroscopy at 662 nm. At zero relative humidity a large uptake coefficient of N 2 O 5 to illite was obtained, γ(N 2 O 5 ) = 0.09, which decreased to 0.04 as relative humidity was increased to 67%. In contrast, the uptake coefficient derived for ATD is much lower (~ 0.006) and, within experimental uncertainty, independent of relative humidity (0–67%). Potential explanations are given for the significant differences between the uptake behaviour for ATD and illite and the results are compared with uptake coefficients for N 2 O 5 on other mineral surfaces.

Description: A case study of sea breeze blocking regulated by sea surface temperature along the English south coast Atmospheric Chemistry and Physics Discussions, 13, 24785-24807, 2013 Author(s): J. K. Sweeney, J. M. Chagnon, and S. L. Gray The sensitivity of sea breeze structure to sea surface temperature (SST) and coastal orography is investigated in convection-permitting Met Office Unified Model simulations of a case study along the south coast of England. Changes in SST of 1 K are shown to significantly modify the structure of the sea breeze. On the day of the case study the sea breeze was partially blocked by coastal orography, particularly within Lyme Bay. The extent to which the flow is blocked depends strongly on the static stability of the marine boundary layer. In experiments with colder SST, the marine boundary layer is more stable, and the degree of blocking is more pronounced. The implications of prescribing fixed SST from climatology in numerical weather prediction model forecasts of the sea breeze are discussed.

Description: Using a WRF simulation to examine regions where convection impacts the Asian summer monsoon anticyclone Atmospheric Chemistry and Physics Discussions, 13, 24809-24853, 2013 Author(s): N. K. Heath and H. E. Fuelberg The Asian summer monsoon is a prominent feature of the global circulation that is associated with an upper-level anticyclone (ULAC) that stands out vividly in satellite observations of trace gases. The ULAC also is an important region of troposphere-to-stratosphere transport. We ran the Weather Research and Forecasting (WRF) model at convective-permitting scales (4 km grid spacing) between 10–20 August 2012 to understand the role of convection in transporting boundary layer air into the upper-level anticyclone. Such high-resolution modeling of the Asian ULAC previously has not been documented in the literature. Comparison of our WRF simulation with reanalysis and satellite observations showed that WRF simulated the atmosphere sufficiently well to be used to study convective transport into the ULAC. A back-trajectory analysis based on hourly WRF output showed that 〉 90% of convectively influenced parcels reaching the ULAC came from the Tibetan Plateau (TP) and the southern slope (SS) of the Himalayas. A distinct diurnal cycle is seen in the convective trajectories, with their greatest impact occurring between 1600–2300 local solar time. This finding highlights the role of "everyday" diurnal convection in transporting boundary layer air into the ULAC. WRF output at 15 min intervals was produced for 16 August to examine the convection in greater detail. This high-temporal output revealed that the weakest convection in the study area occurred over the TP. However, because the TP is at 3000–5000 m a.m.s.l., its convection does not have to be as strong to reach the ULAC as in lower altitude regions. In addition, because the TP's elevated heat source is a major cause of the ULAC, we propose that convection over the TP and the neighboring SS is ideally situated geographically to impact the ULAC. The vertical mass flux of water vapor into the ULAC also was calculated. Results show that the TP and SS regions dominate other Asian regions in transporting moisture vertically into the ULAC. Because convection reaching the ULAC is more widespread over the TP than nearby, we propose that the abundant convection partially explains the TP's dominant water vapor fluxes. In addition, greater outgoing longwave radiation reaches the upper levels of the TP due to its elevated terrain. This creates a warmer ambient upper level environment, allowing parcels with greater saturation mixing ratios to enter the ULAC. Lakes in the Tibetan Plateau are shown to provide favorable conditions for deep convection during the night.

Description: An assessment of the performance of the Monitor for AeRosols and GAses in ambient air (MARGA): a semi-continuous method for soluble compounds Atmospheric Chemistry and Physics Discussions, 13, 25067-25124, 2013 Author(s): I. C. Rumsey, K. A. Cowen, J. T. Walker, T. J. Kelly, E. A. Hanft, K. Mishoe, C. Rogers, R. Proost, G. M. Beachley, G. Lear, T. Frelink, and R. P. Otjes Ambient air monitoring as part of the US Environmental Protection Agency's (US EPA's) Clean Air Status and Trends Network (CASTNet) currently uses filter packs to measure weekly integrated concentrations. The US EPA is interested in supplementing CASTNet with semi-continuous monitoring systems at select sites to characterize atmospheric chemistry and deposition of nitrogen and sulfur compounds at higher time resolution than the filter pack. The Monitor for AeRosols and GAses in ambient air (MARGA) measures water-soluble gases and aerosols at hourly temporal resolution. The performance of the MARGA was assessed under the US EPA Environmental Technology Verification (ETV) program. The assessment was conducted in Research Triangle Park, North Carolina from 8 September–8 October 2010 and focused on gaseous SO 2 , HNO 3 and NH 3 and aerosol SO 4 − , NO 3 − and NH 4 + . Precision of the MARGA was evaluated by calculating the median absolute relative percent difference (MARPD) between paired hourly results from duplicate MARGA units (MUs), with a performance goal of

Description: Changes in the stability of slopes reinforced with piles involve a complex interaction process between piles, soil, hydrogeological conditions and the engineering geological environment. Correlation analysis between each influencing factor will contribute to a better overall understanding of the main influencing factors. This is of great significance for disaster prevention and the optimization of soil slopes reinforced with piles. The 17 factors influencing the stability of soil slopes reinforced with piles were analyzed in this study, and the weighting of each influencing factor was determined using the analytic hierarchy process along with the experiences of various experts and the author’s experience. The results showed that: (1) soil rheological characteristics and physical and mechanical soil properties have the maximum weighting on the stability of soil slopes reinforced with piles; that is, they are the most important factors influencing the stability of soil slopes reinforced with piles; (2) embedded pile depth or pile anchoring depth and the pile position have the second greatest weighting; (3) rainfall, pile sectional dimensions and pile spacing, are also important factors. Each of these factors was not weighted less than 0.059.

Description: The water quality of the Vacacaí River was assessed at different sites in the period between winter 2005 and autumn 2006. All samples were analyzed for 52 elements (Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Th, Li, Be, Mg, Al, Ca, V, Cr, Mn, Fe, Ni, Co, Cu, Zn, Ga, As, Se, Rb, Sr, Ag, Cd, In, Cs, Ba, Tl, Pb, Bi, U, Na, K, Hg, B, Mo, Sn, Te, Ti), temperature, pH, ammonia, and alkalinity levels. Water from the Vacacaí River ranged from slightly acidic to alkaline. No difference was observed in the chemical composition at different sites of the Vacacaí River. Levels of Ba, Ca, Sr and Mg increase in the dry seasons and reach their highest concentrations in autumn; Be and U decrease in the dry season and reach their highest concentration in spring. Al, Fe, Cr, Ni, Th, U Mn, Ca and Mg are highly positively related, indicating a common origin. Se and Cu are probably from anthropogenic source, from the rice crops of the margins of the river. Waterborne Al and Fe levels were above the desirable level for drinking water at all sites during all seasons. These results demonstrate the need for constant monitoring of water parameters, which is crucial to ensure water quality for the population of this region.

Description: Disasters caused by events such as earthquake, flooding, rock falls, landslides are often encountered. However, generally, the reasons for the destructive and devastating effects of these nature events are that settlement locations were chosen without site investigation studies, or that available studies were inadequate. Such inadequacies in the field are related to inappropriate settlement location and the resulting damage caused by rock falls. This study evaluated rockfall risk in a settlement that developed in a similar manner. The study was carried out in Boğaziçi village of Kemah (Erzincan/Turkey), which is located in a very important tectonic zone. The study site is located on the lower sections of an area with very steep cliffs and 50–75° slopes. This cliff, which is the source of rockfalls, has a slope dip of approximately 90°. The cliff comprises 25–30 m high, fractured and cracked basaltic volcanic mass. To determine block size in the study area, scanline survey measurements and block size measurements were performed on blocks that loosened and fell from the cliff face. It was found that block sizes reached 6 m 3 . Rockfall analyses were performed along the selected profiles using the Rockfall V.4.0 software. Kinetic energy, bounce height, horizontal location of rock end-points, and velocity of the rocks along each section were evaluated separately for each profile. This data were used to produce distribution maps for each profile and the settlement was evaluated in terms of rockfall risk. The results indicate that the study area was at risk of future rockfalls and that it would be appropriate to relocate one part of the settlement.

Description: Sensitivity of simulated climate to latitudinal distribution of solar insolation reduction in SRM geoengineering methods Atmospheric Chemistry and Physics Discussions, 13, 25387-25415, 2013 Author(s): A. Modak and G. Bala Solar radiation management (SRM) geoengineering has been proposed as a potential option to counteract climate change. We perform a set of idealized geoengineering simulations to understand the global hydrological implications of varying the latitudinal distribution of solar insolation reduction in SRM methods. We find that for a fixed total mass of sulfate aerosols (12.6 Mt of SO 4 ), relative to a uniform distribution which mitigates changes in global mean temperature, global mean radiative forcing is larger when aerosol concentration is maximum at the poles leading to a warmer global mean climate and consequently an intensified hydrological cycle. Opposite changes are simulated when aerosol concentration is maximized in the tropics. We obtain a range of 1 K in global mean temperature and 3% in precipitation changes by varying the distribution pattern: this range is about 50% of the climate change from a doubling of CO 2 . Hence, our study demonstrates that a range of global mean climate states, determined by the global mean radiative forcing, are possible for a fixed total amount of aerosols but with differing latitudinal distribution, highlighting the need for a careful evaluation of SRM proposals.

Description: Source apportionment of PM 10 in a North-Western Europe regional urban background site (Lens, France) using Positive Matrix Factorization and including primary biogenic emissions Atmospheric Chemistry and Physics Discussions, 13, 25325-25385, 2013 Author(s): A. Waked, O. Favez, L. Y. Alleman, C. Piot, J.-E. Petit, T. Delaunay, E. Verlinden, B. Golly, J.-L. Besombes, J.-L. Jaffrezo, and E. Leoz-Garziandia In this work, the source of ambient particulate matter (PM 10 ) collected over a one year period at an urban background site in Lens (France) were determined and investigated using a~Positive Matrix Factorization receptor model (US EPA PMF v3.0). In addition, a Potential Source Contribution Function (PSCF) was performed by means of the Hysplit v4.9 model to assess prevailing geographical origins of the identified sources. A selective iteration process was followed for the qualification of the more robust and meaningful PMF solution. Components measured and used in the PMF include inorganic and organic species: soluble ionic species, trace elements, elemental carbon (EC), sugars alcohols, sugar anhydride, and organic carbon (OC). The mean PM 10 concentration measured from March 2011 to March 2012 was about 21 μg m −3 with typically OM, nitrate and sulfate contributing to most of the mass and accounting respectively for 5.8, 4.5 and 2.3 μg m −3 on a yearly basis. Accordingly, PMF outputs showed that the main emission sources were (in a decreasing order of contribution): secondary inorganic aerosols (28% of the total PM 10 mass), aged marine emissions (19%), with probably predominant contribution of shipping activities, biomass burning (13%), mineral dust (13%), primary biogenic emissions (9%), fresh sea salts (8%), primary traffic emissions (6%) and heavy oil combustion (4%). Significant temporal variations were observed for most of the identified sources. In particular, biomass burning emissions were negligible in summer but responsible for about 25% of total PM 10 and 50% of total OC at wintertime. Conversely, primary biogenic emissions were found to be negligible in winter but to represent about 20% of total PM 10 and 40% of total OC in summer. The latter result calls for more investigations of primary biogenic aerosols using source apportionment studies, which quite usually disregards this type of sources. This study furthermore underlines the major influence of secondary processes during daily threshold exceedances. Finally, apparent discrepancies that could be generally observed between filter-based studies (such as the present one) and Aerosol Mass Spectrometer-based PMF analyses (organic fractions) are also discussed here.

Description: Wind extraction potential from 4D-Var assimilation of O 3 , N 2 O, and H 2 O using a global shallow water model Atmospheric Chemistry and Physics Discussions, 13, 25291-25323, 2013 Author(s): D. R. Allen, K. W. Hoppel, and D. D. Kuhl The wind extraction due to assimilation of trace gas (tracer) data is examined using a 4D-Var data assimilation system based on the shallow water equations coupled to the tracer continuity equation. The procedure is outlined as follows. First, a Nature Run is created, simulating middle stratospheric winter conditions. Second, ozone (O 3 ), nitrous oxide (N 2 O), and water vapor (H 2 O) (treated in this study as passive tracers) are initialized using Microwave Limb Sounder (MLS) mixing ratios at 850 K potential temperature and advected by the Nature Run winds. Third, the initial dynamical conditions are perturbed by using a 6 h offset. Fourth, observations based on the simulated tracer data are then assimilated with a 4D-Var system in which the tracer and winds are coupled via the adjoint of the tracer continuity equation. Finally, the wind extraction potential (WEP) is calculated as the reduction of the Root Mean Square (RMS) vector wind error due to tracer assimilation relative to the total possible reduction from the initial perturbed conditions. For a single 6 h assimilation cycle of "perfect" tracer (unbiased and no imposed random errors), WEP values are 70% for O 3 , 49% for N 2 O and 16% for H 2 O. O 3 and N 2 O provide more wind information than H 2 O due to stronger background gradients relative to the tracer precisions. 10 day multi-cycle simulations with "perfect" tracer result in WEP of 98% for O 3 , 97% for N 2 O, and 90% for H 2 O. There is therefore sufficient information in these fields to nearly completely specify the dynamics, even without assimilation of dynamical information. For assimilation of tracer observations with realistic random noise (based on MLS precision at 10 hPa), the WEP after 10 days decreases to 57% for O 3 , 42% for N 2 O, and 28% for H 2 O. The root-mean-square (RMS) wind errors level out at ~ 1–2 m s −1 for these runs, suggesting a limit to which realistic tracers could constrain the winds, given complete global coverage. With higher observation noise levels, the WEP values decrease further, with negative WEP occurring in cases of very large errors for H 2 O, indicating that assimilation of very noisy observations may worsen the wind fields.

Description: The crosslinking reaction caused by blending different biopolymers and/or adding a crosslinking agent to biopolymers was studied. The rate of crosslinking reaction was estimated with weight swelling ratio (WSR), viscosity, and biodegradability. The crosslinked material from blending two biopolymers or mixing a crosslinking agent with a mixture of two biopolymers showed a polymeric volume change, a high microbial resistance even after 80 days, and a viscosity increased because of chemical functional groups to form extensive intra- and interpenetrating polymer networks (IPNs). The organized IPN is a base block in building a three-dimensional (3-D) crosslinked biopolymer structure. This 3-D structure can be utilized in the environmental and geotechnical applications such as an environmental barrier or containment to encapsulate and treat hazardous materials against toxic flow in a subsurface engineering system.

Description: For the countries with a developed stone industry the waste generated in the natural stone processing plants pose environmental and economic problems. The utilisation of stone waste in various areas is still under research. In addition, there are only a limited number of studies concerning the use of stone waste obtained from processing plants in the stabilisation of clayey soil. Furthermore, none of the studies in the literature investigated the effect of the characteristics of the stone on the stabilisation of the soil. This is the first study that compares the efficiency of the waste calcitic marble, dolomitic marble and granite powder as additives for the stabilisation of clayey soil. Artificial soil samples were prepared in the laboratory using bentonite and kaolinite. Natural stone waste powder was added to the soil samples at different percentages, and the index and compaction parameters of the stabilised soil were analysed. The results showed that the types of waste powder used in this study, like lime, could be used as stabilisers. As the percentage of additives increased, the plasticity index of the clayey soil decreased and the physical properties of the soil changed from clay to silt. In terms of compaction parameters, the use of all types of natural waste powder in the study resulted in a decrease in the optimum water content and an increase in the maximum dry unit weight. The lowest optimum water content and the highest maximum dry unit weight were obtained from the dolomitic marble powder.

Description: Tuffs have been used as a construction material possibly since ancient times. In Afyonkarahisar, Turkey, there are numerous buildings constructed by tuff. Tuff has been a local construction material, during the Roman, Seljuk and Ottoman periods. Even though tuffs have relatively low durability and low strength values compared to marble, etc., they have survived with no major deterioration failures on many historical buildings. It has also been preferred because of its high porous texture, lightweight and easy shaping and process properties in the building sector. Naturally, it would be easily affected by water and humidity because of its porous structure. However, having this kind of structure leads to poor durability properties due to keeping water in it. The main objective of this study was to evaluate the physical and mechanical properties of the tuff quarried from the region and possible water effect, which may lead to degradation of its strength and durability of the material, thereby shortening the life span of the building structure used. Samples, which were tested after exposing to water and the freeze and thaw effects, were measured at a certain time. In this study, uniaxial compressive strength and flexural strength tests were conducted on test samples. The test results indicate that water may deteriorate the tuff’s strength properties and durability of the materials in due time.

Description: The simulations of sulfuric acid concentration and new particle formation in an urban atmosphere in China Atmospheric Chemistry and Physics Discussions, 13, 14977-15005, 2013 Author(s): Z. B. Wang, M. Hu, D. Mogensen, D. L. Yue, J. Zheng, R. Y. Zhang, Y. Liu, B. Yuan, X. Li, M. Shao, L. Zhou, Z. J. Wu, A. Wiedensohler, and M. Boy Simulations of sulfuric acid concentration and new particle formation are performed by using the zero-dimensional version of the model MALTE (Model to predict new Aerosol formation in the Lower TropospherE) and measurements from the Campaign of Air Quality Research in Beijing and Surrounding areas (CAREBeijing) in 2008. Chemical reactions from the Master Chemical Mechanism Version 3.2 (MCM v3.2) are used in the model. High correlation (slope = 0.72, R = 0.74) between the modelled and observed sulfuric acid concentrations is found during daytime (06:00–18:00). The aerosol dynamics are simulated by the University of Helsinki Multicomponent Aerosol (UHMA) model including several nucleation mechanisms. The results indicate that the model is able to predict the on- and offset of new particle formation in an urban atmosphere in China. In addition, the number concentrations of newly formed particles in kinetic-type nucleation including homogenous homomolecular ( J=K [H 2 SO 4 ] 2 ) and homogenous heteromolecular nucleation involving organic vapours ( J=K het [H 2 SO 4 ][Org]) are in satisfactory agreement with the observations. However, the specific organic compounds possibly participate in the nucleation process should be investigated in further studies.

Description: Based on data measured by eddy covariance (EC) and the Kormann and Meixner model, footprints of the flux of desert shrub ecosystems were analyzed. The contributions of different land types during the growing season in Fukang station in 2007 were estimated. Spatial distributions of footprint source areas were evaluated to reveal the relative flux contribution to the total flux over the entire observation period. The results indicate that: (1) The applied footprint model provides accurate footprint estimates and the flux data can be used for the shrub flux estimations. The flux contribution from shrub land showed that the observed flux data were able to represent seasonal change in the flux of desert shrub ecosystems. The flux contribution rate of shrub was highest during May to July between 10:00 and 18:00 h. (2) The location of the EC system in Fukang is appropriate for monitoring shrub flux. (3) Footprint analysis is necessary because it assesses the contribution of the target land-use type to the total flux for any user-defined period. The flux contribution rate was affected significantly by wind direction and the source region.