ALBERT

Beschreibung / Inhaltsverzeichnis: Geochemistry is a science that is based on an understanding of chemical processes in the earth. One of the principal tools available to the chemist for understanding systems at equilibrium is thermodynamics. The awareness and application of thermodynamic techniques has increased at a very fast pace in geosciences; in fact, one may be so bold as to say that thermodynamics in geology has reached the "mature" stage, although much future thermodynamic research is certainly needed. However, the natural processes in the earth are often sluggish enough that a particular system may not reach equilibrium. This observation is being supported constantly by new experimental and field data available to the geochemist e.g. the non-applicability of the phase rule in some assemblages, the compositional inhomogeneities of mineral grains, the partial reaction rims surrounding original minerals, the lack of isotopic equilibration or the absence of minerals (e.g. dolomite), which should be present according to thermodynamics. The need to apply kinetics has produced a large number of papers dealing with kinetics in geochemistry. As an initial response to this growing field, a conference on geochemical transport and kinetics was conducted at Airlie House, VA, in 1973, sponsored by the Carnegie Institution of Washington. The papers there dealt with several kinetic topics including diffusion, exsolution, metasomatism and metamorphic layering. Since 1973 the number of kinetic papers has continued to increase greatly. Therefore, the time is ripe for a Short Course in Kinetics, which brings together the fundamentals needed to explain field observations using kinetic data. It is hoped that this book may serve, not only as a reference for researchers dealing with the rates of geochemical processes, but also as a text in courses on geochemical kinetics. One of us has found this need of a text in teaching a graduate course on geochemical kinetics at Harvard and at Penn State during the past several years. Finally, it is our hope that the book may itself further even more research into the rates of geochemical processes and into the quantification of geochemical observations. The book is organized with a rough temperature gradient in mind, i.e. low temperature kinetics at the beginning and igneous kinetics at the end (no prejudices are intended with this scheme!). However, the topics in each chapter are general enough that they can be applied often to any geochemical domain: sedimentary, metamorphic or igneous. The theory of kinetics operates at two complementary levels: the phenomenological and the atomistic. The former relies on macroscopic variables (e.g. temperature or concentrations) to describe the rates of reactions or the rates of transport; the latter relates the rates to the basic forces operating between the particular atomic or molecular species of any system. This book deals with both descriptions of the kinetics of geochemical processes. Chapter one sets the framework for the phenomenological theory of reaction rates. If any geochemical reaction is to be described quantitatively, the rate law must be experimentally obtained in a kinetically sound manner and the reaction mechanism must be understood. This applies to heterogeneous fluid-rock reactions such as those occurring during metamorphism, hydrothermal alteration or weathering as well as to homogeneous reactions. Chapter 2 extends the theory to the global kinetics of geochemical cycles. This enables the kinetic concepts of stability and feedback to be applied to the cycling of elements in the many reservoirs of the earth. Chapter 3 applies the phenomenological treatment of chapter 1 to diagenesis and weathering. The rate of dissolution of minerals as well as the chemical evolution of pore waters are discussed. The atomistic basis of rates of reaction, transition state theory, is introduced in Chapter 4. Transition state theory can be applied to relate the rate constants of geochemical reactions to the atomic processes taking place. This includes not only homogeneous reactions but also reactions that occur at the surface of minerals. Chapter 5 discusses the theory of irreversible thermodynamics and its application to petrology. The use of the second law of thermodynamics along with the expressions for the rate of entropy production in a system have been used successfully since 1935 to describe kinetic phenomena. The chapter applies the concepts to the growth of minerals during metamorphism as well as to the formation of differentiated layers (banding) in petrology. Chapter 6 describes the phenomenological theory of diffusion both in aqueous solutions and in minerals. In particular, the multicomponent nature of diffusion and its consequence in natural systems is elaborated. Chapter 7 provides the atomistic basis for the rates of reactions in minerals. Understanding of the rates of diffusion, conduction, order-disorder reactions or exsolution in minerals depends on proper description of the defects in the various mineral structures. Chapter 8 provides the kinetic theory of crystal nucleation and growth. While many of the concepts in the chapter can be applied to aqueous systems, the emphasis is on igneous processes occurring during crystallization of a melt. To fully understand both the mineral composition as well as the texture of igneous rocks, the processes whereby new crystals form and grow must be quantified by using kinetic theory. Due to space and time limitations (kinetics!) some topics have not been covered in detail. In particular, the mathematical solution of diffusion or conduction equations is discussed very well by Crank in his book, Mathematics of Diffusion, and so is not covered to a great extent here. The treatment of fluid flow (e.g. convection) is also not covered in the text.

Beschreibung / Inhaltsverzeichnis: Antarctic Geoscience is the proceedings volume of the Third Symposium on Antarctic Geology and Geophysics, held in Madison, Wisconsin. The 151 chapters in the book, which include both review papers and original contributions, range over all major fields of geoscience. At a time when interest in Antarctica, its geologic history, and its mineral resource potential is increasing, this book provides the most current and comprehensive overview of the subject. These papers, representing the recent work of many scientists from fifteen nations, offer a balanced assessment of current thought and knowledge concerning the geology and geoscience of Antarctica and the surrounding oceanic regions. Together, they constitute the most up-to-date reference work on Antarctic earth sciences. The book is divided into twelce sections: Gondwanaland (11 chapters), Scotia Arc Region (39, East Antarctica Shield (14), Upper Precambrian-Paleozoic Rocks (11), Paleontology (8), Igneous Rocks (14), Structural Geology and Tectonics (9), Mineral Deposits (4), Crustal Structure (13), Subglacial Morphology (4), Marine Geology (8), and Cenozoic History (16). The volume is generously illustrated with photographs and line drawings and includes a large color geologic map of the continent.

Beschreibung / Inhaltsverzeichnis: Climate Since A.D. 1500 presents a unique perspective on the 'Litte Ice Age' and the climate of the twentieth century. Leading scientists explore historical documents, dendroclimatic data and ice core records from all over the world, presenting an invaluable compilation for all those concerned with past climate and the risks of man-made climatic change in the future. This revised edition includes a new chapter summarizing the wealth of literature on climatic change over the past few years and a new and expanded index.

Beschreibung / Inhaltsverzeichnis: Deterministic chaos offers a striking explanation for irregular behaviour and anomalies in systems which do not seem to be inherently stochastic. The most direct link between chaos theory and the real world is the analysis of time series from real systems in terms of nonlinear dynamics. This book provides experimentalists with methods for processing, enhancing, and analysing measured signals using these methods; and for theorists it also demonstrates the practical applicability of mathematical results. The framework of deterministic chaos constitutes a new approach to the analysis of irregular time series. Traditionally, nonperiodic signals have been modelled by linear stochastic processes. But even very simple chaotic dynamical systems can exhibit strongly irregular time evolution without random inputs. Chaos theory offers completely new concepts and algorithms for time series analysis which can lead to a thorough understanding of the signals. The book introduces a broad choice of such concepts and methods, including phase space embeddings, nonlinear prediction and noise reduction, Lyapunov exponents, dimensions and entropies, as well as statistical tests for nonlinearity. Related topics such as chaos control, wavelet analysis, and pattern dynamics are also discussed. Applications range from high-quality, strictly deterministic laboratory data to short, noisy sequences which typically occur in medicine, biology, geophysics, and the social sciences. All the material discussed is illustrated using real experimental data. This book will be of value to any graduate student or researcher who needs to be able to analyse time series data, especially in the fields of physics, chemistry, biology, geophysics, medicine, economics, and the social sciences.

Beschreibung / Inhaltsverzeichnis: PART I PARTICLE SIMULATIONS --- INTRODUCTION TO PARTICLE SIMULATION MODELS AND OTHER APPLICATION TO ELECTROSTATIC PLASMA WAVES / Hideo Okuda / pp. 3-41 --- PARTICLE SIMULATION OF ELECTROMAGNETIC WAVES AND ITS APPLICATION TO SPACE PLASMAS / Hiroshi Matsumoto and Yoshiharu Omura / pp. 43-102 --- RELATIVISTIC CODE APPLIED TO RADIATION GENERATION / A. T. Lin / pp. 103-116 --- MODERN DEVELOPMENT IN PARTICLE SIMULATION / J. C. Adam / pp. 117-130 --- PART II MHD SIMULATIONS --- PRINCIPLES OF MAGNETOHYDRODYNAMIC SIMULATION IN SPACE PLASMAS / Tetsuya Sato / pp. 133-153 --- MHD MODELLING OF THE EARTH'S MAGNETOSPHERE / C. C. Wu / pp. 155-177 --- NUMERICALLY-SIMULATED FORMATION AND PROPAGATION OF INTERPLANETARY SHOCKS / S. T. Wu / pp. 179-201 --- ANOMALOUS TRANSPORT BY KELVIN-HELMHOLTZ INSTABILITIES / Akira Miura / pp. 203-224 --- PART III OTHER-METHOD SIMULATIONS --- PARTICLE BEHAVIOR IN THE MAGNETOSPHERE / R. A. Wolf and R. W. Spiro / pp. 227-254 --- HYBRID SIMULATION TECHNIQUES APPLIED TO THE EARTH'S BOW SHOCK / D. Winske and M. M. Leroy / pp. 255-278 --- VLASOV SIMULATION OF ION ACOUSTIC DOUBLE LAYERS / G. Chanteur / pp. 279-301 --- SIMULATION MODELS FOR SPACE PLASMAS AND BOUNDARY CONDITIONS AS A KEY TO THEIR DESIGN AND ANALYSIS / Christian T. Dum / pp. 303-375

Beschreibung / Inhaltsverzeichnis: Chapter I. Air-Sea Exchange Processes and Flux --- Chemical composition of marine aerosols over the Central North Pacific—Results ftom the 1991 cruise of Hakurei Maru No. 2 / Uematsu, M., Kawamupa, K., Ibusuki, T. and Kimoto, T. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 3-14 --- Estimation of mineral aerosol fluxes to the Pacific by using environmental plutonium as a tracer / Nakanishi, T., Shiba, Y., Muramatsu, M. and Haque, M. A. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 15-30 --- Land-derived lipid class compounds in the deep-sea sediments and marine aerosols from the North Pacific / Kawamura, K. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 31-51 --- Iron and manganese in the atmosphere and oceanic waters / Nakayama, E., Obata, H., Okamura, K., Isshiki, K., Karatani, H. and Kimoto, T. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 53-68 --- Laboratory estimation of CO2 transfer velocity across the air-sea interface / Komom, S., Shimada, T. and Murakami, Y. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 69-81 --- Dissolution of calcareous tests in the ocean and atmospheric carbon dioxide / Nozaki, Y. and Oba, T. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 83-92 --- Calcium carbonate production and carbon dioxide flux on a coral reef, Okinawa / Ohde, S. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 93-98 --- Chapter II. Geochemical Processes in Seawater --- Generations of carbonyl sulfide and hydrogen peroxide in the Seto Inland Sea—Photochemical reactions progressing in the coastal seawater / Fujiwara, K., Takeda, K. and Kumamoto, Y. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 101-127 --- Speciation of organoarsenical compounds in the hydrosphere / Sohrin, Y., Hasegawa, H. and Matsui, M. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 129-138 --- Chemical speciation of selenium in natural waters / Nakaguchi, Y., Koike, Y. and Hiraki, K. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 139-158 --- The concentration distribution and chemical form of arsenic compounds in seawater / Tanaka, S. and Santosa, S. J. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 159-170 --- The rare earth elements and yttrium in the coastal/offshore mixing zone of Tokyo Bay waters and the Kuroshio / Nozaki, Y. and Zhang, J. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 171-184 --- The tetrad effect in seawater; a long dispute and an analytical approach to the confirmation of the effect / Akagi, T. and Masuda, A. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 185-199 --- Detection, characterization and dynamics of dissolved organic ligands in oceanic waters / Tanoue, E. and Midorikawa, T. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 201-224 --- Chapter III. Primary Production and Other Biological Processes --- Nitrate assimilation and new production in open ocean / Kanda, J. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 227-238 --- Primary production and community respiration in the subarctic water of the western North Pacific / Odate, T. and Furuya, K. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 239-253 --- Effects of a seamount on phytoplankton production in the western Pacific Ocean / Furuya, K., Odate, T. and Taguchi, K. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 255-273 --- Marine colloids: Their roles in food webs and biogeochemical fluxes / Nagata, T. and Koike, I. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 275-292 --- Regional and seasonal variations of biomass and bio-mediated materials in the North Pacific Ocean / Yanada, M. and Maita, Y. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 293-306 --- Nitrogen and carbon stable isotopic ecology in the ocean: The transportation of organic materials through the food web / Sugisakj, H. and Tsuda, A. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 307-317 --- The role of carnivorous zooplankton, particularly chaetognaths in ocean flux / Terazaki, M. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 319-330 --- Seasonal changes in deep-sea benthic foraminiferal populations: Results of long-term observations at Sagami Bay, Japan / Kitazato, H. and Ohga, T. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 331-342 --- Chapter IV. Particle Flux and Sediment Geochemistry --- Spatial variation of Al flux in the North Pacific observed with sediment trap / Noriki, S., Iwai, T., Shimamoto, A., Tsunogai, S. and Harada, K. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 345-354 --- Spatial and temporal variation of δ515N in sinking particles in deep waters: Its implication for the origin and transport of particulate organic matter / Nakatsuka, T., Handa, N. and Imaizumi, S. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 355-374 --- 230Th and 231Pa distributions in surface sediments off Enshunada, Japan / Taguchi, K. and Narita, H. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 375-382 --- Remobilization of transition elements in pore water of continental slope sediments / Kato, Y., Tanase, M., Minami, H. and Okabe, S. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 383-405 --- Geochemistry of pore waters from a bathyal Calyptogena community off Hatsushima Island, Sagami Bay, Japan / Masuzawa, T., Nakatsuka, T. and Handa, N. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 407-421 --- Chapter V. Submarine Hydrothermal Processes --- Wide variation of chemical characteristics of submarine hydrothermal fluids due to secondary modification processes after high temperature water-rock interaction: a review / Gamo, T. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 425-451 --- Geochemistry of phase-separated hydrothermal fluids of the North Fiji Basin, Southwest Pacific / Ishibashi, J. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 453-467 --- Chemical modeling of seawater-rock interaction: Effect of rock-type on the fluid chemistry and mineral assemblage / Chiba, H. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 469-486 --- Hydrothermal mineralization in the Mid-Okinawa Trough / Nakashima, K., Sakai, H., Yoshida, H., Chiba, H., Tanaka, Y., Gamo, T., Ishibashi, J. and Tsunogai, U. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 487-508 --- Iron-rich smectite formation in the hydrothermal sediment of Iheya Basin, Okinawa Trough / Masuda, H. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 509-521 --- Formation and alteration of organic compounds in simulated submarine hydrothermal vent environments / Kobayashi, K., Kohara, M., Gamo, T. and Yanagawa, H. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 523-535 --- Localized heat flow anomalies in the middle Okinawa Trough associated with hydrothermal circulation / Kinoshita, M. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 537-559 --- Chapter VI. Modeling and Physical Oceanography --- Material transport models from Tokyo Bay to the Pacific Ocean / Yanagi, T. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 563-574 --- Climate and weather effects on the chlorophyll concentration in the northwestern North Pacific / Sugimoto, T., Tadokoro, K. and Furushima, Y. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 575-592 --- Ecosystem models for the three regional problems in the Northern Pacific / Kishi, M. J. and Kawamiya, M. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 593-611 --- A review on the subtropical mode water of the North Pacific (NPSTMW) / Hanawa, K. and Suga, T. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 613-627 --- Flow distribution at 165°E in the Pacific Ocean / Kawabe, M. and Taira, K. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 629-649 --- Determination of monthly mean sea surface temperature from 1981 to 1990 by the NOAA-AVHRR in the equatorial Pacific / Kishino, M. / Biogeochemical Processes and Ocean Flux in the Western Pacific, / pp. 651-659

Beschreibung / Inhaltsverzeichnis: PREFACE The CERN Accelerator School (CAS) was founded in 1983 with the aim to preserve and disseminate the knowledge accumulated at CERN (European Organization for Nuclear Research) and elsewhere on particle accelerators and storage rings. This is being achieved by means of a biennial programme of basic and advanced courses on general accelerator physics supplemented by specialized and topical courses as well as Workshops. The chapters included in this present volume are taken from one of the specialized courses, Applied Geodesy for Particle Accelerators, held at CERN in April 1986. When construction of the first large accelerators started in the 1950's, it was necessary to use geodetic techniques to ensure precise positioning of the machines' components. Since that time the means employed have constantly evolved in line with technological progress in general, while a number of specific developments - many of them achieved at CERN - have enriched the range of available instruments. These techniques and precision instruments are used for most of the world's accelerators but can also be applied in other areas of industrial geodesy: surveying of civil engineering works and structures, aeronautics, nautical engineering, astronomical radio-interferometers, metrology of large dimensions, studies of deformation, etc. The ever increasing dimensions of new accelerators dictates the use of the best geodetic methods in the search for the greatest precision, such as distance measurements to 10 -7, riqorous evaluation of the local geoid and millimetric exploitation of the Navstar satellites. At the same time, the powerful computer methods now available for solving difficult problems are also applicable at the instrument level where data collection can be automatically checked. Above all, measuring methods and calculations and their results can be integrated into data bases where the collection of technical parameters can be efficiently managed. In order to conserve the logical presentation of the different lectures presented at the CAS school, the chapters presented here have been grouped under four main topics. The first and the fourth deal with spatial and theoretical geodesy, while the second and third are concerned with the work of applied geodesy, especially that carried out at CERN. Readers involved in these subjects will find in the following chapters, if not the complete answer to their problems, at least the beginning of solutions to them.

Beschreibung / Inhaltsverzeichnis: INTRODUCTION The evaporite deposits of the Werra district, especially in the Hattorf mining field, are considered a worldwide unique location for the occurence of numerous basalt dikes and magmatic fluid phases fixed in salt rocks. In spite of the great number of studies dealing with the magmatites in the Werra region, previous investigations have rarely attempted more than a predominantly 'qualitative' description of the basaltic rocks and the effects of volcanism on the evaporites (see Chapter 2). The method of interpreting the mineralogical and chemical composition of the evaporites at the basalt contact is based on previous works (KNIPPING 1984; KNIPPING & HERRMANN 1985). This study should contribute to understanding (i) the mechanism of intrusion of the basaltic rnelts and (ii) the metamorphic processes occurring in the evaporites caused by mobile phases during volcanism. Hence, the following methods were applied: The mineralogical and chemical description of the basaltic rocks with recent nomenclature including the possible differences between individual dikes and between surface- and subsurface-exposed basalts. Seven surface and 48 subsurface exposures at the Hattorf mine of Kali & Salz AG were studied. Application of the most recent knowledge on basalt genesis for interpreting observational and experimental results. Studies on the sulfur and carbon isotope distributions of the native sulfur from several subsurface exposures and the enrichments of gases (predominantly CO2) in the evaporites. Calculation of the spatial and temporal temperature distribution in the evaporite rocks following intrusion of the basaltic melts. For purposes of clarity a few of the terms which will be used frequently here will first be defined: basalt - all of the intrusive rocks studied can be assigned mineralogically and chemically to the basalt family in a broader sense. Thus, the terms basaltic rock or, in short, basalt will be used for these rocks. rock salt - instead of the term salt for halitic rocks the term rock salt is used. Besides, the evaporites are generally designated as host rocks (for the basalt dikes) as well. gases - especially in the German literature the term carbon dioxide or carbonic acid (= Kohlensäure) is frequently used for the gases enclosed in the evaporites of the Werra-Fulda district. ACKERMANN et al (1964) found, in addition to carbon dioxide, considerable amounts of nitrogen and minor amounts of methane. In the following therefore the terms gas mixture or gas will be used. The various basalt dikes found in the Hattorf mining field are described here in terms of their mineralogy and geochemistry for the first time. In doing so it is necessary to number them from east to west. To avoid confusion with older numerations (e.g. SIEMENS 1971) the various dike systems are designated by capital letters (A to P).

Beschreibung / Inhaltsverzeichnis: PREFACE The Lower Triassic Buntsandstein in Middle Europe which originated in mainly continental fluvla] environment in the Mid-European Triassic Basin is a famous terrestrial red bed sequence that is discussed in the geological literature since more than 200 years. Much of the earlier work had been devoted to stratigraphical, palaeogeographical and petrographical problemsof the Buntsandstein. The sedimentological analysis and deposltional modelling in the German-type facies, however, is the youngest branch of Buntsandstein investigation and started only a few decades ago. During the last ten years when I began to concentrate on the interpretation of the genesis of the Buntsandstein, much work has been carried out and has already been documented in numerous papers that focussed on various aspects of sedimentology, particularly on reconstruction of fluvial and aeolian depositional mechanisms, significance of palaeosols, importance of fluvial conglomerates, palaeoecology of the fossils, interdisciplinary sedimentology, diagenesis of heavy minerals and origin of the red colour. A summary of the present knowledge in the western part of the German Basin is given in a compilation of regional articles together with general discussions and comparative contributions and especially with an extensive colour photographic documentation in an earlier book (reference on p. 12). In the last few years when more and more material became available not only from the Buntsandstein s. str. (Lower Triassic Scythian) in the Mid-European Triassic Basin, but also from correlative sequences in adjoining areas and even older or younger series of similar facies and origin, it became more and more evident that a synthesis of the state of the art would be necessary, if not inevitably for outlining the general frame and illustrating the diversification of facies associations in numerous temporal and spatial scales. That is why I decided to edit an international proceedings volume on the Buntsandstein which is to compile contributions from many regions and different stratigraphic units with emphasis on various aspects of fluvia] sedi~ntation, but stressing also the importance of the distribution of associated environments such as aeolian dunes and calcrete palaeosols. In spite of my own enthusiasm for the Buntsandstein continental red bed formation (the Lower Triassic red rocks seem to have a very special flavour for being so attractive for me) and regardless of the expansion of my investigations from my original Eife] area (where I learnt how to assess the facies assoCiations in terms of depositional modelling and where I collected an enormous amount of data that served as a valuable base for the production of various case studies which were published during the last years) to several other regions, it was without any doubt that it would not be possible for me alone to finish such an overregional proceedings book within a reasonable time, but that I had to beg various colleagues for their collaboration by writing papers on the Buntsandstein in their investigated areas for this volume. Although the response to my first and second circulars soon showed that it would not be possible to publish a compilation of articles from almost all the studied regions, formations and aspects within a reasonable time with avoiding too much delay of appearance for early contributors, I am very happy that finally many colleagues provided me with papers from almost all the countries in Europe where Buntsandstein is cropping out at the surface. In spite of the tremendous editorial work which was necessary to polish the English, to improve the contents of text and drawings and to put the sequence of papers into a general stream line, I would like to thank all my colleagues who contributed to this volume for their support of the project and particularly for their understanding of my editorial task, especially in case of my frequently serious intervention into their early manuscripts and illustrations. Looking for a publisher in the early stages of planning the volume, I found immediately support by Dr. W. Engel (Department of Geological Sciences of the Springer- Verlag) who generously offered me to take the book into the newly founded series "Lecture Notes in Earth Sciences". From the beginning of organization, writing and editing, I appreciated very much the close cooperation with Dr. Engel who always had an ear for my problems and gave me the necessary freedom to finish the volume along the lines of my intention. Although the preparation of the camera-ready manuscript leaves nearly all the work and responsibility with the author, I am especially grateful to Dr. Engel for his guarantee of almost immediate publication after receipt of the final manuscript which allowed me to polish and incorporate latest ideas up to the very terminal moment. Writing on a subject like the Buntsandstein which has proven to be considerably diversified in terms of sedimentary processes and depositional mechanisms, it became soon apparent that a full discussion along my original intention would easily end up with several thousands of pages in size and would consume much more than a few years. Having already rePeatedly experienced in the past that during course of incorporation of nearly all the relevant literature, the reference l i s t of the final paper is often longer than the whole first draft of the article after one or two years collection of data and ideas, there was no other way than to decide to keep the bibliography short. In order to restrict the book to an economical frame and not to frighten the readership to death, but especially to avoid drowning of the red line through the volume, many contributions had to be written as summary presentations without detailed discussion of the literature. Speaking particularly for the articles that have been written by myself either alone or together with friends, I can assure that this is by no means the result of proud neglectance of other works, but only the necessity of streamlining of the book, and that much of the detailed discussion of comparative examples from the literature has to be done in subsequent special papers. It is impossible to acRnowledge all the people that helped me to arrive at the present goal. Special merits, however, deserve those who stimulated my interest for the Buntsandstein. I am especially indebted to Prof. Dr. G. Fuchs (Landessammlungen fur Naturkunde, Karlsruhe) who proposed me ten years ago to work on the Eifel Buntsandstein for my M.Sc. Thesis, and who later supervised together with Prof. Dr. W. Dachroth (Department of Geology and Palaeontology, University of Heidelberg) the preparation of my Ph.D. Thesis. The good luck of the former to choose the Eifel for me as a starting region (which later proved to have a key position for approaching the evolution of fluvial sedimentation in many other Buntsandstein areas), and the earlier investigations of the latter (although largely unpublished and even only briefly touched in his contribution to this volume) triggered my love of the Buntsandstein which has reached a preliminary climax with the present book. It is my pleasure to dedicate this volume to my two former supervisors with very many thanks for their support and in honour of their merit to have lighted the fire. It is my sincere wish to acknowledge again all the people who contributed with articles to this volume for their help to prepare this summary of the state of the art of Buntsandstein fluvial sedimento]og~y. I also want to sincerely thank all friends and colleagues who supplied ideas and facts in oral or written form and who guided me in the field during course of my comparative investigations that helped me considerably in proceeding with the interpretation of the Buntsandstein. Thanks are also due to Helmut Mader (my father) and Martha Herrmann (my aunt) for their support. I am further indebted to those who have been involved in the various technical aspects of the preparation of the manuscript from the beginning of word processor typesetting of the text and reprography of the illustrations to the final printing. I do hope that the compilation of articles on fluvial aspects of the Buntsandstein in this book will stimulate the interest of many people in the topic of sedimentological modelling of terrestrial red bed sequences and will internationally highlight the position of the Buntsandstein as an extraordinarily attractive case history of fluvial deposition.

Beschreibung / Inhaltsverzeichnis: Biolaminated deposits, produced by microbial communities, were studied in modern peritidal environments and in the rock record. The term microbial, mat refers to modern, the term stromatolite to ancient analogs. The term biolaminated deposits was used to encompass both microbial mats and stromatolites. Microbial mat environments studied are the Gavish Sabkha, the Solar Lake, both hypersaline back-barrier systems at the Gulf of Aqaba, Sinai Peninsula, and the "Farbstreifen-Sandwatt" (versicolored sandy tidal flats) on Mellum, an island in the estuary embayment of the southern North Sea coast. Three facies-relevant categories were distinguished: (i) the mat-forming microbiota, (2) environmental conditions controlling mat types and lithology, (3) bioturbation and grazing. Cyanobacteria account for biogenic sediment accretion in all cases studied. Three major groups occur: filamentous cyanobacteria, coccoid unicells with binary fission and those with multiple fission. In the presence of these groups the following mat types evolve: (i) continuously flat (stratiform) L~-laminae (occur in all environments studied); (2) translucent, vertically extended Lv-laminae (only Gavish Sabkha and Solar Lake); (3) nodular granules (only Gavish Sabkha). Basically, the development of mats is controlled by moisture. Thus high-lying parts where the groundwater table runs more than 40 cm below surface are bare of mats. These are: The circular slope and elevated center of the Gavish Sabkha, the shorelines of the Solar Lake and the episodically flooded upper supratidal zone of Mellum Island. The following situations of water supply were found to stimulate mat growth: (i) Capillary movement of groundwater to exposed surfaces, (2) shallowest calm water, both realized in the Gavish Sabkha and the Solar Lake. On Mellum Island, mats form in the lower supratidal zone, which is flooded in the spring tide cycle and wetted during low tide by capillary groundwater. Salinity is almost that of normal seawater, whereas in the Solar Lake, it ranges from 45 °/oo to 180 °/oo and in the Gavish Sabkha, it reaches more than 300 °/oo. Salinity increase is correlated with rising concentrations of magnesium and sulfate ions. In the Gavish Sabkha, episodic sheetfloods cause high-rate sedimentation which is accidental to the living mats. Episodic low-rate sedimentation stimulates the mats to grow through the freshly deposited sediment layer. This occurs predominantly on Mellum Island due to eolian transport. Within the Gavish Sabkha, mineralogy of sediments, community structures, standing crops, redox potentials and pH are highly correlative to the increasing evenness in moisture supply which is realized by the inclination of the system below mean sea level. These conditions bring about a lateral sequence of facies types which include (I) siliciclastic biolaminites at the coastal bar base, (2) nodular to biolaminoid carbonates at saline mud flats, (3) regularly stratified stromatolitic carbonates with ooids and oncoids within the hypersaline lagoon, (4) biolaminated sulfate towardthe elevated center. High-magnesium calcite in facies type 3 precipitates around decaying organic matter and forms also the ooids and oncoids. These occur predominantly within hydroplastic Lv-laminae which provide numerous nucleation centers. Within the Solar Lake, facies type 3 (stromatolitic carbonates with ooids and oncoids) is most important, and grows to extraordinary thickness at the lake's shelf. The regular alternation of dark and light laminae results from seasonally oscillating water depths. These conditions couple back over changing light and salinity intensities to changing dominance structures of mat-building communities. Increasing salinity correlates with decreasing water depth and accounts for the relative abundance of coccoid unicells and diatoms, both active producers of extracellular slimes (Lv-laminae). Water depths locally or temporarily increased favor surface colonization by Mic~ocoleu8 chthonoplastes (Lh-laminae). The biolaminated deposits of the versicolored tidal flats on Mellum Island are similar to facies type 1 of the Gavish Sabkha (siliciclastic biolaminites). Differences exist in the lithology: Sediments upon or through which the mats on Mellum Island grow are made up of clean sand. The grains originate predominantly from re-worked glacial sediments and are rounded to well rounded. By contrast, the strong angularity of siliciclastic grains in the Gavish Sabkha clearly shows their status as primary weathering products. In all environments studied, insects play a significant role. Mainly salt beetles contribute to the lebensspuren spectrum. There is no indication that burrowing and grazing beetles and dipterans are detrimental to the growing mat systems. According to the marine fauna, two distributional barriers exist: (i) physical and (2) biogeochemical factors. Physical barriers are (a) hypersalinity and barrier-closing, which restrict the marine fauna in the Gavish Sabkha and the Solar Lake to a few species, mainly meiofaunal elements such as ostracods and copepods. Only in the Gavish Sabkha, one marine gastropod species occurs which colonizes mud flats of lower salinity. A salinity barrier of about 70 °/oo separates the gastropod habitats from the zones of growing mats. Under reduced salinity, the snails are able to destroy the microbial mats completely. (b) Decreasing regularity of flooding in the microbial mat environment of Mellum Island excludes intertidal deformative burrowers such as cockles and lugworms. However, locally the mats are pierced by numerous dwelling traces. These stem from small polychaetes and amphipod crustaceans which are able to spread over the intertidal-supratidal boundary and settle up to the MHWS-Ievel. Biogeochemical barriers are oxygen depletion within the sediments, high ammonia and sulfide contents, which generate through bacterial break-down of organic matter. Within the highly productive mats of Mic~ocoleu8 chthonoplastes on Mellum Island, dwelling traces of marine polychaetes and amphipod crustaceans disappear due to these conditions. The name of the mat-forming species, Microcoleus chthonoplastes, indicates its capacity to form "soils" (Greek chthonos). While lithology is not altered, the presence of Mic~ocoleu8 mats leads to a habitat change which excludes trace-making "arenophile" invertebrate species and favors "chthonophile" species which do not leave traces. Stromatolitic microstructures studied in rock specimens were interpreted using modern analogs: Microcolumnar buildups in Precambrian stromatolites, ooids and oncoids were compared with those of modern microbial mats. The nodular to biolaminoid facies type found in the Gavish Sabkha was suggested to be an analog to the Plattendolomite facies of Permian Zechstein, North Poland. Studies of the Lower Jurassic ironstone of Lorraine clearly indicate that fungi have been involved in the formation of stromatolites, ooids and oncoids. In conclusion, the comparative study of microstructures in microbial mats and stromatolites reveals a better understanding in both fields. In many cases, it was geology which first revealed the similarity of recent forms to those ancient ones and consequently encouraged research into them.

Beschreibung / Inhaltsverzeichnis: INTRODUCTION Sediments are increasingly recognized as both a carrier and a possible source of contaminants in aquatic systems, and these materials may also affect groundwater quality and agricultural products when disposed on land. Contaminants are not necessarily fixed permanently by the sediment, but may be recycled via biological and chemical agents both within the sedimentary compartment and the water column. Bioaccumulation and food chain transfer may be strongly affected by sediment-associated proportions of pollutants. Benthic organisms, in particular, have direct contact with sediment, and the contaminant level in the sediment may have greater impact on their survival than do aqueous concentrations. Following the findings of positive correlations between liver lesions in English Sole and concentrations of certain aromatic hydrocarbons in Puget Sound (Washington) sediment, it can be suspected that such substrates may also be responsible for a host of other serious and presently unrecognized changes at both the organismal and ecosystem levels (Malins et al., 1984). Modern research on particle-bound contaminants probably originated with the idea that sediments reflect the biological, chemical and physical conditions in a water body (Züllig, 1956). Based on this concept the historical evolution of limnological parameters could be traced back from the study of vertical sediment profiles. In fact, already early in this century Nipkow (1920) suggested that the alternative sequence of layers in a sediment core from Lake Zürich might be related to variations in the trophic status of the lake system. During the following decades of limnological research on eutrophication problems sediment aspects were playing only a marginal role, until it was recognized that recycling from bottom deposits can be a significant factor in the nutrient budget of an aquatic system. Similarly, in the next global environmental issue, the acidification of inland waters sediment-related research only became gradually involved. Here too, it is now accepted that particle-interactions can affect aquatic ecosystems, e.g. by enhancing the mobility of toxic metals. In contrast to the eutrophication and acidification problems, research on toxic chemicals has included sediments aspects from its beginning: Artificial radionuclides in the Columbia and Clinch Rivers in the early sixties (Sayre et al., 1963); in the late sixties heavy metals in the Rhine River system (De Groot, 1966) and methyl mercury (Jensen & Jerne- 16v, 1967) at Minamata Bay in Japan, in Swedish lakes, in Alpine Lakes, Laurentian Great Lakes and in the Wabigoon River system in Canada; organochlorine insecticides and PCBs in Lakes St. Clair and Erie during the seventies (Frank et al., 1977); chlorobenzenes and TCDDs in the Niagara River system and Lake Ontario in the early eighties (Oliver & Nicol, 1982; Smith et al., 1983). In the present lecture notes, following the description of priority pollutants related to sedimentary phases (Chapter 2), four aspects will be covered, which in an overlapping succession also reflect the development of knowledge in particle-associated pollutants during the past twenty-five years: - the identification, surveillance, monitoring and control of sources and distribution of pollutants (Chapter 3); - the evaluation of solid/solution relations of contaminants in surface waters (Chapter 4); - the study of in-situ processes and mechanisms in pollutant transfer in various compartments of the aquatic ecosystems (Chapter 5);- The assessment of the envlroD-mental impact of particle-bound contaminants, i.e. the development of sediment quality criteria (Chapter 6). A final chapter will focus on practical aspects with contaminated sediments. Available technologies will be described as well as future perspectives for the management of dredged materials. Here too, validity of remedial measures can only be assessed by integrated, multidisciplinary research. In the view of the growing information on the present subject and owing to the limitations in the framework of this monography, the reader is referred to additional selected bibliography, which is attached at the end of this Chapter i. Additional information on the more recent publications on contaminated sediments is given in the annual review volume of the Journal of the Water Pollution Control Federation, June edition.

Beschreibung / Inhaltsverzeichnis: PREFACE It is increasingly necessary to develop industrial and hydraulic engineering constructions under unfavourable geological or geotechnical conditions. Furthermore, it becomes more and more important to build effectively and economically and to find optimal solutions for a long-term steady function of the constructions. This emphatically demands exhaustive information on the structural situations and engineering parameters of local site assessments by areal investigations of the sites and the petrophysical parameters in situ. This requires, however, the use of geophysical techniques. During the last two or three decades international applied geophysics has systematically developed new possibilities for site investigations for the determination of petrophysical parameters in situ as well as for observation of the system building and site. As in "New techniques in engineering", geophysical methods make it possible to develop areal models of subsurface conditions of building sites, to quantify relevant engineering parameters in situ, as well as to analyze the longterm behaviour of the buildings, which are influenced by internal or external factors. With regard to the broad spectrum of applied geophysics, there are few methods, that especially favour application in engineering and groundwater studies. These methods are distinguished by a relatively simple measuring technique and good measuring progress, e.g. the geoelectrical self-potential method, the geoelectrical resistivity method as well as a newly developed devices for geothermic measurements. There exist numerous publications, broadly scattered in the technical literature, concerning the theoretical bases and applications of these methods, but until now, there have been only a few meetings to exchange experience and results on an international level. This was the aim of the symposium "Detection of Subsurface Flow Phenomena by Self-Potential/Geoelectrical and Thermometric Methods", held in Karlsruhe from 14-18 March 1988. An outstanding part of the symposioum was represented by the results of a research project, coordinated by the University of Karlsruhe (Department of Geology and Institute of Soil and Rock Mechanics) and the Federal Waterway Engineering and Research Institute (BAW), Karlsruhe. Regarding the subject "Experiments to ascertain the relations between hydraulic potentials in the underground and the geoelectrical and thermic potentials set off by these", the research work took four years. The project was sponsered by the Volkswagen Foundation/Hannover. The goal was to develop and test objective techniques for detecting leakages in dams, locating, demarcating and designating quantitatively inhomogeneous spheres in dams with the aim of detecting damage and subsurface flow phenomena as soon as possible. The symposium consisted of a three-day lecture meeting with about 40 papers and a summarizing respectively closing roundtable discussion, a visit to the laboratories and to the in situ constructions within the area of BAW developed in the frame of the research project. This included a technical excursion to the Rhine-Staustufe Iffezheim with its very impressive waterway constructions and an excursion to the Geophysical Observatory near Schiltach (Black Forest). The Observatory belongs to the Universities of Karlsruhe and Stuttgart. Approximately 80 scientists from 15 countries participated the symposium. They were welcomed by the Rector of the University, Professor Dr. A. Kunle and the representative of the Federal Ministry of Traffic, Dr. G. Schröder. Professor Dr. H. Hötzl elucidated the scientific problems and the economical importance of the project as a speaker of the research group. The following papers dealt with the fundamental aspects of geoelectrical and thermometric measurements, with the theory of these methods, the state and developing ter~dencies concerning devices, data acquisition, processing and interpretation as well as noise effects. It became clear that the solution of the complex scientific-technical problems of waterway constructions and environmental protection requires broad, interdisciplinary cooperation and international collaboration. Thus it would be possible to minimize the personnel, temporal and economic efforts. The intended cooperation of geoscientists, engineering geologists, building engineers and representatives of other disciplines make it possible, not only to exchange experiences and results relating to international problems unsolved until now, but also to determine new guidelines with regard to the scientific organization of further investigations. Thus in order to inform all interested parties of the main topics of the symposium and to advance international cooperation in the future, the present review includes a part of the papers and reports of the excursions recommended by the participants of the meeting, which have been divided into the following topics: - Introduction to engineering-geophysical problems and attempts at their solution; - Geoelectrical self-potential measurements; - Geoelectrical resistivity measurements; - Geothermic measurements; - Case histories; - Some topics of the roundtable discussion; - Reports concerning the excursions. The editors wish to thank very much all those, who contributed to the success of the symposium and to the publication of the present report. Finally they venture the note, that the authors theirselves are responsible for the content of their papers.

Beschreibung / Inhaltsverzeichnis: The study of calcareous bedding rhythms has become an important field in Geology. Often these bedding rhythms are simply interpreted as representations of primary climatic cycles without showing the effects of any appreciable diagenetic overprinting. This study, however, deals predominantly with the diagenetic processes which are usually large and affect both the amplitude and rhythm of carbonate oscillations. The purpose of this textbook is two fold. First, it intends to provide a better understanding of the processes of diagenetic bedding. Secondly, this new approach allows one to quantify and to understand diagenesis in terms of mass exchanges. This is possible through the development of methods which combine chemical data with compaction measurements. These methods can be also used independent of the marl-limestone alternation problem.

Beschreibung / Inhaltsverzeichnis: PREFACE The aim of this volume is two-fold. At the more pragmatic level, it is to help answer the many questions about the structure of the Pacific continental margin of North America, which have arisen over the years as a result of continuing field mapping and geophysical surveys. The second objective is methodological - to illustrate the irreplaceable role of geological information among the various data sets used in earth-science studies. The need to address these issues became apparent to the author during the several years he spent taking part in geological and geophysical studies on the west coast of Canada. All too often, results of geologic field mapping disagreed with tectonic predictions from too-straightforward local applications of global plate reconstructions, which due to their generality do not always take a full account of specific character of particular regions. To be sure, the global approach has during the last q~/artercentury greatly expanded the vision of geoscientists, previously restricted to continental regions. However, a negative by-product of this expansion has been a decline of attention paid to local information, as tectonic studies have increasingly relied on simply fitting the development of a particular region into this or that prefabricated tectonic template. Direct geological observations have limitations of their own. The observer in most cases deals with products of geologic processes, rather than with the processes themselves. Field mapping provides local information, and many years of effort are needed before a regional overview becomes possible. Geologic mapping is restricted to the ground surface, and even the deepest drillholes cannot sample more than the outermost shell of the Earth. The factual side of geologic mapping is usually limited to determination of rock types and their relationships in areas of exposure. Conclusions about the three-dimensional structure of a region and its evolution are still mostly inferential. Broad incorporation into geological studies of geophysical data, assisted by ever-more-sophisticated modern computers, provides a huge volume of information unobtainable in other ways. Geophysical methods quickly afford regional coverage or images of the Earth's deep interior. Geophysical methods have prompted the application in geological sciences of methodologies borrowed from exact sciences, such as mathematics and physics. Particularly important has been quantitative modeling, which allows a scientist to use the known parameters of a system to predict others. But in taking this approach too far, one encounters a dangerous pitfall. A model is a simplified representation of a natural phenomenon. The quality of this or that representation is relative, and a representation is never perfect. To incorporate all characteristics of a geologic phenomenon, in a parametrized form, into a numerical or physical imitation is impossible. This requires one to rely on simplifying assumptions, and a model is no better than the assumptions at its base. Unrealistic assumptions lead to unrealistic models. When a disagreement arises between model predictions and observations - such as those from geologic field mapping - a modeler may be tempted to downplay the differences or the significance of the offending observations. It becomes tempting to underestimate the role of an experienced geologist as a principal arbiter of the realism of a model. But it is geological data and geological control that provide the ultimate means of testing abstract models. From this methodological position, the present study of the western North American continental margin is organized as follows: 1. Geological information, available from field mapping and drilling, is gathered and summarized. 2. Current geophysical models for this region are considered, with particular attention to their underlying assumptions. 3. The available data, geological and geophysical, are synthesized into an internally consistent geologic-evolution concept. 4. This concept is tested by comparison with direct geological observations from field mapping and drilling. Because most current data sets and models cover northwestern Washington and western British Columbia, particular attention was paid to these areas. Fortunately, these areas contain many keys that help understand the structure of the entire western North American continental margin, which has baffled scientists for decades. The author does not claim to have resolved all these problems, but he does believe he has made a useful contribution to understanding continental-oceanic plate interrelations at this continental margin. Rigidity of lithospheric plates is a critical assumption in current models of plate evolution. The lithophere of a plate is created at spreading centers manifested in the global system of mid-ocean ridges. It moves away from the place of its birth towards boundaries with other plates, with which it can interact in a variety of ways. Some interactions are of strike-slip type, with two plates simply sliding past each other. However, to compensate for the creation of new lithosphere at spreading centers, older lithosphere at some plate boundaries descends into the mantle as it is overriden by other plates. At such plate boundaries lie subduction zones. If both regimes occur along a single plate boundary, the transition between them must be abrupt. Unless it can be tied to a change in orientation of the boundary, it must be associated with a junction of not two, but three different plates. Such a template was used to interpret the structure and tectonic evolution of the western North American continental margin in the late 1960s and thereafter (Atwater, 1970; McManus et al., 1972; Barr and Chase, 1974; Riddihough and Hyndman, 1976). To satisfy the principles of rigid-plate tectonics, both regimes have to exist along this continental margin. Also needed in rigid-plate reconstructions is a plate triple junction somewhere between the areas of proven ongoing subduction (in Oregon and southern Washington) and transform plate motion (along the southeastern Alaska margin; Atwater, 1970; McManus et al., 1972). Such a triple junction has been placed off Queen Charlotte Sound offshore British Columbia (Keen and Hyndman, 1979; Riddihough et al., 1983), where a spreading center has been postulated between the Pacific and Explorer oceanic plates (Hyndman et al. 1979; Riddihough, 1984). Off northern Vancouver Island, a transform boundary between the Explorer and Juan de Fuca oceanic plates has been postulated, but both these plates are assumed to be subducting beneath Vancouver Island (Hyndman et al., 1979; Riddihough and Hyndman, 1989)o With the assumed universality of the rigid-plate model, "broad similarity" has been suggested between the geology of western Oregon and that of western British Columbia, and the Cascadia zone of active subduction has been extended as far north as the mouth of Queen Charlotte Sound (Riddihough, 1979, 1984). An accretionary sedimentary prism (Yorath, 1980) - or even an accretionary complex containing several exotic "terranes" (Davis and Hyndman, 1989) - has been postulated off Vancouver Island. Geological observations onshore and offshore (Shouldice, 1971; Tiffin et al., 1972) have come to be considered too "surficial" to be of major consequence for large-scale tectonic modeling (Yorath et al., 1985a,b; Yorath, 1987). Variants of the principal geophysical model for this area during the last decade (Clowes et al., 1987; Hyndman et alo, 1990; Spence et al. 1991; Yuan et al., 1992; Dehler and Clowes, 1992) have become increasingly distant from geological observations. As new model variants emerged, they were checked for internal consistency, compatibility with neighboring local models and fidelity to the overall assumed tectonic picture. However, detailed geological work continued, and many of its results proved incompatible with the conventional wisdom (Gehrels, 1990; Babcock et al., 1992, 1994; Allan et al., 1993; Lyatsky, 1993a). Importantly, questions arose about the applicability in this region of the conventional, simple rigid-plate assumption, as it was shown to be unable to account for all the geological and geophysical peculiarities in some areas (Carbotte et al., 1989; Allan et al., 1993; Davis and Currie, 1993). New solutions were made necessary by new findings and by rediscovery of forgotten old data (see Lyatsky et al., 1991; Lyatsky, 1993b). Without aiming to resolve all the outstanding debates, tectonic implications of the geologic mapping and drilling results in this region are considered in the following chapters. These results are integrated with geochemical and geophysical data. Interpretations of these data, made by this author and by other workers, are verified by geological observations and by geologically plausible extrapolations from these observations. In searching for solutions consistent with all the information, the author has restricted himself to analyzing continental-crust structures along this continental margin. He believes, however, that future models for the offshore regions of the northeastern Pacific should consider the results obtained herein.

Beschreibung / Inhaltsverzeichnis: INTRODUCTION Evaporites may form in a spectrum of environments from continental sabkha (playa) to deep basins (see Kendall 1978 a, b, Schreiber 1978, 1986, Friedman and Krumbein 1985, for review). In the last two decades, many ancient evaporite basins have been interpreted using the sabkha model and the deep desiccated basin model, the former not excluding the latter. However, growing evidence has been gathered indicating that most evaporites are formed in subaqueous environments, so that it cannot be reasonably expected that one depositional model alone will explain the entire basin fill. The chapters in this volume discuss characteristic examples of evaporite basins, mostly of moderate size. Aspects of a saline giant, the Zechstein basin of Central and NW Europe, have been considered in Volume 10 of "Lecture Notes in Earth Sciences"...

Beschreibung / Inhaltsverzeichnis: PREFACE During the so-called Mid-Cretaceous interval, approximately 100 million years ago, the earth experienced a dynamic phase in its geologic history. Enhanced global tectonic activity resulted in a major rearrangment of the continental plates; accelerated spreading rates induced a first-order sea level highstand; intense off-ridge volcanism contributed to a modeled high atmospheric CO 2 rate; climatic conditions fluctuated; and major changes occurred in biologic evolutionary patterns. With the initiation of a gradual change from an equatorial, east-west directed current-circulation pattern to a regime, dominated by south-north and north-south directed current systems, the earth's internal clock was set for Cenozoic, "modern" times. The Mid-Cretaceous dynamic phase is recorded in a suite of sediments of remarkable similarity around the globe. Shallow-water carbonate platforms drowned on a global scale; widespread sediment-starved, glauconite and phosphate- rich sequences developed; and consequently, pelagic sedimentary regimes "invaded" shelf and epicontinental sea areas. This typical "deepening-upward" pattern is well-documented in Mid-Cretaceous sequences along the northern Tethys margin. Shallow-water carbonates are overlain by condensed glauconitic and phosphatic sediments, which, in turn, are blanketed by pelagic carbonates. In this volume, the example of the western Austrian helvetic Alps, built up of inner and outer shelf sediments deposited along the northern Tethys margin, is used to elucidate the paleoceanographic conditions, under which the Mid-Cretaceous triad of platform carbonates, condensed phosphatic and glauconitic sediments, and pelagic carbonates was formed. In the first part, the evolution of this sequence is traced from the demise of the platform (Aptian) to the return of detritus-dominated deposition (Upper Santonian). The second part includes a discussion of the reconstructed paleoceanographic and tectonic variables, their possible interaction, as well as their influence on sediment properties during this period. Special attention is paid to (1) subsidence behavior of the inner, platform-based shelf and the outer shelf beyond the platform, (2) ammonoid paleobiogeography, (3) the northern tethyan current system and its impact on sediment patterns, (4) the influence of an oxygen minimum zone, (5) sediment bypassing mechanisms on the inner shelf, (6) condensation processes, (7) phosphogenesis, (8) relative sea level changes, (9) genesis and the development of unconformities, (10) tectonic phases and their impact on sediment configuration, (11) drowning of the shallow-water carbonate platform, and (12) "asymmetric" sedimentary cycles. The detailed reconstruction of the development of sedimentary patterns both in time and space in this particular area, and its environmental interpretation, given in this volume, may serve as a contribution to a better understanding of the Mid-Cretaceous dynamic phase in earth's history...

Beschreibung / Inhaltsverzeichnis: The subject of the book is an indepth description of the theory and mathematical models behind the application of the Global Positioning System in geodesy and geodynamics. The text has been prepared by leading experts in the field, contributing their particular points of view. Unlike a collection of disjoint papers, the text provides a continous flow of ideas and developments. The mathematical models for GPS measurements are developed in the first half of the book, followed by the description of GPS solutions for geodetic applications on local, regional and global scales.

Beschreibung / Inhaltsverzeichnis: This volume contains the contributions which have been presented at the 5. ALFRED WEGENER-Conference , held in Göttingen, Federal Republic of Germany, 21 - 24 May 1986. This conference was the first international meeting of the IGCP Project 216 :"global biological events in earth history". The aim of the conference was, to discuss (a) the state-of-the-art in respect to the recognition of bio-events and to the analysis of their causes (b) the presentation of new data (c) the strategies which are needed for further research, carried out in the international cooperation programme of Project 216. It was intended to achieve with these discussions a more critical approach to the problems of global bio-events.

Beschreibung / Inhaltsverzeichnis: OPENING ADDRESS On behalf of the Local Organizing Committee, I welcome you all to the first International Workshop on GPS-techniques in surveying and geodesy held at this university. This workshop is designed to bring together experts from various countries and also scientists who carry out, analyze and interpret such measurements with those who work on instrumental and theoretical problems. The workshop focuses hereby on high-precision applications with emphasis on monitoring time-dependent phenomena such as those relevant to geodynamics as well as men-made constructions as those in civil engineering and similar fields. It is astonishing to see how, in spite of all earlier satellite work over the last two decades, GPS-methods became so fast a relevant new technology, in its proper sense, in modern geodesy and surveying besides VLBI and Satellite Laser Ranging (SLR). With the recent development of new dual-frequency receivers the role of GPS-procedures in monitoring large-scale phenomena over big distances will still expand; and the application of kinematical GPS-approaches is of utmost interest in solving high-precision problems. It is indeed fascinating to realize how GPS-methods have become in such a short time a surprisingly efficient and effective, this means : fast, precise and easy to apply, tool which is able to replace already now, after a few years of existence and with an incomplete set of a few out of the 18 satellites (of the final stage), at least partially some expensive, slow and cumbersome classical surveying methods. On the other hand, it cannot be overemphasized that GPS-procedures are still at their beginning and the full spectrum of their capabilities still has to be explored. In Europe, for example, where excellent classical surveying systems do exist the situation is quite different from the situation in other countries such as Canada or the USA. Even within Europe the application types of GPS-methods will vary; for example, in Norway the situation is quite different from central European countries. It is often forgotten, that together with GPS we will have to introduce new concepts and a new thinking in combination with other modern satellite procedures. GPS itself can resolve only a small part of the problems to be solved by modern geodesy but it will open the way to a great variety of new applications and capabilities. Modern global tectonics is just one of the new disciplines of high interest and great practical impact. I could continue in citing other similarly important new fields. GPS is, however, of special importance because it replaces old technologies and fills gaps where modern and efficient tools are most needed. Consequently, also the optimal combination of GPS-methods with new auxiliary and also classical high-precision techniques is of great importance, mainly under the european conditions outlined above. Moreover, the real-time or almost-real-time use of GPS in combination with photogrammetry, inertial geodesy, gravity gradiometry or even classical surveying is of substantial interest. It is indeed important to realize the new concepts in modern satellite and space methods and I, therefore, spoke above of a new "technology" which should be optimally developed as there is a worldwide need of such capabilities and tools. In view of the few active NAVSTAR-satellites in sky in 1988 this is perhaps not the best year for GPS-applications but the right time for a review of the experience gained until now and using it as a base for the planning of the future...

Beschreibung / Inhaltsverzeichnis: PREFACE The objective of this book is to introduce the practitioner as well as the more theoretically interested reader into the integration problem of spatial information for Geo-lnformation Syslems. Former Get-Information Systems are restricted to 2D space. They realize the integration of spatial information by a conversion of vector and raster representations. This, however. leads to conceptual difficulties because of the two totally different paradigms. Furthermore, the internal topology of the get-objects is not considered. In recent years the processing of 3D information has played a growing role in Get-Information Systems. For example, planning processes for environmental protection or city planning are dependent on 3D data. The integration of spatial reformation will become even more impoaant in the 3D context and with the development of a new generation of open GISs. This book is intended to respond to some of these requirements. It presents a model for the integration of spatial information for 3D Geo-lnformation Systems (3D-GISs). As a precondition for the integration of spatial information, the integration of different spatial representations is emphasized. The model is based on a three-level notion of space that likewise includes the geometry, metrics and the topology of get-objects. The so called extended complex (e-complex) is introduced as a kernel of the model. Its internal basic geometries are the point, the line, the triangle and the tetrahedron. It is shown how a convex e-complex (ce-complex) is generated by the construction of the convex hull and the "'filling" of lines, triangles and tetrahedra, respectively. As we know from computer geometry, this results in substantially simpler geometric algorithms. Additionally, the algorithms gain by the explicit utilization of the topology of the ce-complex. This book also builds a bridge from the GIS to the object-oriented database technology, which will likely become a key technology for the development of a new generation of open Geo-lnformation Systems. In the so-called GEtmodel kernel "building blocks" are introduced that s~mplify the development of software architectures for geo-applications. A geological application in the Lower Rhine Basin shows the practical use of the introduced geometric and topological representation for a 3D-GIS...

Beschreibung / Inhaltsverzeichnis: INTRODUCTION The awareness that mankind is able to influence and modify not only the local but also the global climate has led to a strongly growing interest in climate research. Strengthened research activities, which also made use of improved and novel experimental techniques, have yielded a wealth of information on climatic patterns in the past. At the same time, climate modelling has made much progress. While some questions have been answered, new problems have been recognized. One question related to anthropogenio climatic change is about the nature and causes of natural variations, against the background of which man-made changes must be viewed. The contributions to this volume all deal with the variabilitY of climate. Some papers are reviews of the knowledge to a current topic, others have more the character of an original contribution. The obseryational studies cover the range from year-to-year variations up to glacial-interglacial contrast, thereby going from instrumental data to results from proxy records...

Beschreibung / Inhaltsverzeichnis: PREFACE Through the last few decades inversion concepts have become an integral past of experimental data interpretation in several branches of science. In numerous cases similar inversion-like techniques were developed independently in separate disciplines, sometimes based on different lines of reasoning, and sometimes not to the same level of sophistication. This fact was realized early in inversion history. In the seventies and eighties "generalized inversion" and "total inversion" became buzz words in Earth Science, and some even saw inversion as the panacea that would eventually raise all experimental science into a common optimal frame. It is true that a broad awareness of the generality of inversion methods is established by now. On the other hand, the volume of experimental data varies greatly among disciplines, as does the degree of nonlinearity and numerical load of forward calculations, the amount and accuracy of a priori information, and the criticality of correct error propagation analysis. Thus, some clear differences in terminology, philosophy and numerical implementation remain, some of them for good reasons, but some of them simply due to tradition and lack of interdisciplinary communication. In a sense the development of inversion methods could be viewed as an evolution process where it is important that "species" can arise and adapt through isolation, but where it is equally important that they compete and mate afterwards through interdisciplinary exchange of ideas. This book was actually initiated as a proceedings volume of the "Interdisciplinary Inversion Conference 1995", held at the University of Aarhus, Denmark. The aim of this conference was to further the competition and mating part of above-mentioned evolution process, and we decided to extend the effect through this publication of 35 selected contributions. The point of departure is a story about geophysics and astronomy, in which the classical methods of Backus and Gilbert from around 1970 have been picked up by helioseismology. Professor Douglas Gough, who is a pioneer in this field, is the right person to tell this success story of interdisciplinary exchange of research experience and techniques [1-31] (numbers refer to pages in this book). Practitioners of helioseismology like to stress the fact that the seismological coverage on the Sun in a sense is much more complete and accurate than it is on Earth. Indeed we witness vigorous developments in the Backus & Gilbert methods (termed MOLA/SOLA in the helioseismology literature) [32-59] driven by this fortunate data situation. Time may have come for geophysicists to look into helioseismology for new ideas. Seismic methods play a key role in the study of the Earth's lithosphere. The contributions in [79 - 130,139 - 150] relate to reflection seismic oil exploration, while methods for exploration of the whole crust and the underlying mantle axe presented in [131 - 138, 151 - 166]. Two contributions [167 - 185] present the application of inversion for the understanding of the origin of petroleum and the prediction of its migration in sedimentary basins. Inversion is applied to hydrogeophysical and environmental problems [186 - 222], where again developments are driven by the advent of new, mainly electromagnetic, experimental techniques. The role of inversion in electromagnetic investigations of the lithosphere/astenosphere system as well as the ionosphere axe exemplified in [223 - 238]. Geodesy has a fine tradition of sophisticated linear inversion of large, accurate sets of potential field data. This leads naturally to the fundamental study of continuous versus discrete inverse formulations found in [262-275]. Applications of inversion to geodetic satellite data are found in [239 - 261]. General mathematical and computational aspects are mainly found in [262 - 336]. Nonlinearity in weakly nonlinear problems may be coped with by careful modification of lineaxized methods [295 - 302]. Strongly nonlinear problems call for Monte Carlo methods, where the cooling scedule in simulated annealing [303 - 311,139 - 150] is critical for convergence to a useful (local) minimum, and the set of consistent models is explored through importance sampling [89 - 90]. The use of prior information, directly or indirectly, is a key issue in most contributions, ranging from Bayesian formulations based a priori covariances e.g. [98 - 112,122 - 130, 254 - 261], over more general but also less tractable prior probability densities [79 - 97], to inclusion of specific prior knowledge of shape [284 - 294, 312 - 319]. Given the differences and similarities in approach, can we benefit from exchange of ideas and experience? In practice ideas and experience seldom jump across discipline boundaries by themselves. Normally one must go and get them the hard way, for instance by reading and understanding papers from disciplines far from the home ground. Look at the journey into the interdisciplinary cross-field of inversion techniques as a demanding safari into an enormous hunting ground. This book is meant to provide a convenient starting point.

Beschreibung / Inhaltsverzeichnis: PREFACE This volume comprises the main lectures delivered at the Fourth International Summer School in the Mountains on "Mathematical and Numerical Techniques in Physical Geodesy", held from August 25 to September 5, 1986 in Admont, Austria. The School was organized by the Institute of Theoretical Geodesy of the Technical University Graz, Austria under the auspices of the International Association of Geodesy. All five continents were represented by 70 participants from over 20 countries. The purpose of the Summer School was to provide an introduction to advanced techniques which represent the mathematical vehicle for the treatment of modern geodetic problems, to familiarize participants with the present state of the art of global and local gravity field determination methods, ranging from orbit theory, the key satellite techniques, to inertial and standard terrestrial methods, and to discuss future scientific developments. The arrangement of this volume matches the sequence of lectures given at the School. The theoretical PART A represents the mathematical framework of modern physical geodesy, the application PART B deals with the key satellite and surface techniques, providing the detailed structure of the earth's gravity field. PART A: One of the main goals in physical geodesy, global and local gravity field determination, is pursued by extensively applying functional analytic methods. Recently special attention is being given to the base function and norm choice problem, and to the establishment of a sound link between density distributions inside the earth as the source and observed or estimated gravity field quantities as the effect. The lectures by C.C. Tscherning focus on this topic. Space and time dependent problems of discrete and continuous type are encountered in modern geodesy nowadays and dealt with in the lectures by F. Sans6. Estimation theory either in its stochastic or statistic formulation plays a key role in the processing of processes like the earth's gravity field. The consistent processing of large structured data sets calls for equally structured numerical algorithms. Spectral analysis with its powerful fast Fourier transform has become a common tool for the treatment of such problems. An introduction to spectral methods, supplemented by numerous examples, is provided by B. Hofmann-Wellenhof and H. Moritz. PART B: The theory of orbit dynamics, tailored to the near circular orbits of most geodetic satellites, is fundamental to modern geodetic satellite techniques and discussed in the lectures by O.L. Colombo. Particular emphasis is put on the interplay between orbit perturbations and the earth's disturbing gravity field and its mapping by satellite techniques like satellite altimetry, satellite-tosatellite tracking and satellite gradiometry. Satellite gradiometry, which is discussed in the lectures by R. Rummel in detail, with regard to the geometric structure of the gravitational field, the observability of the gradients, and the mathematical model underlying the gravity field recovery problem, promises to provide particularly detailed information about the gravity field of our planet. The global structure of the earth's gravity field is described in terms of earth gravity field models which are derived from both satellite and surface data. The many delicate, mathematically as well as numerically challenging problems, related to the consistent processing of very large space distributed data sets, and proposed solutions are presented in the lecture by R.H. Rapp. For many years various attempts have been made to explain the shorter wavelength part of the earth's anomalous gravity field by isostatic phenomena. Recently several high resolution topographicisostatic earth models have been computed based on global digital terrain data using different techniques fo~ the estimation of the parameters of the chosen isostatic model. A declared goal is the maximum smoothing of the observed gravity field by removing the contribution of the topography and its isostatic compensation. This topic is discussed in the lectures by H. SUnkel. Inertial methods are steadily gaining importance, power and application. This is not only due to hardware improvements in terms of precision and reliability, but also due to recent advances in the mathematical and numerical modelling of the system's performance. An investigation of the error characteristics of inertial survey systems and their interaction with the anomalous gravity field, studied in the framework of dynamic system analysis, is the topic of the lectures by K.-P. Schwarz and the key issue for further improvements and possible integrations with other positioning systems. Geodetic data have both geometric and physical ingredients of various nature. Standard geodetic processing procedures aim at a separation of geometry from physics. Integrated geodesy, in contrast, has been designed as a very sophisticated melting pot which handles practically all available geodetic data in a consistent and optimal way.lt handles surface and satellite data with either geometrically or gravity field dominated content, and geophysical data in terms of density and seismic informatlon just as well and represents as such the great synthesis of mathematical modelling in connexion with geodetic data processing techniques; these advanced ideas are presented in the lectures by G. Hein. This volume presents highlights of modern geodetic activity and takes the reader to the frontiers of current research. It is not a textbook on a closed and limited subject, but rather a reference book for graduates and scientists working in the vast and beautiful, demanding but rewarding field of earth science in general and physical geodesy in particular. The editor expresses his appreciation to all authors of this volume for their advice and help in formulating and designing the scientific program of the Summer School, for providing typewritten lecture notes, and for their excellent cooperation.

Beschreibung / Inhaltsverzeichnis: PREFACE The four-year period of activity of the Groupement de Recherche 942 (GDR) of the Centre National de la Recherche Scientifique (CNRS) came to an end in December 1993. This GDR was a scientific association grouping research teams from the academic sphere -- i.e. the Unités de Recherches Associées 723 & 724 of the CNRS as well as the Universities of Orléans and Paris-Sud -- and from the industrial world: Elf-Aquitaine Production, TOTAL and the Institut Français du Pétrole (IFP). The aim of the GDR was to understand the processes and the causes of organic carbon fossilization in sediments, especially when they can be modified by environmental conditions such as climate, eustatism, productivity etc., factors which can alko interact. This goal implies the simultaneous study of ancient geological formations (hydrocarbon source rocks from the famous Kimmeridge Clay Formation) and recent Quaternary sediments (the Lac du Bouchet or lake Bouchet maar, Massif Central, France). In the latter case, we benefit from a fine-scale stratigraphical framework as well as a reliable reconstruction of the local and regional environment. This volume is a collection of papers representing oral presentations given on December 7, 1993, at the Société Géologique de France in Paris, during the final meeting of the GDR. These articles thus report the latest developments of the studies carried out under the GDR. However, this is not the first publication of our results, which can be found in the papers referred to in each article. The Kimmeridge Clay Formation was previously studied in 1987, by the Yorkim Group from IFP, Elf-Aquitaine and the British Geological Survey, on the basis of a series of wells drilled across the Cleveland Basin of Yorkshire. In each well, the distribution with depth of the total organic content is cyclic. We have compared some of the organic cycles from two wells (Matron and Ebberston) based on mineralogy, organic and inorganic geochemistry and petrography, at a high resolution scale (centimetric). The main conclusion of this work is that the driving force for organic matter accumulation in the studied cycles was organic phytoplankton productivity. Oxygenation conditions seem to have played a secondary role as a positive feedback action enhancing organic matter storage. Lac du Bouchet is located on the Devès volcanic plateau, 15 km SW of Le Puy en Velay, at an altitude of 1205 m. The depth of the water column is 28 m. The lake has a subcircular shape (1 km in diameter) and a very restricted watershed. This site is exceptionally suitable for research on climate variations and palaeomagnetic field modifications (Euromaars EC Program). The GDR focused on sedimentary organic matter and its relationship to inorganic phases. An important result is that organic matter appears to be a good indicator of palaeoenvironmental reconstructions for over 350 000 years. In addition, the study of early diagenetic reactions in surficial sediments (porewater and solid phase) allows the specification of the processes of organic matter degradation and storage in such an oligothrophic lake.

Beschreibung / Inhaltsverzeichnis: PREFACE During the last decades, remarkable progress in heat flow studies has been made and a rough picture of the global surface heat flow density distribution can now be drawn. Simultaneously, the question of over which time period the surface heat flow is constant arose. There is a big field of model calculations, based on the changes in radioactive heat generation of the Earth, on plate motions, on stretching hypotheses or on other ideas, which result in geotherms in the geological past. Although these speculative paleogeotherms seem to be realistic especially in oceanic areas they do not belong to the scope of this book. In continental areas however, it is not possible to find a simple time dependence of the surface heat flow density. However, petroleum research and tectogenetic studies are very interested in the geothermal history of sedimentary basins and other continental areas. To obtain satisfactory results, a more or less direct determination of paleo heat flow density or geothermal gradient would be necessary to give more certain boundary conditions for calculating oil generation, and for controlling tectogenetic hypotheses. There are many methods available in the geosciences to determine temperatures in the geological past. Most of these models are able to estimate temperatures at which a mineral or a mineral assemblage was formed. These methods, however, are mostly unsuitable to reach the main goal of paleogeothermics in general, which is to determine the (regional) heat flow density variations during the geological past for bigger geological units, such as sedimentary basins. The methods applied most in sedimentary basins have been deduced from the degree of coalification of organic matter. Although much effort has been made to explain analytically the organic metamorphism, the results found up to now have been insufficient . However, the widespread application of this thermometer to estimate ancient thermal conditions is also reflected in the contents of this very volume where the interpretation of the degree of coalification of organic matter plays an important role. As well as this geothermometers, other methods are reviewed from a geophysical viewpoint which favours methods suitable to determine a paleothermal state of the upper crust. Further contributions of this book deal with - the history of the earth's surface temperature whose change provides an essential correction factor in heat flow density determinations, - isotope geothermometers and their application to various environments to evaluate thermal conditions in the past geological history, - an application of the radiometric dating method to retrace the paleothermal condition of the Central Alps. Most of the contributions were presented at the symposium "Paleogeothermics" which was held at the 18. General Assembly of the International Union of Geodesy and Geophysics, August 15-27, 1983 in Hamburg/FRG. It has been the first time that such a symposium has been organized by the International Heat Flow Commission, and this book presents an attempt to define paleogeothermics under the auspices of the International Heat Flow Commission.

Beschreibung / Inhaltsverzeichnis: INTRODUCTION Theoretical modelling and the use of mathematical methods are presently gaining in importance since progress in both geology and mathematics offers new possibilities to combine both fields. Most geological problems are inherently geometrical and morphological, and, therefore, amenable to a classification of forms from a "Gestalt point of view". Geometrical objects have to possess an inherent stability in order to preserve their essential quality under slight deformations. Otherwise, we could hardly conceive of them or describe them, and today's observation would not reproduce yesterday's result (DANGELMAYR & GÜTTINGER, 1982). This principle has become known as "structural stability" (THOM, 1975), i.e. the persistence of a phenomenon under all allowed perturbations. Stability is also, of course, an assumption of classical Newtonian physics, which is essentially the theory of various kinds of smooth behavior (POSTON &STEWART, 1978). However, things sometimes "jump". A new species with a different morphology appears suddenly in the paleontological record (EI.DREDGE & GOULD, 1972), a fault develops, a landslide moves, a computer program becomes unstable with a certain data configuration, etc. It is, surprisingly, the topological approach which permits the study of a broad range of such phenomena in a coherent manner (POSTON & STEWART, 1978; LU, 1976; STEWART, 1982). The universal singularities and bifurcation processes derived from the concept of structural stabiIity determine the spontaneous formation of qualitatively similar spatio-temporal structures in systems of various geneses exhibiting critical behavior (DANGELMAYR & GÜTTINGER, 1982; THOM, 1975; POSTON & STEWART, 1978; GÜTTINGER & EIKEMEIER, t979; STEWART, 1981). In addition, this return to a "geometrization of phenomena"-- after decades of algorithmization-- comes much closer to the geologist's intuitive geometric reasoning. It is the aim of this study to elucidate, by examples, how the qualitative geometrical approach allows one to classify forms and to control the behavior of complex computer algorithms...

Beschreibung / Inhaltsverzeichnis: PREFACE In the geologic record, vertical crustal uplift has often resulted in erosional removal of huge thicknesses of sedimentary strata. If the uplift is of a broad regional nature or the uplifted strata remain relatively undeformed and sediments deposited after the uplift are not preserved, the magnitude of uplift and subsequent erosion may be difficult to quantify. This may lead to misinterpretation or omission of chapters of geologic history of a region. Fortunately, a number of indirect methods can be used to infer the thicknesses of missing strata and reconstruct the geologic history. Our book titled "Thick Post-Devonian Sediment Cover Over New York State: Evidence from Fluid-Inclusion, Organic Maturation, Clay Diagenesis and Stable Isotope Studies" uses four techniques of paleotemperature measurements in sedimentary rocks in order to determine burial depths of the existing Paleozoic strata in New York State. Since every technique has its own analytical and interpretative uncertainties, the use of four techniques allowed us to place a better constraint on our results. We show how regionally extensive paleotemperature data can be used to estimate the thicknesses of strata lost from an uplifted sedimentary basin. We also provide a tentative tectonic-, paleogeographic- and depositional history of New York State after the Devonian when the missing strata were deposited...

Beschreibung / Inhaltsverzeichnis: INTRODUCTION - WHY THIS BOOK? Why study Numerical Geology? Although geologists have dabbled in numbers since the time of Hutton and Playfair, 200 years ago (Merriam 1981e), geology until recently lagged behind other sciences in both the teaching and geological application of mathematics, statistics and computers. Geology Departments incorporating these disciplines in their undergraduate courses are still few (particularly outside the USA). Only two international geomathematical/computing journals are published (Computers & Geosciences; Mathematical Geology), compared with dozens covering, say, petrology or mineralogy. It also remains common practice for years (and $1000s) to be spent setting up computerized machines to produce large volumes of data in machine-readable form, and then for geologists to plot these by hand on a sheet of graph paper! Despite this, the use of numerical methods in geology has now begun to increase at a rate which implies a revolution of no less importance than the plate tectonic revolution of the 1960's -- one whose impact is beginning to be felt throughout the academic, commercial, governmental and private consultative geological communities (Merriam 1969, 1981c). Although a few pioneers have been publishing benchmark papers for some years, the routine usage of machine-based analytical techniques, and the advent of low-priced desk-top microcomputers, have successively enabled and now at last persuaded many more geologists to become both numerate and computerate. Merriam (1980) estimated that two decades of increasing awareness had seen the percentage of geomathematical papers (sensu lato) rise to some 15% of all geological literature; meanwhile, mineralogy-petrology and geochemistry had both fallen to a mere 5% each! In these Notes, geomathematics and numerical geology are used interchangeably, to cover applications of mathematics, statistics and computing to processing real geological data. However, as applications which primarily store or retrieve numbers (e.g. databases) are included, as well as those involving actual mathematical calculations, 'Numerical Geology' is preferred in the title. 'Geomathematics' in this sense should not be confused with 'geostatistics', now usually restricted to a specialised branch of geomathematics dealing with ore body estimation (§20). Reasons for studying Numerical Geology can be summarised as follows: (1) Volumes of new and existing numerical data: The British Geological Survey, the world's oldest, recently celebrated its 150th anniversary by establishing a National Geoscience data-centre, in which it is hoped to store all accumulated records on a computer (Lumsden & Flowarth 1986). Information already existing in the Survey's archives is believed to amount to tens or hundreds of Gb (i.e. = 1010-11 characters) and to be increasing by a few percent annually. The volumes of valuable data existing in the worM's geological archives, over perhaps 250 years of geological endeavour, must therefore be almost immeasurably greater. It is now routine even for students to produce hundreds or thousands of multi-element analyses for a single thesis, while national programs of geochemical sampling easily produce a million individual dement values. Such volumes of data simply cannot be processed realistically by manual means; they require mathematical and statistical manipulation on computers -- in some cases large computers. (2) Better use of coded/digitised data: In addition to intrinsically numerical (e.g. chemical) data, geology produces much information which can be more effectively used if numerically coded. For example, relatively little can be done with records of, say, 'limestone' and 'sandstone' in a borehole log, but very much more can be done if these records are numerically coded as 'limestone = 1' and 'sandstone = 2'. Via encoding, enormous volumes of data are opened to computer processing which would otherwise have lain dormant. More importantly, geological maps - perhaps the most important tool of the entire science - can themselves be digitised (turned into large sets of numbers), opening up vast new possibilities for manipulation, revision, scale-change and other improvements. (3) Intelligent data use: It is absurd to acquire large volumes of data and then not to interpret them fully. Field geologists observing an outcrop commonly split into two (or more) groups, arguing perhaps over the presence or absence of a preferred orientation in kyanite crystals on a schist foliation surface. The possibility of actually measuring these orientations and analyzing them statistically (§17) is rarely aired-- at last in this author's experience! Petrologists are equally culpable when they rely on X-Y or, at maximum 'sophistication', X-Y-Z (triangular) variation diagrams, in representing the evolution of igneous rocks which have commonly been analyzed for up to 50 elements! Whereas some geological controversies (especially those based on interpretation of essentially subjective field observations) cannot be resolved numerically, many others can and should be. This is not to say (as Lord Kelvin did) that quantitative science is the only good science, but qualitative treatment of quantitative data is rarely anything but bad science. (4) Literature search and data retrieval: Most research projects must begin with reviews of the literature and, frequently, with exhaustive compilations of existing data. These are essential if informed views on the topic are to be reached, existing work is not merely to be duplicated, and optimum use is to be made of available funding, The ever-expanding geological literature, however, makes such reviews and compilations increasingly time-consuming and expensive via traditional manual means. Use of the increasing number of both bibliographical and analytical databases (§3) is therefore becoming a prequisite for well-informed, high-quality research. (5) Unification of interests: In these days of inexorably increasing specialisation in ever narrower topics, brought about by the need to keep abreast of the exploding literature, numerical geology forms a rare bridge between different branches not only of geology but of diverse other sciences. The techniques covered in this book are equally applicable (and in many cases have been in routine use for far longer) in biology, botany, geography, medicine, psychology, sociology, zoology, etc. Within geology itself, most topics covered here are as valuable to the stratigrapher as to the petrologist. 'Numerical geologists' are thus in the unique (and paradoxical) position of being both specialists and non-specialists; they may have their own interests, but their numerical and computing knowledge can often help all of their colleagues. (6) Employment prospects: There is a clear and increasing demand for computerate/numerate geologists in nearly all employment fields. In Australia, whose economy is dominated by geology-related activities (principally mining), a comprehensive national survey (AMIRA 1985) estimated that A$40M per annum could be saved by more effective use of computers in geology. Professional computer scientists are also of course in demand, but the inability of some of their number to communicate with 'laymen' is legendary! Consequently, many finns have perpetual need for those rare animals who combine knowledge of computing and mathematics with practical geological experience. Their unique bridging role also means that numerical geologists are less likely to be affected by the vaguaries of the employment market than are more specialised experts. Rationale and aims of this book This is a highly experimental book, constituting the interim text for new (1988) courses in 'Numerical Geology' at the University of Western Australia. It is published in the Springer Lecture Notes in Earth Sciences series precisely because, as the rubric for this series has it, "the timeIiness of a manuscript is more important than its form, which may be unfinished or tentative." Readers are more than welcome to send constructive comments to the author, such that a more seasoned, comprehensive version can be created in due course. Readers' indulgence is meanwhile craved for the number of mistakes which must inevitably remain in a work involving so many citations and cross-references. Emphasis is particularly placed on the word Notes in the series rifle: this book is not a statistical or mathematical treatise. It is not intended to stand on its own, but rather to complement and target the existing literature. It is most emphatically not a substitute for sound statistical knowledge, and indeed, descriptions of each technique are deliberately minimized such that readers shouM never be tempted to rely on this book alone, but should rather read around the subject in the wealth of more authoritative statistical and geomathematical texts cited. In other words, this is a synoptic work, principally about 'how to do', 'when not to do', 'what are the alternatives' and 'where to find out more'. It aims specifically: (1) to introduce geologists to the widest possible range of numerical methods which have already appeared in the literature; and thus (2) to infuse geologists with just sufficient background knowledge that they can: (a) locate more detailed sources of information; (b) understand the broad principles behind interpreting most common geological problems quantitatively; (c) appreciate how to take best advantage of computers; and thereby (d) cope with the "information overload" (Griffiths 1974) which they increasingly face. Even these aims require the reader to become to some extent geologist, computer scientist, mathematician and statistician rolled into one, and a practical balance has therefore been attempted, in which just enough information is hopefully given to expedite correct interpretation and avoidance of pitfalls, but not too much to confuse or deter the reader. Despite the vast literature in mathematics, statistics and computing, and that growing in geomathematics, no previous book was found to fulfill these alms on its own. The range of methods covered here is deliberately much wider than in previous geomathematical textbooks, to provide at least an introduction to most methods geologists may encounter, but other books are consequently relied on for the detail which space here precludes. These Notes adopt a practical approach similar to that in language guidebooks -- at the risk of emulating the 'recipe book' abhorred in some quarters. Every Topic provides a minimum of highly condensed sketch-notes (fuller descriptions are included only where topics are not well covered in existing textbooks), complemented by worked examples using real data from as many fields of geology as space permits. Specialists should thereby be able to locate at least one example close to their problems of the moment. In the earlier (easier) topics, simple worked examples are calculated in full, and equations are given wherever practicable (despite their sometimes forbidding appearance), to enable readers not only to familiarise themselves with the calculations but also to experiment with their own data. In the later (multivariate) topics (where few but the sado-masochistic would wish to try the calculations by hand!), the worked examples comprise simplified output from actual software, to familiarise readers with the types of computer output they may have to interpret in practice. Topics were arranged in previous geomathematical textbooks by statistical subject: 'analysis of variance', 'correlation', 'regression', etc., while nonparametric (rank) methods were usually dealt with separately from classical methods (if at all). Here, topics are arranged by operation (what is to be done), and both classical and rank techniques are covered together, with similar emphasis. When readers know what they want to do, therefore, they need only look in one Topic for all appropriate techniques. The main difficulty of this work is the near impossibility of its goal-- though other books with similarly ambitious goals have been well enough received (e.g.J.Math.Geol. 18(5), 511-512). Some constraints have necessarily been imposed to keep the Notes of manageable size. Geophysics, for example, is sketchily covered, because (i) numerical methods are already far more integrated into most geophysics courses than geology courses; (ii) several recent textbooks (e.g. Cantina & Janecek 1984) cover the corresponding ground for geophysicists. Structural geology is less comprehensively covered or cited than, say, stratigraphy, because (a) it commands many applications of statistics and computing unto itself alone (e.g. 3-D modelling, 'unravelling' of folds), whereas these Notes aim at techniques equally applicable to most branches of geology; (b) excellent comprehensive reviews of structural applications are already available (e.g. Whitten 1969,1981). Remote sensing is also barely covered, since comprehensive source guides similar in purpose to the present one already exist (Carter 1986). For the sake of brevity, phrases throughout this book which refer to males are, with apologies to any whose sensitivities are thereby offended, taken to include females!

Beschreibung / Inhaltsverzeichnis: PREFACE During the last few years, evaporites have increasingly been regarded as sediments and not only as chemical precipitates. Especially the intensive study of the Zechstein facies has resulted in a vast amount of observations and interpretations which are of general significance, offering important information to all sedimentologists interested in carbonates and evaporites. It seems therefore useful to introduce the sedimentological approach in a basin where various chemical concepts have been developed. This is the aim of the present volume, and this approach will be recognized by the reader in most of the chapters. The idea of publishing a collection of papers on the Zechstein facies and related rocks found an enthusiastic response, although later some contributors were, for various reasons, unable to meet the deadline. However, the papers submitted cover all major fields and will certainly stimulate further research...

Beschreibung / Inhaltsverzeichnis: Introduction / Tomotoshi Okaichi / pp. 3-5 --- Seto Inland Sea—Historical Background / Tetsuo Yanagi and Tomotoshi Okaichi / pp. 9-14 --- Biological Productivity of the Lower Trophic Levels of the Seto Inland Sea / Hiroaki Hashimoto, Toshiya Hashimoto, Osamu Matsuda, Kuninao Tada, Kyoichi Tamai, Shin-ichi Uye and Tamiji Yamamoto / pp. 17-58 --- Fisheries Production / Tatsuki Nagai and Yasuki Ogawa / pp. 61-94 --- The Preservation and Creation of Fisheries Grounds / Tetsuo Yanagi / pp. 97-119 --- Strategies for Reduction of Nutrient Loads from the Land / Masahiko Sekine and Masao Ukita / pp. 123-158 --- The Relationship between the Fishery Industry and Environmental Evaluation of the Seto Inland Sea / Hidenori Niizawa, Ken'ichi Nakagami and Kazuhisa Oba / pp. 161-185 --- Legal System and Coastal Management / Mitsuru Nakayama / pp. 189-214 --- Synthesis and Proposal / Tetsuo Yanagi and Tomotoshi Okaichi / pp. 217-219 --- Comparison of the Seto Inland Sea with Other Enclosed Seas from Around the World / Hidetaka Takeoka / pp. 223-247 --- Red Tides in the Seto Inland Sea / Tomotoshi Okaichi / pp. 251-304 --- Law Concerning Special Measures for Conservation of the Environment of the Seto Inland Sea / pp. 307-317 --- International EMECS Center International Center for the Environmental Manage ment of Enclosed Coastal Sea / pp. 321-325