ALBERT

Description: The plateau is a foundered continental block, and lies at an average depth of 2000-3000 m. On the plateau the dominant fault direction is NW to WNW, an ancient strike direction on the Australian continent. The western margin probably formed as a series of NE-trending rifts and NW-trending transforms during Late Jurassic breakup. Canyons cut the western margin, and some of these appear to be fault-bounded. One such fault forms the northern margin of a major NW-trending feature, the Wilson Spur. This appears to be a transform fault and perhaps extends across the abyssal plain as far as the eastern end of the Java Trench. Seismic profiles suggest that, at the trench, it separates thrust-faulted continental crust to the east from oceanic crust to the west. This could explain the eastern termintion of the deep part of the trench. The bathymetric depression of the Roti Basin, which lies southeast of the Java Trench, links the trench to the Timor Trough. The Argo Abyssal Plain slopes gently southward, with water depths ranging from 5000 m near the Java Trench to 5730 m in the south. Oceanic basement varies from smooth to hummocky and irregular, and is overlain by about 4000 m of acoustically semi-transparent Late Jurassic and Cretaceous sediments, that is in turn unconformably overlain by 200 m of layered Tertiary sediment. Bottom samples from the outer Scott Plateau show that Callovian breakup was preceded by a period of basic volcanism and shallow marine sedimentation, that restricted shallow marine conditions followed in the Late Jurassic, and that bathyal carbonate sedimenation prevailed by the Late Cretaceous (Campanian). Quaternary marls cored on the northern Scott Plateau straddled the Pleistocene-Holocene boundary, and siliceous oozes cored on the southern slope of the Java Trench contain nannofossils which, below a few decimetres, are older than late Pleistocene. The Java Trench cores indicate that the calcite compensation depth was apparently between 5420 and 5700 m in the early or midel Pleistocene, and is above 4950 m now. The Scott Plateau cores indicate that the present calcite compensation depth in the region lies below 3290 m. On the Scott Plateau Holocene sedimentation rates are about 5 cm/1000 years, but in the Java Trench they are much lower. Manganese oxide crusts and nodules were recovered from the Scott Plateau, but their content of valuable metals was low.

Description: The Marine Minerals Database contains geochemical analyses and auxiliary information on present-day marine deposits of primarily ferromanganese nodules and crusts. Some data for heavy minerals are also included. Sources of ferromanganese analyses include the historic Scripps Institution of Oceanography (SIO) manganese nodule analysis file compiled under the direction of Jane Frazer and Mary Fisk.

Description: Concentrically ringed manganese nodules, similar in form to many found on modern ocean and sea floors, occur in a very fine grained argillaceous sandstone bed of the Permian Park City Formation near Dillon, Montana. They are enriched in many rare elements and contain us much as 2.5 percent zinc, l.3 percent nickel, and 0.22 percent cobalt. The manganese minerals are chalcophanite and todorokite. The nodules probably formed in a shallow marine oxidizing environment on the western side of the Permian sedimentary basin. The occurrence of an appreciable amount of fluorite in the bed suggests that the water was saline.

Description: In the 1960s and 1970s, the Kennecott Corporation conducted a number of activities in the evaluation of manganese nodule deposits as well as in their possible hydrometallurgy.

Description: Deep sea manganese nodules from the Central Pacific Basin are mainly composed of 10Å manganite and d-MnO2 Two zones equivalent to the minerals are evidently distinguishable according to their optical properties. Microscopic and microprobe analyses revealed quite different chemical compositions and textnral characteristics of the two zones. These different feature of the two zones of nodules suggest the different conditions under which they were formed. Concentrations of 11 metal elements in the zones and inter-element relationships show that the 10Å manganite zone is a monomineralic oxide phase containing a large amount of manganese and minor amounts of useful metals, and that the d-MnO2 zone which is apparently homogeneous under the microscope is a mixture of three or more different minerals. The chemical characteristics of the two zones can explain the variation of bulk composition of deep sea manganese nodules and inter-element relationships previously reported, suggesting that the bulk compositions are attributable to the mixing of the 10Å manganite and d-MnO2 zones in various ratios. Characteristic morphology and surface structure of some types of nodules and their relationships to chemistry are also attribut able to the textural and chemical features of the above mentioned two phases. Synthesis of hydrated manganese oxides was carried out in terms of the formation of manganese minerals in the ocean. The primary product which is an equivalent to d-MnO2 was precipitated from Mn 2+ -bearing alkaline solution under oxigenated condition by air bubbling at one atmospheric pressure and room temperature. The primary product was converted to a l0Å manganite equivalent by contact with Ni 2+, Cu 2++ or CO2+ chloride solutions. This reaction caused the decrease of Ni2+, Cu2+ or CO2+ concentrations and the increase of Na+ concentration in the solution. The reaction also proceeded even in diluted solutions of nickel chloride and resulted in a complete removal of Ni2+ from the solution. Reaction products were exclusively 10Å manganite equivalents and their chemical compositions were very similar to those of 10Å manganite in manganese nodules. The maximum value of(Cu+Ni+Co)/Mn ratio of 10Å manganite zones in manganese nodules is 0.16, and the Ni/Mn ratio of synthetic 10Å manganite ranges from 0.15 to 0.18 with the average of 0.167.

Description: The major and some of the minor constituents and the rate of accumulation of manganese nodules in the western North Pacific were determined. Manganese concentration in the nodules ranged from 20 to 30 per cent in the acid soluble fraction. As to the rare earth concentration, enrichment of cerium was observed in the manganese nodule as compared with that in shales or sea water. Thorium to uranium ratio in the nodule ranged from 9.4 to 14.3, which was very much higher than that in sea water. From the distribution of excess ionium, excess protactinium and Io/Th ratio, a rate of accumulation of 7 mm per million years was obtained with the surface layer of several mm in thickness of the JEDS-4-E4 nodule.