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  • Articles  (23)
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  • crystal structure  (15)
  • Heat stress
  • anisotropy
  • fish
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  • Springer  (23)
  • 1995-1999  (23)
  • 1995  (23)
  • Chemistry and Pharmacology  (18)
  • Geography  (5)
  • 1
    ISSN: 1436-5073
    Keywords: mercury ; fish ; collaborative study ; atomic absorption spectrometry
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract One of the major analytical problem in the analysis of fish tissues for total mercury is the dissolution of the sample. This paper compares two different methods of wet digestion (microwave and closed pressurized vessel), followed by FIAAS as final determination and a Zeeman-solid-sample-AAS determination method without previous mineralization. Six fish samples were selected for this study. The top, the central and the bottom portions of the fish were analyzed separately. The mercury contents in the bottom portions determined by Zeeman-solid-sample-AAS were significantly higher than those obtained by the other two systems. A good correlation was observed among the results of the different techniques.
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  • 2
    ISSN: 1436-5073
    Keywords: microwave digestion ; fish ; mercury ; CVAAS
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Food samples digestion, in view to quantify total mercury, is the first step to perform before measuring mercury by cold vapour atomic absorption spectrometry (CVAAS). We have compared two microwave digestion systems, one working at atmospheric pressure (open system) and the other one under pressure (closed system). Results obtained for fish muscle samples by the two methods are in good agreement. However, fat is not digested in the open system, whereas in the closed system no more fat remains in the final solution. During the quantification step, applying the CVAAS technique, we have noticed that the choice and the concentration of the reductant solution is very important to obtain good results. Elaborated methods have been validated using certified reference materials.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    International journal of biometeorology 38 (1995), S. 216-217 
    ISSN: 1432-1254
    Keywords: Aldosterone ; Electrolytes ; Broiler ; Heat stress
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Abstract An experiment was conducted to evaluate the effects of supplementing drinking water with isomolar (0.067 mol/l) KCl or NaCl on mass gain, food and water consumption, rectal temperature, and plasma concentrations of aldosterone, Na+, and K+ in broiler chickens reared in thermoneutral and cycling heat stressing environments. Heat stress decreased (P≤0.05) mass gain, food consumption, and plasma concentrations of Na+ and K+, while increases (P≤0.05) in plasma concentrations of aldosterone, rectal temperature, and water consumption were observed. Drinking water supplemented with either KCl or NaCl increased (P≤0.05) broiler mass gain and water consumption, but had no effect (P〉0.1) on the other variables evaluated. The results of this study indicate that broiler chickens in a heat stress environment are under osmotic stress and supplementing drinking water with 0.067 mol/1 KCl or NaCl does not lessen this stress.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    International journal of biometeorology 38 (1995), S. 57-59 
    ISSN: 1432-1254
    Keywords: Polyol pathway ; Diabetes mellitus ; Water immersion ; Heat stress
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geography , Physics
    Notes: Abstract Activities of erythrocyte aldose reductase were compared in 34 normal subjects, 45 diabetic patients, and nine young men following immersion in water at 25, 39, and 42° C. Mean basal enzyme activity was 1.11 (SEM 0.12) U/g Hb and 2.07 (SEM 0.14) U/g Hb in normal controls and diabetic patients, respectively (P〈0.0001). Activities of the enzyme showed a good correlation with hemaglobin A1 (HbA1) concentrations (P〈0.01) but not with fasting plasma glucose concentrations. After immersion at 42° C for 10 min, enzyme activity was increased by 37.6% (P〈0.01); however, the activity decreased by 52.2% (P〈0.005) after immersion for 10 min at 39° C and by 47.0% (P〈0.05) at 25° C. These changes suggest that heat stress might aggravate diabetic complications, and body exposure to hot environmental conditions is not recommended for diabetic patients.
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  • 5
    ISSN: 1572-9001
    Keywords: MM3 ; PM3 ; MMX ; crystal structure ; norbonadienone ; distorted compound
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The reaction of 4,5-didehydroacenaphthene with phencyclone yields the title compound, a stable dibenzo-fused norbornadienone (8). The X-ray structure of8 is presented and compared with the structure predicted from a MM3, PM3, and a MMX calculation. Thermal decomposition of 8 produces, 7,16-diphenylcyclopenta[d,e]tribenzo[a,h,j]anthracene (9), a hydrocarbon that is computed to have a significantly twisted polycyclic aromatic skeleton with 19 kcal/mole of strain energy.
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Structural chemistry 6 (1995), S. 57-63 
    ISSN: 1572-9001
    Keywords: Hydrogen bonding ; carcinogen ; polycyclic aromatic hydrocarbon derivative ; dihydrodiol ; crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The crystal structure of the weak carcinogen 5-methylchrysene-7,8-dihydro-7,8-trans-(e,e)-diol is reported. This molecule contains a distorted bay region as a result of the presence of the 5-methyl group as found in 5-methylchrysene and 5,6- and 5, 12-dimethylchrysene. One torsion angle in this bay region is 20
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  • 7
    ISSN: 1573-4919
    Keywords: DNA adducts ; liver ; fish ; 32P-postlabelling ; polycyclic aromatic hydrocarbons ; genotoxic biomarker
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology , Medicine
    Notes: Abstract The levels of DNA adducts in the hepatic tissue of the white sucker fish speciesCatostomus commersoni were determined by32P-postlabelling. The fish were caught at four sites: two sites near the city of Windsor (Québec, Canada) on the St. François River, a downstream tributary of the St. Lawrence River, and two sites in the St. Lawrence River itself, near the city of Montréal (Québec, Canada). The latter sites are known to be contaminated by many pollutants including polycyclic aromatic hydrocarbons. Total adduct levels in all fish ranged from 25.1–178.0 adducts per 109 nucleotides. White sucker from the selected sites of the St. Lawrence River had a significantly higher mean level of DNA adducts than those of the St. François River (129.4 vs 56.8, respectively). These results suggest that the effluents of many heavy industries (e.g. from a Soderberg aluminium plant) flowing in the St. Lawrence River are more likely to produce genotoxic damage to fish than those released in one of its tributary, and mainly associated to the activities of a small town and a nearby pulp and paper mill.
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  • 8
    ISSN: 1573-9171
    Keywords: resorcinol-based crown ethers ; crystal structure ; intramolecular nonbonded C-H...O contacts
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract 13- and 26-Membered crown ethers have been synthesized based on resorcinol and 1,8-dichloro-3,6-dioxaoctane. The products with substituents in the benzene ring have been prepared by alkylation of 13-membered crown ether. Complexing properties of the macrocycles have been studied with the use of ion-selective membrane electrodes. The structures of 13- and 26-membered crown ethers have been established by X-ray structural analysis.
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  • 9
    ISSN: 1573-9171
    Keywords: dihydroisoquinoline derivatives ; crystal structure ; electronic, IR, and1H NMR spectra ; quantum-chemical calculation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract 3,3-Dimethyl-3,4-dihydroisocarbostyryl azine (2) has been synthesized by oxidation of l-hydrazino-3,3-dimethyl-3,4-dihydroisoquinoline (1). The crystal and molecular structures of compound 2 were determined. It has been established that in the solid state, compound2 exists as an azine tautomer. The IR, electronic, and NMR spectral data indicate that in solution the tautomeric form of2 does not change. A possible mechanism of the oxidation of1 to2 is suggested.
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  • 10
    ISSN: 1573-8590
    Keywords: China ; Qinghai ; Koko Nor ; Cyprinidae ; fish ; fishery ; recruitment ; spawning ; catch per unit effort ; management ; translocation ; saline lake ; dryland ; semi-arid ; irrigation ; conservation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geography
    Notes: Abstract Quinghai Hu is a large, high-altitude, saline lake in north-western China, and supports a fishery based on an endemic species of naked carp (‘snow trout’). The fish take seven years to attain maturity and a marketable weight of 300 g, and have a lifespan of 14–21 years under the present fishery regime. They seasonally migrate from the lake to spawn over the gravel beds of inflowing rivers, but these areas have been reduced by weirs and irrigation diversions and recruitment may have declined. The population may have been affected also by a 1.85-m fall in the lake level over the past 30 years, and by associated changes in salinity. The fishery was opened to large-scale exploitation in 1958. Yields declined sharply (max. 28,523 tonnes, 1960) as the larger, older fish were removed, and then more slowly (min. 2523 tonnes, 1983). Since 1987 the fish factory has been limited to an annual quota of 1200 tonnes, taken by a fleet of four pair trawlers. Another 800 tonnes are taken by licensed fishermen, mainly using gill nets, and perhaps 1000 tonnes are taken illegally. The estimated total catch in 1992 was 3000 tonnes. New trawlers introduced in 1989–90 substantially increased the factory's catch per unit effort, and in 1990 the quota was virtually filled in one month in a zone within 20 km of the factory. Although this could suggest that the stocks will be conserved if the quota is retained, at least half of the catch in 1989–92 consisted of immature individuals. Trawling operations recently were suspended following a further decline in the catch after 1992. While the new trawlers are capable of a major increase in effort, neither the changing environment, the fish stocks or the present markets favour intensified pressure. Gillnets may provide better control over the minimum size limit and may cause less damage than trawling. Other options to improve the viability and profitability of the fishery include improvements in handling, processing and marketing. Failure to develop the fishery may encourage attempts to introduce exotic fish, at some risk to survival of the local species.
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