ALBERT

Description: The distribution of lipid S (sulpholipids) in 27 soils was examined in relation to factors which influence its abundance in different soil environments. Lipid S was found in all soils examined, but at levels varying from 1.6 to 291 ppm S. Lipid S content was higher in organic horizons than in mineral horizons, and poorly drained soils had higher lipid S than freely drained soils. Highest levels were observed in poorly drained organic soils. Lipid S accounted for a small proportion of total S (0.5–3.5%) and of total lipid (0.03–1.7%). Lipid S levels were on average three times higher than lipid P. Lipid S was significantly correlated with total S, HI-reducible S and organic C. In a regression analysis, 89% of the variation in soil content of lipid S was accounted for by total lipid and total S contents. The distribution of total lipids confirmed previous reports that higher levels were associated with soils having restricted biological activity.

Description: The morphological expression of podzolization in four Humo-Ferric Podzols increased in a northerly direction over a distance of approximately 74 km from the north shore of Lake Huron. The transect coincided with changes in both geology and vegetation. All the soils were developed in coarse-textured acid tills whose composition was not significantly different to explain the observed variations in soil morphology. Using quartz as an internal standard, the order of mobility from surface horizons was found to be Mg 〉 Fe = Ca 〉 Na = Al 〉 K 〉 Ti. Pyroxenes, amphiboles, chlorite and albite were the most easily weathered minerals. Protocatechuic, p-coumaric, gentisic and gallic acids were found to be the major phenolic acids in water extracts of soil surface horizons. The content of both phenolic acids and carbohydrates in surface horizons increased as the morphological expression of podzolization increased.

Description: This study was conducted to evaluate the impact of tillage and fertilization practices on soil organic carbon (organic-C) and the distribution of phosphorus between inorganic (Pi) and organic (Po) pools in a clay and sandy loam soil under a continuous corn (Zea mays L.) production system. Tillage treatments were established in the fall of 1981. The soils for this study were sampled (0- to 10-cm and 10- to 20-cm) in June 1988. Treatments consisted of three types of tillage: (i) conventional (CT): fall moldboard ploughing with two spring diskings; (ii) reduced (RT): with either fall chisel ploughing (1981–1986) or no fall tillage (1987) followed by one spring disking, and (iii) no-till (NT); and two types of fertilization (i) inorganic (I): 170 kg N ha−1. 80 kg P2O5, ha−1, 75 kg K2O ha−1, and (ii) organic fertilizer (O): dairy manure applied to give 170 kg N ha−1 plus 80 kg P2O5, ha−1 from inorganic P fertilizer. Even though a lime application was made in the fall of 1985, soil pH was significantly lower in the I fertilizer treatments. Reduction of tillage intensity resulted in a lower pH in the surface layer of the sandy loam soil. Tillage did not affect soil organic-C, or total soil Po (soil-Po) in either soil. Compared with the I fertilizer treatment, the O fertilizer treatment resulted in increased levels of soil organic-C and soil-Po only in the sandy loam soil. Labile levels of Po in the soil were not affected by treatments. Increased soil-Po levels possibly resulted from an increase in stable Po complexes. Moderately labile Po levels were not affected by treatments in the clay soil. In the sandy loam soil, O fertilization decreased moderately labile Po levels in the surface layer of the NT treatment, and increased this P fraction in the 10- to 20-cm soil layer of the RT and CT treatments. In the surface layer of both soils, labile levels of Pi were greater for the O fertilization treatment (approximately 40 and 47% higher for the clay and sandy loam, respectively), and were lower under CT. Increased labile Pi levels were associated with the O fertilizer treatment in the 10- to 20-cm depth increment in the sandy loam soil only, suggesting a greater downward movement of P with manure applications. Key words: Conventional tillage, zero-tilled, no-till, reduced tillage, manure, P fractionation

Description: Concern has been expressed that reduced tillage systems may lead to excess soil compaction, negatively impacting on crop growth. The objectives of this study were to determine the effects of tillage systems zero (ZT), minimum (MT) and conventional tillage (CT) and crop rotations on soil bulk density and penetration resistance after 4 yr on an Indian Head heavy clay soil, in southeastern Saskatchewan. Moisture content was similar among tillage systems, except for slight differences in the lower soil depths with crop rotation. Penetration resistance and bulk density of a heavy clay soil were increased in the surface 10 cm of the soil by ZT as compared to CT management. However, in the deeper soil zones, tillage system did not consistently influence either bulk density or penetration resistance. Inclusion of peas in the crop rotation had a moderating effect on bulk density and penetration resistance, while inclusion of flax in a continuous rotation increased bulk density and penetration resistance in the surface soil profile. At the 30- to 45-cm depth, ZT had a lower bulk density than CT or MT in the rotation which included fallow, possibly because the tillage operations associated with the cultivated fallow led to compaction in the deeper soil zone. Penetration resistance was great enough in the deeper soil zone in all tillage systems to restrict rooting, but difference due to tillage treatment or cropping rotation was not sufficient to markedly influence crop production. Key words: Penetration resistance, bulk density, crop rotation, tillage

Description: Soils cultivated for 60 yr were compared with uncultivated forested soils at 10 sites in Appalachian Quebec. All soils belonged to the Humo-Ferric Podzol Great Group, five sets of comparisons being located on the Ascot soil series and five on the Greensboro. Comparisons were made between corresponding soil horizons, analytical data being derived from the bulking and analysis of six sample cores per horizon. Cultivation increased weight of soil in the solum and in the whole profile of both the Greensboro and the two soil series combined; bulk density was slightly affected. Field capacity, permanent wilting point and available water of the surface and sub-surface layers, in the solum and in the whole profile, were significantly increased by cultivation. The increase of available water was accompanied by a corresponding decrease in gravitational water. The content fine clay was significantly decreased in the surface layer and in the solum, while it was increased significantly in the C horizon by cultivation which also decreased the acidity of the surface and sub-surface in both series. There was a marked increase in organic matter content, but the level of fulvic acid was relatively unaffected by cultivation, indicating that the increased H/F ratio was primarily due to an increase in humic acid. Generally, Al content was not significantly changed, while significant increases in Fe and Mn were observed in the surface and solum of cultivated profiles. A deduction is made that cultivation has regraded podzol profiles into Dystric Brunisol ones which have started to evolve already toward kinds of Luvisolic profiles.

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Description: The variability of forest floor properties over short distances and the number of samples required to achieve desired levels of precision for estimation of property means have received little attention. The importance of the forest floor for forest management is well known and increasingly forest floor characteristics are being used to classify forest sites. Highly variable forest floor properties require more intensive sampling and often have less predictive value for characterization and classification purposes. A study site at Port Hardy was used to characterize forest floors for selected physical and chemical properties. The three sites chosen represented xeric, mesic and hygric positions along a hygrotopic gradient. A stratified random sampling procedure was used to obtain 15 samples at each site. Fifteen samples were adequate to characterize the means at 10% allowable error with a 95% confidence level for total nitrogen, organic carbon, pH and cation exchange capacity. Greater than 15 samples were required for exchangeable bases and forest floor thickness for the same level of accuracy and confidence. Even at 25% allowable error and 90% confidence, 40 samples and 16 samples, respectively, were required for exchangeable Ca and Mg.

Description: Atomic absorption spectrophotometric measurements of Al in plant digests and neutral salt extracts of soils were studied. Using a new lamp (Westinghouse design) and 5 × scale expansion, 1.0 ± 0.08 ppm Al was measured. Lanthanum (2000 ppm) suppressed enhancements from Na, K, Sr, Fe and a mixture of a large number of constituents. The measurements in plant digests were independent of dilution, gave complete recovery of added Al and showed excellent agreement with the 8-quinolinolate colorimetric values. Similarly, there was complete recovery from soil extracts, but the measurements by atomic absorption were larger than by 8-quinolinolate or Aluminon. It was concluded that the new lamp provides adequate sensitivity, stability and freedom from interferences so that atomic absorption can be used for routine measurements of Al in plant digests and neutral salt extracts of soils.

Description: Five vegetation treatments were established in 1.2 m × 1.2 m plots in 1990: (1) bare mineral soil, (2) Epilobium angustifolium, (3) Rubus spectobilis, (4) Alnus rubra and (5) a mixture of all three species. Soil temperatures were measured at 10-cm depths in three replicates of each treatment during the early summer of 1991. Mean, maximum and minimum temperatures always exhibited the same rank order of treatments — bare 〉 Epilobium 〉 Rubus 〉 mixture 〉 Alnus — but the latter four treatments were not readily distinguishable. A data-adjustment procedure based on Fourier analysis was conducted and its utility discussed for use in the separation of treatment effects where observations exhibit a detectable diurnal cycle. Using this method, the soil thermal regime of the Epilobium treatment was demonstrated to be statistically distinct from that of the bare plots and from those of the other vegetation treatments. Key words: Fourier analysis, diurnal pattern, soil temperature, vegetation effects, microclimate

Description: Organic matter with high C:N ratios accumulated on mineral soil retards cycling of nutrients in semi-mature jack pine (Pinus banksiana Lamb.) ecosystems. To test whether N as ammonium sulfate or as urea stimulates organic matter decomposition, 200 kg N∙ha−1 were applied to mixed L and F horizon material in Warburg respirometer flasks. Soils were incubated at 13 °C and constant 0.3 bar (340%) moisture; O2 consumption was measured as an index of microbial activity. In urea-treated soil, O2 uptake was much higher than with unamended soil over a 7-wk incubation period, and this indicated a marked effect of urea on microbial activity. The fact that ammonium sulfate depressed respiration rates was evidence that stimulation of microbial respiration by urea was not initially related to added N, but rather to an increase in soil-soluble C resulting from soil pH changes during hydrolysis. In the presence of a C source (ethanol), a 5-fold increase in respiration was noted, whereas C and urea together produced a 15-fold increase in activity. These results suggest that readily available energy for microbial growth, rather than N, limits the initial decomposition of L and F materials in this pine stand. Once microbial demand for C is satisfied, a further increase in microbial activity is produced by N addition.

Description: From the solubility equilibrium data of basic aluminite at three temperatures, the standard free energy change (ΔG°), enthalpy change (ΔH°), and entropy change (ΔS°) were determined as 160.02 kcal∙mole−1, 65.48 kcal∙mole−1 and 317.1 cal∙deg−1]mole−1, respectively. From these values the free energy of formation (ΔGf°) and the heat of formation (ΔHf°) of basic aluminite was also computed and was 1465.25 kcal∙mole−1 and 1682.08 kcal∙mole−1, respectively.

Description: Copper, in the form of Cu-polyflavonoid, was applied at 50 or 100 ppm to surface samples of nine Wisconsin soils varying from 0.8 to 12.5% organic matter. The effects on yield and on plant uptake of Cu, Zn and Mn were evaluated using oats (Avena sativa L. cv. Lodi). Complexed Cu additions increased extractable Cu, had little effect on extractable Zn, but also increased extractable Mn. Complexed Cu decreased plant uptake of Zn, but increased uptake of Mn. Interactive effects of organic matter, clay, available phosphorus and Zn appeared to occur with respect to plant yield and Cu, Zn, and Mn uptake.

Description: In a soil incubation experiment with different rates of Zn, the amounts of Zn extracted with 0.005 M DTPA, 1 M MgCl2, and 0.01 M CaCl2 increased with an increase in the organic matter content of a neutral sandy loam soil and with alfalfa added as an organic amendment. Addition of muck and peat increased the amount of Zn exchanged with 1 M MgCl2 but decreased the amount soluble in 0.01 M CaCl2, whereas addition of clay increased the amount of exchangeable Zn but decreased the amounts in the DTPA and 0.01 M CaCl2 extracts. Liming of an acid sandy loam soil (pH 4.9) to about the neutral point reduced the amounts of extractable Zn markedly. A pretreatment of the soils with phosphate almost invariably increased the amounts of extractable Zn. In a corresponding pot experiment, the highest rate of Zn (250 ppm) reduced the yield of corn slightly, prevented the growth of lettuce, and reduced the yield of alfalfa markedly when these crops were grown successively in the acid soil. The concentration of Zn reached levels of 792 ppm in the corn and 702 ppm in the alfalfa. Addition of 50 ppm Zn to the acid soil restricted the growth of lettuce and increased the concentration of Zn to 523 ppm. Despite discrepancies, the concentrations of Zn in the plants as influenced by soil organic matter, organic amendments and liming were usually in accord with the amounts of Zn extracted from the soils. But the P pretreatment tended to decrease the concentration of Zn in corn and lettuce. The mean weight concentrations of Zn in the three species were correlated significantly with the amounts of Zn extracted with 0.005 M DTPA (r = +0.73), 1 M MgCl2 (r = +0.93) and 0.01 M CaCl2 (r = +0.90).

Description: The results of two studies are reported: (1) a comparison of colorimetric and atomic absorption measurements of Fe and Al in dithionite, oxalate, and pyrophosphate extracts of soils; and (2) a comparison among nine Canadian laboratories of measurements of dithionite-, oxalate-, and pyrophosphate-extractable Fe and Al in six soils. Colorimetric and atomic absorption analyses gave the same measurements of Fe and Al in dithionite, oxalate, and pyrophosphate extracts of soils. Data reported by six Canadian laboratories showed close agreement; data reported by three laboratories showed poor agreement, indicating a need for reference soil samples containing known amounts of extractable Fe and Al to standardize laboratory procedures. Atomic absorption analysis of the extracts is much more rapid than colorimetric analysis and details of the atomic absorption methods are appended.

Description: Regression and covariance analysis of a 13-yr rotation experiment of corn on Brookston clay soil showed that grain yield of corn could be related to each of nine other plant and soil measurements. Soil compaction as measured by bulk density was negatively associated with the level of leaf K in the plants, as well as available soil moisture. The major part of the yield difference between fertilized continuous corn and fertilized corn following alfalfa could be accounted for by multiple regression of grain yield on leaf N and K nutrient levels, soil compaction and soil moisture. Soil compaction was not affected or modified by fertilizer treatment. Response of corn grain yield to soil conditions, moisture and plant nutrient level appears to vary with rotation and fertilizer input.

Description: The dynamics of fixation and release of NH4+ in soils were studied using tracer N under field and laboratory conditions. Field data showed that release of fixed NH4+ was relatively slow after an initial moderately fast release. Forty months of field weathering of Bainsville soil left 3.48 kg 15N/ha in the 75-cm profile of the 13.5 kg 15N/ha applied and most (76%) of this recovered 15N was fixed NH4+–N. The relative quantitative importance of recently fixed NH4+ in the various particle size fractions was not in the same order as the native fixed NH4+. The fine silt fraction (2–5 μm) fixed a larger amount (whole soil basis) than the fine clay fraction (

Description: We used a simple empirical model to predict denitrification rates from measurements of bulk soil properties. Boundary analysis was used to define relationships between denitrification rate and each of air-filled porosity, respiration rate and mineralizable-C content. The ratio of measured denitrifying enzyme activity to the maximum measured value was used to account for variation in amounts of enzymes and numbers of denitrifiers in soil. Nitrate content had little effect on denitrification rate and was excluded from the model. Because the model did not account for microscale variability, it did not accurately predict rates in individual soil cores. Nevertheless, population means and distributions of predicted and measured values were similar. The seasonal patterns of mean values of predicted and measured denitrification rates were also similar over the second half of the sampling period, which extended from May to November. The model did not account for appreciable denitrification on three dates in May. This discrepancy indicated that environmental regulation of denitrification may not be uniform over the season. The model was not sufficiently sensitive to factors influencing episodic events. Key words: Denitrification rate, model, boundary line

Description: Inorganic phosphorus (P) is generally believed to be relatively immobile in Chernozemic soils. However, available P (e.g., Olsen-P) has been found at depth in some soils and this has been postulated to be either the result of leaching or of transportation by plant roots. Lagumes, in particular, are believed to be involved in the latter mechanism. A long-term (34-yr) crop rotation study conducted on a heavy clay, thin Black Chernozemic soil at Indian Head, Saskatchewan, was sampled to a depth of 4.5 m in May and September 1991, to determine the influence of fertilization, cropping frequency, legume green manure and legume-grass hay crops on Olsen-P distribution in the soil profile. The results indicated that Olsen-P may indeed leach in Chernozemic soils, especially when fallow-containing cropping systems are fertilized. It also appeared that deep-rooted legumes, such as sweetclover Melilotus officinalis L.) green manure and alfalfa-bromegrass (Medicago sativa L. — Bromus inermis Leyss) hay crops do increase Olsen-P in the subsoil, possibly through root decomposition in situ. Key words: Rotations, bicarbonate-soluble Pi, legumes, green manure, fertilizers

Description: The effects of cultivation on the net mineralization of carbon and nitrogen in a lacustrine Brown clay (Sceptre) and two Orthic Black soils on glacial till (Oxbow) were assessed with the aid of fractionation and radiocarbon dating techniques. Fractionation of the soil organic matter of comparative virgin and cultivated soils by acid hydrolysis and peptization in dilute NaOH showed that the distribution of carbon and nitrogen among fractions of these soils was similar. There was no measurable alteration in the mean residence time (MRT) of the soil during the first 15 to 20 yr of cultivation, during which time the Sceptre soil had lost 19% of its carbon and the Oxbow, 35%. However, the MRT increased from 250 yr before present (BP) to 710 years BP after 60 yr of cultivation of the Oxbow soil. The losses for nitrogen were 10% lower than for carbon in the Oxbow soil due to the recycling of nitrogen in the soil. The rate of loss of carbon from the Oxbow soil during the cultivation period was simulated by expressing it as the sum of two first order reactions using fractionation and carbon dating data as the variables.

Description: The effects of incubating monocalcium phosphate monohydrate (MCPM) with liquid hog manure (LHM) on P availability and uptake by Italian ryegrass (Lolium multiflorum Lam.) were evaluated in a 99-d growth chamber experiment. Liquid hog manure with (0.738 g P kg−1 fresh LHM) or without MCPM was aerated for a 21-d period at 24 °C. The soils used in this experiment were an Ormstown silty clay loam (Orthic Humic Podzol), and a Ste. Rosalie clay loam (Humic Podzol). Five treatments were applied to each soil: (i) control with no LHM or MCPM additions, (ii) MCPM, (iii) LHM incubated without MCPM, (iv) LHM incubated with MCPM, and (v) the separate applications of MCPM and LHM incubated without MCPM. Rates of MCPM and LHM applications were 513 kg P2O5 ha−1 and 32 t ha−1, respectively. Incubating LHM with MCPM resulted in a loss of 6% of the total manure-N during the 3-wk incubation period, compared with a 67% loss from the unamended LHM. Additions of both MCPM and LHM had the same effect on shoot-P contents and soil P fractions regardless of whether the materials had been incubated together or added to the soil separately. When compared with adding MCPM only, LHM-MCPM mixtures resulted in greater ryegrass shoot-P contents for plants growing on the Ste. Rosalie soil. However, this increase was approximately equal to the response to LHM additions, and thus presumably not due to improved MCPM P availability. Additions of both LHM and MCPM did not affect soil inorganic P forms compared with the lone addition of MCPM, but sodium hydroxide extractable organic P and sodium bicarbonate extractable organic P tended to be higher when just MCPM was added. Key words: P fractionation, liquid hog manure, manure-fertilizer mixtures, monocalcium phosphate, P uptake

Description: Cutans that coat and link sand grains in cemented podzolic B horizons (ortstein) of well and poorly drained podzolic soils from Nova Scotia and New Brunswick were described in thin sections and analyzed by energy dispersive spectrometry (EDS). The principal type of cutan was brown and weakly to moderately anisotropic; it included numerous silt and fine sand grains. X-ray spectra showed this type to be composed dominantly of Al and Si with lesser amounts of K and Fe, and minor amounts of P, S, and other elements. The silt and clay particles of these cutans were apparently impregnated with Al, Fe-organic complexes. Another common type of cutan was dark reddish brown, monomorphic and isotropic; it consisted mainly of Al and organic matter as indicated by dominant Al and weak P and S peaks. In a few samples such cutans were composed mainly of Fe and organic matter. Rarer black cutans contained Mn in various proportions. The dominant cementing material of these ortstein horizons was shown to be organic complexes of Al and, less commonly, of Fe. The genesis of soils with ortstein is discussed.

Description: Wood Mountain loam was wetted with water or (NH4)2SO4 solution to provide a factorial combination among three moisture and three NH4-N levels. Samples in polyethylene bags were incubated at 2.5-cm depths in fallow, and in an incubator that simulated the diurnal patterns of temperature fluctuation recorded in the field. During the growing season, treatments were sampled regularly for moisture, NO3− and exchangeable NH4-N. Similar determinations were made on in situ samples taken in fallow Wood Mountain loam. The incubator simulated the effects of growing season temperatures on soil N transformations satisfactorily. Pronounced increases or decreases in temperature led to flushes in N mineralization. However, in the 1972 growing season, temperature was suboptimal and temperature changes were generally small. Consequently, when a stepwise multiple regression technique was used to analyze the data, neither ammonification nor nitrification showed a quantitative relationship to temperature. Comparison of the nitrification occurring in laboratory-incubated soils with that occurring in situ led to the conclusion that 70 to 90% of the NO3-N produced in surface soil resulted from wetting and drying. Estimates of potentially ammonifiable soil N(No) and its rate of mineralization (k) were derived from cumulative ammonification by assuming that the laws of first-order kinetics were applicable. In the 10, 15, and 20% moisture treatments the average No was 27, 41, and 82 ppm, respectively. Under the conditions of this study, the time required to mineralize half of No was about 7 wk.

Description: An understanding of the mineralization factors in contrasting cultivated soils is necessary for accurate predictions of plant-available N. The objective of this work was to determine the N-mineralization potential and mathematical models that can properly describe the dynamics of the mineralization process in 20 meadow soils from Quebec. The mineralization was monitored over 55.4 wk in a laboratory incubation at 20 °C with intermittent leaching. The cumulative mineralization curves in most soils were characterized by definite lags or a sigmoidal pattern and near-linear release with time after 20 wk. The data were best described by the Gompertz equation; first-order models were inadequate. The total amount of mineralizable N and the potential mineralization rate were very closely correlated with the total amounts of C or N (r 〉 0.73; P 

Description: Acadia or dykeland soils have produced forages successfully for centuries. The formation of barren areas within very productive forage stands has been noted recently in some land-formed fields, indicating either poor germination or poor growing conditions. A survey was undertaken in 1988 to determine the differences in soil attributes between barren and productive areas, namely: topographical position, resistance to penetration, bulk density, pH, plant-available P2O5, -K2O, Ca, and Mg, salt content (as measured by conductivity and sodium adsorption ratio), and exchangeable and soluble Ca, Mg, K and Na. Barren areas had greater: plant-available P2O5, resistance to penetration (the differential ranged from 480 to 1440 kPa), bulk density (in the top 15 cm), salt and sodium content than the productive ones. The exchangeable and soluble Na:Mg and Na:Ca ratios were higher on barren areas than on productive areas. Organic matter content was lower on barren than on productive areas. Values for topographic position, pH, particle size classes and plant-available K2O, Ca, and Mg were similar between the productivity areas. The results of this survey indicate that the formation of barren areas appears to be mainly due to accumulation of excess salts, especially sodium. Reasons for salt accumulation in these areas are discussed. Key words: Acadia soils, dykeland, salt, sodium, organic matter, resistance to penetration

Description: Twelve soil profiles, developed on gravelly parent material, have been sampled in the region of Quebec City and analyzed. Six profiles are developed on sandstones and shales whilst the six other profiles are formed on shales and mudstones. The shales, and to a lesser extent the sandstones, weathered readily to produce a large percentage of clay. Because of this, many B horizons with significant pyrophosphate-extractable Fe and Al do not meet the criteria for a Podzol B. The coarser than 2 mm material, which ranges in individual horizons from 14 to 82% in the first group of soils and from 0 to 84% in the second group, cannot be ignored as it contributes up to 69% of the total exchange capacity of the soil and therefore is important for the natural fertility of the soils. The differences between the stability of the gravel in air and in water also explain some of the problems in classifying these soils.

Description: The salinity tolerance of six annual crop species, wheat, oats, barley, rye, flax and rapeseed, were determined on saline soils that occur north of the Quill Lakes in the northeastern corner of the agricultural area of Saskatchewan. The relative merits of a salt-tolerant grass-legume mixture were also given consideration. The effects of salt stress on spring-sown cultivars became most apparent following exposure to hot, dry summer weather. In contrast, maximum salt tolerance for both winter wheat and winter rye was a function of winterkill. The winterhardiness of both winter annuals was reduced by saline conditions, but winter rye was more adversely affected than winter wheat. Large decreases in seed yield, plant dry weight and height occurred before the effects of increased soil conductivity were expressed for hectoliter weight, 1000-kernel weight, date of maturity, protein content and oil content. Among the spring and winter annual cultivars considered, Bonanza barley and Garry oats demonstrated the greatest salt tolerance. However, where severely saline conditions occurred, mixtures of salt-tolerant perennial grasses and alfalfa proved to be more productive than either barley or oats. The salinity tolerance of all cultivars was greater for years with more favorable growing conditions. It was apparent that stress factors, such as soil salinity, cold, heat, drought, etc., have a cumulative effect in reducing crop performance. This observation emphasizes the importance of minimizing all stress factors when attempting to crop saline soils. Detailed soil analyses indicated that where salts were a problem, the level of salinity was extremely variable, often changing dramatically over short distances. This extreme variability made it difficult to assess the magnitude of the salinity problem. In this regard, crop performance, especially plant height, provided a good indicator for identifying saline areas for purposes of soil testing.

Description: Field studies were conducted on a Landry clay-loam soil (Black Solod) to evaluate the effects of green manuring Tangier flatpea (Lathyrus tingitanus 'Tinga'), lentil (Lens culinaris 'Indianhead') and alfalfa (Medicago sativa 'Moapa') on subsequent barley (Hordeum vulgare 'Galt') crops. Each trial consisted of separate legume phases planted in 1984, 1985 and 1986 and barley phases in each of the subsequent years. The flatpea and lentil were incorporated (green manured) in late July or in late August to early September. The alfalfa was incorporated in late August to early September. The 3-yr mean dry matter (DM) yields of lentil and Tangier flatpea varied from 1047 to 2308 kg ha−1, with considerable variability from year to year. Alfalfa, used as an annual legume, produced 812 kg DM ha−1. Dinitrogen fixation by the annual legumes, as assayed by acetylene reduction was 16 kg N ha−1 or less. Soil moisture measurements following the legumes showed 2–3 cm less water in the profile to a depth of 120 cm following alfalfa and late-incorporated Tangier flatpea than following summerfallow and early-incorporated lentil and Tangier flatpea. Ammonium-N levels in the soil were similar following the various legume green-manure treatments. Nitrate-N levels following the legumes were variable, but the levels of nitrate-N in the plots following legume incorporation generally followed the order: fallow 〉 early incorporation 〉 late incorporation. The grain and N yield of barley following early-incorporated lentil and flatpea were equal to or only slightly less than the yield following fallow, suggesting that annual legumes have a good potential as green-manure crops in place of fallow in Black Solod soils of the Peace River region. Key words: Legume plow-down, soil conservation, dinitrogen fixation, soil moisture, nitrate-N

Description: Possible sources of SO4 in soil, drift and bedrock at two saline sites in southern Alberta were investigated using sulfur and oxygen isotope analyses. Slight differences (0.6–5.2 per mil) between δ34S values of SO4 and insoluble S in the geologic material were attributed to kinetic fractionation during oxidation of organic S. Negative δ18O values of SO4 in the shallow (6 m) bedrock indicated sulfate reduction. The exact source of SO4 could not be determined in this preliminary study. The isotope approach, however, shows promise and warrants more detailed study. Key words: Salinization, sulfates, sulfur isotopes, oxygen isotopes

Description: A survey of efflorescent crusts and associated surface soils in central and southern Alberta was conducted to determine evaporite mineralogy and elemental composition. X-ray powder diffraction indicates that efflorescence mineralogies are dominated by sodium sulfate minerals, such as thenardite and mirabilite. Sodium magnesium sulfate minerals such as konyaite and bloedite are also frequently present, with eugsterite, halite and thermonatrite among other evaporites identified. The content of selected elements in the salt crusts and surface soils was determined using instrumental neutron activation analysis. Trace-element concentrations from site to site were extremely variable. However, comparisons with elemental abundances previously reported for till and soils indicate that there is generally no mean accumulation of trace elements in salt-affected soils. Exceptions are Br and Cl, which show enrichment in soils infused with soluble salts. Key words: Salinity, trace elements, evaporites, mineralogy

Description: The distribution of selenium (Se) in 54 Canadian soil profiles was examined according to horizon in the profile, and to soil properties. Apart from the organic surface layers, the Podzolic B horizons had the highest Se values (0.52 ppm), and so displayed a marked accumulation. The Luvisolic and Gleysolic B horizons also showed some accumulation. The Se content of parent materials was generally low (0.10 ppm). Simple correlation analyses of the combined data (irrespective of horizon) indicated that Se distribution was closely associated with both organic carbon and NH4-oxalate extractable Fe and Al. When the data were arranged according to genetic groupings, this association remained true only for Podzolic B horizons. Multiple regression analyses revealed that the predominant factors involved in the Se distribution were the Se content of parent materials, and the organic carbon content of the upper horizons, in that order, except for Podzolic soils. Clay had little or no influence on the Se distribution. In spite of the relationship of Se to parent materials, the contribution by atmospheric contaminants to the Se enrichment of soils could remain important.

Description: Fluorescence excitation spectra of fulvic acid (FA) and humic acid (HA) were recorded at different pH as well as at different netural salt concentrations. Spectra of both FA and HA exhibited distinct bands at 465 nm, while spectra of FA showed additional bands at 360 nm. Fluorescence intensities decreased with decreasing pH and increasing ionic strength. This is due to decreasing ionization, increasing particle association, and to coiling of macromolecular structures. The fluorescence characteristics of FA and HA were observed to be related to the free radical content, color, and phenolic structures. Our data show that fluorescence excitation spectra can be utilized for differentiating between soil FA and HA.

Description: The distribution, composition and nature of concretions occurring in some moderately well-drained to poorly drained soils of Saskatchewan were investigated. The soils selected were: Gleyed Humo-Ferric Podzol, Orthic Luvic Gleysol, Orthic Gray Luvisol and Gleyed Gray Luvisol. The concretions range from  15 mm in diameter and are distributed throughout the sola with maximum concentrations of about 8% in Aeg and Bf horizons. The data indicate that the concretions from Gleysolic and Gray Luvisolic soils are markedly higher in Fe, Mn and P than the surrounding soil matrix; concretions from the Podzol are high in Fe but very low in Mn and P. Mn is directly related to the size of concretions whereas Fe and P contents generally increase with decreasing size of concretions. The formation of concretions and their significance in soil genesis are discussed.

Description: Many measurements of oxygen flux in mineral soils have been reported; however, few such measurements have been made in organic soil. Almost all reported measurements of oxygen flux are at constant applied voltage, despite criticism of this technique, possibly due to the complexity of existing techniques for measuring oxygen flux at effective voltage. Equipment suitable for measuring oxygen flux at applied and effective voltage in organic soil was designed, and simplified techniques were developed and tested. As reported for mineral soils, soil resistance is relatively constant spatially and with depth in individual soils. Limited poisoning of the platinum electrode surface occurred after long periods of time and, contrary to previous assumptions, cannot be detected by erratic readings. Unlike mineral soil, the amperage-voltage slopes are constant over a wide range of organic soils, simplifying the technique for estimating oxygen flux at constant effective volatage. Comparison of simultaneous measurements of oxygen flux at constant and effective voltage indicates that oxygen flux measurements at effective voltage were twice those at applied voltage and strongly correlated (r2 = 0.96, n = 22).

Description: Soil respiration during the growing season was calculated from CO2 profiles in a heavy clay soil under native grass and on cultivated plots. Soil respiration of the native grass plots was correlated with moisture content and temperature of the surface soil. However, the correlation accounted for only ⅓ of the observed variation in soil respiration and could not explain the large difference between two growing seasons. Addition of mineral N decreased soil respiration and irrigation increased it. Total soil respiration on the cultivated plots was higher than on the native grassland. On the wheat plots, soil respiration was significantly correlated with soil moisture but not with temperature; the reverse was true for the fallowed plots. Soil respiration between 1 May and 1 September on the native grassland was highly correlated with rainfall and the number of days with rain in excess of 5 mm. It was concluded that the number of wetting and drying cycles in the soil was mainly responsible for the annual variation in soil respiration. From comparison with data on shoot production, it appears that soil respiration exceeds net production in wet years and that the opposite is true in dry years.

Description: A simple power-function equation was developed to relate changes in soil 137Cs with time to an average annual soil-loss rate. The equation accounts for tillage dilution of the concentration of 137Cs in the surface plow layer and for enrichment in the eroding soil. The predictions from the relationship were similar to values for a more complicated model and to measured values given in previous studies. Key words: Erosion rate, prediction, cesium-137

Description: Potassium mine refinery dust at rates from 1.12 to 11.2 ton/ha (½ to 5 ton per, acre) was applied to a Dark Brown Chernozemic silt loam and to a Black Chernozemic loam. Under dryland farming conditions, no significant effects on yields of cereal grains have been recorded. After 5 years there is no indication that any K has moved deeper than 46 cm (18 inches). The chlorides have been removed from the surface soil and about 50% have leached to below 213 cm (7 ft). The K replaced some of the exchangeable Ca and Mg which were subsequently leached to lower depths. Much of the added K is now in the exchangeable form; some may have become fixed in the clay lattice.

Description: The impact of cultural practices on soil aggregate characteristics which determine the susceptibility of the soil to wind and water erosion was studied at two long-term (〉 30-yr) crop rotation sites on Black Chernozemic soils at Indian Head and Melfort, Saskatchewan. Surface soil (top 5 cm) taken in spring and fall, 1991, was air-dried and sieved by rotary sieve to measure aggregate size distribution. The water-stability of soil aggregates (1–2 mm) was determined after: (i) slow wetting, and (ii) fast wetting. Both rotation studies employed conventional tillage management until 1990 when the Indian Head experiment was converted to zero-tillage. Summerfallowing increased the wind-erodible (

Description: An improved procedure for measuring water retention curves at low suction (0–300 mbar) by the hanging-water-column method is described. The proposed method produces curves obtained on the same sample over the whole range of measurements. Good agreement was found between data measured by the proposed technique and those obtained by a conventional pressure plate technique.

Description: The long-term effects of wood-residue applications on soil properties are not well documented. This study was undertaken to characterize the organic matter and aggregation of a sandy loam after 9 yr of biennial application of wood residues (tree clippings) at rates of 25, 50 and 100 Mg ha−1 with and without nitrogen fertilization. Carbon (C) and nitrogen (N) contents of the whole soil were determined as well as the C content of the density fractions and of the fractions soluble and insoluble to Na4P2O7. In comparison with the control, the whole-soil C content was 16–24% higher following application of wood residues alone and 16–37% higher for application of wood residues supplemented with nitrogen. The treatments had no effect on soil water-stable macroaggregation (〉 250 μm). Wood-residue applications had no effect on the humic material (soluble in Na4P2O7) but favored the humin-C content (the fractions insoluble in Na4P2O7) by 25–60% relative to the control. The light-fraction organic matter was on average 68% larger, and the heavy fraction 17% larger, in the treated soils than in the control. On average, 80% of the differences in total organic C induced by residue application could be attributed to differences in the humin and heavy fractions. The long-term effect of wood-residue applications to the soil was, therefore, reflected in an accumulation of the more stable organic matter present as heavy and humin fractions. In addition, the differences in the light fractions suggested a short-term effect of wood-residue applications.Key words: Light and heavy fractions, wood residues, organic C, water-stable aggregates, humic acids, humins

Description: An increase in wheat yield in 1977 on an Elstow silt loam to levels slightly greater than those of the checks was obtained on dolomite-treated (11.2 and 22.4 t/ha) plots that had formerly received 17.9 and 33.6 t/ha KCl dust, and had subsequent wheat yield reductions of 21 and 53% in 1973, and rapeseed yield reductions of 19 and 25% in 1975. Water-soluble and NH4 Ac-extractable K in the surface horizons were increased by high application of KCl, and the Ca and Mg were reduced; K was not increased below the 55-cm depth. An application of 33.6 t/ha KCl had made this soil, below 45 cm, slightly saline due to Ca and Mg from the upper horizon’s exchange complex, and Cl from the added KCl. Eighteen months after the application of dolomite, K was slightly reduced, Ca mainly restored, and Mg partly restored in the surface 15 cm of this soil. Forty percent of the Cl applied with 33.6 t/ha KCl had leached beyond 213 cm by 1976. An upward movement of Ca and MgCl occurred during 1977.

Description: Much forested land in the wetter zones of northern Vancouver Island is characterized by thick humus layers, with two distinct ecosystem phases: the younger "HA" phase arising from disturbance is productive after clearcutting, but in the old-growth "CH" phase, seedlings suffer growth check after 5–8 yr, with reinvasion of the ericaceous shrub salal (Gaultheria shallon Pursh.). We used solid-state 13C nuclear magnetic resonance (NMR) spectroscopy and CuO oxidation to examine whether chemical differences in the humus might be associated with difference in forest productivity after clearcutting. NMR spectra of woody horizons, which were similar for CH and HA sites, were dominated by signals from lignin of decomposed wood. Non-woody humus types were typical of forest litter layers, and were dominated by signals in the O-alkyl region. The differences between CH and HA sites were: (i) higher tannin content in the CH sites, most likely from salal inputs and (ii) higher ratio of carbohydrate to lignin C, indicating less effective decomposition in CH sites. Oxidation with CuO also showed more advanced decomposition in the non-woody horizons of HA than of CH sites. Less effective decomposition possibly due in part to tannin accumulation could contribute to the lower forest productivity on salal-dominated CH sites in this region. Key words: 13C NMR, CuO oxidation, decomposition, humus, tannin, salal

Description: Development of Typic Haplorthods in a heathland area in Denmark responded over a short period of time (decades) to changes of vegetation. Part of the heath, Hjelm Hede, was left undisturbed and was invaded by trees, mainly oak and a few aspen and conifers. Another part of the heath was planted with Norway and Sitka spruce 60–70 yr ago. The soils under heath, oak and spruce were studied. Major differences were found, some visible in the field and others detectable in the laboratory. Under oak, relative to heath, horizon boundaries were less distinct, pH increased in the top horizons, organic carbon and C/N ratio decreased, and iron and aluminum contents in the upper B horizons decreased. Compared with the original heath podzol, the soil under spruce had a lower pH in the O, E and upper B horizons, higher organic carbon content and C/N ratio in the top horizons, increased cementation, and a placic horizon. However the pyrophosphate-extractable iron and aluminum content was significantly lower than in any of the other soils. The soil under oak showed "depodzolization" features, whereas the soil under spruce was increasingly podzolized, though the podzolization mechanism might be different from that under heath. Analyses of phenolic compounds in the soil water were consistent with these conclusions. The three main components of substituted benzoic acids were gallic acid, protocatechuic acid and coumaric acid, which are all strongly complexing agents believed to take part in the podzolization process. Generally, the highest concentrations were found under spruce and the lowest under oak.Key words: Vegetation-induced soil changes, Spodosols, phenolic compounds

Description: The concentration, contents, and distribution of nutrients, metals, and soil materials were quantified at the Howland Integrated Forest Study (HIFS) site in eastern Maine. The site is a mature, low-elevation spruce-fir forest on Podzolic soils developed from dense basal till. Standard morphologically based soil sampling and quantitative soil pits were both used to characterize the soil component of this ecosystem. Vertical trends in nutrient concentrations at the site were largely governed by the distribution of organic matter. Standard morphological soil sampling techniques tended to overestimate soil pools of labile cationic nutrients and C, and underestimate trace metals and P, as a result of underestimations of coarse fragment content. These discrepancies can be critical if extrapolations for nutrients, metals, and C are made using existing databases to regional or global scales.Key words: Forest soils, spruce-fir, quantitative pits, sample size

Description: Methane oxidation by soils is an important sink for this greenhouse gas. When tested at 50 mg L−1, the herbicide bromoxynil, the insecticide methomyl, and the nitrification inhibitor nitrapyrin inhibited methane oxidation by soil slurries. The results suggest that these chemicals might decrease methane oxidation by agricultural soils. Key words: Soil methane oxidation, inhibition, agrochemicals

Description: Mixtures of ammonium nitrate and ammonium polyphosphate fertilizers were used to drip fertigate Summerland McIntosh apple trees (Malus domestica Borkh.) grown on M.9 rootstocks in gravelly sandy loam. Levels of N corresponding to 25 and 50% of the recommended broadcast rate (23.5 and 47.0 g tree−1, respectively) and three levels of P (0, 17.5 and 35.0 g tree−1) were applied in a factorial randomized complete block design. Soil acidification began within 1 yr in a zone extending approximately 60 cm vertically and horizontally from the drip source. Acidification was most severe at 20–30 cm directly beneath the emitter where the soil pH decreased from 5.8 to 4.5 after 1 yr and to 3.7 after three seasons of fertigation. Rate and magnitude of pH decline were equal for both rates of N and acidification was not enhanced by the simultaneous addition of P. Calcium, Mg and K were leached to the periphery of the acidified zone. The rapid displacement of K may be of concern, particularly when NH4 forms of N are drip-fertigated in coarse-textured soils with marginal K levels. Key words: Fertigation, soil acidification, cation leaching, nitrogen fertilizer

Description: To better understand environmental regulation of denitrification, we examined relationships between denitrification rate and six determinant soil properties: moisture content, air-filled porosity, NO3− content, respiration rate, mineralizable-C concentration and denitrifying enzyme activity (DEA). Soil cores were collected on 27 sampling dates over a growing season at a site seeded to barley (Hordeum vulgare). Denitrification rate was measured using a static core technique and acetylene blockage. Moisture content and air-filled porosity and, to a lesser extent, mineralizable-C concentration and respiration rate were more strongly related to denitrification rate than was DEA. Denitrification rate was unrelated to NO3− content. On most sampling dates, mean denitrification rate increased substantially only below an air-filled porosity of 0.3. Moreover, the distribution of individual measurements of denitrification rate was less skewed at lower air-filled porosities. Approximately 60% of variation in mean values of denitrification rate for each sampling date could be accounted for by measurements of bulk soil properties, of which moisture content and air-filled porosity were most important. Measurements of bulk soil properties did not account for nil values of denitrification rate at low air-filled porosities or for small-scale spatial variability. Such measurements were better indicators of temporal variation — that is, when denitrification occurred — than of actual rates. Key words: Denitrification, air-filled porosity, denitrifying enzyme activity

Description: A study was made of the effects of temperature and different microorganisms, or mixtures of microorganisms, on the changes in the nitrogenous constituents of mixed forest litters (mixed pine, oak, maple) during decomposition periods of up to 4 yr at 1, 4, 10, and 27 C. The percentage of total-N in the decomposing materials increased with time, the increase being related to loss in weight of sample. The percentage of amino-N/total-N was higher with the soil-extract-treated leaf mixture than with the fungi-inoculated material; it increased to a maximum at some intermediate period, then decreased, and was highest with the 930 day 27 C material. Most of the individual amino acids increased in amount up to 930 days; then decreased, the amounts being, in general, higher with higher temperatures. Much of this increase was related to loss in weight of sample, but there appeared to be some net synthesis of amino acid. Lysine and, to a lesser extent, histidine were exceptions to this generalization. The amounts of hexosamines increased with decomposition: with the soil-extract-treated materials the increase of galactosamine was relatively greater than that of glucosamine, but little or no galactosamine was found in any of the fungi-inoculated materials. The amino acid ratios, i.e., the proportion of one relative to another, did not change in any consistent fashion, except for lysine. With the fungi-inoculated material, autoclaving reduced the amount of lysine to less than one-half and a ninhydrin-reacting material appeared before arginine on the amino acid chromatograms; its amount was not changed during decomposition. It may be similar to lysine derivatives found in acid hydrolyzates of heated milk.

Description: Three tillage treatments were evaluated over a 4-yr period for their effects on runoff and soil loss under natural precipitation on a Donnelly silt loam soil (Solonetzic Gray Luvisol) near Dawson Creek in the Peace River region of British Columbia. Conventional-tilled (CT) plots (spring or fall cultivation) received twice the amount of tillage as the reduced-tilled (RT) plots, while the zero-tilled (ZT) plots were only disturbed at seeding once a year. The plots were seeded to barley (Hordeum vulgare L.). Rainfall and snowmelt runoff were collected throughout the year to determine seasonal runoff and soil losses. The effects of the tillage treatments on runoff and soil loss depended on the season (whether caused by rainfall or snowmelt) and the crop year. Mean snowmelt runoff was ZT 〉 CT 〉 RT. Conventional tillage had significantly higher rainfall runoff and soil loss from snowmelt than the other two tillage treatments, with no significant differences between RT and ZT. Mean rainfall-induced soil loss was significantly different for each tillage treatment, with CT 〉 RT 〉 ZT. Soil losses from snowmelt were low, less than 30% of those from rainfall, since snowfall was 45% below normal. Soil losses from rainfall were consistently higher than from snowmelt for each tillage treatment in each of the four crop years and provided over 75% of the 4-yr total annual soil loss. Tillage effects were more pronounced in years with low runoff and soil loss than in years with high runoff and soil loss. Zero tillage and RT are effective in reducing average annual soil losses by 81 and 53%, respectively, of those observed under conventional tillage. Key words: Runoff, soil loss, erosion plots, seasons, tillage

Description: Humus fraction distribution in a wide range of horizon samples was examined by measuring carbon content in humic acid (Ch), in fulvic acid (Cf) and in the strongly colored polyphenolic component of the fulvic acid fraction (Ca). Fraction distribution was described by the ratios Ch/Cf and Ca/Cf. It was concluded that humus fraction ratios were related to horizon types as used in the Canadian System of Soil Classification, and were effective in discriminating between certain horizon types, particularly between Luvisolic Bt and Podzolic Bf. The results also suggested that humus fraction ratios may be effective in separating distinct sub-populations within Ah horizons and Bf horizons in general, based on qualitative differences in organic matter present. Aspects of the role of humus fractions in soil genesis are discussed.

Description: Growth chamber and laboratory studies of four selected soils differing in C:N:S ratios and the percentage of total S present as HI-reducible S in the soil organic matter showed that: (1) the yield response of alfalfa to applied S occurred when the 0.01 M CaCl2-extractable soil SO4—S was less than 3.3 μg/g, (2) mineralization of soil organic S was unaffected by the addition of 25 μg S/g to the soils, and (3) the amount of S mineralized was not directly related to the quantity of total S, HI-S or the percentage of total S present as Hi-reducible S. It was noted that the largest amount of S mineralized occurred from the soil with the lowest C:N:S ratios.

Description: Growth chamber studies were conducted on the relative effects of various placements of NH4H232PO4 applied at 20 kg P ha−1 in a single band away from the seed on growth, and on uptake of soil and fertilizer P by flax (Linum usitatissimum L. ’Linott’) grown on two P-deficient Chernozemic soils; one calcareous, the other non-calcareous. Crop response was very sensitive to location of the placed P. Placement of the P away from, and up to 3.0 cm to the side and from 0–4.5 cm below the seed on average increased aboveground dry matter yield and P uptake of flax 8 wk after seeding by 2.3- and 2.1-fold, respectively, compared with the non-P fertilized soils. Maximum yields and P uptake, which were approximately four and three and a half times greater, respectively, than the non-P fertilized values, were achieved by placing the P no more than 1.5 cm to the side and 1.5–3.0 cm below the seed. Flax root development studies indicated that this was due largely to root development during the first few weeks being limited to a small cylinder of soil immediately surrounding the single vertical tap root. Distance of placement of P away from the seed was more critical for the calcareous soil, with crop use of the applied P being noticeably less for this soil (4.8–17.3%) than for the non-calcareous soil (18.3–40.2%).

Description: Three non-replicated, non-fertilized, dryland grain rotations — continuous wheat, wheat-fallow, and wheat-wheat-fallow — were established in 1912 on a Dark Brown Chernozemic soil. In 1967, the rotations were altered to include an annual application of 45 kg N/ha to a portion of each field. Above- and below-ground organic residue and soil were sampled in September 1975, April and August 1976, and April 1977 from both the fertilized and non-fertilized treatments of each rotation to measure the effects of the rotations on a number of chemical characteristics. The soil samples were analyzed for pH and contents of C, N, ethanol/benzene- and resin-extractable C, polysaccharides, and waterstable aggregates. The organic residues were analyzed for contents of C, N, ethanol/benzene-extractable C, lignin, and methoxyl groups, and for caloric content. The soils of the continuous wheat rotation contained the most C, total N, and polysaccharides, whereas the soils of the wheat-fallow rotation were about 12 percentage points higher in resin-extractable C than those of the continuous wheat or wheat-wheat-fallow rotations. The cultivated soils contained 47% less C, 46% less N, 53% less polysaccharides, 100% more solvent-extractable C, 49% more resin extractable C, and a slightly higher pH than the soils from the proximate native grassland. Individual rotations had little effect on the chemical composition of organic residues on the soil surface but did affect the decomposition and nature of subsurface plant residues.

Description: In the Canadian prairie, producers generally sample soils in the autumn for nutrient analyses, whereas calibration of crop responses has been made based on soils sampled in the spring prior to seeding. A recent report suggests that available phosphorus (P) in soil increases between autumn and spring. At Swift Current, Saskatchewan, we have monitored bicarbonate-extractable P (Olsen P) every autumn and spring for the past 24 years, in four cropping systems: continuous wheat (Cont W), fallow-wheat (F-W), and two fallow-wheat-wheat (F-W-W) rotations. The first three systems received nitrogen (N) and P each crop year, with one F-W-W rotation receiving only N. These data were analyzed to test the authenticity of the aforementioned observations. We found that although there were some apparent overwinter increases in Olsen P there were also some decreases. Further, because of the considerable variability in Olsen P, relatively few of the overwinter changes were significant (P = 0.10). Efforts to correlate the changes in Olsen P to overwinter temperature or precipitation were unsuccessful. We concluded that Saskatchewan soil testing laboratories need not make adjustments to P fertilizer recommendations to account for changes in overwinter soil test P levels. Key words: Soil testing, bicarbonate-extractable P, crop rotations, available P

Description: A method to obtain relatively large portions of particle size separates from soil is described. The method was designed to minimize dilution of the soil with dispersant solution, to use simple materials and operations, and to allow fractionation of a single soil sample into a broad range of size classes. These are advantages over elutriation or batch sedimentation methods, and are important when obtaining size separates for studies of contaminant behaviour, erodable soil materials and other related topics. The method is ideally suited to study of contaminant concentrations on soil particle size separates. Key words: Sedimentation, size fractionation, clay, silt, sand, contaminants

Description: To assess the extent to which moist color value of forest mineral soils supports their differentiation according to concentrations of mineralizable and total N, 239 samples of 0–30-cm mineral-soil layers were examined for the relationship between nitrogen measures and selected categorical climatic and soil variables. The best regression models, using soil color value (SCV), climate, soil moisture and soil texture as categorical variables, explained nearly 70% of the variation in both mineralizable and total N, with climate accounting for most of the variation. The results provided support for the present usage of SCV in estimating mineralizable and total N in forest soils but suggested improvements for the development of a more effective estimation procedure. Key words: Forest soil color, soil nitrogen, climate, soil moisture, soil texture, regression analysis

Description: Field studies were conducted on Prince Edward Island (PEI) at two locations over a period of 2 years on the effect of soil and foliar applied Co on Co concentration in forages and cereals. Application of Co did not affect crop yields, although the yields varied considerably from location to location (data not reported). The Co concentration in cereal grain ranged from 10 to 25 μg kg−1 in the control plots. With foliar-applied Co, maximum Co concentrations in wheat, barley and oat grain were 101, 70 and 29 μg kg−1, respectively, in the three crops. In forages, large increases in Co were found in the first cut using foliar sprays but in the second cut the Co increases were small and significant only in one-half of the cuts. Soil applications of Co at 150 g ha−1 were ineffective in raising the grain Co but in forages Co was significantly increased in about one-third of the cuts. The mean Co concentration in forages and cereals from various fields in PEI ranged from 13 to 28 μg kg−1; such levels are considered deficient for livestock. In the case of suspected Co deficiency, 60 and 100 g Co ha−1 applied as a foliar spray to forages and cereals, respectively, should raise the feed crop Co concentration in the sufficiency range for livestock. Key words: Cobalt, wheat, barley, oats, alfalfa, timothy

Description: The capacity of soils to oxidize S was measured by incubation with finely divided elemental S in 13 calcareous orchard soils from the southern interior of British Columbia. Sulphur oxidation rates ranged from 3.4 to 26 μg S cm−2 d−1. The magnitude of pH decrease in response to added S varied inversely with initial CaCO3 content (r = − 0.58, P = 0.04) and silt content (r = − 0.64, P = 0.02) and directly with sand content (r = 0.64, P = 0.02). Incubation studies with one calcareous orchard soil indicated that finely divided S was more effective over time than other acidulants (FeSO4, Al2 (SO4)3 and H2SO4). A field study was carried out on the same soil. Finely divided and bentonitic granulated S were applied at 4.5 t ha−1 on the grass surface or incorporated to a depth of 15 cm. Incorporated fine S was oxidized to a much greater extent during a 2-yr period than was incorporated grandulated S. However, when surface applied, they were oxidized equally but slowly. Key words: S incubation, acidulating materials, S oxidation, soil pH, electrical conductivity

Description: The effect of timing of application on the recovery of fertilizer N applied to irrigated soft white wheat (Triticum aestivum L.) was investigated in a 3-yr field study and a 1-yr lysimeter study using 15N-labelled urea and ammonium nitrate. Fertilizer N treatments consisted of a check and 90 kg ha−1 applied as preplant N, postplant N or combinations. Under a controlled watering regime in the lysimeter experiment, timing of N application had no effect on plant growth parameters. In the field studies, although grain yield was not affected by N timing, grain N concentration increased from 17.9 to 19.6 g kg−1 as the proportion of postplant N was increased from 0 to 100%. Plant N uptake was greater when all of the N was applied postplant than preplant (means = 124.5 and 114.2 kg ha−1, respectively) in the field studies. Plant recovery of fertilizer N (FNR) by the difference method was greater when all of the fertilizer N was applied postplant (43.7%) man preplant (28.6%) in the field experiments. With a negative apparent added N interaction (ANI), the FNR was less by the difference method than by the 15N method. However, with a positive ANI, FNR was less by the 15N method than by the difference method. There was a greater difference between methods as the proportion of N applied as postplant N increased. Key words: Fertilizer N timing, irrigation, soft white wheat, nitrogation, fertilizer N recovery

Description: The effect of hexazinone (applied as Velpar L.) on carbon dioxide (CO2) evolution, nitrogen (N), phosphorus (P), and sulfur (S) mineralization in a surface organic layer (L–H horizons) of a forest soil was followed during a 150-d laboratory incubation. Hexazinone was applied at recommended field rates equivalent to 2 and 4 kg a.i. ha−1 and at a higher rate, 8 kg a.i. ha−1. A bioassay determined that hexazinone at 4 and 8 kg a.i. ha−1 affected the root and shoot biomass of oats for up to 63 d after application. Hexazinone had no effect on CO2 evolution, ammonification, nitrification or net S mineralization in the L–H horizons. An increase in extractable P was found in the hexazinone-treated soils at the end of the incubation. Hexazinone applied at recommended field rates of 2 and 4 kg a.i. ha−1 would have little direct impact on nutrient-cycling processes in the L–H horizons of mixed-wood cutovers. Key words: Hexazinone, carbon dioxide evolution, nitrogen, phosphorus, sulfur, forest soils

Description: 137Cs in the soil was used to estimate soil erosion at two National Soil Conservation Program benchmark sites in the province of Quebec (sites 15-QU and 16-QU). The 137Cs baseline in an uneroded forest area was approximately 3100 Bq m−2. The 137Cs content at site 15-QU ranged from 1072 Bq m−2 to 6389 Bq m−2, while at site 16-QU it ranged from 663 Bq m−2 to 5444 Bq m−2. Computed net erosion over the past 30 yr at site 15-QU varied from a loss of 9.65 kg m−2 yr−1 to a gain of 10.88 kg m−2 yr−1 and at site 16-QU from a loss of 6.38 kg m−2 yr−1 to a gain of 1.73 kg m−2 yr−1. The average net erosion rates were 2.43 kg m−2 yr−1 at site 15-QU and 1.29 kg m−2 yr−1 at site 16-QU. Soil samples collected on a grid pattern indicated that 90% and 83% of the area at sites 15-QU and 16-QU, respectively, was subjected to net soil loss. A comparison of total 137Cs movement from eroded areas to depositional areas showed that 24.2% of 137Cs was lost from site 15-QU, while about 17.6% of 137Cs was lost from site 16-QU. Mapping of 137Cs content and calculated soil loss and deposition showed that soil erosion was closely related to topography.Under similar slope conditions, the soil erosion rates were 27–68% higher at site 15-QU than at site 16-QU. Higher tillage frequency and use of silage corn were the suggested reasons for the higher soil erosion rates at site 15-QU compared with site 16-QU, which had been used for hay and small grains. Key words: 137Cs, erosion, deposition, soil conservation

Description: The objective of this study was to document the effect of forest invasion on Black soils of the Aspen Parkland in Saskatchewan. A prairie-forest transition zone less than 100-m wide was studied in an upland landscape (LM) with a strong eluvial regime and a lowland landscape (WQ) where strong leaching was restricted to depressional areas. A direct count of grass opal along each transect provided evidence that forest vegetation had invaded prairie as similar amounts of grass opal occurred under forest and prairie. Soil morphology and horizon development could be related to microrelief and to site productivity as inferred from grass opal content along the transects. Forest invasion affected soils differently in the two landscapes. At LM, forest invasion was accompanied by losses of clay and organic materials as soils were progressively transformed into leached and more acidic Luvisolic soils. Eluvial and illuvial development occurring under forest were most pronounced in microdepressions and concave portions of the transect. At WQ, leached acidic soils occurred only in a depression. Forested soils outside the depression maintained high levels of organic matter and high base status comparable to adjacent prairie soils. Alteration of Black soils following migration of forest vegetation onto prairie depends on large scale physiographical effects as well as smaller scale microrelief effects. This study indicates landscape control of water movement plays a vital role in soil development and regulation of ecosystem processes. Thus, the relationship among water, soil and landscape must be considered in environmental research and environmental impact studies. Key words: Prairie-forest transition, forest invasion, Aspen Parkland, biogenic opal, soil-landscape relationships

Description: The use of inter-row ground covers has been suggested to reduce soil degradation in raspberry (Rubus idaeus L.) production. The effect after 6 yr of consistent inter-row management of ground covers or roto-tillage in raspberry on soil wet aggregate stability (WAS), bulk density, organic C and total N, and mineralizable nitrogen in the Fraser Valley of British Columbia was studied. Management treatments included no cover crop or cover crops of barley (Hordeum vulgare L.), sheep's fescue (Festuca ovina L.), perennial ryegrass (Lolium perenne L.), and white clover (Trifolium repens L.). A general pattern of perennial grasses 〉 legume and barley 〉 control was observed for soil WAS. Some quantitative and qualitative differences in the organic component of the soil profile to 30 cm were detected among management treatments. The differences were not statistically strong because the changes were small relative to the large pool present, but were relatively consistent overall. The white clover treatment tended to have more organic carbon, particularly in the subsurface, than the other treatments. The four treatments that included inter-row vegetation tended to have a greater amount of total and mineralizable N than the clean-tilled control. Crop vigour, as indicated by cane diameter, was reduced by the perennial grasses, but the inter-row management had only limited effects on berry yield. White clover appears to provide the best compromise between improving soil quality and minimizing competition with the berry crop. Key words: Wet aggregate stability, barley, sheep's fescue, perennial ryegrass, white clover

Description: Three years after disturbance of soil, by digging sample pits to a depth of 1 m, soil at a depth of 85–95 cm had greater air porosity and greater total porosity than previously and soil strength of disturbed soil was much less than strength of the undisturbed side wall. At a depth of 25–35 cm, air porosity was increased and soil strength was decreased. Disturbance of wet soil tended to have less beneficial or detrimental effects. These data suggest than Berwick and Kentville sandy loams would be amenable to improvement by deep tillage provided moisture conditions were favorable.

Description: Atomic absorption analyses of pyrophosphate extractions of B horizons from some Luvisolic, Gleysolic and Solods had higher Fe and Al contents when using 0.1% Superfloc and low speed centrifugation than those obtained when using 0.2% or 0.5% Superfloc or when using high speed centrifugation. Laboratories not equipped with a high speed centrifuge should use a method other than Superfloc to clarify the solution or use the recommended colorimetric method.

Description: The inorganic clay constituents of the B horizons of three Podzolic soils from British Columbia were analyzed by X-ray diffraction, infrared, electron-optical and chemical methods. The amorphous inorganic constituents comprised from 51 to 82% of the clay in these Podzol B horizons. Quartz, feldspar, chlorite, and vermiculite were the dominant minerals in the crystalline portion of the clay. Infrared spectra suggested the presence of appreciable amounts of imogolite in the fine clays of the three soils. Electron optical evidence confirmed its presence in small amounts (

Description: The internal drainage of a saline-sodic soil having till at 51 cm from the surface was studied in the field and laboratory. Average water intake (infiltration) for the profile was 3.76 cm/day. The Btj could be a limiting factor for vertical flow. The horizontal hydraulic conductivity indicated that lateral flow of water in the C horizon (36 cm/day) and surface of the till (22 cm/day) could be as much as five times greater than that of the Ah (5 cm/day) and Btj (8 cm/day) horizons. Salts were leached from the profile by the 22 cm of water that had been applied. It was concluded that the internal drainage of the soil was sufficient to accommodate infiltrated water under normal conditions, and that the buildup of a water table and salinization of the soil were probably due to lateral flow of water from canal seepage and irrigation mismanagement.

Description: These calcareous brown soils are low in organic matter. The clay and carbonate content increase with depth. Carbonate percentage ranges from 1.7 to 27.5% and the accumulation is found between 45 and 105 cm from the soil surface. Sulfate exceeds chloride ions in the soil extract. The exchange capacity, varying from 8.2 to 27.9 meq/100 g of soil, increases with depth. The major clay mineral is vermiculite and the maximum percentage is found in the lower horizons, while illite, which is the second clay mineral in these soils, decreases with depth. There was a relationship between K+ fixation and the content in clay and vermiculite. K+ fixation, which represents 7–11% of the cation exchange, is also enhanced by the drying of the soil.

Description: Four series of agricultural soils of Quebec were sampled in the Lowlands on drained and undrained sites in order to investigate the effect of long-term internal drainage on the physical and chemical properties of the profiles. Change in structure was observed in the Ste-Rosalie soils. A massive layer found below 18 cm in the undrained profile was replaced by a more structured layer at greater depth in the drained profiles. Occurrence of mottles down to the Cg horizon reflected the better aeration conditions in the drained sites. Saturated hydraulic conductivity values were sometimes higher and sometimes lower than those measured in the undrained profiles. Below the plow layer, the two profiles drained for more than 50 yr had a cation exchange capacity 12–15% higher than the undrained profiles. Oxalate-extractable iron represented a high percentage of the dithionite-extractable iron and indicated a low rate of formation of crystalline pedogenic oxides. Mn accumulations were found in the more compact layers. The improvement of internal drainage requires a soil management that will enhance soil structure.

Description: Forty-nine sandy soils developed in till, outwash, alluvium and marine sands were studied to determine the effect of mode of deposition on soil development and to classify the soils according to the Canadian and U.S. classification systems. Forty-three of the soils met the morphological and chemical criteria of Humo-Ferric Podzols but none of these was a Spodosol because the ratio of pyrophosphate-extractable Fe + Al to clay in the B horizon was below 0.2. Mode of deposition had only a minor effect on soil evolution. However, B horizon development was strongest in the till soils, perhaps because of their somewhat finer texture and greater age. A pronounced maximum of clay occurred in the B horizons of the Podzolic soils; commonly, clay in the B exceeded that in the A and C by a factor of 2–5. A higher pyrophosphate Al/Fe ratio was found associated with soils low in total pyrophosphate Al + Fe and vice versa. It was also found that pyrophosphate Al + Fe was positively correlated with total organic C (r = 0.891).

Description: Analysis by energy dispersive X-ray spectrometry (EDS) of cutans linking grains in coarse-textured duric horizons with plectic fabrics indicated that Al-organic material was a component of the cement. (Al, Fe)-organic material occurred in voids near the upper surface of duric horizons with porphyroskelic fabrics but EDS was not useful in detecting the cement of such horizons. Ground (2 mm) sandy loam C horizon material from a soil with a dense duric horizon was cemented strongly by as little as 0.1% (Al + Fe) precipitated with Na2 SiO3. Results of this and previous studies suggest that various combinations oa Al, Fe and Si hydrous oxides and humified organic matter act as cementing agents of duric horizons and that very little cement is required to indurate closely packed materials.

Description: The effect of degree of decomposition and depth of sampling on gamma probe wet bulk density measurements was investigated for two organic soils. Sampling depth did not significantly affect the probe calibration. In situ calibration must be done rather than in laboratory.

Description: The neutral monosaccharides released by the acid hydrolysis of five peat profiles were analyzed by ion exchange chromatography and gas-liquid chromatography in order to ascertain whether monosaccharide composition can be used to differentiate peats. Glucose, mannose and galactose were the predominant monosaccharides found. Changes observed with depth in the relative abundances of the monosaccharides were not always correlated with the degree of decomposition as measured by fibre content or pyrophosphate index. The arabinose to xylose ratio was a diagnostic chemical feature which reflected the degree of decomposition of the peats.

Description: Sand-soil mixtures are commonly used in drained turf sites such as golf greens and athletic fields to ensure adequate soil strength, minimum compaction, and corresponding suitable water retention and infiltrability. The physical properties of the components vary significantly from site to site and mixture proportions must be adjusted to compensate for this. This adjustment usually involves empirical testing of various mixtures of the components to determine the correct proportions to use. One objective of this project is to develop a simple, applied method useful in the prediction of mixture porosity and water retention, which might eliminate or at least significantly reduce empirical testing. A graphical method based on component bulk volume proportions and which requires knowledge of the component porosities was developed and demonstrated to accurately predict water retention porosity, aeration porosity, and total porosity in sand-soil mixtures. This method, described herein, should prove of practical use in determining correct mixtures of sand and soil for drained turf sites.

Description: The influence of soil moisture on urea hydrolysis and microbial respiration in mixed L and F horizons of a Brunisolic soil under a boreal forest jack pine (Pinus banksiana Lamb.) stand was determined in an incubation study at 13 °C. Respiration rates in untreated soil were similar over a wide range of moisture contents below 300% (45% water-holding capacity). Significant decreases in respiration rates occurred only below 60% moisture content. Initial microbial response to urea increased as soil moisture rose from 20 to 300%. There was sufficient urease in pine humus to hydrolyze rapidly the equivalent of 200 kg urea-N∙ha−1, when moisture was not limiting. During the drying of initially moist soil (340% H2O) to 240% H2O or lower, urea hydrolysis was retarded significantly and microbial respiration reduced by an average of 25% over that observed in a constantly moist soil.

Description: Recommended concentrations of Vorlex and linuron exerted little initial effect on bacterial and actinomycete populations in a muck, whereas Vorlex caused drastic reduction in that of the fungi. This resulted in linuron accumulation in the soil which was deleterious to growth of Lactuca sativa L. New fungal population produced by the survivors was resistant to subsequent Vorlex treatments, but was linuron passive. Proliferation of the surviving fungi was accompanied by appreciable and lasting increases in the bacterial and actinomycete populations. Absence of pathogenic symptoms on lettuce plants due to any of these organisms precluded selection or enrichment of pathogens potentially present in the soil. The findings demonstrated the consequence of this pesticide combination on non-target microbiota, the accumulation of linuron, and plant growth.

Description: N and P fertilizers were applied at increasing rates in alternating directions crossed over (IRADCO) at right angles upon each other. One fertilizer was applied so that, in the contiguous strips, the rates increased in alternate directions. The second fertilizer was applied similarly but at right angles to and on top of the first fertilizer. This arrangement with the increasing-rate spreader available allowed 162 combinations of the two fertilizer elements in duplicate in each block. Two such blocks set at right angles to each other were considered to offer reasonable control of possible fertility gradients in the field. The main value of the design is that many fertilizer levels for the establishment of yield response surface functions can be acquired with less effort and in a fraction of the area required with plots of conventional size. The form of the yield response to fertilizer was adequately represented by regression models fitted to the data. The IRADCO design, involving both the field technique and regression modelling, can be used to determine the response to fertilizer levels by various crops at several locations.

Description: The map index linkages (from CanSIS cartographic file) of seven soil maps were analyzed to find out how many map delineations represented each map unit and what proportion of the map they covered. Many map units were represented by only one or two delineations. This was more true for uncontrolled than controlled legends (51–85% of map units in uncontrolled legends versus 27–37% of map units in controlled legends). In both types of map the map units that had only one or two delineations covered only a small proportion of the land area. On the other hand, only a small proportion of the map units (between 14 and 31%) was needed to cover 75% of the land area in both types of maps. It proved possible to reduce the number of map units in one map with an uncontrolled legend from 193 to 91. This was done, firstly, by combining map units that represented only very small areas (or were represented by only one delineation) with larger map units that were very similar for the purpose of the survey. Secondly, map units were combined when more than 85% of the soils within them were the same. Controlled legends need not be very long and need not omit significant information.

Description: Cryosolic soils have been identified on forested, upper subalpine, north facing slopes in eastern Banff and Jasper National Parks. Soil morphology and soil and air temperatures all confirm the presence of permafrost.

Description: Poultry numbers, density and potential environmental quality problems have increased greatly in the Lower Fraser Valley. A field experiment was carried out in 1975 and 1976 to determine the effect of manure from a deep-pit laying house on the growth, yield and chemical composition of orchardgrass-ladino clover forage. The manure had N:P:K, ratios of 5.1:2.5:2.0 and 3.5:1.6:1.4 in 1975 and 1976, indicating that its K content relative to N and P was relatively low for forages. Manure rates were 1.25, 2.5, 5.0, 10, 20 and 40 t/ha. In 1976, these rates were applied as a single application in the early spring or split into three equal increments applied in the early spring and following the first and second cuts. The grass component of the sward responded positively to increased manure rates. However, at rates in excess of 2.5 t/ha, the clover was almost totally eliminated from the stand. The maximum 1975 dry matter yield of 7.00 t/ha occurred with 40 t/ha of manure although the rate of yield increase was greatest at rates of 10 t/ha or less. The maximum forage yield of 16.1 t/ha occurred in 1976 at the 20 t/ha split-application rate of manure. At the 5, 10 and 20 t/ha manure rates the split application produced yields about 1.2 t/ha higher than the single application method. Except for the last cuts in both years, manure significantly increased percent total Kjeldahl nitrogen, especially at rates of 20 t/ha or less. Forage NO3-N concentrations exceeded 0.20%, the level cited as being toxic to ruminants, at rates of 20 and 40 t/ha. Forage P concentrations were not significantly affected by manure addition, probably because the available P level in the soil was high. Forage K concentrations were increased at all cuts by increasing manure rates although K was not a factor in the crop response to manure because initial soil K was high. Manure applied at rates in excess of 20t/ha to supply adequate K for forage production would make inefficient use of the N and P in the manure. Good forage yields without damage to the sward and with little problem with high forage NO3 concentrations were obtained at the 10 t/ha rate; however, for manure disposal, rates as high as 20 t/ha could be used.

Description: Application of Ca(NO3)2 to a Black Solonetz soil at Vegreville, Alberta provided the known beneficial effects of NH4NO3 in increasing yields and improving the chemical and physical properties of the Ap and Bnt horizons without the harmful increase in soil acidity associated with the use of NH4NO3.

Description: A simple and inexpensive instrument for measuring soil water table levels that can be used with metal or plastic wells was designed and constructed. The accuracy of the measurements is within ± 1 mm. The instrument has been thoroughly tested both in the field and in the greenhouse and proved to be very reliable.

Description: Nitrous oxide emission from agricultural soil has been measured in two relatively long-term studies over two different soil types, Brookston clay and Fox sandy loam, located at Woodslee and Harrow Ontario, respectively. The clay plots treated with various amounts (0–366 kg N∙ha−1) of ammonium nitrate, potassium nitrate, or urea were routinely monitored for periods up to 1 yr. Extreme variability in rates within the range 109–1013 molecules∙cm−2∙s−1 was observed (1 × 109 molecules∙cm−2∙s−1 = 4.02 = 10−4 kg N∙ha−1∙day−1 = 1.68 μg N∙m−2∙h−1). Over sandy loam, rates which were lower and more uniform (108–1011 molecules∙cm−2∙s−1) showed a strong correlation with amount of NH4NO3 applied. About 0.25% of applied fertilizer was released as N2O within 80 days following treatment.

Description: Agricultural land use and cropping statistics were examined to determine yield trends of wheat and barley since the early 1900’s. A general decline in yields of these crops occurred until the return of favorable weather and introduction of disease-resistant varieties in the mid-1930’s. Since about the mid-1950’s, yields of wheat and barley have been greater than at any previous period, and have generally been increasing rapidly during the period 1958–1978. An estimate of the contribution of modern technology to the increased yields was calculated, using 5-yr moving averages for the periods ending 1962 and 1978. Increased fertilizer use had the greatest effect on yield increases achieved. New disease-resistant varieties with improved yielding potential had a lesser effect. The impact of herbicides and improved machinery was examined but could not be effectively evaluated from available data.