ALBERT

Description: A non-Fickian physico-chemical model for electrolyte transport in high-ionic strength systems is developed and tested with laboratory experiments with copper sulfate as an example electrolyte. The new model is based on irreversible thermodynamics and uses measured mutual diffusion coefficients, varying with concentration. Compared to a traditional Fickian model, the new model predicts less diffusion and asymmetric diffusion profiles. Laboratory experiments show diffusion rates even smaller than those predicted by our non-Fickian model, suggesting that there are additional, unaccounted for processes retarding diffusion. Ionic diffusion rates may be a limiting factor in transporting salts whose effect on fluid density will in turn significantly affect the flow regime. These findings have important implications for understanding and predicting solute transport in geologic settings where dense, saline solutions occur.

Description: Alkaline volcanic rocks including nephelinites, basanites and trachybasalts dredged from the volcanic pedestal of Rakahanga Atoll and from a volcanic edifice with 100 satellite volcanoes at the eastern edge of the Manihiki Plateau, ca. 40 km southwest of the atoll, fall well within the category of EM-type ocean island basalts. They indicate a hotspot involvement during the formation of the plateau basement. The rocks are thought to be products of explosive eruptions which took place subaerially or in shallow water in the Aptian. The volcanoes, together with other volcanic eruption centers, most likely were responsible for the formation of the 230 m thick volcaniclastite layer which rests on the basement for at least 5000 km2 of the eastern part of the Manihiki Plateau. Erosion has prevented any substantial sediment cover on the volcanic cone field and most of the slope of Rakahanga and thin pelagic limestones were deposited instead at least since the Maastrichtian.

Description: Detrital sediment is carried from land to the sea by three agents, rivers, glaciers, and winds. The shoreline is an arbitrary boundary within the detrital sediment transport system, which extends from a site of origin across areas of temporary storage to a site of long-term deposition. The most important of the agents moving sediment across the land is river transport, estimated to be in the order of 20×1012 kg of sediment annually at present. Analysis of drainage basins indicates that relief and runoff are the most important factors in determining the sediment load of rivers. The competence of rivers to transport sediment is governed by the volume flow, gradient, and the sediment load itself. Today, most large rivers are fed by snowmelt in highland areas, runoff from rainfall in the drainage basin, and groundwater inflow. Along the river course, water is lost to evaporation and groundwater infiltration. River courses can often be divided into two segments, a degradational section in which the gradient is relatively steep and little temporary storage of sediment takes place, and an aggradational section where the gradient is sharply reduced through meandering, and where large-scale temporary sediment storage forms a flood plain. Lakes trap sediment inland and prevent its transport to the sea. Today, many high and mid-latitude rivers are interrupted by lakes of glacial origin. There are also some large areas of internal drainage that deliver no sediment to the sea. The load carried by rivers has been markedly altered by human activity, and may have doubled over the past few thousand years, only to be reduced in the past century by the widespread construction of dams. The ancient use of fire in hunting and its subsequent use in clearing land has increased erosion. Extensive deforestation and cultivation processes have also increased the sediment supply. Dam construction is a relatively new factor and affects the sediment transport system by trapping sediment before it can reach the sea. The resulting lower sediment supply from rivers is, at least in part, compensated by increased coastal erosion. Glacial erosion is difficult to estimate. There is an ongoing controversy whether ice sheets are effective erosive agents or not. Estimates of the present global flux of glacial detritus range from 0.8–50×1012 kg annually, with the lower value most probable. The dust flux is in the order of 0.5 to 0.9×1012 kg annually, but may vary greatly with time.

Description: This chapter discusses the rates of protein synthesis in fish. Protein synthesis can be viewed at a number of levels. Whole-animal values can be integrated into the descriptions of assimilation/growth or assimilation/metabolism patterns in different fish species and is the focus of the chapter. The measurement of protein synthesis rates in body organs and tissues can provide information on the extent to which differences exist among various tissues and offer a challenge in understanding the integration of organ metabolism into whole animal physiology. The majority of methods for estimating protein synthesis measure the flux of an amino acid or nitrogen. This involves the use of tracer substances—that is, amino acids labeled with an isotope, which are given in a single dose or by continuous infusion. The measurements, parameters, and formulae that are commonly employed in the studies of protein growth, synthesis, and degradation are described in the chapter. It discusses the mechanism of nutrition and protein synthesis in the fish and explains the impact that protein synthesis has upon the rates of oxygen consumption.

Description: Grain‐size‐dependent flow mechanisms tend to be favored over dislocation creep at low differential stresses and can potentially influence the rheology of low‐stress, low‐strain rate environments such as those of planetary interiors. We experimentally investigated the effect of reduced grain size on the solid‐state flow of water ice I, a principal component of the asthenospheres of many icy moons of the outer solar system, using techniques new to studies of this deformation regime. We fabricated fully dense ice samples of approximate grain size 2±1 μm by transforming “standard” ice I samples of 250±50 μm grain size to the higher‐pressure phase ice II, deforming them in the ice II field, and then rapidly releasing the pressure deep into the ice I stability field. At T≤200 K, slow growth and rapid nucleation of ice I combine to produce a fine grain size. Constant‐strain rate deformation tests conducted on these samples show that deformation rates are less stress sensitive than for standard ice and that the fine‐grained material is markedly weaker than standard ice, particularly during the transient approach to steady state deformation. Scanning electron microscope examination of the deformed fine‐grained ice samples revealed an unusual microstructure dominated by platelike grains that grew normal to the compression direction, with c axes preferentially oriented parallel to compression. In samples tested at T≥220 K the elongation of the grains is so pronounced that the samples appear finely banded, with aspect ratios of grains approaching 50:1. The anisotropic growth of these crystallographically oriented neoblasts likely contributes to progressive work hardening observed during the transient stage of deformation. We have also documented remarkably similar microstructural development and weak mechanical behavior in fine‐grained ice samples partially transformed and deformed in the ice II field.

Description: In the Neil Brown Instruments' MKIIIB-CTD (conductivity-temperature-depth profiler), the system's digital outputs for the three basic measurements of temperature, conductivity and pressure typically show some small amplitude deviations from smooth calibrations which should be corrected for to achieve high accuracies, as required, e.g. within the Hydrographic Program (WHP) of the current World Ocean Circulation Experiment (WOCE). These deviations show up as (i) a strong nonlinearity or even discontinuity of several mK close to 0°C in temperature output leading to too high subzero temperatures; (ii) a jump of order 0.002 mS cm−1 in conductivity output when passing the half-range value 32.768 mS cm−1, which causes jumps in the relation of potential temperature and salinity; and (iii) errors in pressure measurements of up to 4 dbar due to mechanical hysteresis and both static and dynamic responses to temperature changes. The existence of these effects is demonstrated, and methods to reduce the associated errors are suggested.

Description: The sea-ice export out of the central Arctic through the Fram Strait is a key variable in the Arctic climate system. Satellite data provide the only basis for mapping ice features with a high spatial and temporal resolution in polar regions. An automatic drift algorithm has been employed and optimized to monitor the sea-ice drift velocity in the Greenland Sea with AVHRR data. The combination of the ice drift and the spatial ice distribution provides an insight into the ice transport processes along the coast of Greenland. The combination with sea-ice thickness measurements allows an estimation of the spatial distribution of the sea-ice mass flux. The seasonal and spatial variability of the mass flux allows further predictions of the meridional melting and freezing processes along the East Greenland Current. This investigation covers the years 1993 and 1994. Seasonal and spatial distributions of the sea-ice drift were derived. The derived absolute values in this study are in good agreement with estimates proposed by other authors.

Description: Dissolved and atmospheric nitrous oxide (N2O) were measured on the legs 3 and 5 of the R/V Meteor cruise 32 in the Arabian Sea. A cruise track along 65°E was followed during both the intermonsoon (May 1995) and the southwest (SW) monsoon (July/August 1995) periods. During the second leg the coastal and open ocean upwelling regions off the Arabian Peninsula were also investigated. Mean N2O saturations for the oceanic regions of the Arabian Sea were in the range of 99–103% during the intermonsoon and 103–230% during the SW monsoon. Computed annual emissions of 0.8–1.5 Tg N2O for the Arabian Sea are considerably higher than previous estimates, indicating that the role of upwelling regions, such as the Arabian Sea, may be more important than previously assumed in global budgets of oceanic N2O emissions.

Description: Dinoflagellate cysts and other organic-walled microfossils have been studied in recent surface sediments from the entire Norwegian-Greenland Sea. More than 30 taxa have been recognized, of which only few show a distinct distribution pattern, and allow description of four assemblages. The occurrence of most taxa is related to the relatively warmer waters of the Norwegian Sea. Algidaspaeridium? minutum s.1., Brigantedinium simplex and Impagidinium? pallidum are the only species showing a preference for colder water masses. Two species, I.? pallidum and Nematosphaeropsis labyrinthus are mainly restricted to the oceanic environment, whereas the other species have also been reported from neritic environments in previous studies. Due to the limited knowledge of the ecological and sedimentological factors influencing the occurrence of dinoflagellate cysts in oceanic environments, their distribution in recent sediments can be only related to surface water masses in a broad sense. Although the distribution of assemblages correlates with specific surface water masses, comparison with assemblages recovered from sediment traps deployed basinwide in the Norwegian-Greenland Sea (Dale and Dale, 1992) revealed some major discrepancies in species composition and percentage abundances. The differences cannot be explained with certainty at the moment, although there is some evidence that transport of dinoflagellate cysts and other fossilizable microplankton in water masses by currents, in sea-ice and sediments may modify the assemblages found in recent oceanic surface sediments from the Norwegian-Greenland Sea.

Description: Benthic foraminifera and surface sediments were analyzed from 23 box-core and core-top samples from 250 to 3600 m depth at the southern Portuguese continental margin between 37 and 38 °N. This area is affected by the MOW which flows northwards along the slope between 600 and 1500 m waterdepth. Sediment structures, grain-size distribution and clay mineral assemblages of surface sediments indicate active winnowing in the upper part of the MOW, and deposition of the fine fraction near its lower boundary. R-mode cluster analyses of foraminiferal census data from the 〉 250 μm fraction revealed four associations. The ‘Shelf Edge Association’ occurs on glauconitic shelf and upper slope sands down to 268 m. The ‘Upper Slope Association’ is recognized between 498 and 1300 m where sand-silt-clays to clayey silts are encountered. The ‘Lower Slope Association’ is found between 1405 and 2985 m and differs markedly from assemblages below 3000 m (‘Deep Water Association’) where the near-surface sediments are soft hemipelagic clays. The ‘Boundary Layer Association’ shows no significant depth limits but abundance maxima both in the density interface above the MOW and in the interval of decreasing turbulence below it. The boundaries of the ‘Shelf Edge’ and ‘Upper Slope Association’ correspond to these hydrographic boundary layers whereas the boundary between ‘Lower Slope’ and ‘Deep Water Assemblage’ is related to threshold values of nutrient flux to the benthic community. Examination of hard-substrates reveals 27 different species of epibenthic foraminifera. Six of these, the ‘Epibenthos Group’, were found attached to elevated substrates only within the MOW. Above the MOW, elevated substrates were inhabited by different species, whilst below the MOW they were not used by any epibenthic foraminifers. Evidently, the hydrodynamic environment of the MOW current provides an ecological niche which is efficiently used by opportunistic suspension feeders. The ‘Epibenthos Group’ is more abundant in the middle part of the study area between 37 °20′ and 37 °40′N where the sand content of surface sediments is also higher. Both indicate an enhanced sediment-water interaction in this area which results from an obstruction of the MOW flow by the ‘Principes d'Avis’ basement spur.