ALBERT

Description: The volcanic arc of the Hellenic subduction zone with its four volcanic centers is of major relevance when evaluating the seismovolcanic hazard for the Aegean region. We present results from a 22-station temporary seismic network (CYCNET) in the central Hellenic Volcanic Arc (HVA). CYCNET recordings allow to analyze the level and spatio-temporal evolution of microseismic activity in this region for the first time. A total of 2175 events recorded between September 2002 and July 2004 are analyzed using statistical methods, cluster analysis and relative relocation techniques. We identify distinct regions with significantly varying spatiotemporal behavior of microseismicity. A large portion of the seismic activity within the upper crust is associated with the presence of islands representing horst structures that were generated during the major Oligocene extensional phase. In contrast, the central part of the Cyclades metamorphic core complex remains aseismic considering our magnitude threshold of 1.8 except one spot where events occur swarm-like and with highly similar waveforms. The highest activity in the study area was identified along the SW–NE striking Santorini–Amorgos zone. Within this zone the submarine Columbo volcano exhibits strong temporal variations of seismic activity on a high background level. This activity is interpreted to be directly linked to the magma reservoir and therein the migration of magma and fluids towards the surface. NE of Columbo where no volcanic activity has yet been reported we observe a similar seismicity pattern with small-scaled activity spots that might represent local pathways of upward migrating fluids or even developing volcanic activity within this zone of crustal weakness. In contrast, the Santorini and Milos volcanic complexes do not show significant temporal variations and low to moderate background activity, respectively. Relating our results to the distribution of historical earthquakes and the GPS-derived horizontal velocity field we conclude that the Santorini–Amorgos zone is presently in the state of right-lateral transtension reflecting a major structural boundary of the volcanic arc subdividing it into a seismically and volcanically quiet western and an active eastern part.

Description: There is growing concern about the transfer of methane originating from water bodies to the atmosphere. Methane from sediments can reach the atmosphere directly via bubbles or indirectly via vertical turbulent transport. This work quantifies methane gas bubble dissolution using a combination of bubble modeling and acoustic observations of rising bubbles to determine what fraction of the methane transported by bubbles will reach the atmosphere. The bubble model predicts the evolving bubble size, gas composition, and rise distance and is suitable for almost all aquatic environments. The model was validated using methane and argon bubble dissolution measurements obtained from the literature for deep, oxic, saline water with excellent results. Methane bubbles from within the hydrate stability zone (typically below 500 m water depth in the ocean) are believed to form an outer hydrate rim. To explain the subsequent slow dissolution, a model calibration was performed using bubble dissolution data from the literature measured within the hydrate stability zone. The calibrated model explains the impressively tall flares (〉1300 m) observed in the hydrate stability zone of the Black Sea. This study suggests that only a small amount of methane reaches the surface at active seep sites in the Black Sea, and this only from very shallow water areas (〈100 m). Clearly, the Black Sea and the ocean are rather effective barriers against the transfer of bubble methane to the atmosphere, although substantial amounts of methane may reach the surface in shallow lakes and reservoirs.

Description: Structure-based inhibitor design has led to the discovery of a number of potent inhibitors of glycogen phosphorylase b (GPb), N-acyl derivatives of β-d-glucopyranosylamine, that bind at the catalytic site of the enzyme. The first good inhibitor in this class of compounds, N-acetyl-β-d-glucopyranosylamine (NAG) (Ki = 32 μM), has been previously characterized by biochemical, biological and crystallographic experiments at 2.3 Å resolution. Bioisosteric replacement of the acetyl group by trifluoroacetyl group resulted in an inhibitor, N-trifluoroacetyl-β-d-glucopyranosylamine (NFAG), with a Ki = 75 μM. To elucidate the structural basis of its reduced potency, we determined the ligand structure in complex with GPb at 1.8 Å resolution. To compare the binding mode of N-trifluoroacetyl derivative with that of the lead molecule, we also determined the structure of GPb–NAG complex at a higher resolution (1.9 Å). NFAG can be accommodated in the catalytic site of T-state GPb at approximately the same position as that of NAG and stabilize the T-state conformation of the 280s loop by making several favourable contacts to Asn284 of this loop. The difference observed in the Ki values of the two analogues can be interpreted in terms of subtle conformational changes of protein residues and shifts of water molecules in the vicinity of the catalytic site, variations in van der Waals interaction, and desolvation effects.

Description: A comprehensive understanding of the shear behavior of sand in the context of shear band development has not been achieved yet in spite of many detailed research works on each specified subject. In order to observe the entire drained shear behavior of Toyoura sand from the macromechanical point of view, conventional triaxial tests were performed and analyzed up to an axial strain of 30% for various void ratios, initial confining stresses, and stress paths, paying particular attention to volume changes. The strong correlation was found between “double strain softening” and “diagonally crossing shear bands” as a remarkable result. Finally, a qualitative explanation of relations among the stress–strain curve, the failure shape, the dilatancy index–strain curve and the strain localization, could be clearly made. Also, it is concluded that the dilatancy index is an indicator not only of the ratio of the volumetric strain increment to the axial strain increment but also the condition of the strain localization.

Description: The impact of atmospheric stability on vertical wind profiles is reviewed and the implications for power performance testing and site evaluation are investigated. Velocity, temperature, and turbulence intensity profiles are generated using the model presented by Sumner and Masson. This technique couples Monin-Obukhov similarity theory with an algebraic turbulence equation derived from the k-ϵ turbulence model to resolve atmospheric parameters u∗, L, T∗, and z0. The resulting system of nonlinear equations is solved with a Newton-Raphson algorithm. The disk-averaged wind speed u¯disk is then evaluated by numerically integrating the resulting velocity profile over the swept area of the rotor. Power performance and annual energy production (AEP) calculations for a Vestas Windane-34 turbine from a wind farm in Delabole, England, are carried out using both disk-averaged and hub height wind speeds. Although the power curves generated with each wind speed definition show only slight differences, there is an appreciable impact on the measured maximum turbine efficiency. Furthermore, when the Weibull parameters for the site are recalculated using u¯disk, the AEP prediction using the modified parameters falls by nearly 5% compared to current methods. The IEC assumption that the hub height wind speed can be considered representative tends to underestimate maximum turbine efficiency. When this assumption is further applied to energy predictions, it appears that the tendency is to overestimate the site potential.

Description: We employ a combined interpretation of Hydrosweep swath bathymetry and high resolution multi-channel seismic reflection data to investigate the development of Cap Timiris Canyon, a newly discovered submarine canyon offshore Mauritania. The dominantly V-shaped and deeply entrenched canyon exhibits many fluvial features including dendritic and meander patterns, cut-off loops and terraces, and is presently incising. Distal meander patterns, confined within a narrow fault-controlled corridor, show several stages of evolution, the latest of which is dominated by a down-system meander-loop migration. Terraces exhibit a variety of internal structures suggesting they originated through different processes including sliding/slumping, uplift-induced incision and lateral accretion. We ascribe canyon origin to an ancient river system in the adjacent presently arid Sahara Desert that breached the shelf during a Plio/Pleistocene sea level lowstand and delivered sediment directly into the slope area. Our data suggest that the initial invading unchannelised sheet of sand-rich turbidity flows initiated canyon formation by gradually mobilising along linear seafloor depressions and fault-controlled zones of weakness. We propose that the development of canyon morphology and structure was influenced by the stages of active flow of the coupling river system, and hence could act as a proxy for understanding the paleo-climatic evolution of a ‘green’ Sahara since Plio/Pleistocene times.

Description: The discovery of coelacanths, Latimeria chalumnae, in Jesser Canyon off Sodwana Bay in northern KwaZulu-Natal in 2000 triggered renewed interest in the deep subtidal habitats associated with submarine canyons. Information stemming from three recreational Trimix diving expeditions in Wright and Jesser canyons between April 1998 and June 2001 revealed distinct and diverse invertebrate and fish communities in the canyons of the Greater St Lucia Wetland Park (GSLWP). In total, 69 invertebrate taxa were collected from Wright Canyon, including at least 15 new records for South Africa plus 11 potential new species and 16 range or depth extensions. Divers documented the first five coelacanth specimens and obtained information on fish distribution and abundance. Five different habitat types were recognized supporting distinct biological communities; the sandy plains outside of the canyons, scattered rock outcrops within the sandy plains, the canyon margin, canyon walls and caves and overhangs. The canyon margin is the richest habitat and supports dense communities of invertebrate suspension feeders, as well as a diverse and abundant fish fauna. Dominant canyon invertebrates included sponges, black corals, gorgonians, alcyonarian soft corals and stylasterine lace corals. These invertebrates support a diverse epifauna including basket- and brittlestars, winged oysters and other molluscs. The canyons within the GSLWP protect large populations of commercially important

Description: Latimeria chalumnae is the icon for the multidisciplinary, multinational African Coelacanth Ecosystem Programme (ACEP) dedicated to improving the understanding of biological and other processes that support marine life. This article provides an overview of contributions made at a conference hosted by ACEP at the end of 2003. It also reviews significant developments regarding coelacanth conservation which have taken place since the conference. Delegates at the meeting concluded that the integrated regional,ecosystem approach that had been adopted by ACEP should continue. Underwater observation and exploration, however, should be supplemented by more experimental and technical analyses in order to answer longstanding questions related to coelacanths and other organisms.

Description: Evidence for a Miocene period of transient shallow subduction under the Neuquén Basin in the Andean backarc, and an intermittent Upper Cretaceous to Holocene frontal arc with a relatively stable magma source and arc-to-trench geometry comes from new 40Ar/39Ar, major- and trace-element, and Sr, Pb, and Nd isotopic data on magmatic rocks from a transect at ∼36°–38°S. Older frontal arc magmas include early Paleogene volcanic rocks erupted after a strong Upper Cretaceous contractional deformation and mid-Eocene lavas erupted from arc centers displaced slightly to the east. Following a gap of some 15 m.y., ca. 26–20 Ma mafic to acidic arc-like magmas erupted in the extensional Cura Mallín intra-arc basin, and alkali olivine basalts with intraplate signatures erupted across the backarc. A major change followed as ca. 20–15 Ma basaltic andesite–dacitic magmas with weak arc signatures and 11.7 Ma Cerro Negro andesites with stronger arc signatures erupted in the near to middle backarc. They were followed by ca. 7.2–4.8 Ma high-K basaltic to dacitic hornblende-bearing magmas with arc-like high field strength element depletion that erupted in the Sierra de Chachahuén, some 500 km east of the trench. The chemistry of these Miocene rocks along with the regional deformational pattern support a transient period of shallow subduction that began at ca. 20 Ma and climaxed near 5 Ma. The subsequent widespread eruption of Pliocene to Pleistocene alkaline magmas with an intraplate chemistry in the Payenia large igneous province signaled a thickening mantle wedge above a steepening subduction zone. A pattern of decreasingly arc-like Pliocene to Holocene backarc lavas in the Tromen region culminated with the eruption of a 0.175 ± 0.025 Ma mafic andesite. The northwest-trending Cortaderas lineament, which generally marks the southern limit of Neogene backarc magmatism, is considered to mark the southern boundary of the transient shallow subduction zone.

Description: The wide variety of metal sulfide structures and their accommodation of atomic substitution, non-stoichiometry and metal-metal (M-M) and ligand-ligand interactions allows for diverse physical, chemical and electronic properties. The energy band structure of 3d transition-metal sulfides, in particular, is strongly influenced by the covalence of metal-S bonds, which results in hybridization of S 3p and metal 3d bonding states and direct or indirect M-M bonding interactions in favorable cases. Differences in the phase relations of isostructural metal sulfides are often attributable to subtle changes in electronic states. The literature on metal sulfide phase relations relevant to the earth sciences is very extensive and could not possibly be summarized in a single chapter. Therefore, following Craig and Scott (1974), this chapter focuses on the base metal (Fe, Co, Ni, Cu, and Zn) sulfides, with the literature for other metal chalcogenides and pnictides and some sulfosalts summarized in a single table (Table 1⇓). The relevant phase relations of the platinum-group element (PGE) chalcogenides and pnictides have been comprehensively reviewed in Makovicky (2002). A section on the halite structure sulfides (niningerite, alabandite and oldhamite) is also included in this chapter. The material presented here relates closely to that discussed in other chapters, in particular the chapter on sulfide thermochemistry (Sack and Ebel 2006). The importance of understanding phase equilibria in the context of electronic and magnetic properties and, hence, electronic structure is also emphasized, thereby reinforcing material presented in several other chapters (Pearce et al. 2006; Vaughan and Rosso 2006).

Description: A continuous ∼5280 calendar (cal.) yr long cryptotephrostratigraphic record of a peat core from northern New Zealand demonstrates that cryptotephra studies can enhance conventional tephra records by extending the known distribution of ash fall and enabling re-assessment of volcanic hazards. A systematic sampling strategy was used to locate peaks in glass-shard concentrations and to determine loci of individual geochemical populations, and a palynological method involving spiking samples with Lycopodium spores was adapted to facilitate accurate counting of glass-shard concentrations. Using glass shard major element compositions, and a core chronology based on eight AMS 14C ages and two visible macroscopic tephra layers, Taupo Tephra (Unit Y) (1688-1748 cal. BP) and Tuhua Tephra (6800-7230 cal. BP) (2cr-age ranges), four cryptotephras were correlated with known eruptions: Whakaipo (Unit V) (2743-2782 cal. BP), Stent (Unit Q) (4240-4510 cal. BP), and Unit K (4970-5290 cal. BP), erupted from Taupo Volcanic Centre, and Whakatane Tephra (5470-5600 cal. BP) erupted from Okataina Volcanic Centre. Mixed glass populations were found in the core, most likely an artefact of post-depositional remobilization of shards vertically (both up and down) in the peat or on its surface by wind, or a result of closely spaced eruption events, or a combination of these. A secondary glass population identified within the macroscopic Taupo Tephra was tentatively attributed to either an earlier phase within that eruption or to mixing with a slightly older Taupo-derived eruptive or (less likely) a currently unknown Okataina-derived eruptive. These results indicate that, in the absence of continuous cryptotephrostratigraphic analysis, a peak in shard concentrations may not in itself be indicative of the ‘true’ stratigraphic (ie, isochronous) level of a tephra layer. For cryptotephra studies of peat cores, we recommend (1) using a detailed sampling strategy for the analysis of distal tephra-derived glass to detect and account for any mixed populations and possible vertical spread of glass shards through the peat, and (2) analysing more shards from larger samples to help ‘capture’ sparsely represented cryptic andesitic tephra deposits.

Description: Methane (CH4) concentration and stable isotope (δ2H-CH4 and δ13C-CH4) depth distributions show large differences in the water columns of the Earth's largest CH4-containing anoxic basins, the Black Sea and Cariaco Basin. In the deep basins, the between-basin stable isotope differences are large, 83‰ for δ2H-CH4 and 9‰ for δ13C-CH4, and the distributions are mirror images of one another. The major sink in both basins, anaerobic oxidation of CH4, results in such extensive isotope fractionation that little direct information can be obtained regarding sources. Recent measurements of natural 14C-CH4 show that the CH4 geochemistry in both basins is dominated (∼64 to 98%) by inputs of fossil (radiocarbon-free) CH4 from seafloor seeps. We derive open-system kinetic isotope effect equations and use a one-dimensional (vertical) stable isotope box model that, along with isotope budgets developed using radiocarbon, permits a quantitative treatment of the stable isotope differences. We show that two main factors control the CH4 concentration and stable isotope differences: (1) the depth distributions of the input of CH4 from seafloor seeps and (2) anaerobic oxidation of CH4 under open-system steady state conditions in the Black Sea and open-system non-steady-state conditions in the Cariaco Basin.

Description: This paper presents an event stratigraphy based on data documenting the history of vegetation cover, lake-level changes and fire frequency, as well as volcanic eruptions, over the Last Glacial–early Holocene transition from a terrestrial sediment sequence recovered at Lake Accesa in Tuscany (north-central Italy). On the basis of an age–depth model inferred from 13 radiocarbon dates and six tephra horizons, the Oldest Dryas–Bølling warming event was dated to ca. 14 560 cal. yr BP and the Younger Dryas event to ca. 12 700–11 650 cal. yr BP. Four sub-millennial scale cooling phases were recognised from pollen data at ca. 14 300–14 200, 13 900–13 700, 13 400–13 100 and 11 350–11 150 cal. yr BP. The last three may be Mediterranean equivalents to the Older Dryas (GI-1d), Intra-Allerød (GI-1b) and Preboreal Oscillation (PBO) cooling events defined from the GRIP ice-core and indicate strong climatic linkages between the North Atlantic and Mediterranean areas during the last Termination. The first may correspond to Intra-Bølling cold oscillations registered by various palaeoclimatic records in the North Atlantic region. The lake-level record shows that the sub-millennial scale climatic oscillations which punctuated the last deglaciation were associated in central Italy with different successive patterns of hydrological changes from the Bølling warming to the 8.2 ka cold reversal. Copyright © 2006 John Wiley & Sons, Ltd.

Description: The evolution of local strains during shear of particles of a granular material is presented in this paper. A cylindrical specimen composed of 6.5-mm spherical plastic particles was loaded under an axisymmetric triaxial loading condition. Computed tomography (CT) was used to acquire three-dimensional images of the specimen at three shearing stages. The high-resolution CT images were used to identify the 3D coordinates of 400 particles. Nine strain components (normal, shear, and rotation), rotation angles, and local dilatancy angles for particle groups were calculated, and their frequency distribution histograms are presented and discussed. It was found that there is no preferred shear direction, and the standard deviation values for shear strain components (εxy, εxz, and εyz) were almost equal for the specific test shearing stage. Shear strains as high as 25.6% were recorded for some particle groups. Furthermore, granular particle groups rotated in the 3D space with almost equal amounts of rotation strains when loaded under axisymmetric triaxial condition. Rotation strain values are very close to the corresponding shear strains. Compared to particle sliding, rotation plays a major role in the shearing resistance of granular materials. The cumulative vertical rotation angles can be as high as 38° and the horizontal rotation angles have values as high as 60°. The statistical distributions of the local dilatancy angle (ψ1) of particle groups were calculated and found to be increasing as shearing continues. The “global” dilatancy angle value is very close to the mean local ψ1 during the first stage of shearing (i.e, when global εz=−7.3%)

Description: The paper gives a brief historical outline of JEBAR and its role in the ocean modeling, the cases of plagiarism by W. Holland and other scholars, and the main scientific results obtained with the help of JEBAR, JEBAR-2, and BARBE (baroclinic β-effect). The paper consists of the following main sections: the use of JEBAR as a correction of an error made by the authors of the method of mass flux; G. Neumann, P. Welander, bottom pressure torque, and JEBAR; opposition in the Institute of Oceanology of the Russian Academy of Sciences; W. Holland and his disciples as would-be hijackers of JEBAR; wide recognition and mass plagiarism of JEBAR in the English-language literature; JEBAR-2; the main results of the use of water baroclinicity, BARBE, JEBARs, and other factors of ocean modeling; adaptation of thermohydrodynamic parameters and diagnosis of long-term variations in the oceanic climate; and JEBAR and modern prognostic calculations.

Description: Numerous methane-emitting bottom features, such as seeps, methane clathrate hydrates (clathrates), and mud volcanoes, have been identified recently in the Black Sea. The fluxes of methane from these sources averaged over large spatial scales are unknown. Here we take advantage of the fact that the Black Sea is a semi-enclosed basin with restricted deep water circulation to establish first-order estimates of basin-wide fluxes of methane from these sources to the water column and atmosphere. First, we measured the natural radiocarbon content of methane (14C–CH4) dissolved in the water column and emitted from seeps. The 14C–CH4 results showed that the dominant source of methane to the water column is emitted from seeps and a smaller source is diagenetically produced in relatively modern sediments. The 14C–CH4 results were then used to partition a basin-wide total methane budget; this analysis estimated the basin-wide flux of methane from seeps and clathrates to the water column to be 3.60 to 4.28 Tg yr− 1. Second, a geochemical box model was used to calculate possible distributions of methane inputs from seeps and clathrates as well as provide additional estimates of the basin-wide flux of methane from seeps and clathrates to the water column (4.95 to 5.65 Tg yr− 1).

Description: Sulfate reduction accounts for about a half of the remineralization of organic carbon in anoxic marine shelf regions. Moreover, it was already a major microbial process in the very early ocean at least 2.4 billion years before the present. Here we demonstrate for the first time the capability of sulfate-reducing bacteria (SRB) to biosynthesize hopanoids, compounds that are quantitatively important and widely distributed biomarkers in recent and fossil sediments dating back to the late Archean. We found high concentrations (9.8–12.3 mg per gram of dry cells) of non-extended and extended bacteriohopanoids (bacteriohopanetetrol, aminobacteriohopanetriol, aminobacteriohopanetetrol) in pure cultures of SRB belonging to the widely distributed genus Desulfovibrio. Biohopanoids were found – considered as membrane rigidifiers – in more than 50% of bacterial species analysed so far. However, their biosynthesis appeared to be restricted to aerobes or facultative anaerobes with a very few recently described exceptions. Consequently, findings of sedimentary hopanoids are often used as indication for oxygenated settings. Nevertheless, our findings shed new light on the presence of hopanoids in specific anoxic settings and suggests that SRB are substantial sources of this quantitatively important lipid class in recent but also past anoxic environments.

Description: The Monterey Bay Aquarium Research Institute (MBARI) has developed an autonomous seafloor mapping capability for high resolution mapping of the deep ocean seafloor. The MBARI Mapping AUV is a 21" diameter, Dorado class autonomous underwater vehicle (AUV) equipped with a 200 kHz multibeam sonar, 110 kHz and 410 kHz sidescan sonars, and a 2-16 kHz subbottom profiler. All components of the vehicle are rated to 6000 m depth. Using precise navigation and attitude data from an laser-ring-gyro-based inertial navigation system (INS) integrated with a Doppler velocity log sonar (DVL), the Mapping AUV can image the deep-ocean seafloor and shallow subsurface structure with much greater resolution than is possible with hull-mounted sonars. The system can also be operated in an ROV-mounted configuration, allowing near-bottom surveys in very restricted terrain. The Mapping AUV has conducted several autonomous surveys of Monterey Canyon and Smooth Ridge in Monterey Bay, and ROV-mounted surveys of five sites along the Monterey Canyon axis during 2005 and 2006. During June 2006, the Mapping AUV surveyed mounds and channel deposits in the Santa Monica Basin. The bathymetric surveys have achieved a vertical precision of 0.3 m; surveys from a 20 m altitude achieve sub-meter lateral resolution and surveys from 50-100 m altitudes achieve lateral resolutions less than 2 m. The subbottom profile data provides resolution of ~0.1 m with penetrations up to 50 m in soft sediments. The combination of high-resolution bathymetry with closely spaced subbottom profiles allow us to Additional Mapping AUV expeditions are planned for 2006, including surveys of Barclay submarine canyon and the summits of Davidson and Axial seamounts.

Description: The African Coelacanth Ecosystem Programme (ACEP) Geographic Information System (GIS) has been developed to integrate, analyse and map all spatial data generated within the ACEP programme. A GIS is a multidisciplinary tool, and within ACEP the GIS has been used to integrate information from marine biology studies, oceanographic surveys, geophysical exploration as well as the observations made and footage taken from a research submersible. The core data in the GIS are based on deep marine ecosystems and the programme's flagship species, 〈I〉Latimeria chalumnae〈/I> (the coelacanth). Over and above the utility of the GIS as a tool for science through its considerable information storage, analysis and display capabilities, the ACEP GIS has been used for interactive environmental education purposes and to generate public awareness of the programme at various meetings, training events and conferences.

Description: Trimix scuba divers discovered coelacanths in Jesser Canyon at a depth of 104 m on the northern KwaZulu-Natal (KZN) coast (Sodwana Bay) in October 2000. The existence of these animals at such a shallow depth and in the swift and powerful Agulhas Current led to a suggestion that this might be an isolated group swept well away from the main population in the Comoros, where they live at depths of 200-350 m with little current. Subsequent observations from three manned submersible surveys and one remotely operated vehicle expedition together with recreational diver observations indicate that the South African population of coelacanths has at least 26 individuals, mostly occupying the depth range of 104-140 m in canyons. Seventeen CTD sections collected during four cruises in 2002 and 2003 indicate the temperature range in this habitat to be similar to that found in the Comoros Islands (that is, 15-22〈sup〉o〈/sup〉C cf. 15-19〈sup〉o〈/sup〉C in the Comoros). However, a 2.5-month-long time series of hourly data collected by a thermistor array deployed near a known coelacanth cave in Wright Canyon indicated greater variation than anticipated, with temperature changes between 16〈sup〉o〈/sup〉C and 24〈sup〉o〈/sup〉C occurring in a day. Dissolved oxygen levels in this depth zone were found to range between 3.0 ml l〈sup>-1〈/sup> and 4.8 ml l〈sup>-1〈/sup> compared to 3.5 ml l〈sup>-1〈/sup> in the Comoros. The low oxygen values along this coast are a result of the shallow oxygen minimum, which becomes shallower in the southwest Indian Ocean, particularly in the Agulhas Current, than in tropical latitudes. Current velocities measured using a ship-borne ADCP in the depth range 100-140 m at Sodwana were considerably higher than those measured in the Comoros habitat (20-60 cm s〈sup>-1〈/sup> cf. 3-4 cm s〈sup〉-1〈/sup〉) and may be an important factor explaining the coelacanths' occupation of the canyons found along the northern KZN shelf-break.

Description: The behavioural and physical mechanisms involved in the tactics used by predators to catch their prey have been explored for a wide variety of vertebrate taxa but most studies have considered the viewpoints of predator and prey independently. We tackled this issue using an ecologically relevant predator–prey model: wolf spiders (Pardosa spp.) and wood crickets, Nemobius sylvestris. Crickets are particularly challenging prey to catch because their air-sensing systems enable them to detect small air movements caused by approaching predators. Using a high-speed video camera, we found that freely behaving spiders adopted either a fast or a slow velocity tactic to approach crickets. We then developed a device using a piston to simulate, as faithfully as possible, the spider's attack. The air flow generated by the piston was quantified by particle image velocimetry and then used to test the escape success of crickets at different attack velocities. Cricket escape success was lower for low and high piston velocities, matching the two tactics adopted by the spiders. Based on our results, we propose that the escape probability of prey after a given predator signal can be explained by the distance between the prey and the predator, the velocity of the predator and the strength of the signal. Both methodological and conceptual approaches presented in this study could provide useful methods to understand the biological and physical basis of predatory tactics in other animals.

Description: Loss processes in magnetic nanoparticles are discussed with respect to optimization of the specific loss power (SLP) for application in tumour hyperthermia. Several types of magnetic iron oxide nanoparticles representative for different preparation methods (wet chemical precipitation, grinding, bacterial synthesis, magnetic size fractionation) are the subject of a comparative study of structural and magnetic properties. Since the specific loss power useful for hyperthermia is restricted by serious limitations of the alternating field amplitude and frequency, the effects of the latter are investigated experimentally in detail. The dependence of the SLP on the mean particle size is studied over a broad size range from superparamagnetic up to multidomain particles, and guidelines for achieving large SLP under the constraints valid for the field parameters are derived. Particles with the mean size of 18 nm having a narrow size distribution proved particularly useful. In particular, very high heating power may be delivered by bacterial magnetosomes, the best sample of which showed nearly 1 kW g−1 at 410 kHz and 10 kA m−1. This value may even be exceeded by metallic magnetic particles, as indicated by measurements on cobalt particles.

Description: While local and wavelet-based methods have mostly been applied to single time records of wave data, Donelan et al. (1996) derived and applied the Wavelet Directional Method (WDM) to small arrays of wave elevation recorders. After a short review of the Morlet wavelet transform applied to random signals, the WDM is revisited and compared to a Local Triplet Analysis (LTA) where the wavelet transform replaces the discrete Fourier transform in the directional analysis. The sampling statistics of the WDM and LTA are summarized, assuming that the wave records are weakly stationary stochastic processes. All methods show consistent results when applied to real data. Time-averaged local estimates of common wave parameters closely fit the estimates from the standard analysis. Frequency-averaged local wave directions show considerable variation and, in addition, the local directional spread tends to take a significant drop during the passage of large wave groups. The methods are illustrated using offshore directional wave data from the Ekofisk field in the North Sea.

Description: A comprehensive understanding of the shear behavior of sand in the context of shear band development has not been achieved yet in spite of many detailed research works on each specified subject. In order to observe the entire drained shear behavior of Toyoura sand from the macromechanical point of view, conventional triaxial tests were performed and analyzed up to an axial strain of 30% for various void ratios, initial confining stresses, and stress paths, paying particular attention to volume changes. The strong correlation was found between “double strain softening” and “diagonally crossing shear bands” as a remarkable result. Finally, a qualitative explanation of relations among the stress–strain curve, the failure shape, the dilatancy index–strain curve and the strain localization, could be clearly made. Also, it is concluded that the dilatancy index is an indicator not only of the ratio of the volumetric strain increment to the axial strain increment but also the condition of the strain localization.

Description: Today's solid streamers are generally less sensitive to mechanical noise originating from sea swell effects and are insensitive to vibration from depth controllers (birds) and mechanical towing equipment. In addition, for a given level of sea swell, they can be towed shallower without a significant noise increase. The dominant transport mechanism for parasitic or unwanted vibration in any streamer design (whether using solid or fluid‐based buoyancy) is the axial extensional wave. If such extensional waves are permitted to generate significant pressure or stress at the locations of the hydrophone elements, then undesirable coherent noise will result. In fluid streamers, coupling between extensional waves and hydrophones occurs through the medium of bulge waves. With extremely careful mechanical design, and by forming linear arrays of individual hydrophone elements which exploit the low speed of bulge waves, fluid filled streamers may achieve acceptable mechanical noise performance. Single hydrophones in fluid streamers are always excessively noisy. In a solid buoyancy streamer the low speed bulge waves are replaced by higher speed compressional waves, thus precluding array forming as a primary means of mechanical noise reduction within the critical 3Hz to 50Hz band. However with appropriate design and materials, a high degree of noise isolation can be realised. As mechanical isolation must be achieved independently of the use of arrays, both arrays and single hydrophones in a solid streamer can be relatively quiet. One successful method of manufacturing a solid streamer encloses the hydrophone element in a relatively stiff package which resists the stress and strain normally induced by the passage of axial extensional waves. This package or Strain Isolation Module (SIM) contains acoustically transparent coupling fluid and also includes an elongated external diaphragm or diaphragms providing a high degree of turbulent noise reduction. Using this technology, improvements in mechanical noise isolation of the order of 15dB have been measured at sea. Observed improvements in field results are well predicted by simple axial wave theory.

Description: The control exerted by some invertebrates on the calcium carbonate polymorph produced is intriguing but not understood. Mytilus edulis shells, with the abrupt polymorph switch within their valves from an outer calcite to inner aragonite layer, are excellent examples of this phenomenon. Detailed crystallography of intact valves using Electron Backscatter Diffraction (EBSD) is considered in the context of quantitative chemical analyses by electron microprobe. Apart from the outer 40 μm, individual crystals that comprise the calcite layer of M. edulis differ from each other in terms of misorientation by less than 10°. Similar uniformity occurs in the inner aragonite layer with notable 'mineral bridging' between tablets of aragonite nacre. The first-formed aragonite laminae are submicron thickness and the subsequent laminae of uniform 1 μm thickness.Variations in chemical composition through the two valves correspond in part with the distribution of the two polymorphs. Magnesium is present in notably higher concentrations within calcite than aragonite. However, the Mg2+ concentration in calcite is not uniform and increases with growth before decreasing at the polymorph switch. Sodium concentrations decrease steadily through the calcite layer. The aragonite layer is compositionally more uniform. Sulphur is not a good proxy for organic content in this system because it does not reflect the higher organic content of the aragonite. Sector zoning is not responsible for the element distribution seen here while differences in crystal size and association with organic components remain as possible explanations.

Description: A series of 500 years long coupled general circulation model simulations has been performed, in which the sea surface temperatures (SSTs) in different tropical oceans have been prescribed from climatology. A statistically significant reduction by about one Sverdrup of the meridional overturning circulation (MOC) in the North Atlantic was found when the tropical Pacific SSTs do not vary interannually. Anomalously low salinities originating in the tropical Atlantic due to increased precipitation drive the reduction of the MOC. Climatological SSTs in the tropical Pacific lead to a “La Niña”-like state due to the nonlinear response of the atmosphere to SST anomalies. The shift of the mean atmospheric circulation in the tropical Pacific leads to a cyclonic anomaly over the eastern tropical Atlantic with a corresponding precipitation increase. The results suggest that changes in the SST variability of the tropical Pacific can drive changes in the mean state of remote regions.

Description: Large volcanic edifices are often shaped by the coalescence of adjacent volcanoes as well as intrusive rift zones and gravitational spreading. To better understand the structure of such volcanoes we designed analogue experiments simulating gravitational spreading of an edifice made by overlapping cones of different age, and examined the formation of rift zones. The results allow distinction of two main rift geometries. (i) Spreading edifices of similar age that partly overlap, tend to develop a rift zone approximately perpendicular to the boundary of both volcanoes. Such a rift zone causes two volcanoes to grow together and form an elongated topographic ridge. (ii) Partly overlapping volcanoes of different age are spreading at different rates and thus form a rift zone parallel to the boundary of both volcanoes. Such a rift zone causes two volcanoes to structurally separate. The results are widely applicable for large volcanoes subject to rifting and flank spreading, which we demonstrate for Réunion Island and for southern Hawaii.

Description: Background: Halogenated compounds in the atmosphere are of great environmental concern due to their demonstrated negative effect on atmospheric chemistry and climate. Detailed knowledge of the emission budgets of halogenated compounds has to be gained to understand better their specific impact on ozone chemistry and the climate. Such data are also highly relevant to guide policy decisions in connexion with international agreements about protection of the ozone layer. In selected cases, the relevance of specific emission sources for certain compounds were unclear. In this study we present new and comprehensive evidence regarding the existence and relevance of a volcanic contribution of chlorofluorocarbons (CFCs), hydrofluorocarbons (HFCs), hydrochlorofluorocarbons (HCFCs), halons (bromine containing halo(hydro)carbons), and fully fluorinated compounds (e.g. CF4 and SF6) to the atmospheric budget. Methods: In order to obtain new evidence of a volcanic origin of these compounds, we collected repeatedly, during four field campaigns covering a period of two years, gases from fumaroles discharging over a wide range of temperatures at the Nicaraguan subduction zone volcanoes Momotombo, Cerro Negro and Mombacho, and analysed them with very sensitive GC/MS systems. Results and Discussion: In most fumarolic samples certain CFCs, HFCs, HCFCs, halons, and the fully fluorinated compounds CF4 and SF6 were present above detection limits. However, these compounds occur in the fumarole gases in relative proportions characteristic for ambient air. Conclusion: This atmospheric fingerprint can be explained by variable amounts of air entering the porous volcanic edifices and successively being incorporated into the fumarolic gas discharges. Recommendation and Outlook: Our results suggest that the investigated volcanoes do not constitute a significant natural source for CFCs, HFCs, HCFCs, halons, CF4, SF6 and NF3.

Description: The deep demersal fish fauna at depths of 100–400min canyons off the St Lucia Marine Protected Area along the north coast of KwaZulu-Natal is compared with similar fish communities at the Comoro Islands and in the Indo-Pacific region. Fifty-four fish species were seen or photographed from the submersible Jago or by the discovery team of scuba divers in the coelacanth, Latimeria chalumnae, habitat of the canyons off Sodwana Bay. An additional 94 fish species known from depths of 100–200 m along the coast of northern KwaZulu-Natal are likely to occur in the canyon habitat. The fish fauna of the Sodwana canyons shares at least 18 species with the deep demersal fish community off tropical coral reefs of the Indo-Pacific region. Thirty-seven of the Sodwana canyon fishes are also known from the coelacanth habitat in the Comoros.

Description: During four field campaigns (2001-2003), fumarolic gases from the two Nicaraguan volcanoes Mombacho and Momotombo were repeatedly sampled with the objective of gaining a better understanding of processes occurring within their volcano-magma-systems. Mombacho is a highly dissected stratocone volcano that is generally considered extinct. The combined chemical and isotopic composition of the gases provide evidence for high-temperature conditions in the shallow subsurface. This suggests that Mombacho volcano should not be considered extinct, and could re-awaken and erupt in the future. Momotombo is an active volcano in persistent state of fumarolic activity since its last eruption in 1905 and discharges gases at high temperatures. The chemistry, isotopic compositions and trace element contents of the gases have changed considerably over the last 20 years. These changes appear to be related to degassing of different magma batches and major changes in the interaction between the magmatic and hydrothermal systems. Flux estimates for some highly volatile and potentially harmful trace elements of magmatic origin (e.g. Tl, Bi, As, Se, Sb, Hg, Cd) show that Momotombo is only a minor source of pollutants in the atmosphere.

Description: The circulation of the northeastern Atlantic Ocean at intermediate depths is characterized by watermass transformation processes that involve Iceland–Scotland Overflow Water (ISOW) from the northeast, Labrador Sea Water (LSW) from the west, and Mediterranean Water from the south. Field observations were carried out with 89 eddy-resolving floats (RAFOS and MARVOR types). The data coverage achieved is remarkably high and enables a comprehensive study of the eastern basins between Iceland and the Azores. The trajectories show typical pathways of the water masses involved and the role that the complex bottom topography plays in defining them. The ISOW paths tend to lean against the slopes of the Reykjanes Ridge and Rockall Plateau. Westward escapes through multiple gaps in the ridge are possible, superimposed on a sustained southward flow in the eastern basin along the Mid-Atlantic Ridge. LSW pathways leading to the eastern basins are subject to high variability in flow direction and eddy activity. In addition to a selection of characteristic trajectories, maps of the horizontal distributions of Lagrangian eddy kinetic energy and integral time scales are presented. These reveal distinct areas of intensified mixing in the Iceland Basin, as well as the sharp contrast between the subpolar and subtropical dynamics. A self-contained eddy detection scheme is applied to obtain statistics on individual eddy properties and their abundance. It is suggested that much of the intensified mixing can be related to cyclonic activity, particularly in the subpolar region.

Description: Marine organisms have evolved defence mechanisms to prevent epibiosis. This study investigated the anti-settlement properties of natural periostracal microtopographies of two mytilid species, Mytilus edulis (from North, Baltic and White Seas) and Perna perna (from the SW Atlantic). Resin replicas of shells were exposed to cyprids of the barnacle Semibalanus balanoides. Replicas with intact isotropic microtopographies and smooth controls were much less fouled than roughened anisotropic surfaces. This indicates that in both M. edulis and P. perna the periostracum possesses a generic anti-settlement property, at least against S. balanoides cyprids, which is not regionally adapted. Such a potential globally effective anti-settlement mechanism possibly contributes to the invasive success of Mytilidae.

Description: The concentration of trace elements within cephalopod statoliths can provide a record of the environmental characteristics at the time of calcification. To reconstruct accurately the environmental characteristics at the time of calcification, it is important to understand the influence of as many factors as possible. To test the hypothesis that the elemental composition of cuttlefish statoliths could be influenced by diet, juvenile Sepia officinalis were fed either shrimp Crangon sp. or fish Clupea harengus under equal temperature and salinity regimes in laboratory experiments. Element concentrations in different regions of the statoliths (core–lateral dome–rostrum) were determined using laser ablation inductively coupled plasma mass spectrometry (LA- ICPMS). The ratios of Sr/Ca, Ba/Ca, Mn/Ca and Y/Ca in the statolith’s lateral dome of shrimp-fed cuttlefish were significantly higher than in the statolith’s lateral dome of fish-fed cuttlefish. Moreover, significant differences between statolith regions were found for all analysed elements. The fact that diet adds a considerable variation especially to Sr/Ca and Ba/Ca must be taken into account in future micro-chemical statolith studies targeting cephalopod’s life history.

Description: Merian 4/1 Vom 01.12. bis 21.12.2006 fand die 4. Forschungsfahrt des Forschungsschiffs Maria S. Merian unter der Fahrtleitung von Dr. T. J. Müller statt. Wissenschaftliches Programm Im Rahmen des internationalen Programms zur Untersuchung von Klimavariabilität (CLIVAR) werden seit dem Jahr 2000 im westlichen subtropischen Nordatlantik bei 16°N Volumentransporte des nordatlantischen Tiefenwassers als Teil des Kaltwasserzweiges der thermohalinen Zirkulation erfasst (Projekt MOVE). Da sich die Meridionalzirkulation nicht auf die westlichen Randströme beschränkt, müssen Messungen das gesamte Becken abdecken, wobei sich integrale Methoden anbieten. Mit der Aufnahme verankerter Geräte bei der Fahrt MSM04/1 werden die Messungen des IFM-GEOMAR zu MOVE abgeschlossen. Die Implementierung eines vergleichbaren Programms in 2004 im US-UK Projekt RAPID bei 26°N war jedoch Anlass, die Messungen bei MOVE im westlichen Atlantik durch das amerikanische Scripps Institution of Oceanography (SIO) fortzusetzen, wobei es im östlichen Atlantik durch die von IFM-GEOMAR neu implementierte Station bei den Kapverden transatlantisch vervollständigt wird. Die globale thermohaline Zirkulation (THZ) hat einen erheblichen Einfluss auf den Klimazustand, und es gibt eine Reihe von Indizien dafür, dass Schwankungen oder gar der Zusammenbruch der THZ eine Schlüsselrolle für die Klimavariabilität spielen. Numerische Simulationen haben eine Vielfalt an Prozessen gefunden, die zu solcher Variabilität auf zwischenjährlichen bis interdekadischen Zeitskalen führen, aber Beobachtungen derselben fehlten bisher weitgehend oder sind von zu kurzer Dauer bzw. Momentaufnahmen. Dies gilt auch für den vermutlich stärksten Zweig der THZ, nämlich das Nordatlantische Tiefenwasser (NADW) als Teil des Kaltwasserzweiges, und seine Ausbreitung im westlichen Nordatlantik. Die Ausbreitung des Tiefenwassers ist entgegen der klassischen Theorie nicht auf einen westlichen Randstrom beschränkt. Vielmehr können sich beckenweite großräumige Rezirkulationszellen bilden, so dass Messungen von Transporten ebenfalls beckenweit erfolgen müssen. Wegen günstig steiler Topographie eignet sich im westlichen Nordatlantik ein Schnitt von den französischen Antillen zum Mittelatlantischen Rücken bei 16°N gut zur direkten Messung im Transport von NADW mit integralen Methoden. Seit dem Jahr 2000 wurden deshalb im Projekt MOVE (Meridional Overturning Experiment) auf 16°N integrale Messungen mit verankerten Geräten (s. Abb. 1) zur Dichtemessung durchgeführt. Zusammen mit direkten Strömungsmessungen im westlichen Randstrom kann so der Gesamttransport und seine Variabilität abgeschätzt werden. Ergänzend werden invertierte Lotmessungen kombiniert mit Bodendrucksensoren (PIES) eingesetzt, die entlang und quer zum Schnitt und an Satellitenbahnen angepasst ein ‚ground truth’ zu den GRACE Satellitendaten geben und somit ebenso absolute Messungen der Schwankungen im Transport ergeben. Ziel von MOVE ist es den Einfluss der zwischenjährlichen Variabilität des NADW-Volumentransportes auf 16°N auf die THZ zu bestimmen typische ("mittlere") NADW-Transporte bei dieser Breite zu bestimmen Schwankungen des internen und externen Anteils an den Schwankungen im Transport abzuschätzen mögliche Zusammenhänge mit Variabilitäten im subpolaren und tropischen Atlantik zu untersuchen Seit Ende 2004 werden zusammen mit dem zeitgleich weiter nördlich bei 26°N transatlantisch britisch-amerikanischen Experiment RAPID die südwärts gerichtete Ausbreitung von Signalen in den Trans-portschwankungen des NADW gemessen. Mit der jetzigen Fahrt werden die Feldmessungen von IFM-GEOMAR im westli-chen Atlantik beendet. In einem amerika-nischen Programm des SIO sollen sie jetzt jedoch fortgesetzt und mit der kürzlich bei den Kapverden installierten Station des IFM-GEOMAR transatlantisch erweitert werden. Während der Fahrt MSM04/1 sollen hierzu die verankerten Geräte des IFM-GEOMAR bei den Positionen M3/M4 im Westen und M1 im Osten aufgenommen werden und durch amerikanische Geräte teilweise ersetzt werden. Einige der PIES lassen sich akustisch auslesen, so dass sie nicht aufgenommen werden müssen. Da die amerikanischen Kollegen die Arbeiten beim südlichen PIES auf einem ihrer Schiffe übernehmen, ist die Zeit gewon-nen, deren Verankerungen bei MSM04/1 auszulegen. Die weitere Auswertung wird im Schwerpunktprogramm „Massentransporte und Massenverteilung im System Erde“ der DFG erfolgen. FS MARIA S. MERIAN, Fahrt MSM04/1 03.12. – 21.12.2006 Fort de France – Fort de France Second Weekly Report, period 08.12.-14.12.2006

Description: Merian 4/1 Vom 01.12. bis 21.12.2006 fand die 4. Forschungsfahrt des Forschungsschiffs Maria S. Merian unter der Fahrtleitung von Dr. T. J. Müller statt. Wissenschaftliches Programm Im Rahmen des internationalen Programms zur Untersuchung von Klimavariabilität (CLIVAR) werden seit dem Jahr 2000 im westlichen subtropischen Nordatlantik bei 16°N Volumentransporte des nordatlantischen Tiefenwassers als Teil des Kaltwasserzweiges der thermohalinen Zirkulation erfasst (Projekt MOVE). Da sich die Meridionalzirkulation nicht auf die westlichen Randströme beschränkt, müssen Messungen das gesamte Becken abdecken, wobei sich integrale Methoden anbieten. Mit der Aufnahme verankerter Geräte bei der Fahrt MSM04/1 werden die Messungen des IFM-GEOMAR zu MOVE abgeschlossen. Die Implementierung eines vergleichbaren Programms in 2004 im US-UK Projekt RAPID bei 26°N war jedoch Anlass, die Messungen bei MOVE im westlichen Atlantik durch das amerikanische Scripps Institution of Oceanography (SIO) fortzusetzen, wobei es im östlichen Atlantik durch die von IFM-GEOMAR neu implementierte Station bei den Kapverden transatlantisch vervollständigt wird. Die globale thermohaline Zirkulation (THZ) hat einen erheblichen Einfluss auf den Klimazustand, und es gibt eine Reihe von Indizien dafür, dass Schwankungen oder gar der Zusammenbruch der THZ eine Schlüsselrolle für die Klimavariabilität spielen. Numerische Simulationen haben eine Vielfalt an Prozessen gefunden, die zu solcher Variabilität auf zwischenjährlichen bis interdekadischen Zeitskalen führen, aber Beobachtungen derselben fehlten bisher weitgehend oder sind von zu kurzer Dauer bzw. Momentaufnahmen. Dies gilt auch für den vermutlich stärksten Zweig der THZ, nämlich das Nordatlantische Tiefenwasser (NADW) als Teil des Kaltwasserzweiges, und seine Ausbreitung im westlichen Nordatlantik. Die Ausbreitung des Tiefenwassers ist entgegen der klassischen Theorie nicht auf einen westlichen Randstrom beschränkt. Vielmehr können sich beckenweite großräumige Rezirkulationszellen bilden, so dass Messungen von Transporten ebenfalls beckenweit erfolgen müssen. Wegen günstig steiler Topographie eignet sich im westlichen Nordatlantik ein Schnitt von den französischen Antillen zum Mittelatlantischen Rücken bei 16°N gut zur direkten Messung im Transport von NADW mit integralen Methoden. Seit dem Jahr 2000 wurden deshalb im Projekt MOVE (Meridional Overturning Experiment) auf 16°N integrale Messungen mit verankerten Geräten (s. Abb. 1) zur Dichtemessung durchgeführt. Zusammen mit direkten Strömungsmessungen im westlichen Randstrom kann so der Gesamttransport und seine Variabilität abgeschätzt werden. Ergänzend werden invertierte Lotmessungen kombiniert mit Bodendrucksensoren (PIES) eingesetzt, die entlang und quer zum Schnitt und an Satellitenbahnen angepasst ein ‚ground truth’ zu den GRACE Satellitendaten geben und somit ebenso absolute Messungen der Schwankungen im Transport ergeben. Ziel von MOVE ist es den Einfluss der zwischenjährlichen Variabilität des NADW-Volumentransportes auf 16°N auf die THZ zu bestimmen typische ("mittlere") NADW-Transporte bei dieser Breite zu bestimmen Schwankungen des internen und externen Anteils an den Schwankungen im Transport abzuschätzen mögliche Zusammenhänge mit Variabilitäten im subpolaren und tropischen Atlantik zu untersuchen Seit Ende 2004 werden zusammen mit dem zeitgleich weiter nördlich bei 26°N transatlantisch britisch-amerikanischen Experiment RAPID die südwärts gerichtete Ausbreitung von Signalen in den Trans-portschwankungen des NADW gemessen. Mit der jetzigen Fahrt werden die Feldmessungen von IFM-GEOMAR im westli-chen Atlantik beendet. In einem amerika-nischen Programm des SIO sollen sie jetzt jedoch fortgesetzt und mit der kürzlich bei den Kapverden installierten Station des IFM-GEOMAR transatlantisch erweitert werden. Während der Fahrt MSM04/1 sollen hierzu die verankerten Geräte des IFM-GEOMAR bei den Positionen M3/M4 im Westen und M1 im Osten aufgenommen werden und durch amerikanische Geräte teilweise ersetzt werden. Einige der PIES lassen sich akustisch auslesen, so dass sie nicht aufgenommen werden müssen. Da die amerikanischen Kollegen die Arbeiten beim südlichen PIES auf einem ihrer Schiffe übernehmen, ist die Zeit gewon-nen, deren Verankerungen bei MSM04/1 auszulegen. Die weitere Auswertung wird im Schwerpunktprogramm „Massentransporte und Massenverteilung im System Erde“ der DFG erfolgen. FS MARIA S. MERIAN, Fahrt MSM04/1 03.12. – 21.12.2006 Fort de France – Fort de France First Weekly Report, period 01.12.-07.12.2006

Description: Sonne 190/2 Am 11.11. startete die 190. Forschungsfahrt des Forschungsschiffs SONNE unter der Fahrtleitung von Prof. Dr. E. Flüh. SINDBAD SO 190 – 2 1. Wochenbericht

Description: Sonne 190/2 Am 11.11. startete die 190. Forschungsfahrt des Forschungsschiffs SONNE unter der Fahrtleitung von Prof. Dr. E. Flüh. SINDBAD SO 190 – 2 2. Wochenbericht

Description: Der 3. Fahrtabschnitt der 1. Reise des neuesten deutschen Forschungsschiffes Maria S. Merian führt in die Schlammvulkanprovinz des Golf von Cadiz. Hier sollen Untersuchungen von biogeochemischen Stoffumsätzen, Fluid- und Gas-Flüssen an spezifischen Ökosystemen wie anoxischen Lebensgemeinschaften und azooxanthellaten Steinkorallen durchgeführt werden. Die Fahrt, die in 2 Unterabschnitte geteilt ist, beginnt in Kiel gefolgt von einem Zwischenstopp in Cadiz (Spanien) und endet in Lissabon (Portugal). MSM- 1/3 ist eine multidisziplinäre Expedition mit biologischen, geologischen und hydrographischen Fragestellungen. Ein Teil der Untersuchungen wird im Rahmen des „Geotechnologien” Programms des BMBF und der DFG für den Schwerpunkt „Methan im Geo-/Biosystem” durch das am IFM-GEOMAR koordinierte und für das ebenfalls hier schwerpunktmäßig angesiedelte Programm COMET (Controls on methane fluxes and their climatic relevance in marine gas hydrate-bearing environments) durchgeführt. Ein weiterer Teil der Ausfahrt dient den Untersuchungen im Rahmen des FP-6 Programms der EU HERMES (Hotspot Ecosystem Research on the Margins of European Seas). Aus dem HERMES-Programm nehmen 6 Partner teil. Beide Forschungsvorhaben sind sehr umfangreich und in ihrer Thematik komplex. Es gibt neben der geographischen Orientierung auf das Gebiet des Golf von Cadiz eine Vielzahl von inhaltlichen, personellen und logistischen Verbindungen zwischen beiden Programmen. Golf von Cadiz: Geologischer Hintergrund Die Region des Golf von Cadiz hat eine sehr komplexe geologische Geschichte. Sie ist seit der Trias durch mehrere tektonische Phasen mit Extension, Kompression und Lateralverschiebungen gekennzeichnet. Während des Mesozoikums und frühen Känozoikums bildeten sich in diesem Gebiet Bruchzonen mit Halbgraben-Strukturen und Karbonatplattformen. Im Torton verlagerte sich der Gibraltar-Bogen nach Westen. Dadurch wurde der Golf von Cadiz zu einem Forearc-Becken, in das Olistostrome (Rutschmassen) hineinglitten. In diesem Ablagerungsmilieu, das sonst für Akkretionskeile charakteristisch ist, wurden die Sedimente des südiberischen und nordafrikanischen Kontinentalrandes der damaligen Tethys stark deformiert. Die Olistostrom-Bildung war im oberen Miozän beendet. Gleichzeitig nahm die Subsidenz des Gebietes zu, und es kam zur Ausbildung von mächtigen Abfolgen progradierender und aggradierender Vorschüttfächer. Die geodynamische Interpretation dieser tektonisch sehr komplexen Region ist bis heute kontrovers. Der Gibraltarbogen liegt am östlichen Ausläufer der Azoren-Gibraltar Transformstörung, die als transpressionelle Grenze der iberischen und afrikanischen Platte gesehen wird. Die NW-SE gerichtete Konvergenz dieser beiden Platten zeigt sehr langsame Relativbewegungen von nur 4 mm pro Jahr. Die Ergebnisse neuester geophysikalischer Untersuchungen weisen jedoch darauf hin, dass auch eine ostwärtige Subduktion unter den Gibraltar-Bogen die gegensätzlichen Beobachtungen tektonischer Phänomene aus dem Riffgebirge und der Bethischen Kordillere erklären kann. Eine westwärts gerichtete Gegenrotation erzeugt Krustendehnung und damit Subsidenz in der Alboran See, während die damit verbundene westwärtige Verlagerung des Gibraltar-Bogens eine kompressionelle Deformation des Atlantis-Akkretionskeiles bewirkt. Es ist zu erwarten, dass die aktive Subduktion im Golf von Cadiz einen starken Einfluss auf das natürliche Gefahrenpotential dieser Region ausübt. Sie muss beispielsweise als Ursache für das große Erdbeben von 1755 gesehen werden (Stärke 8.5), durch das und den nachfolgenden Tsunami schwere Schäden in Lissabon und im angrenzenden Küstengebiet des Golf von Cadiz verursacht wurden. Diese historischen Ereignisse sind ein gewichtiger Grund dafür, dass der Golf von Cadiz eine Schlüsselregion für Europäische Forschungsaktivitäten und instrumenteller Langzeitbeobachtungen im Rahmen der EU-Programme ESONET, HERMES und EuroSEIZE bildet. Aus den Ergebnissen verschiedener Expeditionen ergeben sich viele Hinweise auf weit verbreitete Fluidaustritte, Karbonatmounds mit Tiefwasserkorallen (Lophelia-Skelette), Kohlenwasserstoff-Gasaustritte und Schlammdiapirismus am portugiesischen, spanischen und marokkanischen Kontinentalrand des Golf von Cadiz. Diese Phänomene wurden als Indikatoren für die weit verbreitete Existenz von gasübersättigten Sedimenten und der Migration von Fluiden diffusiv durch die Sedimente oder advektiv entlang von tektonischen Störungen interpretiert.

Description: The emphasis of this review is on linear furano- and pyrroloterpenoids, together with their relevant biological activities, source organisms and country of origin. First total syntheses that lead to the revision of structures or stereochemistries have been included, and 206 references are cited.

Description: Polycyclic aromatic hydrocarbons (PAHs) are key contaminants of concern under the Arctic Environmental Monitoring Programme (AMAP) due to their carcinogenic potential. The concentration of the different PAH components may be connected to the geochemical background of the sediments, including leakage and erosion of fossil carbon, as well as epigenetic processes such as decaying peat. In other cases there is a human influence connected to petroleum spills or combustion of fossil fuel or other human activities. The overall goal of this study was to identify and analyze existing comparable datasets on PAHs from Norwegian and Russian arctic shelves, and use the concentration and composition of PAH components in the selected datasets to assess baseline concentration of PAH, geographical anomalies and sources and routes of transport, as well as the human impact. PAHs in 330 samples of surface sediment from the Barents and Kara Sea shelves, collected during the period 1991-1998, have been selected for the study. In the Southwest Barents Sea the nature of PAHs is formed by a complex sedimentation regime made up of inflowing Atlantic and North Sea water, coastal discharges, coastal abrasion and atmospheric transport. The PAHs basically correspond to background compositions with a low but notable anthropogenic influence. In the Northern Barents Sea both concentration and composition of PAHs are genetically (genesis, conditions and level of transformation) connected with eroded sediment material from the Spitsbergen and Franz Josef Land archipelagos. The relative high PAH levels observed off Spitsbergen thus generally may have a non- anthropogenic explanation. In the central part of the Barents Sea the PAH levels in the deep-water bottom sediments are generally low, non-anthropogenic in origin, and determined by endogenous processes. Erosion and re-deposition of Novaya Zemlya strata do not have a significant influence on PAH composition in this part of the Barents Sea. In the Southeast Barents Sea (Pechora Sea) the PAH composition corresponds, in general, well with the PAH allocation in the Barents Sea. However, the terrigenous influence is stronger. The PAH composition exhibits both epigenetic processes (such as the high level of perylene which most probably is derived from decaying peat) and the presence of petrogenic PAH. The latter findings may be due to the influx of rivers draining oil-rich onshore territories. In estuaries and offshore the Kara Sea the PAH composition of bottom sediments reflects the significant influence of river run-off (with the same patterns as in the Pechora Sea), but also atmospheric transport of combustion derived PAHs, most probably from the smelters in Norilsk.

Description: Data on the zooplankton community structure, gut evacuation rate and carbon content of zooplankton faecal pellets were used for assessing the contribution of zooplankton to vertical carbon fluxes in the White and Kara Seas. The results revealed strong regional and seasonal variations of pellet carbon input related to differences in structure and dynamics of the zooplankton communities in the regions studied. In the deep regions of the White Sea, maximum daily pellet carbon flux from the 0-50 m layer was observed in the spring. It reached 98 mg Corg m-2 day-1 and coincided with a strong predominance of the large arctic herbivorous copepod Calanus glacialis in the surface layers. In summer and fall, it decreased by 1 to 2 orders of magnitude due to migration of this copepod to its overwintering depths. In contrast, in the shallow coastal regions, the pellet production was low in spring, gradually increased during summer and reached its maximum of 138 mg Corg m-2 day-1 by late summer to beginning of autumn. Such a seasonal pattern was in accordance with the seasonal variation of abundance of major pellet producers, the small boreal copepods Acartia bifilosa, Centropages hamatus, and Temora longicornis. In the estuarine zone of the Kara Sea, the pellet flux was mostly formed by pellets of brackish-water omnivorous copepods. It varied from 35 mg Corg m-2 day-1 in 1997 to 96 mg Corg m-2 day-1 in 1999. In the central Kara Sea with its typical marine community, the daily flux reached 125 mg Corg m-2 day-1 in summer. The results of our calculations indicate that both in the White and Kara seas zooplankton pellet carbon contributes up to 30 % to the total carbon flux during particular seasons.

Description: Based on the study of aquatic palynomorph assemblages in two Holocene sediment cores obtained from the eastern Laptev Sea shelf, the main stages in the postglacial transgression are reconstructed for the last 11.3 ky. During that period, the inner shelf of the Laptev Sea (sea depth of 51 m) was already flooded representing an area of intense freshwater sedimentation in the immediate proximity from the river mouth in the period of 11.3 to 10.3 ky B.P. Approximately 1.0–1.5 ky later, the inner shelf (sea depth of 32 m) was flooded, although it remained under the influence of the river runoff up to 7.4 ky B.P. The period of 10.3–7.4 ky B.P. was marked by the dominant dinoflagellate cysts Operculodinium centrocarpum among the aquatic palynomorphs, the appearance of more thermophilic dinoflagellate species, and elevated values of the AH ratio, which indicates an enhanced influx of relatively warm North Atlantic waters to the Laptev Sea shelf. The environment close to the present-day one became dominant on the outer and inner shelf of the Laptev Sea approximately 8.6 and 7.4 ky B.P., respectively.

Description: A variety of methods were successfully applied to examine the efficacy of a modular ballast water system according to the standards as adopted by the International Maritime Organization. The ballast water treatment system had a capacity of 530 m3 h−1 consisted of a pump system, a hydrocyclone, a 50 μm mesh-size self-cleaning filter and an installation for the addition of a chemical disinfectant (PERACLEAN® Ocean). The land-based testing facility used natural sea water of high turbidity during the spring phytoplankton bloom. The mesozooplankton fraction was inspected with a standard binocular. Larger zooplankton were effectively removed with the filter; the smaller sized fraction containing larvae and nauplia were killed after chemical treatment. The phytoplankton component was monitored using flow cytometry. The huge colonies of the phytoplankton Phaeocystis globosa were disrupted in the hydrocyclone liberating the colony cells which passed as single cells through the filter. These cells remained viable but were finally killed in the secondary (chemical) step. Bacteria also passed all mechanical treatment steps unharmed but were killed in the final step. Viability tests with SYTOX Green, which were specifically designed for phytoplankton, showed that mechanical treatment did not affect the percentage of viable cells a short-term, but after several hours the viable cell counts dropped down to 70%. Phytoplankton cells recovered within a single day and formed a new dense bloom rapidly. The bacteriostatic component of the chemical disinfectant (H2O2) remained present for several days preventing regrowth of bacteria for up to 15 days after addition. In conclusion, the IMO standards were met using the modular ballast water treatment unit and the applied instruments and assays were effective and rapid tools to qualify and quantify the organisms present as well as their viability.

Description: Es ist nicht zuletzt den Wissenschaftlern und Forschern des Leibniz-Instituts für Meereswissenschaften an der Universität Kiel (IFM-GEOMAR) zu verdanken, dass wir von Jahr zu Jahr mehr über das Meer erfahren. Hier beschäftigen sich neben den Meereswissenschaftlern auch Geologen, Biologen, Vulkanologen und Meteorologen mit vielen Fragen rund um die blauen Riesen. Gibt es Leben in der Tiefsee? Warum brechen Vulkane aus? Sind Algen Tiere? Warum gibt es Tsunamis? Sind Feuerquallen giftig? Wie tief ist der Ozean? Was sind Gashydrate? Wie verraten Steine unsere Geschichte? Warum leuchten manche Tiere im Dunkeln? Wie atmen Fische unter Wasser? Eben solche Fragen beschäftigen jedoch nicht nur die klugen Köpfe weltweit. Auch Kinder sind kleine Forscher. Ihre Neugier ist unermesslich, ihr Wissensdurst oft schwerlich zu stillen. Diesen kindlichen Lerndrang wollen wir nutzen um in kurzen Episoden die acht- bis zehnjährigen Kinder anzuregen und zu motivieren sich aktiv mit dem Thema Meer auseinander zu setzen. Dabei geht es also nicht um reine Wissensvermittlung. Vielmehr ist es unser Ziel, Kinder entsprechend ihrer Veranlagung, früh mit den Naturwissenschaften in Kontakt zu bringen. Das Ziel der Bachelor-Thesis ist die Erstellung eines Konzeptes für diesen meereswissenschaftlichen Film. Dazu haben wir zunächst anhand von bestehenden Informationsformaten und umfangreich vorliegender Literatur die Rahmenbedingungen für solch einen Film analysiert und abgesteckt. Dabei haben wir neben der Ton-, Bild- und Sendungsanalyse wert auf die Fähigkeiten und Fertigkeiten von Kindern im Umgang mit dem Medium Fernsehen gelegt. Wie der Speicherprozess von Informationen neuropsychologisch passiert, haben wir an dieser Stelle nicht betrachtet. Aus der Analyse entstand in der zweiten Hälfte der Arbeit das Konzept für den meereswissenschaftlichen Film. Auf der Grundlage der abgesteckten Rahmenbedingungen haben wir die Rahmenhandlung entwickelt und die Informationsebenen des Films definiert. Abschließend gibt der Ausblick einen Eindruck, welche Probleme uns bei der Umsetzung des Filmes erwarten. Außerdem zeigen wir auf, an welchen Stellen der Film in der Öffentlichkeitsarbeit eingesetzt werden und dieses Konzept als Grundlage für weitere Filme dienen kann.

Description: This study was performed to investigate gas formation and gas saturation conditions related to acoustic turbidity in shallow (∼40 m deep) marine basins. The Arkona Basin, Baltic Sea, with its organic-rich fine-grained surface sediment provides an ideal “Natural Laboratory” to characterise free gas using seismic, geoacoustic, and geochemical methods. The area of acoustic turbidity covers about 1500 km2 of the central Arkona Basin, corresponding to areas where organic-rich post-glacial sediments exceed 4–6 m in thickness. The highest concentration of pore water methane (7660 μmol L−1), found in areas of high acoustic turbidity, was near the calculated lower limit of methane solubility for the measured in situ temperature, salinity, and pressure. Pore water methane concentration decreased to near 4 μmol L−1 in areas outside of the zone of high acoustic turbidity. Stable carbon (−70.7‰ to −92.3‰ PDB) and hydrogen (−124‰ to −185‰ SMOW) isotope values of methane indicate that methane is predominantly formed by microbial CO2 reduction in Arkona Basin surface sediments and rules out significant contributions of other sources.

Description: The study of interfacial properties in the marine environment is important for the understanding of air-sea gas exchange processes, especially with respect to the behaviour of entrained air bubbles. Seawater contains surfactant material, much of which is thought to origin from the exudation of dissolved organic material (DOM) by phytoplankton. This study aims at investigating the influence of different phytoplankton species on the surface shear viscosity of an air-water interface. Measurements of surface shear viscosity were carried out with the ISR1 interfacial shear rheometer. Surface shear viscosities of stock cultures of Phaeocystis sp., Thalassiosira rotula, Thalassiosira punctigera and Nitzschia closterium as well as of F/2 nutrient medium and seawater were measured. The surface shear viscosity of N. closterium was investigated during different stages of its growth as well as for an unfiltered stock culture sample and its filtrate. Results reveal that the influence of phytoplankton on the surface shear viscosity is species specific. An increase in surface shear viscosity occurred for the N. closterium stock culture only. The remaining cultures showed similar behaviour to F/2 nutrient medium. The increase of surface shear viscosity during the growth of N. closterium occurred mainly during the exponential growth phase. The increases in surface shear viscosity depend on the presence of phytoplankton cells in the sample. The formation of compact mechanical structures at the air-water interface originating from the aggregation of DOM released by N. closterium as a cause for the observed increases in surface shear viscosity is discussed.

Description: Sampling an intact sequence of oceanic crust through lavas, dikes, and gabbros is necessary to advance the understanding of the formation and evolution of crust formed at mid-ocean ridges, but it has been an elusive goal of scientific ocean drilling for decades. Recent drilling in the eastern Pacific Ocean in Hole 1256D reached gabbro within seismic layer 2, 1157 meters into crust formed at a superfast spreading rate. The gabbros are the crystallized melt lenses that formed beneath a mid-ocean ridge. The depth at which gabbro was reached confirms predictions extrapolated from seismic experiments at modern mid-ocean ridges: Melt lenses occur at shallower depths at faster spreading rates. The gabbros intrude metamorphosed sheeted dikes and have compositions similar to the overlying lavas, precluding formation of the cumulate lower oceanic crust from melt lenses so far penetrated by Hole 1256D.

Description: On the basis of a detailed study of the diatom and aquatic palynomorph assemblages and a detailed radiocarbon chronology of sediment cores obtained from the south-eastern inner Laptev Sea shelf adjacent to the Lena Delta the spatial and temporal variability in the Lena River discharge during the last 6 cal. ka were reconstructed. It was shown that in the area adjacent to the Lena Delta variations in surface water salinities, reconstructed using freshwater diatoms as a proxy, were mainly caused by changes in the volume of the Lena River runoff through the major riverine channels Trofimovskaya, Bykovskaya and Tumatskaya. Several paleohydrological phases are recognized: (i) establishment of modern-like conditions within the eastern Lena River Valley occurred from 6-4.2 cal. ka; (ii) Lena River outflow increased in north-eastward direction via the Trofimovskaya or Bykovskaya channels from 4.2-2.7 cal. ka, coeval with a reduction of runoff toward the north via the Tumatskaya Channel; (iii) generally stable hydrological conditions northward of the Tumatskaya Channel and variations in riverine discharge north-eastward of the Trofimovskaya and Bykovskaya channels prevail since 2.7 cal. ka. Using indicator species of dinocysts as principle marine proxy, an influence of Atlantic water to the southeast inner Laptev Sea shelf could be inferred, possibly along the Eastern Lena paleovalley, brought into this area by winddriven reversed bottom currents. Zusammenfassung: Untersuchungen von Diatomeen- und aquatischen Palynomorphen-Vergesellschaftungen wurden an Radiokohlenstoff datierten Sedimentkernen aus der inneren südöstlichen Laptevsee nahe des Lenadeltas durchgeführt. Anhand dieser Daten wurde die zeitliche und räumliche Veränderlichkeit des Flusswasserausstromes der Lena für die letzten 6 ka (Kalenderjahre) rekonstruiert. Zeitliche Veränderungen in den Häufigkeiten von Süßwasserdiatomeen sind begründet durch Wechsel in der Menge des Lenaausflusses durch die drei großen Haupkanäle im Delta: Trofimovskaja, Bykovskja, sowie Tumatskaja. Darauf basierend konnten prinzipiell drei große paläohydrologische Phasen unterschieden werden: (1) heutigen Verhältnissen vergleichbare Bedingungen wurden östlich des Lenadeltas zwischen 6 und 4.2 ka etabliert; (2) Erhöhung des Flusswasseraustrags in nordöstliche Richtung über die Kanäle Trofimovskaja und/oder Bykovskaja zwischen 4.2 und 2.7 ka bei gleichzeitiger Reduzierung Richtung Norden via Tumatskaja; (3) Ausbildung relativ stabiler Bedingungen nördlich des Deltas sowie Auftreten wechselhafter Flusswasserausträgen in östliche Richtung nach 2.7 ka. Das Auftreten von marinen Dinocysten in den Sedimenkernen belegt den Einfluss von Wassermassen mit vermutlich atlantischem Ursprung. Es ist zu vermuten, dass diese durch windgetriebene Bodenströmungen entlang der alten versunkenen Flusstäler auf den östlichen inneren Schelf verfrachtet werden.

Description: Uptake of half of the fossil fuel CO2 into the ocean causes gradual seawater acidification. This has been shown to slow down calcification of major calcifying groups, such as corals, foraminifera, and coccolithophores. Here we show that two of the most productive marine calcifying species, the coccolithophores Coccolithus pelagicus and Calcidiscus leptoporus, do not follow the CO2-related calcification response previously found. In batch culture experiments, particulate inorganic carbon (PIC) of C. leptoporus changes with increasing CO2 concentration in a nonlinear relationship. A PIC optimum curve is obtained, with a maximum value at present-day surface ocean pCO2 levels (∼360 ppm CO2). With particulate organic carbon (POC) remaining constant over the range of CO2 concentrations, the PIC/POC ratio also shows an optimum curve. In the C. pelagicus cultures, neither PIC nor POC changes significantly over the CO2 range tested, yielding a stable PIC/POC ratio. Since growth rate in both species did not change with pCO2, POC and PIC production show the same pattern as POC and PIC. The two investigated species respond differently to changes in the seawater carbonate chemistry, highlighting the need to consider species-specific effects when evaluating whole ecosystem responses. Changes of calcification rate (PIC production) were highly correlated to changes in coccolith morphology. Since our experimental results suggest altered coccolith morphology (at least in the case of C. leptoporus) in the geological past, coccoliths originating from sedimentary records of periods with different CO2 levels were analyzed. Analysis of sediment samples was performed on six cores obtained from locations well above the lysocline and covering a range of latitudes throughout the Atlantic Ocean. Scanning electron micrograph analysis of coccolith morphologies did not reveal any evidence for significant numbers of incomplete or malformed coccoliths of C. pelagicus and C. leptoporus in last glacial maximum and Holocene sediments. The discrepancy between experimental and geological results might be explained by adaptation to changing carbonate chemistry.

Description: Six new linear peptides, pterulamides I−VI (1−6), were isolated from the fruiting bodies of a Malaysian Pterula species. The structures were elucidated by MS and 2D NMR experiments, and the absolute configurations of the constituent amino acids established using Marfey's method. The pterulamides are mainly assembled from nonpolar N-methylated amino acids and, most interestingly, have non-amino-acid N-terminal groups, among them the unusual cinnamoyl, (E)-3-methylsulfinylpropenoyl, and (E)-3-methylthiopropenoyl groups. Furthermore, pterulamides I−V are the first natural peptides with a methylamide C-terminus. Pterulamides I and IV are cytotoxic against the P388 cell line with IC50 values of 0.55 and 0.95 μg/mL (0.79 and 1.33 μM), respectively.

Description: Deposits and transport processes resulting from the resedimentation of cold, unconsolidated ignimbrite into water were simulated by flume experiments. The ignimbrite sample used was poorly sorted (σ = 2·4–3), fine ash-rich (〈 63 μm, 17–30 wt%) and included both dense lithic clasts (〉 2000 kg m−3) and pumice (500 to ca 1300 kg m−3). As a result of the binding forces of the ash matrix, the experiments involved resedimentation from a steep front onto the floor (with or without an initial ramp) of the water-filled tank under both still and wave-generated conditions. Larger discrete collapse events were induced by oversteepening the sample front and by undercutting from wave action. The mass of the collapse and proportion of pore–space water strongly influenced the style of resedimentation and the deposits. Initial collapse events were from the top of the steep front and fell onto the floor. The largest, densest clasts were deposited as a lithic lag in a proximal sediment wedge or rolled down to a break-in-slope. Fine ash was transported in dilute turbidity currents, and coarse unsaturated pumice clasts floated off. Moderate collapse events generated high-density turbidity currents, trapping pumice in the flow, causing them to saturate. These low-density pumice clasts were easily remobilized by wave activity and passing currents and accumulated on the gentle slope at the bottom of the resedimented deposit. Large collapse events slumped, producing poorly sorted mounds similar in texture to the original starting material. As the matrix of the ignimbrite sample became saturated with water, moderate and large collapse events generated debrisflows and slurries that deposited massive, poorly sorted deposits. Furthermore, once more gentle slopes were established between the sample and deposit, small cascading grainflows deposited lithic clasts on the upper slopes and levees of pumice at the terminus of low-relief, ash channels. The experiments show that, excluding large collapse events and debrisflows, resedimenting ignimbrite in water is effective at segregating low-density pumice clasts from dense lithic clasts and fine ash. Experiments using fine-ash poor ignimbrite and well-sorted quartz sand for comparison formed an inherently unstable initial steep front that immediately collapsed by continuous grain avalanches. The grainflow deposits had textures similar to the fines-poor starting material.

Description: To date no study exists that directly addresses changes in dynamics of heterotrophic bacteria in surface waters in relation to partial pressure of CO2 (pCO2). Therefore, we studied the effect of changes in pCO2 on bacterial abundance and activities by using mesocosms with different pCO2 levels (~190, ~370, and ~700 ppmV, representing past, present-day, and future atmospheric pCO2, respectively). Abundance of total bacteria did not differ with increasing pCO2 throughout the whole study period, whereas bacterial protein production (BPP) was highest at highest pCO2. This effect was even more pronounced for cell-specific production rates, especially those of attached bacteria, which were up to 25 times higher than those of free bacteria. During the breakdown of the bloom, however, the abundance of both free and attached bacteria was significantly increased with pCO2. Differences in bacterial growth rate (µ) were smaller than those of BPP, but both µ and BPP of attached bacteria were elevated under high pCO2. Averages of total protease as well as α- and α -glucosidase activities were highest at elevated pCO2 levels, but a statistically significant dependence on pCO2 was only evident for protease activity. There is a measurable but indirect effect of changes in pCO2 on bacterial activities that are mainly linked to phytoplankton and presumably particle dynamics

Description: The early life-history of Chinese rock carp Procypris rabaudi was investigated during a 56-day rearing period: 318 artificially propagated P. rabaudi larvae were reared throughout metamorphosis in a small-scale recirculation system (345 L water volume, 10 × 18 L rearing tanks, 150 L storage and filter compartment with bioballs, 20–30 larvae L−1) at the Institute of Hydrobiology, Wuhan, Hubei Province, China. The newly hatched larvae had an initial total length of 8.93 ± 0.35 mm SD (n = 10) at 3 days post-hatch and reached an average total length of 33.29 mm (±1.88 mm SD, n = 10) 56 days after hatching. Length increment averaged 0.45 mm day−1, resulting in a mean growth of 24.4 mm within the 56-day period. High mortality rates of up to 92% derived from an introduced fungus infection and subsequent treatment stress with malachite green. Our results indicate that Chinese rock carp can be raised successfully from artificially fertilized eggs. We therefore assume this species to be a candidate for commercial aquaculture.

Description: During the MARGASCH cruise M52/1 in 2001 with RV Meteor we sampled surface sediments from three stations in the crater of the Dvurechenskii mud volcano (DMV, located in the Sorokin Trough of the Black Sea) and one reference station situated 15 km to the northeast of the DMV. We analysed the pore water for sulphide, methane, alkalinity, sulphate, and chloride concentrations and determined the concentrations of particulate organic carbon, carbonate and sulphur in surface sediments. Rates of anaerobic oxidation of methane (AOM) were determined using a radiotracer (14CH4) incubation method. Numerical transport-reaction models were applied to derive the velocity of upward fluid flow through the quiescently dewatering DMV, to calculate rates of AOM in surface sediments, and to determine methane fluxes into the overlying water column. According to the model, AOM consumes 79% of the average methane flux from depth (8.9 · 10+ 6 mol a− 1), such that the resulting dissolved methane emission from the volcano into the overlying bottom water can be determined as 1.9 · 10+ 6 mol a− 1. If it is assumed that all submarine mud volcanoes (SMVs) in the Black Sea are at an activity level like the DMV, the resulting seepage represents less than 0.1% of the total methane flux into this anoxic marginal sea. The new data from the DMV and previously published studies indicate that an average SMV emits about 2.0 · 10+ 6 mol a− 1 into the ocean via quiescent dewatering. The global flux of dissolved methane from SMVs into the ocean is estimated to fall into the order of 10+ 10 mol a− 1. Additional methane fluxes arise during periods of active mud expulsion and gas bubbling occurring episodically at the DMV and other SMVs

Description: Phagotrophy and competitive ability of the mixotrophic Ochromonas minima were investigated in a three-factorial experiment where light intensity (low: 1.0 μmol m−2 s−1 and high: 60 μmol m−2 s−1 PPFD), nutrient concentration (ambient: 7.0 μmol N l−1, 0.11 μmol P l−1 and enriched: 88 μmol N l−1, 6.3 μmol P l−1) and DOC supply (without and with enrichment, 250 μmol C l−1) were manipulated. Ochromonas minima and bacterial abundance were monitored for 12 days. We found significant and interacting effects of light and nutrients on Ochromonas minima growth rate and abundance. At high light intensity, nutrient enrichment resulted in increased growth rates and population sizes. In contrast, reduced growth rates and population sizes were observed for nutrient enrichment when light intensity was low. Although, Ochromonas minima was able to ingest bacteria under both high and low light conditions, it grew only when light intensity was high. At high light intensity, Ochromonas minima grew exponentially under nutrient conditions that would have been limiting for photoautotrophic microalgae. In non-enriched low light treatments, Ochromonas minima populations survived, probably by using background DOC as an energy source, indicating that this ability can be of relevance for natural systems even when DOC concentrations are relatively low. When competing with photoautotrophic microalgae, the ability to grow under severe nutrient limitation and to survive under light limitation should be advantageous for Ochromonas minima.

Description: The distribution of diatoms, radiolarians, planktonic and benthic foraminifers, and sediment components in the fraction 〉0.125 mm was analyzed in the core obtained from the central Sea of Okhotsk within the frameworks of the Russian-German KOMEX project. The core section characterizes the period 190–350 ka, which corresponds to marine-isotopic stages (MIS) 7 to 10. During glacial MIS 10 and MIS 8, the basin accumulated terrigenous material lacking microfossils or containing them in low abundance, which reflects, along with their composition, heavy sea-ice conditions, suppressed bioproductivity, and bottom environments aggressive toward calcium carbonate. Interglacial MIS 9 was characterized by elevated bioproductivity with accumulation of diatomaceous ooze during the climatic optimum (328 to 320 ka). The water exchange with the Pacific was maximal from 328 to 324 ka ago. Environments became moderate and close to the present-day ones at the end of the optimum exhibiting the possible existence of a dichothermal layer with substantial amounts of the surface Pacific water still flowing into the basin. Similar to interglacial MIS 5e and MIS 1, the “old” Pacific water determined near-bottom environments in the central Sea of Okhotsk during that period, although the influx of terrigenous material was higher, probably reflecting a more humid climate of the region. Slight warming marked the terminal MIS 8 (approximately 260 ka ago). The paleoceanographic situation during interglacial MIS 7 was highly variable: from warm-water to almost glacial. The main climatic optimum of MIS 7 occurred within 220–210 ka, when the subsurface stratification increased and the dichothermal layer developed. Bottom environments during the studied time interval, except for the optimum of interglacial MIS 9, resembled those characteristic of glacial periods: the actively formed “young” Okhotsk water displaced the “old” Pacific deep water.

Description: K-feldspar is a common detrital mineral in sandstones. It contains little U or Th, and hence the common Pb isotope composition of unaltered K-feldspar is that of the source rock. Pb isotope variations in igneous and metamorphic crustal rocks define broad spatial patterns that make the Pb signature of detrital K-feldspar grains a useful provenance tool. However, it is unclear how robust this signal is, and to what extent it can be modified by weathering, transport, burial diagenesis, and/or exposure to hydrothermal fluids. This study reports an evaluation of the technique, using two granite–arkose pairs (from Helmsdale, northern Scotland, and Shap, northwest England) where the composition of the detrital grains can be compared to feldspars in the granite from which they were derived. The results of this test have informed a pilot study using the Pb isotope composition of detrital K-feldspar in Upper Carboniferous fluvial sedimentary rocks of northern England to constrain the sediment routing. Pb isotope compositions have been measured using an in situ high-resolution single-grain technique that can distinguish original composition, heterogeneity, and subsequent alteration within individual sand grains. The results for the granite–arkose pairs show that the common Pb isotope signature of the detrital K-feldspar grains matches the in situ feldspars in the source granites. The signal is independent of grain size (medium-grained sand to granules), but alteration along a paleo-regolith at Helmsdale has resulted in perturbations in Pb composition and an increase in the errors on the analyses. The application of the technique to arkosic Carboniferous (Serpukhovian–Bashkirian) Millstone Grit Group sandstones in the Pennine Basin reveals two discrete populations of K-feldspars that cannot be distinguished petrographically. Matching of the compositions to potential sourcelands to the north and northeast of the basin suggest a far-traveled (〉 500 km) source of K-feldspar from the Archean–Paleoproterozoic Lewisian rocks of northwest Scotland or their extension to the north, but also an equally important proximal source emanating from the Southern Uplands Belt of Scotland in what would have been the lower part of the hinterland drainage basin of the Millstone Grit.