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  • 1
    Call number: ZSP-271-29
    In: Examensarbeit / Max-Planck-Institut für Meteorologie ; 29
    Type of Medium: Dissertations
    Pages: IV, 109 S. , Ill., graph. Darst., Kt
    ISSN: 0938-5177
    Series Statement: Max-Planck-Institut für Meteorologie Examensarbeit 29
    Note: Zugl.: Hamburg, Univ., FB Geowiss., Diss., 1995 , Inhaltsverzeichnis: 1. Einleitung. - 2. Beschreibung des Chemie-Transport-Modells. - 2.1. Das Chemie-Transport-Modell des EURAD-Systems. - 2.2. Anpassung des Chemie-Transport-Modells an die Hamburger Klimamodellumgebung. - 3. Bedeutung der Wolkenparametrisierung für ein Chemie-Transport-Modell. - 3.1. Wolkenmodule im EURAD-System. - 3.2. Wolkenmodule im Hamburger Modellsystem. - 4. Der Gasphasen-Chemiemechanismus. - 4.1. Vereinfachung photochemischer Reaktionsmechanismen. - 4.2. Das Gasphasen-Chemiemodul. - 4.3. Optimierung des Gasphasen-Chemiemoduls. - 5. Modellrechnungen. - 5.1. Simulation einer Winterepisode. - 5.1.1. Die synoptische Situation vom 13.1.1991 bis zum 23.1.1991. - 5.1.2. Modellergebnisse und Vergleich mit Beobachtungen. - 5.2. Simulation einer Sommerepisode. - 5.2.1. Photochemische Ozonbildung. - 5.2.2. Die synoptische Situation vom 23.7.1990 bis zum 31.7.1990. - 5.2.3. Modellergebnisse und Vergleich mit Beobachtungen. - 5.2.4. Sensitivitätsstudien. - 6. Ausblick. - Anhang 1: Koordinatensysteme und Koordinatentransformation. - Anhang 2: Spurenstoffe des Gasphasenchemiemechanismus. - Anhang 3: Nadel- und Laubwaldbedeckungsdichte in Europa. - 7. Literatur.
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  • 2
    Monograph available for loan
    Monograph available for loan
    Cambridge : Cambridge University Press
    Call number: AWI A12-95-0117
    Type of Medium: Monograph available for loan
    Pages: X, 206 Seiten , Illustrationen , 23 cm
    Edition: First published
    ISBN: 0-521-47387-X , 0-521-47933-9
    Language: English
    Note: Contents Preface 1 Chemical equilibrium 1.1 Some introductory concepts 1.2 Equilibrium constants 1.3 Reaction quotient 1.4 LeChatelier' s principle Exercises 2 Chemical thermodynamics 2.1 The first law of thermodynamics; enthalpy 2.2 Enthalpies of reaction and formation 2.3 Entropy and the second law of thermodynamics 2.4 The third law of thermodynamics; absolute entropies 2.5 Criteria for equilibrium and spontaneous transformation 2.6 Standard free energy changes 2. 7 Free energy change and the equilibrium constant 2.8 Chemical potential; homogeneous nucleation of water-vapor condensation Exercises 3 Chemical kinetics 3.1 Reaction rates 3.2 Reaction mechanisms 3.3 Reaction rates and equilibria 3.4 Collision theory of gaseous reactions 3.5 The effect of temperature on reaction rates: the Arrhenius' relation 3.6 Catalysis 3.7 Half-life, residence time, and renewal time Exercises 4 Solution chemistry and aqueous equilibria 4.1 Definitions and types of solutions 4.2 Solution concentrations 4.3 Factors affecting solubility 4.4 Colligative properties 4.5 Aqueous solutions; electrolytes 4.6 Aqueous equilibria 4.7 Strong and weak electrolytes; ion-product constant for water Exercises 5 Acids and bases 5.1 Some definitions and concepts 5.2 The nature of H+(aq) 5.3 The Brønsted-Lowry theory; conjugate acid-base pairs 5.4 The Lewis theory 8 5.5 Strengths of acids and bases; acid-dissociation (or ionization) constant 5.6 The pH scale 5.7 Polyprotic acids 5.8 Hydrolysis 5.9 Buffers 5.10 Complex ions 5.11 Mass balance and charge balance relations 5.12 The pH of rainwater Exercises 6 Oxidation-reduction reactions 6.1 Some definitions 6.2 Oxidation numbers 6.3 Balancing oxidation-reduction reactions 6.4 Half-reactions in electrochemical cells 6.5 Strengths of oxidants and reductants; standard cell and half-cell potentials 6.6 Standard cell potentials and free-energy change 6.7 The Nernst equation 6.8 Redox potentials; Eh-pH diagrams 6.9 Gram-equivalent weight and normality Exercises 7 Photochemistry 7.1 Some properties of electromagnetic waves 7.2 Some photochemical terminology and principles 7.3 Quantum yields 7.4 Rate coefficients for photolysis 7.5 Photostationary states 7.6 Stratospheric ozone and photochemistry; depletion of stratospheric ozone Exercises Appendix I International system of units (SI) Appendix II Some useful numerical values Appendix III Atomic weights Appendix IV Equilibrium (or dissociation) constants for some chemical reactions Appendix V Some molar standard Gibbs free energies of formation, molar standard enthalpies (or heats) of formation and molar absolute entropies at 25°C and 1 atmosphere Appendix VI Names, formulas, and charges of some common ions Appendix VII Answers to exercises and hints and solutions to selected exercises Index
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  • 3
    Monograph available for loan
    Monograph available for loan
    Cambridge : Cambridge University Press
    Associated volumes
    Call number: AWI S2-98-0216
    In: Cambridge nonlinear science series, 7
    Description / Table of Contents: Deterministic chaos offers a striking explanation for irregular behaviour and anomalies in systems which do not seem to be inherently stochastic. The most direct link between chaos theory and the real world is the analysis of time series from real systems in terms of nonlinear dynamics. This book provides experimentalists with methods for processing, enhancing, and analysing measured signals using these methods; and for theorists it also demonstrates the practical applicability of mathematical results. The framework of deterministic chaos constitutes a new approach to the analysis of irregular time series. Traditionally, nonperiodic signals have been modelled by linear stochastic processes. But even very simple chaotic dynamical systems can exhibit strongly irregular time evolution without random inputs. Chaos theory offers completely new concepts and algorithms for time series analysis which can lead to a thorough understanding of the signals. The book introduces a broad choice of such concepts and methods, including phase space embeddings, nonlinear prediction and noise reduction, Lyapunov exponents, dimensions and entropies, as well as statistical tests for nonlinearity. Related topics such as chaos control, wavelet analysis, and pattern dynamics are also discussed. Applications range from high-quality, strictly deterministic laboratory data to short, noisy sequences which typically occur in medicine, biology, geophysics, and the social sciences. All the material discussed is illustrated using real experimental data. This book will be of value to any graduate student or researcher who needs to be able to analyse time series data, especially in the fields of physics, chemistry, biology, geophysics, medicine, economics, and the social sciences.
    Type of Medium: Monograph available for loan
    Pages: XVI, 304 Seiten , Illustrationen , 25 cm
    Edition: First published
    ISBN: 0-521-55144-7
    Series Statement: Cambridge nonlinear science series 7
    Language: English
    Note: Preface Acknowledgements Part S Basic topics Chapter I Introduction: Why nonlinear methods? Chapter 2 Linear tools and general considerations 2.1 Stationarity and sampling 2.2 Testing for stationarity 2.3 Linear correlations and the power spectrum 2.3.1 Stationarity and the low-frequency component in the power spectrum 2.4 Linear filters 2.5 Linear predictions Chapter 3 Phase space methods 3.1 Determinism: Uniqueness in phase space 3.2 Delay reconstruction 3.3 Finding a good embedding 3.4 Visual inspection of data 3.5 Poincare surface of section Chapter 4 Determinism and predictability 4.1 Sources of predictability 4.2 Simple nonlinear prediction algorithm 4.3 Verification of successful prediction 4.4 Probing stationarity with nonlinear predictions 4.5 Simple nonlinear noise reduction Chapter 5 Instability: Lyapunov exponents 5.1 Sensitive dependence on initial conditions 5.2 Exponential divergence 5.3 Measuring the maximal exponent from data Chapter 6 Self-similarity: Dimensions 6.1 Attractor geometry and fractals 6.2 Correlation dimension 6.3 Correlation sum from a time series 6.4 Interpretation and pitfalls 6.5 Temporal correlations, nonstationarity, and space time separation plots 6.6 Practical considerations 6.7 A useful application: Determination of the noise level Chapter 7 Using nonlinear methods when determinism is weak 7.1 Testing for nonlinearity with surrogate data 7.1.1 The null hypothesis 7.1.2 How to make surrogate data sets 7.1.3 Which statistics to use 7.1.4 What can go wrong 7.1.5 What we have learned 7.2 Nonlinear statistics for system discrimination 7.3 Extracting qualitative information from a time series Chapters Selected nonlinear phenomena 8.1 Coexistence of attractors 8.2 Transients 8.3 Intermittency 8.4 Structural stability 8.5 Bifurcations 8.6 Quasi-periodicity Part 2 Advanced topics Chapter 9 Advanced embedding methods 9.1 Embedding theorems 9.1.1 Whitney's embedding theorem 9.1.2 Takens's delay embedding theorem 9.2 The time lag 9.3 Filtered delay embeddings 9.3.1 Derivative coordinates 9.3.2 Principal component analysis 9.4 Fluctuating time intervals 9.5 Multichannel measurements 9.5.1 Equivalent variables at different positions 9.5.2 Variables with different physical meanings 9.5.3 Distributed systems 9.6 Embedding of interspike intervals Chapter 10 Chaotic data and noise 10.1 Measurement noise and dynamical noise 10.2 Effects of noise 10.3 Nonlinear noise reduction 10.3.1 Noise reduction by gradient descent 10.3.2 Local projective noise reduction 10.3.3 Implementation of locally projective noise reduction 10.3.4 How much noise is taken out? 10.3.5 Consistency tests 10.4 An application: Foetal ECG extraction Chapter ! 1 More about invariant quantities 11.1 Ergodicity and strange attractors 11.2 Lyapunov exponents II 11.2.1 The spectrum of Lyapunov exponents and invariant manifolds 11.2.2 Flows versus maps 11.2.3 Tangent space method 11.2.4 Spurious exponents 11.2.5 Almost two-dimensional flows 11.3 Dimensions II 11.3.1 Generalised dimensions, multifractals 11.3.2 Information dimension from a time series 11.4 Entropies 11.4.1 Chaos and the flow of information 11.4.2 Entropies of a static distribution 11.4.3 The Kolmogorov-Sinai entropy 11.4.4 Entropies from time series data 11.5 How things are related 11.5.1 Pesin's identity 11.5.2 Kaplan-Yorke conjecture Chapter 12 Modelling and forecasting 12.1 Stochastic models 12.1.1 Linear filter 12.1.2 Nonlinear filters 12.1.3 Markov models 12.2 Deterministic dynamics 12.3 Local methods in phase space 12.3.1 Almost model free methods 12.3.2 Local linear fits 12.4 Global nonlinear models 12.4.1 Polynomials 12.4.2 Radial basis functions 12.4.3 Afeura/ networks 12.4.4 Wfcat to do in practice 12.5 Improved cost functions 12.5.1 Overfitting and model costs 12.5.2 The errors-in-variables problem 12.6 Model verification Chapter 13 Chaos control 13.1 Unstable periodic orbits and their invariant manifolds 13.1.1 Locating periodic orbits 13.1.2 Stable/unstable manifolds from data 13.2 OGY-control and derivates 13.3 Variants of OGY-control 13.4 Delayed feedback 13.5 Chaos suppression without feedback 13.6 Tracking 13.7 Related aspects Chapter 14 Other selected topics 14.1 High dimensional chaos 14.1.1 Analysis of higher dimensional signals 14.1.2 Spatially extended systems 14.2 Analysis of spatiotemporal patterns 14.3 Multiscale or self-similar signals, wavelets 14.3.1 Dynamical origin of multiscale signals 14.3.2 Scaling laws 14.3.3 Wavelet analysis Appendix A Efficient neighbour searching Appendix B Program listings Appendix C Description of the experimental data sets References Index
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  • 4
    Monograph non-lending collection
    Monograph non-lending collection
    Cambridge : Cambridge University Press
    Associated volumes
    Call number: AWI A4-97-0466
    In: Cambridge atmospheric and space science series
    Description / Table of Contents: This book presents a comprehensive survey of the climatology and meteorology of Antarctica. As well as describing the climate which prevails in the Antarctic, the book also considers the processes by which this climate is maintained and explores links between the Antarctic and the global climate system. The first section of the book reviews the methods by which we can observe the Antarctic atmosphere and presents a synthesis of climatological measurements. In the second section, the processes whcih maintain the observed climate are considered, starting with large-scale weather systems to mesoscale and small-scale processes. The final section reviews our current knowledge of the variability of the Antarctic climate and considers changes that may occur in Antarctica as a result of 'greenhouse' warming. Throughout the book, the links between the Antarctic atmosphere and other elements of the Antarctic climate system (oceans, sea ice and ice sheets) are stressed and the processes which couple the Antarctic with the global climate system are examined. The instruments and platforms used in Antarctic climate studies are discussed (including automatic stations and international data centres), with special emphasis on the role of remote sensing from satellites and numerical modelling techniques. This volume will be of greatest interest to meteorologists and climatologists with a specialised interest in Antarctica and the Southern Ocean, but it will also appeal to researchers in Antarctic glaciology, oceanography and biology. Graduates and undergraduates studying physical geography or the earth, atmospheric and environmental sciences will find much useful background material in the book.
    Type of Medium: Monograph non-lending collection
    Pages: XI, 409 Seiten , Illustrationen
    Edition: First published
    ISBN: 0521465605 , 0-521-46560-5
    Series Statement: Cambridge atmospheric and space science series
    Language: English
    Note: Contents: Preface. - 1 Introduction. - 1.1 Physical characteristics of the Antarctic. - 1.2 A brief history of Antarctic meteorology. - 1.3 The role of the Antarctic atmosphere in the global climate system. - 2 Observations and instrumentation. - 2.1 Observing in the Antarctic. - 2.2 Instruments for meteorological measurements. - 2.3 Automatic weather stations. - 2.4 Drifting buoys. - 2.5 Surface-based remote sensing. - 2.6 Satellites, space-based observing systems and ground stations. - 2.7 The station network and communications. - 2.8 Data sets and data centres. - 3 Physical climatology. - 3.1 Radiation. - 3.2 Temperature and humidity. - 3.3 Pressure, geopotential and wind. - 3.4 Clouds and precipitation. - 3.5 Sea ice and the Southern Ocean environment. - 4 The large-scale circulation of the Antarctic atmosphere. - 4.1 Introduction. - 4.2 The heat budget. - 4.3 Atmospheric circulation and the vorticity budget. - 4.4 The water vapour budget. - 4.5 Representation of the Antarctic atmosphere in general circulation models. - 5 Synoptic-scale weather systems and fronts. - 5.1 Introduction. - 5.2 The role of depressions. - 5.3 Depressions in the Antarctic and over the Southern Ocean. - 5.4 Climatology. - 5.5 Preparation of operational analyses and forecasts. - 5.6 Future research needs. - 6 Mesoscale systems and processes. - 6.1 Local wind systems. - 6.2 Internal gravity waves. - 6.3 The atmospheric boundary layer. - 6.4 Blowing snow. - 6.5 Mesocyclones. - 7 Climate variability and change. - 7.1 Variations in the historical climate record. - 7.2 Interactions with the tropical and mid-latitude circulation. - 7.3 Future climate predictions - Antarctica in a 'greenhouse' climate. - Appendix A: A chronological list of stations that have made multi-year meteorological observations in the Antarctic and on the sub-Antarctic islands. - Appendix B: A chronological list of automatic weather stations that have been deployed in the Antarctic and on the sub-Antarctic Islands. - References. - Index.
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  • 5
    Monograph available for loan
    Monograph available for loan
    Cambridge : Cambridge University Press
    Associated volumes
    Call number: AWI A7-20-93527
    In: Cambridge atmospheric and space science series
    Type of Medium: Monograph available for loan
    Pages: XVIII, 316 Seiten , Illustrationen
    Edition: Transferred to digital printing
    ISBN: 0521380529 , 0521467454
    Series Statement: Cambridge atmospheric and space science series
    Language: English
    Note: Contents Preface Symbols Abbreviations 1 The atmospheric boundary layer 1.1 Introduction 1.2 History 1.3 Observing the ABL 1.4 ABL modelling 1.5 Applications 1.6 Scope of the book 1.7 Nomenclature and some definitions Notes and bibliography 2 Basic equations for mean and fluctuating quantities 2.1 Turbulence and flow description 2.2 Governing equations for mean and fluctuating quantities 2.3 The simplified mean equations 2.4 The turbulence closure problem 2.5 The second-moment equations 2.6 Turbulent kinetic energy and stability parameters Notes and bibliography 3 Scaling laws for mean and turbulent quantities 3.1 The wind profile: simple considerations 3.2 Wind profile laws: the neutral case 3.3 Monin-Obukhov similarity theory: the non-neutral surface layer 3.4 Generalized ABL similarity theory 3.5 Similarity theory and turbulence statistics Notes and bibliography 4 Surface roughness and local advection 4.1 Aerodynamic characteristics of the land 4.2 Scalar roughness lengths 4.3 The vegetation canopy 4.4 Flow over the sea 4.5 Local advection and the internal boundary layer Notes and bibliography 5 Energy fluxes at the land surface 5.1 Surface energy balance and soil heat flux 5.2 Radiation fluxes 5.3 Evaporation 5.4 Condensation Notes and bibliography 6 The thermally stratified atmospheric boundary layer 6.1 The convective boundary layer 6.2 The stable (nocturnal) boundary layer 6.3 The marine atmospheric boundary layer 6.4 Mesoscale flow and IBL growth Notes and bibliography 7 The cloud-topped boundary layer 7.1 General properties of the CTBL 7.2 Observations 7.3 Radiation fluxes and cloud-top radiative cooling 7.4 Entrainment and entrainment instability 7.5 Numerical modelling of the CTBL Notes and bibliography 8 Atmospheric boundary-layer modelling and parameterization schemes 8.1 Introduction 8.2 Surface temperature 8.3 Surface humidity (soil moisture) 8.4 Canopy parameterization 8.5 Surface fluxes 8.6 Rate equation for ABL depth 8.7 Turbulence closure schemes 8.8 ABL cloud parameterization Notes and bibliography 9 The atmospheric boundary layer, climate and climate modelling 9.1 Introduction 9.2 Sensitivity of climate to the ABL and to land surface 9.3 Research priorities Notes and bibliography Appendices References Index
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