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  • Articles  (144)
  • 1995-1999  (144)
Collection
  • Articles  (144)
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Year
Journal
  • 11
    Electronic Resource
    Electronic Resource
    Copenhagen : International Union of Crystallography (IUCr)
    Applied crystallography online 30 (1997), S. 628-632 
    ISSN: 1600-5767
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Geosciences , Physics
    Notes: Reversible changes in the optical properties of photochromic glasses are observed owing to the presence of small silver halide crystals inside the glassy matrix. These crystals grow during the glass heat-treatment processing. Samples with molar composition of 40SiO2.10Al2O3.16.1K20.33.9B2O3, doped with AgCl and CuO, were produced and submitted to different heat treatments: (i) for 0.5 h at temperatures from 753 to 893 K and (ii) at 873 K for periods of time from 0.25 to 1.25 h. Small-angle X-ray scattering (SAXS) was used to characterize the samples. The samples heat treated between 843 and 893 K presented an increasing growth rate of the Guinier radius (Rg). Samples heat treated at a fixed temperature of 873 K and different time t showed a law Rg3 = kt + c. Variations in the optical absorbance at 280 nm and the additional absorbance spectra of samples exposed to light showed correlation with the SAXS results.
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  • 12
    ISSN: 1573-0972
    Keywords: Citronellyl ester ; fatty acid vinyl ester ; geranyl ester ; lipase ; transesterification ; Trichosporon fermentans
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Abstract Enzymatic synthesis of terpenyl esters by esterification or transesterification with fatty acid vinyl esters as acyl donors by celite-adsorbed lipase of Trichosporon fermentans was investigated. In direct esterification of geraniol, the lipase showed high reactivity toward fatty acids with carbon chains longer than C-8, but little reactivity toward fatty acids with shorter chains. With fatty acid vinyl esters as acyl donors, the lipase catalysed the synthesis of geranyl and citronellyl esters with carbon chains shorter than C-6 in with yields of 〉90% molar conversion. Time course, effects of added water, temperature and substrate concentration were studied for the synthesis of geranyl acetate. Molar conversion yield reached 97.5% after 5 h incubation at 30–40°C with the addition of 3% water. In this reaction, no inhibition by substrates such as geraniol and vinyl acetate was observed.
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  • 13
    Electronic Resource
    Electronic Resource
    Springer
    Journal of comparative physiology 184 (1999), S. 553-562 
    ISSN: 1432-1351
    Keywords: Key words Terrestrial slug ; Procerebrum ; Glutamate receptors ; Quisqualate ; Ibotenate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Abstract Glutamate-induced responses in the procerebral neurons of the terrestrial slug Limax marginatus were examined using the nystatin-perforated patch recording technique applied in the voltage-clamp mode and local application of drugs. The procerebrum contains two types of interneurons with different spontaneous activities, bursting and nonbursting neurons. In the bursting neurons, a puff of glutamate evoked a rapidly desensitizing current followed by a smaller sustained current. The reversal potential of the early component showed that the current was mediated by Cl− ions, while the late component was presumed to be mediated by K+ ions. In the nonbursting neurons, glutamate evoked a sustained current with a strong outward rectification, and the current was mediated by K+ ions. Ibotenate selectively evoked the rapidly desensitizing response in the bursting neurons, whereas quisqualate evoked a non-desensitizing K+ current both in the bursting and nonbursting neurons. The glutamate-induced K+ current had similar characteristics with the spontaneous synaptic activities in the procerebrum neurons, suggesting the possibility that glutamate receptors are involved in the spontaneous oscillatory activity.
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  • 14
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 65 (1997), S. 475-480 
    ISSN: 1432-0649
    Keywords: PACS: 32.00
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
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  • 15
    Electronic Resource
    Electronic Resource
    Springer
    Computational mechanics 23 (1999), S. 182-189 
    ISSN: 1432-0924
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Application of lattice gas automaton (LGA) to engineering will be examined by dealing with mixing of two component flow without chemical reaction in a simplified stirred tank. In mechanical engineering, it is important to know quality and accumulation rate of products which depend essentially on mixing of raw materials. Mixing is usually formulated by partial differential equations of conservation laws and empirical formulae, and solved numerically by derived finite difference equations. LGA will be capable of calculating the fine structure of time-dependent interfacial behavior mesoscopically, since this has advantages of describing pattern formation of mixture in detail and is good at parallel computation. Parallel computation must now be a selected issue to determine whether LGA is applicable to practical problems. Computing power intends us to approach complex flow by new concept. This means that days of pure fluid dynamics are over and chemical process, phase change, material behavior must now be taken into account. The present example can described as a numerically intensive parallel computing problem as far as the number of PEs is increased up to 32 in the present numerical experiment.
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  • 16
    ISSN: 1433-7479
    Keywords: Key words Biomechanical model ; Soft computing algorithms ; Intelligent robot unicycle ; Robust control ; Posture stability ; Controllability ; Fuzzy control ; Entropy measure of controllability
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Notes: Abstract  The posture stability and driving control of a human-riding-type unicycle have been realized. The robot unicycle is considered as a biomechanical system using an internal world representation with a description of emotion, instinct and intuition mechanisms. We introduced intelligent control methods based on soft computing and confirmed that such an intelligent control and biological instinct as well as intuition together with a fuzzy inference is very important for emulating human behaviors or actions. Intuition and instinct mechanisms are considered as global and local search mechanisms of the optimal solution domains for an intelligent behavior and can be realized by genetic algorithms (GA) and fuzzy neural networks (FNN) accordingly. For the fitness function of the GA, a new physical measure as the minimum entropy production for a description of the intelligent behavior in a biological model is introduced. The calculation of robustness and controllability of the robot unicycle is presented. This paper provides a general measure to estimate the mechanical controllability qualitatively and quantitatively, even if any control scheme is applied. The measure can be computed using a Lyapunov function coupled with the thermodynamic entropy change. Interrelation between Lyapunov function (stability condition) and entropy production of motion (controllability condition) in an internal biomechanical model is a mathematical background for the design of soft computing algorithms for the intelligent control of the robotic unicycle. Fuzzy simulation and experimental results of a robust intelligent control motion for the robot unicycle are discussed. Robotic unicycle is a new Benchmark of non-linear mechatronics and intelligent smart control.
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  • 17
    ISSN: 1432-2153
    Keywords: Low-porosity foam ; Shock-foam interaction ; Environmental problem
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics , Technology
    Notes: Abstract One-dimensional interaction between a planar shock wave and a rubber or low-porosity foam is investigated experimentally and numerically. The considered polyurethane foam is of high density (ρ c=290 kg/m3) and lowporosity (ϕ=0.76), and this corresponds to an intermediate condition between rubber and high-porosity foam. Stress-strain relations for the low-porosity foam are investigated by machine tests, which show larger deformation against compressive force and higher non-linearity in stress-strain curve as compared with rubber. Also the low-porosity foam shows a hysteresis cycle. Experiments on shock wave-foam interactions are conducted by using a shock tube. Experimental time history of the surface stress of the foam at the end of the shock tube does not show shock type stress increase, but continuous excessive stress rise can be seen, and then dumping vibration approaching to gas dynamic pressure of the reflected shock wave is followed, and the highest stress amounts about 3∼4 times of the pressure after the reflected gas dynamic shock wave. Interactive motions of gas and the low-porosity foam are analyzed using the Lagrangean coordinates system. An elastic model for a low-porosity foam is assumed to be a single elastic material with the measured stress-strain relation. Results of numerical simulations are compared with the shock tube experiments, which show essentially same stress variations with experimental results.
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  • 18
    ISSN: 1432-0630
    Keywords: PACS: 73.20.At; 73.61.-r; 61.16.Ch; 68.35.Bs
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 19
    ISSN: 1432-0649
    Keywords: 32.00
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We observed the energy distribution of the photoelectrons generated from the highly charged ions in the tunneling regime by using a circularly polarized Ti:Sapphire laser (745 nm, 100 fs). The peaks for each successive charge state up to Ar3+, Kr4+, and Xe5+ were clearly resolved, and the peaks due to higher charge states were flattened in the high-energy region and deviated from those predicted by the quasistatic model. This deviation is explained by pondero-motive acceleration in the strong field gradient. In Xe, Xe8+ was generated at a peak intensity of 2.0 × 1016 W/cm2.
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  • 20
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 68 (1999), S. 169-175 
    ISSN: 1432-0649
    Keywords: PACS: 42.60; 42.55; 42.79
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
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