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  • 11
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 25 (1985), S. 1-5 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Turbulent flow in the impingement mixing head of a reactions injection molding machine produces a laminated mixture, whose striations are mostly so thick that any subsequent copolymerization would be hindered by diffusion. However, further reduction in striation thickness occurs during laminar flow through the runner. This is calculated here and is a function of the radial position in the runner and of its length/diameter ratio. So, for example, when L/D = 10, it is predicted that at least 79 percent of, the reagent striations would be thin enough to permit reaction under kinetically controlled conditions.
    Additional Material: 3 Ill.
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  • 12
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 23 (1983), S. 556-559 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The striation thickness distribution developed in an impingment T-mixer is predicted using the statistical theory of turbulent diffusion. The predicted distribution is independent of the mixing nozzle Reynolds number, in agreement with some experiments, and is primarily a function of the mixing head geometry, the ratio of the reagent flow rates and the residence time distribution of the flow in the mixing head. Mixing is described as the result of fluid deformation in the intertial subrange of turbulent flow. The relationship of deformation to time and energy dissipation rate ∊ is examined. In the impingement T-mixer ∊ is related to the kinetic energies of the streams entering and leaving the head. (There are no surface tension effects and pressure is relatively uniform in the mixing head, so that the kinetic energy is dissipated by viscous forces.) The distribution of residence times of fluid elements in the T-mixer is responsible for varying degrees of deformation and hence a distribution of striation thickness. This residence time distribution does not seem to have been studied and the flow pattern was thus modeled as perfect macromixing, having an exponential distribution. The procedure developed in this paper to calculate the distribution of striation thickness allows reasonable estimates of its parameters from fluid mechanical information and showed good agreement with experimental values, without having to fit any quantities. This new approach to striation thickness distribution is worth further evaluation.
    Additional Material: 4 Ill.
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  • 13
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 14
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 27 (1985), S. 482-489 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The dissolved oxygen (DO) level has been shown to have a profound effect on the product distribution of a Bacillus subtilis culture, with acetoin being excreted with DO above 100 parts per billion (ppb) and butanediol below 100 ppb. The product concentration ratio changed rapidly in the 80-90 ppb range. Switching from one oxygen level to another caused one already accumulated product to be converted to the other in a reversible manner. Rates of change of 0.5-1 g/L h enabled detection within 10 min. Detection sensitivity is enhanced because the ratio of two concentrations can be measured. Remarkably sensitive to mixing rates, the culture responded to changes in stirring speed during experiments in which the dissolved oxygen was controlled at a constant level with a novel control system. Thus, the culture is capable of detecting dead zones in relatively well-mixed reactors and oxygen gradients in column and tubular reactors. High-viscosity effects can also be investigated since the culture grows well in xanthan gum solutions. Preliminary kinetic model development indicates that a useful model for simulating reactor mixing and transport effects can be developed to aid in the planning of experiments.
    Additional Material: 16 Ill.
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  • 15
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 30 (1987), S. 1019-1025 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Enzymatic lactose hydrolysis by β-galactosidase (lactase) was investigated with respect to the formation of oligosaccharides. An analysis of the formation of oligosaccharides and their control is important in the development of technical applications for enzymatic lactose hydrolysis. The available literature data on transfer reactions of lactase were reviewed, compared, and presented in a concise tabular form. Mechanisms and possible ways of modelling enzymatic lactose hydrolysis, including formation of oligosaccharides, are presented.
    Additional Material: 6 Ill.
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  • 16
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 25 (1983), S. 1625-1639 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A high degree of conversion is desired when lactose is hydrolyzed to glucose and galactose. This produces, however, a high concentration of galactose, which is inhibitory for the enzyme catalyst (β-galactosidase). The inhibition can be reduced by limiting the conversion per pass over the enzyme (e.g. to ca. 50%), separating unconverted lactose from the reactor effluent, and recycling it to the reactor inlet. (This allows the overall conversion to be raised to ca. 80-90%). The solubilities of lactose, glucose, and galactose have been determined at various temperatures and for sugar mixtures having different concentrations and degrees of hydrolysis. Various cooling crystallizations have defined convenient and simple processes for the selective separation of lactose from its hydrolysis products.
    Additional Material: 14 Ill.
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  • 17
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 30 (1987), S. 1026-1031 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Enzymatic lactose hydrolysis using two yeast and two fungal lactases that are of current technical interest was studied. The enzymes were compared regarding their oligosaccharide production. Parameters influencing oligosaccharide formation, together with the effect of immobilization were examined and conditions minimizing oligosaccharide content in the hydrolysis product were proposed. Enzymatic whey hydrolysis was also considered. A possibility of enzymatic lactose recombination from its hydrolysis products was shown.
    Additional Material: 8 Ill.
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