ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Crosslinked copolymers of N-vinylcarbazole and poly N-vinylcarbazole) and formaldehyde have been phosphorylated using PCl3 and anhydrous AlCl3 under different conditions. The cation exchange resins, thus obtained, have been characterized by elemental analyses, evaluation of total ion-exchange capacities and salt-splitting capacities, pH metric titration behavior, and IR analysis. The phosphorylated resin exhibites significantly better thermal stability than the corresponding sulfonated N-vinylcarbazole-formaldehyde cation exchange resin or the unmodified N-vinylcarbazole-formaldeyde copolymer, as well as the phosphorylated poly(N-vinylcarbazole). The phosphorylated resins also behave as polymeric dyes with pH dependent color change. Possible explanations for color change and ion-exchange capacity differences have been attempted on the basis of the structural characteristics of the resins.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1984.070291210
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