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  • Artikel  (10.196)
  • Polymer and Materials Science  (7.845)
  • Chemical Engineering  (2.351)
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  • 1
    Digitale Medien
    Digitale Medien
    Poly(sodium acrylamidoalkanoate) s: Syntheses and solution properties in relation to flocculation study in water treatment (1991)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 42 (1991), S. 225-232 
    Details
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The micelle-forming monomers of sodium 6-acrylamidocaproate (Na 6-AAC), sodium 11-acrylamidoundecanoate (Na 11-AAU), sodium 11-(N-methylacrylamido) undecanoate (Na 11-MAAU), and sodium 11-(N-ethylacrylamido) undecanoate (Na 11-EAAU) have been synthesized and polymerized. Except poly(Na 6-AAC), the molecular weights of the other three poly(sodium acrylamidoalkanoate) s were over 106. They behave as strong anionic polyelectrolytes in aqueous solutions. Their solution properties, such as viscosity, charge density, and radius of gyration, were investigated. The performance of these anionic polyelectrolytes as coagulant aids in water treatment were assessed by jar test. Poly(Na 6-AAC) and poly (Na 11-AAU) were superior to poly (Na 11-MAAU) and poly (Na 11-EAAU) in terms of flocs settling. All these four anionic polyelectrolytes tested in water treatment are as effective as a commercially available cationic polyamine organic coagulant (Hyperfloc CP 753).
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/app.1991.070420127
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  • 2
    Digitale Medien
    Digitale Medien
    The monsanto polyacrylonitrile hollow-fiber artificial kidney (1972)
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 6 (1972), S. 59-79 
    Details
    ISSN: 0021-9304
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Medizin , Technik allgemein
    Notizen: Advantages of a hollow-fiber hemodialyzer have been well described. The goal of this program was to provide a working model of a noncellulosic hollow fiber artificial kidney with nonthrombogenic blood-contacting surfaces, low blood-priming volume and low pressure drop, a satisfactory rate of urea transport, and high rate of ultrafiltration of water. Also, the reliability and utility of these devices was to be demonstrated through clinical evaluation.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/jbm.820060208
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  • 3
    Digitale Medien
    Digitale Medien
    Electron microscopic investigation of polyamidohydrazide solutions (1985)
    Weinheim : Wiley-Blackwell
    Acta Polymerica 36 (1985), S. 624-627 
    Details
    ISSN: 0323-7648
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Beschreibung / Inhaltsverzeichnis: Unter Hernziehung unterschiedlicher Präparationsmethoden wurde die Struktur verdünnter und konzentrierter (0,01 bis 9,8%) Lösungen des starkettigen Polyamidohydrazid (PAH) mittels Elektronenmikroskopie in zwei Lösungsmitteln (DMSO und DMAA) untersucht. Beginnend mit der Konzentration 0,01% erfolgt unterschiedliche Strukturierung in diesen Lösungsmitteln, die bezüglich des Polymers eine unterschiedliche Güte aufweisen. Die Ergebnisse wurden früheren Untersuchungen zur Rheologie konzentrierter PAH-Lösungen in den genannten Lösungsmitteln gegenüber gestellt.
    Notizen: The structure of dilute and concentrated solutions (0.01-9.8%) of rigid-chain polyamidohydrazide (PAH) in dimethylsulphoxide and dimethylacetamide was investigated by electron microscopy using various preparation techniques. Starting with a 0.01% concentration, PAH shows two distinct types of structuration in the solvents. The results are compared with previously studied rheological properties of PAH in these solvents.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/actp.1985.010361110
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  • 4
    Digitale Medien
    Digitale Medien
    Synthesis of fibre-forming copolymers of acrylonitrile with acrylates in systems based on lithium alkoxides (1984)
    Weinheim : Wiley-Blackwell
    Acta Polymerica 35 (1984), S. 65-67 
    Details
    ISSN: 0323-7648
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Beschreibung / Inhaltsverzeichnis: Die Copolymerisation von Acrylnitril und Acrylaten wurde in Dimethylformamid bei hohem Acrylnitril/Acrylat-Verhältnis im Temperaturbereich von -50 bis +10°C durch Lithiumalkoxide initiiert. Die Bedingungen zur direkten Präparation von Spinnlösungen der Copolymere wurden erarbeitet. Das Lösungsspinnen dieser Copolymere durch Orientierungsfällung ergab Fasern mit hohen Festigkeitswerten.
    Notizen: The copolymerization of acrylonitrile with acrylates has been initiated by lithium alkoxides in dimethylformamide at a high acrylonitrile/acrylate ratio over the temperature range from -50 to 10°C. The conditions for a direct preparation of spinning solutions of the copolymers were determined. The solution-spinning of these copolymers by orientational precipitation yielded fibres exhibiting high strength properties.
    Zusätzliches Material: 3 Tab.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/actp.1984.010350115
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  • 5
    Digitale Medien
    Digitale Medien
    Interpenetrating polymer networks of poly(dimethyl siloxane-urethane) and poly(methyl methacrylate) (1993)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 31 (1993), S. 2481-2491 
    Details
    ISSN: 0887-624X
    Schlagwort(e): interpenetrating polymer networks ; poly(dimethylsiloxane-urethane) ; poly(methyl methacrylate) ; Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Simultaneous IPNs of poly(dimethyl siloxane-urethane) (PDMSU)/poly(methyl methacrylate) (PMMA) and related isomers have been prepared by using new oligomers of bis(β-hydroxyethoxymethyl)poly(dimethyl siloxane)s (PDMS diols) and new crosslinkers biuret triisocyanate (BTI) and tris(β-hydroxylethoxymethyl dimethylsiloxy) phenylsilane (Si-triol). Their phase morphology have been characterized by DSC and SEM. The SEM phase domain size is decreased by increasing crosslink density of the PDMSU network. A single phase IPN of PDMSU/PMMA can be made at an Mc = 1000 and 80 wt % of PDMSU. All of the pseudo- or semi-IPNs and blends of PDMSU and PMMA were phase separated with phase domain sizes ranging from 0.2 to several micrometers. The full IPNs of PDMSU/PMMA have better thermal resistance compared to the blends of linear PDMSU and linear PMMA. © 1993 John Wiley & Sons, Inc.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/pola.1993.080311008
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  • 6
    Digitale Medien
    Digitale Medien
    Influence of hard segments of polyurethane on cell growth (1996)
    New York, NY [u.a.] : Wiley-Blackwell
    Polymer International 41 (1996), S. 419-425 
    Details
    ISSN: 0959-8103
    Schlagwort(e): polyurethane ; cell growth ; phase separation ; hydrogen bonding index ; cytotoxicity ; Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Polyurethanes (PU) with suitable soft segments have been found to be good blood-compatible polymers and have attracted much attention recently. In this study, various molar amounts of 4,4′-methylene bisphenyl isocyanate reacted with poly(tetramethylene oxide) were synthesized to explore the optimal ratio of hard/soft segments for cell attachment and proliferation in in vitro systems. Differential scanning calorimetry and dynamic mechanical analysis were used to determine the physical properties, hydrogen bonding index (HBI) and transmission electron microscopy to observe the phase-separation phenomena in the materials, and 3T3 fibroblast to evaluate the dependence of the cell proliferation at 37°C on the material properties. Our results show that cell attachment and proliferation are closely related to the cell growth surface, which in turn is controlled by (1) the ratio of hard to total segment concentration and (2) the recrystallization temperature (Tc) of PU. To obtain a good cell growth surface, the ratio of hard to total segment concentration is found to be between 0.4 and 0.6, and HBI is between 1.5 and 2.1. Furthermore, when the Tc of PU is near the physiology temperature, a stable surface for cell growth can be provided. The shorter molecules in the soft segment region can rearrange the molecular chain at 37°C.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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  • 7
    Digitale Medien
    Digitale Medien
    Studies on VOCl3/MgCl2/NaY/Al2Et3Cl3 complex support catalysts for the copolymerization of ethylene and propyleneThe work was financed by National Natural Science Foundation of China. (1994)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 54 (1994), S. 1403-1408 
    Details
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Using VO2+ as a spin probe, a new method to obtain microenvironmental information on supports was developed which can be used in the choice of supports for coordination catalysts. Utilizing the above method, NaY was chosen as second support component. A complex support catalyst VOCl3/MgCl2/NaY/Al2Et3Cl3 was prepared and used in ethylene-propylene copolymerization. Higher polymerization activity was obtained with this catalytic system. Alternating the ratio of two kinds of supports, the composition and sequence structure of copolymers could be controlled, which showed that NaY participated in the active species, affected the insertion of monomer, and changed the composition and sequence structure of copolymers. © 1994 John Wiley & Sons, Inc.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/app.1994.070541003
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  • 8
    Digitale Medien
    Digitale Medien
    Self-assembled structures of azobenzene amphiphiles: A new photorecording medium (1994)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 53 (1994), S. 687-699 
    Details
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The self-assembly of azobenzene amphiphiles by themselves and in the presence of a nonionic polymer has been studied. The conditions that yield homeotropic and uniaxial films, i.e., the optical properties of a single crystal, by spin-coating were identified. It is shown that these films constitute a very sensitive write and erase recording medium. © 1994 John Wiley & Sons, Inc.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/app.1994.070530519
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  • 9
    Digitale Medien
    Digitale Medien
    Terpene-anhydride resins as coating materials (1995)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 58 (1995), S. 69-76 
    Details
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Low to moderate molecular weight terpene-anhydride resins were synthesized and evaluated in coatings applications. The terpenes used were terepinolene, β-pinene, and alloocimene. The comononmers used were maleic or itaconic anhydride. The terpene-anhydride resins were used to formulate solvent-borne coatings with an epoxy or diol as a coreactant. The coatings were evaluated as films over aluminum or steel panels. When a diol was used as a coreactant, the film properties were relatively poor. When epoxy was used as a coreactant, the properties of the films were much improved in terms of resistance to solvent and hardness. © 1995 John Wiley & Sons, Inc.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/app.1995.070580107
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  • 10
    Digitale Medien
    Digitale Medien
    Characterization of water vapor plasma-modified polyimide (1992)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 46 (1992), S. 2189-2202 
    Details
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: To enhance polyimide-to-polyimide adhesion, we have investigated the effect of surface modification in water vapor plasma. The use of a water vapor plasma to treat a fully cured polyimide (PMDA-ODA) surface before subsequent layers of polyimide are applied results in dramatically enhanced interfacial adhesion. The polyimide-to-polyimide interfacial adhesion strength attained following water vapor plasma treatment exceeds the cohesive strength of the applied polyimide layer. The effect of surface modification in water vapor plasma on metal-to-polyimide adhesion has also been investigated. The use of a water vapor plasma to treat a fully cured polyimide (PMDA-ODA) surface prior to metallization results in increased metal-to-polymer interfacial adhesion. A study of both electroless and vacuum-deposited metal was conducted. The use of contact-angle measurements, peel tests, Fourier transform infrared spectroscopy, optical emission spectroscopy, nuclear forward scattering, and X-ray photoelectron spectroscopy has led us to a preliminary understanding of the resulting surface modification and the subsequent effect of adhesion promotion. © 1992 John Wiley & Sons, Inc.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/app.1992.070461216
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