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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Journal of solution chemistry 20 (1991), S. 391-401 
    ISSN: 1572-8927
    Schlagwort(e): Cell constant ; conductance ; demal ; electrolytic conductivity ; potassium chloride ; primary standards ; resistance ; specific conductance
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract An absolute determination of aqueous electrolytic conductivity has been made for primary standards 0.01D and 0.1D (demal) potassium chloride solutions over the temperature range of 0 to 50°C in 5 degree intervals. A cell with a removable center section of accurately known length and area was used for the measurements. Values were adjusted to be in conformity with the ITS-90 temperature scale. The overall uncertainty over the entire temperature range is estimated to be 0.03%. Values at 25°C for 0.01D and 0.1D KCl solutions are 0.0014086 and 0.012852 S-cm−1, respectively.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Journal of solution chemistry 18 (1989), S. 515-528 
    ISSN: 1572-8927
    Schlagwort(e): Absolute standard ; conductivity cell ; demal ; electrolyte ; molality ; potassium chloride ; primary standard ; specific conductance
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract A determination of the absolute specific conductance of KCl solutions is demonstrated. The measurement is based on the conductance cell with a well defined geometry, having a difference in the removable center tube of accurately measured dimensions. The specific conductance of the solution is obtained from the measured resistances of the cell with and without the center tube and the measured l/A ratio of the center tube. Specific conductances obtained using the cell agree with the previously accepted standards for 0.1 demal and 0.01 demal solutions within 0.02%. Results are also presented for solutions based on molality. The temperature control, bridge, and detector technology used to obtain results of this accuracy are described.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Springer
    Journal of solution chemistry 16 (1987), S. 985-997 
    ISSN: 1572-8927
    Schlagwort(e): Aqueous solution ; cell constant ; conductance ; electrolytic conductivity ; potassium chloride ; primary ; resistance ; resistivity, secondary, standards, and temperature scale
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Measurements of aqueous electrolytic conductance are performed routinely in a variety of disciplines and industries. Conductivity is a measure of the ionic content in solution and thus has applications in pharmaceuticals, power plants, rainwater, lake surveys, and oceanography, to name a few. A thorough review of the measurement of and standards for aqueous electrolytic conductance is herein presented. At present, the most precise and accurate standards have been set forth by the International Organization of Legal Metrology (OIML), and have been adopted by most other standards organizations. However, the uncertainty assigned to these standards, especially the secondary standards, is somewhat larger than would be expected from the physical aspects of the measurement. Several changes in the units and measurement scales, including temperature, volume, molar mass, resistance, and concentration obfuscate the accuracy of these standards. In addition to the review, research is proposed, using a conductance cell with variable length, to establish new standards for aqueous electrolytic conductance.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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