ISSN:
1434-193X
Schlagwort(e):
Hydroaminomethylation
;
Rhodium
;
Catalysis
;
Carbonylation
;
Heterofunctionalised allylic compounds
;
Chemistry
;
General Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
-Heterofunctionalised allylic ethers 1, silanes 5, and amines 9 are hydroformylated in the presence of primary or secondary amines 2 to form the corresponding γ-amino- and δ-amino-functionalised compounds. The rhodium(I)-catalysed reaction sequence proceeds by aldehyde formation and subsequent reductive amination to generate the corresponding functionalised secondary or tertiary amines. This selective one-pot hydroaminomethylation procedure establishes access to γ-amino- and δ-amino-functionalised ethers, amines or silanes with potential biological activity.
Zusätzliches Material:
4 Tab.
Materialart:
Digitale Medien
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