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  • 1
    Publikationsdatum: 2019-07-11
    Beschreibung: Collisional quenching of molecular species is an important process in a variety of astrophysical environments including interstellar clouds, photodissociation regions, and cool stellar/planetary atmospheres. In this work, quantum mechanical scattering calculations are presented for the rotational and vibrational relaxation of rotationally-excited CO due to collisions with H, He and H2 for collision energies between 10(exp -6) and approx.15000/cm. The calculations were performed using the close-coupling approach and the l-labeled form of the coupled-states approximation. Cross sections and rate coefficients for the quenching of the v=0-2, j=0-6 levels of CO are presented and comparisons with previous calculations and measurements, where available, are provided.
    Schlagwort(e): Astrophysics
    Materialart: Proceedings of the NASA Laboratory Astrophysics Workshop; 288-291; NASA/CP-2006-214549
    Format: application/pdf
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Publikationsdatum: 2019-07-11
    Beschreibung: It has been suggested that in photon-dominated regions, oxygen chemistry is initiated by the O+H2 yields OH+H reaction. The reaction has an energy barrier of about 0.4 eV with ground state reactants and it is slow at low temperatures. There is strong experimental evidence that vibrational excitation of the H2 molecule increases the reactivity significantly. We present extensive quantum calculations of cross sections and rate coefficients for the O+H2(v) reaction for v = 0 - 3 of the H2 molecule and show that the vibrational excitation of the molecule has a significant effect on reactivity, especially at low temperatures.
    Schlagwort(e): Astrophysics
    Materialart: Proceedings of the NASA Laboratory Astrophysics Workshop; 225-228; NASA/CP-2006-214549
    Format: application/pdf
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Publikationsdatum: 2019-07-11
    Beschreibung: We present preliminary results of a full quantum calculation of state to state cross sections for H on H2. These cross sections are calculated for v=0,4 j=0,15 for energies up to 3.0 eV. The cross sections are calculated on the BKMP2 potential surface (Boothroyd et al. 1996) with the ABC scattering code (Skouteris et al. 2000).
    Schlagwort(e): Astrophysics
    Materialart: Proceedings of the NASA Laboratory Astrophysics Workshop; 210-212; NASA/CP-2006-214549
    Format: application/pdf
    Standort Signatur Erwartet Verfügbarkeit
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