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  • 1
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    Detection of abundant ethane and methane, along with carbon monoxide and water, in comet C/1996 B2 Hyakutake: evidence for interstellar origin (1996)
    In:  Other Sources
    Details
    Publication Date: 2011-08-24
    Description: The saturated hydrocarbons ethane (C2H6) and methane (CH4) along with carbon monoxide (CO) and water (H2O) were detected in comet C/1996 B2 Hyakutake with the use of high-resolution infrared spectroscopy at the NASA Infrared Telescope Facility on Mauna Kea, Hawaii. The inferred production rates of molecular gases from the icy, cometary nucleus (in molecules per second) are 6.4 X 10(26) for C2H6, 1.2 X 10(27) for CH4, 9.8 X 10(27) for CO, and 1.7 X 10(29) for H2O. An abundance of C2H6 comparable to that of CH4 implies that ices in C/1996 B2 Hyakutake did not originate in a thermochemically equilibrated region of the solar nebula. The abundances are consistent with a kinetically controlled production process, but production of C2H6 by gas-phase ion molecule reactions in the natal cloud core is energetically forbidden. The high C2H6/CH4 ratio is consistent with production of C2H6 in icy grain mantles in the natal cloud, either by photolysis of CH4-rich ice or by hydrogen-addition reactions to acetylene condensed from the gas phase.
    Keywords: Lunar and Planetary Science and Exploration
    Type: Science (ISSN 0036-8075); Volume 272; 5266; 1310-4
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  • 2
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    Design concept for an IR mapping spectrometer for the Pluto fast flyby mission (1993)
    In:  Other Sources
    Details
    Publication Date: 2019-01-25
    Description: The design of an IR mapping spectrometer that exceeds all the criteria of the Pluto Fast Flyby Mission will be presented. The instrument has a mass of approximately 1700 g and uses less than 4 W of power. The design concept is based on an f/3 spectrograph using an aberration-corrected concave holographic grating. Up to four spectral regions can be covered simultaneously by dividing the grating into two to four sections, each imaging the entrance slit on a different area of the array. The spectrography will be fed by a lightweight 5 in. f/3 telescope based on SDIO precepts. In order to provide spectroscopic access to the fundamental molecule frequencies, an extended-range NICMOS array to approximately 3.5 microns and an InSb array going to 5.8 microns will be considered.
    Keywords: SPACECRAFT INSTRUMENTATION
    Type: Lunar and Planetary Inst., Workshop on Advanced Technologies for Planetary Instruments, Part 1; p 8
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  • 3
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    A Comparison of Oxidized Carbon Abundances among Comets (2010)
    In:  CASI
    Details
    Publication Date: 2018-06-06
    Description: Comets contain relatively well preserved icy material remaining from the epoch of Solar System formation, however the extent to which these ices are modified from their initial state remains a fundamental question in cometary science. As a comet approaches the Sun, sublimation of the ices contained in its nucleus (termed " native ices") releases parent volatiles into the coma, where they can be measured spectroscopically. One means of assessing the degree to which interstellar ices were processed prior to their incorporation into cometary nuclei is to measure the relative abundances of chemically-related parent volatiles. For example, formation of C2H6 by hydrogen atom addition (e.g., to C2H2) on surfaces of ice-mantled grains was proposed to explain the high C2H6 to CH4 abundance observed in C/1996 B2 (Hyakutake) [1]. The large C2H6/CH4 abundance ratios measured universally in comets, compared with those predicted by gas phase production of C2H6, establishes H-atom addition as an important and likely ubiquitous process. CO should also be hydrogenated on grain surfaces. Laboratory irradiation experiments on interstellar ice analogs indicate this to require very low temperatures (T approx. 10-25 K), the resulting yields of H2CO and CH3OH being highly dependent both on hydrogen density (i.e., fluence) and on temperature ([2],[3]). This relatively narrow range in temperature reflects a lack of mobility below 8-10 K on the one hand, and reduced sticking times for H-atoms as grain surfaces are warmed above 20 K on the other. The relative abundances of these three chemically-related molecules in comets provides one measure of the efficiency of H-atom addition to CO on pre-cometary grains (Fig. 1).
    Keywords: Astronomy
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  • 4
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    Primary Volatiles During the 2010 Apparition of Comet 103P/Hartley-2 as Revealed at Infrared Wavelengths: Production Rates and Spatial Profiles (2011)
    In:  CASI
    Details
    Publication Date: 2019-07-19
    Description: We acquired high resolution near-infrared spectra of comet 103P/Hartley-2 with NIRSPEC at the W. M. Keck Observatory and CRIRES at the ESO VLT, emphasizing primary volatiles before, during, and after the comet's close approach to Earth (July-December 2010; R(sub h) =1.62 right arrow 1.26 AU). We will present the mixing ratios for trace volatiles (C2H6, HCN, CH3OH, etc.), their rotational temperatures, and their spatial distributions in the coma both along the polar jet (UT 19.5 October) and nearly orthogonal to the jet (UT 22.5 October).
    Keywords: Astronomy
    Type: 42nd Lunar and Planetary Science Conference; Mar 07, 2011 - Mar 11, 2011; The Woodlands, TX; United States
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  • 5
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    A Quantum Band Model of the nu3 Fundamental of Methanol (CH3OH) and Its Application to Fluorcescence Spectra of Comets (2012)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Description: Methanol (CH3OH) radiates efficiently at infrared wavelengths, dominating the C-H stretching region in comets, yet inadequate quantum-mechanical models have imposed limits on the practical use of its emission spectra. Accordingly, we constructed a new line-by-line model for the 3 fundamental band of methanol at 2844 / cm (3.52 micron) and applied it to interpret cometary fluorescence spectra. The new model permits accurate synthesis of line-by-line spectra for a wide range of rotational temperatures, ranging from 10 K to more than 400 K.We validated the model by comparing simulations of CH3OH fluorescent emission with measured spectra of three comets (C/2001 A2 LINEAR, C/2004 Q2 Machholz and 8P/Tuttle) acquired with high-resolution infrared spectrometers at high-altitude sites. The new model accurately describes the complex emission spectrum of the nu3 band, providing distinct rotational temperatures and production rates at greatly improved confidence levels compared with results derived from earlier fluorescence models. The new model reconciles production rates measured at infrared and radio wavelengths in C/2001 A2 (LINEAR). Methanol can now be quantified with unprecedented precision and accuracy in astrophysical sources through high-dispersion spectroscopy at infrared wavelengths
    Keywords: Astrophysics
    Type: GSFC.CPR.01134.2012 , The Astrophysical Journal; 747; 1; 37
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  • 6
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    The Composition of Comet C/2009 PI (Garradd) from Infrared Spectroscopy: Evidence for an Oxygen-Rich Heritage? (2012)
    In:  CASI
    Details
    Publication Date: 2019-07-13
    Description: Comets retain relatively primitive icy material remaining from the epoch of Solar System for111ation, however the extent to which their ices are modified remains a key question in cometary science. One way to address this is to measure the relative abundances of primary (parent) volatiles in comets (i.e., those ices native to the nucleus). High-resolution (lambda/delta lambda greater than 10(exp 4)) infrared spectroscopy is a powerful tool for measuring parent volatiles in comets through their vibrational emissions in the ~ 3-5 micrometer region. With modern instrumentation on worldclass telescopes, we can quantify a multitude of species (e.g., H2O, C2H2, CH4, C2H6 CO, H2CO, CH3OH, HCN, NH3), even in comets with modest gas production. In space environments, compounds of keen interest to astrobiology could originate from HCN and NH3 (leading to amino acids), H2CO (leading to sugars), or C2H6 and CH4 (suggested precursors of ethyl- and methylamine). Measuring the abundances of these precursor molecules and their variability among comets contributes to understanding the synthesis of the more complex prebiotic compounds.
    Keywords: Astronomy
    Type: GSFC.ABS.01161.2012 , Asteroids, Comets, Meteors (ACM) 2012; May 16, 2012 - May 20, 2012; Niigata; Japan
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  • 7
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    Temporal and Spatial Aspects of Gas Release During the 2010 Apparition of Comet 103P/Hartley-2 (2011)
    In:  CASI
    Details
    Publication Date: 2019-07-13
    Description: We report measurements of eight primary volatiles (H2O, HCN, CH4, C2H6, CH3OH, C2H2, H2CO, and NH3) and two product species (OH and NH2) in comet 103P/Hartley-2 using high dispersion infrared spectroscopy. We present production rates for individual volatiles species, their mixing ratios relative to water, and their spatial distributions in the coma on multiple dates that span the interval Sept. - Dec. 2010. The production rates vary strongly with nucleus rotation, but the mixing ratios remain constant throughout the campaign. The released primary volatiles exhibit diverse spatial properties which favor the presence of separate polar and apolar ice phases in the nucleus, establish dust and gas release from icy clumps (and also, directly from the nucleus), and provide insights into the driver for the cyanogen (CN) polar jet.
    Keywords: Lunar and Planetary Science and Exploration
    Type: GSFC.OVPR.4972.2011 , 43rd Annual DPS Meeting; Oct 02, 2011 - Oct 07, 2011; Nantes; France
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  • 8
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    The Molecular Composition of Comet C/2007 W1 (Boattini): Evidence of a Peculiar Outgassing and a Rich Chemistry (2011)
    In:  Other Sources
    Details
    Publication Date: 2019-07-13
    Description: We measured the chemical composition of Comet C/2007 W1 (Boattini) using the long-slit echelle grating spectrograph at Keck-2 (NIRSPEC) on 2008 July 9 and 10. We sampled 11 volatile species (H2O, OH*, C2H6, CH3OH, H2CO, CH4, HCN, C2H2, NH3, NH2, and CO), and retrieved three important cosmogonic indicators: the ortho-para ratios of H2O and CH4, and an upper-limit for the D/H ratio in water. The abundance ratios of almost all trace volatiles (relative to water) are among the highest ever observed in a comet. The comet also revealed a complex outgassing pattern, with some volatiles (the polar species H2O and CH3OH) presenting very asymmetric spatial profiles (extended in the anti-sunward hemisphere), while others (e.g., C2H6 and HCN) showed particularly symmetric profiles. We present emission profiles measured along the Sun-comet line for all observed volatiles, and discuss different production scenarios needed to explain them. We interpret the emission profiles in terms of release from two distinct moieties of ice, the first being clumps of mixed ice and dust released from the nucleus into the sunward hemisphere. The second moiety considered is very small grains of nearly pure polar ice (water and methanol, without dark material or apolar volatiles). Such grains would sublimate only very slowly, and could be swept into the anti-sunward hemisphere by radiation pressure and solar-actuated non-gravitational jet forces, thus providing an extended source in the anti-sunward hemisphere.
    Keywords: Lunar and Planetary Science and Exploration
    Type: GSFC-JA-01229-2012 , Icarus (ISSN 0019-1035); 216; 1; 227-240
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  • 9
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    The Volatile Fraction of Comets as Quantified at Infrared Wavelengths - An Emerging Taxonomy and Implications for Natal Heritage (2012)
    In:  CASI
    Details
    Publication Date: 2019-07-13
    Description: It is relatively easy to identify the reservoir from which a given comet was ejected. But dynamical models demonstrate that the main cometary reservoirs (Kuiper Belt, Oort Cloud) each contain icy bodies that formed in a range of environments in the protoplanetary disk, and the Oort Cloud may even contain bodies that formed in disks of sibling stars in the Sun s birth cluster. The cometary nucleus contains clues to the formative region(s) of its individual components. The composition of ices and rocky grains reflect a range of processes experienced by material while on the journey from the natal interstellar cloud core to the cometary nucleus. For that reason, emphasis is placed on classifying comets according to their native ices and dust (rather than orbital dynamics). Mumma & Charnley [1] reviewed the current status of taxonomies for comets and relation to their natal heritage.
    Keywords: Astrophysics
    Type: GSFC.CPR.6307.2012 , Asteroids, Comets and Meteors 2012; May 16, 2012 - May 20, 2012; Niigata; Japan
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  • 10
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    The Evolution of Volatile Production in Comet C-2009 P1(Garradd) During its 2011-2012 Apparition (2015)
    In:  CASI
    Details
    Publication Date: 2019-07-12
    Description: We report observations at millimeter and submillimeter wavelengths of comet C/2009 P1 (Garradd) from 2011 December 28 to 2012 April 24, using the Arizona Radio Observatory submillimeter telescope (SMT) and the James Clerk Maxwell Telescope (JCMT). Garradd is a dynamically young long-period comet from the Oort Cloud, with a periodicity of 127,000 years, that reached perihelion on 2011 December 23 (at Heliocentric distance (Rh) = 1.55 Astronomical Units and delta = 20.1 Astronomical Units ) and made its closest approach to the Earth on 2012 March 05 (at Heliocentric distance (Rh) = 1.84 Astronomical Units and delta = 1.26 Astronomical Units). We obtained gas production rates, and molecular abundances relative to water for HCN, ortho-H2CO, CS, CO and CH3OH. A rotational temperature, T (sub rot) approximately equal to 50 degrees Kelvin, was determined by observing multiple methanol lines with the JCMT. By averaging the abundance ratio relative to water from the SMT and the JCMT we derive: CO: 7.03 plus or minus 1.84 percent, HCN: 0.04 plus or minus 0.01 percent, ortho H2CO: 0.14 plus or minus 0.03 percent as a parent molecule (and 0.28 plus or minus 0.06 percent as an extended source), CS: 0.03 plus or minus 0.01 percent and CH3OH: 3.11 for a range from plus 1:86 to minus 0.51 percent. We concluded that Garradd is normal in CH3OH, depleted in HCN, ortho-H2CO and CS and slightly enriched in CO with respect to typically observed cometary mixing ratios. We also studied the temporal evolution of HCN and CO and find that the production of HCN has a trend similar to water (but with short-term variation), with a decrease after perihelion, while that of CO shows contrary behavior: remaining constant or increasing after perihelion.
    Keywords: Lunar and Planetary Science and Exploration; Astronomy
    Type: GSFC-E-DAA-TN23079
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