ALBERT

Description: The observability of minor species in Titan's atmosphere in its infrared thermal range is systematically studied and modeled to generate synthetic spectra. The model results on methane, water vapor, benzene, allene, and other heavier trace molecules are used to illustrate the capabilities of instruments aboard the Infrared Space Observatory, in particular a high-resolution composite infrared spectrometer, to determine vertical distributions of the molecules in a few hours of integration time.

Description: During the 1981 Voyager encounter, Titan's stratosphere exhibited a large thermal asymmetry, with high northern latitudes being colder than comparable southern latitudes. Given the short radiative time constant, this asymmetry would not be expected at the season of the Voyager observations (spring equinox), if the infrared and solar opacity sources were distributed symmetrically. We have investigated the radiative budget of Titan's stratosphere, using two selections of Voyager IRIS spectra recorded at symmetric northern and southern latitudes. In the region 0.1-1 mbar, temperatures are 7 K colder at 50 degrees N than at 53 degrees S and the difference reaches approximately 13 K at 5 mbar. On the other hand, the northern region is strongly enriched in nitriles and hydrocarbons, and the haze optical depth derived from the continuum emission between 8 and 15 micrometers is twice as large as in the south. Cooling rate profiles have been computed at the two locations, using the gas and haze abundances derived from the IRIS measurements. We find that, despite lower temperatures, the cooling rate profiles in the pressure range 0.15-5 mbar are 20 to 40% larger in the north than in the south, because of the enhanced concentrations of infrared radiators. Because the northern hemisphere appears darker than the southern one in the Voyager images, enhanced solar heating is also expected to take place at 50 degrees N. Solar heating rate profiles have been calculated, with two different assumptions on the origin of the hemispheric asymmetry. In the most likely case where it results from a variation in the absorbance of the haze material, the heating rates are found to be 12-15% larger at the northern location than at the southern one, a smaller increase than that in the cooling rates. If the lower albedo in the north results from an increase in the particle number density, a 55 to 75% difference is found for the pressure range 0.15-5 mbar, thus larger than that calculated for the cooling rates. Considering the uncertainties in the haze model, dynamical heat transport may significantly contribute to the meridional temperature gradients observed in the stratosphere. On the other hand, the latitudinal variation in gas and haze composition may be sufficient to explain the entire temperature asymmetry observed, without invoking a lag in the thermal response of the atmosphere due to dynamical inertia.

Description: The observations of Titan performed by the Infrared Space Observatory (ISO) short wavelength spectrometer (SWS), in the 2 micrometer to 45 micrometer region using the grating mode, are reported on. Special attention is given to data from Titan concerning 7 micrometer to 45 micrometer spectral resolution. Future work for improving Titan's spectra investigation is suggested.

Description: The albedo, T(eff), and energy balance of Uranus are presently derived from Voyager IR Spectrometer and Radiometer data. By obtaining the absolute phase curve of Uranus, it has become possible to evaluate the Bond albedo without making separate determinations of the geometric albedo and phase integral. An orbital mean value for the bolometric Bond albedo of 0.3 + or - 0.049 yields an equilibrium temperature of 58.2 + or - 1.0 K. Thermal spectra from pole-to-pole latitude coverage establish a T(eff) of 59.1 + or - 0.3 K, leading to an energy balance of 1.06 + or - 0.08 for Uranus.

Description: A systematic study made of the observability of minor species in Titan's atmosphere is reported. This was done by modeling its thermal spectrum at 0.5/cm resolution under the conditions of the Infrared Space Observatory (ISO) and Composite Infrared Radiometer Spectrometer (CIRS), and by exploring the capabilities of the 0.03/cm resolution mode of ISO.

Description: Voyager 1 IR spectra have been used to infer the Titan north polar region minor stratospheric constituents' temperature structure and vertical distribution. The mixing ratios of the species C4H2, C2H6, C3H4, HCN, HC3N, and C2N2 increase with altitude, implying upper stratosphere (and higher) formation regions. When compared with abundances obtained near the equator, it is found that the HC3N and C2N2 nitriles, together with such hydrocarbons as C2H4, C3H4, and C4H2, are substantially enhanced over the north polar region. A factor-of-2 (minimum) depletion of CO2 relative to the equator is noted; it is judged that current photochemical models are inadequate bases for interpretation of these observations.

Description: A fundamental goal of solar system exploration is to understand the origin of the solar sys-tem, the initial stages, conditions, and processes by which the solar system formed, how the formation pro-cess was initiated, and the nature of the interstellar seed material from which the solar system was born. Key to understanding solar system formation and subsequent dynamical and chemical evolution is the origin and evolution of the giant planets and their atmospheres. Several theories have been put forward to explain the process of solar system formation, and the origin and evolution of the giant planets and their atmospheres. Each theory offers quantifiable predictions of the abundances of noble gases He, Ne, Ar, Kr, and Xe, and abundances of key isotopic ratios 4He3He, DH, 15N14N, 18O16O, and 13C12C. Detection of certain dis-equilibrium species, diagnostic of deeper internal pro-cesses and dynamics of the atmosphere, would also help discriminate between competing theories. Measurements of the critical abundance profiles of these key constituents into the deeper well-mixed at-mosphere must be complemented by measurements of the profiles of atmospheric structure and dynamics at high vertical resolution and also require in situ explora-tion. The atmospheres of the giant planets can also serve as laboratories to better understand the atmospheric chem-istries, dynamics, processes, and climates on all planets including Earth, and offer a context and provide a ground truth for exoplanets and exoplanetary systems. Additionally, Giant planets have long been thought to play a critical role in the development of potentially habitable planetary systems. In the context of giant planet science provided by the Galileo, Juno, and Cassini missions to Jupiter and Sat-urn, a small, relatively shallow Saturn probe capable of measuring abundances and isotopic ratios of key at-mospheric constituents, and atmospheric structure in-cluding pressures, temperatures, dynamics, and cloud locations and properties not accessible by remote sens-ing can serve to test competing theories of solar system and giant planet origin, chemical, and dynamical evolution.

Description: In 2012 an emission feature at 220 cm(exp -1) in Titan's far-infrared spectrum was seen for the first time in the south. Attributed to a stratosphere ice cloud formed at the winter pole, the 220 (exp -1) emission had previously been seen only at high northern latitudes where it bad been decreasing since the arrival of Cassini in 2004. Our far-infrared observations were performed With the Composite Infrared Spectrometer (CIRS) on Caasini. Although it bad been expected that the 220 cm(exp -1) emission would eventnal1y appear in the south, the emission appeared rather suddenly, increasing by a factor of at least four between February (when it was not detected) and July 2012. At the time of our observations, one Titan month after equinox, the 220 cm(exp -1) feature was present in both the north and south and showed a trend of continued slow decrease in the north and steep increase in the south. As has been the case in the north, the emission in the south was confined to high latitudes associated with winter polar shadowing. Our spectroscopic detection of the southern 220 cm(exp -1) ice cloud coincided with the rapid formation in 2012 of a haze hood and vortex at the south pole as seen in Cassini image. The 220 cm(exp -1) feature was first observed by the Infrared Interferometer Spectrometer (IRIS) on Voyager I and has been extensively studied in the north by CIRS. Until now the 220 cm(exp -1) emission, like the polar hood, has been associated solely with the north, owing to the fact that Voyager and Cassini have viewed Titan only during winter-spring. In 2012 we witnessed the start of a seasonal shift of this pattern to the south. The 220 cm(exp -1) emission arises from altitudes of 80-150 km and peaks sharply near 140 km. The material responsible for the spectral feature is not known, but indirect evidence hints at a condensate arising from complex nitriles, which also tend to be present only at high winter latitudes.

Description: In August 2009 Titan passed through northern spring equinox, and the southern hemisphere passed into fall. Since then, the moon's atmosphere has been closely watched for evidence of the expected seasonal reversal of stratospheric circulation, with increased northern insolation leading to upwelling, and consequent downwelling at southern high latitudes. If the southern winter mirrors the northern winter, this circulation will be traced by increases in short-lived gas species advected downwards from the upper atmosphere to the stratosphere. The Cassini spacecraft in orbit around Saturn carries on board the Composite Infrared Spectrometer (CIRS), which has been actively monitoring the trace gas populations through measurement of the intensity of their infrared emission bands (7-1000 micron). In this presentation we will show fresh evidence from recent CIRS measurements in June 2012, that the shortest-lived and least abundant minor species (C3H4, C4H2, C6H6, HC3N) are indeed increasing dramatically southwards of 50S in the lower stratosphere. Intriguingly, the more stable gases (C2H2, HCN, CO2) have yet to show this trend, and continue to exhibit their 'summer' abundances, decreasing towards the south pole. Possible chemical and dynamical explanations of these results will be discussed , along with the potential of future CIRS measurements to monitor and elucidate these seasonal changes.

Description: Seven years after Cassini's Saturn orbit insertion, we have in hand almost a complete picture of the stratospheric evolution within a Titanian year by combining Voyager 1 Infrared Radiometer Spectrometer (IRIS) measurements from 1980, Cassini Composite Infrared Spectrometer (CIRS) continuous recordings from 2004 to 2010 and the intervening ground-based and space-borne observations with ISO (Coustenis et al 2003). We have re-analyzed the Voyager l/IRIS data acquired during the 1980 encounter, 30 years (one Titan revolution) before 2010, with the most recent spectroscopic data releases and haze descriptions (Vinatier et al 2010, 2012) by using our radiative transfer code (ART). The re-analysis confirms the Vl/IRIS retrievals by Coustenis and Bezard (1995) and updates the abundances for all molecules and latitudes based on new temperature, haze and spectroscopic parameters. ART was also applied to all available CIRS spectral averages corresponding to more than 70 flybys binned over 10 deg in latitude for both medium (2.5 cm(exp -1) and higher (0.5 cm(exp -1) resolutions and from nadir and limb data both. In these spectra, we search for variations in temperature (following the method in Achterberg et al 2011) and composition at northern (around 50 deg N), equatorial and southern (around 50 deg S) latitudes as the season on Titan progresses and compare them to the new Vl/IRIS, ISO and other ground-based reported composition values (Coustenis et al., 2012, in prep). Other latitudes were examined in previous papers (e.g. Coustenis et al 2010).