ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Carbonyl Metal Compounds with Polydentate Cyclic Ligands. I. Pentacarbonyl Complexes of s-Trithiane and Related CompoundsThe complexes (RCHS)nM(CO)5 (R = H, CH3, n = 3; R = H, n = 4; M = Cr, Mo, W) were prepared from the tetrahydrofuran pentacarbonyl metal compounds and the respective ligands. The Cotton-Kraihanzel force constants of these complexes indicate the sulfur ligands to be slightly more basic than triphenylphosphine. The trimethyltrithiane complexes (R = CH3, n = 3) exhibit rapid intramolecular exchange of the M(CO)5-group along the three coordination centers of the ligand.
Notes:
Die Komplexe (RCHS)nM(CO)5 (R = H, CH3, n = 3; R = H, n = 4; M = Cr, Mo, W) wurden aus den Tetrahydrofuran-pentacarbonylmetallverbindungen und dem jeweiligen Liganden dargestellt. Die Cotton-Kraihanzel-Kraftkonstanten dieser Komplexe weisen die Schwefelliganden als geringfügig schwächere Akzeptoren, verglichen mit Triphenyl-phosphin, aus. Die Komplexe des Trimethyltrithians (R = CH3, n = 3) zeigen einen raschen intramolekularen Austausch der M(CO)5-Gruppe über die drei Koordinationsstellen des Liganden.
Additional Material:
4 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19754160316
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