ISSN:
1600-5368
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The NiII centre in the cation of the title compound, [Ni(C6H12S3)2]Br2·4H2O, occupies a crystallographic inversion centre and is octahedrally coordinated by six S-donors from two [9]aneS3 ligands. Ni—S distances range from 2.3749 (16) to 2.4077 (15) Å and S—Ni—S angles where both thia donors belong to the same ligand lie in a narrow range between 88.09 (5) and 88.67 (6)°. The water molecules participate in extensive hydrogen bonding with each other and with the Br− anions to form double chains with eight- and 12-membered hydrogen-bonded rings running along the crystallographic a direction.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S1600536801011187
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