ISSN:
1600-5368
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The title compound, [Fe(C2H3N)6][SbF6]2, (I), synthesized by reaction of AgSbF6 with FeCl2 in CH3CN, is isostructural with the analogous nickel complex [see Leban et al. (1987), Acta Cryst. C43, 1888–1890]. The FeII centre in the cation occupies a crystallographic \overline 3 site and is octahedrally coordinated by six acetonitrile ligands, with an Fe—N distance of 2.153 (2) Å and an N—Fe—N angle of 88.05 (10)°. The SbF6− anion lies on a crystallographic threefold rotation axis.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S1600536801017585
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