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  • 1
    ISSN: 1420-9136
    Keywords: High pressure ; pressure calibration ; ZnTe ; synchrotron X-ray source ; DIA type cubic anvil apparatus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract Pressure behavior of ZnTe at room temperature was studied using an X-ray energy dispersive method on a DIA type cubic anvil apparatus (SAM-85) at NSLS-X17B1. By using powdered polyethylene, the sample and NaCl for a pressure scale were held under quasihydrostatic conditions, which were confirmed by X-ray diffraction method. Two high-pressure phase transitions were confirmed using X-ray powder diffraction simultaneously with electrical resistance measurements. The phase transition pressures under quasihydrostatic conditions were determined to be 9.6 GPa, at which the resistance increased, and 12.0 GPa, which was the midpoint of a large resistance decrease. Errors in the pressure determinations were estimated to be less than 0.2 GPa. These pressure values may depend on grain size and anisotropic stress effects on the calibrant. From X-ray observation of ZnTe, the bulk modulus of the zinc blende structure was calculated to beK 0=51(3) GPa andK 0 ′ =3.6(0.8), and the first transition at 9.6 GPa was found to have about 9% volume change. It was consistent with an anomaly in the pressure generating curves.
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Pure and applied geophysics 146 (1996), S. 533-549 
    ISSN: 1420-9136
    Keywords: Lower mantle ; seismic tomography ; thermoelasticiti ; composition models ; geodynamics ; shear modulus
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract We estimate (ϖμ/ϖT) P of the lower mantle at seismic frequencies using two distinct approaches by combining ambient laboratory measurements on lower mantle minerals with seismic data. In the first approach, an upper bound is estimated for |(ϖμ/ϖT) P | by comparing the shear modulus (μ) profile of PREM with laboratory room-temperature data of μ extrapolated to high pressures. The second approach employs a seismic tomography constraint (ϖ lnV S /ϖ lnV P ) P =1.8–2, which directly relates (ϖμ/ϖT) P with (ϖK S /ϖT) P . An average (ϖK S /ϖT) P can be obtained by comparing the well-established room-temperature compression data for lower mantle minerals with theK S profile of PREM along several possible adiabats. Both (ϖK S /ϖT) and (ϖμ/ϖT) depend on silicon content [or (Mg+Fe)/Sil of the model. For various compositions, the two approaches predict rather distinct (ϖμ/ϖT) P vs. (ϖK S /ϖT) P curves, which intersect at a composition similar to pyrolite with (ϖμ/ϖT) P =−0.02 to −0.035 and (ϖK S /ϖT) P =−0.015 to −0.020 GPa/K. The pure perovskite model, on the other hand, yields grossly inconsistent results using the two approaches. We conclude that both vertical and lateral variations in seismic velocities are consistent with variation due to pressure, temperature, and phase transformations of a uniform composition. Additional physical properties of a pyrolite lower mantle are further predicted. Lateral temperature variations are predicted to be about 100–250 K, and the ratio of (ϖ lnp/ϖ lnV S ) P around 0.13 and 0.26. All of these parameters increase slightly with depth if the ratio of (ϖ lnV S /ϖ lnV P ) P remains constant throughout the lower mantle. These predicted values are in excellent agreement with geodynamic analyses, in which the ratios (ϖ ln ϱ/ϖ lnV S ) P and (ϖ ϱ/ϖ lnV S ) P are free parameters arbitrarily adjusted to fit the tomography and geoid data.
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