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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 321 (1985), S. 589-592 
    ISSN: 1434-601X
    Keywords: 34.50.Fa ; 25.70.−z
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We show that emission of high-energy electrons and photons in nuclear collisions at intermediate energies is sensitive to the space-time evolution of the reaction. The electron and photon spectra measure related but complementary quantities connected with the nuclear charge distribution. We show that at 60 MeV/u beam energy production of 50 MeV electrons is predicted to measurable probability.
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 323 (1986), S. 261-274 
    ISSN: 1434-601X
    Keywords: 34.50.Fa ; 25.70.Ef ; 12.20.Fv
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Dynamical and spontaneous positron emission are investigated for heavy-ion collisions with long time delay using a semiclassical description. Numerical results and analytical expressions for the characteristic quantities of the resulting spontaneous positron line, i.e., its position, width, and cross section, are compared. The expected behaviour of the line position and cross section and its visibility against the spectrum of dynamically created positrons is discussed in dependence on the united chargeZ u of projectile and target nucleus in a range of systems fromZ u =180 up toZ u =188. The results are confronted with presently available experimental data, and possible implications on further experiments are worked out.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 323 (1986), S. 275-280 
    ISSN: 1434-601X
    Keywords: 34.50.Fa ; 25.70.Gh ; 12.20.Fv
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract U-U collisions at energies near the Coulomb barrier are discussed. A quantum mechanical treatment of nuclear motion including the influence of quasibound states in a pocket of the scattering potential is developed. Positron emission probabilities are calculated exhibiting a sharp line due to the decay of a hole in the supercritical 1s-state. In addition conversion processes and multiple pockets in the potential creating sidebands in the spectrum are computed.
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 329 (1988), S. 365-369 
    ISSN: 1434-601X
    Keywords: 34.50.Fa ; 25.70.Lm
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We calculateδ-electron and positron distributions resulting from heavy ion collisions under consideration of a sequential fission in the outgoing channel. The resulting spectra are found to be only weakly sensitive to the underlying dynamics of the fission process. Thus experiments of deep inelastic scattering provide information mainly on the primary reaction process.
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 597 (1991), S. 9-18 
    ISSN: 0044-2313
    Keywords: Alkali fluoro palladate(II) ; preparation ; single crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: New Fluoropalladates(II) M2[PdF4] (M = Na, K) and K2RbPdF5For the first time bright yellow single crystals M2[PdF4] (M = Na, K) have been obtained and their structure determined. K2[PdF4] crystallizes monoclinic, space group C2/m-C2h3 (No. 12) with a = 975.2(3) pm, b = 597.6(1) pm, c = 420.2(1) pm, β = 92.17(2)° and Z = 2. Structure related Na2[PdF4] crystallizes monoclinic too, but in space group P21/c-C2h5 (No. 14) with a = 340.88(7) pm, b = 561.1(1) pm, c = 999.2(2) pm, β = 93.97(2)° and Z = 2. K2RbPdF5, yellow, crystallizes tetragonal with a = 724.9(1) pm, c = 627.9(1) pm, Z = 2 and is isotypic with Rb2CsPdF5 (space group P4/mbm-D4h5, No. 127), an ordered structure variant of the Rb3PdF5-type [1].
    Notes: Erstmals konnten leuchtend gelbe Einkristalle M2[PdF4] (M = Na, K) dargestellt und ihre Struktur bestimmt werden. K2[PdF4] kristallisiert monoklin, R.G. C2/m-C32h (Nr. 12) mit a = 975,2(3) pm, b = 597,6(1) pm, c = 420,2(1) pm, β = 92,17(2)° und Z = 2. Strukturverwandtes Na2[PdF4] kristallisiert ebenfalls monoklin, jedoch in der R.G. P21/c-C2h5 (Nr. 14) mit a = 340,88(7) pm, b = 561,1(1) pm, c = 999,2(2) pm, β = 93,97(2)°und Z = 2. K2RbPdF5, gelb, kristallisiert tetragonal mit a = 724,9(1) pm, c = 627,9(1) pm, Z = 2 und ist isotyp zu Rb2CsPdF5 (R.G. P4/mbm-D4h5, Nr. 127), einer geordneten Strukturvarianten des Rb3PdF5-Typs [1].
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 598 (1991), S. 103-110 
    ISSN: 0044-2313
    Keywords: Lithium, rubidium tetrafluoroaurate(III) ; preparation ; crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis and Structure of Tetrafluoroaurates(III) MI[AuF4] with MI = Li, RbSingle crystal investigations on Rb[AuF4], light yellow, confirm the tetragonal unit cell (K[BrF4]-type) with a = 618.2(1) and c = 1191(1) pm, Z = 4, space group I 4/mcm-D4h18 (No. 140).Li[AuF4], light yellow too, crystallizes monoclinic with a = 485.32(7), b = 634.29(8), c = 1004.43(13) pm, β = 92.759(12), Z = 4; space group P 2/c-C2h4 (No. 13). The structure of Li[AuF4] is related to the Rb[AuF4]-type of structure.
    Notes: Einkristalluntersuchungen an Rb[AuF4], hellgelb, bestätigen die tetragonale Elementarzelle (K[BrF4]-Typ) mit a = 618,2(1) und c = 1191(1) pm, Z = 4, Raumgruppe I 4/mcm-D4h18 (Nr. 140).Ebenfalls hellgelbes Li[AuF4] hingegen kristallisiert monoklin (eigener Typ) in der Raumgruppe P 2/c-C2h4 (Nr. 13) mit a = 485,32(7), b = 634,29(8), c = 1004,43(13) pm, β = 92,759(12), Z = 4 und ist mit der Rb[AuF4]-Struktur verwandt.
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 619 (1993), S. 1661-1668 
    ISSN: 0044-2313
    Keywords: Rare earth tetrafluoroaurates(III) ; preparation ; crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Tetrafluoroaurates(III) of Lanthanides MF[AuF4]2 (M = Tm, Yb, Lu).Tetrafluoroaurates(III) MF[AuF4]2 with M = Tm, Yb, Lu, all yellow, have been prepared for the first time. From single crystal data they crystallize orthorhombic, space group Pbcn-D2h14 (No. 60) with M = Tm: a = 1 102.92(8) pm, b = 904.38(8) pm, c = 2 164.46(23) pm; M = Yb: a = 1 100.98(12) pm, b = 902.23(8) pm, c = 2 157.36(23) pm; M = Lu: a = 1 099.28(18) pm, b = 900.70(15) pm, c = 2 151.50(46) pm.
    Notes: Neu dargestellt wurden gelbe Tetrafluoroaurate(III) der Lanthaniden MF[AuF4]2 mit M = Tm, Yb, Lu. Nach Einkristalluntersuchungen kristallisieren diese orthorhombisch in der Raumgruppe Pbcn-D2h14 (Nr. 60) mit Z = 12. Im Einzelnen wurden folgende Werte gefunden: Für M = Tm: a = 1 102,92(8) pm, b = 904,38(8) pm, c = 2 164,46(23) pm; M = Yb: a = 1 100,98(12) pm, b = 902,23(8) pm, c = 2 157,36(23) pm; M = Lu: a = 1 099,28(18) pm, b = 900,70(15) pm, c = 2 151,50(46) pm.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 619 (1993), S. 1431-1440 
    ISSN: 0044-2313
    Keywords: Fluoroplatinates(IV) ; preparation ; single crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Fluoroplatinates(IV) of the Lanthanides LnF[PtF6] (Ln = Pr, Sm, Gd, Tb, Dy, Ho, Er)For the first time fluorides LnF[PtF6] (Ln = Pr, Sm, Gd, Tb, Dy, Ho, Er), all yellow have been obtained. From single crystal data they crystallize monoclinic, space group P21/n-C2h5 (No. 14), Z = 4, Pr: a = 1 125.77(19) pm, b = 559.04(7) pm, c = 910.27(17) pm, β = 107.29(1)°; Sm: a = 1 114.63(31) pm, b = 552.70(12) pm, c = 898.02(20) pm, β = 107.24(2)°; Gd: a = 1 112.12(15) pm, b = 551.22(7) pm, c = 891.99(11) pm, β = 107.09(1)°; Tb (Powder data): a = 1 108.88(20) pm, b = 552.71(9) pm, c = 889.56(16) pm, β = 107.30(1)°; Dy: a = 1 100.28(23) pm, b = 547.77(8) pm, c = 882.41(13) pm, β = 107.32(1); Ho: a = 1 099.11(16) pm, b = 546.16(7) pm, c = 879.45(15) pm, β = 107.34(1)°; Er: a = 1 095.10(16) pm, b = 544.82(10) pm, c = 874.85(14) pm, β = 107.37(1)°.
    Notes: Erstmals dargestellt wurden Fluoride LnF[PtF6] (Ln = Pr, Sm, Gd, Tb, Dy, Ho, Er), alle gelb. Nach Einkristalluntersuchungen kristallisieren diese monoklin in der Raumgruppe P21/n-C2h5 (Nr. 14), Z = 4, Pr: a = 1 125,77(19) pm, b = 559,04(7) pm, c = 910,27(17) pm, β = 107,29(1)°; Sm: a = 1 114,63(31) pm, b = 552,70(12) pm, c = 898,02(20) pm, β = 107,24(2)°; Gd: a = 1 112,12(15) pm, b = 551,22(7) pm, c = 891,99(11) pm, β = 107,09(1)°; Tb (Pulverdaten): a = 1 108,88(20) pm, b = 552,71(9) pm, c = 889,56(16) pm, β = 107,30(1)°; Dy: 1 100,28(23) pm, b = 547,77(8) pm, c = 882,41(13) pm, β = 107,32(1)°; Ho: a = 1 099,11(16) pm, b = 546,16(7) pm, c = 879,45(15) pm, β = 107,34(1)°; Er: a = 1 095,10(16) pm, b = 544,82(10) pm, c = 874,85(14) pm, β = 107,37(1)°. Im Gegensatz zu älteren Befunden liegt die Raumgruppe P21/n-C2h5 (Nr. 14) mit einem verdoppelten Zellvolumen vor.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 616 (1992), S. 7-13 
    ISSN: 0044-2313
    Keywords: Alkali fluoro palladates(II) ; preparation ; single crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On Complex Fluorides of Divalent PalladiumFor the first time single crystals of the new compounds RbPdPdF5, KPdPdF5, and K2CsPdF5 have been obtained. Orange brown RbPdPdF5 crystallizes orthorhombic, space group Imma-D2h28 (No. 74) with a = 633.6(1) pm, b = 765.5.(1) pm, c = 1067.5(1) pm and Z = 4 and is isotypic with CsPdPdF5 [1]. Structure related KPdPdF5 (also orange brown) crystallizes orthorhombic too, but in space group Pnma-D2h16 (No. 62) with a 614.12(9) pm, b = 748.7(1) pm, c = 1065.0(2) pm and Z = 4. K2CsPdF5, light yellow, crystallizes tetragonal with a = 736.3(1) pm, c = 628.0(1) pm, Z = 2, and is isotypic with Rb2CsPdF5 (space group P4/mbm—D4h5 Nr. 127), an ordered structure variant of the Rb3PdF5-Type [1].
    Notes: Neu dargestellt wurden RbPdPdF5, KPdPdF5 und K2CsPdF5, alle in Form von Einkristallen. Orangebraunes RbPdPdF5 kristallisiert orthorhombisch, R. G. Imma-D2h28 (Nr. 74) mit a = 633,6(1) pm, b = 765,5(1) pm, c = 1067,5(1) pm und Z = 4 und ist isotyp zu CsPdPdF5 [1]. Strukturverwandtes KPdPdF5 (ebenfalls orange-braun) kristallisiert gleichfalls orthorhombisch, jedoch in der R. G. Pma—D2h16 (Nr. 62) mit a = 614,12(9) pm, b = 748,7(1) pm, c = 1065,0(2) pm und Z = 4. K2CsPdF5, hellgelb, kristallisiert tetragonal mit a = 736,3(1) pm, c = 628,0(1) pm Z = 2, ist isotyp zu Rb2CsPdF5 (R. G. P4/mbm—D4h5) (Nr. 127) und somit ein weiterer Vertreter der geordneten Strukturvariante des Rb3PdF5-Typs [1].
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 606 (1991), S. 169-176 
    ISSN: 0044-2313
    Keywords: Lithium samarium hexafluoroaluminate ; preparation ; crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: LiSmAlF6  -  the First Fluoroaluminate with Divalent SamariumLiSmAlF6, the first quaternary fluoride with Sm2+ that has been obtained as red transparent single crystals, is formed while heating corresponding mixtures of the starting materials in niobium or tantalum crucibles under argon after 7-10 d at about 800°C. Orange-red, microcrystalline powder samples of LiSmAlF6 could be prepared at T ≤ 700°C after 1-2 d under the same conditions.LiSmAlF6, crystallizes as a new structure type in P6322 (Nr. 182) with a = 507.9(1), c = 1 040.5(1) pm and Z = 2 (CAD4, 2 512 Io, Rw = 2,3%). The crystal structure of LiSmAlF6 is related to the LiCaAlF6 structure type whereby the essential difference lies in the coordination of the M2+ ions. Ca2+, as well as Sr2+ in LiSrAlF6, exhibit octahedral coordination, whereas Sm2+ has, surprisingly, trigonal prismatic coordination to F-. The two triangles of the SmF6 prism are twisted by 8.3° with respect to each other.Measurements of the magnetic susceptibility show the temperature dependence typically found for Sm2+. The Madelung part of the lattice energy has been calculated and is discussed.
    Notes: LiSmAlF6, das erste in Form roter, transparenter Einkristalle erhaltene quaternäre Fluorid mit Sm2+, bildet sich beim Erhitzen geeigneter Ausgangsmenge in Niob- oder Tantaltiegln unter Ar nach 7-10 d bei ca. 800°C. Orangerote, mikrokristalline Pulverproben von LiSmAlF6 können bei T ≤ 700°C bereits nach 1-2 Tagen unter sonst gleichen Bedingungen dargestellt werden.LiSmAlF6 kristallisiert in einem neuen Strukturtyp in P6322 (Nr. 182) mit a = 507,9(1), c = 1 040,5(1) pm und Z = 2(CAD4, 2 512 Io, Rw = 2,3%). Die Kristallstruktur von LiSmAlF6 ist dem LiCaAlF6-Typ verwandt, zeigt aber den wesentlichen Unterschied in der Umgebung für M2+ : Ca2+, wie auch Sr2+ in LiSrAlF6, werden oktaedrisch, Sm2+ jedoch überraschenderweise trigonal-prismatisch von F- koordiniert. Die beiden Dreiecke des SmF6-Prismas sind um 8,3° gegeneinander verdreht.Messungen der magnetischen Suszeptibilität zeigen die für Sm2+ typische Temperaturabhängigkeit. Der Madelunganteil der Gitterenergie wurde berechnet und diskutiert.
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