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  • Chemistry  (14)
  • pendant silyl group  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 28 (1990), S. 3179-3184 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 25 (1987), S. 1781-1791 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A novel diisocyanate monomer, thiophene-2,5-diisocyanate (ThDI) was prepared from readily available adipic acid via the intermediate formation of thiophene-2,5-dicarboxylic acid chloride (ThDAC) and thiophene-2,5-dicarboxylic acid azide (ThDAA) which was subjected to a Curtius rearrangement. Polyurethanes and polyureas containing 2,5-thiophenylene linkage were synthesized by the polycondensation of thiophene-2,5-diisocyanate with various diols and diamines, respectively, in N,N-dimethylformamide. Polymerization conditions were optimized and the high yields of polymers were obtained. The identity of ThDI, model compounds, and the resulting polymers was confirmed by elemental analysis and spectroscopic methods. These polyurethanes and polyureas were found to have inherent viscosities in the range of 0.33-0.68 dL/g. Some physical properties of these polymers were also investigated.
    Additional Material: 3 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 27 (1989), S. 2417-2426 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A series of polyketones containing thiophene links was synthesized by the Friedel-Crafts polymerization of these dithienylalkanes with aromatic diacid chlorides or dicarbonyl chlorides comprising thiophene links with diphenyl compounds. The resulting polymers had inherent viscosities in the range of 0.11-0.27 dL/g and showed poor solubilities to common organic solvents except strong acids. These thiophene-based polyketones exhibited fairly good thermal stabilities. The TGA data revealed 5% weight losses at 375-450°C and residual weights at 500°C were 43-79% under nitorgen. It was found that the thermal stabilities of these polymers were superior to those of polymides or polysulfonamides containing thiophene links and almost comparable to common aromatic polyketones
    Additional Material: 3 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 30 (1992), S. 1575-1581 
    ISSN: 0887-624X
    Keywords: polyarylates ; pendant silyl group ; two-phase polycondensation ; tough films ; good thermal stabilities ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polyarylates containing pendant silyl group were prepared by the phase-transfer catalyzed, two-phase polycondensations of 2,2-bis (4-hydroxyphenyl) propane with corresponding dicarbonyl chlorides such as 2-trimethylsilylterephthaloyl chloride, 5-trimethylsilylisophthaloyl chloride, 5-dimethylphenylsilylisophthaloyl chloride, and 5-triphenylsilylisophthaloyl chloride. The resulting amorphous polyarylates with glass transition temperatures of 163-214°C had inherent viscosities in the range of 0.41-0.95 dL/g. These polyarylates were readily soluble in common chlorinated hydrocarbons and it was possible to obtain transparent, flexible, and tough films from the polymer solutions. The prepared polyarylates showed fairly good thermal stabilities as well as tensile strengths, i.e., the tensile strengths of the cast films from chloroform solution were 6.0-6.7 kg/mm2. And TGA data revealed 10% weight losses and residual weights at 800°C were 437-495°C and 27-40% under nitrogen atmosphere, respectively. © 1992 John Wiley & Sons, Inc.
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 27 (1989), S. 443-449 
    ISSN: 0887-6258
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 5 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 26 (1988), S. 1507-1517 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In order to study the synthesis and properties of polysulfonamides containing thiophene links, 2,2-bis(5-chlorosulfonyl-2-thienyl)propane [BCTP], 2,2-bis(5-chlorosulfonyl-2-thienyl)butane [BCTB], 1,1-bis(5-chlorosulfonyl-2-thienyl)cyclohexane [BCTC], and 2,4-dichlorosulfonyl thiophene [DCST] were prepared and interfacial polycondensations with various aliphatic diamines were carried out. The resulting polymers had inherent viscosities in the range of 0.13-0.41 dL/g and showed high extent of moisture absorptions. Most of the polysulfonamides were soluble in electron-donating solvents such as pyridine, DMF, DMSO, NMP, etc. These polysulfonamides exhibited relatively good thermal stabilities. The TGA data revealed 5% weight losses at 275-405°C and residual weights at 500°C were 13-40% under nitrogen. It was also found that dithienyldisulfonyl chlorides produced more thermally stable polymers than DCST, which were comparable to common polysulfonamides from aromatic disulfonyl chlorides.
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  • 7
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 30 (1992), S. 1583-1588 
    ISSN: 0887-624X
    Keywords: aromatic polyamides ; pendant silyl groups ; direct polycondensation ; improved solubilities ; good thermal stability ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In order to improve the solubility of aromatic polyamides without significant loss of thermal stability, synthesis of aromatic polyamides containing pendant silyl groups was carried out by direct polycondensation of silylated aromatic diacids such as 2-trimethylsilylterephthalic acid (TSTA), 2,5-bis (trimethylsilyl) terephthalic acid (BTSTA), 5-trimethylsilylisophthalic acid (TSIA), 5-dimethylphenylsilylisophthalic acid (DMSIA), and 5-triphenylsilylisophthalic acid (TPSIA) with various aromatic diamines. The resulting polyamides had inherent viscosities in the range of 0.18-1.10 dL/g and showed improved solubilities toward aprotic polar solvents such as NMP, DMF, DMSO, etc. The prepared aromatic polyamides exhibited fairly good thermal stabilities, which were almost comparable to those of corresponding nonsubstituted aromatic polyamides. That is, thermogravimetric analysis (TGA) data revealed 10% weight losses at 358-500°C and residual weights at 700°C were 46-67% under nitrogen atmosphere. © 1992 John Wiley & Sons, Inc.
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  • 8
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 32 (1994), S. 175-179 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 35 (1995), S. 1643-1651 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The morphology and dynamic mechanical properties of blends of poly(ether imide) (PEI) and nylon 66 over the full composition range have been invesigated. Torque changes during mixing were also measured. Lowertorque values than those calculated by the log-additivity rule were ontained, resulting from the slip at the interface due to low interaction between the componeents. The particle size of the dispersed phase and morphology of the blends were examined by scanning electron microscopy. The composition of each phase was calculated. The blends of PEI and nylon 66 showed phase-seoarated structures with small spherical domains of 0.3 ∼ 0.7 μm. The glass transition temperatures (Tgg) of the blends were shifted inward, compared with those of the homopolymers, which implied that the blends were partially imiscible over a range of compositions. Tg1, corresponding to nylon 66-rich phase. This indicated that the fraction of PEI mixed into nylon 66-rich phase increased with decreasing PEI content and that nylon 66 was rerely mixed into the PEI-rich phase. The effect of composition of the secondary relaxations was examined. Both Tβ, corresponding to the motion of amide groups in nylon 66. and Tγ′, corresponding to that of either groups in PEI, were shifted to higher temperature, probably because of the formation of intermolecular interactions between the components.
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  • 10
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: New aromatic polyetherimides containing the 1,1′-bis[4-(3,4-dicarboxyphenoxy)phenyl]-1-phenyl-2,2,2-trifluoroethane dianhydride unit were prepared by a conventional two-step method from 1,1′-bis[4-(3,4-dicarboxyphenoxy)phenyl]-1-phenyl-2,2,2-trifluoroethane dianhydride and several diamines. This procedure yielded high molecular weight polyetherimides with inherent viscosities of 0.22-1.29 dL/g. Most of the corresponding polyetherimides were soluble in organic solvents such as N-methyl-2-pyrrolidone, N, N-dimethylformamide, N,N-dimethylacetamide, and methylene chloride under ambient temperature. The glass transition temperatures (Tg) of these polymers were in the range of 207-264°C and the temperatures of 10% weight loss were over 520°C at a heating rate 20°C/min in nitrogen. © 1996 John Wiley & Sons, Inc.
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