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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 80 (1995), S. 159-168 
    ISSN: 1573-2932
    Keywords: Mercury ; dry deposition ; particle phase mercury ; size distribution ; Great Lakes ; Lake Champlain
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The importance of participate mercury (Hg(p)) in the transport, chemistry and deposition of this toxic metal has long been underestimated and largely ignored. While it was once believed to constitute a small percentage of total atmospheric mercury, Hg(p) may contribute a significant portion of the deposition of this metal to adjacent natural waters. Recent measurements of Hg(p) in several urban/industrial areas have documented that Hg can be associated with large particles (〉2.5 μm) and in concentrations similar to those of the vapor phase Hg (ng/m3). As part of ongoing effort to diagnose the sources, transport and deposition of Hg to the Great Lakes and other Great Waters, the University of Michigan Air Quality Laboratory (UMAQL) has investigated the physical and chemical properties of particulate-phase Hg in both urban and rural locations. It appears that particulate Hg may be the one of the most difficult of the Hg measurements to perform, and perhaps the one of the most important for deposition and source apportionment studies. Particulate Hg concentrations measured in rural areas of the Great Lakes Region and Vermont ranged from 1 to 86 pg/m3 whereas Hg(p) levels in urban/industrialized areas were in the range 15 pg/m3 to 1.2 ng/m3.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Water, air & soil pollution 88 (1996), S. 145-165 
    ISSN: 1573-2932
    Keywords: urban pollution ; trace metal ; long-term trend ; emission source ; Detroit ; market parameter ; land use
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Ambient concentrations of particulate Fe, Zn, Ph, Ni, Cr, Cd and Hg were measured at nine sites located in the metropolitan area of Detroit from 1971 to 1992. The ambient concentrations of all the trace metals were found to be generally higher at industrial and commercial sites. The concentrations show significant variations between residential and commercial areas and between residential and industrial areas; however, no significant variation was found between the industrial and commercial settings. The spatial variation of trace metal levels within the urban area was influenced by the frequency distribution of the wind direction as well as type and location of emission sources. The ambient concentrations of the trace metals during the decade of 1971–1981 declined by 37–88%. In the 1980s many of the trace metals reversed this trend with the exception of Fe and Pb which continued to decline at annual rates of 2% and 9.8%, respectively. The sharp decrease in Pb concentrations during the 1980s, reflected the significant reduction of Pb content in gasoline from 0.28 g/liter in the 1982 to 0.026 g/liter in the 1989. The ambient concentrations of Zn, Ni, Cr, Cd and Hg showed an upward trend during the 1980s with an annual rate in the range of 0.6% to 10.6%. The long-term trends of selected U.S. market parameters, analyzed as potential long-term indicators of emission sources activityies, were consistent with the changes of ambient concentrations, the correlation coefficient being in the range of 0.58 to 0.84 for most of the trace metals.
    Type of Medium: Electronic Resource
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