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  • Polymer and Materials Science  (34)
  • General Chemistry  (19)
  • genetic engineering  (2)
  • Wiley-Blackwell  (55)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 49 (1996), S. 101-105 
    ISSN: 0006-3592
    Keywords: Xanthomonas maltophilia ; benzoic acid ; Vitreoscilla hemoglobin gene ; genetic engineering ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Xanthomonas maltophilia was transformed with the gene encoding Vitreoscilla (bacterial) hemoglobin, vgb, and the growth of the engineered strain was compared with that of the untransformed strain using benzoic acid as the sole carbon source. In general, growth of the engineered strain was greater than that of the untransformed strain; this was true for experiments using both overnight cultures and log phase cells as inocula, but particularly for the latter. In both cases the engineered strain was also more efficient than the untransformed strain in converting benzoic acid into biomass. © 1996 John Wiley & Sons, Inc.
    Additional Material: 4 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 8 (1964), S. 119-140 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The standardization of notched Izod impact test data to normalized values of foot pounds per inch of notch is based on the assumption of a 1:1 increase in breaking strength with increasing notch width. This assumed relation is not supported by experimental tests on commercial thermoplastics. As notch width was increased from 1/8 to 1/4 to 3/8 to 1/2 in., nine of ten thermoplastics tested showed a decrease in normalized impact strength. Each material appears to show a characteristic loss in breaking strengths as the notch width increases. A technique developed for calibration of pendulum impact testers has been used to examine the variation of impact breaking strength in relation to the total kinetic energy of the hammer. Experimental tests show practically no change in impact strengths up to values that take 2/3 of the available hammer energy. Experimental work on the comparison of the impulse transferred by the hammer during breaking with impulse curves photographed by the Autographic Impact test show very good agreement for catastrophic breaks and fair agreement for plastic type breaks. The reduction in recorded impulse is attributed to the degrading of the sample during the plastic portion of the breaking cycle. The peak force of thermoplastics as measured by the Autographic Impact test increases as the temperature decreases from 100°C. or above to 0°C. Over the same temperature range flexural tests on small cantilever samples of these thermoplastics show the same thermal dependence for the flexural yield or permanent distortion stress. Plots of the impact peak forces and flexural yield stress at corresponding temperatures give a linear correlation. Each thermoplastic material exhibits a unique relation for this correlation between impact yielding and flexural yielding. This correlation between the impact and flexural tests over the range of temperatures is the first known experimental indication of a direct relation between impact properties and standard physical tests.
    Additional Material: 11 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 10 (1966), S. 1777-1786 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A method for assessing extent of swelling of the gel fraction of formaldehyde-modified cottons, employing cupriethylenediamine hydroxide as the swelling agent, is described. Substantial differences in apparent specific volumes of swollen gel fractions are observed for cottons crosslinked by different processes to the same level of agent. The apparent crosslink density measured by the swelling of gel fraction increases with formaldehyde content of the cotton; at 0.20% formaldehyde the order of increasing crosslink density in the various processes of reaction is as follows: nonaqueous system (forms D and D′) 〈 aqueous system (forms W and W′) 〈swelling system (form F) 〈 vapor system (form V) 〈 bake-cure system (form C).
    Additional Material: 4 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 57 (1998), S. 477-483 
    ISSN: 0006-3592
    Keywords: Vitreoscilla hemoglobin ; bacterial hemoglobin ; Serratia marcescens ; genetic engineering ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The bacterial hemoglobin from Vitreoscilla has been shown to increase growth yield and yield of genetically engineered product in Escherichia coli. To test the generality of this phenomenon, the approximately 560-bp bacterial (Vitreoscilla) hemoglobin gene (vgb) (including the native promoter), cloned into the vector pUC8 in two constructs containing about 1650 and 850 bp, respectively, of Vitreoscilla DNA downstream of vgb, was transformed into Serratia marcescens. After several transfers of the transformants on selective media, both plasmids became stable in this host and the resulting strains produced hemoglobin. Both transformants were compared, regarding growth in liquid Luria-Bertani (LB) medium, with untransformed S. marcescens and S. marcescens transformed with pUC8. The vgb-bearing strains had about 5 times lower maximum viable cell numbers than the strains without hemoglobin, but the former also had late log or early stationary phase cells that were 5-10 times larger than those of the latter. Further, on a dry cell mass basis the presence of vgb inhibited cell growth in liquid media. In contrast, growth of the vgb-bearing strains on LB plates based on cell mass (determined from colony size) was markedly enhanced compared with that of the pUC8 transformant. Respiration of the vgb-bearing strains was lower than that of the strains without vgb on a cell mass basis. These results show that the presence of vgb can have idiosyncratic effects and is not always an aid to cell growth so that its use for genetic engineering must be tested on a case by case basis. ©1998 John Wiley & Sons, Inc. Biotechnol Bioeng 57: 477-483, 1998.
    Additional Material: 4 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 50 (1976), S. 9-14 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Verbindungen der Strukturformeln [π-C5H5M(CO)nX] (M = Fe, n = 2; M = Mo, n = 3; X = CH3, CH2C6H5, CH2Si(CH3)3, CH2OCH3, Sn(C6H5)3, SnCl3, HgCl, I), [Mn(CO)5CH3], und [(π-CH3C5H4)Mn(CO)3] wurden als Katalysatoren für die Härtung von Epoxidharzen unter verschiedenen Bedingungen geprüft. Es wurde gefunden, daß die Verbindungen [π-C5H5Fe(CO)2R] (R = CH3, CH2C6H5) und [π-C5H5Mo(CO)3CH3] wirksame lichtempfindliche Beschleuniger für die Anhydridhärtung von Expoxidharzen sind. Der Aktivierungsmechanismus wird diskutiert.
    Notes: Compounds of the types [π-C5H5M(CO)nX] (M = Fe, n = 2; M = Mo, n = 3; X = CH3, CH2C6H5, CH2Si(CH3)3, CH2OCH3, Sn(C6H5)3, SnCl3, HgCl, I), [Mn(CO)5CH3], and [(π-CH3C5H4)Mn(CO)3] have been examined as catalysts for the cure of epoxy resins under various conditions. It was found that the compounds [π-C5H5Fe(CO)2R] (R = CH3, CH2C6H5) and [π-C5H5Mo(CO)3CH3] are active photosensitizing agents for the anhydride cure of certain epoxy resins. The mechanism of the process is discussed.
    Additional Material: 1 Tab.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 27 (1972), S. 159-164 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Es wurde eine Voruntersuchung des Einflusses unternommen, den die Verschiebereagenzien Tris-(dipivaloylmethano)-europium uncl Tris-(dipivaloylmethano)-pra-seodym auf das NMR-Spektrum des Diglyzidyläthers des Bisphenol A ausüben. Es ergab sich, daß die Signale der am Epoxidring anliegenden Protonen durch den Zusatz dieser Chelate weit mehr als die Signale der exozyklischen -OCH2-Gruppen verschoben werden. Die Verschiebung kann man durch den Zusatz eines Alkohols rückgängig machen, der vorzugsweise mit dem Verschiebemittel reagiert.
    Notes: A preliminary study has been made of the effects of the shift reagents Eu (DPM)3 and Pr(DPM)3 on the NMR spectrum of Bisphenol A diglycidyl ether (I). Protons attached to the epoxy ring were observed to shift appreciably more than protons of the exocyclic —OCH2— group, on addition of these chelates. The shifts could be reversed by addition of an alcohol, which interacted preferentially with the shift reagent.
    Additional Material: 4 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 56 (1976), S. 157-162 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: 13C-und 1H-NMR-Untersuchungen haben überzeugend gezeigt, daß die Hauptkomponente des Epoxidharzes aus Phenolphthalein und Epichlorhydrin ein aromatischer Diglycidyläther mit einem Lactonring ist und nicht eine chinoide Verbindung mit Glycidylätherund Glycidylesterstruktur.
    Notes: 13C- and 1H-NMR studies have shown conclusively that the main component of the epoxy resin derived from phenolphthalein and epichlorohydrin is an aromatic diglycidyl ether containing a lactone ring, rather than a glycidyl ether-glycidyl ester compound containing a quinoid ring.
    Additional Material: 1 Tab.
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 26 (1972), S. 171-176 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Es wird eine NMR-Methode zur Bestimmung der ungefähren Verhältnisse zwischen aus Phenolkernen, Resorcinkernen und Formaldehyd gebildeten Gruppenin Kondensationsprodukten aus Phenol, Resorcin und Formaldehyd beschrieben.
    Notes: A method is reported, based on NMR spectroscopy, for approximate determination of the component ratios of resins formed by condensation of resorcinol, phenol and formaldehyde.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 27 (1972), S. 151-157 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Es wurden die Verschiebungen untersucht, die durch Tris-(dipivaloylmethano)-europium und Tris-(dipivaloylmethano)-praseodym im NMR- Spektrum versehiedener Derivate substituierter Phenole hervorgerufen werden. Der Zweck dieser Arbeiten war, die Möglichkeiten zu erfassen, die diese Verschiebereagenzien als Hilfsmittel in der NMR-Analyse von Phenolharzen bieten, und Information über Verschiebungen bei Molekülen zu gewinnen, die mehr als eine Koordinationsposition besitzen.
    Notes: An investigation into the shifts induced in the NMR spectra of some derivatives of substituted phenols by tris(dipivalomethanato)europium and tris(dipivalomethanato)praseodymium is reported. The phenol derivatives were studied to ascertain the possible utility of the shift reagents as an aid in the analysis of phenolformaldehyde resins by NMR spectroscopy, and to gain information on induced shifts with molecules having more than one possible co-ordination site.
    Additional Material: 1 Tab.
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  • 10
    ISSN: 0323-7648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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