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  • 1
    Electronic Resource
    Electronic Resource
    Neue Alkylchlorsulfonium-Salze und Kristallstruktur von Diethylchlorsulfoni-umhexachloroantimonat (C2H5)2SCl+SbCl6- (1995)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 621 (1995), S. 1547-1551 
    Details
    ISSN: 0044-2313
    Keywords: Dialkylchlorosulfonium hexachloroantimonates ; crystal structure ; preparation ; IR, Raman, NMR spectra ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: New Alkylchlorosulfonium Salts and Crystal Structure of Diethylchlorosulfonium-Hexachloroantimonate (C2H5)2SCl+SbCl6-We describe the preparation and spectroscopic characterization of Dialkylchlorosulfonium-Hexachloroantimonates R2SCl+SbCl6- (R = C2H5, i-C3H7) and the crystal structure of Diethylchlorosulfonium-Hexachloroantimonate (C2H5)2SCl+SbCl6- at 172(1) K. The salt crystallize in the orthorhombic space group P212121 with a = 980.4(13) pm, b = 1010.6(8) pm, c = 1492.8(14) pm with four formula units per unit cell.
    Notes: Es wird die Darstellung und spektroskopische Charakterisierung von Dialkylchlorsulfoniumhexachloroantimonaten R2SCl+SbCl6- (R = C2H5, i-C3H7), sowie die Einkristallröntgenstrukturanalyse von Diethylchlorsulfoniumhexachloroantimonat (C2H5)2SCl+SbCl6- bei 172(1) K beschrieben. Das Salz kristallisiert in der orthorhombischen Raumgruppe P212121 mit a = 980,4(13) pm, b = 1010,6(8) pm, c = 1492,8(14) pm mit 4 Formeleinheiten pro Elementarzelle.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19956210919
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  • 2
    Electronic Resource
    Electronic Resource
    Reaktion von Chlornitrat mit CF3I: Isolierung von Trifluormethylchloriodnitrat CF3I(Cl)ONO2 und Kristallstruktur von Trifluormethylioddinitrat CF3I(ONO2)2 (1995)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 621 (1995), S. 1552-1557 
    Details
    ISSN: 0044-2313
    Keywords: Chlorine Nitrate ; Trifluormethylchloroiodinenitrate ; Trifluormethyliodinedinitrate ; crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Reaction of Chlorine Nitrate with CF3I: Isolation of Trifluormethylchloroiodinenitrate CF3I(Cl)ONO2 and the Crystal Structure of Trifluormethyliodinedinitrate CF3I(ONO2)2CF3I reacts with ClONO2 to Iodine(III)-compounds. After an addition CF3I(Cl)ONO2 is isolated and characterized by vibrational spectra. With surplus ClONO2 it is formed CF3I(ONO2)2.CF3I(ONO2)2 crystallizes monoclinic in the space group P21/c with the cell parameters a = 1 024.3(6) pm, b = 873.5(6) pm, c = 873.4(6) pm and Z = 4.We measered following bonding distances: I—O: 207.3(3) and 220.8(2) pm, I—C: 221.1(4) pm and N—O: from 119.1(4) to 141.5(3) pm.Through an intermolecular I ··· O-contact the central iodine becomes a distorted plane geometry.
    Notes: CF3I reagiert mit ClONO2 in einer oxidativen Additionsreaktion zu Iod(III)-Verbindungen. Das Additionsprodukt CF3I(Cl)ONO2 wird isoliert und schwingungsspektroskopisch charaktersiert. Mit überschüssigem ClONO2 bildet sich CF3I(ONO2)2.CF3I(ONO2)2 kristallisiert monoklin in der Raumgruppe P21/c mit a = 1 024,3(6) pm, b = 873,5(6) pm, c = 873,4(6) pm und Z = 4.Es werden folgende Bindungslängen gemessen: I—O: 207,3(3) bzw. 220,8(2) pm, I—C: 221,2(4) pm und N—O: 119,1(4) bis 141,5(3) pm.Durch einen intermolekularen I ··· O-Kontakt erlangt das zentrale Iodatom eine verzerrt-planare Umgebung.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19956210920
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  • 3
    Electronic Resource
    Electronic Resource
    Schwingungsspektroskopische Untersuchungen an Trimethylphosphonium-Kationen (CH3)3PX+ (X = H, D) und Kristallstrukturen von (CH3)3PD+SbCl6- und (CH3)3PCl+SbCl6- (1992)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 614 (1992), S. 102-108 
    Details
    ISSN: 0044-2313
    Keywords: Trimethylphosphonium Salts ; Preparation ; Vibrational Spectra ; NMR Spectra ; Crystal Structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Vibrational Spectra of Trimethylphosphonium Cations (CH3)3PX+ (X = H, D) and Crystal Structures of (CH3)3PD+SbCl6- and (CH3)3PCl+SbCl6-The trimethylphosphonium salts (CH3)3PX+SbCl6- (X = H, D) and (CH3)3PH+MF6- (M = As, Sb) are prepared and characterized by vibrational and NMR spectroscopy (1H, 31P, 13C).In addition the crystal structures of (CH3)3PD+SbCl6- and (CH3)3PCl+SbCl6- are reported. (CH3)3PD+SbCl6- crystallizes in the orthorhombic space group Pnma with a = 1555(1) pm, b = 753.1(8) pm, c = 1166(1) pm Z = 4. (CH3)3PCl+SbCl6- crystallizes triclinic in the space group P1 with a = 704.6(4) pm, b = 729.5(3) pm, c = 1391.1(7) pm, α = 89.57(4)°, b̃ = 88.04(4)°, γ = 74.98(4)° and Z = 2.
    Notes: Die Trimethylphosphonium-Salze (CH3)3PX+SbCl6- (X = H, D) und (CH3)3PH+MF6- (M = As, Sb) werden dargestellt und schwingungs- sowie NMR-spektroskopisch (1H, 31P, 13C) untersucht.Zusätzlich wird über die Kristallstrukturen von (CH3)3PD+SbCl6- und (CH3)3PCl+SbCl6- berichtet. (CH3)3PD+SbCl6- kristallisiert in der orthorhombischen Raumgruppe Pnma mit a = 1 555(1) pm, b = 753,1(8) pm, c = 1166(1) pm und Z = 4. (CH3)3PCl+SbCl6- kristallisiert triklin in der Raumgruppe P1 mit a = 704,6(4) pm, b = 729,5(3) pm, c = 1391,1(7) pm, α = 89,57(4)°, b̃ = 88,04(4)°, γ = 74,98(4)° und Z = 2.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19926140818
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  • 4
    Electronic Resource
    Electronic Resource
    Kristallstruktur einer neuen Modifikation von Sb8F30 (1991)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 605 (1991), S. 109-116 
    Details
    ISSN: 0044-2313
    Keywords: Antimony(III)fluoride,(Sb2F5+)(Sb3F72+)(SbF6-)3 ; preparation ; crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Crystal Structure of a new Modification of Sb8F30The modification of Sb8F30, described here, crystallizes in the orthorhombic space group Pca21 (No. 29) with a = 1115.7(1), b = 1100.2(1), c = 1917.8(3) pm and Z = 4. Within this complex molecule, the Sb3F72+-cation was identified besides a heavily distorted form of the mixed valent Sb4F17--anion.
    Notes: Die hier beschriebene Modifikation von Sb8F30 kristallisiert in der orthorhombischen Raumgruppe Pca21 (Nr. 29) mit a = 1115,7(1), b = 1100,2(1), c = 1917,8(3) pm und Z = 4. Innerhalb dieses komplexen Moleküls werden ein Sb3F72+-Kation und eine stark verzerrte Form des gemischt valenten Sb4F17--Anions identifiziert.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19916050112
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  • 5
    Electronic Resource
    Electronic Resource
    Synthese von (C6F5)2SF+MF6- (M = As, Sb) und Kristallstruktur von (C6F5)2SF+SbF6- [1] (1992)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 611 (1992), S. 23-27 
    Details
    ISSN: 0044-2313
    Keywords: (C6F5)2SF+SbF6- ; Preparation ; Crystal Structure ; Spectroscopic Data ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Preparation of (C6F5)2SF+MF6- (M = As, Sb) and Crystal Structure of (C6F5)2SF+SbF6-XeF+MF6- (M = As, Sb) reacts with (C6F5)2S in HF to form (C6F5)2SF+MF6-. The deeply violet sulfonium salts can be kept without decomposition up to 24 h at room temperature.The hexafluoroantimonate salt crystallizes in the monoclinic space group P21/n with a = 1056.4(7) pm, b = 1446.3(10) pm, c = 1102.9(8) pm, β = 91.29(6)° und Z = 4. The SF-bond distance with 158.4(3) pm is of unusual length. Cations and anions are connected via interionic fluorine contacts to an infinite chain, in which cations and anions form to ABAB sequence along the chain.
    Notes: XeF+MF6- (M = As, Sb) reagiert mit (C6F5)2S in HF zu (C6F5)2SF+MF6-/. Die beiden tiefvioletten Sulfoniumsalze sind bei Raumtemperatur bis zu 24 Stunden unzersetzt haltbar.Das Hexafluoroantimonat kristallisiert in der monoklinen Raumgruppe P21/n mit a = 1056,4(7) pm, b = 1446,3(10) pm, c = 1102,9(8) pm, β = 91,29(6)° und Z = 4. Der SF-Bindungsabstand ist mit 158,4(3) pm außergewöhnlich lang. Kationen und Anionen werden durch interionische Fluor-Kontakte zu einer unendlichen Kette verknüpft, in der Kationen und Anionen in einer ABAB-Folge angeordnet sind.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19926110504
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  • 6
    Electronic Resource
    Electronic Resource
    Darstellung der Dichlormethyleniminium-Salze Cl2C=NClH+ MF6- und Cl2C=NClCH3+ MF6- (M = As, Sb) und Kristallstruktur von Dichlormethyleniminiumhexachloroantimonat Cl2C=NH2+SbCl6- (1992)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 617 (1992), S. 136-142 
    Details
    ISSN: 0044-2313
    Keywords: Dichloromethyleneiminum Salts ; Preparation ; Vibrational Spectra ; NMR-Spectra ; Crystal Structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis of the Dichloromethyleneiminium Salts Cl2C=NClH+MF6- and Cl2C=NClCH3+ MF6- (M = As, Sb) and Crystal Structure of Dichloromethyleneiminium-hyxachloroantimonate Cl2C=NH2+SbCl6-The N-chloro-dichloromethyleneiminium salts Cl2C=NCIH+MF6- (M = As, Sb) are prepared by protonationof trichloromethyleneimine in the superacide system HF/MF5 at 195 K. The synthesis of the N-chloro-N-methyl-dichloromethyleneiminium salts Cl2C=NClCH3+MF6- (M = As, Sb) is proceeded by methylation of perchloromethylenimine by CH3OSO+MF6- in SO2 also at low temperature. All salts are characterized by vibrational and NMR spectra. The dichloromethyleneiminiumhexachloroantimonate crystallizes in the space group P21/c with a = 971.3(4)pm, b = 1134.0(4)pm, c = 2154.2(7)pm β = 102.04(3)° and Z = 8.
    Notes: Die N-Chlor-dichlormethyleniminium-Salze Cl2C=NClH+MF6- (M = As, Sb) werden aus Trichlormethylenimin durch Protonierung mit dem supersauren System HF/MF5 bei 195 K dargestellt. Die Synthese der N-Chlor-N-methyl-dichlormethylen-iminium-Salze Cl2C=NClCH3+MF6- (M = As, Sb) erfolgt durch Methylierung von Perchlormethylenimin mit CH3OSO+MF6- in SO2 ebenfalls bei tiefer Temperatur. Alle Salze werden schwingungs- und NMR-spektroskopisch charakterisiert. Dichlormethyleniminiumhexachloroantimonat kristallisiert monoklin in der Raumgruppe P21/c mit a = 971,3(4)pm, b = 1134,0(4)pm, c = 2154,2(7) pm, β = 102,04(3)° und Z = 8.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19926170124
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  • 7
    Electronic Resource
    Electronic Resource
    Darstellung und spektroskopische Charakterisierung der Cyannitrilium-Salze NCCNH+MF6- und der N-Methyl-cyannitrillium-Salze NCCNCH3+MF6- (M = As, Sb) (1992)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 618 (1992), S. 139-143 
    Details
    ISSN: 0044-2313
    Keywords: Cyanonitrilium Salts ; Preparation ; Vibrational Spectra ; NMR Spectra ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis and Spectroscopic Characterization of the Cyanonitrilium Salts NCCNH+MF-6 and the N-Methyl-cyanonitrilium Salts NCCNCH3+MF6- (M = As, Sb)The cyanonitrilium salts NCCNH+MF-6 (M = As, Sb) are prepared by protonation of cyanogene (CN)2 in the superacid HF/MF5 at 195 K. The synthesis of the N-methyl-cyanonitrilium salts NCCNCH3+MF6- (M = As, Sb) is proceeded by methylation of cyanogene by CH3OSO+MF6- in SO2 also at low temperature. All salts are characterized by vibrational and NMR spectra.
    Notes: Die Cyannitrilium-Salze NCCNCH+MF6- (M = As, Sb) werden aus Dicyan (CN)2 durch Protonierung in der Supersäure HF/MF5 bei 195 K dargestellt. Die Synthese der N-Methylcyannitriliumsalze NCCNCH3+MF6- (M = As, Sb) erfolgt durch Methylierung von Dicyan mit CH3OSO+MF6- in SO2 ebenfalls bei tiefer Temperatur. Alle Salze werden schwingungs- und NMR-spektroskopisch charakterisiert.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19926180123
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  • 8
    Electronic Resource
    Electronic Resource
    Über die Darstellung der Dichlormethylen-halogensulfenium-Salze Cl2CSCl+ AsF6- und Cl2CSBr+ AsF6- [1] (1993)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 619 (1993), S. 583-586 
    Details
    ISSN: 0044-2313
    Keywords: Sulfenium Salts ; Preparation ; Vibrational Spectra ; NMR-Spectra ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The Synthesis of the Dichloromethylene-halogenosulfenium Salts Cl2CSCl+ AsF6- and Cl2CSBr+ AsF6-The sulfenium salts Cl2CSCl+ AsF6- and Cl2CSBr+ AsF6- are synthesized by oxidative halogenation of thiophosgene, Cl2CS with X2/AsF5 (X = Cl, Br) at 195 K and are characterized by vibrational as well as NMR spectroscopy.
    Notes: Die Sulfeniumsalze Cl2CSCl+ AsF6- und Cl2CSBr+ AsF6- werden aus Thiophosgen Cl2CS durch oxidative Halogenierung mit X2/AsF5 (X = Cl, Br) bei 195 K dargestellt und schwingungs- sowie NMR-spektroskopisch charakterisiert.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19936190325
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  • 9
    Electronic Resource
    Electronic Resource
    Fluorieren mit Trifluormethylhypochlorit CF3OCl. Darstellung und Kristallstrukturanalyse von Trifluormethyliodtetrafluorid CF3IF4Professor Peter Paetzold zum 60. Geburtstag gewidmet (1995)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 621 (1995), S. 1247-1250 
    Details
    ISSN: 0044-2313
    Keywords: Trifluoromethyliodine tetrafluoride ; crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Fluorinate with Trifluoromethylhypochlorite CF3OCl. Preparation and Crystal Structure Determination of Trifluoromethyliodine Tetrafluoride CF3IF4The preparation of Trifluoromethyliodine tetrafluoride (CF3IF4), from Trifluoromethyliodide (CF3I) with Trifluoromethylhypochlorite (CF3OCl), and the crystal structure of CF3IF4 at 172(1) K is described. CF3IF4 crystallizes in the monoclinic space group P21/c with a = 762.2(7) pm, b = 842.9(10) pm, c = 856.4(7) pm, β = 99.65(7)° with four formula units per unit cell.
    Notes: Es wird die Darstellung von Trifluormethyliodtetrafluorid (CF3IF4), aus Trifluormethyliodid (CF3I) und Trifluormethylhypochlorit (CF3OCl), sowie die Kristallstrukturanalyse bei 172(1) K beschrieben. CF3IF4 kristallsiert in der monoklinen Raumgruppe P21/c mit a = 762,2(7) pm, b = 842,9(10) pm, c = 856,4(7) pm, β = 99,65(7), Z = 4.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19956210724
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