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  • 1
    Electronic Resource
    Electronic Resource
    Basel : Wiley-Blackwell
    Die Makromolekulare Chemie, Rapid Communications 2 (1981), S. 287-291 
    ISSN: 0173-2803
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Basel : Wiley-Blackwell
    Die Makromolekulare Chemie, Rapid Communications 3 (1982), S. 99-102 
    ISSN: 0173-2803
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 2 Tab.
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 18 (1980), S. 2143-2153 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The radical-induced grafting of styrene onto polyisoprene (PIP) in benzene solution at, 60°C was studied in rubber concentration (up to 0.5 monomer mole liter-1) in which the polymerization of styrene shows ideal kinetics with no retardation by PIP. The proportion of polystyrene incorporated as graft is independent of the initiator (benzoyl peroxide) concentration and was found to be consistent with the kinetic expression derived by Cameron et al. The graft fraction of polystyrene which is higher than in the corresponding styrene-polybutadiene system reflects the higher reactivity of PIP toward radicals. Azobisisobutyronitrile produces no graft copolymer in this system.
    Additional Material: 11 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 18 (1980), S. 3149-3161 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The radical grafting of methyl methacrylate (MMA) onto polybutadiene (PBD) in benzene solution at 60°C is more efficiently induced by benzoyl peroxide (BP) than by azoisobutyronitrile (AIBN). PBD exerts a pronounced retardation on the polymerization of MMA and the grafting efficiency is governed by the ratio of rubber to monomer in the system. With BP as initiator, a fairly simple kinetic expression, relating grafting efficiency with reactant concentrations, can be derived by making certain approximations, including the neglect of termination grafting. The experimental data are reasonably consistent with this equation and yield acceptable values of several kinetic parameters. With AIBN, termination grafting is more significant. In consequence the relevant kinetic equation can be only qualitatively validated.
    Additional Material: 6 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 28 (1983), S. 327-334 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Three high molecular weight polycaprolactones (M̄w = 35,000, 18,600, and 7,130) were utilized as the sole carbon source by five of six fungi tested by the American Standards for Testing and Materials (ASTM) agar plate method. The fungi were Aspergillus flavus, A. niger, A. fumigatus, Chaetomium globosum, Pencillium funiculosum, and a Fusarium sp. Quantitative analysis of degradation was performed using gel permeation chromatography (GPC). GPC analysis demonstrated differences between the activities of organisms which appeared similar by the ASTM method, and showed that, while all molecular weight species within each polymer were hydrolyzed, in several cases low molecular weight end products were not assimilated. Depending on the organism, the dominant factor determining degradability was either polymer molecular weight or degree of crystallinity.
    Additional Material: 2 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 28 (1983), S. 335-342 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The degradability of three high molecular weight polycaprolactones (M̄w = 35,000, 18,600, and 7,130) and one low molecular weight polycaprolactone diol(M̄w = 2060) by mixed and pure cultures of microorganisms was assayed. A yeast, Cryptococcus laurentii, a gram-negative rod, Acinetobacter calcoaceticus var. lwoffi, and a gram-positive coryneform rod were used in the pure culture assays. The analysis of degradation by gel permation chromatography (GPC) allowed for quantitation independent of the growth of the organisms or the addition of supplementary growth factors. GPC analysis showed that the degradation effected by pure cultures was often enhanced when alternate carbon sources were present. This was not the case for mixed cultures. Mixed cultures. Mixed cultures completely metabolized polymer breakdown products while in some cases pure cultures did not.
    Additional Material: 4 Tab.
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  • 7
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Adducts of cis-1,4-polybutadiene with both benzene- and toluenesulfenyl chlorides were conveniently oxidised in a second stage modification with m-chloroperbenzoic acid to yield novel sulfone thermoplastic polymers. These have higher glass transition temperatures and are more thermostable than the parent adducts.
    Additional Material: 2 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 19 (1981), S. 1799-1800 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 184 (1983), S. 1645-1651 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Thermal analysis by differential scanning calorimetry (DSC) indicated that graft copolymers of poly(tetrahydrofuran) (PTHF) on a nitrile rubber containing 39 wt.-% acrylonitrile have a two-phase morphology comprising crystalline PTHF and amorphous rubber. In rubbers with an 18 wt.-% acrylonitrile content the PTHF is more compatible with the rubber and exerts a plasticising effect; crystallinity of the PTHF is not as well developed. cis-1,4-Polybutadiene and PTHF are partially miscible and in grafts on these two the melting endotherm of the latter was not detected. The relative values of the solubility parameters of PTHF and the three rubbers are consistent with this behaviour. All graft copolymers have a fairly low thermal stability and begin to decompose under N2 below 200°C. Degradation appears to be initiated at the PTHF grafts. Graft copolymers of PTHF with nitrile rubbers are less resistant to petroleum than the ungrafted rubbers.
    Additional Material: 3 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 184 (1983), S. 1153-1161 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: cis-1,4-Polybutadiene and nitrile rubbers were functionalised with chlorohydrin groups up to levels of 10 mol-% in a two-stage process. In the first stage epoxide groups were introduced by reaction of the rubber with m-chloroperbenzoic acid and in the second stage the epoxide ring was opened by reaction with hydrochloric acid to yield chlorohydrin groups. Both steps in the process are clean and virtually quantitative. Graft chains of poly(tetrahydrofuran) were introduced by coupling the hydroxyl groups with living poly(tetrahydrofuran) cations. The lengths of the graft chains were determined by the time between initiation (by the action of silver perchlorate on ethyl bromide in tetrahydrofuran solution) and the coupling step with the functionalised rubber.
    Additional Material: 4 Ill.
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