ISSN:
0021-8383
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The reaction of c-Si6Me12 with SbCl5 proceeds with cleavage of the methyl groups from silicon and gives c-ClSi6Me11 and c-Cl2Si6Me10 as main products. The molar ratio of those compounds depends on solvent. The same chlorodemethylation reaction takes place if c-Si6Me12 reacts with GaCl3.The reaction with SnCl4 proceeds with cleavage of the Si—Si bonds of polysilane and α,ω-dichloropermethylpolysilanes, with the 1,6-Cl2Si6Me12 as the main product, are formed.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19903320214
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