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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of atmospheric chemistry 14 (1992), S. 353-374 
    ISSN: 1573-0662
    Keywords: North Pacific ; global atmospheric chemistry ; modeling ; radon
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract The atmospheric distribution of222Rn over the north Pacific is simulated with a three-dimensional chemical tracer model using meteorological input from the NASA-GISS general circulation model (4°×5° resolution). Radon-222 (half-life 3.8 days) is a tracer of continental air. Model results are in good agreement with measurements from ships and aircraft. Strong Asian influence is found throughout the tropospheric column over the north Pacific in spring, reflecting a combination of frequent convection over the continent, strong westerly winds at altitude, and subsidence over the ocean. In summer, the upper troposphere over the north Pacific is heavily affected by deep convection over China; however, Asian influences at the surface are then at their yearly minimum. In winter, strong Asian influence is found near the surface but not at high altitudes. Transport of American air over the Pacific is important only at low latitudes. American sources account for 11% of total222Rn in the model at Midway, 30% at Mauna Loa and 59% at Oahu. Results for Hawaii indicate two seasonal peaks of American influence, one in summer and one in winter. The tropical western Pacific is particularly remote from continental influences year round.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2019-07-13
    Description: Measurements of reactive nitrogen oxides (NO(x) and NO(y)) and ozone (O3) were made in the planetary boundary layer (PBL) above a taiga woodland in northern Quebec, Canada, during June-August, 1990, as part of NASA Artic Boundary Layer Expedition (ABLE) 3B. Levels of nitrogen oxides and O3 were strongly modulated by the synoptic scale meteorology that brought air from various source regions to the site. Industrial pollution from the Great Lakes region of the U.S. and Canada appears to be a major source for periodic elevation of NO(x), and NO(y) and O3. We find that NO/NO2 ratios at this site at midday were approximately 50% those expected from a simple photochemical steady state between NO(x) and O3, in contrast to our earlier results from the ABLE 3A tundra site. The difference between the taiga and tundra sites is likely due to much larger emissions of biogenic hydrocarbons (particularly isoprene) from the taiga vegetation. Hydrocarbon photooxidation leads to relatively rapid production of peroxy radicals, which convert NO to NO2, at the taiga site. Ratios of NO(x) to NO(y) were typically 2-3 times higher in the PBL during ABLE 3B than during ABLE 3A. This is probably the result of high PAN levels and suppressed formation of HNO3 from NO2 due to high levels of biogenic hydrocarbons at the ABLE 3B site.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Journal of Geophysical Research (ISSN 0148-0227); 99; D1; p. 1927-1936
    Format: text
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  • 3
    Publication Date: 2019-07-12
    Description: An eddy correlation measurement of O3 deposition and CO2 exchange at a level 10 m above the canopy of the Amazon forest, conducted as part of the NASA/INPE ABLE2b mission during the wet season of 1987, is presented. It was found that the ecosystem exchange of CO2 undergoes a well-defined diurnal variation driven by the input of solar radiation. A curvilinear relationship was found between solar irradiance and uptake of CO2, with net CO2 uptake at a given solar irradiance equal to rates observed over forests in other climate zones. The carbon balance of the system appeared sensitive to cloud cover on the time scale of the experiment, suggesting that global carbon storage might be affected by changes in insolation associated with tropical climate fluctuations. The forest was found to be an efficient sink for O3 during the day, and evidence indicates that the Amazon forests could be a significant sink for global ozone during the nine-month wet period and that deforestation could dramatically alter O3 budgets.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Journal of Geophysical Research (ISSN 0148-0227); 95; 16851-16
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  • 4
    Publication Date: 2019-07-12
    Description: A three-dimensional tracer model based on the Goddard Institude of Space Studies GCM is used to simulate the distribution of Rn-222 over North America to test the ability of the model to describe the transport of pollutants in the boundary layer and the exchange of mass between the boundary layer and the free troposphere. The model results are compared with surface observations from five sites in the U.S., showing that Rn-222 concentrations are primarily regulated by dry convection. The simulations show satisfactory agreement with observations although the model underpredicts observations at night and the simulated Rn-222 concentrations over the northeastern U.S. are too high in the spring and too low in the fall.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Tellus, Series B - Chemical and Physical Meteorology (ISSN 0280-6509); 42B; 118-134
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  • 5
    Publication Date: 2019-07-12
    Description: The occurrence of high Rn-222 episodes (radonic storms) observed at three islands (Crozet, Kerguelen, and Amsterdam) in the subantarctic Indian Ocean is simulated using a three-dimensional chemical tracer model. The chemical tracer model is described and the simulated time series of Rn-222 concentrations at the three islands are compared to observations. The origin, seasonal frequencies, and periodicities of the storms are examined. It is found that the storms are due to fast boundary layer advection of air from South Africa, made possible by the conjunction of a subtropical high SE of Madagascar and a midlatitudes low off the southern tip of Africa. The implications of the results for the transport of continental air to the subantarctic Indian Ocean are discussed.
    Keywords: METEOROLOGY AND CLIMATOLOGY
    Type: Tellus, Series B - Chemical and Physical Meteorology (ISSN 0280-6509); 42B; 62-75
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